CN106604936A - 聚丁烯制备方法 - Google Patents

聚丁烯制备方法 Download PDF

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Publication number
CN106604936A
CN106604936A CN201580045007.8A CN201580045007A CN106604936A CN 106604936 A CN106604936 A CN 106604936A CN 201580045007 A CN201580045007 A CN 201580045007A CN 106604936 A CN106604936 A CN 106604936A
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China
Prior art keywords
isomerization
polybutene
isobutene
reactor
catalyst
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CN201580045007.8A
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English (en)
Chinese (zh)
Inventor
金明奭
朴敏燮
徐炯在
李说铉
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DL Holdings Co Ltd
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Daelim Industrial Co Ltd
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Publication of CN106604936A publication Critical patent/CN106604936A/zh
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/08—Butenes
    • C08F210/10—Isobutene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/08—Butenes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • B01J19/245—Stationary reactors without moving elements inside placed in series
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/04—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
    • B01J8/0403—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the fluid flow within the beds being predominantly horizontal
    • B01J8/0407—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the fluid flow within the beds being predominantly horizontal through two or more cylindrical annular shaped beds
    • B01J8/0419—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the fluid flow within the beds being predominantly horizontal through two or more cylindrical annular shaped beds the beds being placed in separate reactors
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/23—Rearrangement of carbon-to-carbon unsaturated bonds
    • C07C5/25—Migration of carbon-to-carbon double bonds
    • C07C5/2506—Catalytic processes
    • C07C5/2556—Catalytic processes with metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
    • C07C5/2702—Catalytic processes not covered by C07C5/2732 - C07C5/31; Catalytic processes covered by both C07C5/2732 and C07C5/277 simultaneously
    • C07C5/2708—Catalytic processes not covered by C07C5/2732 - C07C5/31; Catalytic processes covered by both C07C5/2732 and C07C5/277 simultaneously with crystalline alumino-silicates, e.g. molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
    • C07C5/2767—Changing the number of side-chains
    • C07C5/277—Catalytic processes
    • C07C5/2775—Catalytic processes with crystalline alumino-silicates, e.g. molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/08—Butenes
    • C08F110/10—Isobutene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/08—Butenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/08—Butenes
    • C08F210/10—Isobutene
    • C08F210/12—Isobutene with conjugated diolefins, e.g. butyl rubber
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F236/06—Butadiene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/24—Stationary reactors without moving elements inside
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/42—Platinum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Fluid Mechanics (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
CN201580045007.8A 2014-08-22 2015-08-21 聚丁烯制备方法 Pending CN106604936A (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
KR10-2014-0109548 2014-08-22
KR1020140109548A KR101658545B1 (ko) 2014-08-22 2014-08-22 폴리부텐의 제조방법
PCT/KR2015/008776 WO2016028123A1 (ko) 2014-08-22 2015-08-21 폴리부텐의 제조방법

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Publication Number Publication Date
CN106604936A true CN106604936A (zh) 2017-04-26

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CN201580045007.8A Pending CN106604936A (zh) 2014-08-22 2015-08-21 聚丁烯制备方法

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US (1) US10202476B2 (enExample)
EP (1) EP3184557B1 (enExample)
JP (1) JP6673904B2 (enExample)
KR (1) KR101658545B1 (enExample)
CN (1) CN106604936A (enExample)
BR (1) BR112017003296B1 (enExample)
MY (1) MY182242A (enExample)
SG (1) SG11201701392VA (enExample)
WO (1) WO2016028123A1 (enExample)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109134719A (zh) * 2017-06-28 2019-01-04 因菲纽国际有限公司 聚合引发系统和生产高反应性烯烃功能聚合物的方法
WO2023016561A1 (zh) * 2021-08-13 2023-02-16 南京中科康润新材料科技有限公司 用于c4液化石油气阳离子聚合的催化剂体系及聚丁烯生产方法

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6988642B2 (ja) * 2018-03-29 2022-01-05 国立大学法人九州大学 アリル化合物の異性化方法
JP7188543B2 (ja) * 2018-03-29 2022-12-13 国立大学法人九州大学 アリル化合物の異性化方法
WO2023172750A1 (en) * 2022-03-10 2023-09-14 Lummus Technology Llc Converting isobutane and refinery c4s to propylene
WO2024242906A1 (en) 2023-05-19 2024-11-28 Ntp Tec, Llc Processes for converting c4 feeds to isobutylene, polyisobutylene, or derivatives thereof

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CN1120049A (zh) * 1994-03-07 1996-04-10 英国石油化学品有限公司 聚异丁烯的生产方法
CN1140749A (zh) * 1995-05-11 1997-01-22 法国石油公司 C4烯烃馏分转化成聚异丁烯和丙烯的方法与设备
US5969203A (en) * 1996-12-23 1999-10-19 Institut Francais Du Petrole Process for the production of high purity isobutene combining reactive distillation with hydroisomerization, distillation and skeletal isomerization
US5981818A (en) * 1995-03-21 1999-11-09 Stone & Webster Engineering Corp. Integrated cracking and olefins derivative process utilizing dilute olefins
US6137023A (en) * 1996-12-23 2000-10-24 Institut Francais Du Petrole Process for the production of high purity isobutene combining reactive distillation with hydroisomerisation and skeletal isomerisation
CN1384843A (zh) * 1999-10-28 2002-12-11 巴斯福股份公司 高反应性聚异丁烯的制备方法
CN1395582A (zh) * 2000-11-13 2003-02-05 大林产业株式会社 聚丁烯的制备方法
CN101223197A (zh) * 2005-07-12 2008-07-16 巴斯福股份公司 制备高品质聚异丁烯的方法
KR100851639B1 (ko) * 2007-03-22 2008-08-13 대림산업 주식회사 고농도 이소부텐을 이용한 고반응성 폴리이소부텐의제조방법
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CN1120049A (zh) * 1994-03-07 1996-04-10 英国石油化学品有限公司 聚异丁烯的生产方法
US5981818A (en) * 1995-03-21 1999-11-09 Stone & Webster Engineering Corp. Integrated cracking and olefins derivative process utilizing dilute olefins
CN1140749A (zh) * 1995-05-11 1997-01-22 法国石油公司 C4烯烃馏分转化成聚异丁烯和丙烯的方法与设备
US6207115B1 (en) * 1995-05-11 2001-03-27 Institut Francais Du Petrole Process and plant for the conversion of olefinic C4 cuts to polyisobutene and to propylene
US5969203A (en) * 1996-12-23 1999-10-19 Institut Francais Du Petrole Process for the production of high purity isobutene combining reactive distillation with hydroisomerization, distillation and skeletal isomerization
US6137023A (en) * 1996-12-23 2000-10-24 Institut Francais Du Petrole Process for the production of high purity isobutene combining reactive distillation with hydroisomerisation and skeletal isomerisation
CN1384843A (zh) * 1999-10-28 2002-12-11 巴斯福股份公司 高反应性聚异丁烯的制备方法
CN1395582A (zh) * 2000-11-13 2003-02-05 大林产业株式会社 聚丁烯的制备方法
CN101223197A (zh) * 2005-07-12 2008-07-16 巴斯福股份公司 制备高品质聚异丁烯的方法
CN101460530A (zh) * 2006-06-06 2009-06-17 巴斯夫欧洲公司 由低异丁烯的c4烃混合物制备反应性且基本上无卤聚异丁烯的方法
KR100851639B1 (ko) * 2007-03-22 2008-08-13 대림산업 주식회사 고농도 이소부텐을 이용한 고반응성 폴리이소부텐의제조방법

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109134719A (zh) * 2017-06-28 2019-01-04 因菲纽国际有限公司 聚合引发系统和生产高反应性烯烃功能聚合物的方法
CN109134719B (zh) * 2017-06-28 2020-11-24 因菲纽国际有限公司 聚合引发系统和生产高反应性烯烃功能聚合物的方法
WO2023016561A1 (zh) * 2021-08-13 2023-02-16 南京中科康润新材料科技有限公司 用于c4液化石油气阳离子聚合的催化剂体系及聚丁烯生产方法

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KR20160023321A (ko) 2016-03-03
EP3184557A1 (en) 2017-06-28
BR112017003296B1 (pt) 2022-02-08
EP3184557C0 (en) 2023-12-20
MY182242A (en) 2021-01-18
US10202476B2 (en) 2019-02-12
KR101658545B1 (ko) 2016-09-21
BR112017003296A2 (pt) 2017-11-28
JP6673904B2 (ja) 2020-03-25
EP3184557A4 (en) 2018-04-18
EP3184557B1 (en) 2023-12-20
WO2016028123A1 (ko) 2016-02-25
JP2017526779A (ja) 2017-09-14
US20170267795A1 (en) 2017-09-21
SG11201701392VA (en) 2017-04-27

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