BR112012016978B1 - Processo para a produção de dióxido de cloro - Google Patents
Processo para a produção de dióxido de cloro Download PDFInfo
- Publication number
- BR112012016978B1 BR112012016978B1 BR112012016978-5A BR112012016978A BR112012016978B1 BR 112012016978 B1 BR112012016978 B1 BR 112012016978B1 BR 112012016978 A BR112012016978 A BR 112012016978A BR 112012016978 B1 BR112012016978 B1 BR 112012016978B1
- Authority
- BR
- Brazil
- Prior art keywords
- chlorine dioxide
- aqueous solution
- storage tank
- water
- residence time
- Prior art date
Links
- OSVXSBDYLRYLIG-UHFFFAOYSA-N dioxidochlorine(.) Chemical compound O=Cl=O OSVXSBDYLRYLIG-UHFFFAOYSA-N 0.000 title claims abstract description 298
- 239000004155 Chlorine dioxide Substances 0.000 title claims abstract description 149
- 235000019398 chlorine dioxide Nutrition 0.000 title claims abstract description 149
- 238000000034 method Methods 0.000 title claims abstract description 46
- 238000004519 manufacturing process Methods 0.000 title claims description 15
- 238000003860 storage Methods 0.000 claims abstract description 63
- 239000007864 aqueous solution Substances 0.000 claims abstract description 39
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 50
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 27
- XTEGARKTQYYJKE-UHFFFAOYSA-M chlorate Inorganic materials [O-]Cl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-M 0.000 claims description 15
- 239000003638 chemical reducing agent Substances 0.000 claims description 13
- -1 chlorate ions Chemical class 0.000 claims description 11
- 239000012431 aqueous reaction media Substances 0.000 claims description 5
- 230000015572 biosynthetic process Effects 0.000 claims description 4
- 239000000243 solution Substances 0.000 claims description 4
- 239000012429 reaction media Substances 0.000 description 25
- 238000006243 chemical reaction Methods 0.000 description 19
- 239000002253 acid Substances 0.000 description 15
- 239000007789 gas Substances 0.000 description 14
- 238000010521 absorption reaction Methods 0.000 description 9
- BZSXEZOLBIJVQK-UHFFFAOYSA-N 2-methylsulfonylbenzoic acid Chemical compound CS(=O)(=O)C1=CC=CC=C1C(O)=O BZSXEZOLBIJVQK-UHFFFAOYSA-N 0.000 description 8
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 8
- 239000000460 chlorine Substances 0.000 description 8
- 229910052801 chlorine Inorganic materials 0.000 description 8
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 8
- 239000006096 absorbing agent Substances 0.000 description 7
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 6
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 6
- 229910052783 alkali metal Inorganic materials 0.000 description 6
- 238000004061 bleaching Methods 0.000 description 6
- 239000012535 impurity Substances 0.000 description 6
- 239000011261 inert gas Substances 0.000 description 6
- 239000000047 product Substances 0.000 description 5
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 4
- 239000006227 byproduct Substances 0.000 description 4
- 238000002425 crystallisation Methods 0.000 description 4
- 230000008025 crystallization Effects 0.000 description 4
- 235000019253 formic acid Nutrition 0.000 description 4
- 238000000746 purification Methods 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 238000009835 boiling Methods 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 159000000000 sodium salts Chemical class 0.000 description 3
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- XTEGARKTQYYJKE-UHFFFAOYSA-N chloric acid Chemical compound OCl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-N 0.000 description 2
- 229940005991 chloric acid Drugs 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 238000010517 secondary reaction Methods 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 description 2
- 235000011152 sodium sulphate Nutrition 0.000 description 2
- NHYCGSASNAIGLD-UHFFFAOYSA-N Chlorine monoxide Chemical class Cl[O] NHYCGSASNAIGLD-UHFFFAOYSA-N 0.000 description 1
- 239000007832 Na2SO4 Substances 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 150000008043 acidic salts Chemical class 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 238000007792 addition Methods 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000011260 aqueous acid Substances 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 229910001902 chlorine oxide Inorganic materials 0.000 description 1
- UHZZMRAGKVHANO-UHFFFAOYSA-M chlormequat chloride Chemical compound [Cl-].C[N+](C)(C)CCCl UHZZMRAGKVHANO-UHFFFAOYSA-M 0.000 description 1
- 238000010960 commercial process Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000007872 degassing Methods 0.000 description 1
- SAUMVKNLVQDHMJ-UHFFFAOYSA-N dichlorine trioxide Inorganic materials ClOCl(=O)=O SAUMVKNLVQDHMJ-UHFFFAOYSA-N 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 101150025733 pub2 gene Proteins 0.000 description 1
- 238000004076 pulp bleaching Methods 0.000 description 1
- 238000004537 pulping Methods 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B11/00—Oxides or oxyacids of halogens; Salts thereof
- C01B11/02—Oxides of chlorine
- C01B11/022—Chlorine dioxide (ClO2)
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B11/00—Oxides or oxyacids of halogens; Salts thereof
- C01B11/02—Oxides of chlorine
- C01B11/022—Chlorine dioxide (ClO2)
- C01B11/023—Preparation from chlorites or chlorates
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B11/00—Oxides or oxyacids of halogens; Salts thereof
- C01B11/02—Oxides of chlorine
- C01B11/022—Chlorine dioxide (ClO2)
- C01B11/023—Preparation from chlorites or chlorates
- C01B11/025—Preparation from chlorites or chlorates from chlorates without any other reaction reducing agent than chloride ions
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B11/00—Oxides or oxyacids of halogens; Salts thereof
- C01B11/02—Oxides of chlorine
- C01B11/022—Chlorine dioxide (ClO2)
- C01B11/023—Preparation from chlorites or chlorates
- C01B11/026—Preparation from chlorites or chlorates from chlorate ions in the presence of a peroxidic compound, e.g. hydrogen peroxide, ozone, peroxysulfates
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B11/00—Oxides or oxyacids of halogens; Salts thereof
- C01B11/02—Oxides of chlorine
- C01B11/022—Chlorine dioxide (ClO2)
- C01B11/028—Separation; Purification
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Paper (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Gas Separation By Absorption (AREA)
- Treatment Of Water By Oxidation Or Reduction (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US29588110P | 2010-01-18 | 2010-01-18 | |
| EP10150944 | 2010-01-18 | ||
| EP10150944.6 | 2010-01-18 | ||
| US61/295,881 | 2010-01-18 | ||
| PCT/EP2011/050430 WO2011086147A1 (en) | 2010-01-18 | 2011-01-14 | Process for the production of chlorine dioxide |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BR112012016978A2 BR112012016978A2 (pt) | 2016-04-12 |
| BR112012016978B1 true BR112012016978B1 (pt) | 2023-10-31 |
Family
ID=42224034
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BR112012016978-5A BR112012016978B1 (pt) | 2010-01-18 | 2011-01-14 | Processo para a produção de dióxido de cloro |
Country Status (15)
| Country | Link |
|---|---|
| US (1) | US20120294794A1 (enExample) |
| EP (1) | EP2526047B1 (enExample) |
| JP (1) | JP5735985B2 (enExample) |
| KR (1) | KR101765735B1 (enExample) |
| CN (1) | CN102712471B (enExample) |
| AR (1) | AR080358A1 (enExample) |
| AU (1) | AU2011206595B2 (enExample) |
| BR (1) | BR112012016978B1 (enExample) |
| CA (1) | CA2785438C (enExample) |
| CL (1) | CL2012001982A1 (enExample) |
| MX (1) | MX340592B (enExample) |
| MY (1) | MY161887A (enExample) |
| PT (1) | PT2526047T (enExample) |
| RU (1) | RU2562858C2 (enExample) |
| WO (1) | WO2011086147A1 (enExample) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2639204B1 (en) * | 2012-03-15 | 2017-07-12 | Evoqua Water Technologies GmbH | Process and device for generating chlorine dioxide for the disinfection of water |
| CN103101883B (zh) * | 2013-03-01 | 2015-04-15 | 唐洪权 | 食品添加剂稳定态二氧化氯溶液生产及活化方法 |
| CN105036083A (zh) * | 2015-07-08 | 2015-11-11 | 优尼克生技股份有限公司 | 一种二氧化氯水溶液的保存方法 |
| CN106865501B (zh) * | 2015-12-11 | 2019-03-22 | 深圳市罗奇环保科技有限公司 | 二氧化氯的吸收方法 |
| US11535541B2 (en) | 2017-02-27 | 2022-12-27 | Ecolab Usa Inc. | Method for onsite production of chlorine dioxide |
| TWI751311B (zh) | 2017-03-24 | 2022-01-01 | 美商藝康美國公司 | 低風險的二氧化氯現場產生系統 |
| TWI750356B (zh) | 2017-08-17 | 2021-12-21 | 美商藝康美國公司 | 低風險二氧化氯現場產生系統 |
| US11970393B2 (en) | 2018-07-05 | 2024-04-30 | Ecolab Usa Inc. | Decomposition mediation in chlorine dioxide generation systems through sound detection and control |
| US12063900B2 (en) | 2018-07-30 | 2024-08-20 | King Abdullah University Of Science And Technology | Liquid desiccant based humidity pump, evaporative cooler, and air purification systems |
| KR102117101B1 (ko) | 2018-08-16 | 2020-05-29 | 이준식 | 이산화염소수 희석 장치 |
Family Cites Families (51)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2833624A (en) | 1956-10-02 | 1958-05-06 | Du Pont | Production of chlorine dioxide |
| US3864456A (en) * | 1964-08-13 | 1975-02-04 | Electric Reduction Co | Manufacture of chlorine dioxide, chlorine and anhydrous sodium sulphate |
| US3816077A (en) * | 1971-05-21 | 1974-06-11 | Hooker Chemical Corp | Chlorine dioxide generating system |
| CA1088274A (en) * | 1976-03-24 | 1980-10-28 | Alain Caillol | Process and installation for the manufacture of chlorine dioxide |
| US4129484A (en) | 1976-05-11 | 1978-12-12 | Kemanord Ab | Process for regeneration of spent reaction solutions |
| US4152073A (en) * | 1977-06-22 | 1979-05-01 | Westvaco Corporation | Liquid and gas chlorine dioxide photometer |
| GB2051758B (en) * | 1979-05-31 | 1983-09-14 | Erco Ind Ltd | Small scale chlorine dioxide plant |
| CA1136378A (en) * | 1979-05-31 | 1982-11-30 | Gerald Cowley | Small scale chlorine dioxide plant |
| US4325934A (en) * | 1980-09-22 | 1982-04-20 | Erco Industries Limited | Production of chlorine dioxide with conversion of by-product solid phase sodium acid sulphate to its neutral form |
| US4534952A (en) | 1984-02-24 | 1985-08-13 | Erco Industries Limited | Small scale generation of chlorine dioxide for water treatment |
| JPS61117102A (ja) * | 1984-11-12 | 1986-06-04 | マルチフアイバ−・プロセス・リミテツド | 二酸化塩素の生成方法 |
| JPS638203A (ja) | 1986-06-26 | 1988-01-14 | Japan Carlit Co Ltd:The | 高純度の二酸化塩素を製造する方法 |
| US5009875A (en) * | 1988-08-03 | 1991-04-23 | International Dioxcide, Inc. | Process of preparing clorine dioxide and apparatus therefor |
| US4925645A (en) * | 1988-10-05 | 1990-05-15 | Mason James A | Method of preparing a mixture of chlorine containing substances including chlorine dioxide |
| SE8804251D0 (sv) * | 1988-11-24 | 1988-11-24 | Alby Klorat Ab | Saett att framstaella klordioxid |
| WO1990008558A1 (en) * | 1989-01-27 | 1990-08-09 | Trans Delta Corporation | Stabilized sterilizing or disinfecting halogen containing composition, method and apparatus |
| JPH0621004B2 (ja) * | 1989-08-29 | 1994-03-23 | ダイソー株式会社 | 二酸化塩素の製造法 |
| JPH0621005B2 (ja) | 1989-09-29 | 1994-03-23 | ダイソー株式会社 | 二酸化塩素の製造法 |
| CA2023452C (en) * | 1990-03-05 | 1994-05-24 | Birgitta Sundblad | Process for production of chlorine dioxide |
| US5770171A (en) | 1990-03-05 | 1998-06-23 | Eka Nobel Inc. | Process for production of chlorine dioxide |
| SE500042C2 (sv) | 1990-08-31 | 1994-03-28 | Eka Nobel Ab | Förfarande för kontinuerlig framställning av klordioxid |
| SE500043C2 (sv) | 1990-08-31 | 1994-03-28 | Eka Nobel Ab | Förfarande för kontinuerlig framställning av klordioxid |
| US5207532A (en) * | 1991-01-09 | 1993-05-04 | Exxon Chemical Patents Inc. | Process for conditioning material for disposal |
| US5324497A (en) * | 1992-02-26 | 1994-06-28 | Westerlund G Oscar | Integrated procedure for high yield production of chlorine dioxide and apparatus used therefor |
| US5366714A (en) | 1992-06-09 | 1994-11-22 | Sterling Canada Inc. | Hydrogen peroxide-based chlorine dioxide process |
| US5487881A (en) | 1993-02-26 | 1996-01-30 | Eka Nobel Inc. | Process of producing chlorine dioxide |
| US5380517B1 (en) | 1993-02-26 | 1999-01-19 | Eka Nobel Inc | Process for continuously producing chlorine dioxide |
| US5478446A (en) | 1993-07-02 | 1995-12-26 | Eka Nobel Inc. | Electrochemical process |
| US5458858A (en) * | 1994-02-08 | 1995-10-17 | Vulcan Chemicals | Integrated procedure for high yield production of chlorine dioxide |
| AU2204995A (en) * | 1994-04-07 | 1995-10-30 | Jon L. Richter | Oral rinse and method of treating halitosis |
| NZ272769A (en) | 1994-08-18 | 1996-03-26 | Eka Nobel Inc | Process for producing chlorine dioxide by reducing chlorate in acidic reaction medium |
| US6585950B1 (en) | 1995-06-07 | 2003-07-01 | Eka Nobel Ab | Method of producing chlorine dioxide |
| SE9502077L (sv) | 1995-06-07 | 1996-08-22 | Eka Chemicals Ab | Sätt att framställa klordioxid |
| US5855861A (en) * | 1996-02-23 | 1999-01-05 | Water Technologies Limited | Method and apparatus for making aqueous chlorine dioxide |
| US5895638A (en) * | 1997-03-20 | 1999-04-20 | Akzo Nobel N.V. | Method of producing chlorine dioxide |
| US7070710B1 (en) | 1999-06-11 | 2006-07-04 | Eka Chemicals Inc. | Chemical composition and method |
| US6322690B1 (en) | 1999-11-26 | 2001-11-27 | Akzo Nobel N.V. | Chemical method |
| US20030031621A1 (en) | 2001-05-29 | 2003-02-13 | Alan Gravitt | Process and apparatus for the generation of chlorine dioxide using a replenished foam system |
| US6790427B2 (en) | 2001-06-25 | 2004-09-14 | Eka Chemicals, Inc. | Process for producing chlorine dioxide |
| US20040175322A1 (en) | 2003-03-03 | 2004-09-09 | Woodruff Thomas E. | Process for producing chlorine dioxide |
| US20040228790A1 (en) * | 2003-05-15 | 2004-11-18 | Costa Mario Luis | Chlorine dioxide from a methanol-based generating system as a chemical feed in alkali metal chlorite manufacture |
| CN100471791C (zh) | 2004-02-23 | 2009-03-25 | 阿克佐诺贝尔公司 | 二氧化氯的生产方法 |
| EP1750502A4 (en) * | 2004-05-17 | 2011-09-07 | John Y Mason | PROCESS FOR TREATMENT WITH CHLORIDE DIOXIDE |
| US7833392B2 (en) * | 2004-07-29 | 2010-11-16 | Pureline Treatment Systems, Llc | Chlorine dioxide solution generator |
| CA2581318C (en) | 2004-09-24 | 2011-03-15 | Akzo Nobel N.V. | A process for the production of chlorine dioxide |
| DE602005019778D1 (de) | 2004-12-06 | 2010-04-15 | Akzo Nobel Nv | Chemisches verfahren und produktionseinheit |
| PT1831102E (pt) | 2004-12-06 | 2011-07-20 | Akzo Nobel Nv | Processo químico e dispositivo |
| ZA200803849B (en) | 2005-11-10 | 2009-09-30 | Akzo Nobel Nv | Process for production of chlorine dioxide |
| CA2629888C (en) * | 2005-11-14 | 2017-02-14 | Cdg Technology Inc. | Storage-stable aqueous solutions of chlorine dioxide and methods for preparing and using them |
| CN101421182A (zh) | 2006-04-10 | 2009-04-29 | 阿克佐诺贝尔股份有限公司 | 制备二氧化氯的方法 |
| TWI447065B (zh) * | 2007-07-13 | 2014-08-01 | Akzo Nobel Nv | 二氧化氯之製造方法 |
-
2011
- 2011-01-14 PT PT117005363T patent/PT2526047T/pt unknown
- 2011-01-14 JP JP2012548445A patent/JP5735985B2/ja not_active Expired - Fee Related
- 2011-01-14 MX MX2012008098A patent/MX340592B/es active IP Right Grant
- 2011-01-14 BR BR112012016978-5A patent/BR112012016978B1/pt active IP Right Grant
- 2011-01-14 WO PCT/EP2011/050430 patent/WO2011086147A1/en not_active Ceased
- 2011-01-14 MY MYPI2012003152A patent/MY161887A/en unknown
- 2011-01-14 KR KR1020127018024A patent/KR101765735B1/ko not_active Expired - Fee Related
- 2011-01-14 US US13/522,572 patent/US20120294794A1/en not_active Abandoned
- 2011-01-14 EP EP11700536.3A patent/EP2526047B1/en active Active
- 2011-01-14 CN CN201180005814.9A patent/CN102712471B/zh not_active Expired - Fee Related
- 2011-01-14 CA CA2785438A patent/CA2785438C/en active Active
- 2011-01-14 RU RU2012134406/05A patent/RU2562858C2/ru not_active IP Right Cessation
- 2011-01-14 AU AU2011206595A patent/AU2011206595B2/en not_active Ceased
- 2011-01-17 AR ARP110100135A patent/AR080358A1/es not_active Application Discontinuation
-
2012
- 2012-07-17 CL CL2012001982A patent/CL2012001982A1/es unknown
Also Published As
| Publication number | Publication date |
|---|---|
| JP5735985B2 (ja) | 2015-06-17 |
| MX340592B (es) | 2016-07-15 |
| CA2785438C (en) | 2018-02-20 |
| MY161887A (en) | 2017-05-15 |
| RU2012134406A (ru) | 2014-02-27 |
| EP2526047A1 (en) | 2012-11-28 |
| JP2013517199A (ja) | 2013-05-16 |
| KR101765735B1 (ko) | 2017-08-07 |
| WO2011086147A1 (en) | 2011-07-21 |
| RU2562858C2 (ru) | 2015-09-10 |
| AU2011206595B2 (en) | 2013-10-03 |
| CA2785438A1 (en) | 2011-07-21 |
| PT2526047T (pt) | 2017-11-17 |
| EP2526047B1 (en) | 2017-08-23 |
| AR080358A1 (es) | 2012-04-04 |
| AU2011206595A1 (en) | 2012-07-12 |
| KR20120128608A (ko) | 2012-11-27 |
| CN102712471A (zh) | 2012-10-03 |
| CL2012001982A1 (es) | 2012-11-30 |
| MX2012008098A (es) | 2012-07-30 |
| US20120294794A1 (en) | 2012-11-22 |
| BR112012016978A2 (pt) | 2016-04-12 |
| CN102712471B (zh) | 2015-02-18 |
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