BR102015014235B1 - Composição compreendendo um polímero condutor dispersado e processo para tratamento de uma superfície metálica - Google Patents
Composição compreendendo um polímero condutor dispersado e processo para tratamento de uma superfície metálica Download PDFInfo
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- BR102015014235B1 BR102015014235B1 BR102015014235-8A BR102015014235A BR102015014235B1 BR 102015014235 B1 BR102015014235 B1 BR 102015014235B1 BR 102015014235 A BR102015014235 A BR 102015014235A BR 102015014235 B1 BR102015014235 B1 BR 102015014235B1
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- Prior art keywords
- composition
- coating
- cerium
- silane
- metallic surface
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- 239000000203 mixture Substances 0.000 title claims abstract description 108
- 238000000034 method Methods 0.000 title claims abstract description 65
- 230000008569 process Effects 0.000 title claims abstract description 55
- 229920001940 conductive polymer Polymers 0.000 title claims abstract description 30
- 238000011282 treatment Methods 0.000 title description 20
- 238000000576 coating method Methods 0.000 claims abstract description 86
- 229910052751 metal Inorganic materials 0.000 claims abstract description 73
- 239000002184 metal Substances 0.000 claims abstract description 73
- 239000011248 coating agent Substances 0.000 claims abstract description 62
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims abstract description 52
- 238000007739 conversion coating Methods 0.000 claims abstract description 46
- 229910000077 silane Inorganic materials 0.000 claims abstract description 42
- HSJPMRKMPBAUAU-UHFFFAOYSA-N cerium(3+);trinitrate Chemical compound [Ce+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O HSJPMRKMPBAUAU-UHFFFAOYSA-N 0.000 claims abstract description 34
- 150000003754 zirconium Chemical class 0.000 claims abstract description 21
- 238000001035 drying Methods 0.000 claims abstract description 9
- 150000003839 salts Chemical class 0.000 claims description 44
- 229920000128 polypyrrole Polymers 0.000 claims description 15
- 238000007654 immersion Methods 0.000 claims description 14
- 125000000217 alkyl group Chemical group 0.000 claims description 8
- BPSIOYPQMFLKFR-UHFFFAOYSA-N trimethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical group CO[Si](OC)(OC)CCCOCC1CO1 BPSIOYPQMFLKFR-UHFFFAOYSA-N 0.000 claims description 7
- NOZAQBYNLKNDRT-UHFFFAOYSA-N [diacetyloxy(ethenyl)silyl] acetate Chemical compound CC(=O)O[Si](OC(C)=O)(OC(C)=O)C=C NOZAQBYNLKNDRT-UHFFFAOYSA-N 0.000 claims description 6
- 125000000524 functional group Chemical group 0.000 claims description 6
- VVXLFFIFNVKFBD-UHFFFAOYSA-N 4,4,4-trifluoro-1-phenylbutane-1,3-dione Chemical group FC(F)(F)C(=O)CC(=O)C1=CC=CC=C1 VVXLFFIFNVKFBD-UHFFFAOYSA-N 0.000 claims description 5
- 229920001609 Poly(3,4-ethylenedioxythiophene) Polymers 0.000 claims description 5
- ITZXULOAYIAYNU-UHFFFAOYSA-N cerium(4+) Chemical compound [Ce+4] ITZXULOAYIAYNU-UHFFFAOYSA-N 0.000 claims description 5
- 150000002823 nitrates Chemical class 0.000 claims description 5
- 229920000767 polyaniline Polymers 0.000 claims description 5
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 claims description 4
- TZZGHGKTHXIOMN-UHFFFAOYSA-N 3-trimethoxysilyl-n-(3-trimethoxysilylpropyl)propan-1-amine Chemical compound CO[Si](OC)(OC)CCCNCCC[Si](OC)(OC)OC TZZGHGKTHXIOMN-UHFFFAOYSA-N 0.000 claims description 3
- IZRJPHXTEXTLHY-UHFFFAOYSA-N triethoxy(2-triethoxysilylethyl)silane Chemical compound CCO[Si](OCC)(OCC)CC[Si](OCC)(OCC)OCC IZRJPHXTEXTLHY-UHFFFAOYSA-N 0.000 claims description 3
- JCGDCINCKDQXDX-UHFFFAOYSA-N trimethoxy(2-trimethoxysilylethyl)silane Chemical compound CO[Si](OC)(OC)CC[Si](OC)(OC)OC JCGDCINCKDQXDX-UHFFFAOYSA-N 0.000 claims description 3
- 238000005260 corrosion Methods 0.000 abstract description 66
- 230000007797 corrosion Effects 0.000 abstract description 65
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- 238000012360 testing method Methods 0.000 description 16
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- 239000000758 substrate Substances 0.000 description 15
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- 229910001868 water Inorganic materials 0.000 description 14
- 239000006185 dispersion Substances 0.000 description 13
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 description 12
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- 239000012972 dimethylethanolamine Substances 0.000 description 11
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- JOPOVCBBYLSVDA-UHFFFAOYSA-N chromium(6+) Chemical class [Cr+6] JOPOVCBBYLSVDA-UHFFFAOYSA-N 0.000 description 10
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- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 9
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- 239000000243 solution Substances 0.000 description 8
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- 150000000703 Cerium Chemical class 0.000 description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 6
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- 229910002651 NO3 Inorganic materials 0.000 description 6
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- 125000002947 alkylene group Chemical group 0.000 description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
- 239000002987 primer (paints) Substances 0.000 description 6
- -1 silane compound Chemical class 0.000 description 6
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 5
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- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 5
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- 239000002253 acid Substances 0.000 description 5
- 150000001785 cerium compounds Chemical class 0.000 description 5
- VYLVYHXQOHJDJL-UHFFFAOYSA-K cerium trichloride Chemical compound Cl[Ce](Cl)Cl VYLVYHXQOHJDJL-UHFFFAOYSA-K 0.000 description 5
- 239000011777 magnesium Substances 0.000 description 5
- 229910052749 magnesium Inorganic materials 0.000 description 5
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- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 4
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- 229910000831 Steel Inorganic materials 0.000 description 4
- XMPZTFVPEKAKFH-UHFFFAOYSA-P ceric ammonium nitrate Chemical compound [NH4+].[NH4+].[Ce+4].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O XMPZTFVPEKAKFH-UHFFFAOYSA-P 0.000 description 4
- 238000005238 degreasing Methods 0.000 description 4
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- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 4
- 229910000853 7075 T6 aluminium alloy Inorganic materials 0.000 description 3
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- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- 229910003899 H2ZrF6 Inorganic materials 0.000 description 3
- 229910019142 PO4 Inorganic materials 0.000 description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 3
- 125000002015 acyclic group Chemical group 0.000 description 3
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- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
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- 229910001335 Galvanized steel Inorganic materials 0.000 description 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 2
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- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- UEUMIMKGIUYUGH-UHFFFAOYSA-H [F-].[F-].[F-].[F-].[F-].[F-].[Zr+6] Chemical compound [F-].[F-].[F-].[F-].[F-].[F-].[Zr+6] UEUMIMKGIUYUGH-UHFFFAOYSA-H 0.000 description 2
- 229960000583 acetic acid Drugs 0.000 description 2
- 150000001242 acetic acid derivatives Chemical class 0.000 description 2
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- LQCIDLXXSFUYSA-UHFFFAOYSA-N cerium(4+);tetranitrate Chemical group [Ce+4].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O LQCIDLXXSFUYSA-UHFFFAOYSA-N 0.000 description 2
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- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/34—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D165/00—Coating compositions based on macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/24—Electrically-conducting paints
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/34—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides
- C23C22/36—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides containing also phosphates
- C23C22/361—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides containing also phosphates containing titanium, zirconium or hafnium compounds
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/78—Pretreatment of the material to be coated
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2222/00—Aspects relating to chemical surface treatment of metallic material by reaction of the surface with a reactive medium
- C23C2222/20—Use of solutions containing silanes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31652—Of asbestos
- Y10T428/31663—As siloxane, silicone or silane
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- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Metallurgy (AREA)
- Mechanical Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Chemical Treatment Of Metals (AREA)
- Paints Or Removers (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
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| EP14382078.5A EP2915903B1 (en) | 2014-03-05 | 2014-03-05 | Chromium-free conversion coating |
| US14/628,756 | 2015-02-23 | ||
| US14/628,756 US9290846B2 (en) | 2014-03-05 | 2015-02-23 | Chromium-free conversion coating |
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| BR102015014235B1 true BR102015014235B1 (pt) | 2021-12-14 |
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| US9744640B2 (en) * | 2015-10-16 | 2017-08-29 | Applied Materials, Inc. | Corrosion resistant retaining rings |
| US11365321B2 (en) | 2016-11-04 | 2022-06-21 | Battelle Memorial Institute | Corrosion inhibiting coating additive |
| CN107475704B (zh) * | 2017-07-11 | 2019-09-17 | 沈阳瑞驰表面技术有限公司 | 金属表面硅烷处理剂及其制备方法 |
| CN110945087A (zh) * | 2017-07-31 | 2020-03-31 | 诺维尔里斯公司 | 预处理组合物、经涂覆的铝合金及其制作方法 |
| US11746245B2 (en) | 2018-02-02 | 2023-09-05 | The Boeing Company | Soluble corrosion resistant sol-gel |
| US10926237B2 (en) | 2018-02-02 | 2021-02-23 | The Boeing Company | Soluble corrosion resistant sol-gel |
| US11414726B2 (en) * | 2018-03-07 | 2022-08-16 | The University Of Akron | Inhibitor-containing metal particles by mechanical alloying |
| US11530362B2 (en) | 2020-04-23 | 2022-12-20 | The Boeing Company | Organosiloxane-based surface treatments for enhancing the adhesion and lubricity of metal surfaces |
| JP7001209B1 (ja) * | 2021-03-08 | 2022-01-19 | 日本製鉄株式会社 | 塗装めっき鋼板又は塗装めっき鋼帯 |
| CN113913803B (zh) * | 2021-09-28 | 2023-07-11 | 中国人民解放军空军工程大学 | 镁合金化学转化复合膜及其制备方法 |
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| CA1292155C (en) | 1987-03-03 | 1991-11-19 | Lance Wilson | Method of forming a corrosion resistant coating |
| US5194138A (en) | 1990-07-20 | 1993-03-16 | The University Of Southern California | Method for creating a corrosion-resistant aluminum surface |
| EP0825280A3 (en) * | 1991-08-30 | 1998-04-01 | Henkel Corporation | Process for treating metal with aqueous acidic composition that is substantially free from chromium (VI) |
| US5362335A (en) | 1993-03-25 | 1994-11-08 | General Motors Corporation | Rare earth coating process for aluminum alloys |
| US6190780B1 (en) | 1996-02-05 | 2001-02-20 | Nippon Steel Corporation | Surface treated metal material and surface treating agent |
| US5866652A (en) | 1996-02-27 | 1999-02-02 | The Boeing Company | Chromate-free protective coatings |
| DE10026850A1 (de) * | 2000-05-31 | 2001-12-06 | Chemetall Gmbh | Verfahren zum Behandeln bzw. Vorbehandeln von Bauteilen mit Aluminium-Oberflächen |
| DE10149148B4 (de) | 2000-10-11 | 2006-06-14 | Chemetall Gmbh | Verfahren zur Beschichtung von metallischen Oberflächen mit einer wässerigen, Polymere enthaltenden Zusammensetzung, die wässerige Zusammensetzung und Verwendung der beschichteten Substrate |
| US6613390B2 (en) | 2000-12-19 | 2003-09-02 | United Technologies Corporation | Compound, non-chromium conversion coatings for aluminum alloys |
| US7294211B2 (en) | 2002-01-04 | 2007-11-13 | University Of Dayton | Non-toxic corrosion-protection conversion coats based on cobalt |
| US7048807B2 (en) | 2002-08-08 | 2006-05-23 | The Curators Of The University Of Missouri | Cerium-based spontaneous coating process for corrosion protection of aluminum alloys |
| ES2211348B1 (es) | 2002-12-27 | 2005-10-01 | Universidad De Cadiz | Procedimiento para la obtencion de capas de conversion libres de cromatos sobre aleaciones de aluminio. |
| JP2006328445A (ja) * | 2005-05-23 | 2006-12-07 | Nippon Parkerizing Co Ltd | プレコート金属材料用水系表面処理剤、表面処理方法及びプレコート金属材料の製造方法 |
| JP2007262577A (ja) * | 2006-03-01 | 2007-10-11 | Nippon Paint Co Ltd | 金属表面処理用組成物、金属表面処理方法、及び金属材料 |
| US7906002B2 (en) * | 2006-08-04 | 2011-03-15 | Kansai Paint Co., Ltd. | Method for forming surface-treating film |
| US9476125B2 (en) | 2006-08-08 | 2016-10-25 | The Boeing Company | Chromium-free conversion coating |
| ES2463446T3 (es) * | 2006-08-08 | 2014-05-28 | The Boeing Company | Recubrimiento de conversión sin cromo |
| DE102010030115A1 (de) | 2009-08-11 | 2011-02-17 | Evonik Degussa Gmbh | Glycidyloxyalkylalkoxysilan-basierte wässrige Silansysteme für den Blankkorrosionsschutz und Korrosionsschutz von Metallen |
| JP5669293B2 (ja) * | 2009-09-24 | 2015-02-12 | 関西ペイント株式会社 | 金属表面処理用組成物及び金属表面処理方法 |
| JP5554531B2 (ja) * | 2009-09-24 | 2014-07-23 | 関西ペイント株式会社 | 金属材料の塗装方法 |
| ES2359550B1 (es) | 2009-11-11 | 2012-04-04 | Consejo Superior De Investigaciones Cient�?Ficas (Csic) | Recubrimientos v�?treos realizados por sol-gel para la protección de metales frente a la corrosión. |
| FR2981366B1 (fr) | 2011-10-14 | 2014-10-17 | Univ Toulouse 3 Paul Sabatier | Procede de traitement anticorrosion d'un substrat metallique solide et substrat metallique solide traite susceptible d'etre obtenu par un tel procede |
| CA2819340C (en) * | 2012-08-31 | 2019-04-30 | The Boeing Company | Chromium-free conversion coating |
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| EP2915903A1 (en) | 2015-09-09 |
| US9290846B2 (en) | 2016-03-22 |
| JP2016194134A (ja) | 2016-11-17 |
| BR102015014235A2 (pt) | 2016-12-20 |
| CA2895054A1 (en) | 2016-08-23 |
| US20150252480A1 (en) | 2015-09-10 |
| EP2915903B1 (en) | 2018-02-21 |
| CA2895054C (en) | 2016-11-22 |
| JP6440581B2 (ja) | 2018-12-19 |
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