BR0010289A - Copolìmeros de etileno, processo para preparar os mesmos, e filmes destes - Google Patents

Copolìmeros de etileno, processo para preparar os mesmos, e filmes destes

Info

Publication number
BR0010289A
BR0010289A BR0010289-0A BR0010289A BR0010289A BR 0010289 A BR0010289 A BR 0010289A BR 0010289 A BR0010289 A BR 0010289A BR 0010289 A BR0010289 A BR 0010289A
Authority
BR
Brazil
Prior art keywords
copolymers
ethylene
films
lmw
hmw
Prior art date
Application number
BR0010289-0A
Other languages
English (en)
Other versions
BR0010289B1 (pt
Inventor
Choon Kooi Chai
Christopher James Frye
Original Assignee
Bp Chem Int Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=26315511&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=BR0010289(A) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Priority claimed from GBGB9910370.7A external-priority patent/GB9910370D0/en
Priority claimed from GBGB9927205.6A external-priority patent/GB9927205D0/en
Application filed by Bp Chem Int Ltd filed Critical Bp Chem Int Ltd
Publication of BR0010289A publication Critical patent/BR0010289A/pt
Publication of BR0010289B1 publication Critical patent/BR0010289B1/pt

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18Manufacture of films or sheets
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/34Polymerisation in gaseous state
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65925Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/08Copolymers of ethene
    • C08L23/0807Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
    • C08L23/0815Copolymers of ethene with aliphatic 1-olefins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/02Anti-static agent incorporated into the catalyst
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/04Homopolymers or copolymers of ethene
    • C08J2323/08Copolymers of ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/08Copolymers of ethene
    • C08L23/0846Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
    • C08L23/0853Vinylacetate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2314/00Polymer mixtures characterised by way of preparation
    • C08L2314/06Metallocene or single site catalysts
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Polymerisation Methods In General (AREA)

Abstract

"COPOLìMEROS DE ETILENO, PROCESSO PARA PREPARAR OS MESMOS, E FILMES DESTES". Os novos copolímeros compreendem etileno e alfaolefinas possuindo de 3 a 10 átomos de carbono e que possuem ( a ) uma densidade na faixa de 0,900 a 0,940; ( b ) Mw/Mn aparente de 2,0 a 3,4; ( c ) uma I~ 21~/I~ 2~ de 16 a 24; ( d ) uma energia de ativação de fluxo de 28 a 45 KJ/mol; ( e ) uma proporção Ea ( HMW )/Ea ( LMW ) > 1,1; e ( f ) uma proporção g'( HMW ) / g'( LMW ) de 0,85 a 0,95 . Os copolímeros são particularmente úteis em aplicações de filme mostrando um excelente equilíbrio de propriedades de processamento, ópticas e mecânicas. Os novos polímeros podem ser preparados adequadamente na fase gasosa na presença de complexos de metaloceno.
BRPI0010289-0A 1999-05-05 2000-04-26 copolìmeros de etileno, processo para preparar os mesmos, e filmes destes. BR0010289B1 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GBGB9910370.7A GB9910370D0 (en) 1999-05-05 1999-05-05 Novel copolymers and films thereof
GBGB9927205.6A GB9927205D0 (en) 1999-11-17 1999-11-17 Novel copolymers and films thereof
PCT/GB2000/001611 WO2000068285A1 (en) 1999-05-05 2000-04-26 Ethylene copolymers and films thereof

Publications (2)

Publication Number Publication Date
BR0010289A true BR0010289A (pt) 2002-05-21
BR0010289B1 BR0010289B1 (pt) 2011-01-25

Family

ID=26315511

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0010289-0A BR0010289B1 (pt) 1999-05-05 2000-04-26 copolìmeros de etileno, processo para preparar os mesmos, e filmes destes.

Country Status (22)

Country Link
US (2) US6642339B1 (pt)
EP (1) EP1177225B1 (pt)
JP (1) JP5314823B2 (pt)
KR (1) KR100666890B1 (pt)
CN (1) CN1174010C (pt)
AR (1) AR023881A1 (pt)
AT (1) ATE420902T1 (pt)
BR (1) BR0010289B1 (pt)
CA (1) CA2372537C (pt)
CO (1) CO5160388A1 (pt)
CZ (1) CZ20013865A3 (pt)
DE (1) DE60041397D1 (pt)
EA (1) EA005112B1 (pt)
EG (1) EG22873A (pt)
ES (1) ES2317834T3 (pt)
MX (1) MXPA01011239A (pt)
MY (1) MY121886A (pt)
NO (1) NO20015384L (pt)
PT (1) PT1177225E (pt)
SK (1) SK15792001A3 (pt)
TW (1) TWI291470B (pt)
WO (1) WO2000068285A1 (pt)

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US20060210804A1 (en) * 2004-10-28 2006-09-21 Sumitomo Chemical Company, Limited Resin composition, foamed molding and laminate
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JP5019780B2 (ja) * 2005-04-22 2012-09-05 旭化成ケミカルズ株式会社 容器包装用エチレン系樹脂
US9175105B2 (en) 2005-05-10 2015-11-03 Ineos Sales (Uk) Limited Copolymers
GB0610668D0 (en) * 2006-05-30 2006-07-12 Nova Chem Int Sa Supported antistatic polymerization catalysts
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TW200932762A (en) * 2007-10-22 2009-08-01 Univation Tech Llc Polyethylene compositions having improved properties
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GB0802550D0 (en) * 2008-02-12 2008-03-19 Ineos Mfg Belguim Nv Polymers and articles thereof
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EP2344551B1 (en) 2008-09-25 2014-05-28 Basell Polyolefine GmbH Impact resistant lldpe composition and films made thereof
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EP2177548A1 (en) 2008-10-14 2010-04-21 Ineos Europe Limited Copolymers and films thereof
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US8822601B2 (en) * 2010-12-17 2014-09-02 Dow Global Technologies Llc Ethylene-based polymers and processes to make the same
US20150118469A1 (en) 2011-12-01 2015-04-30 Ineos Europe Ag Polymer blends
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EP2610269A1 (en) * 2011-12-28 2013-07-03 Saudi Basic Industries Corporation Catalyst composition and method for preparing the same
KR102483085B1 (ko) * 2014-05-30 2022-12-30 닛산 가가쿠 가부시키가이샤 박막의 평탄화 방법, 평탄화 박막의 형성 방법 및 박막 형성용 바니시
KR101689456B1 (ko) * 2015-01-23 2016-12-23 한화토탈 주식회사 에틸렌계 공중합체 및 이의 제조
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US10442921B2 (en) 2017-04-19 2019-10-15 Nova Chemicals (International) S.A. Means for increasing the molecular weight and decreasing the density employing mixed homogeneous catalyst formulations
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Also Published As

Publication number Publication date
DE60041397D1 (de) 2009-03-05
CO5160388A1 (es) 2002-05-30
US20040044155A1 (en) 2004-03-04
SK15792001A3 (sk) 2002-10-08
EA005112B1 (ru) 2004-10-28
US6919414B2 (en) 2005-07-19
MXPA01011239A (es) 2002-08-12
ATE420902T1 (de) 2009-01-15
AR023881A1 (es) 2002-09-04
EG22873A (en) 2003-10-30
CN1174010C (zh) 2004-11-03
CZ20013865A3 (cs) 2002-10-16
BR0010289B1 (pt) 2011-01-25
WO2000068285A1 (en) 2000-11-16
EA200101153A1 (ru) 2002-06-27
KR100666890B1 (ko) 2007-01-10
CA2372537C (en) 2010-09-28
TWI291470B (en) 2007-12-21
NO20015384L (no) 2001-12-06
ES2317834T3 (es) 2009-05-01
JP5314823B2 (ja) 2013-10-16
EP1177225B1 (en) 2009-01-14
JP2002544300A (ja) 2002-12-24
US6642339B1 (en) 2003-11-04
NO20015384D0 (no) 2001-11-02
PT1177225E (pt) 2009-02-11
KR20020038579A (ko) 2002-05-23
MY121886A (en) 2006-03-31
EP1177225A1 (en) 2002-02-06
CA2372537A1 (en) 2000-11-16
CN1360601A (zh) 2002-07-24

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