BR0007716A - Preparação de catalisador de fósforo/vanádiopara anidrido maléico - Google Patents

Preparação de catalisador de fósforo/vanádiopara anidrido maléico

Info

Publication number
BR0007716A
BR0007716A BR0007716-0A BR0007716A BR0007716A BR 0007716 A BR0007716 A BR 0007716A BR 0007716 A BR0007716 A BR 0007716A BR 0007716 A BR0007716 A BR 0007716A
Authority
BR
Brazil
Prior art keywords
temperature
precursor
catalyst
elements
preparation
Prior art date
Application number
BR0007716-0A
Other languages
English (en)
Other versions
BR0007716B1 (pt
Inventor
Arie Bortinger
Original Assignee
Scient Design Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Scient Design Co filed Critical Scient Design Co
Publication of BR0007716A publication Critical patent/BR0007716A/pt
Publication of BR0007716B1 publication Critical patent/BR0007716B1/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/215—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of saturated hydrocarbyl groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
    • B01J27/19—Molybdenum
    • B01J27/192—Molybdenum with bismuth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/195—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with vanadium, niobium or tantalum
    • B01J27/198—Vanadium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0018—Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/10—Heat treatment in the presence of water, e.g. steam
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/12—Oxidising
    • B01J37/14—Oxidising with gases containing free oxygen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Furan Compounds (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Patente de Invenção: "PREPARAçãO DE CATALISADOR DEFóSFORO/VANáDIO PARA ANIDRIDO MALéICO". Um precursorde catalisador de VPO tendo a fórmula (VO)HPO~ 4~aH~ 2~OM~m~P~ p~O~ y~, em que M é pelo menos um elemento promotorselecionado do grupo consistindo em elementos dos Grupos IA, IB,IIA, IIIA, IIIB, IVA, IVB, VA, VB, VIA, VIB, e VIIIA da TabelaPeriódica dos Elementos, e suas misturas, a é um número de pelomenos cerca de 0,3, m é um número de cerca de O a cerca de0,3, p é um número de cerca de O a cerca de 0,3, qualquer ycorresponde à quantidade de oxigênio necessária para satisfazeras exigências de valência de todos os elementos presentes, éativado aquecendo-se o precursor de catalisador em umaatmosfera selecionada do grupo consistindo em ar, vapor, gásinerte, e misturas dos mesmos, até uma temperatura para nãoexceder cerca de 300<198>C, mantendo-se o precursor decatalisador nesta temperatura e proporcionando-se uma atmosferacontendo oxigênio molecular, vapor, e opcionalmente um gásinerte, aumentando-se a temperatura em uma taxa programada decerca de 0,5<198>C/min a cerca de 15<198>C/min, até um valorefetivo para eliminar a água de hidratação do precursor decatalisador, ajustando-se a temperatura até um valor maior do que350<198>C, porém menor do que 550<198>C, e mantendo-se atemperatura ajustada em uma atmosfera contendo oxigêniomolecular/vapor compreendida de pelo menos 1% em vol deoxigênio, por um tempo efetivo para proporcionar um estado deoxidação do vanádio de cerca de +4,0 a cerca de +4,5 e paracompletar a transformação do precursor no catalisador ativo tendoa fórmula (VO)~ 2~P~ 2~O~ 7~M~ 2~P~ 2p~O~ y~, em que M,m, p e y são como definidos acima.
BRPI0007716-0A 1999-01-29 2000-01-13 processo para ativar precursor de catalisador de fosfóro/vanádio para anidrido maléico. BR0007716B1 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US09/239,651 1999-01-29
US09/239,651 US6107234A (en) 1999-01-29 1999-01-29 Phosphorus/vanadium maleic anhydride catalyst preparation
PCT/US2000/000920 WO2000044494A1 (en) 1999-01-29 2000-01-13 Phosphorus/vanadium maleic anhydride catalyst preparation

Publications (2)

Publication Number Publication Date
BR0007716A true BR0007716A (pt) 2001-11-27
BR0007716B1 BR0007716B1 (pt) 2011-08-09

Family

ID=22903120

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0007716-0A BR0007716B1 (pt) 1999-01-29 2000-01-13 processo para ativar precursor de catalisador de fosfóro/vanádio para anidrido maléico.

Country Status (13)

Country Link
US (1) US6107234A (pt)
EP (1) EP1152826A4 (pt)
JP (1) JP4969727B2 (pt)
KR (1) KR100647511B1 (pt)
CN (1) CN1118326C (pt)
AU (1) AU2726900A (pt)
BR (1) BR0007716B1 (pt)
CA (1) CA2358876C (pt)
ID (1) ID29987A (pt)
MX (1) MX228048B (pt)
SA (1) SA00201051B1 (pt)
TW (1) TW499324B (pt)
WO (1) WO2000044494A1 (pt)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6281378B1 (en) * 1995-06-08 2001-08-28 Nippon Shokubai Co., Ltd. Vanadium-containing catalysts, process for manufacturing and use of the same
KR20020080379A (ko) * 2000-01-20 2002-10-23 이 아이 듀폰 디 네모아 앤드 캄파니 촉진제 시약을 포함하는 바나듐―인 산화물 촉매
US6858561B2 (en) * 2003-05-15 2005-02-22 Scientific Design Company, Inc. Phosphorus/vanadium catalyst preparation
US8143461B2 (en) 2006-09-05 2012-03-27 Huntsman Petrochemical Llc Maleic anhydride catalyst and method for its preparation
CN101157048B (zh) * 2007-11-20 2010-04-07 吐哈石油勘探开发指挥部石油天然气化工厂 一种具有纳米结构的高性能钒磷氧催化剂的制备方法
DE102014004786B4 (de) 2014-04-02 2021-09-30 Clariant International Ltd. Alkalimetall-modifizierter Vanadium-Phosphor-Oxid (VPO)-Katalysator
CN106540728B (zh) * 2016-10-13 2018-11-06 西安元创化工科技股份有限公司 一种由正丁烷氧化制备顺酐时所使用vpo催化剂的活化方法
CN109046412B (zh) * 2018-08-23 2021-05-25 常州新日催化剂股份有限公司 一种正丁烷氧化制顺酐催化剂及其制备方法
CN111054409B (zh) * 2018-10-16 2022-12-13 中国石油化工股份有限公司 一种正丁烷氧化制顺酐催化剂的活化方法
CN112705243B (zh) * 2019-10-24 2023-07-04 中国石油化工股份有限公司 一种含钒氧化物催化剂的活化方法

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US3980585A (en) * 1974-05-28 1976-09-14 Petro-Tex Chemical Corporation Catalyst and process for preparing maleic anhydride from C4 hydrocarbons
US4043943A (en) * 1974-11-06 1977-08-23 Chevron Research Company Process for producing a mixed oxide of vanadium and phosphorus having an improved intrinsic surface area
US4056487A (en) * 1975-10-02 1977-11-01 Petro-Tex Chemical Corporation Vanadium phosphorus oxygen oxidation catalysts useful for preparing anhydrides from alkanes
GB1591307A (en) * 1976-11-11 1981-06-17 Ici Ltd Production of maleic anhydride and catalysts therefor
EP0003431B1 (en) * 1978-01-30 1984-04-11 Imperial Chemical Industries Plc Production of carboxylic acid anhydrides and catalysts therefor
US4283307A (en) * 1980-06-02 1981-08-11 Denka Chemical Corporation Catalyst structure for the partial oxidation of n-butane to produce maleic anhydride
US4418003A (en) * 1982-05-26 1983-11-29 Standard Oil Company (Indiana) Catalysts for the production of maleic anhydride
US4569925A (en) * 1982-07-01 1986-02-11 Exxon Research & Engineering Co. Process for preparing a vanadium phosphorus oxygen catalyst composition by an organic solution method
US4515904A (en) * 1983-09-30 1985-05-07 Standard Oil Company (Indiana) Catalysts for the production of maleic anhydride by the oxidation of butane
US4560674A (en) * 1983-12-28 1985-12-24 Monsanto Company Catalysts for the production of maleic anhydride
JPH01201016A (ja) * 1987-10-12 1989-08-14 Mitsubishi Kasei Corp バナジウム−リン系結晶性酸化物又はそれを含有する触媒の製造法
US5137860A (en) * 1991-06-27 1992-08-11 Monsanto Company Process for the transformation of vanadium/phosphorus mixed oxide catalyst precursors into active catalysts for the production of maleic anhydride
US5288880A (en) * 1992-03-17 1994-02-22 Maruzen Petrochemical Co., Ltd. Process for the manufacture of maleic anhydride
US5280003A (en) * 1992-08-24 1994-01-18 Scientific Design Company, Inc. Static condition process for the preparation of phosphorous/vanadium oxidation catalyst
US5296436A (en) * 1993-01-08 1994-03-22 Scientific Design Company, Inc. Phosphorous/vanadium oxidation catalyst
EP0608837B1 (en) * 1993-01-29 1998-07-08 Mitsubishi Chemical Corporation Process for producing a vanadium-phosphorus oxide catalyst precursor
US5480853A (en) * 1994-07-15 1996-01-02 Scientific Design Company, Inc. Phosphorus/vanadium catalyst preparation
US5510308A (en) * 1994-10-19 1996-04-23 E. I. Du Pont De Nemours And Company Cation and vanadium substituted heteropolyacid catalysts for vapor phase oxidation
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Also Published As

Publication number Publication date
JP2002535136A (ja) 2002-10-22
MX228048B (es) 2005-05-26
KR100647511B1 (ko) 2006-11-23
SA00201051B1 (ar) 2006-10-11
EP1152826A1 (en) 2001-11-14
MXPA01007652A (es) 2002-02-01
AU2726900A (en) 2000-08-18
KR20010101742A (ko) 2001-11-14
EP1152826A4 (en) 2002-10-02
CA2358876C (en) 2008-07-22
US6107234A (en) 2000-08-22
WO2000044494A1 (en) 2000-08-03
CA2358876A1 (en) 2000-08-03
CN1118326C (zh) 2003-08-20
JP4969727B2 (ja) 2012-07-04
CN1337889A (zh) 2002-02-27
TW499324B (en) 2002-08-21
BR0007716B1 (pt) 2011-08-09
ID29987A (id) 2001-10-25

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Legal Events

Date Code Title Description
B07A Application suspended after technical examination (opinion) [chapter 7.1 patent gazette]
B06A Patent application procedure suspended [chapter 6.1 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

Free format text: PRAZO DE VALIDADE: 10 (DEZ) ANOS CONTADOS A PARTIR DE 09/08/2011, OBSERVADAS AS CONDICOES LEGAIS.

B21A Patent or certificate of addition expired [chapter 21.1 patent gazette]

Free format text: PATENTE EXTINTA EM 09.08.2021