BR0007018A - Pó de metal refretário de baixo oxigênio para metalurgia do pó - Google Patents
Pó de metal refretário de baixo oxigênio para metalurgia do póInfo
- Publication number
- BR0007018A BR0007018A BR0007018-1A BR0007018A BR0007018A BR 0007018 A BR0007018 A BR 0007018A BR 0007018 A BR0007018 A BR 0007018A BR 0007018 A BR0007018 A BR 0007018A
- Authority
- BR
- Brazil
- Prior art keywords
- powder
- refractory metal
- low oxygen
- metal
- target level
- Prior art date
Links
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 title abstract 6
- 229910052760 oxygen Inorganic materials 0.000 title abstract 6
- 239000001301 oxygen Substances 0.000 title abstract 6
- 239000000843 powder Substances 0.000 title abstract 4
- 238000004663 powder metallurgy Methods 0.000 title abstract 2
- 239000003870 refractory metal Substances 0.000 title 1
- 239000002184 metal Substances 0.000 abstract 3
- 239000000047 product Substances 0.000 abstract 2
- 239000006227 byproduct Substances 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 150000004678 hydrides Chemical class 0.000 abstract 1
- 229910052987 metal hydride Inorganic materials 0.000 abstract 1
- 150000004681 metal hydrides Chemical class 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
- H01G9/004—Details
- H01G9/04—Electrodes or formation of dielectric layers thereon
- H01G9/042—Electrodes or formation of dielectric layers thereon characterised by the material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F9/00—Making metallic powder or suspensions thereof
- B22F9/16—Making metallic powder or suspensions thereof using chemical processes
- B22F9/30—Making metallic powder or suspensions thereof using chemical processes with decomposition of metal compounds, e.g. by pyrolysis
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F1/00—Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
- B22F1/14—Treatment of metallic powder
- B22F1/145—Chemical treatment, e.g. passivation or decarburisation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
- B22F3/12—Both compacting and sintering
- B22F3/16—Both compacting and sintering in successive or repeated steps
- B22F3/162—Machining, working after consolidation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F9/00—Making metallic powder or suspensions thereof
- B22F9/02—Making metallic powder or suspensions thereof using physical processes
- B22F9/023—Hydrogen absorption
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B34/00—Obtaining refractory metals
- C22B34/20—Obtaining niobium, tantalum or vanadium
- C22B34/24—Obtaining niobium or tantalum
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B9/00—General processes of refining or remelting of metals; Apparatus for electroslag or arc remelting of metals
- C22B9/14—Refining in the solid state
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/04—Making non-ferrous alloys by powder metallurgy
- C22C1/045—Alloys based on refractory metals
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C32/00—Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ
- C22C32/001—Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ with only oxides
- C22C32/0015—Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ with only oxides with only single oxides as main non-metallic constituents
- C22C32/0031—Matrix based on refractory metals, W, Mo, Nb, Hf, Ta, Zr, Ti, V or alloys thereof
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
- H01G9/004—Details
- H01G9/04—Electrodes or formation of dielectric layers thereon
- H01G9/048—Electrodes or formation of dielectric layers thereon characterised by their structure
- H01G9/052—Sintered electrodes
- H01G9/0525—Powder therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
- B22F3/20—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces by extruding
- B22F2003/208—Warm or hot extruding
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F2998/00—Supplementary information concerning processes or compositions relating to powder metallurgy
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F2998/00—Supplementary information concerning processes or compositions relating to powder metallurgy
- B22F2998/10—Processes characterised by the sequence of their steps
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F2999/00—Aspects linked to processes or compositions used in powder metallurgy
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Organic Chemistry (AREA)
- Metallurgy (AREA)
- Power Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Powder Metallurgy (AREA)
- Manufacture Of Metal Powder And Suspensions Thereof (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
- Inorganic Insulating Materials (AREA)
Abstract
Patente de Invenção: <B>"Pó DE METAL REFRATáRIO DE BAIXO OXIGêNIO PARA METALURGIA DO Pó"<D>. A presente invenção refere-se a processos para a produção de produtos de metalurgia de pós de Ta/Nb formados usando-se pós de hidreto de Ta e/ou Nb com um teor de oxigênio maior que de um nível alvo, por exemplo, 300ppm, aquecendo-se o hidreto de metal na presença de um outro metal tendo uma afinidade maior pelo oxigênio, removendo-se o outro metal e quaisquer subprodutos da reação para se formar um pó de metal com um teor de oxigênio menor que do nível alvo e formando-se um produto metalúrgico a partie do pó de Ta/Nb reduzido por oxigênio mencionado com um teor de oxigênio menor que o nível alvo.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US09/377,077 US6261337B1 (en) | 1999-08-19 | 1999-08-19 | Low oxygen refractory metal powder for powder metallurgy |
PCT/US2000/022902 WO2001012364A1 (en) | 1999-08-19 | 2000-08-18 | Low oxygen refractory metal powder for powder metallurgy |
Publications (1)
Publication Number | Publication Date |
---|---|
BR0007018A true BR0007018A (pt) | 2001-07-03 |
Family
ID=23487672
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR0007018-1A BR0007018A (pt) | 1999-08-19 | 2000-08-18 | Pó de metal refretário de baixo oxigênio para metalurgia do pó |
Country Status (18)
Country | Link |
---|---|
US (1) | US6261337B1 (pt) |
EP (3) | EP1541261B1 (pt) |
KR (2) | KR100436108B1 (pt) |
CN (1) | CN1272125C (pt) |
AT (2) | ATE300377T1 (pt) |
AU (1) | AU766574B2 (pt) |
BR (1) | BR0007018A (pt) |
CA (1) | CA2346957A1 (pt) |
CY (1) | CY1108564T1 (pt) |
CZ (1) | CZ20011740A3 (pt) |
DE (2) | DE60021579T2 (pt) |
DK (1) | DK1541261T3 (pt) |
EA (1) | EA002736B1 (pt) |
ES (1) | ES2313136T3 (pt) |
HK (1) | HK1040501B (pt) |
IL (1) | IL142601A (pt) |
PT (2) | PT1541261E (pt) |
WO (1) | WO2001012364A1 (pt) |
Families Citing this family (39)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6521173B2 (en) * | 1999-08-19 | 2003-02-18 | H.C. Starck, Inc. | Low oxygen refractory metal powder for powder metallurgy |
IL132291A0 (en) * | 1999-10-08 | 2001-03-19 | Advanced Alloys Technologies L | A method for production of tantalum powder with highly developed surface |
US6358625B1 (en) * | 1999-10-11 | 2002-03-19 | H. C. Starck, Inc. | Refractory metals with improved adhesion strength |
CA2401779A1 (en) | 2000-03-01 | 2001-09-07 | Cabot Corporation | Nitrided valve metals and processes for making the same |
US6824586B2 (en) * | 2000-11-30 | 2004-11-30 | Showa Denko K.K. | Powder for capacitor, sintered body thereof and capacitor using the sintered body |
US20030002043A1 (en) * | 2001-04-10 | 2003-01-02 | Kla-Tencor Corporation | Periodic patterns and technique to control misalignment |
KR100524166B1 (ko) | 2001-05-15 | 2005-10-25 | 쇼와 덴코 가부시키가이샤 | 일산화 니오브분말, 일산화 니오브 소결체 및 일산화니오브 소결체를 사용한 콘덴서 |
AU2008200187B2 (en) * | 2001-05-15 | 2010-02-18 | Showa Denko K.K. | Niobium powder, niobium sintered body and capacitor using the sintered body |
US6780218B2 (en) * | 2001-06-20 | 2004-08-24 | Showa Denko Kabushiki Kaisha | Production process for niobium powder |
US6770154B2 (en) | 2001-09-18 | 2004-08-03 | Praxair S.T. Technology, Inc. | Textured-grain-powder metallurgy tantalum sputter target |
US7081148B2 (en) * | 2001-09-18 | 2006-07-25 | Praxair S.T. Technology, Inc. | Textured-grain-powder metallurgy tantalum sputter target |
EP1506322A2 (en) * | 2002-01-23 | 2005-02-16 | H.C. Starck Inc. | Stabilized grain size refractory metal powder metallurgy mill products |
PL370639A1 (en) * | 2002-01-24 | 2005-05-30 | H.C.Starck Inc. | Capacitor-grade lead wires with increased tensile strength and hardness |
TWI341337B (en) * | 2003-01-07 | 2011-05-01 | Cabot Corp | Powder metallurgy sputtering targets and methods of producing same |
US20060162822A1 (en) * | 2003-01-21 | 2006-07-27 | Richard Malen | Capacitor-grade lead wires with increased tensile strength and hardness |
DE10304756B4 (de) * | 2003-02-05 | 2005-04-07 | W.C. Heraeus Gmbh | Sauerstoffangereicherter Niob-Draht |
ES2279992T3 (es) * | 2003-03-28 | 2007-09-01 | Mitsubishi Materials Corporation | Metodo para fabricar una punta desechable y aparato para alinear comprimido crudo. |
US7135141B2 (en) * | 2003-03-31 | 2006-11-14 | Hitachi Metals, Ltd. | Method of manufacturing a sintered body |
US20050279630A1 (en) * | 2004-06-16 | 2005-12-22 | Dynamic Machine Works, Inc. | Tubular sputtering targets and methods of flowforming the same |
EP1880035B1 (en) | 2005-05-05 | 2021-01-20 | Höganäs Germany GmbH | Method for coating a substrate surface and coated product |
CN101368262B (zh) * | 2005-05-05 | 2012-06-06 | H.C.施塔克有限公司 | 向表面施加涂层的方法 |
US20080078268A1 (en) * | 2006-10-03 | 2008-04-03 | H.C. Starck Inc. | Process for preparing metal powders having low oxygen content, powders so-produced and uses thereof |
PL2104753T3 (pl) * | 2006-11-07 | 2014-12-31 | Starck H C Gmbh | Sposób powlekania podłoża i powleczony produkt |
US20080145688A1 (en) | 2006-12-13 | 2008-06-19 | H.C. Starck Inc. | Method of joining tantalum clade steel structures |
US8197894B2 (en) | 2007-05-04 | 2012-06-12 | H.C. Starck Gmbh | Methods of forming sputtering targets |
JP2011500962A (ja) * | 2007-10-15 | 2011-01-06 | ハイ−テンプ・スペシャルティー・メタルス・インコーポレーテッド | 再生スクラップを原材料として使用したタンタル粉末の生産方法 |
US8246903B2 (en) | 2008-09-09 | 2012-08-21 | H.C. Starck Inc. | Dynamic dehydriding of refractory metal powders |
US8043655B2 (en) * | 2008-10-06 | 2011-10-25 | H.C. Starck, Inc. | Low-energy method of manufacturing bulk metallic structures with submicron grain sizes |
CN102189261A (zh) * | 2011-05-30 | 2011-09-21 | 华中科技大学 | 一种多孔制件的致密化方法 |
US9120183B2 (en) | 2011-09-29 | 2015-09-01 | H.C. Starck Inc. | Methods of manufacturing large-area sputtering targets |
CN102672181A (zh) * | 2012-06-07 | 2012-09-19 | 太仓市锦立得粉末冶金有限公司 | 一种粉末冶金制品的生产工艺 |
WO2015127613A1 (zh) | 2014-02-27 | 2015-09-03 | 宁夏东方钽业股份有限公司 | 一种高纯钽粉及其制备方法 |
CN103920880A (zh) * | 2014-03-11 | 2014-07-16 | 宁夏东方钽业股份有限公司 | 钽及钽合金棒材的制备方法 |
JP6573629B2 (ja) | 2014-04-11 | 2019-09-11 | ハー ツェー シュタルク インコーポレイテッドH.C. Starck, Inc. | 高純度耐熱金属粉体、及び無秩序な組織を有し得るスパッタリングターゲットにおけるその使用 |
KR101488703B1 (ko) * | 2014-10-29 | 2015-02-04 | 국방과학연구소 | 탄탈륨 분말 소결체 라이너 및 그 제조방법 |
WO2017132322A2 (en) | 2016-01-27 | 2017-08-03 | H.C. Starck Place | Fabrication of high-entropy alloy wire and multi-principal element alloy wire for additive manufacturing |
US10099267B2 (en) | 2016-03-03 | 2018-10-16 | H.C. Starck Inc. | High-density, crack-free metallic parts |
CN111940745B (zh) * | 2019-12-30 | 2024-01-19 | 宁夏东方钽业股份有限公司 | 大松装冶金级钽粉的制造方法 |
CN111560531B (zh) * | 2020-04-15 | 2021-07-09 | 河南中钻新材料有限公司 | 一种低氧化物夹杂高性能粉末冶金镍基高温合金的制备方法 |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4722756A (en) * | 1987-02-27 | 1988-02-02 | Cabot Corp | Method for deoxidizing tantalum material |
US5242481A (en) * | 1989-06-26 | 1993-09-07 | Cabot Corporation | Method of making powders and products of tantalum and niobium |
US5082491A (en) * | 1989-09-28 | 1992-01-21 | V Tech Corporation | Tantalum powder with improved capacitor anode processing characteristics |
DE69128692T2 (de) * | 1990-11-09 | 1998-06-18 | Toyoda Chuo Kenkyusho Kk | Titanlegierung aus Sinterpulver und Verfahren zu deren Herstellung |
US5954856A (en) * | 1996-04-25 | 1999-09-21 | Cabot Corporation | Method of making tantalum metal powder with controlled size distribution and products made therefrom |
-
1999
- 1999-08-19 US US09/377,077 patent/US6261337B1/en not_active Expired - Lifetime
-
2000
- 2000-08-18 CN CNB008019940A patent/CN1272125C/zh not_active Expired - Fee Related
- 2000-08-18 EP EP05005428A patent/EP1541261B1/en not_active Expired - Lifetime
- 2000-08-18 EP EP00959289A patent/EP1200218B1/en not_active Expired - Lifetime
- 2000-08-18 KR KR10-2003-7014108A patent/KR100436108B1/ko active IP Right Grant
- 2000-08-18 DE DE60021579T patent/DE60021579T2/de not_active Expired - Lifetime
- 2000-08-18 WO PCT/US2000/022902 patent/WO2001012364A1/en active IP Right Grant
- 2000-08-18 DK DK05005428T patent/DK1541261T3/da active
- 2000-08-18 EP EP08161538.7A patent/EP1995005B1/en not_active Expired - Lifetime
- 2000-08-18 PT PT05005428T patent/PT1541261E/pt unknown
- 2000-08-18 AT AT00959289T patent/ATE300377T1/de active
- 2000-08-18 DE DE60039923T patent/DE60039923D1/de not_active Expired - Lifetime
- 2000-08-18 AT AT05005428T patent/ATE404308T1/de active
- 2000-08-18 BR BR0007018-1A patent/BR0007018A/pt not_active Application Discontinuation
- 2000-08-18 AU AU70636/00A patent/AU766574B2/en not_active Ceased
- 2000-08-18 EA EA200100441A patent/EA002736B1/ru not_active IP Right Cessation
- 2000-08-18 PT PT00959289T patent/PT1200218E/pt unknown
- 2000-08-18 CZ CZ20011740A patent/CZ20011740A3/cs unknown
- 2000-08-18 KR KR10-2001-7004864A patent/KR100431095B1/ko not_active IP Right Cessation
- 2000-08-18 ES ES05005428T patent/ES2313136T3/es not_active Expired - Lifetime
- 2000-08-18 CA CA002346957A patent/CA2346957A1/en not_active Abandoned
-
2001
- 2001-04-15 IL IL142601A patent/IL142601A/en not_active IP Right Cessation
-
2002
- 2002-03-14 HK HK02101960.2A patent/HK1040501B/zh not_active IP Right Cessation
-
2008
- 2008-11-13 CY CY20081101302T patent/CY1108564T1/el unknown
Also Published As
Publication number | Publication date |
---|---|
CZ20011740A3 (cs) | 2002-02-13 |
IL142601A (en) | 2006-10-05 |
HK1040501B (zh) | 2007-04-20 |
EA002736B1 (ru) | 2002-08-29 |
CA2346957A1 (en) | 2001-02-22 |
EP1541261B1 (en) | 2008-08-13 |
CN1272125C (zh) | 2006-08-30 |
EP1541261A1 (en) | 2005-06-15 |
ES2313136T3 (es) | 2009-03-01 |
KR100431095B1 (ko) | 2004-05-12 |
AU7063600A (en) | 2001-03-13 |
EP1200218A1 (en) | 2002-05-02 |
EA200100441A1 (ru) | 2001-10-22 |
DE60021579D1 (de) | 2005-09-01 |
US6261337B1 (en) | 2001-07-17 |
ATE300377T1 (de) | 2005-08-15 |
WO2001012364A1 (en) | 2001-02-22 |
EP1995005B1 (en) | 2015-02-25 |
KR100436108B1 (ko) | 2004-06-14 |
DE60039923D1 (de) | 2008-09-25 |
DE60021579T2 (de) | 2006-05-24 |
ATE404308T1 (de) | 2008-08-15 |
CY1108564T1 (el) | 2014-04-09 |
KR20030087087A (ko) | 2003-11-12 |
EP1200218A4 (en) | 2004-04-14 |
KR20010099702A (ko) | 2001-11-09 |
CN1322157A (zh) | 2001-11-14 |
EP1995005A1 (en) | 2008-11-26 |
AU766574B2 (en) | 2003-10-16 |
PT1200218E (pt) | 2005-11-30 |
PT1541261E (pt) | 2008-11-12 |
DK1541261T3 (da) | 2008-12-01 |
EP1200218B1 (en) | 2005-07-27 |
HK1040501A1 (en) | 2002-06-14 |
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