EA200100441A1 - Порошки тугоплавких металлов с малым содержанием кислорода для порошковой металлургии - Google Patents
Порошки тугоплавких металлов с малым содержанием кислорода для порошковой металлургииInfo
- Publication number
- EA200100441A1 EA200100441A1 EA200100441A EA200100441A EA200100441A1 EA 200100441 A1 EA200100441 A1 EA 200100441A1 EA 200100441 A EA200100441 A EA 200100441A EA 200100441 A EA200100441 A EA 200100441A EA 200100441 A1 EA200100441 A1 EA 200100441A1
- Authority
- EA
- Eurasian Patent Office
- Prior art keywords
- oxygen content
- powder metallurgy
- ferrous metal
- metal powders
- metal
- Prior art date
Links
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 title abstract 6
- 229910052760 oxygen Inorganic materials 0.000 title abstract 6
- 239000001301 oxygen Substances 0.000 title abstract 6
- 239000002184 metal Substances 0.000 title abstract 4
- 239000000843 powder Substances 0.000 title abstract 4
- 238000004663 powder metallurgy Methods 0.000 title abstract 2
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 title 1
- 239000000047 product Substances 0.000 abstract 2
- 239000006227 byproduct Substances 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 150000004678 hydrides Chemical class 0.000 abstract 1
- 229910052987 metal hydride Inorganic materials 0.000 abstract 1
- 150000004681 metal hydrides Chemical class 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
- H01G9/004—Details
- H01G9/04—Electrodes or formation of dielectric layers thereon
- H01G9/042—Electrodes or formation of dielectric layers thereon characterised by the material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F9/00—Making metallic powder or suspensions thereof
- B22F9/16—Making metallic powder or suspensions thereof using chemical processes
- B22F9/30—Making metallic powder or suspensions thereof using chemical processes with decomposition of metal compounds, e.g. by pyrolysis
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F1/00—Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
- B22F1/14—Treatment of metallic powder
- B22F1/145—Chemical treatment, e.g. passivation or decarburisation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
- B22F3/12—Both compacting and sintering
- B22F3/16—Both compacting and sintering in successive or repeated steps
- B22F3/162—Machining, working after consolidation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F9/00—Making metallic powder or suspensions thereof
- B22F9/02—Making metallic powder or suspensions thereof using physical processes
- B22F9/023—Hydrogen absorption
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B34/00—Obtaining refractory metals
- C22B34/20—Obtaining niobium, tantalum or vanadium
- C22B34/24—Obtaining niobium or tantalum
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B9/00—General processes of refining or remelting of metals; Apparatus for electroslag or arc remelting of metals
- C22B9/14—Refining in the solid state
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/04—Making non-ferrous alloys by powder metallurgy
- C22C1/045—Alloys based on refractory metals
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C32/00—Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ
- C22C32/001—Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ with only oxides
- C22C32/0015—Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ with only oxides with only single oxides as main non-metallic constituents
- C22C32/0031—Matrix based on refractory metals, W, Mo, Nb, Hf, Ta, Zr, Ti, V or alloys thereof
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
- H01G9/004—Details
- H01G9/04—Electrodes or formation of dielectric layers thereon
- H01G9/048—Electrodes or formation of dielectric layers thereon characterised by their structure
- H01G9/052—Sintered electrodes
- H01G9/0525—Powder therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
- B22F3/20—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces by extruding
- B22F2003/208—Warm or hot extruding
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F2998/00—Supplementary information concerning processes or compositions relating to powder metallurgy
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F2998/00—Supplementary information concerning processes or compositions relating to powder metallurgy
- B22F2998/10—Processes characterised by the sequence of their steps
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F2999/00—Aspects linked to processes or compositions used in powder metallurgy
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Power Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Powder Metallurgy (AREA)
- Manufacture Of Metal Powder And Suspensions Thereof (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
- Inorganic Insulating Materials (AREA)
Abstract
Способ получения формованных продуктов из порошков Ta/Nb в порошковой металлургии с использованием порошков гидрида Ta и/или Nb с содержанием кислорода больше порогового, то есть 300 млн. долей, состоящий из нагревания гидрида металла в присутствии другого металла, имеющего более высокое сродство к кислороду, удалении другого металла и других побочных продуктов реакции, образовании металлического порошка с содержанием кислорода менее порогового уровня и формовании металлургического продукта из этого порошка Ta/Nb с содержанием кислорода ниже порогового уровня.Международная заявка была опубликована вместе с отчетом о международном поиске.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US09/377,077 US6261337B1 (en) | 1999-08-19 | 1999-08-19 | Low oxygen refractory metal powder for powder metallurgy |
PCT/US2000/022902 WO2001012364A1 (en) | 1999-08-19 | 2000-08-18 | Low oxygen refractory metal powder for powder metallurgy |
Publications (2)
Publication Number | Publication Date |
---|---|
EA200100441A1 true EA200100441A1 (ru) | 2001-10-22 |
EA002736B1 EA002736B1 (ru) | 2002-08-29 |
Family
ID=23487672
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EA200100441A EA002736B1 (ru) | 1999-08-19 | 2000-08-18 | Порошки тугоплавких металлов с малым содержанием кислорода для порошковой металлургии |
Country Status (18)
Country | Link |
---|---|
US (1) | US6261337B1 (ru) |
EP (3) | EP1200218B1 (ru) |
KR (2) | KR100431095B1 (ru) |
CN (1) | CN1272125C (ru) |
AT (2) | ATE404308T1 (ru) |
AU (1) | AU766574B2 (ru) |
BR (1) | BR0007018A (ru) |
CA (1) | CA2346957A1 (ru) |
CY (1) | CY1108564T1 (ru) |
CZ (1) | CZ20011740A3 (ru) |
DE (2) | DE60039923D1 (ru) |
DK (1) | DK1541261T3 (ru) |
EA (1) | EA002736B1 (ru) |
ES (1) | ES2313136T3 (ru) |
HK (1) | HK1040501B (ru) |
IL (1) | IL142601A (ru) |
PT (2) | PT1200218E (ru) |
WO (1) | WO2001012364A1 (ru) |
Families Citing this family (39)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6521173B2 (en) * | 1999-08-19 | 2003-02-18 | H.C. Starck, Inc. | Low oxygen refractory metal powder for powder metallurgy |
IL132291A0 (en) * | 1999-10-08 | 2001-03-19 | Advanced Alloys Technologies L | A method for production of tantalum powder with highly developed surface |
US6358625B1 (en) * | 1999-10-11 | 2002-03-19 | H. C. Starck, Inc. | Refractory metals with improved adhesion strength |
JP4261105B2 (ja) | 2000-03-01 | 2009-04-30 | キャボット コーポレイション | 窒化バルブ金属およびその製造方法 |
EP1340235B1 (en) * | 2000-11-30 | 2006-08-09 | Showa Denko K.K. | Powder for capacitor, sintered body thereof and capacitor using the sintered body |
US20030002043A1 (en) * | 2001-04-10 | 2003-01-02 | Kla-Tencor Corporation | Periodic patterns and technique to control misalignment |
AU2008200187B2 (en) * | 2001-05-15 | 2010-02-18 | Showa Denko K.K. | Niobium powder, niobium sintered body and capacitor using the sintered body |
US6934146B2 (en) | 2001-05-15 | 2005-08-23 | Showa Denko K.K. | Niobium powder, niobium sintered body and capacitor using the sintered body |
US6780218B2 (en) * | 2001-06-20 | 2004-08-24 | Showa Denko Kabushiki Kaisha | Production process for niobium powder |
US7081148B2 (en) * | 2001-09-18 | 2006-07-25 | Praxair S.T. Technology, Inc. | Textured-grain-powder metallurgy tantalum sputter target |
US6770154B2 (en) | 2001-09-18 | 2004-08-03 | Praxair S.T. Technology, Inc. | Textured-grain-powder metallurgy tantalum sputter target |
BR0307073A (pt) * | 2002-01-23 | 2004-12-28 | Starck H C Inc | Produtos de moinho de metalurgia de pulverizado de metal refratário de tamanho de grão estabilizado |
CA2473845A1 (en) * | 2002-01-24 | 2004-01-08 | H.C. Starck Inc. | Capacitor-grade lead wires with increased tensile strength and hardness |
TWI341337B (en) * | 2003-01-07 | 2011-05-01 | Cabot Corp | Powder metallurgy sputtering targets and methods of producing same |
US20060162822A1 (en) * | 2003-01-21 | 2006-07-27 | Richard Malen | Capacitor-grade lead wires with increased tensile strength and hardness |
DE10304756B4 (de) * | 2003-02-05 | 2005-04-07 | W.C. Heraeus Gmbh | Sauerstoffangereicherter Niob-Draht |
ES2320253T3 (es) * | 2003-03-28 | 2009-05-20 | Mitsubishi Materials Corporation | Metodo para fabricar una planta desechable y aparato para alinear comprimido crudo. |
US7135141B2 (en) * | 2003-03-31 | 2006-11-14 | Hitachi Metals, Ltd. | Method of manufacturing a sintered body |
US20050279630A1 (en) * | 2004-06-16 | 2005-12-22 | Dynamic Machine Works, Inc. | Tubular sputtering targets and methods of flowforming the same |
CA2606478C (en) * | 2005-05-05 | 2013-10-08 | H.C. Starck Gmbh | Method for coating a substrate surface and coated product |
JP4904341B2 (ja) * | 2005-05-05 | 2012-03-28 | ハー.ツェー.スタルク ゲゼルシャフト ミット ベシュレンクテル ハフツング | スパッタターゲット及びx線アノードを製造又は再処理するための被覆方法 |
US20080078268A1 (en) * | 2006-10-03 | 2008-04-03 | H.C. Starck Inc. | Process for preparing metal powders having low oxygen content, powders so-produced and uses thereof |
MX2009004773A (es) * | 2006-11-07 | 2009-05-21 | Starck H C Gmbh | Metodo para revestir una superficie de sustrato y producto revestido. |
US20080145688A1 (en) | 2006-12-13 | 2008-06-19 | H.C. Starck Inc. | Method of joining tantalum clade steel structures |
US8197894B2 (en) * | 2007-05-04 | 2012-06-12 | H.C. Starck Gmbh | Methods of forming sputtering targets |
JP2011500962A (ja) * | 2007-10-15 | 2011-01-06 | ハイ−テンプ・スペシャルティー・メタルス・インコーポレーテッド | 再生スクラップを原材料として使用したタンタル粉末の生産方法 |
US8246903B2 (en) | 2008-09-09 | 2012-08-21 | H.C. Starck Inc. | Dynamic dehydriding of refractory metal powders |
US8043655B2 (en) * | 2008-10-06 | 2011-10-25 | H.C. Starck, Inc. | Low-energy method of manufacturing bulk metallic structures with submicron grain sizes |
CN102189261A (zh) * | 2011-05-30 | 2011-09-21 | 华中科技大学 | 一种多孔制件的致密化方法 |
US9412568B2 (en) | 2011-09-29 | 2016-08-09 | H.C. Starck, Inc. | Large-area sputtering targets |
CN102672181A (zh) * | 2012-06-07 | 2012-09-19 | 太仓市锦立得粉末冶金有限公司 | 一种粉末冶金制品的生产工艺 |
CN105377481B (zh) | 2014-02-27 | 2018-02-06 | 宁夏东方钽业股份有限公司 | 一种高纯钽粉及其制备方法 |
CN103920880A (zh) * | 2014-03-11 | 2014-07-16 | 宁夏东方钽业股份有限公司 | 钽及钽合金棒材的制备方法 |
EP3129176A1 (en) | 2014-04-11 | 2017-02-15 | H.C. Starck Inc. | High purity refractory metal sputtering targets which have a uniform random texture manufactured by hot isostatic pressing high purity refractory metal powders |
KR101488703B1 (ko) * | 2014-10-29 | 2015-02-04 | 국방과학연구소 | 탄탈륨 분말 소결체 라이너 및 그 제조방법 |
EP3408047B8 (en) | 2016-01-27 | 2022-08-17 | H.C. Starck Inc. | Fabrication of high-entropy alloy wire and multi-principal element alloy wire for additive manufacturing |
US10099267B2 (en) | 2016-03-03 | 2018-10-16 | H.C. Starck Inc. | High-density, crack-free metallic parts |
CN111940745B (zh) * | 2019-12-30 | 2024-01-19 | 宁夏东方钽业股份有限公司 | 大松装冶金级钽粉的制造方法 |
CN111560531B (zh) * | 2020-04-15 | 2021-07-09 | 河南中钻新材料有限公司 | 一种低氧化物夹杂高性能粉末冶金镍基高温合金的制备方法 |
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Publication number | Priority date | Publication date | Assignee | Title |
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US4722756A (en) * | 1987-02-27 | 1988-02-02 | Cabot Corp | Method for deoxidizing tantalum material |
US5242481A (en) * | 1989-06-26 | 1993-09-07 | Cabot Corporation | Method of making powders and products of tantalum and niobium |
US5082491A (en) * | 1989-09-28 | 1992-01-21 | V Tech Corporation | Tantalum powder with improved capacitor anode processing characteristics |
EP0484931B1 (en) * | 1990-11-09 | 1998-01-14 | Kabushiki Kaisha Toyota Chuo Kenkyusho | Sintered powdered titanium alloy and method for producing the same |
US5954856A (en) * | 1996-04-25 | 1999-09-21 | Cabot Corporation | Method of making tantalum metal powder with controlled size distribution and products made therefrom |
-
1999
- 1999-08-19 US US09/377,077 patent/US6261337B1/en not_active Expired - Lifetime
-
2000
- 2000-08-18 AU AU70636/00A patent/AU766574B2/en not_active Ceased
- 2000-08-18 AT AT05005428T patent/ATE404308T1/de active
- 2000-08-18 CZ CZ20011740A patent/CZ20011740A3/cs unknown
- 2000-08-18 BR BR0007018-1A patent/BR0007018A/pt not_active Application Discontinuation
- 2000-08-18 EP EP00959289A patent/EP1200218B1/en not_active Expired - Lifetime
- 2000-08-18 EA EA200100441A patent/EA002736B1/ru not_active IP Right Cessation
- 2000-08-18 KR KR10-2001-7004864A patent/KR100431095B1/ko not_active IP Right Cessation
- 2000-08-18 PT PT00959289T patent/PT1200218E/pt unknown
- 2000-08-18 EP EP05005428A patent/EP1541261B1/en not_active Expired - Lifetime
- 2000-08-18 ES ES05005428T patent/ES2313136T3/es not_active Expired - Lifetime
- 2000-08-18 AT AT00959289T patent/ATE300377T1/de active
- 2000-08-18 WO PCT/US2000/022902 patent/WO2001012364A1/en active IP Right Grant
- 2000-08-18 KR KR10-2003-7014108A patent/KR100436108B1/ko active IP Right Grant
- 2000-08-18 DK DK05005428T patent/DK1541261T3/da active
- 2000-08-18 DE DE60039923T patent/DE60039923D1/de not_active Expired - Lifetime
- 2000-08-18 PT PT05005428T patent/PT1541261E/pt unknown
- 2000-08-18 DE DE60021579T patent/DE60021579T2/de not_active Expired - Lifetime
- 2000-08-18 CN CNB008019940A patent/CN1272125C/zh not_active Expired - Fee Related
- 2000-08-18 EP EP08161538.7A patent/EP1995005B1/en not_active Expired - Lifetime
- 2000-08-18 CA CA002346957A patent/CA2346957A1/en not_active Abandoned
-
2001
- 2001-04-15 IL IL142601A patent/IL142601A/en not_active IP Right Cessation
-
2002
- 2002-03-14 HK HK02101960.2A patent/HK1040501B/zh not_active IP Right Cessation
-
2008
- 2008-11-13 CY CY20081101302T patent/CY1108564T1/el unknown
Also Published As
Publication number | Publication date |
---|---|
HK1040501A1 (en) | 2002-06-14 |
KR20010099702A (ko) | 2001-11-09 |
DE60021579D1 (de) | 2005-09-01 |
US6261337B1 (en) | 2001-07-17 |
CA2346957A1 (en) | 2001-02-22 |
EA002736B1 (ru) | 2002-08-29 |
CY1108564T1 (el) | 2014-04-09 |
CZ20011740A3 (cs) | 2002-02-13 |
HK1040501B (zh) | 2007-04-20 |
DK1541261T3 (da) | 2008-12-01 |
EP1200218A1 (en) | 2002-05-02 |
KR100436108B1 (ko) | 2004-06-14 |
KR100431095B1 (ko) | 2004-05-12 |
AU7063600A (en) | 2001-03-13 |
EP1200218A4 (en) | 2004-04-14 |
DE60021579T2 (de) | 2006-05-24 |
EP1200218B1 (en) | 2005-07-27 |
CN1322157A (zh) | 2001-11-14 |
KR20030087087A (ko) | 2003-11-12 |
CN1272125C (zh) | 2006-08-30 |
EP1541261B1 (en) | 2008-08-13 |
PT1541261E (pt) | 2008-11-12 |
WO2001012364A1 (en) | 2001-02-22 |
IL142601A (en) | 2006-10-05 |
PT1200218E (pt) | 2005-11-30 |
ATE404308T1 (de) | 2008-08-15 |
ATE300377T1 (de) | 2005-08-15 |
EP1995005A1 (en) | 2008-11-26 |
BR0007018A (pt) | 2001-07-03 |
ES2313136T3 (es) | 2009-03-01 |
AU766574B2 (en) | 2003-10-16 |
EP1541261A1 (en) | 2005-06-15 |
DE60039923D1 (de) | 2008-09-25 |
EP1995005B1 (en) | 2015-02-25 |
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