BG100002A - Състави предназначени за полимеризация на олефини и методи за получаването и използването им - Google Patents

Състави предназначени за полимеризация на олефини и методи за получаването и използването им Download PDF

Info

Publication number
BG100002A
BG100002A BG100002A BG10000295A BG100002A BG 100002 A BG100002 A BG 100002A BG 100002 A BG100002 A BG 100002A BG 10000295 A BG10000295 A BG 10000295A BG 100002 A BG100002 A BG 100002A
Authority
BG
Bulgaria
Prior art keywords
catalyst
transition metal
composition
boroxin
range
Prior art date
Application number
BG100002A
Other languages
Bulgarian (bg)
English (en)
Inventor
Ted Pettijohn
Original Assignee
Phillips Petroleum Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Phillips Petroleum Company filed Critical Phillips Petroleum Company
Publication of BG100002A publication Critical patent/BG100002A/bg

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63904—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with another component of C08F4/62
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63912—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/6392—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/63922—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65904—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with another component of C08F4/64
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
BG100002A 1994-09-16 1995-09-15 Състави предназначени за полимеризация на олефини и методи за получаването и използването им BG100002A (bg)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US08/307,201 US5622906A (en) 1994-09-16 1994-09-16 Compositions useful for olefin polymerization and processes therefor and therewith

Publications (1)

Publication Number Publication Date
BG100002A true BG100002A (bg) 1997-01-31

Family

ID=23188691

Family Applications (1)

Application Number Title Priority Date Filing Date
BG100002A BG100002A (bg) 1994-09-16 1995-09-15 Състави предназначени за полимеризация на олефини и методи за получаването и използването им

Country Status (15)

Country Link
US (1) US5622906A (no)
EP (1) EP0705848A3 (no)
JP (1) JPH08176220A (no)
KR (1) KR960010692A (no)
CN (1) CN1123795A (no)
AU (1) AU2727695A (no)
BG (1) BG100002A (no)
BR (1) BR9503923A (no)
CA (1) CA2154823A1 (no)
CZ (1) CZ239195A3 (no)
FI (1) FI954352A (no)
HU (1) HUT73051A (no)
NO (1) NO953642L (no)
PL (1) PL310494A1 (no)
ZA (1) ZA957034B (no)

Families Citing this family (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000513399A (ja) * 1996-06-17 2000-10-10 エクソン・ケミカル・パテンツ・インク オレフィン重合用の混合遷移金属触媒系
CA2196493C (en) * 1997-01-31 2002-07-16 Huanyu Mao Additives for improving cycle life of non-aqueous rechargeable lithium batteries
US6114483A (en) * 1997-08-27 2000-09-05 E. I. Du Pont De Nemours And Company Polymerization of olefins
US6291608B1 (en) * 1998-12-23 2001-09-18 Phillips Petroleum Company Polymerization catalyst system and polymerization process
US6653254B1 (en) * 1999-02-22 2003-11-25 Fina Technology, Inc Ziegler-Natta catalyst with metallocene for olefin polymerization
US6300439B1 (en) 1999-11-08 2001-10-09 Univation Technologies, Llc Group 15 containing transition metal catalyst compounds, catalyst systems and their use in a polymerization process
US6274684B1 (en) 1999-10-22 2001-08-14 Univation Technologies, Llc Catalyst composition, method of polymerization, and polymer therefrom
US6281306B1 (en) * 1999-12-16 2001-08-28 Univation Technologies, Llc Method of polymerization
US6399531B1 (en) 1999-12-28 2002-06-04 Union Carbide Chemicals & Plastics Technology Corporation Hybrid ziegler-natta and cycloalkadienyl catalysts for the production of polyolefins
EP1172385A1 (fr) * 2000-07-14 2002-01-16 SOLVAY POLYOLEFINS EUROPE - BELGIUM (Société Anonyme) Procédé pour la polymérisation des alpha-oléfines
US6916892B2 (en) * 2001-12-03 2005-07-12 Fina Technology, Inc. Method for transitioning between Ziegler-Natta and metallocene catalysts in a bulk loop reactor for the production of polypropylene
JP2005524742A (ja) 2002-05-06 2005-08-18 ユニオン・カーバイド・ケミカルズ・アンド・プラスティックス・テクノロジー・コーポレイション ポリオレフィンを製造するための混合触媒組成物
EP1509552A1 (en) * 2002-06-03 2005-03-02 Univation Technologies LLC Solid, particulated, spray dried, heterogenous catalyst composition
JP4732444B2 (ja) * 2004-04-22 2011-07-27 シェブロン フィリップス ケミカル カンパニー エルピー 広い分子量分布を有する重合体を生成する触媒系およびそれらと同じものを作成する方法
KR100681233B1 (ko) 2004-10-28 2007-02-09 김재황 복강경수술 모니터장치 및 디스플레이 방법
US8101695B2 (en) * 2004-11-22 2012-01-24 Basell Polyolefine Gmbh Propylene based terpolymers
KR101331556B1 (ko) 2012-03-30 2013-11-20 대림산업 주식회사 멀티모달 폴리올레핀 수지 및 이로부터 제조되는 성형체
KR101437509B1 (ko) 2012-12-03 2014-09-03 대림산업 주식회사 성형성 및 기계적 물성이 우수한 멀티모달 폴리올레핀 수지 제조를 위한 촉매 조성물 및 이를 이용한 중합 방법
KR101800866B1 (ko) 2016-04-26 2017-12-21 대림산업 주식회사 용융강도가 높은 멀티모달 폴리올레핀 수지 및 이로부터 제조되는 성형체
BR112019006072B1 (pt) * 2016-09-29 2023-02-14 Dow Global Technologies Llc Método de polimerização de uma olefina usando um catalisador ziegler-natta e um catalisador molecular não suportado em um mesmo reator ao mesmo tempo e método de polimerização
CN109715677B (zh) * 2016-09-29 2022-03-22 陶氏环球技术有限责任公司 改性的齐格勒-纳塔(前)催化剂和体系
JP6990032B2 (ja) * 2017-03-28 2022-02-03 三井化学株式会社 オレフィン重合体の製造方法および遷移金属錯体の保存方法
US11897090B1 (en) 2020-10-22 2024-02-13 Peter H. Hines Orientation independent tool for underground stop and waste valve

Family Cites Families (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4363746A (en) * 1979-05-29 1982-12-14 Phillips Petroleum Company Composition of matter and method of preparing same, catalyst, method of producing the catalyst and polymerization process employing the catalyst
US4326988A (en) * 1980-08-12 1982-04-27 Phillips Petroleum Company Catalyst, method of producing the catalyst, and polymerization process employing the catalyst
US4808561A (en) * 1985-06-21 1989-02-28 Exxon Chemical Patents Inc. Supported polymerization catalyst
US5124418A (en) * 1985-11-15 1992-06-23 Exxon Chemical Patents Inc. Supported polymerization catalyst
US4752597A (en) * 1985-12-12 1988-06-21 Exxon Chemical Patents Inc. New polymerization catalyst
US4939217A (en) * 1987-04-03 1990-07-03 Phillips Petroleum Company Process for producing polyolefins and polyolefin catalysts
DE3743322A1 (de) * 1987-12-21 1989-06-29 Hoechst Ag Polyethylenwachs und verfahren zu seiner herstellung
DE3743320A1 (de) * 1987-12-21 1989-06-29 Hoechst Ag 1-olefinstereoblockpolymerwachs und verfahren zu seiner herstellung
DE3743321A1 (de) * 1987-12-21 1989-06-29 Hoechst Ag 1-olefinpolymerwachs und verfahren zu seiner herstellung
US5001244A (en) * 1988-06-22 1991-03-19 Exxon Chemical Patents Inc. Metallocene, hydrocarbylaluminum and hydrocarbylboroxine olefin polymerization catalyst
US5264088A (en) * 1988-06-23 1993-11-23 Norsolor Tour Aurore Catalytic composition for the polymerization of olefins and its process of preparation
DE3904468A1 (de) * 1989-02-15 1990-08-16 Hoechst Ag Polypropylenwachs und verfahren zu seiner herstellung
US5262487A (en) * 1989-09-13 1993-11-16 Mitsubishi Petrochemical Company Limited Process for producing propylene block copolymer
US5082882A (en) * 1989-11-30 1992-01-21 Phillips Petroleum Company Use of starch in the preparation of polymers
US5032562A (en) * 1989-12-27 1991-07-16 Mobil Oil Corporation Catalyst composition and process for polymerizing polymers having multimodal molecular weight distribution
US5145818A (en) * 1989-12-29 1992-09-08 Mitsui Petrochemical Industries, Ltd. Olefin polymerization catalyst and process for the polymerization of olefins
TW198726B (no) * 1989-12-29 1993-01-21 Mitsui Petroleum Chemicals Ind
US5266544A (en) * 1989-12-29 1993-11-30 Mitsui Petrochemical Industries, Ltd. Olefin polymerization catalyst and process for the polymerization of olefins
FR2659337B1 (fr) * 1990-03-12 1992-06-05 Bp Chemicals Snc Procede de preparation d'un catalyseur a base de zirconium, de titane et/ou de vanadium supporte sur du chlorure de magnesium, et utilisation du catalyseur dans la polymerisation des olefines.
US5239022A (en) * 1990-11-12 1993-08-24 Hoechst Aktiengesellschaft Process for the preparation of a syndiotactic polyolefin
US5411925A (en) * 1993-02-12 1995-05-02 Phillips Petroleum Company Organo-aluminoxy product and use
DE4203753A1 (de) * 1992-02-10 1993-08-12 Basf Ag Katalysatorsysteme zur polymerisation von c(pfeil abwaerts)2(pfeil abwaerts)-bis c(pfeil abwaerts)1(pfeil abwaerts)(pfeil abwaerts)0(pfeil abwaerts)-alkenen
US5258344A (en) * 1992-06-30 1993-11-02 Phillips Petroleum Company Transition metal catalyst, method of producing the catalyst, polymerization process employing the catalyst, and polymer produced by the polymerization process
US5449650A (en) * 1992-12-08 1995-09-12 Mitsubishi Petrochemical Company Limited Catalyst components for polymerization of olefins and use thereof
US5354721A (en) * 1993-06-22 1994-10-11 Phillips Petroleum Company Organo-aluminoxy product and use
US5414180A (en) * 1993-07-14 1995-05-09 Phillips Petroleum Company Organo-aluminoxy product and use

Also Published As

Publication number Publication date
NO953642D0 (no) 1995-09-15
HU9502707D0 (en) 1995-11-28
KR960010692A (ko) 1996-04-20
FI954352A (fi) 1996-03-17
EP0705848A3 (en) 1997-02-12
HUT73051A (en) 1996-06-28
AU2727695A (en) 1996-04-04
EP0705848A2 (en) 1996-04-10
NO953642L (no) 1996-03-18
ZA957034B (en) 1996-04-26
JPH08176220A (ja) 1996-07-09
CN1123795A (zh) 1996-06-05
BR9503923A (pt) 1996-09-17
CA2154823A1 (en) 1996-03-17
PL310494A1 (en) 1996-03-18
US5622906A (en) 1997-04-22
FI954352A0 (fi) 1995-09-15
CZ239195A3 (en) 1996-04-17

Similar Documents

Publication Publication Date Title
US5622906A (en) Compositions useful for olefin polymerization and processes therefor and therewith
KR940004715B1 (ko) 중합 보조 촉매
EP0822946B1 (en) Azaborolinyl metal complexes as olefin polymerization catalysts
US5587439A (en) Polymer supported catalyst for olefin polymerization
CA2105015C (en) Catalyst compositions and process for preparing polyolefins
EP0514594A1 (en) Catalyst composition and process for preparing polymers having multimodal molecular weight distribution
EP0586168A1 (en) Catalyst compositions and process for preparing polyolefins
EP2261266A2 (en) Process for the polymerization of a monomer with a catalyst composition containing an organometal compound, an organoaluminum compound and a treated solid oxide compound
JP2001526731A (ja) ２反応ゾーンを使用するメタロセン触媒を用いた２山型ポリオレフィンの製造法
EP0314797A1 (en) Olefin polymerization catalyst and process for polymerizing olefin
WO1999049970A1 (en) Polymerization catalysts and processes therefor
US6255415B1 (en) Ethylene polymerization process
EP0272132A1 (en) Improved olefin polymerization catalysts, production and use
US20040063876A1 (en) Olefin polymerization process
JPH0832733B2 (ja) オレフインの重合方法
US6228959B1 (en) Single-site catalysts containing homoaromatic ligands
US6228958B1 (en) Azaborolinyl metal complexes as olefin polymerization catalysts
JP2549632B2 (ja) オレフインの重合方法
CA2219816C (en) Azaborolinyl metal complexes as olefin polymerization catalysts
EP0173486A1 (en) Polymerization catalyst, production and use
CA2154746A1 (en) Olefin polymerization catalyst and process for preparing polyolefins
JPH0832735B2 (ja) オレフインの重合方法
PL150405B1 (en) Carrier-supported catalyst for polymerization of olefines and method of obtaining it