AU708136B2 - Isoparaffin-olefin alkylation process - Google Patents
Isoparaffin-olefin alkylation process Download PDFInfo
- Publication number
- AU708136B2 AU708136B2 AU72633/96A AU7263396A AU708136B2 AU 708136 B2 AU708136 B2 AU 708136B2 AU 72633/96 A AU72633/96 A AU 72633/96A AU 7263396 A AU7263396 A AU 7263396A AU 708136 B2 AU708136 B2 AU 708136B2
- Authority
- AU
- Australia
- Prior art keywords
- zeolite
- olefin
- catalyst
- process according
- alkylation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
- C07C2/56—Addition to acyclic hydrocarbons
- C07C2/58—Catalytic processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
- B01J29/10—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing iron group metals, noble metals or copper
- B01J29/12—Noble metals
- B01J29/126—Y-type faujasite
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/18—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/561643 | 1995-11-22 | ||
| US08/561,643 US5705729A (en) | 1995-11-22 | 1995-11-22 | Isoparaffin-olefin alkylation process |
| PCT/US1996/016218 WO1997019041A1 (en) | 1995-11-22 | 1996-10-14 | Isoparaffin-olefin alkylation process |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| AU7263396A AU7263396A (en) | 1997-06-11 |
| AU708136B2 true AU708136B2 (en) | 1999-07-29 |
Family
ID=24242823
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AU72633/96A Ceased AU708136B2 (en) | 1995-11-22 | 1996-10-14 | Isoparaffin-olefin alkylation process |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US5705729A (enExample) |
| EP (1) | EP0871600B1 (enExample) |
| JP (1) | JP3992738B2 (enExample) |
| AU (1) | AU708136B2 (enExample) |
| CA (1) | CA2230756C (enExample) |
| DE (1) | DE69636956T2 (enExample) |
| ES (1) | ES2279527T3 (enExample) |
| WO (1) | WO1997019041A1 (enExample) |
Families Citing this family (51)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6037513A (en) * | 1998-07-09 | 2000-03-14 | Mobil Oil Corporation | Hydroalkylation of aromatic hydrocarbons |
| US6974787B2 (en) * | 1998-08-31 | 2005-12-13 | Exxonmobil Corporation | Gasoline sulfur reduction in fluid catalytic cracking |
| US20020153283A1 (en) * | 1998-12-28 | 2002-10-24 | Arthur W Chester | Gasoline sulfur reduction in fluid catalytic cracking |
| US6846403B2 (en) * | 1998-12-28 | 2005-01-25 | Mobil Oil Corporation | Gasoline sulfur reduction in fluid catalytic cracking |
| US6852214B1 (en) * | 1998-08-31 | 2005-02-08 | Mobil Oil Corporation | Gasoline sulfur reduction in fluid catalytic cracking |
| US7803267B2 (en) * | 1998-12-28 | 2010-09-28 | W. R. Grace & Co.-Conn. | Gasoline sulfur reduction in fluid catalytic cracking |
| US7838708B2 (en) * | 2001-06-20 | 2010-11-23 | Grt, Inc. | Hydrocarbon conversion process improvements |
| US7507686B2 (en) * | 2002-12-03 | 2009-03-24 | W. R. Grace & Co. - Conn. | Gasoline sulfur reduction in fluid catalytic cracking |
| US20050171393A1 (en) * | 2003-07-15 | 2005-08-04 | Lorkovic Ivan M. | Hydrocarbon synthesis |
| EP1682465A1 (en) * | 2003-07-15 | 2006-07-26 | GRT, Inc. | Hydrocarbon synthesis |
| US7750197B2 (en) * | 2004-02-09 | 2010-07-06 | Albemarle Netherlands B.V. | Alkylation process using a catalyst comprising a solid acid and a hydrogenation metal |
| JP4446032B2 (ja) * | 2004-03-22 | 2010-04-07 | 日揮触媒化成株式会社 | イソパラフィン−オレフィンアルキル化用ゼオライト触媒および該触媒を用いたアルキル化法 |
| US8173851B2 (en) | 2004-04-16 | 2012-05-08 | Marathon Gtf Technology, Ltd. | Processes for converting gaseous alkanes to liquid hydrocarbons |
| US20080275284A1 (en) * | 2004-04-16 | 2008-11-06 | Marathon Oil Company | Process for converting gaseous alkanes to liquid hydrocarbons |
| US20060100469A1 (en) | 2004-04-16 | 2006-05-11 | Waycuilis John J | Process for converting gaseous alkanes to olefins and liquid hydrocarbons |
| US7674941B2 (en) * | 2004-04-16 | 2010-03-09 | Marathon Gtf Technology, Ltd. | Processes for converting gaseous alkanes to liquid hydrocarbons |
| US8642822B2 (en) | 2004-04-16 | 2014-02-04 | Marathon Gtf Technology, Ltd. | Processes for converting gaseous alkanes to liquid hydrocarbons using microchannel reactor |
| US7244867B2 (en) | 2004-04-16 | 2007-07-17 | Marathon Oil Company | Process for converting gaseous alkanes to liquid hydrocarbons |
| US7432408B2 (en) * | 2004-12-21 | 2008-10-07 | Chevron U.S.A. Inc. | Integrated alkylation process using ionic liquid catalysts |
| KR101368416B1 (ko) | 2006-02-03 | 2014-03-05 | 리액션 35, 엘엘씨 | 천연 가스를 액체 탄화수소로 변환시키는 연속 공정 |
| WO2007092410A2 (en) * | 2006-02-03 | 2007-08-16 | Grt, Inc. | Separation of light gases from halogens |
| TWI433829B (zh) * | 2007-01-26 | 2014-04-11 | Albemarle Netherlands Bv | 使用含稀土元素之沸石及氫化金屬之催化劑的烷化法 |
| EA201200888A1 (ru) * | 2007-05-14 | 2013-02-28 | Грт, Инк. | Способ конверсии углеводородного сырья с электролитическим извлечением галогенов |
| CN101765574A (zh) | 2007-05-24 | 2010-06-30 | Grt公司 | 使卤化氢可逆性俘获与释放相结合的区域反应器 |
| ES2573261T3 (es) * | 2008-04-14 | 2016-06-06 | Exxonmobil Chemical Patents Inc. | Procedimiento para producir ciclohexilbenceno |
| CN102015589B (zh) * | 2008-05-01 | 2013-05-29 | 埃克森美孚化学专利公司 | 用于制备环己基苯的方法 |
| US8282810B2 (en) | 2008-06-13 | 2012-10-09 | Marathon Gtf Technology, Ltd. | Bromine-based method and system for converting gaseous alkanes to liquid hydrocarbons using electrolysis for bromine recovery |
| KR101740419B1 (ko) * | 2008-07-18 | 2017-05-26 | 지알티, 인코포레이티드 | 천연 가스를 액체 탄화수소로 변환시키는 연속 공정 |
| WO2010014401A1 (en) * | 2008-07-28 | 2010-02-04 | Exxonmobil Chemical Patents Inc. | Hydroalkylation of aromatic compounds using emm-13 |
| WO2010014402A1 (en) * | 2008-07-28 | 2010-02-04 | Exxonmobil Chemical Patents Inc. | Hydroalkylation of aromatic compounds using emm-12 |
| CN102333747A (zh) | 2009-02-26 | 2012-01-25 | 埃克森美孚化学专利公司 | 生产环己基苯的方法 |
| US20100270167A1 (en) * | 2009-04-22 | 2010-10-28 | Mcfarland Eric | Process for converting hydrocarbon feedstocks with electrolytic and photoelectrocatalytic recovery of halogens |
| US8367884B2 (en) | 2010-03-02 | 2013-02-05 | Marathon Gtf Technology, Ltd. | Processes and systems for the staged synthesis of alkyl bromides |
| US8198495B2 (en) | 2010-03-02 | 2012-06-12 | Marathon Gtf Technology, Ltd. | Processes and systems for the staged synthesis of alkyl bromides |
| RU2445164C1 (ru) * | 2010-09-09 | 2012-03-20 | Учреждение Российской Академии Наук Ордена Трудового Красного Знамени Институт Нефтехимического Синтеза Им. А.В. Топчиева Ран (Инхс Ран) | Катализатор, способ его получения (варианты) и способ жидкофазного алкилирования изобутана олефинами c2-c4 в его присутствии |
| WO2012050751A1 (en) | 2010-10-11 | 2012-04-19 | Exxonmobil Chemical Patents Inc. | Activation and use of hydroalkylation catalysts |
| CN103261125B (zh) | 2010-12-21 | 2016-03-30 | 埃克森美孚化学专利公司 | 生产单环烷基取代的芳族化合物的方法 |
| US8815050B2 (en) | 2011-03-22 | 2014-08-26 | Marathon Gtf Technology, Ltd. | Processes and systems for drying liquid bromine |
| US8436220B2 (en) | 2011-06-10 | 2013-05-07 | Marathon Gtf Technology, Ltd. | Processes and systems for demethanization of brominated hydrocarbons |
| US8829256B2 (en) | 2011-06-30 | 2014-09-09 | Gtc Technology Us, Llc | Processes and systems for fractionation of brominated hydrocarbons in the conversion of natural gas to liquid hydrocarbons |
| WO2013058882A1 (en) | 2011-10-17 | 2013-04-25 | Exxonmobil Chemical Patents Inc. | Process for producing cyclohexylbenzene |
| US8802908B2 (en) | 2011-10-21 | 2014-08-12 | Marathon Gtf Technology, Ltd. | Processes and systems for separate, parallel methane and higher alkanes' bromination |
| RU2505357C2 (ru) * | 2011-10-27 | 2014-01-27 | Российская Федерация, от имени которой выступает Министерство промышленности и торговли Российской Федерации (Минпромторг России) | Разработка технологии производства катализаторов алкилирования |
| US9193641B2 (en) | 2011-12-16 | 2015-11-24 | Gtc Technology Us, Llc | Processes and systems for conversion of alkyl bromides to higher molecular weight hydrocarbons in circulating catalyst reactor-regenerator systems |
| CN103962177B (zh) * | 2013-01-31 | 2016-08-24 | 中国石油化工股份有限公司 | 一种含分子筛的催化剂的制备方法 |
| SG11201700069SA (en) * | 2014-07-07 | 2017-02-27 | Albemarle Europe Sprl | Alkylation process using a catalyst comprising cerium rich rare earth containing zeolites and a hydrogenation metal |
| JP6268110B2 (ja) * | 2015-02-05 | 2018-01-24 | 旭化成株式会社 | 炭化水素の製造方法 |
| CN106631656B (zh) * | 2015-10-28 | 2019-09-24 | 中国石油化工股份有限公司 | 一种烷基化反应方法 |
| RU2647575C2 (ru) * | 2016-06-02 | 2018-03-16 | Публичное акционерное общество "Электрогорский институт нефтепереработки" (ПАО "ЭлИНП") | Способ получения катализатора (варианты) и способ алкилирования изобутана бутиленами в присутствии полученного катализатора (варианты) |
| CN111491908B (zh) * | 2017-12-21 | 2025-03-21 | 巴斯夫欧洲公司 | 脂族有机化合物的烷基化方法 |
| CN112007652A (zh) * | 2019-05-31 | 2020-12-01 | 中国石油化工股份有限公司 | 一种固体酸催化剂及其应用 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5012033A (en) * | 1988-10-06 | 1991-04-30 | Mobil Oil Corp. | Isoparaffin-olefin alkylation process and catalyst composition thereof |
| US5285569A (en) * | 1990-11-09 | 1994-02-15 | Eubanks Engineering Company | Method of processing wire using multiple blade set |
| US5292981A (en) * | 1992-06-16 | 1994-03-08 | Mobil Oil Corporation | Isoparaffin-olefin alkylation process |
Family Cites Families (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3251902A (en) * | 1963-07-15 | 1966-05-17 | Socony Mobil Oil Co Inc | Isoparaffin-olefin alkylation using crystalline zeolite catalyst |
| US3236671A (en) * | 1964-03-02 | 1966-02-22 | Armour & Co | Method of reducing seepage loss from contained bodies of water |
| US3865894A (en) * | 1966-08-25 | 1975-02-11 | Sun Oil Co Pennsylvania | Process for paraffin-olefin alkylation |
| US3450644A (en) * | 1966-11-15 | 1969-06-17 | Union Carbide Corp | Treatment of oxidatively regenerated molecular sieve catalysts |
| US3624173A (en) * | 1968-03-26 | 1971-11-30 | Sun Oil Co | Gd ZEOLITE AND HYDROCARBON CONVERSION PROCESS WITH Gd ZEOLITE CATALYST |
| US3549557A (en) * | 1968-06-26 | 1970-12-22 | Union Carbide Corp | Isoparaffin alkylation process and catalyst for use therein |
| US3644565A (en) * | 1968-09-18 | 1972-02-22 | Union Oil Co | Alkylation process |
| US3655813A (en) * | 1969-06-05 | 1972-04-11 | Sun Oil Co | Continuous alkylation process |
| US3647916A (en) * | 1969-10-08 | 1972-03-07 | Mobil Oil Corp | Isoparaffin-olefin alkylation with crystalline zeolite catalysts at low isoparaffin to olefin ratios |
| US3706814A (en) * | 1970-05-04 | 1972-12-19 | Sun Oil Co | Continuous process for producing gasoline blending components |
| US3738977A (en) * | 1971-04-22 | 1973-06-12 | Union Oil Co | Polymerization of ethylene with a supported palladium catalyst |
| US3893942A (en) * | 1973-09-27 | 1975-07-08 | Union Carbide Corp | Isoparaffin alkylation process with periodic catalyst regeneration |
| US3917738A (en) * | 1974-05-16 | 1975-11-04 | Universal Oil Prod Co | Isoparaffin-olefin alkylation utilizing crystalline aluminosilicate catalyst in an adsorption zone |
| US4008291A (en) * | 1975-06-16 | 1977-02-15 | Universal Oil Products Company | Simulated moving bed alkylation process |
| US4377721A (en) * | 1981-06-22 | 1983-03-22 | Mobil Oil Corporation | Alkylation of isoparaffins with olefins |
| US4384161A (en) * | 1982-03-15 | 1983-05-17 | Mobil Oil Corporation | Heterogeneous isoparaffin/olefin alkylation |
| JPH032336Y2 (enExample) * | 1987-12-15 | 1991-01-23 | ||
| US5073665A (en) * | 1990-07-31 | 1991-12-17 | Mobil Oil Corp. | Process for alkylating olefins and isoparaffins in a fixed bed reactor |
| US5095167A (en) * | 1991-02-04 | 1992-03-10 | Mobil Oil Corporation | Isoparaffin:olefin alkylation process |
| US5254792A (en) * | 1991-10-10 | 1993-10-19 | Mobil Oil Corporation | Isoparaffin:olefin alkylation in the presence of synthetic porous MCM-49 |
| US5258569A (en) * | 1992-08-13 | 1993-11-02 | Mobil Oil Corp. | Isoparaffin-olefin alkylation process with zeolite MCM-36 |
| WO1995011872A1 (en) * | 1993-10-29 | 1995-05-04 | Shell Internationale Research Maatschappij B.V. | Process for upgrading a paraffinic feedstock |
-
1995
- 1995-11-22 US US08/561,643 patent/US5705729A/en not_active Expired - Fee Related
-
1996
- 1996-10-14 CA CA002230756A patent/CA2230756C/en not_active Expired - Fee Related
- 1996-10-14 ES ES96934147T patent/ES2279527T3/es not_active Expired - Lifetime
- 1996-10-14 JP JP51970597A patent/JP3992738B2/ja not_active Expired - Fee Related
- 1996-10-14 EP EP96934147A patent/EP0871600B1/en not_active Expired - Lifetime
- 1996-10-14 AU AU72633/96A patent/AU708136B2/en not_active Ceased
- 1996-10-14 WO PCT/US1996/016218 patent/WO1997019041A1/en not_active Ceased
- 1996-10-14 DE DE69636956T patent/DE69636956T2/de not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5012033A (en) * | 1988-10-06 | 1991-04-30 | Mobil Oil Corp. | Isoparaffin-olefin alkylation process and catalyst composition thereof |
| US5285569A (en) * | 1990-11-09 | 1994-02-15 | Eubanks Engineering Company | Method of processing wire using multiple blade set |
| US5292981A (en) * | 1992-06-16 | 1994-03-08 | Mobil Oil Corporation | Isoparaffin-olefin alkylation process |
Also Published As
| Publication number | Publication date |
|---|---|
| EP0871600A4 (en) | 1999-01-13 |
| US5705729A (en) | 1998-01-06 |
| AU7263396A (en) | 1997-06-11 |
| DE69636956T2 (de) | 2007-06-14 |
| JP2000500485A (ja) | 2000-01-18 |
| EP0871600B1 (en) | 2007-03-07 |
| CA2230756C (en) | 2005-07-26 |
| DE69636956D1 (de) | 2007-04-19 |
| CA2230756A1 (en) | 1997-05-29 |
| WO1997019041A1 (en) | 1997-05-29 |
| EP0871600A1 (en) | 1998-10-21 |
| JP3992738B2 (ja) | 2007-10-17 |
| ES2279527T3 (es) | 2007-08-16 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| AU708136B2 (en) | Isoparaffin-olefin alkylation process | |
| US5304698A (en) | Solid catalyzed supercritical isoparaffin-olefin alkylation process | |
| US4918255A (en) | Heterogeneous isoparaffin/olefin alkylation with isomerization | |
| AU663204B2 (en) | Isoparaffin-olefin alkylation process | |
| US5254792A (en) | Isoparaffin:olefin alkylation in the presence of synthetic porous MCM-49 | |
| US4992616A (en) | Heterogeneous isoparaffin/olefin aklylation process | |
| CA2005258A1 (en) | Heterogeneous isoparaffin/olefin alkylation process | |
| US5258569A (en) | Isoparaffin-olefin alkylation process with zeolite MCM-36 | |
| AU712533B2 (en) | Fluid catalytic alkylation process | |
| AU615090B2 (en) | Heterogeneous isoparaffin/olefin alkylation process | |
| US5461182A (en) | Hydrogen transfer and isoparaffin-olefin alkylation process | |
| AU708623B2 (en) | Isoparaffin/olefin alkylation process using rare-earth exchanged faujasite catalysts | |
| US5326922A (en) | Hydrogen transfer process | |
| US5625113A (en) | Isoparaffin/olefin alkylation | |
| US5498817A (en) | Isoparaffin/olefin alkylation over vacancy-containing titanometallate molecular sieves | |
| JP2000501103A (ja) | 希土類交換フォージャサイト触媒を使用するイソパラフィン/オレフィン・アルキル化方法 |