AU2015292907B2 - High toughness hollow fiber membranes based on vinylidene fluoride polymers - Google Patents

High toughness hollow fiber membranes based on vinylidene fluoride polymers Download PDF

Info

Publication number
AU2015292907B2
AU2015292907B2 AU2015292907A AU2015292907A AU2015292907B2 AU 2015292907 B2 AU2015292907 B2 AU 2015292907B2 AU 2015292907 A AU2015292907 A AU 2015292907A AU 2015292907 A AU2015292907 A AU 2015292907A AU 2015292907 B2 AU2015292907 B2 AU 2015292907B2
Authority
AU
Australia
Prior art keywords
vinylidene fluoride
weight
crystallinity
polymeric component
membrane
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
AU2015292907A
Other languages
English (en)
Other versions
AU2015292907A1 (en
Inventor
Scott Gaboury
Walter Kosar
Gregory S. O'brien
Roderick Reber Iii
Roice A. Wille
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Arkema Inc
Original Assignee
Arkema Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Arkema Inc filed Critical Arkema Inc
Publication of AU2015292907A1 publication Critical patent/AU2015292907A1/en
Application granted granted Critical
Publication of AU2015292907B2 publication Critical patent/AU2015292907B2/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B01D71/30—Polyalkenyl halides
    • B01D71/32—Polyalkenyl halides containing fluorine atoms
    • B01D71/34—Polyvinylidene fluoride
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/02—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor characterised by their properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/08—Hollow fibre membranes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B01D71/30—Polyalkenyl halides
    • B01D71/32—Polyalkenyl halides containing fluorine atoms
    • B01D71/36—Polytetrafluoroethene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B01D71/38—Polyalkenylalcohols; Polyalkenylesters; Polyalkenylethers; Polyalkenylaldehydes; Polyalkenylketones; Polyalkenylacetals; Polyalkenylketals
    • B01D71/383—Polyvinylacetates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B01D71/76—Macromolecular material not specifically provided for in a single one of groups B01D71/08 - B01D71/74
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/022—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the choice of material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
    • B29C48/05—Filamentary, e.g. strands
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
    • B29C48/09—Articles with cross-sections having partially or fully enclosed cavities, e.g. pipes or channels
    • B29C48/10—Articles with cross-sections having partially or fully enclosed cavities, e.g. pipes or channels flexible, e.g. blown foils
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00—Formation of filaments, threads, or the like
    • D01D5/24—Formation of filaments, threads, or the like with a hollow structure; Spinnerette packs therefor
    • D01D5/247—Discontinuous hollow structure or microporous structure
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00—General methods for the manufacture of artificial filaments or the like
    • D01F1/02—Addition of substances to the spinning solution or to the melt
    • D01F1/08—Addition of substances to the spinning solution or to the melt for forming hollow filaments
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/02—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D01F6/08—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds from polymers of halogenated hydrocarbons
    • D01F6/12—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds from polymers of halogenated hydrocarbons from polymers of fluorinated hydrocarbons
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2323/00—Details relating to membrane preparation
    • B01D2323/12—Specific ratios of components used
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2323/00—Details relating to membrane preparation
    • B01D2323/15—Use of additives
    • B01D2323/18—Pore-control agents or pore formers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2323/00—Details relating to membrane preparation
    • B01D2323/15—Use of additives
    • B01D2323/218—Additive materials
    • B01D2323/2182—Organic additives
    • B01D2323/21839—Polymeric additives
    • B01D2323/2185—Polyethylene glycol
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2323/00—Details relating to membrane preparation
    • B01D2323/15—Use of additives
    • B01D2323/218—Additive materials
    • B01D2323/2182—Organic additives
    • B01D2323/21839—Polymeric additives
    • B01D2323/2187—Polyvinylpyrolidone
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2325/00—Details relating to properties of membranes
    • B01D2325/24—Mechanical properties, e.g. strength
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B01D71/30—Polyalkenyl halides
    • B01D71/32—Polyalkenyl halides containing fluorine atoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2027/00—Use of polyvinylhalogenides or derivatives thereof as moulding material
    • B29K2027/12—Use of polyvinylhalogenides or derivatives thereof as moulding material containing fluorine
    • B29K2027/16—PVDF, i.e. polyvinylidene fluoride
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2023/00—Tubular articles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2031/00—Other particular articles
    • B29L2031/755—Membranes, diaphragms

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Textile Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Artificial Filaments (AREA)
  • Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)
AU2015292907A 2014-07-22 2015-07-21 High toughness hollow fiber membranes based on vinylidene fluoride polymers Active AU2015292907B2 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201462027367P 2014-07-22 2014-07-22
US62/027,367 2014-07-22
PCT/US2015/041219 WO2016014446A1 (en) 2014-07-22 2015-07-21 High toughness hollow fiber membranes based on vinylidene fluoride polymers

Publications (2)

Publication Number Publication Date
AU2015292907A1 AU2015292907A1 (en) 2017-02-02
AU2015292907B2 true AU2015292907B2 (en) 2020-05-07

Family

ID=55163605

Family Applications (1)

Application Number Title Priority Date Filing Date
AU2015292907A Active AU2015292907B2 (en) 2014-07-22 2015-07-21 High toughness hollow fiber membranes based on vinylidene fluoride polymers

Country Status (7)

Country Link
US (1) US10322381B2 (ja)
EP (1) EP3171969A4 (ja)
JP (1) JP6701166B2 (ja)
CN (1) CN106659985B (ja)
AU (1) AU2015292907B2 (ja)
SG (1) SG11201700151SA (ja)
WO (1) WO2016014446A1 (ja)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2016201222A1 (en) * 2015-06-12 2016-12-15 Compact Membrane Systems, Inc Amorphous fluorinated copolymer gas separation membranes
TWI698479B (zh) * 2017-03-10 2020-07-11 財團法人工業技術研究院 聚偏二氟乙烯薄膜的形成方法及純化鹽水的方法
CN107913604B (zh) * 2017-09-14 2020-12-22 中南大学 一种pvdf/pvdf-hfp中空纤维膜的制备方法
CN108166093B (zh) * 2018-02-11 2019-02-22 广东奥林科技实业有限公司 一种聚醚砜短纤维的制备方法
FR3083458B1 (fr) * 2018-07-06 2022-08-26 Arkema France Fibres polymeres creuses en tant que membranes de filtration
CN114534510B (zh) * 2022-02-16 2023-06-27 深圳华源再生医学有限公司 一种聚四氟乙烯纤维膜及其制备方法和应用
CN116770456B (zh) * 2023-06-06 2024-06-11 大白熊(广州)新材料科技有限公司 一种热塑性弹性体中空多孔纤维及其制备方法和应用

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20030094409A1 (en) * 2001-10-04 2003-05-22 Toray Industries, Inc. Hollow fiber membrane and method of producing the same
CN101199919A (zh) * 2006-12-11 2008-06-18 胡萍 中空纤维膜以及其制备方法
WO2009099396A2 (en) * 2008-02-05 2009-08-13 Institute Of Environmental Science And Engineering Pte Ltd Method for the production of an asymmetric hollow fiber membrane
US20110017661A1 (en) * 2006-11-21 2011-01-27 Arkema Inc. Caustic resistant membrane

Family Cites Families (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5656202A (en) 1979-10-15 1981-05-18 Asahi Chem Ind Co Ltd Hollow porous membrane yarn made of polyvinylidene fluoride type resin
US4377481A (en) 1980-11-14 1983-03-22 Abcor, Inc. Blended, polymeric, matrix membrane and process of making and using same
US6013688A (en) 1992-05-06 2000-01-11 Corning Costar Corporation PVDF microporous membrane and method
US5552208A (en) 1993-10-29 1996-09-03 Alliedsignal Inc. High strength composite
US6017455A (en) * 1995-05-09 2000-01-25 Asahi Kasei Kogyo Kabushiki Kaisha Porous membrane
DE69633806T2 (de) 1995-08-11 2005-05-12 Zenon Environmental Inc., Oakville Vorrichtung zur Permeatentnahme aus einem flüssigen Substrat mit mehreren Bestandteilen
WO1997026134A1 (en) 1996-01-22 1997-07-24 Memtec America Corporation Highly porous polyvinylidene difluoride membranes
US6074718A (en) * 1996-02-06 2000-06-13 Koch Membrane Systems, Inc. Self supporting hollow fiber membrane and method of construction
RU2256669C2 (ru) * 1999-11-03 2005-07-20 Атофина Кемикалз, Инк. Сополимеры винилиденфторида и гексафторпропилена с низкой кристалличностью
US20030038075A1 (en) 2000-08-02 2003-02-27 Tatsuo Akimoto Hollow yarn membrane module, hollow yarn membrane module unit, and method of producing hollow yarn membrane modules
US7338692B2 (en) 2003-09-12 2008-03-04 3M Innovative Properties Company Microporous PVDF films
EP1769840A4 (en) 2004-04-14 2008-12-31 Kureha Corp VINYLIDENE FLUORIDE RESIN FIBER POROUS WATER FILTRATION MEMBRANE AND MANUFACTURING METHOD THEREOF
US20090206035A1 (en) * 2005-02-15 2009-08-20 Kureha Corporation Vinylidene Fluoride Resin Hollow Filament Porous Membrane, Water Filtration Method Using the Same, and Process for Producing Said Vinylidene Fluoride Resin Hollow Filament Porous Membrane
CA2614567A1 (en) 2005-07-15 2007-01-25 Zymogenetics, Inc. Heterodimeric four helix bundle cytokines
US8557938B2 (en) * 2005-11-10 2013-10-15 Arkema Inc. Branched fluoropolymers
SG154449A1 (en) * 2006-04-19 2009-08-28 Asahi Kasei Chemicals Corp Highly durable porous pvdf film, method of producing the same, and washing method and filtering method using the same
JP5693845B2 (ja) * 2006-07-06 2015-04-01 アーケマ・インコーポレイテッド 超高分子量ポリ（弗化ビニリデン）
KR101408473B1 (ko) 2007-10-11 2014-06-17 쓰리엠 이노베이티브 프로퍼티즈 컴파니 평균 기공 크기가 비교적 큰 미세다공성 막 및 이를 제조하는 방법
US20120012521A1 (en) * 2009-01-15 2012-01-19 Takeo Takahashi Vinylidene fluoride resin hollow fiber porous membrane and process for producing same
EP2675550A4 (en) * 2011-02-18 2017-01-04 Arkema, Inc. Fluoropolymer gas separation films
US20130031260A1 (en) 2011-07-26 2013-01-31 Benjamin Tally Jones Method and apparatus for establishing an ad-hoc bi-directional network with an optical identifier
WO2013022660A1 (en) 2011-08-05 2013-02-14 Arkema Inc. Polymer blend membranes
TWI580701B (zh) 2011-10-27 2017-05-01 三菱麗陽股份有限公司 乙烯基聚合物粉末、硬化性樹脂組成物及硬化物
CN105008029B (zh) 2013-03-04 2019-12-17 阿科玛股份有限公司 长链支化的氟聚合物膜

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20030094409A1 (en) * 2001-10-04 2003-05-22 Toray Industries, Inc. Hollow fiber membrane and method of producing the same
US20110017661A1 (en) * 2006-11-21 2011-01-27 Arkema Inc. Caustic resistant membrane
CN101199919A (zh) * 2006-12-11 2008-06-18 胡萍 中空纤维膜以及其制备方法
WO2009099396A2 (en) * 2008-02-05 2009-08-13 Institute Of Environmental Science And Engineering Pte Ltd Method for the production of an asymmetric hollow fiber membrane

Also Published As

Publication number Publication date
WO2016014446A1 (en) 2016-01-28
EP3171969A1 (en) 2017-05-31
JP2017523037A (ja) 2017-08-17
US20170216780A1 (en) 2017-08-03
SG11201700151SA (en) 2017-02-27
EP3171969A4 (en) 2018-03-14
CN106659985B (zh) 2021-06-15
CN106659985A (zh) 2017-05-10
JP6701166B2 (ja) 2020-05-27
AU2015292907A1 (en) 2017-02-02
US10322381B2 (en) 2019-06-18

Similar Documents

Publication Publication Date Title
AU2015292907B2 (en) High toughness hollow fiber membranes based on vinylidene fluoride polymers
JP5861734B2 (ja) 高分子多孔質膜
US11065587B2 (en) Long chain branched fluoropolymer membranes
JP6270716B2 (ja) 多孔質膜を製造する方法
AU2012294783B2 (en) Polymer blend membranes
EP3252086B1 (en) Copolymer, hydrophilizing agent, composition containing hydrophilizing agent, and porous polymer film
CN105120992B (zh) 聚偏二氟乙烯中空纤维膜及其制备
KR20140025579A (ko) 고분자 다공질막 및 고분자 다공질막의 제조 방법
CN105339427A (zh) 组合物、高分子多孔质膜和亲水化剂
JP2023506230A (ja) Ｐｖｄｆに基づく膜のための、双性イオン性部位を含むポリマー添加剤
CN108697992A (zh) 包含硅酸盐的多孔聚合物膜
JP2023506016A (ja) フッ化ビニリデン（ｖｄｆ）ポリマーに基づく膜のための双性イオン部位含有ポリマー系添加剤
WO2024003351A1 (en) Use of polymer additive comprising zwitterionic moieties in pvdf membranes for increasing the flux of said membranes
KR20230023947A (ko) 장기안정성이 우수한 막접촉기 공정용 다공성 분리막 및 이의 제조방법
JP2014200752A (ja) 高分子多孔質膜

Legal Events

Date Code Title Description
FGA Letters patent sealed or granted (standard patent)