AU2011347262B2 - Electrode for electrolytic cell - Google Patents
Electrode for electrolytic cell Download PDFInfo
- Publication number
- AU2011347262B2 AU2011347262B2 AU2011347262A AU2011347262A AU2011347262B2 AU 2011347262 B2 AU2011347262 B2 AU 2011347262B2 AU 2011347262 A AU2011347262 A AU 2011347262A AU 2011347262 A AU2011347262 A AU 2011347262A AU 2011347262 B2 AU2011347262 B2 AU 2011347262B2
- Authority
- AU
- Australia
- Prior art keywords
- catalytic composition
- electrode
- metals
- electrode according
- noble metal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
- 239000000203 mixture Substances 0.000 claims abstract description 45
- 230000003197 catalytic effect Effects 0.000 claims abstract description 35
- 229910052751 metal Inorganic materials 0.000 claims abstract description 25
- 239000002184 metal Substances 0.000 claims abstract description 25
- 229910000510 noble metal Inorganic materials 0.000 claims abstract description 20
- 238000000151 deposition Methods 0.000 claims abstract description 14
- 239000000758 substrate Substances 0.000 claims abstract description 10
- 239000000126 substance Substances 0.000 claims abstract description 8
- -1 platinum group metals Chemical class 0.000 claims abstract description 7
- 238000000034 method Methods 0.000 claims description 16
- 229910052741 iridium Inorganic materials 0.000 claims description 13
- 229910052707 ruthenium Inorganic materials 0.000 claims description 13
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 11
- 230000008021 deposition Effects 0.000 claims description 11
- 238000011068 loading method Methods 0.000 claims description 10
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims description 7
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 claims description 7
- 229910052719 titanium Inorganic materials 0.000 claims description 7
- 239000010936 titanium Substances 0.000 claims description 7
- 229910052697 platinum Inorganic materials 0.000 claims description 5
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Substances [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 5
- 238000004519 manufacturing process Methods 0.000 claims description 4
- 239000002243 precursor Substances 0.000 claims description 3
- 238000005546 reactive sputtering Methods 0.000 claims description 3
- 238000005979 thermal decomposition reaction Methods 0.000 claims description 3
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 2
- 238000005229 chemical vapour deposition Methods 0.000 claims 2
- 238000005240 physical vapour deposition Methods 0.000 claims 2
- 238000005868 electrolysis reaction Methods 0.000 abstract description 10
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 15
- 150000002739 metals Chemical class 0.000 description 9
- 239000000243 solution Substances 0.000 description 9
- 238000000576 coating method Methods 0.000 description 8
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 7
- 239000000460 chlorine Substances 0.000 description 7
- 229910052801 chlorine Inorganic materials 0.000 description 7
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 6
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 6
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 6
- 239000011248 coating agent Substances 0.000 description 5
- 238000001035 drying Methods 0.000 description 5
- 235000011121 sodium hydroxide Nutrition 0.000 description 5
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 4
- 239000003513 alkali Substances 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 3
- 229910003087 TiOx Inorganic materials 0.000 description 3
- 238000007605 air drying Methods 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 239000012267 brine Substances 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 3
- 229910052593 corundum Inorganic materials 0.000 description 3
- 239000010431 corundum Substances 0.000 description 3
- 239000008367 deionised water Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000011780 sodium chloride Substances 0.000 description 3
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 description 3
- 239000010409 thin film Substances 0.000 description 3
- HLLICFJUWSZHRJ-UHFFFAOYSA-N tioxidazole Chemical compound CCCOC1=CC=C2N=C(NC(=O)OC)SC2=C1 HLLICFJUWSZHRJ-UHFFFAOYSA-N 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 229910052786 argon Inorganic materials 0.000 description 2
- 230000001680 brushing effect Effects 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 239000010970 precious metal Substances 0.000 description 2
- WOCIAKWEIIZHES-UHFFFAOYSA-N ruthenium(iv) oxide Chemical compound O=[Ru]=O WOCIAKWEIIZHES-UHFFFAOYSA-N 0.000 description 2
- 238000005477 sputtering target Methods 0.000 description 2
- 238000007669 thermal treatment Methods 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000004070 electrodeposition Methods 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 238000010285 flame spraying Methods 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000001465 metallisation Methods 0.000 description 1
- 238000007750 plasma spraying Methods 0.000 description 1
- 230000007420 reactivation Effects 0.000 description 1
- 238000004088 simulation Methods 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
- C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
- C25B11/042—Electrodes formed of a single material
- C25B11/046—Alloys
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
- C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
- C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
- C25B11/055—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the substrate or carrier material
- C25B11/057—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the substrate or carrier material consisting of a single element or compound
- C25B11/061—Metal or alloy
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
- C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
- C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
- C25B11/073—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
- C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
- C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
- C25B11/073—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material
- C25B11/091—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of at least one catalytic element and at least one catalytic compound; consisting of two or more catalytic elements or catalytic compounds
- C25B11/093—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of at least one catalytic element and at least one catalytic compound; consisting of two or more catalytic elements or catalytic compounds at least one noble metal or noble metal oxide and at least one non-noble metal oxide
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
- C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
- C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
- C25B11/073—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material
- C25B11/091—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of at least one catalytic element and at least one catalytic compound; consisting of two or more catalytic elements or catalytic compounds
- C25B11/097—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of at least one catalytic element and at least one catalytic compound; consisting of two or more catalytic elements or catalytic compounds comprising two or more noble metals or noble metal alloys
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electrodes For Compound Or Non-Metal Manufacture (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
- Catalysts (AREA)
- Inorganic Chemistry (AREA)
- Electrolytic Production Of Metals (AREA)
- Inert Electrodes (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT002354A ITMI20102354A1 (it) | 2010-12-22 | 2010-12-22 | Elettrodo per cella elettrolitica |
| ITMI2010A002354 | 2010-12-22 | ||
| PCT/EP2011/073605 WO2012085095A2 (en) | 2010-12-22 | 2011-12-21 | Electrode for electrolytic cell |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| AU2011347262A1 AU2011347262A1 (en) | 2013-05-23 |
| AU2011347262B2 true AU2011347262B2 (en) | 2016-03-31 |
Family
ID=43737007
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AU2011347262A Ceased AU2011347262B2 (en) | 2010-12-22 | 2011-12-21 | Electrode for electrolytic cell |
Country Status (20)
| Country | Link |
|---|---|
| US (1) | US20130228450A1 (enExample) |
| EP (2) | EP2655693B1 (enExample) |
| JP (1) | JP6247535B2 (enExample) |
| KR (2) | KR20130143624A (enExample) |
| CN (1) | CN103249872B (enExample) |
| AR (1) | AR083989A1 (enExample) |
| AU (1) | AU2011347262B2 (enExample) |
| BR (1) | BR112013014015B1 (enExample) |
| CA (1) | CA2815137C (enExample) |
| CL (1) | CL2013001620A1 (enExample) |
| CO (1) | CO6741167A2 (enExample) |
| DK (1) | DK2655693T3 (enExample) |
| EA (1) | EA024356B1 (enExample) |
| IL (1) | IL225905A (enExample) |
| IT (1) | ITMI20102354A1 (enExample) |
| MX (1) | MX354730B (enExample) |
| SG (1) | SG190951A1 (enExample) |
| TW (1) | TW201226631A (enExample) |
| WO (1) | WO2012085095A2 (enExample) |
| ZA (1) | ZA201302944B (enExample) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| PL3224392T3 (pl) * | 2014-11-24 | 2019-03-29 | Industrie De Nora S.P.A. | Anoda do elektrolitycznego wydzielania chloru |
| RU2720309C1 (ru) * | 2016-11-22 | 2020-04-28 | Асахи Касеи Кабусики Кайся | Электрод для электролиза |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SU522284A1 (ru) * | 1974-05-22 | 1976-07-25 | Предприятие П/Я В-2287 | Способ восстановлени активности отработанного покрыти |
| US4696731A (en) * | 1986-12-16 | 1987-09-29 | The Standard Oil Company | Amorphous metal-based composite oxygen anodes |
| WO1995005498A1 (en) * | 1993-08-13 | 1995-02-23 | Imperial Chemical Industries Plc | Preparation of electrode |
| WO2000060141A1 (en) * | 1999-04-08 | 2000-10-12 | United States Filter Corporation | Three layer anode and methods of manufacture |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1195871A (en) * | 1967-02-10 | 1970-06-24 | Chemnor Ag | Improvements in or relating to the Manufacture of Electrodes. |
| US3929608A (en) * | 1970-07-29 | 1975-12-30 | Solvay | Catalytic material for electrodes |
| US3684543A (en) * | 1970-11-19 | 1972-08-15 | Patricia J Barbato | Recoating of electrodes |
| GB1352872A (en) * | 1971-03-18 | 1974-05-15 | Ici Ltd | Electrodes for electrochemical processes |
| US4331528A (en) * | 1980-10-06 | 1982-05-25 | Diamond Shamrock Corporation | Coated metal electrode with improved barrier layer |
| DE3270207D1 (en) * | 1981-04-06 | 1986-05-07 | Eltech Systems Corp | Recoating of electrodes |
| JPS6022071B2 (ja) * | 1982-01-14 | 1985-05-30 | ペルメレツク電極株式会社 | 電解用電極の製造方法 |
| CN1012743B (zh) * | 1987-08-22 | 1991-06-05 | 福建省冶金工业研究所 | 电化学工业用钛阳极 |
| GB9018953D0 (en) * | 1990-08-31 | 1990-10-17 | Ici Plc | Electrode |
| TW197475B (enExample) * | 1990-12-26 | 1993-01-01 | Eltech Systems Corp | |
| JP3212327B2 (ja) | 1991-08-30 | 2001-09-25 | ペルメレック電極株式会社 | 電解用電極 |
| GB9316926D0 (en) * | 1993-08-13 | 1993-09-29 | Ici Plc | Electrode |
| FR2797646B1 (fr) * | 1999-08-20 | 2002-07-05 | Atofina | Cathode utilisable pour l'electrolyse de solutions aqueuses |
| ITMI20021128A1 (it) * | 2002-05-24 | 2003-11-24 | De Nora Elettrodi Spa | Elettrodo per sviluppo di gas e metodo per il suo ottenimento |
| JP2008156684A (ja) * | 2006-12-22 | 2008-07-10 | Tanaka Kikinzoku Kogyo Kk | 塩酸電解用の陽極電極 |
| ES2354234T3 (es) * | 2007-04-18 | 2011-03-11 | Industrie De Nora S.P.A. | Electrodos con superficie mecánicamente arrugada para aplicaciones electroquímicas. |
-
2010
- 2010-12-22 IT IT002354A patent/ITMI20102354A1/it unknown
-
2011
- 2011-10-25 TW TW100138559A patent/TW201226631A/zh unknown
- 2011-11-24 AR ARP110104391A patent/AR083989A1/es active IP Right Grant
- 2011-12-21 JP JP2013545366A patent/JP6247535B2/ja not_active Expired - Fee Related
- 2011-12-21 SG SG2013042270A patent/SG190951A1/en unknown
- 2011-12-21 EP EP11802731.7A patent/EP2655693B1/en not_active Not-in-force
- 2011-12-21 CN CN201180055655.3A patent/CN103249872B/zh not_active Expired - Fee Related
- 2011-12-21 BR BR112013014015-1A patent/BR112013014015B1/pt not_active IP Right Cessation
- 2011-12-21 EA EA201390927A patent/EA024356B1/ru not_active IP Right Cessation
- 2011-12-21 US US13/885,118 patent/US20130228450A1/en not_active Abandoned
- 2011-12-21 KR KR1020137018744A patent/KR20130143624A/ko not_active Ceased
- 2011-12-21 MX MX2013006271A patent/MX354730B/es active IP Right Grant
- 2011-12-21 DK DK11802731.7T patent/DK2655693T3/en active
- 2011-12-21 AU AU2011347262A patent/AU2011347262B2/en not_active Ceased
- 2011-12-21 CA CA2815137A patent/CA2815137C/en not_active Expired - Fee Related
- 2011-12-21 WO PCT/EP2011/073605 patent/WO2012085095A2/en not_active Ceased
- 2011-12-21 KR KR1020187010910A patent/KR101886032B1/ko not_active Expired - Fee Related
- 2011-12-21 EP EP16186150.5A patent/EP3118351A1/en not_active Ceased
-
2013
- 2013-04-23 ZA ZA2013/02944A patent/ZA201302944B/en unknown
- 2013-04-23 IL IL225905A patent/IL225905A/en active IP Right Grant
- 2013-06-04 CO CO13135216A patent/CO6741167A2/es not_active Application Discontinuation
- 2013-06-06 CL CL2013001620A patent/CL2013001620A1/es unknown
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SU522284A1 (ru) * | 1974-05-22 | 1976-07-25 | Предприятие П/Я В-2287 | Способ восстановлени активности отработанного покрыти |
| US4696731A (en) * | 1986-12-16 | 1987-09-29 | The Standard Oil Company | Amorphous metal-based composite oxygen anodes |
| WO1995005498A1 (en) * | 1993-08-13 | 1995-02-23 | Imperial Chemical Industries Plc | Preparation of electrode |
| WO2000060141A1 (en) * | 1999-04-08 | 2000-10-12 | United States Filter Corporation | Three layer anode and methods of manufacture |
Non-Patent Citations (4)
| Title |
|---|
| ELECTROCHIMICA ACTA, vol. 36, no. 2, 1 January 1991, pages 225-241, XP026506319,ELSEVIER SCIENCE PUBLISHERS, BARKING, GB. Yl ET AL: "Effect of Ir02 loading on Ru02-Ir02-Ti02 anodes: A study of microstructure and working life for the chlorine evolution reaction", CERAMICS INTERNATIONAL, vol. 33, no. 6, 25 June 2007, pages 1087-1091, XP022127750, ELSEVIER, NL * |
| KOTZ R et al: "Stabilization of Ru02 by Ir02 for anodic oxygen evolution in acid media", ELECTROCHIMICA ACTA, vol . 31, no. 10, 1 October 1986, pages 1311-1316, XP026527386, ELSEVIER SCIENCE PUBLISHERS, BARKING, GB. * |
| MEILLE et al: 'Review on methods to deposit catalysts on structured surfaces', APPLIED CATALYSIS A: GENERAL, vol. 315, 23 November 2006, pages 1-17, XP025142567, ELSEVIER SCIENCE, AMSTERDAM, NL. * |
| TRASATTI et al: 'Physical electrochemistry of ceramic oxides', ELECTROCHIMICA ACTA, vol. 36, no. 2, 1 January 1991, pages 225-241, XP026506319,ELSEVIER SCIENCE PUBLISHERS, BARKING, GB. * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103249872A (zh) | 2013-08-14 |
| WO2012085095A2 (en) | 2012-06-28 |
| JP6247535B2 (ja) | 2017-12-13 |
| CO6741167A2 (es) | 2013-08-30 |
| CL2013001620A1 (es) | 2013-11-08 |
| EP2655693A2 (en) | 2013-10-30 |
| KR20130143624A (ko) | 2013-12-31 |
| AR083989A1 (es) | 2013-04-10 |
| EA024356B1 (ru) | 2016-09-30 |
| TW201226631A (en) | 2012-07-01 |
| CA2815137C (en) | 2019-03-05 |
| MX2013006271A (es) | 2013-08-01 |
| ZA201302944B (en) | 2014-06-25 |
| KR101886032B1 (ko) | 2018-08-07 |
| EP3118351A1 (en) | 2017-01-18 |
| US20130228450A1 (en) | 2013-09-05 |
| DK2655693T3 (en) | 2017-02-20 |
| SG190951A1 (en) | 2013-07-31 |
| KR20180043398A (ko) | 2018-04-27 |
| EA201390927A1 (ru) | 2013-11-29 |
| IL225905A (en) | 2015-08-31 |
| JP2014505166A (ja) | 2014-02-27 |
| MX354730B (es) | 2018-03-15 |
| BR112013014015B1 (pt) | 2020-05-12 |
| IL225905A0 (en) | 2013-07-31 |
| BR112013014015A2 (pt) | 2016-09-13 |
| EP2655693B1 (en) | 2016-11-16 |
| WO2012085095A3 (en) | 2012-10-04 |
| AU2011347262A1 (en) | 2013-05-23 |
| ITMI20102354A1 (it) | 2012-06-23 |
| CN103249872B (zh) | 2016-08-10 |
| CA2815137A1 (en) | 2012-06-28 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FGA | Letters patent sealed or granted (standard patent) | ||
| MK14 | Patent ceased section 143(a) (annual fees not paid) or expired |