ATE432305T1 - Gel coats aus polyurethan mit von aliphatischen isocyanaten abgeleiteten einheiten enthaltende polyester-polyurethan-hybrid-harz- formzusammensetzungen - Google Patents
Gel coats aus polyurethan mit von aliphatischen isocyanaten abgeleiteten einheiten enthaltende polyester-polyurethan-hybrid-harz- formzusammensetzungenInfo
- Publication number
- ATE432305T1 ATE432305T1 AT06776989T AT06776989T ATE432305T1 AT E432305 T1 ATE432305 T1 AT E432305T1 AT 06776989 T AT06776989 T AT 06776989T AT 06776989 T AT06776989 T AT 06776989T AT E432305 T1 ATE432305 T1 AT E432305T1
- Authority
- AT
- Austria
- Prior art keywords
- polyurethane
- hybrid resin
- polyester
- part composition
- compositions containing
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title abstract 7
- 229920002635 polyurethane Polymers 0.000 title abstract 3
- 239000004814 polyurethane Substances 0.000 title abstract 3
- 239000012948 isocyanate Substances 0.000 title abstract 2
- 150000002513 isocyanates Chemical class 0.000 title 1
- 238000000465 moulding Methods 0.000 title 1
- 239000011347 resin Substances 0.000 title 1
- 229920005989 resin Polymers 0.000 title 1
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 2
- -1 isocyanate compound Chemical class 0.000 abstract 2
- 239000002253 acid Substances 0.000 abstract 1
- 125000001931 aliphatic group Chemical group 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 1
- 230000002452 interceptive effect Effects 0.000 abstract 1
- 229920005906 polyester polyol Polymers 0.000 abstract 1
- 239000007870 radical polymerization initiator Substances 0.000 abstract 1
- 239000011342 resin composition Substances 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- KKEYFWRCBNTPAC-UHFFFAOYSA-N terephthalic acid group Chemical group C(C1=CC=C(C(=O)O)C=C1)(=O)O KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/73—Polyisocyanates or polyisothiocyanates acyclic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/67—Unsaturated compounds having active hydrogen
- C08G18/68—Unsaturated polyesters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/63—Block or graft polymers obtained by polymerising compounds having carbon-to-carbon double bonds on to polymers
- C08G18/631—Block or graft polymers obtained by polymerising compounds having carbon-to-carbon double bonds on to polymers onto polyesters and/or polycarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/75—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2120/00—Compositions for reaction injection moulding processes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2220/00—Compositions for preparing gels other than hydrogels, aerogels and xerogels
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2270/00—Compositions for creating interpenetrating networks
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2933—Coated or with bond, impregnation or core
- Y10T428/2971—Impregnation
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
- Y10T428/31554—Next to second layer of polyamidoester
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
- Y10T428/31565—Next to polyester [polyethylene terephthalate, etc.]
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US71064105P | 2005-08-23 | 2005-08-23 | |
| PCT/EP2006/008199 WO2007022932A2 (en) | 2005-08-23 | 2006-08-21 | Polyester-polyurethane hybrid resin molding compositions comprising polyurethane with units derived from aliphatic isocyanates |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE432305T1 true ATE432305T1 (de) | 2009-06-15 |
Family
ID=37771965
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT06776989T ATE432305T1 (de) | 2005-08-23 | 2006-08-21 | Gel coats aus polyurethan mit von aliphatischen isocyanaten abgeleiteten einheiten enthaltende polyester-polyurethan-hybrid-harz- formzusammensetzungen |
Country Status (19)
| Country | Link |
|---|---|
| US (1) | US8742054B2 (de) |
| EP (1) | EP1917286B1 (de) |
| JP (1) | JP5435695B2 (de) |
| KR (1) | KR101318682B1 (de) |
| CN (1) | CN101243116B (de) |
| AT (1) | ATE432305T1 (de) |
| AU (1) | AU2006284121B2 (de) |
| BR (1) | BRPI0615711B1 (de) |
| CA (1) | CA2620015C (de) |
| DE (1) | DE602006007014D1 (de) |
| DK (1) | DK1917286T3 (de) |
| ES (1) | ES2327449T3 (de) |
| MX (1) | MX2008002450A (de) |
| MY (1) | MY141205A (de) |
| PL (1) | PL1917286T3 (de) |
| PT (1) | PT1917286E (de) |
| SI (1) | SI1917286T1 (de) |
| WO (1) | WO2007022932A2 (de) |
| ZA (1) | ZA200801005B (de) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2903412B1 (fr) * | 2006-07-07 | 2012-10-05 | Cray Valley Sa | Pre-polymere urethane - polyester insature et ses applications |
| EP2048172A1 (de) * | 2007-10-09 | 2009-04-15 | Cray Valley Ltd | Vernetzbare und schäumende (Hybrid-)Polyester-Polyurethan-Harzformzusammensetzungen mit Schäumungseigenschaften für geschlossene Formanwendungen |
| US7842349B2 (en) * | 2007-10-11 | 2010-11-30 | Tse Industries, Inc. | Method for spray forming high modulus polyurethane structures |
| US20110059319A1 (en) * | 2007-10-11 | 2011-03-10 | Tse Industries, Inc. | Method for spray forming high modulus polyurethane structures |
| WO2009089075A1 (en) * | 2008-01-11 | 2009-07-16 | The Sherwin-Williams Company | Metal coating composition |
| CN102365309A (zh) | 2009-04-03 | 2012-02-29 | 库克复合材料和聚合物公司 | 含有异氰尿酸酯环的热固性组合物 |
| CN101649176B (zh) * | 2009-08-25 | 2012-11-07 | 东华大学 | 不饱和脂肪族聚酯型聚氨酯粘合剂 |
| US9371468B2 (en) | 2013-01-16 | 2016-06-21 | Composites Intellectual Holdings, Inc. | Co-cured gel coats, elastomeric coatings, structural layers, and in-mold processes for their use |
| US10239265B2 (en) | 2013-03-15 | 2019-03-26 | Composites Intellectual Holdings, Inc. | Structural composite preform wet-out and curing system and method |
| US10329763B2 (en) | 2016-02-24 | 2019-06-25 | Wabash National, L.P. | Composite floor structure and method of making the same |
| CN109071999B (zh) * | 2016-04-22 | 2021-09-21 | 科思创德国股份有限公司 | 热潜催化的双组分体系 |
| WO2018163971A1 (ja) * | 2017-03-09 | 2018-09-13 | 富士フイルム株式会社 | 音響レンズ用樹脂材料、音響レンズ、音響波プローブ、音響波測定装置、超音波診断装置、光音響波測定装置および超音波内視鏡 |
| CN108774393B (zh) * | 2018-06-22 | 2020-08-18 | 天津市中科众晟医疗科技有限责任公司 | 一种女性乳腺自查手套 |
| CN111138845A (zh) * | 2020-01-19 | 2020-05-12 | 南京聚发新材料有限公司 | 一种片状模塑料、纤维增强复合材料及其制备方法和应用 |
Family Cites Families (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5232674B2 (de) * | 1973-02-20 | 1977-08-23 | ||
| DE2427089A1 (de) * | 1974-06-05 | 1975-12-18 | Bayer Ag | Verfahren zur herstellung von kunststoffen |
| DE2644550B1 (de) * | 1976-10-02 | 1977-12-08 | Hoechst Ag, 6000 Frankfurt | Verfahren zur herstellung von ueberzuegen und reaktionslack zur durchfuehrung des verfahrens |
| US4280979A (en) | 1979-09-18 | 1981-07-28 | Union Carbide Corporation | Copolymers, compositions, and articles, and methods for making same |
| JPS57200415A (en) * | 1981-06-03 | 1982-12-08 | Harima Kasei Kogyo Kk | Polyester-polyol for paint formulation |
| US4497918A (en) * | 1982-01-25 | 1985-02-05 | J. M. Huber Corporation | Thixotropic unsaturated polyester compositions and methods |
| JPS60245674A (ja) | 1984-05-21 | 1985-12-05 | Dainippon Toryo Co Ltd | 塗料用被覆組成物 |
| US4822849A (en) * | 1987-08-03 | 1989-04-18 | Reichhold Chemicals, Inc. | Low shrink hybrid resins |
| DE3935495A1 (de) | 1989-10-25 | 1991-05-02 | Bayer Ag | Verfahren zur herstellung von ungesaettigten, urethanisierten polyesterharzen, die nach diesem verfahren erhaeltlichen polyesterharze und ihre verwendung als oder zur herstellung von beschichtungsmittel(n) |
| JPH03185021A (ja) * | 1989-12-14 | 1991-08-13 | Hitachi Chem Co Ltd | ゲルコート用樹脂組成物およびゲルコートの製造法 |
| US5153261A (en) * | 1990-08-30 | 1992-10-06 | Amoco Corporation | Polyester-polyurethane hybrid resin molding compositions |
| US5159044A (en) * | 1990-11-20 | 1992-10-27 | Amoco Corporation | Sheet molding compounds having improved viscosity |
| JP3055197B2 (ja) * | 1991-01-14 | 2000-06-26 | 日本ポリウレタン工業株式会社 | ポリウレタン接着剤組成物 |
| US5344852A (en) * | 1992-01-16 | 1994-09-06 | Aristech Chemical Corporation | Unsaturated polyester-polyurethane hybrid resin foam compositions |
| FR2692901B1 (fr) * | 1992-06-26 | 1994-08-19 | Cray Valley Sa | Résines et compositions pour la fabrication de matériaux de haut module résistants à la chaleur et articles moulés obtenus à partir de ces matériaux. |
| US5296544A (en) * | 1992-07-14 | 1994-03-22 | Cook Composites And Polymers | Polyester-polyurethane hybrid resin systems containing low levels of unsaturation having improved low profiling behavior |
| US5604266A (en) * | 1992-10-15 | 1997-02-18 | Ecomat, Inc. | Cured unsaturated polyest-polyurethane highly filled resin materials and process for preparing them |
| JP3270556B2 (ja) * | 1993-01-13 | 2002-04-02 | 三井化学株式会社 | 貯蔵安定性の良好なハイブリッド架橋型樹脂組成物及びその成形法 |
| FR2730184B1 (fr) * | 1995-02-07 | 1998-11-20 | Cray Valley Sa | Resine pour impregne a renfort oriente formable et produits moules obtenus |
| US5821296A (en) | 1996-04-22 | 1998-10-13 | Aristech Chemical Corporation | Polyurethane-polyester hybrid resin system having improved stability |
| CA2449108C (en) * | 2001-06-01 | 2010-11-09 | Akzo Nobel N.V. | Coating composition comprising a polyisocyanate and a polyester oligomer prepared from a polyol, a poly-carboxylic acid, and a monocarboxylic acid |
| JP2003171429A (ja) * | 2001-12-04 | 2003-06-20 | Hitachi Chem Co Ltd | 不飽和ポリエステル樹脂組成物及びこの製造法、並びにこれを用いた熱硬化性成形材料及びプラスチック成形品 |
| US6808788B2 (en) * | 2002-05-17 | 2004-10-26 | The University Of Maine | Method for strengthening wood products and modified unsaturated polyester resins therefor |
-
2006
- 2006-08-18 US US11/465,529 patent/US8742054B2/en active Active
- 2006-08-21 SI SI200630375T patent/SI1917286T1/sl unknown
- 2006-08-21 PT PT06776989T patent/PT1917286E/pt unknown
- 2006-08-21 AU AU2006284121A patent/AU2006284121B2/en active Active
- 2006-08-21 MY MYPI20080178A patent/MY141205A/en unknown
- 2006-08-21 AT AT06776989T patent/ATE432305T1/de not_active IP Right Cessation
- 2006-08-21 BR BRPI0615711-4A patent/BRPI0615711B1/pt active IP Right Grant
- 2006-08-21 CN CN2006800302024A patent/CN101243116B/zh active Active
- 2006-08-21 KR KR1020087005021A patent/KR101318682B1/ko active IP Right Grant
- 2006-08-21 DE DE200660007014 patent/DE602006007014D1/de active Active
- 2006-08-21 WO PCT/EP2006/008199 patent/WO2007022932A2/en active Application Filing
- 2006-08-21 ES ES06776989T patent/ES2327449T3/es active Active
- 2006-08-21 MX MX2008002450A patent/MX2008002450A/es active IP Right Grant
- 2006-08-21 JP JP2008527369A patent/JP5435695B2/ja active Active
- 2006-08-21 PL PL06776989T patent/PL1917286T3/pl unknown
- 2006-08-21 EP EP06776989A patent/EP1917286B1/de active Active
- 2006-08-21 DK DK06776989T patent/DK1917286T3/da active
- 2006-08-21 CA CA2620015A patent/CA2620015C/en active Active
-
2008
- 2008-01-30 ZA ZA200801005A patent/ZA200801005B/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| KR101318682B1 (ko) | 2013-10-16 |
| BRPI0615711A2 (pt) | 2011-05-24 |
| CN101243116B (zh) | 2012-07-18 |
| DK1917286T3 (da) | 2009-09-14 |
| EP1917286B1 (de) | 2009-05-27 |
| WO2007022932A3 (en) | 2007-05-03 |
| MY141205A (en) | 2010-03-31 |
| ES2327449T3 (es) | 2009-10-29 |
| SI1917286T1 (sl) | 2009-10-31 |
| PL1917286T3 (pl) | 2009-10-30 |
| PT1917286E (pt) | 2009-08-24 |
| AU2006284121B2 (en) | 2011-12-15 |
| WO2007022932A2 (en) | 2007-03-01 |
| CA2620015C (en) | 2014-05-06 |
| JP2009506146A (ja) | 2009-02-12 |
| DE602006007014D1 (de) | 2009-07-09 |
| BRPI0615711B1 (pt) | 2021-10-13 |
| ZA200801005B (en) | 2008-11-26 |
| JP5435695B2 (ja) | 2014-03-05 |
| KR20080039456A (ko) | 2008-05-07 |
| EP1917286A2 (de) | 2008-05-07 |
| MX2008002450A (es) | 2008-04-03 |
| CN101243116A (zh) | 2008-08-13 |
| CA2620015A1 (en) | 2007-03-01 |
| AU2006284121A1 (en) | 2007-03-01 |
| US20070049686A1 (en) | 2007-03-01 |
| US8742054B2 (en) | 2014-06-03 |
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