ATE319747T1 - Kontinuierliches verfahren zur herstellung von materialien mit einer kontrollierten struktur - Google Patents
Kontinuierliches verfahren zur herstellung von materialien mit einer kontrollierten strukturInfo
- Publication number
- ATE319747T1 ATE319747T1 AT00941485T AT00941485T ATE319747T1 AT E319747 T1 ATE319747 T1 AT E319747T1 AT 00941485 T AT00941485 T AT 00941485T AT 00941485 T AT00941485 T AT 00941485T AT E319747 T1 ATE319747 T1 AT E319747T1
- Authority
- AT
- Austria
- Prior art keywords
- continuous process
- controlled structure
- producing materials
- materials
- anionically
- Prior art date
Links
- 238000010924 continuous production Methods 0.000 title abstract 2
- 239000000463 material Substances 0.000 title abstract 2
- 239000011368 organic material Substances 0.000 abstract 2
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 239000000178 monomer Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/01—Processes of polymerisation characterised by special features of the polymerisation apparatus used
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/18—Stationary reactors having moving elements inside
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/18—Stationary reactors having moving elements inside
- B01J19/1812—Tubular reactors
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/18—Stationary reactors having moving elements inside
- B01J19/20—Stationary reactors having moving elements inside in the form of helices, e.g. screw reactors
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/24—Stationary reactors without moving elements inside
- B01J19/2415—Tubular reactors
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F12/02—Monomers containing only one unsaturated aliphatic radical
- C08F12/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F12/06—Hydrocarbons
- C08F12/08—Styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/04—Polymerisation in solution
- C08F2/06—Organic solvent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
- C08F297/04—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00002—Chemical plants
- B01J2219/00027—Process aspects
- B01J2219/00033—Continuous processes
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Programmable Controllers (AREA)
- Manufacture, Treatment Of Glass Fibers (AREA)
- Threshing Machine Elements (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/500,155 US6448353B1 (en) | 2000-02-08 | 2000-02-08 | Continuous process for the production of controlled architecture materials |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE319747T1 true ATE319747T1 (de) | 2006-03-15 |
Family
ID=23988269
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT00941485T ATE319747T1 (de) | 2000-02-08 | 2000-06-16 | Kontinuierliches verfahren zur herstellung von materialien mit einer kontrollierten struktur |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US6448353B1 (enExample) |
| EP (1) | EP1263794B1 (enExample) |
| JP (1) | JP4669186B2 (enExample) |
| AT (1) | ATE319747T1 (enExample) |
| AU (1) | AU2000256189A1 (enExample) |
| DE (1) | DE60026526T2 (enExample) |
| WO (1) | WO2001058962A1 (enExample) |
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| US7112449B1 (en) * | 2000-04-05 | 2006-09-26 | Nanogram Corporation | Combinatorial chemical synthesis |
| US7514263B2 (en) * | 2001-04-02 | 2009-04-07 | 3M Innovative Properties Company | Continuous process for the production of combinatorial libraries of materials |
| US6956084B2 (en) | 2001-10-04 | 2005-10-18 | Bridgestone Corporation | Nano-particle preparation and applications |
| US6962946B2 (en) * | 2001-11-21 | 2005-11-08 | 3M Innovative Properties Company | Nanoparticles having a rutile-like crystalline phase and method of preparing same |
| US7157283B2 (en) * | 2002-08-02 | 2007-01-02 | 3M Innovative Properties Company | Continuous process for the production of combinatorial libraries of modified materials |
| US7632916B2 (en) * | 2002-08-02 | 2009-12-15 | 3M Innovative Properties Company | Process to modify polymeric materials and resulting compositions |
| US6903173B2 (en) | 2002-08-02 | 2005-06-07 | 3M Innovative Properties Co. | Fluorinated polymers |
| US6716935B1 (en) | 2002-12-19 | 2004-04-06 | 3M Innovative Properties Company | Continuous process for the production of controlled architecture materials under high solids loading conditions |
| US7402625B2 (en) * | 2003-06-11 | 2008-07-22 | 3M Innovative Properties Company | Compositions and method for improving the processing of polymer composites |
| US8236874B2 (en) * | 2003-06-11 | 2012-08-07 | 3M Innovative Properties Company | Compositions and method for improving the processing of polymer composites |
| US6969490B2 (en) * | 2003-06-26 | 2005-11-29 | 3M Innovative Properties Company | Device for the continuous process for the production of controlled architecture materials |
| US7205370B2 (en) | 2004-01-12 | 2007-04-17 | Bridgestone Corporation | Polymeric nano-particles of flower-like structure and applications |
| US8063142B2 (en) | 2004-03-02 | 2011-11-22 | Bridgestone Corporation | Method of making nano-particles of selected size distribution |
| US7718737B2 (en) | 2004-03-02 | 2010-05-18 | Bridgestone Corporation | Rubber composition containing functionalized polymer nanoparticles |
| US20050282956A1 (en) | 2004-06-21 | 2005-12-22 | Xiaorong Wang | Reversible polymer/metal nano-composites and method for manufacturing same |
| US7998554B2 (en) | 2004-07-06 | 2011-08-16 | Bridgestone Corporation | Hydrophobic surfaces with nanoparticles |
| ATE415425T1 (de) * | 2004-08-13 | 2008-12-15 | Kuraray Co | Verfahren zur kontinuierlichen herstellung von (meth)acrylsäureesterpolymer oder copolymer |
| US6969491B1 (en) * | 2004-09-01 | 2005-11-29 | 3M Innovative Properties Company | Stirred tube reactor and method of using the same |
| US7495051B2 (en) * | 2004-09-27 | 2009-02-24 | 3M Innovative Properties Company | Nanocomposite and method of making the same |
| US7329702B2 (en) * | 2004-09-27 | 2008-02-12 | 3M Innovative Properties Company | Composition and method of making the same |
| US7691932B2 (en) * | 2004-09-27 | 2010-04-06 | 3M Innovative Properties Company | Method of making a composition and nanocomposites therefrom |
| CN101061166A (zh) * | 2004-11-16 | 2007-10-24 | 3M创新有限公司 | 微球体填充的聚合物复合材料 |
| CN101072823A (zh) * | 2004-12-10 | 2007-11-14 | 3M创新有限公司 | 含有填料的聚合物复合材料 |
| US8193270B2 (en) * | 2004-12-14 | 2012-06-05 | 3M Innovative Properties Company | Method of making composites and nanocomposites |
| CN101107294B (zh) * | 2005-01-14 | 2011-05-25 | 株式会社普利司通 | 官能化聚合物和从其改进的轮胎 |
| US7579398B2 (en) | 2005-02-02 | 2009-08-25 | Bridgestone Corporation | Nano-composite and compositions therefrom |
| US7659342B2 (en) * | 2005-02-03 | 2010-02-09 | Bridgestone Corporation | Polymer nano-particle with polar core and method for manufacturing same |
| US20060189756A1 (en) * | 2005-02-23 | 2006-08-24 | Nelson James M | Polymer blends |
| GB0523707D0 (en) * | 2005-11-22 | 2005-12-28 | Nitech Solutions Ltd | Improved apparatus and method for temperature controlled processes |
| US20070135577A1 (en) * | 2005-12-09 | 2007-06-14 | Shefelbine Terri A | Intermediate elastomer compositions |
| US7538159B2 (en) * | 2005-12-16 | 2009-05-26 | Bridgestone Corporation | Nanoparticles with controlled architecture and method thereof |
| US9061900B2 (en) | 2005-12-16 | 2015-06-23 | Bridgestone Corporation | Combined use of liquid polymer and polymeric nanoparticles for rubber applications |
| US8288473B2 (en) | 2005-12-19 | 2012-10-16 | Bridgestone Corporation | Disk-like nanoparticles |
| US7884160B2 (en) | 2005-12-19 | 2011-02-08 | Bridgestone Corporation | Non-spherical nanoparticles made from living triblock polymer chains |
| US8697775B2 (en) | 2005-12-20 | 2014-04-15 | Bridgestone Corporation | Vulcanizable nanoparticles having a core with a high glass transition temperature |
| US8877250B2 (en) | 2005-12-20 | 2014-11-04 | Bridgestone Corporation | Hollow nano-particles and method thereof |
| US7560510B2 (en) | 2005-12-20 | 2009-07-14 | Bridgestone Corporation | Nano-sized inorganic metal particles, preparation thereof, and application thereof in improving rubber properties |
| EP2046575A4 (en) | 2006-07-28 | 2010-01-13 | Bridgestone Corp | POLYMERS CORE SHELL NANOPARTICLES WITH AN INTERPHASE AREA |
| US20100016530A1 (en) * | 2006-08-01 | 2010-01-21 | Albemarle Corporation | Lithium Reduction in Styrenic Polymers |
| US20080058482A1 (en) * | 2006-08-29 | 2008-03-06 | 3M Innovative Properties Company | Continuous process polymerization of (meth)acrylate copolymers |
| US7597959B2 (en) | 2006-12-19 | 2009-10-06 | Bridgestone Corporation | Core-shell fluorescent nanoparticles |
| US7649049B2 (en) | 2006-12-20 | 2010-01-19 | Bridgestone Corporation | Rubber composition containing a polymer nanoparticle |
| US7829624B2 (en) | 2007-06-29 | 2010-11-09 | Bridgestone Corporation | One-pot synthesis of nanoparticles and liquid polymer for rubber applications |
| JP2011503292A (ja) | 2007-11-08 | 2011-01-27 | スリーエム イノベイティブ プロパティズ カンパニー | 拡散特性を備えた光学的接着剤 |
| RU2560722C2 (ru) | 2008-12-31 | 2015-08-20 | Бриджстоун Корпорейшн | Наночастицы типа "ядро-оболочка", способ их синтеза и их применение |
| US9062144B2 (en) | 2009-04-03 | 2015-06-23 | Bridgestone Corporation | Hairy polymeric nanoparticles with first and second shell block polymer arms |
| CN102459401B (zh) | 2009-06-19 | 2015-04-08 | 东洋工程株式会社 | 聚乳酸的制造方法 |
| US9115222B2 (en) | 2009-12-29 | 2015-08-25 | Bridgestone Corporation | Well defined, highly crosslinked nanoparticles and method for making same |
| US9428604B1 (en) | 2011-12-30 | 2016-08-30 | Bridgestone Corporation | Nanoparticle fillers and methods of mixing into elastomers |
| EP2885363B1 (en) | 2012-08-14 | 2018-02-07 | 3M Innovative Properties Company | Adhesives comprising grafted isobutylene copolymer |
| JP2015120642A (ja) * | 2013-12-20 | 2015-07-02 | 株式会社堀場エステック | 連続反応装置及びこれを用いる連続合成方法 |
| EP3412690A4 (en) * | 2016-02-04 | 2019-05-15 | Nissan Chemical Corporation | POLYMER PRODUCTION PROCESS |
| WO2019118678A1 (en) | 2017-12-14 | 2019-06-20 | Bridgestone Corporation | Coupled polymer products, methods of making and compositions containing |
| WO2020066561A1 (ja) | 2018-09-27 | 2020-04-02 | 富士フイルム株式会社 | 重合体の製造方法、及び重合体を製造するフロー式反応システム |
| JP7274653B1 (ja) * | 2022-08-04 | 2023-05-16 | 株式会社堀場エステック | 重合装置 |
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|---|---|---|---|---|
| US3356763A (en) | 1962-04-09 | 1967-12-05 | Phillips Petroleum Co | Continuous process for producing block copolymers of dienes and vinyl aromatic hydrocarbons |
| US3322857A (en) | 1964-03-04 | 1967-05-30 | Monsanto Co | Polymeric blends containing a graft copolymer of vinyl chloride onto chlorinated or chlorosulfonated polyolefin |
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| US4371661A (en) | 1982-02-17 | 1983-02-01 | Atlantic Richfield Company | Semi-continuous process for making star-block copolymers |
| US4442273A (en) | 1983-04-06 | 1984-04-10 | Atlantic Richfield Company | Process and apparatus for continuous polymerization of a monovinyl aromatic monomer |
| US4485210A (en) | 1983-04-06 | 1984-11-27 | Atlantic Richfield Company | Process for the continuous production of star-block copolymers of a monovinyl aromatic monomer and a conjugated diene |
| US4572819A (en) | 1983-08-24 | 1986-02-25 | The Dow Chemical Company | Apparatus for anionic polymerization wherein the molecular weight of the polymer is closely controlled |
| US4540623A (en) | 1983-10-14 | 1985-09-10 | The Dow Chemical Company | Coextruded multi-layered articles |
| JPH0689047B2 (ja) | 1987-03-27 | 1994-11-09 | 新日鐵化学株式会社 | 重合反応装置 |
| IT1230085B (it) | 1989-05-24 | 1991-10-05 | Montedipe Spa | Processo per la produzione in massa e in continuo di (co) polimeri vinil aromatici antiurto. |
| EP0406906A3 (en) | 1989-07-07 | 1991-11-27 | Toagosei Chemical Industry Co., Ltd. | Ethylene graft copolymer and molding resin composition containing the same |
| JP3037706B2 (ja) | 1989-11-21 | 2000-05-08 | 日東電工株式会社 | 感圧性接着剤組成物およびその製造法 |
| JPH0714990B2 (ja) | 1990-03-02 | 1995-02-22 | 新日鐵化学株式会社 | ゴム変性スチレン系樹脂の製造法 |
| US5120749A (en) | 1991-02-20 | 1992-06-09 | Abbott Laboratories | Platelet activating antagonists |
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| US5705551A (en) | 1991-12-06 | 1998-01-06 | Avery Dennison Corporation | Elastomeric pressure-sensitive adhesive compositions exhibiting good cutting performance |
| US5281651A (en) | 1992-01-29 | 1994-01-25 | Exxon Chemical Patents Inc. | Compatibilization of dissimilar elastomer blends using ethylene/acrylate/acrylic acid terpolymers |
| FR2686886A1 (fr) | 1992-01-31 | 1993-08-06 | Atochem Elf Sa | Procede de fabrication en continu de copolymeres a bloc vinylaromatique. |
| CA2106262C (en) | 1992-10-01 | 2003-11-18 | Ralph H. Bland | Tear resistant multilayer films and articles incorporating such films |
| DE4234601A1 (de) | 1992-10-14 | 1994-04-21 | Basf Ag | Verfahren zur Herstellung von Blockcopolymeren durch ionische Polymerisation |
| DE4235786A1 (de) | 1992-10-23 | 1994-04-28 | Basf Ag | Polystyrol-Formmasse und Verfahren zu ihrer Herstellung |
| DE4235980A1 (de) | 1992-10-24 | 1994-04-28 | Basf Ag | Verfahren zur Herstellung einer vinylaromatischen Verbindung |
| US5391625A (en) | 1993-03-19 | 1995-02-21 | Arjunan; Palanisamy | Compatibilized elastomer blends containing copolymers of isoolefins |
| KR960701949A (ko) | 1993-04-19 | 1996-03-28 | 벤 씨. 카데헤드 | 이소올레핀과 알킬스티렌의 그라프트중합체를 함유하는 상용화된 탄성중합체 블렌드(compatibilized elastomer blends containing grafted polymers of an isoolefin and alkylstyrene) |
| US5585193A (en) | 1993-07-16 | 1996-12-17 | Avery Dennison Corporation | Machine-direction oriented label films and die-cut labels prepared therefrom |
| US5717040A (en) | 1993-08-16 | 1998-02-10 | Basf Aktiengesellschaft | Continuous process for polymerizing anionically polymerizable vinyl compounds |
| US5952065A (en) | 1994-08-31 | 1999-09-14 | Nike, Inc. | Cushioning device with improved flexible barrier membrane |
| FR2735480B1 (fr) | 1995-06-15 | 1997-07-18 | Atochem Elf Sa | Procede de polymerisation anionique en continu d'au moins un monomere (meth)acrylique pour l'obtention de polymeres a haut taux de solide |
| DE19523587A1 (de) | 1995-06-29 | 1997-01-02 | Basf Ag | Verfahren zur anionischen Polymerisation von Vinylaromaten |
| US5644007A (en) | 1996-04-26 | 1997-07-01 | Minnesota Mining And Manufacturing Company | Continuous process for the production of poly(1-alkenes) |
| US6180692B1 (en) | 1996-06-28 | 2001-01-30 | Xerox Corporation | Phase change ink formulation with organoleptic maskant additive |
| DE19648245A1 (de) | 1996-11-21 | 1998-05-28 | Basf Ag | Kontinuierliches Verfahren zur Herstellung thermoplastischer Formmassen |
| DE19701865A1 (de) | 1997-01-21 | 1998-07-23 | Basf Ag | Kontinuierliches Verfahren zur Herstellung von thermoplastischen Formmassen |
| US6045895A (en) | 1997-12-01 | 2000-04-04 | 3M Innovative Properties Company | Multilayer films having pressure sensitive adhesive layers |
| EP0921153A1 (en) | 1997-12-04 | 1999-06-09 | Advanced Elastomer Systems, L.P. | Compatibilized blends of non-polar thermoplastic elastomers and polar thermoplastic elastomers |
| US6013735A (en) * | 1998-02-13 | 2000-01-11 | Ethyl Corporation | Process for the preparation of acrylate and methacrylate polymers |
| US6160060A (en) | 1998-08-04 | 2000-12-12 | Eastman Chemical Company | Process for the synthesis of high molecular weight predominantly amorphous polymers with improved color and adhesive properties |
-
2000
- 2000-02-08 US US09/500,155 patent/US6448353B1/en not_active Expired - Lifetime
- 2000-06-16 AT AT00941485T patent/ATE319747T1/de not_active IP Right Cessation
- 2000-06-16 DE DE60026526T patent/DE60026526T2/de not_active Expired - Lifetime
- 2000-06-16 JP JP2001558108A patent/JP4669186B2/ja not_active Expired - Fee Related
- 2000-06-16 AU AU2000256189A patent/AU2000256189A1/en not_active Abandoned
- 2000-06-16 WO PCT/US2000/016631 patent/WO2001058962A1/en not_active Ceased
- 2000-06-16 EP EP00941485A patent/EP1263794B1/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| US6448353B1 (en) | 2002-09-10 |
| JP4669186B2 (ja) | 2011-04-13 |
| WO2001058962A1 (en) | 2001-08-16 |
| AU2000256189A1 (en) | 2001-08-20 |
| DE60026526T2 (de) | 2006-09-07 |
| JP2003522256A (ja) | 2003-07-22 |
| DE60026526D1 (de) | 2006-05-04 |
| EP1263794B1 (en) | 2006-03-08 |
| EP1263794A1 (en) | 2002-12-11 |
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