ATE273069T1 - Herstellungsverfahren mittels ultraschalls eines palladium und gold enthaltender katalysators zur herstellung von vinyl acetate - Google Patents

Herstellungsverfahren mittels ultraschalls eines palladium und gold enthaltender katalysators zur herstellung von vinyl acetate

Info

Publication number
ATE273069T1
ATE273069T1 AT00976906T AT00976906T ATE273069T1 AT E273069 T1 ATE273069 T1 AT E273069T1 AT 00976906 T AT00976906 T AT 00976906T AT 00976906 T AT00976906 T AT 00976906T AT E273069 T1 ATE273069 T1 AT E273069T1
Authority
AT
Austria
Prior art keywords
water
steps
support
production
reducing
Prior art date
Application number
AT00976906T
Other languages
English (en)
Inventor
Tao Wang
Jerry A Broussard
H Robert Gerberich
Original Assignee
Celanese Int Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Celanese Int Corp filed Critical Celanese Int Corp
Application granted granted Critical
Publication of ATE273069T1 publication Critical patent/ATE273069T1/de

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/34—Irradiation by, or application of, electric, magnetic or wave energy, e.g. ultrasonic waves ; Ionic sputtering; Flame or plasma spraying; Particle radiation
    • B01J37/341—Irradiation by, or application of, electric, magnetic or wave energy, e.g. ultrasonic waves ; Ionic sputtering; Flame or plasma spraying; Particle radiation making use of electric or magnetic fields, wave energy or particle radiation
    • B01J37/343—Irradiation by, or application of, electric, magnetic or wave energy, e.g. ultrasonic waves ; Ionic sputtering; Flame or plasma spraying; Particle radiation making use of electric or magnetic fields, wave energy or particle radiation of ultrasonic wave energy
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/58—Platinum group metals with alkali- or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0203—Impregnation the impregnation liquid containing organic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0205—Impregnation in several steps
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
    • C07C67/05—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation
    • C07C67/055—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation in the presence of platinum group metals or their compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B01J23/52—Gold

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Health & Medical Sciences (AREA)
  • Plasma & Fusion (AREA)
  • Toxicology (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
AT00976906T 1999-11-17 2000-11-03 Herstellungsverfahren mittels ultraschalls eines palladium und gold enthaltender katalysators zur herstellung von vinyl acetate ATE273069T1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US09/441,603 US6303537B1 (en) 1999-11-17 1999-11-17 Vinyl acetate catalyst comprising metallic palladium and gold and prepared utilizing sonication
PCT/US2000/030360 WO2001036092A1 (en) 1999-11-17 2000-11-03 Vinyl acetate catalyst comprising metallic palladium and gold and prepared utilizing sonication

Publications (1)

Publication Number Publication Date
ATE273069T1 true ATE273069T1 (de) 2004-08-15

Family

ID=23753541

Family Applications (1)

Application Number Title Priority Date Filing Date
AT00976906T ATE273069T1 (de) 1999-11-17 2000-11-03 Herstellungsverfahren mittels ultraschalls eines palladium und gold enthaltender katalysators zur herstellung von vinyl acetate

Country Status (15)

Country Link
US (1) US6303537B1 (de)
EP (1) EP1235644B1 (de)
JP (1) JP4873811B2 (de)
KR (1) KR100700852B1 (de)
CN (1) CN1200766C (de)
AT (1) ATE273069T1 (de)
BR (1) BR0015079B1 (de)
CA (1) CA2388808C (de)
CZ (1) CZ299073B6 (de)
DE (1) DE60012968T2 (de)
ES (1) ES2225259T3 (de)
MX (1) MXPA02004921A (de)
MY (1) MY120487A (de)
TW (1) TW539575B (de)
WO (1) WO2001036092A1 (de)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19914066A1 (de) * 1999-03-27 2000-10-05 Celanese Chem Europe Gmbh Katalysatoren für die Gasphasenoxidation von Ethylen und Essigsäure zu Vinylacetat, Verfahren zu ihrer Herstellung und ihre Verwendung
MY139952A (en) * 2001-03-30 2009-11-30 Shell Int Research A process for preparing a catalyst, the catalyst and a use of the catalyst
JP4421201B2 (ja) * 2002-03-27 2010-02-24 シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー 触媒を調製する方法、触媒、および触媒の使用
US6936568B2 (en) 2002-06-12 2005-08-30 Sud-Chemie Inc. Selective hydrogenation catalyst
US20040038820A1 (en) * 2002-08-20 2004-02-26 Nippon Shokubai Co., Ltd. Production process for catalyst
US20060205978A1 (en) * 2002-08-20 2006-09-14 Nippon Shokubai Co., Ltd. Production process for catalyst
US7022643B2 (en) * 2002-08-20 2006-04-04 Nippon Shokubai Co., Ltd. Production process for catalyst
JP4295521B2 (ja) 2003-02-13 2009-07-15 株式会社日本触媒 アクリル酸製造用触媒およびアクリル酸の製造方法
JP4297716B2 (ja) * 2003-03-31 2009-07-15 カウンシル オブ サイエンティフィク アンド インダストリアル リサーチ Ｃ−ｃ結合の形成方法
CA2547318C (en) * 2003-12-19 2010-11-02 Celanese International Corporation Layered support material for catalysts
TW201236755A (en) * 2003-12-19 2012-09-16 Celanese Int Corp Halide free precursors for catalysts
US7465823B2 (en) * 2004-03-17 2008-12-16 Celanese International Corporation Utilization of acetic acid reaction heat in other process plants
RU2422433C2 (ru) * 2004-12-20 2011-06-27 Селаниз Интернэшнл Корпорейшн Модифицированные материалы носителей для катализаторов
US8227369B2 (en) 2005-05-25 2012-07-24 Celanese International Corp. Layered composition and processes for preparing and using the composition
KR101964275B1 (ko) 2015-09-01 2019-04-01 주식회사 엘지화학 아크릴산 제조용 촉매 제조방법 및 이로부터 제조되는 촉매
CN108940383B (zh) * 2017-05-17 2021-07-30 上海交通大学 负载型还原态贵金属催化剂的制备方法
TW202204039A (zh) * 2020-06-11 2022-02-01 美商瑟蘭斯國際股份有限公司 用於乙酸乙烯酯製造之催化劑的製備方法

Family Cites Families (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CH534005A (de) 1968-02-01 1973-02-28 Bayer Ag Verfahren zur Herstellung eines Palladium und Gold enthaltenden Katalysators
JPS514118A (en) * 1974-06-27 1976-01-14 Kuraray Co Sakusanbiniruno seizohoho
US4048096A (en) * 1976-04-12 1977-09-13 E. I. Du Pont De Nemours And Company Surface impregnated catalyst
US4136062A (en) * 1977-10-17 1979-01-23 The Board Of Trustees Of Leland Stanford Junior University Highly active pd-au catalyst
US5274181A (en) * 1991-05-06 1993-12-28 Bp Chemicals Limited Catalysts and processes for the manufacture of vinyl acetate
US5314858A (en) * 1992-10-14 1994-05-24 Hoechst Celanese Corporation Vinyl acetate catalyst preparation method
US5332710A (en) 1992-10-14 1994-07-26 Hoechst Celanese Corporation Vinyl acetate catalyst preparation method
US5347046A (en) 1993-05-25 1994-09-13 Engelhard Corporation Catalyst and process for using same for the preparation of unsaturated carboxylic acid esters
DE4323978C1 (de) * 1993-07-16 1995-02-16 Hoechst Ag Palladium und Kalium sowie Cadmium, Barium oder Gold enthaltender Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung zur Herstellung von Vinylacetat
DE4323981C1 (de) * 1993-07-16 1995-03-09 Hoechst Ag Palladium und Kalium sowie Cadmium, Barium oder Gold enthaltender Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung zur Herstellung von Vinylacetat
DE4323980C1 (de) * 1993-07-16 1995-03-30 Hoechst Ag Palladium und Kalium sowie Cadmium, Barium oder Gold enthaltender Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung zur Herstellung von Vinylacetat
CA2135021A1 (en) * 1993-11-19 1995-05-20 David J. Gulliver Process for the preparation of catalysts for use in the production of vinyl acetate
US5466652A (en) * 1994-02-22 1995-11-14 The Standard Oil Co. Process for the preparation of vinyl acetate catalyst
US6034030A (en) * 1994-02-22 2000-03-07 Celanese International Corporation Vinyl acetate catalyst preparation method
US5536693A (en) * 1994-06-02 1996-07-16 The Standard Oil Company Process for the preparation of vinyl acetate catalyst
US5665667A (en) * 1994-06-02 1997-09-09 The Standard Oil Company Process for the preparation of vinyl acetate catalyst
US6022823A (en) * 1995-11-07 2000-02-08 Millennium Petrochemicals, Inc. Process for the production of supported palladium-gold catalysts
US5705679A (en) * 1996-04-02 1998-01-06 Nicolau; Ioan Honeycomb catalyst for vinyl acetate synthesis
US5691267A (en) * 1996-04-16 1997-11-25 Hoechst Celanese Corporation Two step gold addition method for preparing a vinyl acetate catalyst
SA97180048B1 (ar) 1996-05-24 2005-12-21 هوكست سيلانس كوربوريشن محفز بلاديوم - ذهب palladium gold ثنائي المعدن متغاير الخواص heterogeneous bimetallic vinyl acetate لإنتاج أسيتات فينيل
US5693586A (en) * 1996-06-28 1997-12-02 Hoechst Celanese Corporation Palladium-gold catalyst for vinyl acetate production
US5731457A (en) * 1997-06-03 1998-03-24 Hoechst Celanese Corporation Vinyl acetate process utilizing a palladium-gold-copper catalyst
US5968869A (en) * 1997-06-03 1999-10-19 Celanese International Corporation Vinyl acetate catalyst comprising palladium and gold deposited on a copper containing carrier
US5948724A (en) * 1997-10-28 1999-09-07 Celanese International Corporation Vinyl acetate catalyst comprising metallic palladium and gold and cupric acetate
US5859287A (en) * 1997-10-30 1999-01-12 Celanese International Corporation Process for preparing vinyl acetate utilizing a catalyst comprising palladium, gold, and any of certain third metals
DE19754992C2 (de) * 1997-12-11 2000-03-23 Celanese Chem Europe Gmbh Katalysator, Verfahren zur Herstellung des Katalysators und Verfahren zur Herstellung von Vinylacetat unter Einsatz des Katalysators
DE19754991C2 (de) * 1997-12-11 2000-03-23 Celanese Chem Europe Gmbh Katalysator, Verfahren zur Herstellung des Katalysators und Verfahren zur Herstellung von Vinylacetat unter Einsatz des Katalysators
US6072078A (en) * 1997-12-12 2000-06-06 Celanese International Corporation Vinyl acetate production using a catalyst comprising palladium, gold, copper and any of certain fourth metals
US6017847A (en) * 1998-06-02 2000-01-25 Celanese International Corporation Vinyl acetate catalyst prepared with potassium aurate and comprising metallic palladium and gold on a carrier precoated with copper
US6015769A (en) * 1998-06-02 2000-01-18 Celanese International Corporation Vinyl acetate catalyst comprising metallic palladium, gold and copper supported on a carrier and prepared with potassium aurate

Also Published As

Publication number Publication date
BR0015079A (pt) 2002-07-16
MXPA02004921A (es) 2002-09-18
KR20020048436A (ko) 2002-06-22
EP1235644A1 (de) 2002-09-04
KR100700852B1 (ko) 2007-03-29
ES2225259T3 (es) 2005-03-16
EP1235644B1 (de) 2004-08-11
JP4873811B2 (ja) 2012-02-08
CA2388808C (en) 2009-12-29
CZ299073B6 (cs) 2008-04-16
MY120487A (en) 2005-10-31
CN1200766C (zh) 2005-05-11
CZ20021664A3 (cs) 2003-01-15
DE60012968T2 (de) 2005-08-18
CN1391497A (zh) 2003-01-15
WO2001036092A1 (en) 2001-05-25
CA2388808A1 (en) 2001-05-25
JP2003513789A (ja) 2003-04-15
BR0015079B1 (pt) 2011-03-22
DE60012968D1 (de) 2004-09-16
US6303537B1 (en) 2001-10-16
TW539575B (en) 2003-07-01

Similar Documents

Publication Publication Date Title
ATE273069T1 (de) Herstellungsverfahren mittels ultraschalls eines palladium und gold enthaltender katalysators zur herstellung von vinyl acetate
KR950013579A (ko) 비닐 아세테이트의 제조에 사용되는 촉매의 제조 방법
RU2011131292A (ru) Способ получения катализатора или прокатализатора, содержащего диоксид циркония, каталитическая композиция и способ получения алкенилалканоатов с использованием такой композиции
RU99101904A (ru) Способ получения палладий-золотого катализатора для производства ванилацетата и каталитическая композиция
NZ514433A (en) Catalysts for the gas-phase oxidation of ethylene and acetic acid to vinyl acetate and method for the production and use thereof
MY110347A (en) Supported catalyst, process for its preparation and its use for the preparation of vinyl acetate
MY129802A (en) Fluid bed vinyl acetate catalyst
BR9910837A (pt) Catalizador para produção de acetato de vinila por reação de etileno, oxigênio e ácido acético, método para preparar um catalizador , e processo para produção de acetato de vinila
JP2002516747A5 (de)
NZ504032A (en) A catalyst comprising palladium, gold, and a third metal; and a process for preparing vinyl acetate utilizing this catalyst
DE59707151D1 (de) Verfahren zur Hydrierung von Zuckern mittels eines Schalenkatalysators
ATE298626T1 (de) Verfahren zur herstellung eines gold und titanium beinhaltenden katalysators
TR199701408T1 (xx) Vinil asetat �retimi i�in kataliz�r.
NZ508273A (en) A method of preparing a catalyst for the production of vinyl acetate comprising metallic palladium, copper and gold deposited on a support
BR0015179A (pt) Catalisador constituido de paládio metálico e ouro metálico que são úteis para a produção de acetato de vinila pela reação de etileno, oxigênio e ácido acético
BR9809715A (pt) Catalisador para produção de acetato vinìlico por reação de etileno, oxigênio e ácido acético e processo para produção do mesmo
DE69836295D1 (de) Verfahren zur Herstellung von Trägerkatalysatoren durch stromlose Metallabscheidung
ATE411257T1 (de) Verfahren zur herstellung von wasserstoffperoxid
AR015978A1 (es) Metodo para preparar un catalizador para la produccion de acetato de vinilo mediante la reaccion de etileno, oxigeno y acido acetico.
DE69702313T2 (de) Verfahren zur zweistufigen goldauftragung für die herstellung eines katalysators für die herstellung von vinylacetat
JP2003525723A5 (de)
DE59903042D1 (de) Verfahren zur herstellung von trägerkatalysatoren sowie deren verwendung für die herstellung von vinylacetatmonomer
MY117131A (en) Vinyl acetate process utilizing a palladium-gold-copper catalyst
BR0215542A (pt) Processo para a preparação de um catalisador micro-esferoidal
TH29979C3 (th) ตัวเร่งปฏิกิริยาไวนิลแอซิเททที่ประกอบรวมด้วยเมแทลลิคแพลเลเดียมและโกลด์ที่เตรียมด้วยโพแทสเซียมออเรท

Legal Events

Date Code Title Description
RER Ceased as to paragraph 5 lit. 3 law introducing patent treaties