ATE269755T1 - Katalysator zur herstellung von carbonsäureestern - Google Patents

Katalysator zur herstellung von carbonsäureestern

Info

Publication number
ATE269755T1
ATE269755T1 AT96924148T AT96924148T ATE269755T1 AT E269755 T1 ATE269755 T1 AT E269755T1 AT 96924148 T AT96924148 T AT 96924148T AT 96924148 T AT96924148 T AT 96924148T AT E269755 T1 ATE269755 T1 AT E269755T1
Authority
AT
Austria
Prior art keywords
catalyst
compound
reducible
supported
carrier
Prior art date
Application number
AT96924148T
Other languages
English (en)
Inventor
Setsuo Yamamatsu
Tatsuo Yamaguchi
Koshiro Yokota
Original Assignee
Asahi Kasei Chemicals Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP18154795A external-priority patent/JP3503776B2/ja
Priority claimed from JP18272195A external-priority patent/JP3503777B2/ja
Application filed by Asahi Kasei Chemicals Corp filed Critical Asahi Kasei Chemicals Corp
Application granted granted Critical
Publication of ATE269755T1 publication Critical patent/ATE269755T1/de

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56Platinum group metals
    • B01J23/62Platinum group metals with gallium, indium, thallium, germanium, tin or lead
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00Preparation of carboxylic acid esters
    • C07C67/39Preparation of carboxylic acid esters by oxidation of groups which are precursors for the acid moiety of the ester
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56Platinum group metals
    • B01J23/62Platinum group metals with gallium, indium, thallium, germanium, tin or lead
    • B01J23/622Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead
    • B01J23/628Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead with lead
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/42Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
    • B01J29/44Noble metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/48Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing arsenic, antimony, bismuth, vanadium, niobium tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/30Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00Preparation of carboxylic acid esters
    • C07C67/08Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/52Esters of acyclic unsaturated carboxylic acids having the esterified carboxyl group bound to an acyclic carbon atom
    • C07C69/533Monocarboxylic acid esters having only one carbon-to-carbon double bond
    • C07C69/54Acrylic acid esters; Methacrylic acid esters
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/14Silica and magnesia
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0027Powdering
    • B01J37/0045Drying a slurry, e.g. spray drying

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
AT96924148T 1995-07-18 1996-07-18 Katalysator zur herstellung von carbonsäureestern ATE269755T1 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP18154795A JP3503776B2 (ja) 1995-07-18 1995-07-18 カルボン酸エステル製造用パラジウム、鉛含有担持触媒
JP18272195A JP3503777B2 (ja) 1995-07-19 1995-07-19 パラジウム及び鉛を含む表面制御担持触媒
PCT/JP1996/002008 WO1997003751A1 (fr) 1995-07-18 1996-07-18 Catalyseur conçu pour la preparation d'esters carboxyliques

Publications (1)

Publication Number Publication Date
ATE269755T1 true ATE269755T1 (de) 2004-07-15

Family

ID=26500688

Family Applications (2)

Application Number Title Priority Date Filing Date
AT03077037T ATE280750T1 (de) 1995-07-18 1996-07-18 Verfahren zur herstellung von carbonsäureestern
AT96924148T ATE269755T1 (de) 1995-07-18 1996-07-18 Katalysator zur herstellung von carbonsäureestern

Family Applications Before (1)

Application Number Title Priority Date Filing Date
AT03077037T ATE280750T1 (de) 1995-07-18 1996-07-18 Verfahren zur herstellung von carbonsäureestern

Country Status (10)

Country Link
US (2) USRE38283E1 (de)
EP (2) EP0857512B1 (de)
KR (1) KR100259743B1 (de)
CN (1) CN1086313C (de)
AT (2) ATE280750T1 (de)
DE (2) DE69633753T2 (de)
HK (1) HK1009412A1 (de)
MY (1) MY119415A (de)
TW (1) TW348073B (de)
WO (1) WO1997003751A1 (de)

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US8192519B2 (en) 2005-03-09 2012-06-05 Vitag Corporation Beneficiated, heat-dried biosolid pellets
CA2622881C (en) 2005-09-15 2015-01-27 Vitag Llc Organic containing sludge to fertilizer alkaline conversion process
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US20080108497A1 (en) * 2006-11-08 2008-05-08 Holland Brian T Metal-rich siliceous compositions and methods of producing same
AU2008216035B2 (en) 2007-02-16 2011-09-01 Profile Products Llc Process for treating sludge and manufacturing bioorganically-augmented high nitrogen-containing inorganic fertilizer
US20140206897A1 (en) * 2013-01-22 2014-07-24 Saudi Basic Industries Corporation Method for making methyl methacrylate from propionaldehyde and formaldehyde via oxidative esterification
US9890105B2 (en) 2013-04-19 2018-02-13 Evonik Roehm Gmbh Method for producing methylmethacrylate
TW201509901A (zh) 2013-07-29 2015-03-16 Rohm & Haas 氧化酯化方法
TW201512168A (zh) * 2013-07-29 2015-04-01 Rohm & Haas 氧化酯化方法
TW201509522A (zh) 2013-07-29 2015-03-16 Rohm & Haas 氧化酯化催化劑
JP6382969B2 (ja) 2013-10-28 2018-08-29 ローム アンド ハース カンパニーRohm And Haas Company メタクロレインを分離するための方法
EP2886528A1 (de) 2013-12-20 2015-06-24 Evonik Industries AG Verfahren zur Herstellung von ungesättigten Estern ausgehend von Aldehyden durch Direkte Oxidative Veresterung
EP2886529A1 (de) 2013-12-20 2015-06-24 Evonik Industries AG Verfahren zur Herstellung von Methylmethacrylat
DE102014004170A1 (de) 2014-03-21 2015-09-24 Ceag Notlichtsysteme Gmbh Notlichtsystem und entsprechendes Verfahren
TW201627267A (zh) 2014-10-31 2016-08-01 陶氏全球科技公司 用於從氧化性酯化反應中原位水移除的方法使用經耦合的反應器-蒸餾系統
WO2016069225A1 (en) * 2014-10-31 2016-05-06 Rohm And Haas Company Oxidative esterification process for making methyl methacrylate
US10059651B2 (en) 2014-10-31 2018-08-28 Dow Global Technologies Llc Separation process
SG11201703365VA (en) 2014-10-31 2017-05-30 Dow Global Technologies Llc Process for in situ water removal from an oxidative esterification reaction using a coupled reactor-distillation system
SG11201703368QA (en) 2014-10-31 2017-05-30 Dow Global Technologies Llc Breaking a methanol/methyl methacrylate azeotrope using pressure swing distillation
CN107107034B (zh) 2015-01-16 2020-06-05 罗姆化学有限责任公司 用于将醛氧化酯化以获得羧酸酯的金基催化剂
EP3170558A1 (de) 2015-11-19 2017-05-24 Evonik Röhm GmbH Gold-basierten katalysator für die oxidative veresterung von aldehyden zu carbonsäureestern
US9822053B2 (en) * 2016-01-28 2017-11-21 Eastman Chemical Company Single step conversion of N-butyraldehyde to 2-ethylhexanal
CN106475109B (zh) * 2016-09-22 2019-02-12 中国石油大学(华东) 超高活性加氢催化剂的制备方法
CN108607550A (zh) * 2016-12-10 2018-10-02 中国科学院大连化学物理研究所 一种生产甲基丙烯酸甲酯的黄金催化剂及其应用
RU2641694C1 (ru) * 2016-12-14 2018-01-22 Акционерное общество "Федеральный научно-производственный центр "Алтай" Способ получения катализатора и способ его применения для многократного использования в промышленном процессе двухстадийного гидрогенолиза при производстве 2,4,6,8,10,12-гексанитро-2,4,6,8,10,12-гексаазатетрацикло[5,5,0,03,11,05,9]додекана
EP3630711B1 (de) 2017-05-25 2021-03-17 Rohm and Haas Company Verfahren zur herstellung von methacrolein
WO2018217961A1 (en) 2017-05-25 2018-11-29 Rohm And Haas Company Process for preparing methacrolein
KR20190001369A (ko) * 2017-06-27 2019-01-04 (주)대원인터내셔널 지방산 메틸 에스테르의 생산에 사용되는 세라믹 고체촉매의 조기 활성화를 위한 전처리 방법
CN111372910A (zh) 2017-07-28 2020-07-03 罗门哈斯公司 通过使用非均相催化剂进行氧化酯化来生产甲基丙烯酸甲酯的方法
SG11202000676UA (en) 2017-07-28 2020-02-27 Rohm & Haas Heterogeneous catalyst
US10745341B2 (en) 2017-07-28 2020-08-18 Dow Global Technologies Llc Method for production of methyl methacrylate by oxidative esterification using a heterogeneous catalyst
CN111094230B (zh) 2017-07-28 2023-04-04 罗门哈斯公司 通过使用非均相催化剂进行氧化酯化来生产甲基丙烯酸甲酯的方法
KR102639234B1 (ko) 2017-07-28 2024-02-21 다우 글로벌 테크놀로지스 엘엘씨 불균일 촉매를 사용하여 산화적 에스터화에 의해 메틸 메타크릴레이트를 제조하는 방법
EP3658534A1 (de) 2017-07-28 2020-06-03 Rohm and Haas Company Verfahren zur herstellung von methylmethacrylat durch oxidative veresterung unter verwendung eines heterogenen katalysators
WO2019022891A1 (en) 2017-07-28 2019-01-31 Rohm And Haas Company PROCESS FOR THE PRODUCTION OF METHYL METHACRYLATE BY OXIDATIVE ESTERIZATION USING A HETEROGENEOUS CATALYST
US10829434B2 (en) 2017-07-28 2020-11-10 Dow Global Technologies Llc Method for production of methyl methacrylate by oxidative esterification using a heterogeneous catalyst
MX2020001032A (es) 2017-07-28 2020-07-20 Dow Global Technologies Llc Método para producción de metacrilato de metilo por esterificación oxidativa mediante el uso de un catalizador heterogéneo.
EP3658536A1 (de) 2017-07-28 2020-06-03 Rohm and Haas Company Verfahren zur herstellung von methylmethacrylat durch oxidative veresterung unter verwendung eines heterogenen katalysators
WO2019060192A1 (en) 2017-09-19 2019-03-28 Dow Global Technologies Llc PROCESS FOR THE PRODUCTION OF METHYL METHACRYLATE BY OXIDIZING ESTERIZATION USING A HETEROGENEOUS CATALYST
EP3456704A1 (de) 2017-09-19 2019-03-20 Evonik Röhm GmbH Katalysator für die oxidative veresterung von aldehyden zu carbonsäureestern
EP3587390A1 (de) 2018-06-26 2020-01-01 Röhm GmbH Verfahren zur herstellung von mma in hohen ausbeuten
WO2020005689A1 (en) 2018-06-28 2020-01-02 Dow Global Technologies Llc Heterogeneous catalyst
KR20210022621A (ko) 2018-06-28 2021-03-03 다우 글로벌 테크놀로지스 엘엘씨 불균일 촉매
EP3608305A1 (de) 2018-08-10 2020-02-12 Röhm GmbH Verfahren zur herstellung von methacrylsäure oder methacrylsäureestern
CN109569579B (zh) * 2018-12-26 2021-10-08 淮南安信泰科技有限公司 一种凹凸棒石黏土固载氧化钨制备柠檬酸三丁酯的方法
EP3760608A1 (de) 2019-07-05 2021-01-06 Röhm GmbH Verfahren zur herstellung von alkylmethacrylaten und optional methacrylsäure
EP3798206A1 (de) 2019-09-25 2021-03-31 Röhm GmbH Verfahren zur herstellung von alkylmethacrylaten mit verbesserter wasser- und säureführung
EP3943189A1 (de) 2020-07-24 2022-01-26 Röhm GmbH Verfahren zur herstellung eines mischoxidträgers sowie dessen weitere veredlung zu einem katalysator zur herstellung von alkylmethacrylaten
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Also Published As

Publication number Publication date
TW348073B (en) 1998-12-21
DE69633753D1 (de) 2004-12-02
ATE280750T1 (de) 2004-11-15
US6040472A (en) 2000-03-21
EP0857512A1 (de) 1998-08-12
CN1184439A (zh) 1998-06-10
EP0857512B1 (de) 2004-06-23
EP0857512A4 (de) 2000-01-05
EP1361206B1 (de) 2004-10-27
KR100259743B1 (ko) 2000-07-01
KR19990014874A (ko) 1999-02-25
DE69632788T2 (de) 2005-07-14
CN1086313C (zh) 2002-06-19
DE69633753T2 (de) 2005-12-22
WO1997003751A1 (fr) 1997-02-06
USRE38283E1 (en) 2003-10-21
EP1361206A1 (de) 2003-11-12
HK1009412A1 (en) 1999-09-10
DE69632788D1 (de) 2004-07-29
MY119415A (en) 2005-05-31

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