AR109612A1 - Proceso y catalizador para preparar 1,4-butanodiol - Google Patents

Proceso y catalizador para preparar 1,4-butanodiol

Info

Publication number
AR109612A1
AR109612A1 ARP170102718A ARP170102718A AR109612A1 AR 109612 A1 AR109612 A1 AR 109612A1 AR P170102718 A ARP170102718 A AR P170102718A AR P170102718 A ARP170102718 A AR P170102718A AR 109612 A1 AR109612 A1 AR 109612A1
Authority
AR
Argentina
Prior art keywords
catalyst
butanodiol
prepare
hydroxybutanal
byd
Prior art date
Application number
ARP170102718A
Other languages
English (en)
Inventor
Poss Ren Dr
Schwarz Matthias Dr
Roos Meike Dr
Markus Gttlinger
Monika Berweiler
Original Assignee
Evonik Degussa Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Evonik Degussa Gmbh filed Critical Evonik Degussa Gmbh
Publication of AR109612A1 publication Critical patent/AR109612A1/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/14—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J25/00—Catalysts of the Raney type
    • B01J25/02—Raney nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/755—Nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/86—Chromium
    • B01J23/862—Iron and chromium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/86—Chromium
    • B01J23/866—Nickel and chromium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/31—Density
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B01J35/56—Foraminous structures having flow-through passages or channels, e.g. grids or three-dimensional monoliths
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/657—Pore diameter larger than 1000 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0018—Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0063—Granulating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/008—Details of the reactor or of the particulate material; Processes to increase or to retard the rate of reaction
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/17—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds
    • C07C29/172—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds with the obtention of a fully saturated alcohol
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/26—Chromium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/28—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/745—Iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0215—Coating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0215—Coating
    • B01J37/0217—Pretreatment of the substrate before coating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0215—Coating
    • B01J37/0225—Coating of metal substrates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C31/18—Polyhydroxylic acyclic alcohols
    • C07C31/20—Dihydroxylic alcohols
    • C07C31/207—1,4-Butanediol; 1,3-Butanediol; 1,2-Butanediol; 2,3-Butanediol

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Nanotechnology (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Se refiere a un proceso para preparar 1,4-butanodiol (BDO) por hidrogenación de 2-butino-1,4-diol (BYD) o 4-hidroxibutanal (4-HBA) en presencia de un catalizador del tipo Raney que tiene una estructura espumada porosa, en donde los poros macroscópicos tienen tamaños en el rango de 100 a 5000 mm, y una densidad aparente de hasta 0,8 kg/L.
ARP170102718A 2016-09-30 2017-09-29 Proceso y catalizador para preparar 1,4-butanodiol AR109612A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP16191735.6A EP3300799A1 (de) 2016-09-30 2016-09-30 Verfahren und katalysator zur herstellung von 1,4-butandiol

Publications (1)

Publication Number Publication Date
AR109612A1 true AR109612A1 (es) 2018-12-26

Family

ID=57042820

Family Applications (1)

Application Number Title Priority Date Filing Date
ARP170102718A AR109612A1 (es) 2016-09-30 2017-09-29 Proceso y catalizador para preparar 1,4-butanodiol

Country Status (8)

Country Link
US (1) US11260375B2 (es)
EP (2) EP3300799A1 (es)
JP (1) JP7069134B2 (es)
KR (1) KR102629663B1 (es)
CN (1) CN109789391A (es)
AR (1) AR109612A1 (es)
TW (1) TWI764937B (es)
WO (1) WO2018060269A1 (es)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3300798A1 (de) 2016-09-30 2018-04-04 Evonik Degussa GmbH Katalysatorfestbett enthaltend metallschaumkörper
US11401224B2 (en) 2018-02-14 2022-08-02 Evonik Operations Gmbh Method for the preparation of C3—C12-alcohols by catalytic hydrogenation of the corresponding aldehydes
WO2020033358A1 (en) 2018-08-08 2020-02-13 W. R. Grace & Co.-Conn. Catalysts, preparation method thereof, and selective hydrogenation processes
ES2920969T3 (es) * 2019-09-25 2022-08-12 Evonik Operations Gmbh Reactor catalítico
CN110790634B (zh) * 2019-10-14 2022-07-12 万华化学集团股份有限公司 一种1，3-丁二醇的制备方法
CN114377685B (zh) * 2020-10-22 2024-02-27 上海迅凯新材料科技有限公司 镍基催化剂、制备方法及其在加氢合成1,3-丁二醇中的应用

Family Cites Families (53)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1628190A (en) 1926-05-14 1927-05-10 Raney Murray Method of producing finely-divided nickel
US1915473A (en) 1930-12-31 1933-06-27 Raney Murray Method of preparing catalytic material
US2139602A (en) 1935-06-17 1938-12-06 Raney Murray Method of reclaiming catalytic material from spent catalytic material
US2895819A (en) * 1957-09-03 1959-07-21 Bjorksten Res Lab Inc Method for preparing a catalytic metal foam and use thereof
US2977327A (en) 1958-09-26 1961-03-28 Raney Catalyst Company Inc Process of producing nickel catalysts
US2967893A (en) 1958-12-30 1961-01-10 Gen Aniline & Film Corp Hydrogenation of 2-butyne-1, 4-diol to 1, 4-butanediol
CA922738A (en) 1969-01-31 1973-03-13 G. Low Frederick Hydrogenation of aqueous butynediol over a nickel-aluminum catalyst
US3839011A (en) * 1973-07-31 1974-10-01 Int Nickel Co Nickel-aluminum particle with improved grindability
US4049580A (en) 1976-07-23 1977-09-20 The United States Of America As Represented By The Secretary Of The Interior Method for producing supported Raney nickel catalyst
US4879420A (en) 1988-05-06 1989-11-07 E.I. Du Pont De Nemours And Company Preparation of mixtures of butanediols
US5399793A (en) 1993-11-29 1995-03-21 Exxon Chemical Patents Inc. Hydrogenation catalyst for oxo alcohol process
US5888923A (en) 1996-04-15 1999-03-30 Dairen Chemical Corporation Modified Raney nickel catalyst and a process for preparing diols by using the same
DE19641707A1 (de) * 1996-10-10 1998-04-16 Basf Ag Verfahren zur Herstellung von 1,4-Butandiol durch katalytische Hydrierung von 1,4-Butindiol
DE19933450A1 (de) * 1999-07-16 2001-01-18 Degussa Metallkatalysatoren
US6399793B1 (en) 2000-08-16 2002-06-04 Bristol-Myers Squibb Company Process for the preparation of α' chloroketones
CN1342633A (zh) * 2000-09-12 2002-04-03 上海石油化工股份有限公司 由3－羟基丙醛加氢制备1,3－丙二醇的方法
DE10101647A1 (de) * 2001-01-16 2002-07-18 Degussa Verfahren zur Herstellung von substituierten Aminen durch Hydrierung von substituierten organischen Nitroverbindungen
DE10101646A1 (de) * 2001-01-16 2002-07-18 Degussa Verfahren zur Herstellung von gesättigten organischen Verbindungen
US20030047505A1 (en) 2001-09-13 2003-03-13 Grimes Craig A. Tubular filter with branched nanoporous membrane integrated with a support and method of producing same
DE10245510A1 (de) 2002-09-27 2004-04-08 Scholz, Paul-Friedrich, Dr.-Ing. Abgasfilter für Verbrennungsmotoren und Verfahren zu seiner Herstellung
US7375053B2 (en) 2003-04-07 2008-05-20 W. R. Grace & Co.- Conn. Nickel and cobalt plated sponge catalysts
WO2005042153A1 (en) 2003-10-22 2005-05-12 Degussa Ag The use of activated granulates of base metals for organic transformations
CN100376323C (zh) * 2004-12-03 2008-03-26 中国石油化工股份有限公司 一种泡沫金属加氢催化剂及其制备方法和应用
US6969780B1 (en) 2004-12-20 2005-11-29 Lyondell Chemical Technology, L.P. Production of butanediol
DE102005042184A1 (de) * 2005-09-06 2007-03-08 Basf Ag Verfahren zur Abtrennung von polymeren Nebenprodukten aus 1,4-Butindiol
DE102005042185A1 (de) * 2005-09-06 2007-03-08 Basf Ag Verfahren zur Abtrennung von polymeren Nebenprodukten aus 1,4-Butindiol
EP1922146A1 (en) 2005-09-08 2008-05-21 Evonik Degussa GmbH The production and use of supported activated base metal catalysts for organic transformation
DE102007027837A1 (de) 2007-06-13 2008-12-18 Eads Deutschland Gmbh Verfahren zur Herstellung einer metallischen Mikrostruktur für einen Mikroreaktor
US7612241B1 (en) * 2009-03-23 2009-11-03 Lyondell Chemical Technology, L.P. Hydroformylation process
US20110011772A1 (en) 2009-07-15 2011-01-20 Stephen Raymond Schmidt Nickel and Cobalt Plated Sponge Catalysts
US20120154983A1 (en) * 2010-10-08 2012-06-21 The Regents Of The University Of California Method of Fabrication of Carbon Nanofibers on Nickel Foam
CN103339093A (zh) * 2011-01-24 2013-10-02 巴斯夫欧洲公司 在碳上包含镍的氢化催化剂
US8574340B2 (en) * 2011-02-27 2013-11-05 Board Of Trustees Of The University Of Alabama Methods for preparing and using metal and/or metal oxide porous materials
CN102949981B (zh) * 2011-08-17 2015-09-30 香港城市大学 多孔基底与一维纳米材料的复合材料及其制备方法、其表面改性的复合材料及制备方法
CN102744083B (zh) * 2012-06-26 2015-11-18 华烁科技股份有限公司 1,4-丁炔二醇加氢制1,4-丁二醇专用雷尼镍-铝-x催化剂的制备及活化方法
EP2764916B1 (en) 2013-02-06 2017-06-28 Alantum Europe GmbH Surface modified metallic foam body, process for its production and use thereof
EP2799465A1 (de) 2013-04-29 2014-11-05 Evonik Industries AG Verfahren zur Aufreinigung von Poly(arylenethern)
CN104888808B (zh) 2014-03-07 2018-08-17 中国石油化工股份有限公司 一种复合型催化剂及其制备方法
CN104945225B (zh) * 2014-03-27 2017-02-15 中国石油化工股份有限公司 一种癸烯醛加氢制备醇的方法
EP3037400B1 (de) 2014-12-23 2018-08-01 Evonik Degussa GmbH Chromfreie hydrierung von hydroformylierungsgemischen
US9943818B2 (en) * 2016-06-20 2018-04-17 Air Products And Chemicals, Inc. Steam-hydrocarbon reforming reactor
EP3515593A1 (de) 2016-09-23 2019-07-31 Basf Se Verfahren zur aktivierung eines katalysatorfestbetts, das monolithische katalysatorformkörper enthält oder aus monolithischen katalysatorformkörpern besteht
KR20190052674A (ko) 2016-09-23 2019-05-16 바스프 에스이 Co 및 일체형 촉매 성형체를 함유하는 고정 촉매 층의 존재 하에서 유기 화합물을 수소화시키는 방법
SG11201901336RA (en) 2016-09-23 2019-04-29 Basf Se Method for providing a fixed catalyst bed containing a doped structured shaped catalyst body
EP3515595A1 (de) 2016-09-23 2019-07-31 Basf Se Verfahren zur bereitstellung eines katalytisch aktiven festbetts für die hydrierung organischer verbindungen
EP3300798A1 (de) 2016-09-30 2018-04-04 Evonik Degussa GmbH Katalysatorfestbett enthaltend metallschaumkörper
DE102017202404A1 (de) 2017-02-15 2018-08-16 Evonik Degussa Gmbh Verfahren zur Herstellung von Isophoronaminoalkohol (IPAA)
US11401224B2 (en) 2018-02-14 2022-08-02 Evonik Operations Gmbh Method for the preparation of C3—C12-alcohols by catalytic hydrogenation of the corresponding aldehydes
CN114450109B (zh) 2019-09-25 2024-05-17 赢创运营有限公司 金属体及其制备方法
EP3797901B1 (de) 2019-09-25 2021-09-08 Evonik Operations GmbH Metallschaumkörper und verfahren zu seiner herstellung
ES2920969T3 (es) 2019-09-25 2022-08-12 Evonik Operations Gmbh Reactor catalítico
US20230338932A2 (en) 2019-09-25 2023-10-26 Evonik Operations Gmbh Metal-foam body and method for the production thereof and the use thereof as a catalyst
WO2021058719A1 (de) 2019-09-25 2021-04-01 Evonik Operations Gmbh Cobalthaltige metallschaumkörper und verfahren zu ihrer herstellung

Also Published As

Publication number Publication date
CN109789391A (zh) 2019-05-21
EP3519091A1 (en) 2019-08-07
US11260375B2 (en) 2022-03-01
WO2018060269A1 (en) 2018-04-05
KR102629663B1 (ko) 2024-01-25
JP2019534874A (ja) 2019-12-05
JP7069134B2 (ja) 2022-05-17
KR20190055833A (ko) 2019-05-23
TW201829361A (zh) 2018-08-16
EP3300799A1 (de) 2018-04-04
US20190232256A1 (en) 2019-08-01
TWI764937B (zh) 2022-05-21

Similar Documents

Publication Publication Date Title
AR109612A1 (es) Proceso y catalizador para preparar 1,4-butanodiol
CL2017001987A1 (es) Derivados de 1-(het)arilsulfonil-(pirrolidin o piperidin)-2-carboxamida y su uso como antagonistas de trpa1
CL2018003406A1 (es) Agonista del receptor de glucocorticoides e inmunoconjugados del mismo.
CL2016002751A1 (es) Compuestos y composiciones como agonistas del receptor tipo toll 7.
CL2019001553A1 (es) Modulador del regulador de conductancia transmembrana de fibrosis quística, composiciones farmacéuticas, métodos de tratamiento y proceso para producir el modulador.
BR112018008625A2 (pt) ?processos para preparar um produto de carbono poroso conformado e uma composição catalisadora, produto de carbono poroso conformado, e, composição catalisadora?
CL2012001422A1 (es) Compuestos derivados de sulfonil benzamidas sustituidas, inductores de apoptosis con selectividad por bcl-2; composicion farmaceutica que los comprende; y su uso para el tratamiento del cancer.
BR112018007017A2 (pt) polipeptídeos
CL2015002516A1 (es) Compuestos de 1,3-oxazin-2-amina fusionados con ciclopropilo perfluorado como inhibidores de beta-secretasa y métodos de uso
CL2016000153A1 (es) Derivados de pirrolamida sustituidos con glioxamida y su uso como medicamentos para el tratamiento de la hepatitis b
BR112015022625A2 (pt) micromatrizes para entrega de agente terapêutico e métodos de uso
DOP2015000246A (es) Derivados de oxopiridina sustituida y usos de los mismos en el tratamiento de trastornos cardiovasculares
CL2016001911A1 (es) Compuesto heterocíclico fusionado
CL2017001718A1 (es) Derivados de glucagón con estabilidad mejorada
UY34566A (es) 1,4?dihidropirimidinas 4,4?disustituidas y su uso como medicamentos para el tratamiento de la hepatitis b
CL2015002546A1 (es) Derivados 3-fenilpropilamina sustituidos para el tratamiento de enfermedades y trastornos oftálmicos
CL2016001973A1 (es) Derivados de nucleosido sustituidos con 4' -difluorometilo como inhibidores de la replicación de arn de la influenza.
GT201600091A (es) Derivados de purina 2, 6-sustituidos y su uso en el tratamiento de trastornos proliferativos
CO2017005968A2 (es) Pirazolpiridinaminas como inhibidores de mknk1 y mknk2
CL2015002897A1 (es) Inhibidores de bace1
CL2015003195A1 (es) Derivados de purina como agonistas del receptor cb2.
NI201500118A (es) Imidazopiridazinas sustituidas
CL2019001330A1 (es) Inhibidores de la tirosina quinasa de bruton.
CL2019001329A1 (es) Composiciones farmacéuticas moduladoras del receptor 7 de 5-hidroxitritpina y métodos de uso.
CL2020000869A1 (es) Enantiómeros de tiazoles sustituidos compuestos antivirales.

Legal Events

Date Code Title Description
FG Grant, registration