AR086590A1 - Compuestos de ciclohexanona y herbicidas que los comprenden - Google Patents

Compuestos de ciclohexanona y herbicidas que los comprenden

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Publication number
AR086590A1
AR086590A1 ARP120101882A ARP120101882A AR086590A1 AR 086590 A1 AR086590 A1 AR 086590A1 AR P120101882 A ARP120101882 A AR P120101882A AR P120101882 A ARP120101882 A AR P120101882A AR 086590 A1 AR086590 A1 AR 086590A1
Authority
AR
Argentina
Prior art keywords
group
alkyl
aryl
halogen atoms
different
Prior art date
Application number
ARP120101882A
Other languages
English (en)
Inventor
Yoshinobu Jin
Yosuke Nakashima
Masato Konobe
Original Assignee
Sumitomo Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sumitomo Chemical Co filed Critical Sumitomo Chemical Co
Publication of AR086590A1 publication Critical patent/AR086590A1/es

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Abstract

La presente proporciona un compuesto que tiene una excelente eficacia para controlar malezas. Un compuesto de ciclohexanona de la fórmula (1).Reivindicación 1: Un compuesto de ciclohexanona de la fórmula (1), caracterizado porque m es un número entero de 1, 2 ó 3; n es un número entero de cualquiera de 1 a 5; X representa CH2, O, NR9, S, S(O) o S(O)2; R1 representa un átomo de hidrógeno o un grupo metilo; R2 y R3 representan, de modo independiente entre sí, un átomo de hidrógeno, un grupo alquilo C1-6, un grupo haloalquilo C1-6, un grupo cicloalquilo C3-8, un grupo halocicloalquilo C3-8, un grupo (alquil C1-6)-cicloalquilo C3-8, un grupo (cicloalquil C3-8)-alquilo C1-6, un grupo (cicloalquil C3-8)-cicloalquilo C3-8, un grupo (halocicloalquil C3-8)-alquilo C1-6 o un grupo {(alquil C1-6)-cicloalquil C3-8}alquilo C1-6 o R2 y R3 se conectan entre sí para representar una cadena de alquileno C2-5 o R2 y R3 se combinan entre si para representar un grupo alquilideno C1-3 que opcionalmente tiene uno o varios átomos de halógeno (siempre que, cuando m es 2 ó 3, dos o tres R2 puedan ser iguales o diferentes entre sí y dos o tres R3 puedan ser iguales o diferentes entre sí); R4 representa un grupo arilo C6-10 o un grupo heteroarilo de cinco a seis miembros (siempre que el grupo arilo C6-10 y el grupo heteroarilo de cinco o seis miembros puedan tener uno o varios sustituyentes seleccionados del grupo que consiste en un átomo de halógeno, un grupo ciano, un grupo nitro, un grupo amino, un grupo (alquil C1-6)amino, un grupo (alquil C1-4)(alquil C1-6)amino, un grupo benzoilamino, un grupo aminocarbonilo, un grupo (alquil C1-6)aminocarbonilo, un grupo (alquil C1-6)(alquil C1-6)aminocarbonilo, un grupo pentafluorotio, un grupo alquilo C1-6, un grupo alquenilo C2-6, un grupo alquinilo C2-6, un grupo alcoxi C1-6, un grupo alquil C1-4-tio, un grupo alquenil C3-6-oxi, un grupo alquinil C3-6-oxi, un grupo arilo C6-10, un grupo aril C6-10-oxi, un grupo alquil C1-6-sulfinilo, un grupo alquil C1-6-sulfonilo, un grupo hidroxilo, un grupo (alquil C1-6)carbonilo, un grupo hidroxicarbonilo, un grupo (alcoxi C1-6)carbonilo y un grupo (aril C6-10)-alcoxi C1-6 y cuando existen dos o más sustituyentes, los sustituyentes pueden ser iguales o diferentes entre sí; y el grupo (alquil C1-6)amino, el grupo (alquil C1-6)(alquil C1-6)amino, el grupo benzoilamino, el grupo (alquil C1-6)aminocarbonilo, el grupo (alquil C1-6)(alquil C1-6)aminocarbonilo, el grupo alquilo C1-6, el grupo alquenilo C2-6, el grupo alquinilo C2-6, el grupo alcoxi C1-6, el grupo alquil C1-6-tio, el grupo alquenil C3-6-oxi, el grupo alquinil C1-6-oxi, el grupo arilo C6-10, el grupo aril C6-10-oxi, el grupo alquil C1-6-sulfinilo, el grupo alquil C1-6-sulfonilo, el grupo (alcoxi C1-6)carbonilo y el grupo (aril C6-10)-alcoxi C1-6 pueden tener, cada uno, uno o varios átomos de halógeno o grupos haloalquilo C1-3 y cuando existen dos o más átomos de halógeno o grupos haloalquilo C1-3, los átomos de halógeno o los grupos haloalquilo C1-3 pueden ser iguales o diferentes entre sí, respectivamente); G representa un átomo de hidrógeno o un resto seleccionado del grupo de fórmulas (2) {en donde L representa un átomo de oxígeno o un átomo de azufre; R5 representa un grupo alquilo C1-6, un grupo cicloalquilo C3-8, un grupo alquenilo C2-6, un grupo alquinilo C2-6, un grupo arilo C6-10, un grupo (aril C6-10)-alquilo C1-6, un grupo alcoxi C1-6, un grupo cicloalcoxi C3-8, un grupo alquenil C3-6-oxi, un grupo alquinil C3-6-oxi, un grupo aril C6-10-oxi, un grupo (aril C6-10)-alcoxi C3-6, un grupo (alquil C1-6)(alquil C1-6)amino, un grupo (alquenil C3-6)(alquenil C3-6)amino, un grupo (alquil C1-6)(aril C6-10)amino o un grupo heteroarilo de cinco a seis miembros (siempre que estos grupos puedan ser cada uno o varios átomos de halógeno y cuando existen dos o más átomos de halógeno, los átomos de halógeno pueden ser iguales o diferentes entre sí; y el grupo cicloalquilo C3-6, el grupo arilo C6-10, un resto de arilo del grupo (aril C6-10)-alquilo C1-6, un grupo cicloalcoxi C3-8, un grupo aril C6-10-oxi, un resto de arilo del grupo (aril C6-10)-alcoxi C1-6, un resto de arilo del grupo (alquil C1-6)(aril C6-10)amino y un grupo heteroarilo de cinco o seis miembros pueden tener, cada uno, uno o varios grupos alquilo C1-6 y cuando existen dos o más grupos alquilo C1-6, los grupos alquilo pueden ser iguales o diferentes entre sí); R6 representa un grupo alquilo C1-6, un grupo arilo C6-10 o un grupo (alquil C1-6)(alquil C1-6)amino (siempre que estos grupos puedan tener, cada uno, uno o varios átomos de halógeno y cuando existen dos o más átomos de halógeno, los átomos de halógeno pueden ser iguales o diferentes entre sí; y el grupo arilo C6-10 puede tener uno o varios grupos alquilo C1-6 y cuando existen dos o más grupos alquilo C1-6, los grupos alquilo puedan ser iguales o diferentes entre sí); R7 representa un átomo de hidrógeno o un grupo alquilo C1-6; W representa un grupo alcoxi C1-6, un grupo alquil C1-6-tio, un grupo alquil C1-6-sulfinilo o un grupo alquil C1-6-sulfonilo (siempre que estos grupos puedan tener, cada uno, uno o varios átomos de halógeno y cuando existen dos o más átomos de halógeno, los átomos de halógeno pueden ser iguales o diferentes entre sí)}; R9 representa un átomo de hidrógeno, un grupo alquilo C1-6, un grupo arilo C6-10, un grupo aril C6-10-tio, un grupo aril C6-10-sulfinilo, un grupo aril C6-10-sulfonilo (siempre que el grupo alquilo C1-6 pueda tener uno o varios átomos de halógeno y cuando existen dos o más átomos de halógeno, los átomos de halógeno pueden ser iguales o diferentes entre si; el grupo arilo C6-10, el grupo aril C6-10-tio, el grupo aril C6-10-sulfinilo el grupo aril C6-10-sulfonilo puede tener uno o varios sustituyentes seleccionados del grupo que consiste en un átomo de halógeno, un grupo ciano, un grupo nitro y un grupo amino); Z representa un átomo de halógeno, un grupo ciano, un grupo nitro, un grupo alquilo C1-6, un grupo alquenilo C2-6, un grupo alquinilo C2-6, un grupo alcoxi C1-6, un grupo (alquil C1-6)carbonilo, un grupo alquil C1-6-tio, un grupo aril C6-10-oxi, un grupo heteroariloxi de cinco o seis miembros, un grupo cicloalquilo C, un grupo arilo C6-10 o un grupo heteroarilo de cinco a seis miembros (siempre que el grupo alquilo C1-6, el grupo alquenilo C2-6, el grupo alquinilo C2-6, el grupo alcoxi C1-6, el grupo (alquil C1-6)carbonilo y el grupo alquil C1-6-tio pueden tener, cada uno, uno o varios átomos de halógeno y cuando existen dos o más átomos de halógeno, los átomos de halógeno pueden ser iguales o diferentes entre sí; y el grupo arilo C6-10, un grupo heteroarilo de cinco a seis miembros, grupo aril C6-10-oxi y el grupo heteroariloxi de cinco o seis miembros pueden tener, cada uno, uno o varios sustituyentes seleccionados del grupo que consiste en un átomo de halógeno, un grupo alquilo C1-6 y un grupo haloalquilo C1-6 y cuando existen dos o más sustituyentes, los sustituyentes pueden ser iguales o diferentes entre sí; y el grupo cicloalquilo C3-8 puede tener uno o varios sustituyentes seleccionados del grupo que consiste en un átomo de halógeno y un grupo alquilo C1-6 y cuando existen dos o más sustituyentes, los sustituyentes pueden ser :guales o diferentes entre si; cuando n es un número enero de 2 o más, Z puedan ser iguales o diferentes entre sí).
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