AR075596A1 - Proceso para preparar 1,2-propanodiol a partir de la hidrogenacion de glicerol - Google Patents
Proceso para preparar 1,2-propanodiol a partir de la hidrogenacion de glicerolInfo
- Publication number
- AR075596A1 AR075596A1 ARP100100534A ARP100100534A AR075596A1 AR 075596 A1 AR075596 A1 AR 075596A1 AR P100100534 A ARP100100534 A AR P100100534A AR P100100534 A ARP100100534 A AR P100100534A AR 075596 A1 AR075596 A1 AR 075596A1
- Authority
- AR
- Argentina
- Prior art keywords
- catalyst
- hydrogenation
- prepare
- propanediol
- glycerol
- Prior art date
Links
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 title abstract 7
- 238000000034 method Methods 0.000 title abstract 4
- 238000005984 hydrogenation reaction Methods 0.000 title abstract 3
- 239000003054 catalyst Substances 0.000 abstract 6
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract 3
- 239000010949 copper Substances 0.000 abstract 3
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 abstract 2
- 229910052802 copper Inorganic materials 0.000 abstract 2
- 238000002386 leaching Methods 0.000 abstract 2
- DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 abstract 2
- 235000013772 propylene glycol Nutrition 0.000 abstract 2
- 229910000838 Al alloy Inorganic materials 0.000 abstract 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 abstract 1
- 229910000881 Cu alloy Inorganic materials 0.000 abstract 1
- 229910045601 alloy Inorganic materials 0.000 abstract 1
- 239000000956 alloy Substances 0.000 abstract 1
- 229910052782 aluminium Inorganic materials 0.000 abstract 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 239000003153 chemical reaction reagent Substances 0.000 abstract 1
- 229910052804 chromium Inorganic materials 0.000 abstract 1
- 239000011651 chromium Substances 0.000 abstract 1
- 239000007791 liquid phase Substances 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 239000000725 suspension Substances 0.000 abstract 1
- 229910052723 transition metal Inorganic materials 0.000 abstract 1
- 150000003624 transition metals Chemical class 0.000 abstract 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J25/00—Catalysts of the Raney type
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
- B01J23/755—Nickel
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/80—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with zinc, cadmium or mercury
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/86—Chromium
- B01J23/868—Chromium copper and chromium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/885—Molybdenum and copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/888—Tungsten
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/889—Manganese, technetium or rhenium
- B01J23/8892—Manganese
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/889—Manganese, technetium or rhenium
- B01J23/8896—Rhenium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
- B01J23/8926—Copper and noble metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/613—10-100 m2/g
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/60—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by elimination of -OH groups, e.g. by dehydration
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Se describe un proceso para elaborar 1,2-propanodiol a partir de glicerol. El proceso comprende someter una corriente de glicerol a condiciones de hidrogenacion en presencia de un catalizador de cobre esqueletal promovido con metales de transicion para mejorar la produccion selectiva de un producto constituido por 1,2-propanodiol. Se prefiere catalizador promovido por cromo, y además, se prefiere preparar el catalizador de cobre esqueletal a partir de aleaciones de cobre y aluminio que han sido sometidas a condiciones de lixiviacion seleccionadas para alcanzar por lo menos 40% de lixiviacion del aluminio de la aleacion. Este proceso resulta especialmente ideal para llevar a cabo la hidrogenacion con mezcla de reactivos en la fase líquida. Los catalizadores que se usan en esta solicitud son especialmente adecuados para utilizar en un lecho de catalizadores fijo, pero pueden ser activados y de un tamano tal que el catalizador resulte asimismo adecuado para emplear en reacciones a base de suspensiones.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US20851409P | 2009-02-25 | 2009-02-25 |
Publications (1)
Publication Number | Publication Date |
---|---|
AR075596A1 true AR075596A1 (es) | 2011-04-20 |
Family
ID=42665854
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ARP100100534A AR075596A1 (es) | 2009-02-25 | 2010-02-24 | Proceso para preparar 1,2-propanodiol a partir de la hidrogenacion de glicerol |
Country Status (9)
Country | Link |
---|---|
US (1) | US8735635B2 (es) |
EP (1) | EP2401073A4 (es) |
CN (1) | CN102333591A (es) |
AR (1) | AR075596A1 (es) |
AU (1) | AU2010218248A1 (es) |
BR (1) | BRPI1011383B1 (es) |
CO (1) | CO6430444A2 (es) |
SG (1) | SG173818A1 (es) |
WO (1) | WO2010099078A1 (es) |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102179254A (zh) * | 2011-03-16 | 2011-09-14 | 浙江大学 | 生物柴油基粗甘油直接加氢制备1,2-丙二醇的铜-铼-镁-铝四组分催化剂及其制备方法 |
CN102166525B (zh) * | 2011-03-16 | 2014-04-30 | 浙江大学 | 生物柴油基粗甘油直接加氢制备1,2-丙二醇的铜-铑-镁-铝四组分催化剂及其制备方法 |
CN102188982A (zh) * | 2011-03-16 | 2011-09-21 | 浙江大学 | 生物柴油基粗甘油直接加氢制备1,2-丙二醇的铜-钌-镁-铝四组分催化剂及其制备方法 |
CN102603681B (zh) * | 2012-03-05 | 2014-12-03 | 中国石油大学(华东) | 一种糠醛液相催化加氢制备糠醇的方法 |
JP5928894B2 (ja) * | 2012-08-30 | 2016-06-01 | 国立大学法人大阪大学 | 多価アルコールの水素化分解用触媒、及び該触媒を使用する1,3−プロパンジオールの製造方法 |
AR095195A1 (es) | 2013-03-15 | 2015-09-30 | W R Grace & Co -Conn | Proceso para la producción selectiva de propanoles por hidrogenación de glicerol |
CA2934255C (en) | 2013-12-23 | 2022-07-19 | Archer Daniels Midland Company | Processes for producing propylene glycol |
US20190023632A1 (en) * | 2016-01-06 | 2019-01-24 | Archer Daniels Midland Company | Process for producing 1,3-butanediol and for optionally further producing (r)-3-hydroxybutyl (r)-3-hydroxybutyrate |
MX2019005618A (es) * | 2016-11-16 | 2019-08-12 | Archer Daniels Midland Co | Procedimiento para producir 1,2-propanodiol a partir de glicerol. |
CN106946763B (zh) * | 2017-04-26 | 2020-11-24 | 宿迁联盛科技股份有限公司 | 制备己二胺哌啶的方法、催化剂及其制备方法 |
CN112264044B (zh) * | 2020-11-11 | 2023-02-07 | 中国科学院宁波材料技术与工程研究所 | 一种雷尼铜催化剂及其制备方法与应用 |
Family Cites Families (32)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE524101C (de) | 1926-01-13 | 1931-05-11 | I G Farbenindustrie Akt Ges | Verfahren zur UEberfuehrung von hoeherwertigen Alkoholen in niedrigerwertige |
US1628190A (en) | 1926-05-14 | 1927-05-10 | Raney Murray | Method of producing finely-divided nickel |
US1915473A (en) | 1930-12-31 | 1933-06-27 | Raney Murray | Method of preparing catalytic material |
US2139602A (en) | 1935-06-17 | 1938-12-06 | Raney Murray | Method of reclaiming catalytic material from spent catalytic material |
US2461396A (en) | 1945-07-25 | 1949-02-08 | Raney Murray | Method of producing finely divided metals |
US2977327A (en) | 1958-09-26 | 1961-03-28 | Raney Catalyst Company Inc | Process of producing nickel catalysts |
US3839011A (en) | 1973-07-31 | 1974-10-01 | Int Nickel Co | Nickel-aluminum particle with improved grindability |
US3929673A (en) | 1974-06-28 | 1975-12-30 | Nalco Chemical Co | Method of producing a raney copper catalyst and the catalyst so made |
US3953367A (en) | 1974-06-28 | 1976-04-27 | Nalco Chemical Company | Method of producing a Raney copper catalyst and the catalyst so made |
US4175954A (en) | 1978-07-24 | 1979-11-27 | The United States Of America As Represented By The United States Department Of Energy | Self-disintegrating Raney metal alloys |
GB2208357B (en) | 1987-07-31 | 1991-04-24 | Peter Jowett | Improved raney nickel catalyst |
IT1249955B (it) * | 1991-07-10 | 1995-03-30 | Menon S R L | Procedimento di idrogenazione della glicerina |
DE4302464A1 (de) * | 1993-01-29 | 1994-08-04 | Henkel Kgaa | Herstellung von 1,2-Propandiol aus Glycerin |
EP0737101B1 (fr) | 1993-12-28 | 1998-09-23 | RHODIA FIBER & RESIN INTERMEDIATES | Procede de preparation d'un catalyseur d'hydrogenation de nitriles en amines et application de ce catalyseur en hydrogenation |
DE4442124A1 (de) * | 1994-11-26 | 1996-05-30 | Basf Ag | Verfahren zur Herstellung von Propandiol-1,2 |
JP3793267B2 (ja) | 1995-11-08 | 2006-07-05 | 東和化成工業株式会社 | ラネー触媒、その製造方法及びそれを使用した糖アルコールの製造方法 |
US6309758B1 (en) | 1999-05-06 | 2001-10-30 | W. R. Grace & Co.-Conn. | Promoted porous catalyst |
US20030120116A1 (en) | 1999-07-08 | 2003-06-26 | Daniel Ostgard | Fixed-bed Raney-type catalysts |
US6573213B1 (en) | 1999-07-16 | 2003-06-03 | Degussa Ag | Metal catalysts |
TW553772B (en) | 1999-07-31 | 2003-09-21 | Degussa | Fixed bed catalysts |
DE19936135A1 (de) | 1999-07-31 | 2001-02-15 | Degussa | Festbettkatalysatoren |
US20020038051A1 (en) | 2000-02-18 | 2002-03-28 | Degussa-Huls Ag | Raney copper |
ATE350158T1 (de) | 2000-02-18 | 2007-01-15 | Degussa | Verfahren zur herstellung von carbonsäuren durch dehydrierung von alkoholen |
EP1127613A1 (de) | 2000-02-18 | 2001-08-29 | Degussa AG | Geformter Festbettraney-Kupferkatalysator zur Verwendung bei der Dehydrierung von Alkoholen |
GB0008637D0 (en) | 2000-04-08 | 2000-05-31 | Ceram Research Ltd | Catalyst production |
JP2004526686A (ja) | 2000-12-23 | 2004-09-02 | デグサ アクチエンゲゼルシャフト | カルボニル化合物の水素化によるアルコールの製法 |
DE10101646A1 (de) | 2001-01-16 | 2002-07-18 | Degussa | Verfahren zur Herstellung von gesättigten organischen Verbindungen |
US20030040433A1 (en) | 2001-08-27 | 2003-02-27 | Case Leslie C. | Synergistic, layered, precious metal-base metal hydrogenation catalysts |
US7375053B2 (en) | 2003-04-07 | 2008-05-20 | W. R. Grace & Co.- Conn. | Nickel and cobalt plated sponge catalysts |
GB0514593D0 (en) | 2005-07-15 | 2005-08-24 | Davy Process Techn Ltd | Process |
EP1993985B1 (en) | 2006-03-03 | 2017-10-04 | Basf Se | Process for the preparation of 1,2-propanediol |
ES2402216T3 (es) | 2006-06-07 | 2013-04-29 | The Procter & Gamble Company | Procesos para convertir glicerol en aminoalcoholes |
-
2010
- 2010-02-23 SG SG2011060720A patent/SG173818A1/en unknown
- 2010-02-23 BR BRPI1011383A patent/BRPI1011383B1/pt not_active IP Right Cessation
- 2010-02-23 EP EP10746689.8A patent/EP2401073A4/en not_active Withdrawn
- 2010-02-23 AU AU2010218248A patent/AU2010218248A1/en not_active Abandoned
- 2010-02-23 US US13/203,264 patent/US8735635B2/en not_active Expired - Fee Related
- 2010-02-23 WO PCT/US2010/024977 patent/WO2010099078A1/en active Application Filing
- 2010-02-23 CN CN2010800097740A patent/CN102333591A/zh active Pending
- 2010-02-24 AR ARP100100534A patent/AR075596A1/es unknown
-
2011
- 2011-09-16 CO CO11120343A patent/CO6430444A2/es not_active Application Discontinuation
Also Published As
Publication number | Publication date |
---|---|
US8735635B2 (en) | 2014-05-27 |
BRPI1011383A2 (pt) | 2016-03-15 |
AU2010218248A1 (en) | 2011-09-01 |
SG173818A1 (en) | 2011-09-29 |
WO2010099078A1 (en) | 2010-09-02 |
EP2401073A4 (en) | 2015-11-18 |
CO6430444A2 (es) | 2012-04-30 |
CN102333591A (zh) | 2012-01-25 |
EP2401073A1 (en) | 2012-01-04 |
US20110313211A1 (en) | 2011-12-22 |
BRPI1011383B1 (pt) | 2018-05-08 |
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