AR075596A1 - Proceso para preparar 1,2-propanodiol a partir de la hidrogenacion de glicerol - Google Patents

Proceso para preparar 1,2-propanodiol a partir de la hidrogenacion de glicerol

Info

Publication number
AR075596A1
AR075596A1 ARP100100534A ARP100100534A AR075596A1 AR 075596 A1 AR075596 A1 AR 075596A1 AR P100100534 A ARP100100534 A AR P100100534A AR P100100534 A ARP100100534 A AR P100100534A AR 075596 A1 AR075596 A1 AR 075596A1
Authority
AR
Argentina
Prior art keywords
catalyst
hydrogenation
prepare
propanediol
glycerol
Prior art date
Application number
ARP100100534A
Other languages
English (en)
Original Assignee
Grace W R & Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Grace W R & Co filed Critical Grace W R & Co
Publication of AR075596A1 publication Critical patent/AR075596A1/es

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J25/00—Catalysts of the Raney type
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/755—Nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/80—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with zinc, cadmium or mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/86—Chromium
    • B01J23/868—Chromium copper and chromium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/885—Molybdenum and copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/888—Tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/889—Manganese, technetium or rhenium
    • B01J23/8892—Manganese
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/889—Manganese, technetium or rhenium
    • B01J23/8896—Rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8926—Copper and noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/613—10-100 m2/g
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/60—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by elimination of -OH groups, e.g. by dehydration

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Se describe un proceso para elaborar 1,2-propanodiol a partir de glicerol. El proceso comprende someter una corriente de glicerol a condiciones de hidrogenacion en presencia de un catalizador de cobre esqueletal promovido con metales de transicion para mejorar la produccion selectiva de un producto constituido por 1,2-propanodiol. Se prefiere catalizador promovido por cromo, y además, se prefiere preparar el catalizador de cobre esqueletal a partir de aleaciones de cobre y aluminio que han sido sometidas a condiciones de lixiviacion seleccionadas para alcanzar por lo menos 40% de lixiviacion del aluminio de la aleacion. Este proceso resulta especialmente ideal para llevar a cabo la hidrogenacion con mezcla de reactivos en la fase líquida. Los catalizadores que se usan en esta solicitud son especialmente adecuados para utilizar en un lecho de catalizadores fijo, pero pueden ser activados y de un tamano tal que el catalizador resulte asimismo adecuado para emplear en reacciones a base de suspensiones.
ARP100100534A 2009-02-25 2010-02-24 Proceso para preparar 1,2-propanodiol a partir de la hidrogenacion de glicerol AR075596A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US20851409P 2009-02-25 2009-02-25

Publications (1)

Publication Number Publication Date
AR075596A1 true AR075596A1 (es) 2011-04-20

Family

ID=42665854

Family Applications (1)

Application Number Title Priority Date Filing Date
ARP100100534A AR075596A1 (es) 2009-02-25 2010-02-24 Proceso para preparar 1,2-propanodiol a partir de la hidrogenacion de glicerol

Country Status (9)

Country Link
US (1) US8735635B2 (es)
EP (1) EP2401073A4 (es)
CN (1) CN102333591A (es)
AR (1) AR075596A1 (es)
AU (1) AU2010218248A1 (es)
BR (1) BRPI1011383B1 (es)
CO (1) CO6430444A2 (es)
SG (1) SG173818A1 (es)
WO (1) WO2010099078A1 (es)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102179254A (zh) * 2011-03-16 2011-09-14 浙江大学 生物柴油基粗甘油直接加氢制备1,2-丙二醇的铜-铼-镁-铝四组分催化剂及其制备方法
CN102166525B (zh) * 2011-03-16 2014-04-30 浙江大学 生物柴油基粗甘油直接加氢制备1,2-丙二醇的铜-铑-镁-铝四组分催化剂及其制备方法
CN102188982A (zh) * 2011-03-16 2011-09-21 浙江大学 生物柴油基粗甘油直接加氢制备1,2-丙二醇的铜-钌-镁-铝四组分催化剂及其制备方法
CN102603681B (zh) * 2012-03-05 2014-12-03 中国石油大学(华东) 一种糠醛液相催化加氢制备糠醇的方法
JP5928894B2 (ja) * 2012-08-30 2016-06-01 国立大学法人大阪大学 多価アルコールの水素化分解用触媒、及び該触媒を使用する１，３−プロパンジオールの製造方法
AR095195A1 (es) 2013-03-15 2015-09-30 W R Grace & Co -Conn Proceso para la producción selectiva de propanoles por hidrogenación de glicerol
CA2934255C (en) 2013-12-23 2022-07-19 Archer Daniels Midland Company Processes for producing propylene glycol
US20190023632A1 (en) * 2016-01-06 2019-01-24 Archer Daniels Midland Company Process for producing 1,3-butanediol and for optionally further producing (r)-3-hydroxybutyl (r)-3-hydroxybutyrate
MX2019005618A (es) * 2016-11-16 2019-08-12 Archer Daniels Midland Co Procedimiento para producir 1,2-propanodiol a partir de glicerol.
CN106946763B (zh) * 2017-04-26 2020-11-24 宿迁联盛科技股份有限公司 制备己二胺哌啶的方法、催化剂及其制备方法
CN112264044B (zh) * 2020-11-11 2023-02-07 中国科学院宁波材料技术与工程研究所 一种雷尼铜催化剂及其制备方法与应用

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ES2402216T3 (es) 2006-06-07 2013-04-29 The Procter & Gamble Company Procesos para convertir glicerol en aminoalcoholes

Also Published As

Publication number Publication date
US8735635B2 (en) 2014-05-27
BRPI1011383A2 (pt) 2016-03-15
AU2010218248A1 (en) 2011-09-01
SG173818A1 (en) 2011-09-29
WO2010099078A1 (en) 2010-09-02
EP2401073A4 (en) 2015-11-18
CO6430444A2 (es) 2012-04-30
CN102333591A (zh) 2012-01-25
EP2401073A1 (en) 2012-01-04
US20110313211A1 (en) 2011-12-22
BRPI1011383B1 (pt) 2018-05-08

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