AR032339A1 - Composiciones de moldeo de policarbonato anti-electrostaticas y resistentes a la llama , procedimiento para su preparacion, empleo de las composiciones para la fabricacion de cuerpos o piezas moldeadas, y cuerpos o piezas moldeadas - Google Patents
Composiciones de moldeo de policarbonato anti-electrostaticas y resistentes a la llama , procedimiento para su preparacion, empleo de las composiciones para la fabricacion de cuerpos o piezas moldeadas, y cuerpos o piezas moldeadasInfo
- Publication number
- AR032339A1 AR032339A1 ARP010102461A ARP010102461A AR032339A1 AR 032339 A1 AR032339 A1 AR 032339A1 AR P010102461 A ARP010102461 A AR P010102461A AR P010102461 A ARP010102461 A AR P010102461A AR 032339 A1 AR032339 A1 AR 032339A1
- Authority
- AR
- Argentina
- Prior art keywords
- compositions
- bodies
- mold
- manufacture
- optionally
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title abstract 9
- 238000000465 moulding Methods 0.000 title abstract 4
- 229920000515 polycarbonate Polymers 0.000 title abstract 3
- 239000004417 polycarbonate Substances 0.000 title abstract 3
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- 238000000034 method Methods 0.000 title 1
- 238000002360 preparation method Methods 0.000 title 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 abstract 2
- 229920000642 polymer Polymers 0.000 abstract 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 abstract 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 abstract 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 abstract 1
- 239000000654 additive Substances 0.000 abstract 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 abstract 1
- 238000005266 casting Methods 0.000 abstract 1
- 239000000460 chlorine Substances 0.000 abstract 1
- 229910052801 chlorine Inorganic materials 0.000 abstract 1
- 238000000576 coating method Methods 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- 238000002347 injection Methods 0.000 abstract 1
- 239000007924 injection Substances 0.000 abstract 1
- 229910010272 inorganic material Inorganic materials 0.000 abstract 1
- 239000011147 inorganic material Substances 0.000 abstract 1
- 239000003607 modifier Substances 0.000 abstract 1
- 239000011574 phosphorus Substances 0.000 abstract 1
- 229910052698 phosphorus Inorganic materials 0.000 abstract 1
- 229920001281 polyalkylene Polymers 0.000 abstract 1
- 229920000728 polyester Polymers 0.000 abstract 1
- 229920000098 polyolefin Polymers 0.000 abstract 1
- 239000011814 protection agent Substances 0.000 abstract 1
- 150000003254 radicals Chemical class 0.000 abstract 1
- 230000009466 transformation Effects 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
- C08L69/005—Polyester-carbonates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
- C08L27/18—Homopolymers or copolymers or tetrafluoroethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
- C08L71/02—Polyalkylene oxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L85/00—Compositions of macromolecular compounds obtained by reactions forming a linkage in the main chain of the macromolecule containing atoms other than silicon, sulfur, nitrogen, oxygen and carbon; Compositions of derivatives of such polymers
- C08L85/02—Compositions of macromolecular compounds obtained by reactions forming a linkage in the main chain of the macromolecule containing atoms other than silicon, sulfur, nitrogen, oxygen and carbon; Compositions of derivatives of such polymers containing phosphorus
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Injection Moulding Of Plastics Or The Like (AREA)
Abstract
Las composiciones de moldeo de policarbonato anti-electrostáticas y resistentes a la llama contienen policarbonato y/o poliéster carbonato, al menos un modificador de la resiliencia, al menos un agente protector contra la llama, que contiene fosforo exento de halogeno, elegido entre el grupo de ésteres oligomeros del ácido fosforico, fosfonatoaminas y fosfacenos, así como un polialquilenéter modificado opcionalmente con formadores de radicales libres a base de oxido de propileno y opcionalmente, oxido de etileno. Opcionalmente las composiciones de moldeo pueden contener además poliolefina fluorada, material inorgánico finamente dividido, otros componentes polímeros y otros aditivos polímeros usuales en el comercio. Las composiciones de moldeo exentas de cloro/bromo, tienen buenas propiedades mecánicas y térmicas, especialmente elevadas resistencias a la deformacion por el calor y resiliencias con entalla y una buena aptitud a la transformacion en el procedimiento de colada por inyeccion, con una excelente fluencia (funcion de viscosidad reducida) y una ligera tendencia a la formacion de recubrimientos sobre el molde mediante la exudacion de los componente volátiles de las composiciones de molde. La adicion de los antiestáticos de las composiciones de molde no resulta en composiciones combustibles. Las composiciones se emplean para la fabricacion de cuerpos o piezas moldeadas de cualquier tipo.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10027333A DE10027333A1 (de) | 2000-06-02 | 2000-06-02 | Flammwidrige und anti-elektrostatische Polycarbonat-Formmassen |
Publications (1)
Publication Number | Publication Date |
---|---|
AR032339A1 true AR032339A1 (es) | 2003-11-05 |
Family
ID=7644436
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ARP010102461A AR032339A1 (es) | 2000-06-02 | 2001-05-23 | Composiciones de moldeo de policarbonato anti-electrostaticas y resistentes a la llama , procedimiento para su preparacion, empleo de las composiciones para la fabricacion de cuerpos o piezas moldeadas, y cuerpos o piezas moldeadas |
Country Status (14)
Country | Link |
---|---|
US (1) | US6949596B2 (es) |
EP (1) | EP1294801B1 (es) |
JP (1) | JP2003535182A (es) |
KR (1) | KR100695843B1 (es) |
CN (1) | CN1214068C (es) |
AR (1) | AR032339A1 (es) |
AT (1) | ATE304575T1 (es) |
AU (1) | AU7842601A (es) |
BR (1) | BR0111273B1 (es) |
CA (1) | CA2410943C (es) |
DE (2) | DE10027333A1 (es) |
MX (1) | MXPA02011796A (es) |
TW (1) | TW554007B (es) |
WO (1) | WO2001092418A2 (es) |
Families Citing this family (29)
Publication number | Priority date | Publication date | Assignee | Title |
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KR100422778B1 (ko) * | 2001-09-03 | 2004-03-12 | 제일모직주식회사 | 난연성 열가소성 수지조성물 |
DE10234419A1 (de) * | 2002-07-29 | 2004-02-12 | Bayer Ag | Flammwidrige Formmassen |
WO2005012415A1 (ja) * | 2003-08-01 | 2005-02-10 | Fuji Electric Holdings Co., Ltd. | 反応性難燃剤及びそれを用いた難燃性樹脂加工品 |
JP4478428B2 (ja) * | 2003-10-07 | 2010-06-09 | 出光興産株式会社 | ポリカーボネート系樹脂組成物及び光学部品 |
US20060003154A1 (en) | 2004-06-30 | 2006-01-05 | Snowden Hue S | Extruded thermoplastic articles with enhanced surface segregation of internal melt additive |
EP1856189A4 (en) * | 2005-01-14 | 2010-12-29 | Du Pont | ANTISTATIC AGENT FOR POLYMERS |
US20090143512A1 (en) * | 2005-02-15 | 2009-06-04 | Tatsuya Masuki | Polycarbonate Resin Composition and Molded Product Produced from the Same |
KR101194557B1 (ko) | 2005-02-15 | 2012-10-25 | 미쓰비시 엔지니어링-플라스틱스 코포레이션 | 폴리카보네이트 수지 조성물 및 그의 성형품 |
KR100804173B1 (ko) * | 2006-11-23 | 2008-02-18 | 제일모직주식회사 | 난연성 열가소성 수지 조성물 |
KR100910829B1 (ko) * | 2007-03-30 | 2009-08-06 | 제일모직주식회사 | 난연성 공중합체 및 이를 이용한 난연성 열가소성 수지조성물 |
US7999041B2 (en) * | 2007-05-07 | 2011-08-16 | Sabic Innovative Plastics Ip B.V. | Neutral static polycarbonates, methods of making, and articles formed therefrom |
CN101434743B (zh) * | 2007-11-14 | 2013-08-14 | 帝人化成株式会社 | 抗静电性优异的阻燃性聚碳酸酯树脂组合物 |
DE102008016260A1 (de) * | 2008-03-29 | 2009-10-01 | Bayer Materialscience Ag | Schlagzähmodifizierte Polyalkylenterephthalat/Polycarbonat-Zusammensetzungen |
DE102008062945A1 (de) * | 2008-12-23 | 2010-06-24 | Bayer Materialscience Ag | Flammgeschützte schlagzähmodifizierte Polycarbonat-Zusammensetzungen |
KR100944681B1 (ko) * | 2009-06-18 | 2010-02-26 | 제일모직주식회사 | 난연성 공중합체 및 이를 이용한 난연성 열가소성 수지 조성물 |
JP5587655B2 (ja) * | 2010-04-06 | 2014-09-10 | 帝人株式会社 | 難燃性樹脂組成物 |
KR101312785B1 (ko) * | 2010-05-10 | 2013-09-27 | 박상규 | 광물을 이용한 무기질 난연제의 제조방법 및 그 난연제 |
US9018286B2 (en) | 2012-05-24 | 2015-04-28 | Sabic Global Technologies B.V. | Flame retardant polycarbonate compositions, methods of manufacture thereof and articles comprising the same |
US9023922B2 (en) | 2012-05-24 | 2015-05-05 | Sabic Global Technologies B.V. | Flame retardant compositions, articles comprising the same and methods of manufacture thereof |
WO2014086769A1 (de) * | 2012-12-07 | 2014-06-12 | Bayer Materialscience Ag | Flammgeschützte polycarbonatformmassen iv |
US20140206800A1 (en) | 2013-01-22 | 2014-07-24 | Sabic Innovative Plastics Ip B.V. | Thermoplastic Compositions Containing Nanoscale-Sized Particle Additives For Laser Direct Structuring And Methods For The Manufacture And Use Thereof |
US20150080515A1 (en) * | 2013-09-13 | 2015-03-19 | Sabic Innovative Plastics Ip B.V. | Mineral reinforced thermoplastic polymer compositions with improved properties |
CN106459464B (zh) * | 2014-04-17 | 2019-04-30 | 益瑞石滑石欧洲公司 | 包含无机粒状填料的聚合物类泡沫组合物 |
JP6063101B1 (ja) * | 2015-03-26 | 2017-01-18 | 住化スタイロンポリカーボネート株式会社 | ポリカーボネート樹脂組成物および光学用成形品 |
JP6444008B2 (ja) * | 2015-11-11 | 2018-12-26 | エルジー・ケム・リミテッド | 熱可塑性樹脂組成物及びそれを含む成形品 |
CN106009587A (zh) * | 2016-06-14 | 2016-10-12 | 江苏金发科技新材料有限公司 | 高cti值高耐热性聚碳酸酯组合物及其制备方法 |
CN112625419A (zh) * | 2020-12-17 | 2021-04-09 | 重庆科聚孚工程塑料有限责任公司 | 高耐热无卤阻燃永久抗静电pc/abs复合材料、其制备方法、其制品及制品的制备方法 |
CN114988424B (zh) * | 2022-04-28 | 2023-11-14 | 安徽壹石通材料科技股份有限公司 | 一种掺杂偏硼酸锌及其制备方法、阻燃复合物和阻燃树脂 |
WO2024055232A1 (en) * | 2022-09-15 | 2024-03-21 | Polyone Management (Shanghai) Co. Ltd. | Polycarbonate-based compositions and laser-welded articles including same |
Family Cites Families (28)
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US563560A (en) * | 1896-07-07 | Island | ||
FR1239902A (fr) | 1955-09-02 | 1960-09-02 | Résines synthétiques de moulage et additifs antiélectrostatiques y relatifs | |
DE1297341B (de) | 1961-10-31 | 1969-06-12 | Huels Chemische Werke Ag | Antielektrostatischmachen von Polymeren |
DE1244398B (de) * | 1963-07-11 | 1967-07-13 | Bayer Ag | Antistatische thermoplastische Formmassen |
DE3331158A1 (de) | 1983-08-30 | 1985-03-14 | Basf Ag, 6700 Ludwigshafen | Thermoplastische formmasse |
DE3704488A1 (de) * | 1987-02-13 | 1988-08-25 | Bayer Ag | Antistatische, thermoplastische formmassen auf basis von polycarbonaten und vinylaromatpolymerisaten |
DE3727250A1 (de) | 1987-04-17 | 1988-11-03 | Bayer Ag | Flammwidrige, antistatische polycarbonatformmassen |
ES2031948T3 (es) * | 1987-04-17 | 1993-01-01 | Bayer Ag | Masas de moldeo de policarbonato antiestaticas ignifugas. |
DE3819081A1 (de) * | 1988-06-04 | 1989-12-07 | Bayer Ag | Flammwidrige, schlagzaehe polycarbonat-formmassen |
US5204394A (en) | 1988-09-22 | 1993-04-20 | General Electric Company | Polymer mixture having aromatic polycarbonate, styrene I containing copolymer and/or graft polymer and a flame-retardant, articles formed therefrom |
DE4328656A1 (de) * | 1993-08-26 | 1995-03-02 | Bayer Ag | Flammwidrige, spannungsrißbeständige Polycarbonat-ABS-Formmassen |
TW377367B (en) * | 1994-06-21 | 1999-12-21 | Asahi Kasei Corp | Aromatic polycarbonate-styrene polymer resin composition |
EP0695785B1 (de) * | 1994-08-01 | 1998-05-20 | Bayer Ag | Mischungen aus Polycarbonat, phenolisch hydroxyfunktionellen verzweigten Dimerfettsäurepolyestern und gegebenenfalls Pfropfpolymerisat |
DE4429319A1 (de) * | 1994-08-18 | 1996-02-22 | Bayer Ag | Flammgeschützte thermoplastische Polycarbonat-Formmassen |
US5952408A (en) * | 1994-12-01 | 1999-09-14 | Cheil Industries, Inc. | Flameproof thermoplastic resin compositions |
DE69628613T2 (de) * | 1995-07-12 | 2004-04-29 | Mitsubishi Engineering-Plastics Corp. | Polycarbonatharzzusammensetzung |
US6066686A (en) | 1996-07-05 | 2000-05-23 | Daicel Chemical Industries, Ltd. | Polycarbonate compositions |
DE19530200A1 (de) * | 1995-08-17 | 1997-02-20 | Bayer Ag | Feinstteilige anorganische Pulver als Flammschutzmittel in thermoplastischen Formmassen |
DE19713508A1 (de) * | 1997-04-01 | 1998-10-08 | Bayer Ag | Polycarbonat/Pfropfpolymerisat-Formmassen mit reduzierter Belagsbildung |
US6194497B1 (en) * | 1997-07-23 | 2001-02-27 | General Electric Company | Anti-static resin composition containing fluorinated phosphonium sulfonates |
EP0893476A1 (en) | 1997-07-23 | 1999-01-27 | Daicel Chemical Industries, Ltd. | Thermoplastic resin composition |
DE19734661A1 (de) * | 1997-08-11 | 1999-02-18 | Bayer Ag | Flammwidrige, spannungsrißbeständige Polycarbonat ABS-Formmassen |
GB9719929D0 (en) * | 1997-09-18 | 1997-11-19 | Kobe Steel Europ Ltd | Flame retardant polycarbonate-styrene(or acrylate)polymers,and/or copolymers and/or graft polymer/copolymer mixtures |
DE19817993A1 (de) | 1998-04-22 | 1999-10-28 | Basf Ag | Thermoplastische Formmasse mit hoher Durchstoßfestigkeit und gutem antistatischem Verhalten |
DE19828541A1 (de) * | 1998-06-26 | 1999-12-30 | Bayer Ag | Flammwidrige Polycarbonat-ABS-Formmassen |
JP3432426B2 (ja) * | 1998-08-13 | 2003-08-04 | 出光石油化学株式会社 | 難燃性ポリカーボネート樹脂組成物および射出成形品 |
DE19941824A1 (de) | 1999-09-02 | 2001-03-08 | Bayer Ag | Flammwidrige Polycarbonat-Blends |
DE19959410A1 (de) * | 1999-12-09 | 2001-06-13 | Basf Ag | Füllstoffhaltige thermoplastische Formmassen auf Basis von Polycarbonat und Styrolcopolymeren |
-
2000
- 2000-06-02 DE DE10027333A patent/DE10027333A1/de not_active Withdrawn
-
2001
- 2001-05-21 MX MXPA02011796A patent/MXPA02011796A/es active IP Right Grant
- 2001-05-21 BR BRPI0111273-2A patent/BR0111273B1/pt not_active IP Right Cessation
- 2001-05-21 CA CA2410943A patent/CA2410943C/en not_active Expired - Fee Related
- 2001-05-21 DE DE50107433T patent/DE50107433D1/de not_active Expired - Lifetime
- 2001-05-21 CN CNB018105602A patent/CN1214068C/zh not_active Expired - Fee Related
- 2001-05-21 KR KR1020027016370A patent/KR100695843B1/ko active IP Right Grant
- 2001-05-21 AU AU78426/01A patent/AU7842601A/en not_active Abandoned
- 2001-05-21 US US10/296,687 patent/US6949596B2/en not_active Expired - Lifetime
- 2001-05-21 EP EP01956439A patent/EP1294801B1/de not_active Expired - Lifetime
- 2001-05-21 JP JP2002500616A patent/JP2003535182A/ja active Pending
- 2001-05-21 WO PCT/EP2001/005779 patent/WO2001092418A2/de active IP Right Grant
- 2001-05-21 AT AT01956439T patent/ATE304575T1/de not_active IP Right Cessation
- 2001-05-23 AR ARP010102461A patent/AR032339A1/es unknown
- 2001-05-25 TW TW090112563A patent/TW554007B/zh not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
AU7842601A (en) | 2001-12-11 |
KR20030007826A (ko) | 2003-01-23 |
CN1214068C (zh) | 2005-08-10 |
CN1432043A (zh) | 2003-07-23 |
WO2001092418A3 (de) | 2002-03-28 |
EP1294801B1 (de) | 2005-09-14 |
DE10027333A1 (de) | 2001-12-06 |
JP2003535182A (ja) | 2003-11-25 |
WO2001092418A2 (de) | 2001-12-06 |
KR100695843B1 (ko) | 2007-03-19 |
DE50107433D1 (de) | 2005-10-20 |
CA2410943A1 (en) | 2002-11-29 |
MXPA02011796A (es) | 2003-05-14 |
US20030171472A1 (en) | 2003-09-11 |
CA2410943C (en) | 2010-02-16 |
ATE304575T1 (de) | 2005-09-15 |
EP1294801A2 (de) | 2003-03-26 |
BR0111273A (pt) | 2003-06-10 |
TW554007B (en) | 2003-09-21 |
US6949596B2 (en) | 2005-09-27 |
BR0111273B1 (pt) | 2010-11-30 |
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