AR001084A1 - Procedimiento para la producción de un material estructurado pigmentario - Google Patents

Procedimiento para la producción de un material estructurado pigmentario

Info

Publication number
AR001084A1
AR001084A1 AR33538696A AR33538696A AR001084A1 AR 001084 A1 AR001084 A1 AR 001084A1 AR 33538696 A AR33538696 A AR 33538696A AR 33538696 A AR33538696 A AR 33538696A AR 001084 A1 AR001084 A1 AR 001084A1
Authority
AR
Argentina
Prior art keywords
particles
weight
anionic
inorganic pigment
pvc
Prior art date
Application number
AR33538696A
Other languages
English (en)
Original Assignee
Tioxide Group Services Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tioxide Group Services Ltd filed Critical Tioxide Group Services Ltd
Publication of AR001084A1 publication Critical patent/AR001084A1/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/66—Additives characterised by particle size
    • C09D7/67—Particle size smaller than 100 nm
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/0081—Composite particulate pigments or fillers, i.e. containing at least two solid phases, except those consisting of coated particles of one compound
    • C09C1/0084—Composite particulate pigments or fillers, i.e. containing at least two solid phases, except those consisting of coated particles of one compound containing titanium dioxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
    • C08K3/013—Fillers, pigments or reinforcing additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00—Use of pretreated ingredients
    • C08K9/02—Ingredients treated with inorganic substances
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06—Homopolymers or copolymers of vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L31/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid; Compositions of derivatives of such polymers
    • C08L31/02—Homopolymers or copolymers of esters of monocarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/0081—Composite particulate pigments or fillers, i.e. containing at least two solid phases, except those consisting of coated particles of one compound
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
    • C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D127/04—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C09D127/06—Homopolymers or copolymers of vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/45—Anti-settling agents
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/65—Additives macromolecular
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/66—Additives characterised by particle size
    • C09D7/68—Particle size between 100-1000 nm
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/60—Compounds characterised by their crystallite size
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/62—Submicrometer sized, i.e. from 0.1-1 micrometer
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/64—Nanometer sized, i.e. from 1-100 nanometer
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/80—Particles consisting of a mixture of two or more inorganic phases
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/80—Particles consisting of a mixture of two or more inorganic phases
    • C01P2004/82—Particles consisting of a mixture of two or more inorganic phases two phases having the same anion, e.g. both oxidic phases
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/80—Particles consisting of a mixture of two or more inorganic phases
    • C01P2004/82—Particles consisting of a mixture of two or more inorganic phases two phases having the same anion, e.g. both oxidic phases
    • C01P2004/84—Particles consisting of a mixture of two or more inorganic phases two phases having the same anion, e.g. both oxidic phases one phase coated with the other
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/60—Optical properties, e.g. expressed in CIELAB-values

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Nanotechnology (AREA)
  • Polymers & Plastics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Composite Materials (AREA)
  • Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • General Physics & Mathematics (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Pigments, Carbon Blacks, Or Wood Stains (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Paints Or Removers (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)

Abstract

Procedimiento para la producción de un material estructurado pigmentario en forma de una dispersión que comprende la mezcla de una dispersión acuosa departículas inorgánicas pigmentarias y una dispersión acuosa de partículas de polivinilcloruro.L as partículas de pigmento inorgánicas portan una carga desuperficie positiva y las partículas de polivinil cloruro portan una carga de superficie negativa y las partículas en el compuesto son mantenidas enasociación como un resultado de dichascarg as. Las partículas de pigmento inorgánico y las partículas de PVC son mezcladas en la presencia de unsistema tensioactivo el cual provee tanto una estabilización espacial, es decir en lo que hace a la disposición de los átomos comoaniónica. En una realizaciónel sitema tensioactivo comprende un agente tensioactivo no iónico que presenta un valor de HLB mayor a 12 y al menos 2% en peso de un agente tensioactivoaniónico con respecto al peso de las partículas de PVC. En unasegunda realización el sistema tensioactivo comprende al menos un 2% en peso (conrespecto al PVC) de uno o más agentes tensioactivos proveyendo una estabilización espacial y aniónica y siendo los productos de condensación deóxido deetileno aqué llos que presentan una cadena de polioxietileno con una longitud promedio de al menos 8 unidades de oxietileno. El producto es útil enpinturas y provee una opacidad mejorada comparada con los pigmentos convencionales y unbrillo mejora do comparado con los pigmentos compuestosestructurados ya conocidos.
AR33538696A 1995-02-16 1996-02-13 Procedimiento para la producción de un material estructurado pigmentario AR001084A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GBGB9502982.3A GB9502982D0 (en) 1995-02-16 1995-02-16 Composite pigmentary material

Publications (1)

Publication Number Publication Date
AR001084A1 true AR001084A1 (es) 1997-09-24

Family

ID=10769665

Family Applications (1)

Application Number Title Priority Date Filing Date
AR33538696A AR001084A1 (es) 1995-02-16 1996-02-13 Procedimiento para la producción de un material estructurado pigmentario

Country Status (20)

Country Link
US (1) US5643974A (es)
EP (1) EP0727466B1 (es)
JP (1) JPH08239592A (es)
KR (1) KR960031554A (es)
CN (1) CN1134441A (es)
AR (1) AR001084A1 (es)
AT (1) ATE181095T1 (es)
AU (1) AU692339B2 (es)
BR (1) BR9600386A (es)
CA (1) CA2167628A1 (es)
DE (1) DE69602775T2 (es)
DK (1) DK0727466T3 (es)
ES (1) ES2132839T3 (es)
FI (1) FI960679A7 (es)
GB (1) GB9502982D0 (es)
GR (1) GR3030885T3 (es)
MX (1) MX9600599A (es)
MY (1) MY132168A (es)
NO (1) NO960576L (es)
ZA (1) ZA961240B (es)

Families Citing this family (19)

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Publication number Priority date Publication date Assignee Title
KR970061942A (ko) * 1996-02-09 1997-09-12 무또 미노루 복합 입자 수성 현탁액 및 이의 제조 방법
WO1998001392A1 (fr) * 1996-07-08 1998-01-15 Rhodia Chimie Particules de dioxyde de titane, leur procede de preparation et leur utilisation dans les cosmetiques, vernis et lasures
EP1019454B1 (en) * 1997-01-09 2001-11-07 Ciba SC Holding AG Composite pigment
DE19811791A1 (de) * 1998-03-18 1999-09-23 Borchers Gmbh Wäßrige Dispersionen mit einer speziellen Dispergiermittelkombination
AU782594B2 (en) 2000-11-21 2005-08-11 Rohm And Haas Company Polymer-pigment composites
US6544328B2 (en) * 2001-01-26 2003-04-08 Kerr-Mcgee Chemical Llc Process for preparing pigment dispersible in paints and plastics concentrates
US8822569B2 (en) * 2001-06-20 2014-09-02 Rohm And Haas Company Composite particles
AU785282B2 (en) * 2001-06-20 2006-12-21 Rohm And Haas Company Coating with improved hiding, compositions prepared therewith, and processes for the preparation thereof
ATE408656T1 (de) * 2002-06-12 2008-10-15 Sherwin Williams Co Beschichtungszusammensetzung enthaltend polyvinylchlorid füllstoffteilchen
US7179531B2 (en) * 2002-09-12 2007-02-20 Rohm And Haas Company Polymer particles having select pendant groups and composition prepared therefrom
JP2009503204A (ja) * 2005-08-02 2009-01-29 トプヒム・ナムローゼ・フェンノートシャップ 有機顔料粒子又は無機顔料粒子と有機ナノ粒子とから成るハイブリッド粒子の水性分散液、並びにその製造方法
DE102006034240A1 (de) * 2006-07-25 2008-01-31 Clariant International Limited Mit polymerisierbarem Coating modifizierte Pigmente, deren Herstellung und Anwendung
FR2991990B1 (fr) * 2012-06-15 2015-05-15 Oreal Pigment organique enrobe et composition cosmetique
FR3001222B1 (fr) * 2013-01-24 2016-01-22 Arkema France Composition composite de polymere halogene, son procede de preparation et son utilisation
PT3022251T (pt) 2013-07-15 2019-06-14 Ineos Norge Holdings As Compósito e métodos de produção
AU2015349606B2 (en) * 2014-11-21 2016-11-17 Buckley, Patrick John Apparatus for securing a vehicle flag device
KR101746166B1 (ko) 2015-03-05 2017-06-13 경일대학교산학협력단 한방약재와 천연염료의 복합염색 방법 및 이를 이용하여 염색한 직물
US9790379B2 (en) 2016-03-16 2017-10-17 The Sherwin-Williams Company Opacifying clusters for use in paint compositions
US10703928B2 (en) 2016-04-04 2020-07-07 Rohm And Haas Company Aqueous coating compositions having low or zero VOCs and comprising encapsulated or polymer adsorbed pigments and letdown binders

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JPS6151061A (ja) * 1984-08-21 1986-03-13 Nippon Steel Chem Co Ltd 導電性樹脂成型材料及びその製造方法
US4912139A (en) * 1987-03-19 1990-03-27 Pierce & Stevens Corporation Preparation of opacifier intermediates
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US4898894A (en) * 1987-03-19 1990-02-06 Pierce & Stevens Corporation Film forming binders containing low density composite opacifiers
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US5011862A (en) * 1988-07-29 1991-04-30 Pierce & Stevens Corporation Coating media containing low density composite opacifiers
FR2650514B1 (fr) * 1989-08-04 1991-11-22 Lvmh Rech Procede de fabrication de poudres ordonnees par pulverisation a partir d'au moins deux populations de particules, et poudres ordonnees ainsi obtenues
US5152835A (en) * 1991-05-08 1992-10-06 Engelhard Corporation Composite titania-calcined kaolin opacifying pigments and method for making and using same
US5385960A (en) * 1991-12-03 1995-01-31 Rohm And Haas Company Process for controlling adsorption of polymeric latex on titanium dioxide
JP3535156B2 (ja) * 1991-12-03 2004-06-07 ローム アンド ハース カンパニー 粒子吸着方法
WO1993012183A1 (en) * 1991-12-03 1993-06-24 Rohm And Haas Company Aqueous dispersion of composite particles including polymeric latex
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JPH05163454A (ja) * 1991-12-16 1993-06-29 Mitsui Toatsu Chem Inc 水性顔料インキ組成物
GB9127293D0 (en) * 1991-12-23 1992-02-19 Ici Plc Coating pigment particles with polymers
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GB9211822D0 (en) * 1992-06-04 1992-07-15 Tioxide Group Services Ltd Composite pigmentary material
GB2267503B (en) 1992-06-04 1996-07-24 Tioxide Group Services Ltd Composite pigmentary material comprising particles of opposite surface charge

Also Published As

Publication number Publication date
MY132168A (en) 2007-09-28
JPH08239592A (ja) 1996-09-17
ZA961240B (en) 1996-08-27
CN1134441A (zh) 1996-10-30
AU4228196A (en) 1996-08-22
EP0727466A1 (en) 1996-08-21
AU692339B2 (en) 1998-06-04
GR3030885T3 (en) 1999-11-30
DE69602775T2 (de) 1999-10-07
FI960679A0 (fi) 1996-02-15
NO960576D0 (no) 1996-02-14
KR960031554A (ko) 1996-09-17
DK0727466T3 (da) 1999-11-15
ATE181095T1 (de) 1999-06-15
GB9502982D0 (en) 1995-04-05
DE69602775D1 (de) 1999-07-15
FI960679A7 (fi) 1996-08-17
US5643974A (en) 1997-07-01
EP0727466B1 (en) 1999-06-09
ES2132839T3 (es) 1999-08-16
CA2167628A1 (en) 1996-08-17
NO960576L (no) 1996-08-19
BR9600386A (pt) 1999-10-13
MX9600599A (es) 1997-02-28

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