MX9600599A - Material colorante compuesto. - Google Patents

Material colorante compuesto.

Info

Publication number
MX9600599A
MX9600599A MX9600599A MX9600599A MX9600599A MX 9600599 A MX9600599 A MX 9600599A MX 9600599 A MX9600599 A MX 9600599A MX 9600599 A MX9600599 A MX 9600599A MX 9600599 A MX9600599 A MX 9600599A
Authority
MX
Mexico
Prior art keywords
aqueous dispersion
polyvinyl chloride
surface charge
mixing
particulate
Prior art date
Application number
MX9600599A
Other languages
English (en)
Inventor
Leslie Ainsley Simpson
Keith Robson
David Trevor Knight
Martin Alec Williamson
Original Assignee
Tioxide Group Services Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tioxide Group Services Ltd filed Critical Tioxide Group Services Ltd
Publication of MX9600599A publication Critical patent/MX9600599A/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/66—Additives characterised by particle size
    • C09D7/67—Particle size smaller than 100 nm
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/0081—Composite particulate pigments or fillers, i.e. containing at least two solid phases, except those consisting of coated particles of one compound
    • C09C1/0084—Composite particulate pigments or fillers, i.e. containing at least two solid phases, except those consisting of coated particles of one compound containing titanium dioxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
    • C08K3/013—Fillers, pigments or reinforcing additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00—Use of pretreated ingredients
    • C08K9/02—Ingredients treated with inorganic substances
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06—Homopolymers or copolymers of vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L31/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid; Compositions of derivatives of such polymers
    • C08L31/02—Homopolymers or copolymers of esters of monocarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/0081—Composite particulate pigments or fillers, i.e. containing at least two solid phases, except those consisting of coated particles of one compound
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
    • C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D127/04—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C09D127/06—Homopolymers or copolymers of vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/45—Anti-settling agents
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/65—Additives macromolecular
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/66—Additives characterised by particle size
    • C09D7/68—Particle size between 100-1000 nm
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/60—Compounds characterised by their crystallite size
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/62—Submicrometer sized, i.e. from 0.1-1 micrometer
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/64—Nanometer sized, i.e. from 1-100 nanometer
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/80—Particles consisting of a mixture of two or more inorganic phases
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/80—Particles consisting of a mixture of two or more inorganic phases
    • C01P2004/82—Particles consisting of a mixture of two or more inorganic phases two phases having the same anion, e.g. both oxidic phases
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/80—Particles consisting of a mixture of two or more inorganic phases
    • C01P2004/82—Particles consisting of a mixture of two or more inorganic phases two phases having the same anion, e.g. both oxidic phases
    • C01P2004/84—Particles consisting of a mixture of two or more inorganic phases two phases having the same anion, e.g. both oxidic phases one phase coated with the other
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/60—Optical properties, e.g. expressed in CIELAB-values

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Nanotechnology (AREA)
  • Polymers & Plastics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Composite Materials (AREA)
  • Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • General Physics & Mathematics (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Pigments, Carbon Blacks, Or Wood Stains (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Paints Or Removers (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)

Abstract

Un procedimiento para la produccion de un material colorante compuesto estructurado en la forma de una dispersion que comprende, mezclar una dispersion acuosa de las partículas colorantes inorgánicas y una dispersion acuosa de las partículas de cloruro de polivinilo (PVC). Las partículas del pigmento inorgánico tienen una carga de superficie positiva y las partículas de PVC tienen una carga de superficie negativa y las partículas en el compuesto se sujetan en asociacion como resultado de estas cargas. Las partículas del pigmento inorgánicas y las partículas del PVC se mezclan en presencia de un sistema de surfactante, el cual proporciona ambas estabilizaciones anionicas y estéricas. En una modalidad, el sistema de surfactante comprende un surfactante no ionico que tiene un valor de HLB más grande que 12 y al menos 2% en peso de un surfactante anionico con relacion al peso de las partículas de PVC. En una segunda modalidad, el sistema surfactante comprende al menos 2% en peso (con relacion al PVC) de uno, o de más surfactantes que proporcionan la estabilizacion anionica y estérica, y que son los productos de condensacion del oxido de etileno, que tienen una cadena de polioxietileno con una longitud promedio de al menos 8 unidades de oxietileno. El producto es util en pinturas y proporciona una opacidad mejorada a los pigmentos convencionales y al brillo mejorado comparado a los pigmentos compuestos estructurados conocidos.
MX9600599A 1995-02-16 1996-02-15 Material colorante compuesto. MX9600599A (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GBGB9502982.3A GB9502982D0 (en) 1995-02-16 1995-02-16 Composite pigmentary material

Publications (1)

Publication Number Publication Date
MX9600599A true MX9600599A (es) 1997-02-28

Family

ID=10769665

Family Applications (1)

Application Number Title Priority Date Filing Date
MX9600599A MX9600599A (es) 1995-02-16 1996-02-15 Material colorante compuesto.

Country Status (20)

Country Link
US (1) US5643974A (es)
EP (1) EP0727466B1 (es)
JP (1) JPH08239592A (es)
KR (1) KR960031554A (es)
CN (1) CN1134441A (es)
AR (1) AR001084A1 (es)
AT (1) ATE181095T1 (es)
AU (1) AU692339B2 (es)
BR (1) BR9600386A (es)
CA (1) CA2167628A1 (es)
DE (1) DE69602775T2 (es)
DK (1) DK0727466T3 (es)
ES (1) ES2132839T3 (es)
FI (1) FI960679A (es)
GB (1) GB9502982D0 (es)
GR (1) GR3030885T3 (es)
MX (1) MX9600599A (es)
MY (1) MY132168A (es)
NO (1) NO960576L (es)
ZA (1) ZA961240B (es)

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR970061942A (ko) * 1996-02-09 1997-09-12 무또 미노루 복합 입자 수성 현탁액 및 이의 제조 방법
DE69707461T2 (de) * 1996-07-08 2002-05-23 Rhone Poulenc Chimie Titandioxidteilchen, ihr herstellungsverfahren und ihre verwendung in kosmetika und lacken
DE69802430T2 (de) * 1997-01-09 2002-07-18 Ciba Sc Holding Ag Kompositpigment
DE19811791A1 (de) * 1998-03-18 1999-09-23 Borchers Gmbh Wäßrige Dispersionen mit einer speziellen Dispergiermittelkombination
AU782594B2 (en) 2000-11-21 2005-08-11 Rohm And Haas Company Polymer-pigment composites
US6544328B2 (en) * 2001-01-26 2003-04-08 Kerr-Mcgee Chemical Llc Process for preparing pigment dispersible in paints and plastics concentrates
AU785282B2 (en) * 2001-06-20 2006-12-21 Rohm And Haas Company Coating with improved hiding, compositions prepared therewith, and processes for the preparation thereof
US8822569B2 (en) * 2001-06-20 2014-09-02 Rohm And Haas Company Composite particles
BR0311773B1 (pt) * 2002-06-12 2014-08-26 Sherwin Williams Co Composições de tinta, de tinta transportada em água e de revestimento transportada em água, tendo partículas diluentes de cloreto de polivinila, e processo de revestimento de um substrato
US7179531B2 (en) * 2002-09-12 2007-02-20 Rohm And Haas Company Polymer particles having select pendant groups and composition prepared therefrom
CA2617231A1 (en) * 2005-08-02 2007-02-08 Topchim N.V. Aqueous dispersion of hybrid particles consisting of organic or inorganic pigment particles and organic nano-particles and process for preparing the same
DE102006034240A1 (de) * 2006-07-25 2008-01-31 Clariant International Limited Mit polymerisierbarem Coating modifizierte Pigmente, deren Herstellung und Anwendung
FR2991990B1 (fr) * 2012-06-15 2015-05-15 Oreal Pigment organique enrobe et composition cosmetique
FR3001222B1 (fr) * 2013-01-24 2016-01-22 Arkema France Composition composite de polymere halogene, son procede de preparation et son utilisation
PT3022251T (pt) * 2013-07-15 2019-06-14 Ineos Norge Holdings As Compósito e métodos de produção
AU2015349606B2 (en) * 2014-11-21 2016-11-17 Buckley, Patrick John Apparatus for securing a vehicle flag device
KR101746166B1 (ko) 2015-03-05 2017-06-13 경일대학교산학협력단 한방약재와 천연염료의 복합염색 방법 및 이를 이용하여 염색한 직물
AU2017232631B2 (en) 2016-03-16 2020-02-06 The Sherwin-Williams Company Opacifying clusters for use in paint compositions
US10703928B2 (en) 2016-04-04 2020-07-07 Rohm And Haas Company Aqueous coating compositions having low or zero VOCs and comprising encapsulated or polymer adsorbed pigments and letdown binders

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JPS6151061A (ja) * 1984-08-21 1986-03-13 Nippon Steel Chem Co Ltd 導電性樹脂成型材料及びその製造方法
US4912139A (en) * 1987-03-19 1990-03-27 Pierce & Stevens Corporation Preparation of opacifier intermediates
US4898894A (en) * 1987-03-19 1990-02-06 Pierce & Stevens Corporation Film forming binders containing low density composite opacifiers
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US5011862A (en) * 1988-07-29 1991-04-30 Pierce & Stevens Corporation Coating media containing low density composite opacifiers
FR2650514B1 (fr) * 1989-08-04 1991-11-22 Lvmh Rech Procede de fabrication de poudres ordonnees par pulverisation a partir d'au moins deux populations de particules, et poudres ordonnees ainsi obtenues
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DE69219149T2 (de) * 1991-12-03 1997-10-02 Rohm & Haas Wässrige dispersion aus komposit-teilchen enthaltende polymerischen latex
US5663224A (en) * 1991-12-03 1997-09-02 Rohm And Haas Company Process for preparing an aqueous dispersion
US5385960A (en) * 1991-12-03 1995-01-31 Rohm And Haas Company Process for controlling adsorption of polymeric latex on titanium dioxide
BR9206868A (pt) * 1991-12-03 1995-11-21 Rohm & Haas Processo para formar uma suspensão de partículas compósitas discretas,suspensão,e,partícula multi-compósita discreta
JPH05163454A (ja) * 1991-12-16 1993-06-29 Mitsui Toatsu Chem Inc 水性顔料インキ組成物
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GB9211822D0 (en) * 1992-06-04 1992-07-15 Tioxide Group Services Ltd Composite pigmentary material
GB2267503B (en) 1992-06-04 1996-07-24 Tioxide Group Services Ltd Composite pigmentary material comprising particles of opposite surface charge

Also Published As

Publication number Publication date
FI960679A0 (fi) 1996-02-15
NO960576L (no) 1996-08-19
GB9502982D0 (en) 1995-04-05
KR960031554A (ko) 1996-09-17
CA2167628A1 (en) 1996-08-17
DE69602775D1 (de) 1999-07-15
ATE181095T1 (de) 1999-06-15
AR001084A1 (es) 1997-09-24
GR3030885T3 (en) 1999-11-30
NO960576D0 (no) 1996-02-14
AU692339B2 (en) 1998-06-04
BR9600386A (pt) 1999-10-13
AU4228196A (en) 1996-08-22
EP0727466B1 (en) 1999-06-09
CN1134441A (zh) 1996-10-30
JPH08239592A (ja) 1996-09-17
DE69602775T2 (de) 1999-10-07
EP0727466A1 (en) 1996-08-21
ES2132839T3 (es) 1999-08-16
MY132168A (en) 2007-09-28
FI960679A (fi) 1996-08-17
DK0727466T3 (da) 1999-11-15
US5643974A (en) 1997-07-01
ZA961240B (en) 1996-08-27

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