ZA200609419B - Polymer mixture consisting of an impact-resistance modified poly(meth)acrylate and a fluoropolymer - Google Patents
Polymer mixture consisting of an impact-resistance modified poly(meth)acrylate and a fluoropolymer Download PDFInfo
- Publication number
- ZA200609419B ZA200609419B ZA200609419A ZA200609419A ZA200609419B ZA 200609419 B ZA200609419 B ZA 200609419B ZA 200609419 A ZA200609419 A ZA 200609419A ZA 200609419 A ZA200609419 A ZA 200609419A ZA 200609419 B ZA200609419 B ZA 200609419B
- Authority
- ZA
- South Africa
- Prior art keywords
- molding
- meth
- impact
- polymer
- fluoropolymer
- Prior art date
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- 229920000193 polymethacrylate Polymers 0.000 title claims abstract description 61
- 229920002959 polymer blend Polymers 0.000 title claims abstract description 50
- 229920002313 fluoropolymer Polymers 0.000 title claims abstract description 49
- 239000004811 fluoropolymer Substances 0.000 title claims abstract description 49
- 239000000203 mixture Substances 0.000 claims abstract description 36
- 239000002245 particle Substances 0.000 claims abstract description 33
- 239000011159 matrix material Substances 0.000 claims abstract description 21
- 229920001971 elastomer Polymers 0.000 claims abstract description 18
- 239000000806 elastomer Substances 0.000 claims abstract description 18
- 239000000463 material Substances 0.000 claims abstract description 18
- 239000000109 continuous material Substances 0.000 claims abstract description 11
- 229920003023 plastic Polymers 0.000 claims abstract description 8
- 239000004033 plastic Substances 0.000 claims abstract description 8
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims abstract description 7
- 239000004926 polymethyl methacrylate Substances 0.000 claims abstract description 7
- 229920000642 polymer Polymers 0.000 claims description 54
- 238000000465 moulding Methods 0.000 claims description 50
- 239000002131 composite material Substances 0.000 claims description 27
- 238000000034 method Methods 0.000 claims description 26
- 230000008569 process Effects 0.000 claims description 23
- 238000003860 storage Methods 0.000 claims description 16
- -1 acrylic ester Chemical class 0.000 claims description 15
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 10
- 238000000576 coating method Methods 0.000 claims description 10
- 229920001577 copolymer Polymers 0.000 claims description 9
- 238000001125 extrusion Methods 0.000 claims description 8
- 239000004611 light stabiliser Substances 0.000 claims description 8
- 229920000139 polyethylene terephthalate Polymers 0.000 claims description 8
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 8
- 230000008646 thermal stress Effects 0.000 claims description 7
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 claims description 6
- 229920001707 polybutylene terephthalate Polymers 0.000 claims description 6
- 229920001169 thermoplastic Polymers 0.000 claims description 6
- 239000004416 thermosoftening plastic Substances 0.000 claims description 6
- 239000012528 membrane Substances 0.000 claims description 5
- 230000015572 biosynthetic process Effects 0.000 claims description 4
- 238000003475 lamination Methods 0.000 claims description 4
- 239000004417 polycarbonate Substances 0.000 claims description 4
- 229920000515 polycarbonate Polymers 0.000 claims description 4
- 229920000098 polyolefin Polymers 0.000 claims description 4
- 239000004800 polyvinyl chloride Substances 0.000 claims description 4
- 238000012545 processing Methods 0.000 claims description 4
- 238000001746 injection moulding Methods 0.000 claims description 3
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 3
- 238000000807 solvent casting Methods 0.000 claims description 3
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 2
- 239000004793 Polystyrene Substances 0.000 claims description 2
- 238000004891 communication Methods 0.000 claims description 2
- 238000012790 confirmation Methods 0.000 claims description 2
- 238000007765 extrusion coating Methods 0.000 claims description 2
- 229920000578 graft copolymer Polymers 0.000 claims description 2
- 229920005644 polyethylene terephthalate glycol copolymer Polymers 0.000 claims description 2
- 229920002223 polystyrene Polymers 0.000 claims description 2
- 239000011145 styrene acrylonitrile resin Substances 0.000 claims description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 claims 1
- 238000010438 heat treatment Methods 0.000 claims 1
- 239000002184 metal Substances 0.000 claims 1
- 238000003825 pressing Methods 0.000 claims 1
- 239000010408 film Substances 0.000 description 64
- 239000010410 layer Substances 0.000 description 28
- 239000000178 monomer Substances 0.000 description 15
- 239000006096 absorbing agent Substances 0.000 description 14
- 239000004609 Impact Modifier Substances 0.000 description 12
- 239000002033 PVDF binder Substances 0.000 description 12
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 12
- 239000012963 UV stabilizer Substances 0.000 description 9
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical group COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 8
- 239000000654 additive Substances 0.000 description 8
- 239000000945 filler Substances 0.000 description 7
- 239000000499 gel Substances 0.000 description 7
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 6
- 239000011248 coating agent Substances 0.000 description 6
- 230000007774 longterm Effects 0.000 description 6
- 230000009477 glass transition Effects 0.000 description 5
- 239000004971 Cross linker Substances 0.000 description 4
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 4
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 239000000975 dye Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 229910052731 fluorine Inorganic materials 0.000 description 4
- 239000011737 fluorine Substances 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 239000012778 molding material Substances 0.000 description 4
- 239000000049 pigment Substances 0.000 description 4
- 230000001681 protective effect Effects 0.000 description 4
- 238000011144 upstream manufacturing Methods 0.000 description 4
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 3
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 3
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 description 3
- 125000005250 alkyl acrylate group Chemical group 0.000 description 3
- 150000001412 amines Chemical class 0.000 description 3
- 239000003963 antioxidant agent Substances 0.000 description 3
- 150000001565 benzotriazoles Chemical class 0.000 description 3
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 3
- 238000004132 cross linking Methods 0.000 description 3
- 239000003995 emulsifying agent Substances 0.000 description 3
- 238000007720 emulsion polymerization reaction Methods 0.000 description 3
- 239000000155 melt Substances 0.000 description 3
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 3
- 238000006116 polymerization reaction Methods 0.000 description 3
- 238000007639 printing Methods 0.000 description 3
- FBCQUCJYYPMKRO-UHFFFAOYSA-N prop-2-enyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC=C FBCQUCJYYPMKRO-UHFFFAOYSA-N 0.000 description 3
- 230000004224 protection Effects 0.000 description 3
- 150000003254 radicals Chemical class 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- FCKXGFANXSHGAW-DTXPUJKBSA-N (2s)-n,n'-bis[(2s)-1-(2-chloro-4-nitroanilino)-1-oxo-3-phenylpropan-2-yl]-2-hydroxybutanediamide Chemical compound C([C@H](NC(=O)C[C@H](O)C(=O)N[C@@H](CC=1C=CC=CC=1)C(=O)NC=1C(=CC(=CC=1)[N+]([O-])=O)Cl)C(=O)NC=1C(=CC(=CC=1)[N+]([O-])=O)Cl)C1=CC=CC=C1 FCKXGFANXSHGAW-DTXPUJKBSA-N 0.000 description 2
- BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 description 2
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- 230000006750 UV protection Effects 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 2
- 125000003647 acryloyl group Chemical group O=C([*])C([H])=C([H])[H] 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 230000002051 biphasic effect Effects 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 238000005227 gel permeation chromatography Methods 0.000 description 2
- 238000007646 gravure printing Methods 0.000 description 2
- QUAMTGJKVDWJEQ-UHFFFAOYSA-N octabenzone Chemical compound OC1=CC(OCCCCCCCC)=CC=C1C(=O)C1=CC=CC=C1 QUAMTGJKVDWJEQ-UHFFFAOYSA-N 0.000 description 2
- ZQBAKBUEJOMQEX-UHFFFAOYSA-N phenyl salicylate Chemical compound OC1=CC=CC=C1C(=O)OC1=CC=CC=C1 ZQBAKBUEJOMQEX-UHFFFAOYSA-N 0.000 description 2
- 229920002647 polyamide Polymers 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 230000002035 prolonged effect Effects 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 230000000087 stabilizing effect Effects 0.000 description 2
- 230000035882 stress Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000003017 thermal stabilizer Substances 0.000 description 2
- HJIAMFHSAAEUKR-UHFFFAOYSA-N (2-hydroxyphenyl)-phenylmethanone Chemical class OC1=CC=CC=C1C(=O)C1=CC=CC=C1 HJIAMFHSAAEUKR-UHFFFAOYSA-N 0.000 description 1
- IMNBHNRXUAJVQE-UHFFFAOYSA-N (4-benzoyl-3-hydroxyphenyl) 2-methylprop-2-enoate Chemical compound OC1=CC(OC(=O)C(=C)C)=CC=C1C(=O)C1=CC=CC=C1 IMNBHNRXUAJVQE-UHFFFAOYSA-N 0.000 description 1
- DQQLQPFHERGYEK-UHFFFAOYSA-N 1,1,2,3,3-pentafluoro-3-(1,1,2,3,3-pentafluoroprop-2-enoxy)prop-1-ene Chemical compound FC(F)=C(F)C(F)(F)OC(F)(F)C(F)=C(F)F DQQLQPFHERGYEK-UHFFFAOYSA-N 0.000 description 1
- YAXWOADCWUUUNX-UHFFFAOYSA-N 1,2,2,3-tetramethylpiperidine Chemical group CC1CCCN(C)C1(C)C YAXWOADCWUUUNX-UHFFFAOYSA-N 0.000 description 1
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical compound C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 description 1
- MEZZCSHVIGVWFI-UHFFFAOYSA-N 2,2'-Dihydroxy-4-methoxybenzophenone Chemical compound OC1=CC(OC)=CC=C1C(=O)C1=CC=CC=C1O MEZZCSHVIGVWFI-UHFFFAOYSA-N 0.000 description 1
- BJELTSYBAHKXRW-UHFFFAOYSA-N 2,4,6-triallyloxy-1,3,5-triazine Chemical compound C=CCOC1=NC(OCC=C)=NC(OCC=C)=N1 BJELTSYBAHKXRW-UHFFFAOYSA-N 0.000 description 1
- ZXDDPOHVAMWLBH-UHFFFAOYSA-N 2,4-Dihydroxybenzophenone Chemical compound OC1=CC(O)=CC=C1C(=O)C1=CC=CC=C1 ZXDDPOHVAMWLBH-UHFFFAOYSA-N 0.000 description 1
- RJRFVJDPTHVIRV-UHFFFAOYSA-N 2,5-decanedione Natural products CCCCCC(=O)CCC(C)=O RJRFVJDPTHVIRV-UHFFFAOYSA-N 0.000 description 1
- HWRLEEPNFJNTOP-UHFFFAOYSA-N 2-(1,3,5-triazin-2-yl)phenol Chemical class OC1=CC=CC=C1C1=NC=NC=N1 HWRLEEPNFJNTOP-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- ZMWRRFHBXARRRT-UHFFFAOYSA-N 2-(benzotriazol-2-yl)-4,6-bis(2-methylbutan-2-yl)phenol Chemical compound CCC(C)(C)C1=CC(C(C)(C)CC)=CC(N2N=C3C=CC=CC3=N2)=C1O ZMWRRFHBXARRRT-UHFFFAOYSA-N 0.000 description 1
- LHPPDQUVECZQSW-UHFFFAOYSA-N 2-(benzotriazol-2-yl)-4,6-ditert-butylphenol Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC(N2N=C3C=CC=CC3=N2)=C1O LHPPDQUVECZQSW-UHFFFAOYSA-N 0.000 description 1
- IYAZLDLPUNDVAG-UHFFFAOYSA-N 2-(benzotriazol-2-yl)-4-(2,4,4-trimethylpentan-2-yl)phenol Chemical compound CC(C)(C)CC(C)(C)C1=CC=C(O)C(N2N=C3C=CC=CC3=N2)=C1 IYAZLDLPUNDVAG-UHFFFAOYSA-N 0.000 description 1
- WXHVQMGINBSVAY-UHFFFAOYSA-N 2-(benzotriazol-2-yl)-4-tert-butylphenol Chemical compound CC(C)(C)C1=CC=C(O)C(N2N=C3C=CC=CC3=N2)=C1 WXHVQMGINBSVAY-UHFFFAOYSA-N 0.000 description 1
- RTNVDKBRTXEWQE-UHFFFAOYSA-N 2-(benzotriazol-2-yl)-6-butan-2-yl-4-tert-butylphenol Chemical compound CCC(C)C1=CC(C(C)(C)C)=CC(N2N=C3C=CC=CC3=N2)=C1O RTNVDKBRTXEWQE-UHFFFAOYSA-N 0.000 description 1
- PHBCDAHASFSLMJ-UHFFFAOYSA-N 2-hydroxybenzotriazole Chemical compound C1=CC=CC2=NN(O)N=C21 PHBCDAHASFSLMJ-UHFFFAOYSA-N 0.000 description 1
- QMIWYOZFFSLIAK-UHFFFAOYSA-N 3,3,3-trifluoro-2-(trifluoromethyl)prop-1-ene Chemical group FC(F)(F)C(=C)C(F)(F)F QMIWYOZFFSLIAK-UHFFFAOYSA-N 0.000 description 1
- DBCAQXHNJOFNGC-UHFFFAOYSA-N 4-bromo-1,1,1-trifluorobutane Chemical compound FC(F)(F)CCCBr DBCAQXHNJOFNGC-UHFFFAOYSA-N 0.000 description 1
- YKXAYLPDMSGWEV-UHFFFAOYSA-N 4-hydroxybutyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCCCO YKXAYLPDMSGWEV-UHFFFAOYSA-N 0.000 description 1
- VMRIVYANZGSGRV-UHFFFAOYSA-N 4-phenyl-2h-triazin-5-one Chemical compound OC1=CN=NN=C1C1=CC=CC=C1 VMRIVYANZGSGRV-UHFFFAOYSA-N 0.000 description 1
- UWSMKYBKUPAEJQ-UHFFFAOYSA-N 5-Chloro-2-(3,5-di-tert-butyl-2-hydroxyphenyl)-2H-benzotriazole Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC(N2N=C3C=C(Cl)C=CC3=N2)=C1O UWSMKYBKUPAEJQ-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 239000004908 Emulsion polymer Substances 0.000 description 1
- 229940123457 Free radical scavenger Drugs 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 1
- 239000004642 Polyimide Substances 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 description 1
- OKKRPWIIYQTPQF-UHFFFAOYSA-N Trimethylolpropane trimethacrylate Chemical compound CC(=C)C(=O)OCC(CC)(COC(=O)C(C)=C)COC(=O)C(C)=C OKKRPWIIYQTPQF-UHFFFAOYSA-N 0.000 description 1
- KNSXNCFKSZZHEA-UHFFFAOYSA-N [3-prop-2-enoyloxy-2,2-bis(prop-2-enoyloxymethyl)propyl] prop-2-enoate Chemical compound C=CC(=O)OCC(COC(=O)C=C)(COC(=O)C=C)COC(=O)C=C KNSXNCFKSZZHEA-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 150000001491 aromatic compounds Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- IUKQLMGVFMDQDP-UHFFFAOYSA-N azane;piperidine Chemical compound N.C1CCNCC1 IUKQLMGVFMDQDP-UHFFFAOYSA-N 0.000 description 1
- 239000012965 benzophenone Substances 0.000 description 1
- 150000008366 benzophenones Chemical class 0.000 description 1
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 1
- 239000012964 benzotriazole Substances 0.000 description 1
- RSOILICUEWXSLA-UHFFFAOYSA-N bis(1,2,2,6,6-pentamethylpiperidin-4-yl) decanedioate Chemical compound C1C(C)(C)N(C)C(C)(C)CC1OC(=O)CCCCCCCCC(=O)OC1CC(C)(C)N(C)C(C)(C)C1 RSOILICUEWXSLA-UHFFFAOYSA-N 0.000 description 1
- GOJOVSYIGHASEI-UHFFFAOYSA-N bis(2,2,6,6-tetramethylpiperidin-4-yl) butanedioate Chemical compound C1C(C)(C)NC(C)(C)CC1OC(=O)CCC(=O)OC1CC(C)(C)NC(C)(C)C1 GOJOVSYIGHASEI-UHFFFAOYSA-N 0.000 description 1
- XITRBUPOXXBIJN-UHFFFAOYSA-N bis(2,2,6,6-tetramethylpiperidin-4-yl) decanedioate Chemical compound C1C(C)(C)NC(C)(C)CC1OC(=O)CCCCCCCCC(=O)OC1CC(C)(C)NC(C)(C)C1 XITRBUPOXXBIJN-UHFFFAOYSA-N 0.000 description 1
- SODJJEXAWOSSON-UHFFFAOYSA-N bis(2-hydroxy-4-methoxyphenyl)methanone Chemical compound OC1=CC(OC)=CC=C1C(=O)C1=CC=C(OC)C=C1O SODJJEXAWOSSON-UHFFFAOYSA-N 0.000 description 1
- FQUNFJULCYSSOP-UHFFFAOYSA-N bisoctrizole Chemical compound N1=C2C=CC=CC2=NN1C1=CC(C(C)(C)CC(C)(C)C)=CC(CC=2C(=C(C=C(C=2)C(C)(C)CC(C)(C)C)N2N=C3C=CC=CC3=N2)O)=C1O FQUNFJULCYSSOP-UHFFFAOYSA-N 0.000 description 1
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- IAJNXBNRYMEYAZ-UHFFFAOYSA-N ethyl 2-cyano-3,3-diphenylprop-2-enoate Chemical compound C=1C=CC=CC=1C(=C(C#N)C(=O)OCC)C1=CC=CC=C1 IAJNXBNRYMEYAZ-UHFFFAOYSA-N 0.000 description 1
- STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Substances CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 description 1
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- 125000001153 fluoro group Chemical group F* 0.000 description 1
- XUCNUKMRBVNAPB-UHFFFAOYSA-N fluoroethene Chemical compound FC=C XUCNUKMRBVNAPB-UHFFFAOYSA-N 0.000 description 1
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- 125000003707 hexyloxy group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])O* 0.000 description 1
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- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
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- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/3154—Of fluorinated addition polymer from unsaturated monomers
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y10T428/00—Stock material or miscellaneous articles
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- Y10T428/31855—Of addition polymer from unsaturated monomers
- Y10T428/31935—Ester, halide or nitrile of addition polymer
Landscapes
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- Chemical Kinetics & Catalysis (AREA)
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Applications Claiming Priority (1)
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DE200410024429 DE102004024429A1 (de) | 2004-05-14 | 2004-05-14 | Formkörper, enthaltend eine Polymermischung aus schlagzähmodifizierten Poly(meth)-acrylat und Fluorpolymer |
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EP (1) | EP1748890B1 (ko) |
JP (2) | JP2007537063A (ko) |
KR (1) | KR101157690B1 (ko) |
CN (1) | CN100537223C (ko) |
AT (1) | ATE426507T1 (ko) |
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PT (1) | PT1748890E (ko) |
WO (1) | WO2005110745A1 (ko) |
ZA (1) | ZA200609419B (ko) |
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Publication number | Priority date | Publication date | Assignee | Title |
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EP1060209B1 (de) * | 1997-12-05 | 2004-06-02 | Röhm GmbH & Co. KG | Verfahren zur herstellung von oberflächenharten, im "film-insert-moulding"-verfahren handhabbaren, beidseitig hochglänzenden, gelkörperfreien pmma-folien |
DE10236045A1 (de) * | 2002-08-06 | 2004-02-19 | Röhm GmbH & Co. KG | Niedrig orientierte thermoplastische Folien |
DE10345045A1 (de) * | 2003-09-26 | 2005-04-14 | Röhm GmbH & Co. KG | Verfahren zur Oberflächenvergütung von Werkstoffen durch Aufbringen insbesondere transparenter Schichten auf Basis von Polymethacrylaten |
DE10354379A1 (de) * | 2003-11-20 | 2005-06-23 | Röhm GmbH & Co. KG | Formmasse, enthaltend ein Mattierungsmittel |
DE102005002072A1 (de) * | 2005-01-14 | 2006-07-20 | Röhm GmbH & Co. KG | Witterungsstabile Folie zur Gelbeinfärbung retroreflektierender Formkörper |
DE102005019669A1 (de) * | 2005-02-08 | 2006-10-12 | Röhm Gmbh | Folienmembran mit hervorragender Witterungsbeständigkeit, hoher Durchlässigkeit für solare Wärmestrahlung, effektiver Zurückhaltung der von der Erde emittierten Wärmestrahlung und hoher mechanischer Festigkeit sowie Verfahren zur Herstelung der Folienmembran |
DE102005013082A1 (de) * | 2005-02-23 | 2006-08-24 | Röhm GmbH & Co. KG | Extrudierte Folie oder Platte mit elektrisch leitfähiger Beschichtung, Verfahren zu ihrer Herstellung, sowie Verwendungen |
DE102005062687A1 (de) * | 2005-12-23 | 2007-07-05 | Röhm Gmbh | PMMA-Folie mit besonders hoher Witterungsbeständigkeit und hoher UV-Schutzwirkung |
FR2913913A1 (fr) * | 2007-03-21 | 2008-09-26 | Arkema France | Structure multicouche petg/pmma |
DE102007029263A1 (de) * | 2007-06-22 | 2008-12-24 | Evonik Röhm Gmbh | PMMA/PVDF-Folie mit besonders hoher Witterungsbeständigkeit und hoher UV-Schutzwirkung |
JP2010536623A (ja) * | 2007-08-21 | 2010-12-02 | サン−ゴバン パフォーマンス プラスティックス コーポレイション | 屋根板材 |
US20100270767A1 (en) * | 2007-10-04 | 2010-10-28 | Morph Technologies, Inc. | Vehicular suspension components |
CN101952117B (zh) * | 2008-02-25 | 2014-01-22 | 阿科玛法国公司 | 透明的、耐化学性的冲击性丙烯酸类合金 |
WO2010077644A1 (en) * | 2008-12-08 | 2010-07-08 | Sabic Innovative Plastics Ip B.V. | Flame retardant polycarbonate compositions, method of manufacture thereof, and articles therefrom |
CN101457006B (zh) * | 2008-12-31 | 2013-03-27 | 东莞金富亮塑胶颜料有限公司 | 一种仿木纹共挤pmma改性材料及其制备方法 |
DE102009003225A1 (de) * | 2009-05-19 | 2010-11-25 | Evonik Degussa Gmbh | Transparente, witterungsbeständige Barrierefolie, Herstellung durch Lamination, Extrusionslamination oder Extrusionsbeschichtung |
FR2948036B1 (fr) * | 2009-07-17 | 2013-01-25 | Arkema France | Utilisation d'une composition transparente pour photoreacteurs |
KR101752178B1 (ko) * | 2009-11-30 | 2017-06-29 | 덴카 주식회사 | 폴리불화비닐리덴계 수지조성물, 필름, 백시트 및 태양전지 모듈 |
US20120009427A1 (en) * | 2010-07-08 | 2012-01-12 | Christopher Hable | Solvent cast flame retardant polycarbonate coatings, films and laminates |
DE102010038288A1 (de) * | 2010-07-22 | 2012-01-26 | Evonik Röhm Gmbh | Transparente, witterungsbeständige Barrierefolie mit verbesserter Barrierewirkung und Kratzfesteigenschaften |
EP2809509A4 (en) * | 2012-01-31 | 2015-09-23 | 3M Innovative Properties Co | METHOD FOR BORDER SEALING OF MULTILAYER ARTICLES |
EP2883248B1 (en) | 2012-08-08 | 2017-07-19 | 3M Innovative Properties Company | Photovoltaic devices with encapsulating barrier film |
KR20150041058A (ko) | 2012-08-08 | 2015-04-15 | 쓰리엠 이노베이티브 프로퍼티즈 캄파니 | 다이우레탄 (메트)아크릴레이트-실란 조성물 및 이를 포함하는 물품 |
US10562282B2 (en) | 2013-03-15 | 2020-02-18 | Arkema France | Multilayer composite |
EP2970611A4 (en) | 2013-03-15 | 2016-11-09 | Arkema France | THERMOPLASTIC COMPOSITE |
EP2784476B1 (de) * | 2013-03-27 | 2016-07-20 | Ul Llc | Vorrichtung und Verfahren zur Lagerung von Probenkörpern |
FR3014878B1 (fr) * | 2013-12-18 | 2015-12-18 | Arkema France | Film pvdf resistant a la dechirure a basse temperature et ininflammable |
WO2015146752A1 (ja) * | 2014-03-25 | 2015-10-01 | 三菱レイヨン株式会社 | 樹脂組成物、及び樹脂組成物からなる成形体 |
DE102014210007A1 (de) * | 2014-05-26 | 2015-11-26 | Evonik Röhm Gmbh | Drei-Schicht-UV-Schutzfolie für dekorative Schichtpressstoffplatten (HPL) |
DE102014218188B4 (de) | 2014-09-11 | 2023-01-19 | Evonik Operations Gmbh | Formulierung zur Beschichtung von Substraten, Verfahren zur Beschichtung von Substraten, beschichtete Substrate sowie Verwendung der Formulierung |
CN104877278B (zh) * | 2015-06-29 | 2017-08-15 | 北京化工大学 | 一种聚甲基丙烯酸正丁酯/聚偏氟乙烯基复合介电薄膜及其制备方法 |
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JPS59215863A (ja) * | 1983-05-24 | 1984-12-05 | ジェイエスアール株式会社 | 積層体 |
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FR2620127A1 (fr) | 1987-09-04 | 1989-03-10 | Charbonnages Ste Chimique | Composition polymere a base de fluorure de vinylidene et de methacrylate de methyle |
FR2659085B1 (fr) * | 1990-03-02 | 1992-05-15 | Atochem | Composition coextrudable avec le polyfluorure de vinylidene permettant l'adhesion de ce dernier avec une resine polymerique non compatible - composite obtenu avec cette composition. |
EP1060209B1 (de) | 1997-12-05 | 2004-06-02 | Röhm GmbH & Co. KG | Verfahren zur herstellung von oberflächenharten, im "film-insert-moulding"-verfahren handhabbaren, beidseitig hochglänzenden, gelkörperfreien pmma-folien |
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DE10043868A1 (de) | 2000-09-04 | 2002-04-04 | Roehm Gmbh | PMMA Formmassen mit verbesserter Schlagzähigkeit |
JP2002225184A (ja) * | 2001-02-06 | 2002-08-14 | Mitsubishi Plastics Ind Ltd | 耐候性樹脂被覆金属板 |
JP4465127B2 (ja) * | 2001-03-30 | 2010-05-19 | 株式会社クラレ | 耐候性、柔軟性に優れる農業用積層フィルム |
FR2842530B1 (fr) * | 2002-07-17 | 2004-09-03 | Atofina | Composition coextrudable avec le pvdf |
DE10236045A1 (de) * | 2002-08-06 | 2004-02-19 | Röhm GmbH & Co. KG | Niedrig orientierte thermoplastische Folien |
DE10354379A1 (de) | 2003-11-20 | 2005-06-23 | Röhm GmbH & Co. KG | Formmasse, enthaltend ein Mattierungsmittel |
DE102005002072A1 (de) | 2005-01-14 | 2006-07-20 | Röhm GmbH & Co. KG | Witterungsstabile Folie zur Gelbeinfärbung retroreflektierender Formkörper |
DE102005062687A1 (de) | 2005-12-23 | 2007-07-05 | Röhm Gmbh | PMMA-Folie mit besonders hoher Witterungsbeständigkeit und hoher UV-Schutzwirkung |
-
2004
- 2004-05-14 DE DE200410024429 patent/DE102004024429A1/de not_active Withdrawn
-
2005
- 2005-05-17 ES ES05748362T patent/ES2324944T3/es active Active
- 2005-05-17 DE DE200550006947 patent/DE502005006947D1/de active Active
- 2005-05-17 CN CNB2005800092939A patent/CN100537223C/zh not_active Expired - Fee Related
- 2005-05-17 US US10/590,932 patent/US7947781B2/en not_active Expired - Fee Related
- 2005-05-17 AT AT05748362T patent/ATE426507T1/de active
- 2005-05-17 JP JP2007512124A patent/JP2007537063A/ja active Pending
- 2005-05-17 NZ NZ550378A patent/NZ550378A/en unknown
- 2005-05-17 WO PCT/EP2005/005381 patent/WO2005110745A1/de not_active Application Discontinuation
- 2005-05-17 PT PT05748362T patent/PT1748890E/pt unknown
- 2005-05-17 KR KR1020067023760A patent/KR101157690B1/ko not_active IP Right Cessation
- 2005-05-17 MX MXPA06012979A patent/MXPA06012979A/es active IP Right Grant
- 2005-05-17 CA CA 2561254 patent/CA2561254A1/en not_active Abandoned
- 2005-05-17 AU AU2005243962A patent/AU2005243962B2/en not_active Ceased
- 2005-05-17 EP EP20050748362 patent/EP1748890B1/de not_active Not-in-force
-
2006
- 2006-11-13 ZA ZA200609419A patent/ZA200609419B/en unknown
-
2007
- 2007-07-13 HK HK07107526A patent/HK1103055A1/xx not_active IP Right Cessation
-
2011
- 2011-11-28 JP JP2011259371A patent/JP2012052139A/ja active Pending
Also Published As
Publication number | Publication date |
---|---|
MXPA06012979A (es) | 2006-12-20 |
NZ550378A (en) | 2009-07-31 |
JP2007537063A (ja) | 2007-12-20 |
CN1933969A (zh) | 2007-03-21 |
ATE426507T1 (de) | 2009-04-15 |
CA2561254A1 (en) | 2005-11-24 |
AU2005243962B2 (en) | 2010-07-29 |
JP2012052139A (ja) | 2012-03-15 |
AU2005243962A1 (en) | 2005-11-24 |
DE502005006947D1 (de) | 2009-05-07 |
EP1748890B1 (de) | 2009-03-25 |
ES2324944T3 (es) | 2009-08-20 |
EP1748890A1 (de) | 2007-02-07 |
PT1748890E (pt) | 2009-06-24 |
CN100537223C (zh) | 2009-09-09 |
KR101157690B1 (ko) | 2012-06-20 |
WO2005110745A1 (de) | 2005-11-24 |
HK1103055A1 (en) | 2007-12-14 |
US7947781B2 (en) | 2011-05-24 |
DE102004024429A1 (de) | 2005-12-08 |
US20070185270A1 (en) | 2007-08-09 |
KR20070020034A (ko) | 2007-02-16 |
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