ZA200410285B - Process for reducing the amount of fluorinated surfactant in aqueous fluropolymer dispersions. - Google Patents
Process for reducing the amount of fluorinated surfactant in aqueous fluropolymer dispersions.Info
- Publication number
- ZA200410285B ZA200410285B ZA200410285A ZA200410285A ZA200410285B ZA 200410285 B ZA200410285 B ZA 200410285B ZA 200410285 A ZA200410285 A ZA 200410285A ZA 200410285 A ZA200410285 A ZA 200410285A ZA 200410285 B ZA200410285 B ZA 200410285B
- Authority
- ZA
- South Africa
- Prior art keywords
- fluoropolymer dispersion
- amount
- aqueous
- aqueous fluoropolymer
- anion exchange
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F6/00—Post-polymerisation treatments
- C08F6/14—Treatment of polymer emulsions
- C08F6/16—Purification
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F6/00—Post-polymerisation treatments
- C08F6/14—Treatment of polymer emulsions
- C08F6/20—Concentration
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP02100547A EP1364972B1 (en) | 2002-05-22 | 2002-05-22 | Process for reducing the amount of fluorinated surfactant in aqueous fluoropolymer dispersions |
Publications (1)
Publication Number | Publication Date |
---|---|
ZA200410285B true ZA200410285B (en) | 2006-02-22 |
Family
ID=29286201
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ZA200410285A ZA200410285B (en) | 2002-05-22 | 2004-12-21 | Process for reducing the amount of fluorinated surfactant in aqueous fluropolymer dispersions. |
Country Status (11)
Country | Link |
---|---|
US (2) | US6825250B2 (xx) |
EP (1) | EP1364972B1 (xx) |
JP (1) | JP4351155B2 (xx) |
CN (1) | CN1656128A (xx) |
AT (1) | ATE338073T1 (xx) |
AU (1) | AU2003234457A1 (xx) |
CA (1) | CA2484299A1 (xx) |
DE (1) | DE60214343T2 (xx) |
RU (1) | RU2319712C2 (xx) |
WO (1) | WO2003099879A1 (xx) |
ZA (1) | ZA200410285B (xx) |
Families Citing this family (68)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19857111A1 (de) * | 1998-12-11 | 2000-06-15 | Dyneon Gmbh | Wäßrige Dispersionen von Fluorpolymeren |
US7125941B2 (en) * | 2001-03-26 | 2006-10-24 | 3M Innovative Properties Company | Aqueous emulsion polymerization process for producing fluoropolymers |
US7279522B2 (en) | 2001-09-05 | 2007-10-09 | 3M Innovative Properties Company | Fluoropolymer dispersions containing no or little low molecular weight fluorinated surfactant |
RU2342403C2 (ru) * | 2002-10-31 | 2008-12-27 | Зм Инновейтив Пропертиз Компани | Полимеризация в водной эмульсии без эмульгатора для получения сополимеров фторированного олефина и углеводородного олефина |
EP1441014A1 (en) * | 2003-01-22 | 2004-07-28 | 3M Innovative Properties Company | Aqueous fluoropolymer dispersion comprising a melt processible fluoropolymer and having a reduced amount of fluorinated surfactant |
ATE302243T1 (de) * | 2003-02-28 | 2005-09-15 | 3M Innovative Properties Co | Fluoropolymerdispersion enthaltend kein oder wenig fluorhaltiges netzmittel mit niedrigem molekulargewicht |
EP1462465B1 (en) * | 2003-03-25 | 2012-02-22 | 3M Innovative Properties Company | Melt-processible thermoplastic fluoropolymers having improved processing characteristics and method of producing the same |
DE60336400D1 (de) * | 2003-10-24 | 2011-04-28 | 3M Innovative Properties Co | Wässrige Dispersionen von Polytetrafluorethylenteilchen |
EP1533325B1 (en) * | 2003-11-17 | 2011-10-19 | 3M Innovative Properties Company | Aqueous dispersions of polytetrafluoroethylene having a low amount of fluorinated surfactant |
ITMI20040031A1 (it) | 2004-01-14 | 2004-04-14 | Solvay Solexis Spa | Processo per la preparazione di dispersori di fluoropolimeri |
EP1561729A1 (en) | 2004-02-05 | 2005-08-10 | 3M Innovative Properties Company | Removal of fluorinated surfactants from waste water |
ATE433350T1 (de) * | 2004-03-01 | 2009-06-15 | 3M Innovative Properties Co | Verfahren zum beschichten eines gegenstands mit einer fluorhaltigen kunststoffsdispersion |
DE602004016136D1 (de) * | 2004-07-05 | 2008-10-09 | 3M Innovative Properties Co | Grundierung aus PTFE für Metallsubstrate |
US20060014887A1 (en) * | 2004-07-19 | 2006-01-19 | 3M Innovative Properties Company | Method of hydrolyzing a dispersion of ionic fluoropolymer |
US7304101B2 (en) * | 2004-07-19 | 2007-12-04 | 3M Innovative Properties Company | Method of purifying a dispersion of ionic fluoropolymer |
US7790041B2 (en) | 2004-08-11 | 2010-09-07 | E.I. Du Pont De Nemours And Company | Removing fluorosurfactant from aqueous fluoropolymer dispersions |
US20070023360A1 (en) | 2005-08-01 | 2007-02-01 | Noelke Charles J | Removing fluorosurfactant from aqueous fluoropolymer dispersion using sorbent pouches |
JP4838799B2 (ja) * | 2004-08-11 | 2011-12-14 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | 収着剤パウチを使用する、水性フルオロポリマー分散体からのフルオロ界面活性剤の除去 |
US7138551B2 (en) * | 2004-11-05 | 2006-11-21 | E. I. Du Pont De Nemours And Company | Purification of fluorinated alcohols |
US7659329B2 (en) * | 2004-12-22 | 2010-02-09 | E. I. Du Pont De Nemours And Company | Removing fluorosurfactant from aqueous fluoropolymer dispersions using monodisperse ion exchange resin |
US20060135681A1 (en) | 2004-12-22 | 2006-06-22 | Cavanaugh Robert J | Viscosity control for reduced fluorosurfactant aqueous fluoropolymer dispersions by the addition of cationic surfactant |
US7666927B2 (en) * | 2004-12-22 | 2010-02-23 | E.I. Du Pont De Nemours And Company | Removing fluorosurfactant from aqueous fluoropolymer dispersions using anion exchange polymer with functional groups resistant to degradation to trialkylamines |
US7619018B2 (en) * | 2004-12-22 | 2009-11-17 | E.I. Du Pont De Nemours And Company | Process for removing fluorosurfactant from aqueous fluoropolymer dispersions and reducing scum formation |
JPWO2006077737A1 (ja) * | 2004-12-28 | 2008-06-19 | ダイキン工業株式会社 | 含フッ素ポリマー水性分散液製造方法 |
ITMI20042553A1 (it) * | 2004-12-30 | 2005-03-30 | Solvay Solexis Spa | Processo per la preparazione di dispersioni di fluoropolimeri |
ITMI20042554A1 (it) * | 2004-12-30 | 2005-03-30 | Solvay Solexis Spa | Procedimento per la preparazione di dispersioni di fluoropolimeri |
US20060178472A1 (en) * | 2005-02-10 | 2006-08-10 | Johnson David W | Process for producing low fluorosurfactant-containing aqueous fluoropolymer dispersions with controlled pH |
US7671111B2 (en) | 2005-02-10 | 2010-03-02 | E.I. Du Pont De Nemours And Company | Monitoring column breakthrough in a process for removing fluorosurfactant from aqueous fluoropolymer dispersions |
US20060183842A1 (en) * | 2005-02-10 | 2006-08-17 | Johnson David W | Fluoropolymer dispersions with reduced fluorosurfactant content and high shear stability |
JP5061446B2 (ja) * | 2005-03-04 | 2012-10-31 | 旭硝子株式会社 | 含フッ素エラストマーラテックス、その製造方法、含フッ素エラストマーおよび含フッ素ゴム成形品 |
EP1700869A1 (en) * | 2005-03-11 | 2006-09-13 | 3M Innovative Properties Company | Recovery of fluorinated surfactants from a basic anion exchange resin having quaternary ammonium groups |
US20060270780A1 (en) * | 2005-05-25 | 2006-11-30 | Ping Xu | High purity perfluoroelastomer composites and a processes to produce the same |
US7488781B2 (en) * | 2005-05-25 | 2009-02-10 | Gore Enterprise Holdings, Inc. | High purity transparent perfluoroelastomer parts and a process to produce the same |
US7514484B2 (en) * | 2005-06-06 | 2009-04-07 | Asahi Glass Company, Limited | Aqueous dispersion of polytetrafluoroethylene and process for its production |
GB2427170A (en) * | 2005-06-17 | 2006-12-20 | 3M Innovative Properties Co | Fluoropolymer film having glass microspheres |
JP4956925B2 (ja) * | 2005-07-13 | 2012-06-20 | 旭硝子株式会社 | ポリテトラフルオロエチレン水性分散液およびその製造方法 |
GB0514387D0 (en) * | 2005-07-15 | 2005-08-17 | 3M Innovative Properties Co | Aqueous emulsion polymerization of fluorinated monomers using a perfluoropolyether surfactant |
GB0525978D0 (en) * | 2005-12-21 | 2006-02-01 | 3M Innovative Properties Co | Fluorinated Surfactants For Making Fluoropolymers |
GB0523853D0 (en) | 2005-11-24 | 2006-01-04 | 3M Innovative Properties Co | Fluorinated surfactants for use in making a fluoropolymer |
US20070025902A1 (en) * | 2005-07-15 | 2007-02-01 | 3M Innovative Properties Company | Recovery of fluorinated carboxylic acid from adsorbent particles |
US20080015304A1 (en) * | 2006-07-13 | 2008-01-17 | Klaus Hintzer | Aqueous emulsion polymerization process for producing fluoropolymers |
GB0514398D0 (en) | 2005-07-15 | 2005-08-17 | 3M Innovative Properties Co | Aqueous emulsion polymerization of fluorinated monomers using a fluorinated surfactant |
ITMI20051397A1 (it) * | 2005-07-21 | 2007-01-22 | Solvay Solexis Spa | Polveri fini di fluoropolimeri |
JP5106396B2 (ja) * | 2005-08-08 | 2012-12-26 | アーケマ・インコーポレイテッド | 非フッ素化界面活性剤を用いたフルオロポリマーの重合 |
JP4792873B2 (ja) * | 2005-08-19 | 2011-10-12 | 旭硝子株式会社 | 精製ポリテトラフルオロエチレン水性分散液の製造方法 |
GB2430437A (en) * | 2005-09-27 | 2007-03-28 | 3M Innovative Properties Co | Method of making a fluoropolymer |
US7728087B2 (en) | 2005-12-23 | 2010-06-01 | 3M Innovative Properties Company | Fluoropolymer dispersion and method for making the same |
EP1808448B1 (en) * | 2006-01-13 | 2009-06-17 | Asahi Glass Company, Limited | Process for producing elastic fluorocopolymer and crosslinked fluororubber |
EP1845116A1 (en) * | 2006-04-11 | 2007-10-17 | Solvay Solexis S.p.A. | Fluoropolymer dispersion purification |
US7754795B2 (en) | 2006-05-25 | 2010-07-13 | 3M Innovative Properties Company | Coating composition |
US20070276103A1 (en) * | 2006-05-25 | 2007-11-29 | 3M Innovative Properties Company | Fluorinated Surfactants |
US7666928B2 (en) | 2006-05-31 | 2010-02-23 | E.I. Du Pont De Nemours And Company | Staged addition of non-fluorinated anionic surfactant to reduced fluorosurfactant fluoropolymer dispersion |
US20070282044A1 (en) * | 2006-05-31 | 2007-12-06 | Robert John Cavanaugh | Concentrated fluoropolymer dispersions stabilized with anionic polyelectrolyte dispersing agents |
US8202955B2 (en) * | 2006-07-06 | 2012-06-19 | Daikin Industries, Ltd. | Aqueous fluorine-containing polymer dispersion |
WO2008004660A1 (fr) * | 2006-07-07 | 2008-01-10 | Daikin Industries, Ltd. | Procédé de fabrication d'une dispersion aqueuse de polymère contenant du fluor et dispersion aqueuse de polymère contenant du fluor |
US8119750B2 (en) | 2006-07-13 | 2012-02-21 | 3M Innovative Properties Company | Explosion taming surfactants for the production of perfluoropolymers |
JP5446269B2 (ja) * | 2006-11-24 | 2014-03-19 | 旭硝子株式会社 | 含フッ素乳化剤の含有量の減少した含フッ素ポリマー水性分散液の製造方法 |
EP2094742A2 (en) * | 2006-12-12 | 2009-09-02 | 3M Innovative Properties Company | Thermally stable fluoropolymers |
GB0625071D0 (en) * | 2006-12-15 | 2007-01-24 | 3M Innovative Properties Co | Process for removing fluorinated emulsifier from fluoropolmer dispersions using an ion-exchange resin and dispersions obtained therefrom |
US20100084343A1 (en) * | 2007-02-16 | 2010-04-08 | Mader Brian T | System and process for the removal of fluorochemicals from water |
US20100072134A1 (en) * | 2007-03-06 | 2010-03-25 | Mader Brian T | Ultrasonically induced cavitation of fluorochemicals |
US20080264864A1 (en) * | 2007-04-27 | 2008-10-30 | 3M Innovative Properties Company | PROCESS FOR REMOVING FLUORINATED EMULSIFIER FROM FLUOROPOLMER DISPERSIONS USING AN ANION-EXCHANGE RESIN AND A pH-DEPENDENT SURFACTANT AND FLUOROPOLYMER DISPERSIONS CONTAINING A pH-DEPENDENT SURFACTANT |
WO2009020187A1 (ja) * | 2007-08-07 | 2009-02-12 | Daikin Industries, Ltd. | 低分子量ポリテトラフルオロエチレン水性分散液、低分子量ポリテトラフルオロエチレン粉末及び低分子量ポリテトラフルオロエチレンの製造方法 |
US8329813B2 (en) * | 2009-05-08 | 2012-12-11 | E I Du Pont De Nemours And Company | Thermal reduction of fluoroether carboxylic acids or salts from fluoropolymer dispersions |
CN104403036B (zh) * | 2014-12-22 | 2017-02-22 | 上海三爱富新材料股份有限公司 | 水性含氟聚合物分散乳液及其制备方法 |
CN113717300B (zh) * | 2017-03-31 | 2023-11-17 | 大金工业株式会社 | 含氟聚合物的制造方法、聚合用表面活性剂和表面活性剂的使用 |
EP3960773A4 (en) * | 2019-04-26 | 2023-01-04 | Daikin Industries, Ltd. | METHOD FOR PRODUCING AQUEOUS FLUOROPOLYMER DISPERSION, METHOD FOR DRAINAGE TREATMENT AND AQUEOUS FLUOROPOLYMER DISPERSION |
US20220306491A1 (en) | 2019-06-28 | 2022-09-29 | Katholieke Universiteit Leuven | Adsorptive Removal of Perfluorinated or Partially Fluorinated Surfactants |
Family Cites Families (37)
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US4016345A (en) * | 1972-12-22 | 1977-04-05 | E. I. Du Pont De Nemours And Company | Process for polymerizing tetrafluoroethylene in aqueous dispersion |
US4544458A (en) * | 1978-11-13 | 1985-10-01 | E. I. Du Pont De Nemours And Company | Fluorinated ion exchange polymer containing carboxylic groups, process for making same, and film and membrane thereof |
DE2903981A1 (de) * | 1979-02-02 | 1980-08-07 | Hoechst Ag | Rueckgewinnung fluorierter emulgatorsaeuren aus basischen anionenaustauschern |
DE2908001C2 (de) * | 1979-03-01 | 1981-02-19 | Hoechst Ag, 6000 Frankfurt | Verfahren zur Herstellung konzentrierter Dispersionen von Fluorpolymeren |
IT1204903B (it) * | 1986-06-26 | 1989-03-10 | Ausimont Spa | Processo di polimerizzazione in dispersione acquosa di monomeri florati |
US5153322A (en) * | 1987-10-30 | 1992-10-06 | Minnesota Mining And Manufacturing Company | Perfluoro (cycloaliphatic methyleneoxyalkylene) carbonyl fluorides and derivatives thereof |
US5229480A (en) | 1992-09-03 | 1993-07-20 | E. I. Du Pont De Nemours And Company | Vinyl fluoride polymerization |
IT1265067B1 (it) | 1993-05-18 | 1996-10-30 | Ausimont Spa | Processo di (co)polimerizzazione in emulsione acquosa di monomeri olefinici fluorurati |
DE4402694A1 (de) | 1993-06-02 | 1995-08-03 | Hoechst Ag | Verfahren zur Rückgewinnung von fluorierten Carbonsäuren |
IT1269517B (it) * | 1994-05-19 | 1997-04-01 | Ausimont Spa | Polimeri e copolimeri fluorurati contenenti strutture cicliche |
JP2829706B2 (ja) | 1994-07-11 | 1998-12-02 | 三井・デュポンフロロケミカル株式会社 | フルオロポリマー水性エマルジョン及びその製造方法 |
JP3298321B2 (ja) | 1994-08-31 | 2002-07-02 | ダイキン工業株式会社 | ビニリデンフルオライド系共重合体水性分散液、ビニリデンフルオライド系シード重合体水性分散液およびそれらの製法 |
IT1270703B (it) | 1994-11-17 | 1997-05-07 | Ausimont Spa | Microemulsioni di fluoropoliossialchileni in miscela con idrocarburi, e loro uso in processi di (co)polimerizzazione di monomeri fluorurati |
US5895799A (en) | 1995-01-18 | 1999-04-20 | W. L. Gore & Associates, Inc. | Microemulsion polymerization process for the production of small polytetrafluoroethylene polymer particles |
WO1996024622A1 (en) | 1995-02-10 | 1996-08-15 | Alliedsignal Inc. | Production of fluoropolymers, fluoropolymer suspension and polymer formed therefrom |
EP0731081B1 (de) * | 1995-03-09 | 1998-04-15 | Dyneon GmbH | Rückgewinnung hochfluorierter Carbonsäuren aus der Gasphase |
US5688884A (en) | 1995-08-31 | 1997-11-18 | E. I. Du Pont De Nemours And Company | Polymerization process |
IT1276072B1 (it) | 1995-10-31 | 1997-10-24 | Ausimont Spa | Processo di (co)polimerizzazione di monomeri fluorurati per ottenere polimeri contenenti idrogeno |
US5955556A (en) | 1995-11-06 | 1999-09-21 | Alliedsignal Inc. | Method of manufacturing fluoropolymers |
JPH108041A (ja) | 1996-06-21 | 1998-01-13 | Daikin Ind Ltd | 水分散型フッ素系撥水撥油剤 |
IT1295535B1 (it) | 1996-07-01 | 1999-05-12 | Ausimont Spa | Processo di polimerizzazione di vinilidenfluoruro (vdf) |
US5763552A (en) | 1996-07-26 | 1998-06-09 | E. I. Du Pont De Nemours And Company | Hydrogen-containing flourosurfacant and its use in polymerization |
US6013795A (en) * | 1996-11-04 | 2000-01-11 | 3M Innovative Properties Company | Alpha-branched fluoroalkylcarbonyl fluorides and their derivatives |
IT1290428B1 (it) | 1997-03-21 | 1998-12-03 | Ausimont Spa | Grassi fluorurati |
US6642307B1 (en) | 1998-10-13 | 2003-11-04 | Daikin Industries, Ltd. | Process for producing fluoropolymer |
DE19857111A1 (de) * | 1998-12-11 | 2000-06-15 | Dyneon Gmbh | Wäßrige Dispersionen von Fluorpolymeren |
US6395848B1 (en) * | 1999-05-20 | 2002-05-28 | E. I. Du Pont De Nemours And Company | Polymerization of fluoromonomers |
US6429258B1 (en) | 1999-05-20 | 2002-08-06 | E. I. Du Pont De Nemours & Company | Polymerization of fluoromonomers |
ITMI991269A1 (it) | 1999-06-08 | 2000-12-08 | Ausimont Spa | Miscele di dispersioni di fluoropolimeri |
DE19932771A1 (de) | 1999-07-14 | 2001-01-18 | Dyneon Gmbh | Verfahren zur Eluierung fluorierter Emulgatoren |
DE19953285A1 (de) * | 1999-11-05 | 2001-05-10 | Dyneon Gmbh | Verfahren zur Rückgewinnung fluorierter Emulgatoren |
US6593416B2 (en) * | 2000-02-01 | 2003-07-15 | 3M Innovative Properties Company | Fluoropolymers |
US6720360B1 (en) * | 2000-02-01 | 2004-04-13 | 3M Innovative Properties Company | Ultra-clean fluoropolymers |
JP2002059160A (ja) | 2000-08-11 | 2002-02-26 | Daikin Ind Ltd | 含フッ素陰イオン系界面活性剤の分離方法 |
US6730760B2 (en) * | 2001-01-31 | 2004-05-04 | 3M Innovative Properties Company | Perfluoroelastomers having a low glass transition temperature and method of making them |
US20030125421A1 (en) * | 2001-08-03 | 2003-07-03 | Hermann Bladel | Aqueous dispersions of fluoropolymers |
US7279522B2 (en) * | 2001-09-05 | 2007-10-09 | 3M Innovative Properties Company | Fluoropolymer dispersions containing no or little low molecular weight fluorinated surfactant |
-
2002
- 2002-05-22 EP EP02100547A patent/EP1364972B1/en not_active Expired - Lifetime
- 2002-05-22 DE DE60214343T patent/DE60214343T2/de not_active Expired - Lifetime
- 2002-05-22 AT AT02100547T patent/ATE338073T1/de not_active IP Right Cessation
-
2003
- 2003-05-05 WO PCT/US2003/013839 patent/WO2003099879A1/en active Application Filing
- 2003-05-05 JP JP2004508133A patent/JP4351155B2/ja not_active Expired - Fee Related
- 2003-05-05 AU AU2003234457A patent/AU2003234457A1/en not_active Abandoned
- 2003-05-05 RU RU2004134328/04A patent/RU2319712C2/ru not_active IP Right Cessation
- 2003-05-05 CN CN03811526.3A patent/CN1656128A/zh active Pending
- 2003-05-05 CA CA002484299A patent/CA2484299A1/en not_active Abandoned
- 2003-05-05 US US10/429,387 patent/US6825250B2/en not_active Expired - Fee Related
-
2004
- 2004-11-19 US US10/992,961 patent/US20050070633A1/en not_active Abandoned
- 2004-12-21 ZA ZA200410285A patent/ZA200410285B/xx unknown
Also Published As
Publication number | Publication date |
---|---|
ATE338073T1 (de) | 2006-09-15 |
DE60214343T2 (de) | 2007-03-29 |
JP4351155B2 (ja) | 2009-10-28 |
WO2003099879A1 (en) | 2003-12-04 |
JP2006515375A (ja) | 2006-05-25 |
EP1364972B1 (en) | 2006-08-30 |
CN1656128A (zh) | 2005-08-17 |
RU2319712C2 (ru) | 2008-03-20 |
CA2484299A1 (en) | 2003-12-04 |
US20050070633A1 (en) | 2005-03-31 |
EP1364972A1 (en) | 2003-11-26 |
RU2004134328A (ru) | 2005-07-10 |
AU2003234457A1 (en) | 2003-12-12 |
DE60214343D1 (de) | 2006-10-12 |
US6825250B2 (en) | 2004-11-30 |
US20030220442A1 (en) | 2003-11-27 |
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