ZA200206409B - Method for producing carbon monoxide by reverse conversion with an adapted catalyst. - Google Patents
Method for producing carbon monoxide by reverse conversion with an adapted catalyst.Info
- Publication number
- ZA200206409B ZA200206409B ZA200206409A ZA200206409A ZA200206409B ZA 200206409 B ZA200206409 B ZA 200206409B ZA 200206409 A ZA200206409 A ZA 200206409A ZA 200206409 A ZA200206409 A ZA 200206409A ZA 200206409 B ZA200206409 B ZA 200206409B
- Authority
- ZA
- South Africa
- Prior art keywords
- carbon monoxide
- producing carbon
- reverse conversion
- adapted catalyst
- catalyst
- Prior art date
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/008—Details of the reactor or of the particulate material; Processes to increase or to retard the rate of reaction
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/06—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of zinc, cadmium or mercury
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/24—Chromium, molybdenum or tungsten
- B01J23/26—Chromium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/86—Chromium
- B01J23/866—Nickel and chromium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/0242—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly vertical
- B01J8/025—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly vertical in a cylindrical shaped bed
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/0285—Heating or cooling the reactor
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/40—Carbon monoxide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00106—Controlling the temperature by indirect heat exchange
- B01J2208/00115—Controlling the temperature by indirect heat exchange with heat exchange elements inside the bed of solid particles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00106—Controlling the temperature by indirect heat exchange
- B01J2208/00168—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
- B01J2208/00176—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles outside the reactor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00106—Controlling the temperature by indirect heat exchange
- B01J2208/00168—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
- B01J2208/00212—Plates; Jackets; Cylinders
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00477—Controlling the temperature by thermal insulation means
- B01J2208/00495—Controlling the temperature by thermal insulation means using insulating materials or refractories
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/18—Details relating to the spatial orientation of the reactor
- B01J2219/182—Details relating to the spatial orientation of the reactor horizontal
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/19—Details relating to the geometry of the reactor
- B01J2219/194—Details relating to the geometry of the reactor round
- B01J2219/1941—Details relating to the geometry of the reactor round circular or disk-shaped
- B01J2219/1943—Details relating to the geometry of the reactor round circular or disk-shaped cylindrical
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/80—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with zinc, cadmium or mercury
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
- Y02P20/129—Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Fluid Mechanics (AREA)
- Carbon And Carbon Compounds (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0002927A FR2806073B1 (fr) | 2000-03-07 | 2000-03-07 | Procede de production de monoxyde de carbone par retroconversion inverse avec un catalyseur adapte |
Publications (1)
Publication Number | Publication Date |
---|---|
ZA200206409B true ZA200206409B (en) | 2004-01-30 |
Family
ID=8847823
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ZA200206409A ZA200206409B (en) | 2000-03-07 | 2002-08-12 | Method for producing carbon monoxide by reverse conversion with an adapted catalyst. |
Country Status (18)
Country | Link |
---|---|
US (1) | US20030113244A1 (xx) |
EP (1) | EP1263681B1 (xx) |
JP (1) | JP4903339B2 (xx) |
KR (1) | KR100760502B1 (xx) |
CN (1) | CN1198758C (xx) |
AR (1) | AR027616A1 (xx) |
AT (1) | ATE303342T1 (xx) |
AU (1) | AU3935801A (xx) |
BR (1) | BR0109037B1 (xx) |
CA (1) | CA2399956A1 (xx) |
DE (1) | DE60113070T2 (xx) |
ES (1) | ES2247077T3 (xx) |
FR (1) | FR2806073B1 (xx) |
HU (1) | HUP0300106A2 (xx) |
PL (1) | PL201232B1 (xx) |
TW (1) | TWI221463B (xx) |
WO (1) | WO2001066463A1 (xx) |
ZA (1) | ZA200206409B (xx) |
Families Citing this family (30)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100555294B1 (ko) * | 2003-09-17 | 2006-03-03 | 한국과학기술연구원 | 역수성가스 반응을 이용한 디메틸에테르의 제조방법 |
US7351275B2 (en) * | 2004-12-21 | 2008-04-01 | The Boc Group, Inc. | Carbon monoxide production process |
US20080110801A1 (en) * | 2006-11-09 | 2008-05-15 | Leon Yuan | Process For Heating A Hydrocarbon Stream Entering A Reaction Zone With A Heater Convection Section |
US7740751B2 (en) | 2006-11-09 | 2010-06-22 | Uop Llc | Process for heating a stream for a hydrocarbon conversion process |
CN101678329B (zh) * | 2007-04-27 | 2013-09-18 | 沙特基础工业公司 | 将二氧化碳催化加氢成合成气混合物 |
EA016496B9 (ru) * | 2007-06-25 | 2012-07-30 | Сауди Бейсик Индастриз Корпорейшн | Способ получения смеси синтез-газа |
JP5823873B2 (ja) * | 2008-12-17 | 2015-11-25 | サウディ ベーシック インダストリーズ コーポレイション | 合成ガス混合物中の一酸化炭素含有量を増加させるプロセス |
US8282814B2 (en) * | 2009-03-31 | 2012-10-09 | Uop Llc | Fired heater for a hydrocarbon conversion process |
CN101624186B (zh) * | 2009-07-31 | 2011-09-14 | 崔卫东 | 二氧化碳选择性加氢合成一氧化碳的方法 |
US8658554B2 (en) * | 2009-11-04 | 2014-02-25 | The United States Of America, As Represented By The Secretary Of The Navy | Catalytic support for use in carbon dioxide hydrogenation reactions |
WO2012153762A1 (ja) * | 2011-05-11 | 2012-11-15 | 株式会社村田製作所 | 逆シフト反応用触媒、およびそれを用いた合成ガスの製造方法 |
US8962702B2 (en) | 2011-12-08 | 2015-02-24 | Saudi Basic Industries Corporation | Mixed oxide based catalyst for the conversion of carbon dioxide to syngas and method of preparation and use |
WO2013158160A1 (en) * | 2012-04-16 | 2013-10-24 | Seerstone Llc | Method for producing solid carbon by reducing carbon dioxide |
EP2864244A2 (en) * | 2012-06-21 | 2015-04-29 | Saudi Basic Industries Corporation | Process for producing a synthesis gas mixture |
US8551434B1 (en) | 2012-06-29 | 2013-10-08 | Saudi Basic Industries Corporation | Method of forming a syngas mixture |
US8845876B2 (en) * | 2012-07-26 | 2014-09-30 | Liquid Light, Inc. | Electrochemical co-production of products with carbon-based reactant feed to anode |
WO2014180888A1 (en) * | 2013-05-08 | 2014-11-13 | Shell Internationale Research Maatschappij B.V. | Process for the preparation of syngas |
DK3027310T3 (da) | 2013-07-31 | 2023-07-10 | Res Triangle Inst | Blandingsmetaljernoxider og anvendelser deraf |
EP3063113A1 (en) | 2013-10-29 | 2016-09-07 | Saudi Basic Industries Corporation | Method for carbon dioxide hydrogenation of syngas and the integration of the process with syngas conversion processes |
EP3092287A1 (en) | 2014-01-06 | 2016-11-16 | Saudi Basic Industries Corporation | Method for carbon dioxide hydrogenation of syngas |
US9714167B2 (en) | 2014-04-03 | 2017-07-25 | Saudi Basic Industries Corporation | Process for converting of methane steam reforming syngas with CO2 |
EP3261990A1 (en) * | 2015-02-23 | 2018-01-03 | SABIC Global Technologies B.V. | Methods for hydrogenation of carbon dioxide to syngas |
RU2660139C1 (ru) * | 2017-11-28 | 2018-07-05 | Федеральное государственное автономное образовательное учреждение высшего образования "Национальный исследовательский технологический университет "МИСиС" | Способ получения синтез-газа из CO2 |
CN114466815A (zh) | 2019-09-27 | 2022-05-10 | 含氧低碳投资有限责任公司 | 用于二氧化碳的转化的工艺 |
CA3158823C (en) | 2019-12-21 | 2024-06-11 | High Hopes Labs Ltd. | Gaseous matter capture system and method |
CA3180676C (en) * | 2020-05-04 | 2024-02-27 | Infinium Technology, Llc | Reverse water gas shift catalytic reactor systems |
US11498886B2 (en) | 2020-05-04 | 2022-11-15 | Infinium Technology, Llc | Catalysts and processes for the direct production of liquid fuels from carbon dioxide and hydrogen |
CN115516065A (zh) | 2020-05-04 | 2022-12-23 | 英飞纳姆科技有限责任公司 | 用于将二氧化碳和电力转换成燃料和化学品的方法 |
US11560343B2 (en) | 2020-05-04 | 2023-01-24 | Infinium Technology, Llc | Process for capture of carbon dioxide from air and the direct conversion of carbon dioxide into fuels and chemicals |
US11819815B2 (en) | 2021-11-19 | 2023-11-21 | Infinium Technology, Llc | Catalytic reactor for the conversion of carbon dioxide and hydrogen to syngas |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3718418A (en) * | 1970-09-01 | 1973-02-27 | Inst Gas Technology | Co shift process |
JPS53119798A (en) * | 1977-03-30 | 1978-10-19 | Mitsui Toatsu Chem Inc | Production of carbon monoxide |
US4265868A (en) * | 1978-02-08 | 1981-05-05 | Koppers Company, Inc. | Production of carbon monoxide by the gasification of carbonaceous materials |
FR2593164B1 (fr) * | 1986-01-17 | 1989-08-18 | Charbonnages Ste Chimique | Procede de fabrication d'oxyde de carbone a partir d'un melange de gaz carbonique et d'hydrogene et catalyseur pour la mise en oeuvre de ce procede. |
JP2535752B2 (ja) * | 1991-09-25 | 1996-09-18 | 工業技術院長 | 炭酸ガスの気相還元方法 |
DK169615B1 (da) * | 1992-12-10 | 1994-12-27 | Topsoe Haldor As | Fremgangsmåde til fremstilling af carbonmonoxidrig gas |
JPH06279012A (ja) * | 1993-03-24 | 1994-10-04 | Tosoh Corp | 一酸化炭素の製造方法 |
US5911964A (en) * | 1993-06-25 | 1999-06-15 | Cosmo Research Institute | Method for reducing carbon dioxide using a catalyst for reduction of carbon dioxide |
JP2847018B2 (ja) * | 1993-06-25 | 1999-01-13 | 株式会社コスモ総合研究所 | 二酸化炭素還元反応触媒 |
JPH07136462A (ja) * | 1993-11-12 | 1995-05-30 | Toshiba Corp | 排ガス中の二酸化炭素固定方法及びこの方法を用いた環境調和型発電プラント |
JPH07299330A (ja) * | 1994-05-11 | 1995-11-14 | Toshiba Corp | 排ガス処理装置 |
JPH08245211A (ja) * | 1995-03-09 | 1996-09-24 | Tosoh Corp | 一酸化炭素の製造方法 |
-
2000
- 2000-03-07 FR FR0002927A patent/FR2806073B1/fr not_active Expired - Fee Related
-
2001
- 2001-03-05 TW TW090105221A patent/TWI221463B/zh not_active IP Right Cessation
- 2001-03-07 JP JP2001565286A patent/JP4903339B2/ja not_active Expired - Fee Related
- 2001-03-07 DE DE60113070T patent/DE60113070T2/de not_active Expired - Lifetime
- 2001-03-07 WO PCT/FR2001/000689 patent/WO2001066463A1/fr active IP Right Grant
- 2001-03-07 AT AT01913958T patent/ATE303342T1/de not_active IP Right Cessation
- 2001-03-07 AR ARP010101059A patent/AR027616A1/es unknown
- 2001-03-07 CN CNB018062067A patent/CN1198758C/zh not_active Expired - Fee Related
- 2001-03-07 BR BRPI0109037-2A patent/BR0109037B1/pt not_active IP Right Cessation
- 2001-03-07 US US10/220,873 patent/US20030113244A1/en not_active Abandoned
- 2001-03-07 CA CA002399956A patent/CA2399956A1/fr not_active Abandoned
- 2001-03-07 EP EP01913958A patent/EP1263681B1/fr not_active Expired - Lifetime
- 2001-03-07 PL PL365425A patent/PL201232B1/pl not_active IP Right Cessation
- 2001-03-07 ES ES01913958T patent/ES2247077T3/es not_active Expired - Lifetime
- 2001-03-07 HU HU0300106A patent/HUP0300106A2/hu unknown
- 2001-03-07 AU AU39358/01A patent/AU3935801A/en not_active Abandoned
- 2001-03-07 KR KR1020027011687A patent/KR100760502B1/ko not_active IP Right Cessation
-
2002
- 2002-08-12 ZA ZA200206409A patent/ZA200206409B/xx unknown
Also Published As
Publication number | Publication date |
---|---|
WO2001066463A1 (fr) | 2001-09-13 |
CN1198758C (zh) | 2005-04-27 |
KR100760502B1 (ko) | 2007-10-04 |
FR2806073B1 (fr) | 2002-06-07 |
DE60113070D1 (de) | 2005-10-06 |
US20030113244A1 (en) | 2003-06-19 |
AR027616A1 (es) | 2003-04-02 |
EP1263681A1 (fr) | 2002-12-11 |
AU3935801A (en) | 2001-09-17 |
CA2399956A1 (fr) | 2001-09-13 |
KR20020092378A (ko) | 2002-12-11 |
ES2247077T3 (es) | 2006-03-01 |
DE60113070T2 (de) | 2006-09-21 |
BR0109037B1 (pt) | 2010-02-23 |
PL201232B1 (pl) | 2009-03-31 |
TWI221463B (en) | 2004-10-01 |
HUP0300106A2 (en) | 2003-05-28 |
BR0109037A (pt) | 2003-06-03 |
CN1416404A (zh) | 2003-05-07 |
PL365425A1 (en) | 2005-01-10 |
ATE303342T1 (de) | 2005-09-15 |
FR2806073A1 (fr) | 2001-09-14 |
JP2003525832A (ja) | 2003-09-02 |
JP4903339B2 (ja) | 2012-03-28 |
EP1263681B1 (fr) | 2005-08-31 |
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