ZA200107439B - Method for continuously monitoring and controlling the monomer conversion during emulsion polymerization. - Google Patents
Method for continuously monitoring and controlling the monomer conversion during emulsion polymerization. Download PDFInfo
- Publication number
- ZA200107439B ZA200107439B ZA200107439A ZA200107439A ZA200107439B ZA 200107439 B ZA200107439 B ZA 200107439B ZA 200107439 A ZA200107439 A ZA 200107439A ZA 200107439 A ZA200107439 A ZA 200107439A ZA 200107439 B ZA200107439 B ZA 200107439B
- Authority
- ZA
- South Africa
- Prior art keywords
- reactor
- heat
- reaction
- internal temperature
- temperature
- Prior art date
Links
- 238000006243 chemical reaction Methods 0.000 title claims description 71
- 238000000034 method Methods 0.000 title claims description 59
- 238000012544 monitoring process Methods 0.000 title claims description 40
- 239000000178 monomer Substances 0.000 title claims description 35
- 238000007720 emulsion polymerization reaction Methods 0.000 title claims description 12
- 238000001816 cooling Methods 0.000 claims description 14
- 238000005259 measurement Methods 0.000 claims description 11
- 239000002826 coolant Substances 0.000 claims description 6
- 230000002269 spontaneous effect Effects 0.000 claims description 5
- 238000010200 validation analysis Methods 0.000 claims description 5
- 239000003999 initiator Substances 0.000 claims description 4
- 238000006116 polymerization reaction Methods 0.000 description 13
- 238000004364 calculation method Methods 0.000 description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- 239000007858 starting material Substances 0.000 description 8
- 238000009825 accumulation Methods 0.000 description 6
- 239000000498 cooling water Substances 0.000 description 6
- 229920000642 polymer Polymers 0.000 description 5
- 239000000203 mixture Substances 0.000 description 4
- 239000011541 reaction mixture Substances 0.000 description 4
- 238000010992 reflux Methods 0.000 description 4
- 238000013461 design Methods 0.000 description 3
- 239000012429 reaction media Substances 0.000 description 3
- 230000001105 regulatory effect Effects 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 230000033228 biological regulation Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 230000010354 integration Effects 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- 238000004886 process control Methods 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 1
- 101100493710 Caenorhabditis elegans bath-40 gene Proteins 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- 239000012267 brine Substances 0.000 description 1
- 238000012824 chemical production Methods 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- 230000001186 cumulative effect Effects 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 230000007257 malfunction Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 238000011017 operating method Methods 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 239000012074 organic phase Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/0006—Controlling or regulating processes
- B01J19/0013—Controlling the temperature of the process
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/0006—Controlling or regulating processes
- B01J19/002—Avoiding undesirable reactions or side-effects, e.g. avoiding explosions, or improving the yield by suppressing side-reactions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/18—Stationary reactors having moving elements inside
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/01—Processes of polymerisation characterised by special features of the polymerisation apparatus used
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00054—Controlling or regulating the heat exchange system
- B01J2219/00056—Controlling or regulating the heat exchange system involving measured parameters
- B01J2219/00058—Temperature measurement
- B01J2219/0006—Temperature measurement of the heat exchange medium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00054—Controlling or regulating the heat exchange system
- B01J2219/00056—Controlling or regulating the heat exchange system involving measured parameters
- B01J2219/00058—Temperature measurement
- B01J2219/00063—Temperature measurement of the reactants
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00054—Controlling or regulating the heat exchange system
- B01J2219/00056—Controlling or regulating the heat exchange system involving measured parameters
- B01J2219/00065—Pressure measurement
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00054—Controlling or regulating the heat exchange system
- B01J2219/00072—Mathematical modelling
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
- B01J2219/00087—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor
- B01J2219/00094—Jackets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
- B01J2219/00087—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor
- B01J2219/00103—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor in a heat exchanger separate from the reactor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00162—Controlling or regulating processes controlling the pressure
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00191—Control algorithm
- B01J2219/00193—Sensing a parameter
- B01J2219/00195—Sensing a parameter of the reaction system
- B01J2219/002—Sensing a parameter of the reaction system inside the reactor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00191—Control algorithm
- B01J2219/00211—Control algorithm comparing a sensed parameter with a pre-set value
- B01J2219/00216—Parameter value calculated by equations
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00191—Control algorithm
- B01J2219/00222—Control algorithm taking actions
- B01J2219/00225—Control algorithm taking actions stopping the system or generating an alarm
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00191—Control algorithm
- B01J2219/00222—Control algorithm taking actions
- B01J2219/00227—Control algorithm taking actions modifying the operating conditions
- B01J2219/00229—Control algorithm taking actions modifying the operating conditions of the reaction system
- B01J2219/00231—Control algorithm taking actions modifying the operating conditions of the reaction system at the reactor inlet
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00191—Control algorithm
- B01J2219/00222—Control algorithm taking actions
- B01J2219/00227—Control algorithm taking actions modifying the operating conditions
- B01J2219/00238—Control algorithm taking actions modifying the operating conditions of the heat exchange system
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00243—Mathematical modelling
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00245—Avoiding undesirable reactions or side-effects
- B01J2219/00259—Preventing runaway of the chemical reaction
- B01J2219/00261—Predicting runaway of the chemical reaction
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00245—Avoiding undesirable reactions or side-effects
- B01J2219/0027—Pressure relief
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00245—Avoiding undesirable reactions or side-effects
- B01J2219/00272—Addition of reaction inhibitor
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Polymerisation Methods In General (AREA)
- Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19905712A DE19905712A1 (de) | 1999-02-11 | 1999-02-11 | Verfahren zur kontinuierlichen Überwachung und Steuerung des Monomerenumsatzes bei der Emulsionspolymerisation |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ZA200107439B true ZA200107439B (en) | 2002-09-10 |
Family
ID=7897184
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ZA200107439A ZA200107439B (en) | 1999-02-11 | 2001-09-10 | Method for continuously monitoring and controlling the monomer conversion during emulsion polymerization. |
Country Status (16)
| Country | Link |
|---|---|
| US (1) | US6498219B1 (pt) |
| EP (1) | EP1153042B1 (pt) |
| JP (1) | JP4705245B2 (pt) |
| KR (1) | KR100651091B1 (pt) |
| CN (1) | CN1142942C (pt) |
| AR (1) | AR022562A1 (pt) |
| AT (1) | ATE316536T1 (pt) |
| AU (1) | AU772839B2 (pt) |
| BR (1) | BR0008115B1 (pt) |
| CA (1) | CA2362511C (pt) |
| DE (2) | DE19905712A1 (pt) |
| ES (1) | ES2257290T3 (pt) |
| ID (1) | ID30021A (pt) |
| TR (1) | TR200102319T2 (pt) |
| WO (1) | WO2000047632A1 (pt) |
| ZA (1) | ZA200107439B (pt) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6991763B2 (en) * | 2000-04-26 | 2006-01-31 | Rohm And Haas Company | Polymer process |
| DE10225383A1 (de) | 2002-06-07 | 2003-12-18 | Basf Ag | Verfahren zur Überwachung und Sicherung von exothermen Reaktionen |
| US20040143053A1 (en) * | 2003-01-21 | 2004-07-22 | Wu Richard Shu-Hua | Process for preparing emulsion polymers |
| EP1705193B1 (en) * | 2005-03-24 | 2008-05-14 | Rohm and Haas Company | Polymerization processes |
| CN101234322B (zh) * | 2006-01-31 | 2012-04-04 | 住友化学株式会社 | 反应控制方法 |
| CN106940331B (zh) * | 2017-03-21 | 2019-09-06 | 山东京博石油化工有限公司 | 间歇液相本体法制备聚丙烯的聚合转化率的测量方法 |
| EP3621726B1 (en) * | 2017-05-12 | 2022-01-26 | Mitec S.r.l. Società Di Ingegneria | Method and system for monitoring the operating conditions of a semibatch reactor |
| EP3922348A1 (de) | 2020-06-09 | 2021-12-15 | Basf Se | Verfahren zur überwachung eines reaktors für eine mehrphasenreaktion |
| DE102022209657A1 (de) | 2022-09-14 | 2024-03-14 | Siemens Aktiengesellschaft | Überwachung exothermer Reaktionen in einem Reaktor |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2803623A (en) * | 1951-10-29 | 1957-08-20 | Phillips Petroleum Co | Temperature control of low temperature emulsion polymerization |
| DE1283197B (de) * | 1963-09-20 | 1968-11-21 | Huels Chemische Werke Ag | Verfahren zur automatischen Regelung der Umsatzverteilung in kontinuierlich durchflossenen Reaktorreihen |
| US3563946A (en) * | 1968-01-08 | 1971-02-16 | Dow Chemical Co | Process for latex manufacture |
| US3991258A (en) * | 1970-03-10 | 1976-11-09 | Imperial Chemical Industries Limited | Control of exothermic and endothermic chemical reactions |
| JPS60248702A (ja) * | 1984-05-24 | 1985-12-09 | Mitsubishi Rayon Co Ltd | 重合反応制御方法および装置 |
| JPS6274449A (ja) * | 1985-09-28 | 1987-04-06 | Toshiba Corp | 加熱反応釜の温度制御装置 |
| JPH04106104A (ja) * | 1990-08-27 | 1992-04-08 | Nippon Zeon Co Ltd | 重合工程における反応制御方法及び反応制御装置 |
-
1999
- 1999-02-11 DE DE19905712A patent/DE19905712A1/de not_active Withdrawn
-
2000
- 2000-02-10 TR TR2001/02319T patent/TR200102319T2/xx unknown
- 2000-02-10 ES ES00916827T patent/ES2257290T3/es not_active Expired - Lifetime
- 2000-02-10 EP EP00916827A patent/EP1153042B1/de not_active Expired - Lifetime
- 2000-02-10 CA CA002362511A patent/CA2362511C/en not_active Expired - Fee Related
- 2000-02-10 AR ARP000100580A patent/AR022562A1/es not_active Application Discontinuation
- 2000-02-10 BR BRPI0008115-9A patent/BR0008115B1/pt not_active IP Right Cessation
- 2000-02-10 JP JP2000598547A patent/JP4705245B2/ja not_active Expired - Fee Related
- 2000-02-10 CN CNB008036705A patent/CN1142942C/zh not_active Expired - Fee Related
- 2000-02-10 AU AU38037/00A patent/AU772839B2/en not_active Ceased
- 2000-02-10 AT AT00916827T patent/ATE316536T1/de not_active IP Right Cessation
- 2000-02-10 WO PCT/EP2000/001091 patent/WO2000047632A1/de active IP Right Grant
- 2000-02-10 ID IDW00200101977A patent/ID30021A/id unknown
- 2000-02-10 KR KR1020017010101A patent/KR100651091B1/ko not_active IP Right Cessation
- 2000-02-10 DE DE50012127T patent/DE50012127D1/de not_active Expired - Lifetime
- 2000-02-11 US US09/890,968 patent/US6498219B1/en not_active Expired - Lifetime
-
2001
- 2001-09-10 ZA ZA200107439A patent/ZA200107439B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| DE19905712A1 (de) | 2000-08-17 |
| CN1142942C (zh) | 2004-03-24 |
| EP1153042B1 (de) | 2006-01-25 |
| JP2002536509A (ja) | 2002-10-29 |
| US6498219B1 (en) | 2002-12-24 |
| ID30021A (id) | 2001-11-01 |
| TR200102319T2 (tr) | 2001-11-21 |
| BR0008115B1 (pt) | 2010-01-26 |
| AU3803700A (en) | 2000-08-29 |
| AR022562A1 (es) | 2002-09-04 |
| ES2257290T3 (es) | 2006-08-01 |
| KR100651091B1 (ko) | 2006-11-29 |
| EP1153042A1 (de) | 2001-11-14 |
| ATE316536T1 (de) | 2006-02-15 |
| JP4705245B2 (ja) | 2011-06-22 |
| BR0008115A (pt) | 2001-11-06 |
| CA2362511A1 (en) | 2000-08-17 |
| KR20010102026A (ko) | 2001-11-15 |
| CN1340062A (zh) | 2002-03-13 |
| DE50012127D1 (de) | 2006-04-13 |
| AU772839B2 (en) | 2004-05-06 |
| WO2000047632A1 (de) | 2000-08-17 |
| CA2362511C (en) | 2008-05-06 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Soroush et al. | Nonlinear control of a batch polymerization reactor: an experimental study | |
| Russell et al. | Recursive data‐based prediction and control of batch product quality | |
| CA2362511C (en) | Method for continuously monitoring and controlling the monomer conversion during emulsion polymerization | |
| Soroush et al. | Optimal design and operation of batch reactors. 2. A case study | |
| US8273299B2 (en) | Reactor cooling system | |
| US20120173002A1 (en) | Two-degree-of-freedom control having an explicit switching for controlling chemical engineering processes | |
| JP4405383B2 (ja) | 発熱反応をモニタリング及び保護する方法 | |
| CN114288956B (zh) | 反应器温度控制方法、装置和计算机设备 | |
| Scali et al. | Control of the quality of polymer products in continuous reactors: comparison of performance of state estimators with and without updating of parameters | |
| CN109932899B (zh) | 化工产品生产中反应温度的优化控制方法及系统 | |
| JPH08220279A (ja) | プラント制御装置、その異常同定方法および異常同定装置 | |
| MXPA01007427A (es) | Metodo para supervision y control continuos de la conversion de monomeros durante la polimerizacion en emulsion | |
| WO2005063822A1 (en) | Polymer reaction and quality optimizer | |
| Knudsen | Proactive actuator fault-tolerance in economic MPC for nonlinear process plants | |
| US20130203946A1 (en) | Method For Controlling Bubble Formation In Polymerization Reactors | |
| Soroush et al. | Model-Predictive Safety System for Predictive Detection of Operation Hazards | |
| Gygax | Thermal process safety: data assessment criteria measures | |
| Ampelli et al. | Investigation of thermal runaway in semibatch chemical reactors by an early warning detection device | |
| JPH0288602A (ja) | 重合温度の制御方法 | |
| Schork | Reactor operation and control | |
| JPS59161707A (ja) | プラントの運転操作ガイド装置 | |
| CN118313214A (zh) | 一种基于过程安全时间的平推流反应器的本质安全设计方法 | |
| Joseph | Framework of the Control Problem | |
| CN117502910A (zh) | 一种出热水控制方法、设备、装置及介质 | |
| C C | Reactor Control |