WO2024053250A1 - Système de chaudières - Google Patents
Système de chaudières Download PDFInfo
- Publication number
- WO2024053250A1 WO2024053250A1 PCT/JP2023/026068 JP2023026068W WO2024053250A1 WO 2024053250 A1 WO2024053250 A1 WO 2024053250A1 JP 2023026068 W JP2023026068 W JP 2023026068W WO 2024053250 A1 WO2024053250 A1 WO 2024053250A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- gas
- boiler
- oxygen
- combustion
- line
- Prior art date
Links
- 239000007789 gas Substances 0.000 claims abstract description 192
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 125
- 239000001301 oxygen Substances 0.000 claims abstract description 125
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 125
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims abstract description 24
- 229910001882 dioxygen Inorganic materials 0.000 claims abstract description 24
- 239000002737 fuel gas Substances 0.000 claims abstract description 14
- 238000002485 combustion reaction Methods 0.000 claims description 83
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 23
- 239000000446 fuel Substances 0.000 claims description 8
- 239000008400 supply water Substances 0.000 abstract 1
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 18
- 229910002092 carbon dioxide Inorganic materials 0.000 description 9
- 238000001816 cooling Methods 0.000 description 7
- 238000000034 method Methods 0.000 description 7
- 238000011084 recovery Methods 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 5
- 239000000498 cooling water Substances 0.000 description 5
- 238000003359 percent control normalization Methods 0.000 description 4
- 239000000203 mixture Substances 0.000 description 3
- 238000006386 neutralization reaction Methods 0.000 description 3
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 3
- 238000010248 power generation Methods 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- 238000011144 upstream manufacturing Methods 0.000 description 3
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 239000003245 coal Substances 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 230000004044 response Effects 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- 239000002351 wastewater Substances 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000004308 accommodation Effects 0.000 description 1
- 239000004063 acid-resistant material Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000010842 industrial wastewater Substances 0.000 description 1
- 230000007257 malfunction Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000004043 responsiveness Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
Images
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F22—STEAM GENERATION
- F22B—METHODS OF STEAM GENERATION; STEAM BOILERS
- F22B35/00—Control systems for steam boilers
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F22—STEAM GENERATION
- F22D—PREHEATING, OR ACCUMULATING PREHEATED, FEED-WATER FOR STEAM GENERATION; FEED-WATER SUPPLY FOR STEAM GENERATION; CONTROLLING WATER LEVEL FOR STEAM GENERATION; AUXILIARY DEVICES FOR PROMOTING WATER CIRCULATION WITHIN STEAM BOILERS
- F22D1/00—Feed-water heaters, i.e. economisers or like preheaters
- F22D1/02—Feed-water heaters, i.e. economisers or like preheaters with water tubes arranged in the boiler furnace, fire tubes, or flue ways
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN A CARRIER GAS OR AIR
- F23C9/00—Combustion apparatus characterised by arrangements for returning combustion products or flue gases to the combustion chamber
- F23C9/08—Combustion apparatus characterised by arrangements for returning combustion products or flue gases to the combustion chamber for reducing temperature in combustion chamber, e.g. for protecting walls of combustion chamber
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES
- F23J15/00—Arrangements of devices for treating smoke or fumes
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23L—SUPPLYING AIR OR NON-COMBUSTIBLE LIQUIDS OR GASES TO COMBUSTION APPARATUS IN GENERAL ; VALVES OR DAMPERS SPECIALLY ADAPTED FOR CONTROLLING AIR SUPPLY OR DRAUGHT IN COMBUSTION APPARATUS; INDUCING DRAUGHT IN COMBUSTION APPARATUS; TOPS FOR CHIMNEYS OR VENTILATING SHAFTS; TERMINALS FOR FLUES
- F23L7/00—Supplying non-combustible liquids or gases, other than air, to the fire, e.g. oxygen, steam
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23N—REGULATING OR CONTROLLING COMBUSTION
- F23N5/00—Systems for controlling combustion
Definitions
- the present invention relates to a boiler system, and particularly to a boiler system that can increase the CO 2 concentration in exhaust gas discharged from a small boiler.
- Non-Patent Document 1 and Patent Document 1 a method has been proposed to increase the CO2 concentration in exhaust gas by performing oxy-combustion instead of conventional air-combustion in the boiler of a coal-fired power plant. Demonstration tests have also been conducted on carbon dioxide capture and storage (Non-Patent Document 1 and Patent Document 1).
- Oxygen combustion is a method of burning fuel by supplying oxygen gas instead of air as an oxidizing agent or combustion-supporting gas.
- the exhaust gas contains almost no nitrogen component, so the main component of the exhaust gas (for example, 90% or more in the case of coal combustion) can be CO 2 gas. Therefore, if oxyfuel combustion is used, it becomes easier to separate and recover CO 2 by cooling the exhaust gas.
- Non-Patent Document 1 and Patent Document 1 a part of the exhaust gas is circulated and the produced oxygen is mixed with recirculated gas (mainly CO 2 gas) to reduce the oxygen concentration.
- recirculated gas mainly CO 2 gas
- an oxygen production device is installed near the boiler to produce high-purity oxygen from the taken in air using a cryogenic separation method or the like.
- electric power is required to produce oxygen, it is conceivable to take in atmospheric air and perform air combustion as in the past until the start of power generation.
- Patent Document 2 discloses a boiler plant for coal-fired power generation that can switch between oxygen combustion and air combustion.
- air combustion can be performed by supplying atmospheric air instead of oxygen gas and circulating exhaust gas when the boiler is started before shifting to oxyfuel combustion.
- the air supply system was closed and oxygen gas and circulating exhaust gas were supplied to the boiler, which led to the oxy-combustion of coal. Can be easily migrated.
- Patent Document 2 describes a technique for controlling the oxygen concentration in combustion-supporting gas by adjusting the flow rate of circulating exhaust gas, and controlling the ratio of the amount of oxygen to the amount of fuel to a desired setting.
- the oxygen concentration can be calculated from each gas flow rate command value as a ratio of the oxygen flow rate to the total gas flow rate. Furthermore, by setting the feed water temperature based on the calculated oxygen concentration, it is also possible to control the temperature of water or steam flowing through the heat exchanger within an allowable range for safe operation.
- Patent Documents 3 and 4 describe specific exhaust gas CO 2 separation/recovery devices.
- Patent Document 5 describes a technique for adjusting the CO 2 concentration in exhaust gas in a relatively small boiler. However, this exhaust gas is used to neutralize the boiler effluent, and the CO2 concentration is simply adjusted by adjusting the amount of air mixed before being introduced into the boiler effluent. .
- the present invention has been made to solve the above problems, and even when using a small boiler that requires relatively high response in combustion control, it is possible to achieve oxy-fuel combustion while achieving stable combustion.
- the purpose of the present invention is to provide a boiler system that can improve the CO 2 concentration in exhaust gas.
- a boiler system includes a boiler that heats feed water by burning fuel gas, an exhaust line that exhausts exhaust gas from the boiler, and a circulating gas line that branches from the exhaust line, a circulating gas line to which a supply line and an atmospheric supply line are connected and capable of supplying the exhaust gas to the boiler as a combustion supporting gas together with at least one of atmospheric air and oxygen gas;
- a damper for controlling suction is provided, and the oxygen supply line includes a main line provided with an on/off valve and a subline provided with a variable opening valve, and the oxygen supply line includes a main line provided with an on/off valve and a subline provided with a variable opening valve.
- Adjusting the oxygen concentration in the mixed gas of the oxygen gas from the oxygen supply line and the exhaust gas by closing the damper and controlling the opening/closing of the on/off valve and the opening degree of the variable opening valve of the oxygen supply line. It is configured such that it can be supplied to the boiler as a combustion-supporting gas.
- the boiler system includes a combustion-supporting gas fan provided near the boiler for delivering the combustion-supporting gas from the circulating gas line to the boiler;
- the fuel cell further includes an oxygen sensor that measures the oxygen concentration in the combustion-supporting gas sent to the boiler, and the variable opening valve is configured to be feedback-controlled based on the output of the oxygen sensor.
- the outlet of the combustion-supporting gas fan is connected to a burner wind box provided in the boiler, and the oxygen sensor measures the oxygen concentration of the gas inside the burner wind box. Based on the output of the oxygen sensor, the variable opening valve is controlled so that the oxygen concentration of the gas inside the burner wind box is maintained at 20 to 22%.
- the main line of the oxygen supply line is configured by a plurality of lines connected in parallel, each of which is provided with the on/off valve, and by controlling each on/off valve of the plurality of lines, the main line is It is configured so that oxygen gas can be supplied from the line at multiple flow rates.
- a manual valve is provided on at least one of the primary side and the secondary side of the variable opening valve provided in the subline of the oxygen supply line, and a manual valve is provided on at least one of the primary side and secondary side of the variable opening valve provided in the subline of the oxygen supply line, and ⁇ 90% of oxygen can be supplied through the main line, and 0 ⁇ 50% of the theoretical combustion oxygen amount required for combustion can be supplied through the subline. .
- the boiler system further includes an economizer that preheats water supplied to the boiler using the heat of exhaust gas from the boiler, and a gas cooler that cools the exhaust gas downstream of the economizer, and the exhaust line includes:
- the gas cooler is provided to exhaust the exhaust gas cooled by the gas cooler, and the gas cooler is configured to be able to cool the outlet temperature of the exhaust gas to 30°C to 50°C.
- the on-off valve provided in the main line of the oxygen supply line is a solenoid valve
- the variable opening valve provided in the subline of the oxygen supply line is an electric valve
- the fuel gas is either city gas or LP gas
- the boiler is either a once-through boiler or a hot water boiler.
- FIG. 1 is a schematic diagram showing a boiler system according to an embodiment of the present invention.
- FIG. 2 is a diagram illustrating one aspect of an oxygen supply line according to an embodiment of the invention.
- FIG. 1 shows a boiler system 100 according to an embodiment of the invention.
- the boiler system 100 includes a combustion boiler 10 having a burner 11 that burns fuel gas GF, an economizer 12 through which exhaust gas GE from the boiler 10 passes, and a cooling system for cooling the exhaust gas GE that has passed through the economizer 12.
- a gas cooler 14 and an exhaust line 16 for exhausting the exhaust gas GE cooled by the gas cooler 14 are provided.
- the boiler 10 used in this embodiment is a relatively small once-through boiler or a hot water boiler, for example.
- the fuel gas GF used is, for example, city gas (or gas containing methane as a main component) or LP gas (or gas containing propane or butane as a main component).
- the boiler system 100 is configured to generate and provide steam or hot water using a relatively small boiler 10, and is installed in various factories, residences/accommodations, hot bath facilities, etc., depending on the purpose. It is possible to provide hot water or steam at an appropriate temperature.
- the boiler 10 can heat the water supply W1 to the boiler 10 by burning the fuel gas GF with the burner 11, and can generate hot water and steam.
- the economizer 12 can preheat the feed water W1 before supplying it to the boiler 10 using the heat of the exhaust gas GE from the boiler 10, and can save the amount of fuel gas GF consumed.
- the gas cooler 14 exchanges heat with the supplied cooling water W2 using various heat exchangers (for example, a plate heat exchanger or a tube heat exchanger), thereby reducing exhaust gas GE. is configured to cool the The gas cooler 14 is configured to be able to cool the exhaust gas until the outlet temperature T1 reaches, for example, about 30 to 50°C, particularly about 40°C. Thereby, steam contained in the exhaust gas can be converted into drain in the gas cooler 14, and dry exhaust gas can be obtained.
- various heat exchangers for example, a plate heat exchanger or a tube heat exchanger
- Blow water from the boiler 10, drain from the economizer 12, and drain from the gas cooler 14 are sent to the neutralization device 18.
- the neutralization device 18 neutralizes wastewater using various methods, adjusts the pH value to meet industrial wastewater standards, and discharges the wastewater to the outside.
- the exhaust line 16 is provided to discharge the cooled exhaust gas GE from the flue 16A into the atmosphere or to transfer it to the CO 2 recovery facility via the CO 2 recovery line 16B.
- the CO 2 concentration in the exhaust gas can be increased by performing oxygen combustion, so it is possible to efficiently recover CO 2 from the exhaust gas sent through the CO 2 recovery line 16B.
- the exhaust line 16 may be provided with any exhaust gas treatment device such as a bag filter, if necessary.
- a circulating gas line 20 branching from the exhaust line 16 is connected to the exhaust line 16.
- the circulating gas line 20 is configured to be able to circulate the exhaust gas GE cooled by the gas cooler 14 to the boiler 10 using a forced fan (combustion-supporting gas fan) 22 provided near the boiler.
- the circulating gas line 20 is provided with a damper 24 for drawing in circulating gas driven by a motor M, and by adjusting the opening degree of the damper 24 for drawing in circulating gas, exhaust gas GE is supplied to the boiler 10 at an arbitrary flow rate. be able to.
- an atmosphere supply line 26 and an oxygen supply line 30 are connected to the circulating gas line 20.
- atmospheric air AIR, oxygen gas O 2 and/or exhaust gas GE drawn from the exhaust line 16 can be supplied to the boiler 10 as the combustion-supporting gas GS.
- the boiler 10 is capable of performing both air combustion and oxygen combustion.
- the atmospheric supply line 26 is connected to the upstream side of the oxygen supply line 30, but on the contrary, the oxygen supply line 30 may be connected to the upstream side.
- the atmospheric supply line 26 and the oxygen supply line 30 do not necessarily need to be connected to different places, but are connected using a common line at the same connection point of the circulating gas line 20, and are branched on the upstream side of the common line. may be arranged in parallel.
- the atmospheric supply line 26 and the oxygen supply line 30 may be connected in any manner as long as they communicate with the circulating gas line 20 between the circulating gas drawing damper 24 and the boiler 10.
- the forced fan 22 as a combustion-supporting gas fan provided near the boiler is used to form the gas flow in the circulating gas line 20 toward the boiler, but instead of this, Alternatively, in addition to this, another blower (such as a forced fan or an induced fan) may be provided in the circulating gas line 20. Further, an arbitrary blower may be provided in the exhaust line 16 as well, if necessary.
- the atmosphere supply line 26 connected to the circulating gas line 20 is provided with an atmosphere suction damper 28 driven by a motor M.
- atmospheric air (air) AIR can be supplied to the boiler 10 at an arbitrary flow rate.
- air whose flow rate can be controlled can be supplied to the boiler 10 as the combustion-supporting gas GS via the circulating gas line 20, so that oxy-fuel combustion can be performed stably, such as when starting up the boiler.
- boiler operation using air combustion can be performed.
- air is supplied to the boiler 10 at a controlled flow rate via the atmospheric suction damper 28 whose opening degree is adjusted, while the circulating gas suction damper 24 and the oxygen Supply line 30 remains closed.
- the oxygen supply line 30 used for oxygen combustion is composed of a main line 30A and a subline 30B connected in parallel.
- the main line 30A and the subline 30B are connected to the same oxygen supply source, but they may be connected to different oxygen supply sources.
- oxygen supply source for example, oxygen gas generated from air by pressure swing adsorption (PSA) can be used.
- PSA pressure swing adsorption
- the main line 30A of the oxygen supply line 30 is provided with an on/off valve 32, while the subline 30B is provided with a variable opening valve (typically a proportional valve) 34.
- the on-off valve 32 is constituted by a solenoid valve (solenoid valve S), and the variable opening valve 34 is constituted by an electric valve driven by motor M.
- the on-off valve 32 may be configured by, for example, an air-operated valve (AOV).
- the main line 30A can supply 80 to 90% of the theoretical combustion oxygen amount required for combustion that matches the composition and flow rate of the fuel gas GF
- the subline 30B can supply oxygen that is 80% to 90% of the theoretical combustion
- the flow rate of oxygen gas in each line is controlled so that 0 to 50% of the amount of oxygen can be supplied.
- the oxygen gas supplied from the oxygen supply line 30 is mixed with the exhaust gas GE introduced by opening the circulating gas intake damper 24, and is supplied to the boiler 10 as a combustion-supporting gas GS with an adjusted oxygen concentration.
- the sub-line 30B is composed of one line provided with a single variable-opening valve 34, whereas the main line 30A is composed of a single line provided with an on-off valve 32, respectively. Consists of multiple parallel lines.
- FIG. 2 shows an example in which the main line 30A is composed of three lines.
- a main line 30A is composed of lines 301, 302, and 303 connected in parallel, and each line 301, 302, and 303 is connected to an on-off valve (here, a solenoid valve) 321, 322, and 323. are provided for each.
- the rated flow rate (or CV value: the flow rate coefficient of the fluid passing through the open valve when the inlet pressure and outlet pressure values are the specified values) of each on-off valve 321, 322, and 323 when open is the same. It may be different, or it may be different.
- the on-off valves 321, 322, and 323 by controlling the opening and closing of the on-off valves 321, 322, and 323, it is possible to immediately control the oxygen flow rate in multiple stages that match the combustion pattern of the boiler. For example, in the case of 4-position control that controls the combustion pattern at 0%-20%-50%-100%, 0% control is performed with all on-off valves closed, and 20% control is performed with only the on-off valve 321 open. 50% control can be performed with the on-off valves 321 and 322 open, and 100% control can be performed with all the on-off valves 321, 322, and 323 open. In each combustion pattern, the total amount of oxygen supplied via each line is adjusted according to the fluctuation of the fuel gas flow rate so that the amount of oxygen is 80 to 90% of the theoretical combustion oxygen amount as described above. ing.
- main line 30A is also configured with one line, as in the subline 30B, as shown in Fig. 1. may have been done.
- each electromagnetic valve constituting the on-off valve 32 has sufficiently high responsiveness compared to a motor-driven electric valve (opening variable valve 34). Therefore, opening control of each electromagnetic valve can be performed at high speed to match the combustion pattern, and thereby oxygen gas can be supplied at a flow rate that can prevent occurrence of combustion defects. Furthermore, since the on/off valves 32 are provided in a plurality of lines and the flow rate is controlled by controlling the opening and closing of the valves, instantaneous switching between a large flow rate and a small flow rate can be realized relatively easily.
- the output adjustment of small boilers is often switched in a very short time (for example, 2 to 3 seconds, often within 5 seconds) in accordance with the demands of the heat demand side, and the output is high for a narrow combustion chamber. Since combustion is performed using a burner, the amount of oxygen required for fuel combustion may change in a short period of time each time the output is switched. For this reason, if there is even a slight delay in the supply of the required amount of oxygen, it will instantly lead to incomplete combustion, oscillating combustion, and even misfire. In contrast, although the flow rate is controlled in stages, oxygen is supplied from the main line 30A, which is highly responsive and can control the flow rate from small to large. It is possible to reliably supply a limited amount of oxygen. Therefore, the boiler system 100 can prevent misfires and poor combustion even when used as a small boiler with severe output fluctuations.
- a manual valve 38 may be provided on at least one of the primary side and the secondary side of the variable opening valve 34.
- FIG. 1 shows an example in which a manual valve 38 is provided on the primary side of the variable opening valve 34
- FIG. 2 shows an example in which a manual valve 38 is provided on the secondary side of the variable opening valve 34.
- Manual valve 38 arranged in this manner can be used to adjust the maximum control flow rate in subline 30B.
- a subline 30B having a variable opening valve 34 is used.
- the oxygen concentration in the combustion-supporting gas GS formed by the mixture of oxygen gas O 2 from the oxygen supply line 30, exhaust gas from the exhaust line 16, and GE is equivalent to, for example, the oxygen concentration in the atmosphere.
- the overall flow rate of oxygen gas can be fine-tuned so that it remains stable at a ratio of about 21% (eg, 20-22%).
- variable opening valve 34 has a CV value (CV value) that can supply up to about half of the required amount of oxygen. or rated flow rate value).
- the boiler system 100 of this embodiment includes an oxygen sensor 36a for measuring the oxygen concentration of the combustion-supporting gas GS supplied to the burner 11. More specifically, the oxygen sensor 36a is attached to the burner wind box 13 to which the outlet of the forced fan 22 is connected, and is installed to measure the oxygen concentration of the gas inside the burner wind box 13. .
- the oxygen sensor 36a for example, a galvanic cell type sensor is suitably used, but various types of sensors can be used as long as they can measure the oxygen concentration.
- an oxygen concentration control circuit 36b is connected to the oxygen sensor 36a.
- the oxygen concentration control circuit 36b is configured to feedback control the variable opening valve 34 provided in the subline 30B of the oxygen supply line 30 based on the output of the oxygen sensor 36a.
- the variable opening valve 34 is opened with a manipulated variable according to the difference. Increase oxygen concentration. Further, when the oxygen concentration output by the oxygen sensor 36a is higher than 22%, the opening degree of the variable opening valve 34 is closed with a manipulated variable according to the difference to lower the oxygen concentration. In this way, by feedback-controlling the variable opening valve 34 using the oxygen concentration control circuit 36b so that the difference between the set concentration and the measured concentration approaches 0, a desired set oxygen concentration is set for the burner 11. It is possible to continue supplying the combustion-supporting gas GS having the following properties. Note that it goes without saying that the set oxygen concentration may be a constant value (for example, 21%).
- the boiler system 100 can supply the combustion-supporting gas GS, which is a mixture of oxygen gas and exhaust gas (mainly CO 2 ), to the boiler 10 via the circulating gas line 20. Oxygen combustion can be performed stably.
- exhaust gas mixed with oxygen gas is supplied to the boiler 10 as the combustion-supporting gas GS, while normally the atmosphere suction damper 28 is closed and the atmosphere supply line 26 is closed. remains closed.
- the circulating gas suction damper 24 and the on/off valve 32 in the main line 30A are opened in synchronization with the closing operation of the atmospheric suction damper 28.
- an oxygen concentration adjustment operation by adjusting the opening of the variable opening valve 34 in the sub-line 30B is also started.
- the boiler system 100 closes the damper 28 of the atmospheric supply line 26 and controls the opening/closing of the on/off valve 32 and the opening degree of the variable opening valve 34 of the oxygen supply line 30, thereby removing oxygen gas O 2 from the oxygen supply line.
- this is configured to be able to be supplied to the boiler 10 as a combustion-supporting gas GS to perform oxy-fuel combustion.
- the boiler system 100 it is possible to smoothly transition from air combustion to oxyfuel combustion when the boiler is started, and after switching to oxyfuel combustion, the oxygen supply amount can be quickly switched to match the output change characteristics of the small boiler. By doing so, it is possible to discharge exhaust gas with a high concentration of CO 2 while preventing the occurrence of combustion defects such as incomplete combustion and misfire.
- the gas cooler 14 in this embodiment is configured to lower the exhaust gas outlet temperature T1 to, for example, 30° C. to 50° C. to obtain dry exhaust gas.
- the exhaust gas GE does not contain corrosive gases such as sulfur, so it is cooled to near room temperature.
- the cooling water W2 used in the gas cooler 14 is typically provided using a cooling water circulation line that includes a cooling system such as a cooling tower that is provided as a separate system from the supply system for the boiler feed water W1.
- a cooling system such as a cooling tower that is provided as a separate system from the supply system for the boiler feed water W1.
- the gas cooler 14 a large amount of drain is generated during cooling of the exhaust gas.
- the exhaust gas GE flows downward from the top of the gas cooler 14 toward the bottom.
- the cooling water W2 be allowed to flow upward in order to prevent the formation of air pockets.
- the gas cooler 14 be constructed using an acid-resistant material. Note that it is preferable that the gas cooler 14 be constructed using a material having an appropriate heat-resistant temperature, taking into consideration the inlet exhaust gas temperature when the economizer 12 is operated by bypass.
- the boiler system according to the embodiment of the present invention is suitably used in, for example, a small steam boiler or a water heater to increase the CO 2 concentration in exhaust gas while continuing stable combustion.
- Boiler 12 Economizer 14 Gas cooler 16 Exhaust line 18 Neutralization device 20 Circulating gas line 22 Forced fan (combustion-supporting gas fan) 24 Damper for drawing in circulating gas 26 Atmospheric supply line 28 Damper for atmospheric suction 30 Oxygen supply line 30A Main line 30B Sub line 32 On-off valve (electromagnetic valve) 34 Adjustable opening valve (motorized valve) 36a Oxygen sensor 36b Oxygen concentration control circuit 38 Manual valve 100 Boiler system GE Exhaust gas GF Fuel gas GS Combustion supporting gas
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
Abstract
Un système de chaudière (100) comprend : une chaudière (10) qui brûle du gaz combustible (GF) afin de chauffer l'eau d'alimentation (W1); une ligne d'échappement (16) qui évacue le gaz d'échappement (GE) de la chaudière; une ligne de circulation (20) qui se ramifie à partir de la ligne d'échappement, a raccordé à celle-ci une conduite d'alimentation en oxygène (30) et une conduite d'alimentation en air (26), et fournit de l'air ou de l'oxygène gazeux conjointement avec le gaz d'échappement (GE) à la chaudière en tant que gaz de support de combustion (GS). La conduite d'alimentation en oxygène (30) comprend une conduite principale (30A) pourvue d'une soupape MARCHE/ARRÊT (32), et une sous-conduite (30B) comprenant une soupape d'ouverture réglable (34), et est conçue pour pouvoir régler une concentration en oxygène dans un gaz mixte de l'oxygène gazeux et du gaz d'échappement et fournir le gaz mélangé à la chaudière.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2022-143700 | 2022-09-09 | ||
JP2022143700 | 2022-09-09 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2024053250A1 true WO2024053250A1 (fr) | 2024-03-14 |
Family
ID=90192432
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP2023/026068 WO2024053250A1 (fr) | 2022-09-09 | 2023-07-14 | Système de chaudières |
Country Status (1)
Country | Link |
---|---|
WO (1) | WO2024053250A1 (fr) |
Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS57104144U (fr) * | 1980-12-18 | 1982-06-26 | ||
JPH04320702A (ja) * | 1991-04-19 | 1992-11-11 | Toshiba Corp | 排気再燃式複合発電所の給水流量制御装置 |
JPH0526409A (ja) * | 1991-07-16 | 1993-02-02 | Babcock Hitachi Kk | Co2回収型ボイラ |
JPH0778032A (ja) * | 1993-07-30 | 1995-03-20 | Perkin Elmer Corp:The | 流体の流量を変化させる弁装置 |
JP2001336736A (ja) * | 2000-05-30 | 2001-12-07 | Ishikawajima Harima Heavy Ind Co Ltd | 酸素燃焼ボイラ設備の排ガス酸素濃度制御方法及び装置 |
JP2007147162A (ja) * | 2005-11-28 | 2007-06-14 | Electric Power Dev Co Ltd | 酸素燃焼ボイラの燃焼制御方法及び装置 |
JP2012052675A (ja) * | 2010-08-31 | 2012-03-15 | Hitachi Ltd | 酸素燃焼ボイラプラントの制御装置,制御方法,表示方法 |
WO2012049842A1 (fr) * | 2010-10-15 | 2012-04-19 | バブコック日立株式会社 | Système de combustion pour chaudière et son procédé d'exploitation |
CN205288072U (zh) * | 2016-01-12 | 2016-06-08 | 李永陆 | 一种脱硝剂稀释混合计量分配的装置 |
-
2023
- 2023-07-14 WO PCT/JP2023/026068 patent/WO2024053250A1/fr unknown
Patent Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS57104144U (fr) * | 1980-12-18 | 1982-06-26 | ||
JPH04320702A (ja) * | 1991-04-19 | 1992-11-11 | Toshiba Corp | 排気再燃式複合発電所の給水流量制御装置 |
JPH0526409A (ja) * | 1991-07-16 | 1993-02-02 | Babcock Hitachi Kk | Co2回収型ボイラ |
JPH0778032A (ja) * | 1993-07-30 | 1995-03-20 | Perkin Elmer Corp:The | 流体の流量を変化させる弁装置 |
JP2001336736A (ja) * | 2000-05-30 | 2001-12-07 | Ishikawajima Harima Heavy Ind Co Ltd | 酸素燃焼ボイラ設備の排ガス酸素濃度制御方法及び装置 |
JP2007147162A (ja) * | 2005-11-28 | 2007-06-14 | Electric Power Dev Co Ltd | 酸素燃焼ボイラの燃焼制御方法及び装置 |
JP2012052675A (ja) * | 2010-08-31 | 2012-03-15 | Hitachi Ltd | 酸素燃焼ボイラプラントの制御装置,制御方法,表示方法 |
WO2012049842A1 (fr) * | 2010-10-15 | 2012-04-19 | バブコック日立株式会社 | Système de combustion pour chaudière et son procédé d'exploitation |
CN205288072U (zh) * | 2016-01-12 | 2016-06-08 | 李永陆 | 一种脱硝剂稀释混合计量分配的装置 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US8584604B2 (en) | Method and apparatus for controlling combustion in oxygen fired boiler | |
US6247315B1 (en) | Oxidant control in co-generation installations | |
JP5461873B2 (ja) | 酸素燃焼石炭燃料ボイラ及び空気燃焼と酸素燃焼との間の移行方法 | |
JP5138028B2 (ja) | 酸素燃焼ボイラの酸素供給制御方法及び装置 | |
US8561555B2 (en) | Oxyfuel combustion boiler plant and operating method for the same | |
JP5270661B2 (ja) | 酸素燃焼ボイラの排ガス制御方法及び装置 | |
WO2009110035A1 (fr) | Procédé de régulation de la combustion dans une chaudière de combustion d'oxygène et appareil associé | |
JP2010101587A (ja) | 酸素燃焼ボイラ及び酸素燃焼ボイラの制御方法 | |
JP2004516446A (ja) | 酸素分離燃焼装置とその方法 | |
WO2009110034A1 (fr) | Procédé de contrôle du débit des gaz d'échappement de recirculation principaux dans une chaudière à combustion d'oxygène et son appareil | |
JP2011523012A (ja) | 酸素燃焼によって動力を発生させるための方法及び装置 | |
JP5130145B2 (ja) | ボイラプラント,ボイラプラントの制御装置及びその制御方法 | |
JP5487509B2 (ja) | ボイラ燃焼システムとその運転方法 | |
WO2024053250A1 (fr) | Système de chaudières | |
JP4859512B2 (ja) | 燃焼ボイラの制御方法 | |
JP2012137269A (ja) | 石炭火力発電プラント及び石炭火力発電プラントの制御方法 | |
JPS63254391A (ja) | 炉システム | |
JP2010060156A (ja) | 加熱炉のNOx抑制制御装置 | |
KR102258738B1 (ko) | 가압 순산소 연소와 상압 석탄 연소가 연계된 연소 시스템 | |
JP6357701B1 (ja) | 燃焼状態判定システム | |
JP2013057417A (ja) | 石炭火力発電プラント | |
JPH03160210A (ja) | 燃焼装置 | |
CN117628518A (zh) | 一种rto氧化炉的低氮工艺及设备 | |
JPH04340010A (ja) | 微粉炭・酸素バーナーを用いた微粉炭燃焼方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 23862794 Country of ref document: EP Kind code of ref document: A1 |