Classifications

• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
  • A61K8/00—Cosmetics or similar toiletry preparations
  • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
  • A61K8/0216—Solid or semisolid forms
  • A61K8/022—Powders; Compacted Powders
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
  • A61K8/00—Cosmetics or similar toiletry preparations
  • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
  • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
  • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
  • A61K8/37—Esters of carboxylic acids
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
  • A61K8/00—Cosmetics or similar toiletry preparations
  • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
  • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
  • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
  • A61K8/37—Esters of carboxylic acids
  • A61K8/375—Esters of carboxylic acids the alcohol moiety containing more than one hydroxy group
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
  • A61K8/00—Cosmetics or similar toiletry preparations
  • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
  • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
  • A61K8/67—Vitamins
  • A61K8/678—Tocopherol, i.e. vitamin E
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
  • A61K8/00—Cosmetics or similar toiletry preparations
  • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
  • A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
  • A61K8/922—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
  • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
  • A61Q1/02—Preparations containing skin colorants, e.g. pigments
  • A61Q1/10—Preparations containing skin colorants, e.g. pigments for eyes, e.g. eyeliner, mascara
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
  • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
  • A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
  • A61K2800/26—Optical properties
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
  • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
  • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
  • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
  • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
  • A61K2800/41—Particular ingredients further characterized by their size
  • A61K2800/412—Microsized, i.e. having sizes between 0.1 and 100 microns
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
  • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
  • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
  • A61K2800/42—Colour properties
  • A61K2800/43—Pigments; Dyes
  • A61K2800/436—Interference pigments, e.g. Iridescent, Pearlescent
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
  • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
  • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
  • A61K2800/52—Stabilizers
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
  • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
  • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
  • A61K2800/52—Stabilizers
  • A61K2800/524—Preservatives

Definitions

• the present disclosure generally relates to powdery makeup compositions for the skin and hair. More particularly, the present disclosure relates to powdery eye makeup compositions that comprise metallic, pearlescent or other color effect pigments.
• pearlescent pigments create interference effects that depend on the angles of illumination and observation.
• pearlescent pigments may produce a deep gloss and sheen when applied to the skin surface.
• the look conferred by pearlescent pigments is considered aesthetically pleasing,broader, and sensual.
• Typical pearlescent pigments are plate-like particles that consist of mica coated with titanium dioxide and/or iron oxides. The thickness of the coating varies, which gives rise to a range of refractive indices and an assortment of visual effects. Particle size will also affect the feel of the cosmetic when applied to the skin. Roughly speaking, pearlescent pigments in the range of l-15pm confer a velvety feel and a matte shimmer. As pigment size increases slightly (5- 25 pm) the feel becomes more silky and the visual effect more satin. As pigment size is further increased (about 50pm), a sparkly appearance develops. This sparkle effect is increasingly pronounced as pigment size increases at least to about 500pm.
• Cosmetic metallic pigments are very thm platelet-shaped particles typically made out of borosilicates, synthetic fluorphlogopite and mica. Light is reflected from these pigments, but the amount of light perceived by the eye is heavily dependent on the viewing angle. Metallic pigments offer sparkle and gloss. The exact behavior depends on the size and shape of the metallic particles.
• a pressed powder is one type of delivery system for metallic and pearlescent pigments.
• Pressed power compositions usually include a particulate phase and a binder phase.
• the particulate phase may comprises various dry powders and pigments.
• the binder phase may be of the dry or liquid type, but the present invention utilizes a liquid binder system.
• Liquid binder systems that comprise natural oils, esters and emollients, provide lubricity, cushion and film forming ability. Both natural oils and emollients are excellent pigment dispersants that provide great slip, spreading ability, and improved wear. Some oils enhance skin adhesion, and others help to provide a silky -to-powdery feel.
• a liquid binder system improves powder compressibility while reducing dustiness, increases shine of the finished product, and provides a silky-smooth finish on the skin. Nevertheless, even with a liquid binder system, pressed powder compositions are often difficult to stabilize. This is especially true when the concentration of large particle pigments is too great. At some critical point, the particulate phase is unable to completely absorb the liquid binder. This limitation on the concentration of large particle pigments limits the degree of optical effect that can be obtained.
• Synthetic waxes In pressed powder applications, synthetic waxes have been tried as stabilizing agents. These include, but are not limited to, polyolefin wax, paraffin wax, microcrystalline wax, montan wax, polyethylene wax, ceresin, and mixtures thereof. Synthetic waxes, however, tend to be dusty, and unable to provide the requisite adhesion to stabilize compositions that comprise relatively high concentrations of large metallic or pearlescent pigments. Additionally, glittery products tend to have little staying power on the skin. To date, satisfactory results have not been achieved, and there remains a need for a stabilizing agent that is effective to stabilize metallic or pearlescent pigments in pressed powder compositions.
• a main object of the present invention is to provide a binder for use in powdery cosmetic compositions, especially those that comprise metallic and pearlescent pigments
• binder sub-compositions for use in the binder phase of powdery cosmetics, especially pressed powder compositions.
• the binder sub-composition consists of one or more viscous emollients, one or more non-viscous emollients, one or more triglyceride ester fatty acids, and one or more flower waxes.
• the binder sub-composition is preferred for use in pressed cosmetic compositions that comprise metallic and pearlescent pigments.
• the sub-compositions are able to stabilize metallic and pearlescent particles against fallout.
• Pressed powder compositions according to the present invention that utilize the binder subcomposition, have a creamy texture, and are suitable for long-wear (flexible, water-resistant, smudge and flake resistant)
• the compositions provide true color, excellent color payoff and skin conditioning.
• stable and “stability” as used herein refer to a composition which, over a period of at least six months, is substantially unaltered in chemical state, physical homogeneity and/or color when the temperature of the composition varies from about 1°C to about 40°C
• powder includes fine and coarse powders, flakes, crystalline flakes, platelets, spherical particles, precipitates, and other solid particulate materials.
• the present invention relates to cosmetic compositions that comprise a particulate phase and a binder phase.
• the particulate phase comprises various cosmetically acceptable powder ingredients and pigments, especially one or more pearlescent and/or metallic pigments.
• the particulate phase comprises one or more pearlescents and/or metallic pigments. These pigments will typically have a diameter (or other characteristic size) in the range of about 0. 1 pm to about 500pm.
• the binder phase comprises a binder sub-composition that consists of one or more viscous emollients, one or more non-viscous emollients, one or more triglyceride ester fatty acids, and one or more flower waxes.
• the binder phase may also comprise any cosmetically acceptable liquid ingredients that do not interfere with the function of the binder subcomposition.
• Binder sub-compositions of the invention comprises one or more viscous emollients and one or more non-viscous emollients.
• Non-viscous emollients are liquids that exhibit little or no resistance flow.
• a non-viscous emollient as having a dynamic viscosity of less than about 100 mPa»s, more preferably less thana about 50 mPa»s.
• octyldodecyl lactate is a highly polar liquid ester characterized by a dynamic viscosity of about 43 mPa*s.
• Octyldodecyl lactate has proved to be useful in embodiments of the present invention, and is available as Cosmol-13 from Nisshin OilliO group.
• viscous emollients useful in the present invention will have a dynamic viscosity between about 500 mPa»s and 1000 mPa «s.
• tridecyl trimellitate is a liquid emollient ester having a dynamic viscosity of about 860 mPa»s. Tridecyl trimellitate is available as LiponateTM TDTM from Vantage Specialty Ingredients (NJ).
• the binder sub-composition comprises one or more C18-C36 triglyceride ester fatty acids.
• a triglyceride ester fatty acid is an ester derived from glycerol and three fatty acids.
• triglyceride ester fatty acids function to soften waxes and reduce crystallinity.
• tnbehemn a triglyceride of behenic (C22) acid
• Tribehenin is available, for example, as SyncrowaxTM HRC from Croda, in the form of anon-crystalline paste with a melting point between about 60°C and 65°C.
• Flower waxes are solid, aromatic plant waxes that are obtained during the production of floral concretes and absolutes.
• Flower waxes are comprised of the natural wax and aromatics present within the botanical from which they are derived.
• Flower waxes include, but are not limited to, lavender (Lavandula angustifolia)' , blackcurrant, blue lotus, cassie (Acacia dealbata), chamomile, clary sage, everlasting (Helichrysum angustifolium), geranium, jasmine, mimosa, nutmeg, orange, rose, tuberose, violet, and mixtures thereof.
• Preferred flower waxes comprise a mixture of C4-C50 hydrocarbons, which have a characteristic melting point range of about 30°C to 60°C (86°F - 140°F). Longer chain length waxes tend to be too hard for the present invention.
• Pressed powder cosmetic compositions of the invention may optionally comprise various cosmetically acceptable ingredients for know n beauty or skincare benefits, with the proviso that the ingredients are compatible with the pressed powder product form.
• Optional ingredients may be in the particulate phase, the binder phase, or both.
• any nonparticulate ingredients i.e. liquid, paste
• the total of all optional ingredients will range from about 0.1 to about 20% by weight of the total pressed powder cosmetic composition.
• Preferred embodiments of the invention comprise no talc, and no silicone.
• Optional ingredients include, but are not limited to, antioxidants, preservatives, fragrances, vitamins, antiaging agents, antiwrinkle agents, anti-inflammatories, analgesics, anesthetics, anti-acne agents, antimicrobials, anti-bacterials, anti-yeast agents, antifungal agents, antiviral agents, antidandruff agents, anti-dermatitis agents, antipruritic agents, antiemetics, anti-hyperkeratolytic agents, anti-allergenics, antiseptics, anti-dry skin agents, anti-psoriatic agents, anti-seborrheic agents, anti-asthmatic agents, sunscreen agents, antihistamine agents, depigmenting agents, wound-healing agents, corticosteroids, tanning agents, humectants, lubricants, masking agents, medicaments, moisturizers, pH adjusters, chelating agents, emulsifiers, surfactants, thickeners and hormones.
• test samples were prepared according to the pressed powder eyeshadow formula shown in Table 1.
• Nylon-12 microspheres (Kobo Products, Inc.).
• caprylyl glycol I phenoxyethanol/ hexylene glycol (Hampford Research).
• capry lie/ capric triglyceride / polyhydroxystearic acid / isostearic acid / lecithin / polyglyceryl-3 polyricinoleate (Applechem, Inc.).
• Table 3 shows the relative percentages of one binder sub-composition that gave excellent results, performing well in terms of pressability, stability, drop test, overall appearance, texture and color payoff.
• Pressed powders were prepared with the binder phase shown in Table 4, by varying the levels of tridecyl trimellitate, and q.s. to octyldodecyl lactate, while holding all else constant. All trial powders were pressed using the same equipment.
• Pressed powders were prepared with the binder phase shown in Table 5, by varying the levels of tridecyl trimellitate, and q.s. evenly to other ingredients (except Dermaxyl, whose usage is limited).
• the binder phase will comprise one or more viscous emollients totaling about 70% to about 85% by total weight of the binder phase (or about 17.5% to about 21.25% by weight of the total powder cosmetic composition).
• Pressed powders were prepared with the binder phase shown in Table 6 by varying the levels of octyldodecyl lactate, and q.s. to tri decyl trimellitate, while holding all else constant.
• the binder phase will comprise one or more non-viscous emollients totaling about 5% to about 14% by total weight of the binder phase (or about 1.25% to about 3.50% by weight of the total powder cosmetic composition).
• Pressed powders were prepared with the binder phase shown in Table 7 by varying the levels of triglyceride ester fatty acid (Syncrowax HR-C) and q.s. to tridecyl trimellitate, and holding all else constant.
• triglyceride ester fatty acid Synchronization Agent
• the binder phase will comprise one or more triglyceride ester fatty acids totaling about 2.0% - 2.5% by total weight of the binder phase (or about 0.50% to about 0.63% by weight of the total powder cosmetic composition).
• concentration of triglyceride ester fatty acids is outside of this range, then the resulting pressed powder compositions are of insufficient quality compared to the standard.
• Pressed powders were prepared with the binder phase shown in Table 8 by varying the levels of lavender wax and q.s. to tri decyl trimellitate, and holding all else constant.
• the binder phase will comprise one or more C4-C50 hydrocarbon flower waxes that have melting point ranges between 30°C and 60°C.
• Example 7 In this Example, we removed all waxy ingredients from the Standard binder subcomposition (Table 3) and q.s. tridecyl trimellitate.
• Example 8 Table 11 shows the results when tri decyl trimellitate (viscosity - 859.4 mPa’s) is replaced with emollients of varying viscosities.
• Diglyceryl triisostearate (INCI name: Polyglyceryl-2 Triisostearate) (Nisshin Oillio Group, Ltd.)
• the viscous emollient component of the binder sub-composition should have a dynamic viscosity between about 500 mPa «s and 1000 mPa»s.
• the present invention relates to compositions for application to a skin surface.
• the binder sub-composition according to the present invention may find uses in various other cosmetic products.
• a blush composition that utilizes the standard binder sub-composition was formed by pressing at 300 psi. Aesthetics were acceptable, and the blush accomplished four drops in the drop test.
• a face powder composition that utilizes the standard binder sub-composition was formed by pressing at 400 psi. Aesthetics were acceptable, and the face powder survived two drops in the drop test.
• the binder formula can be pressed in different pan sizes, adjusting the pressure to ensure that the pressed formula passes a drop test without compromising the aesthetics of the product.
• a loose powder composition was made by decreasing the binder phase from 25% to about 7% of the total loose powder composition, with q.s. to pearl particles. The aesthetics were acceptable.
• Our observations lead us to conclude that a binder phase according to the present invention is useful in powder cosmetics at concentrations that range from about 7% to about 25% of the total powder cosmetic composition.
• Nylon- 12 microspheres (Kobo Products, Inc ).
• the binder phase comprises a binder sub-composition.
• the binder subcomposition is particularly suited for use in stabilizing pearlescent and metallic pigments.
• the compositions are stable, have a creamy texture, and are suitable for long-wear, while providing true color, excellent color payoff and skin conditioning.

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• 2022
  • 2022-08-12 US US17/819,350 patent/US11752080B1/en active Active
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