Classifications

• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
  • C11D3/16—Organic compounds
  • C11D3/38—Products with no well-defined composition, e.g. natural products
  • C11D3/386—Preparations containing enzymes, e.g. protease or amylase
• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
  • C11D1/02—Anionic compounds
  • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
  • C11D1/28—Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
  • C11D1/88—Ampholytes; Electroneutral compounds
  • C11D1/92—Sulfobetaines ; Sulfitobetaines
• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
  • C11D1/88—Ampholytes; Electroneutral compounds
  • C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
  • C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
  • C11D3/16—Organic compounds
  • C11D3/38—Products with no well-defined composition, e.g. natural products
  • C11D3/386—Preparations containing enzymes, e.g. protease or amylase
  • C11D3/38618—Protease or amylase in liquid compositions only
• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
  • C11D3/16—Organic compounds
  • C11D3/38—Products with no well-defined composition, e.g. natural products
  • C11D3/386—Preparations containing enzymes, e.g. protease or amylase
  • C11D3/38627—Preparations containing enzymes, e.g. protease or amylase containing lipase
• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
  • C11D3/16—Organic compounds
  • C11D3/38—Products with no well-defined composition, e.g. natural products
  • C11D3/386—Preparations containing enzymes, e.g. protease or amylase
  • C11D3/38663—Stabilised liquid enzyme compositions
• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
  • C11D2111/10—Objects to be cleaned
  • C11D2111/14—Hard surfaces

Definitions

• the present invention relates to a method of cleaning a target surface.
• a so-called concentrated type detergent composition which has a higher surfactant concentration than conventional detergent compositions, is known. If it is a concentrated type, the size of the cleaning composition itself can be reduced, which reduces the amount of resin in the container, transportation costs, and waste after use, reducing the burden on the environment. It is considered to be very effective in Furthermore, when cleaning hard items around the kitchen such as tableware and cooking utensils, it is necessary to clean hard stains that are a combination of solid fat and liquid fat. Additionally, tap water is generally used for washing hard articles, clothing, and the like. Generally, detergency is affected by the hardness of the water used.
• the hardness of tap water in Japan is often between 1 and 5 degrees dH (German hardness).
• tap water in some regions within Japan and tap water in regions outside Japan has a high hardness of 8 to 20° dH and is used for washing hard articles, clothing, and the like. Therefore, it is required to have excellent cleaning properties without being affected by the hardness of the water used for cleaning.
• JP 2020-152757 A describes (A) component: a specific sulfosuccinic acid dialkyl ester or its salt, (B) component: at least one selected from semipolar surfactants and amphoteric surfactants, and ( Contains component C): cationized cellulose, component (D): an anionic surfactant other than the component (A), and the mass ratio represented by the component (A)/component (B) is 0. .05 to 0.5, and the mass ratio represented by the component (D)/component (B) is 0.5 to 1.5, and the tableware has excellent detergency, foaming, and drainage properties.
• a liquid cleaning composition is disclosed.
• JP 2019-182911 A describes (a) a sulfosuccinic acid alkyl ester or a salt thereof in which the alkyl group has 5 to 18 carbon atoms [hereinafter referred to as component (a)] in an amount of 0.01% by mass to 5.0% by mass; % or less, (b) one or more surfactants selected from semipolar surfactants and amphoteric surfactants [hereinafter referred to as component (b)] from 0.01% by mass to 5.0% by mass, ( c) Stains containing enzymes [hereinafter referred to as component (c)] and water, with a mass ratio of component (a)/component (b) of 0.01 or more and 100 or less, including solid fat attached to tableware, etc.
• JP 2021-17508 A describes (a) a surfactant [hereinafter referred to as (a) component] of 0.1% by mass or more and 15% by mass or less, (b) an enzyme [hereinafter referred to as (b) component] 1 ppm or more and 1000 ppm or less as an enzyme protein, and at least one of (c) an inorganic salt [hereinafter referred to as (c) component] and (d) a carboxylate [hereinafter referred to as (d) component], and (a) A liquid cleaning composition in which the mass ratio (a)/[(c)+(d)] between the content of the component and the content of the component (c) and the component (d) is 0.1 or more and 10 or less.
• a method of cleaning a hard article is disclosed in which the liquid oil is brought into contact
• JP 2019-182911 an enzyme is added to a formulation containing a low concentration of a sulfosuccinic acid alkyl ester and an amphoteric or semipolar surfactant, and the enzyme's effect removes solid fat that adheres to tableware, etc. It has been reported that cleaning power against stains including . On the other hand, in a formulation containing a high concentration of surfactant, it is expected that the surfactant will more easily act on the enzyme, reducing the effectiveness of the enzyme. There is no disclosure regarding the effects of enzymes in formulations containing high concentrations of agents. In addition, when cleaning target surfaces such as hard articles, it is desired to have high cleaning power for stains containing solid fat attached to target surfaces such as tableware, without being affected by the hardness of the water used for cleaning.
• the present invention has enzyme activity even when a high concentration of surfactant and enzyme are used together, and is capable of cleaning tableware without being affected by the hardness of the water used for washing (for example, 0 to 20° dH (German hardness)).
• a method for cleaning a target surface which is excellent in cleaning properties of dirt containing solid fat attached to the target surface.
• the present invention relates to a method for cleaning a target surface, in which a cleaning liquid obtained by diluting a liquid cleaning composition containing the following components (a), (b), and (e) and water is brought into contact with the target surface.
• a cleaning liquid obtained by diluting a liquid cleaning composition containing the following components (a), (b), and (e) and water is brought into contact with the target surface.
• Component Sulfosuccinic acid alkyl ester or its salt having an alkyl group with 5 to 18 carbon atoms
• Component Sulfobetaine
• e Component: Enzyme
• the present invention also relates to a liquid cleaning composition containing the components (a), (b), (e), and water.
• the enzyme has enzyme activity and is not affected by the hardness of the water used for cleaning (for example, 0 to 20° dH (German hardness)).
• a method for cleaning a target surface, such as tableware which is excellent in cleaning stains containing solid fat adhering to the target surface.
• the liquid cleaning composition of the present invention and the method for cleaning a target surface have enzyme activity even when a high concentration of surfactant and enzyme are used together, and the hardness of the water used for cleaning is (For example, 0 to 20° dH (German hardness)) It is not necessarily clear why it has excellent cleaning performance for stains containing solid fat attached to the target surface such as tableware, but it is estimated as follows. Ru. Generally, surfactants act on enzymes through electrostatic or hydrophobic interactions, so if the concentration of surfactant in a liquid detergent composition is high, enzyme activity is lost. Furthermore, the hardness component contained in the water that dilutes the liquid cleaning composition changes the packing properties of surfactants, thereby significantly changing the cleaning performance of the liquid cleaning composition.
• the various surfactants contained in the composition have strong electrostatic interactions, and the interaction between the various surfactants shields the electric charge. It is thought that the effect of the present invention was achieved because the effect of the surfactant on the enzyme is small, and the strong packing property due to electrostatic interaction between various surfactants makes it less susceptible to the influence of hardness components. .
• the present invention provides a cleaning solution obtained by diluting a liquid cleaning composition (hereinafter referred to as the liquid cleaning composition of the present invention) with water, which contains the components (a), (b), (e), and water.
• the present invention relates to a method of cleaning a target surface, in which the target surface is brought into contact with the target surface.
• the liquid detergent composition of the present invention will be explained below.
• Component (a) of the present invention is a sulfosuccinic acid alkyl ester or a salt thereof having an alkyl group having 5 to 18 carbon atoms.
• component (a) include those in which the ester is a monoester and those in which the ester is a diester.
• the alkyl group of component (a) is a hexyl group, an octyl group, a nonyl group, a decyl group, a dodecyl group, a tridecyl group, a 2-ethylhexyl group, an n-octyl group, a sec-octyl group, an isopentyl group, Isononyl group, isodecyl group, cyclohexyl group, 1-butylhexyl group, 3,5,5-trimethylhexyl group, 1-butylpentyl group, 1-(2-methylpropyl)-3-methylbutyl group, 2-propylpentyl group , and 2-propylheptyl groups, and from the viewpoint of cleaning properties for stains containing solid fat (hereinafter simply referred to as cleaning properties), 2-ethylhexyl groups and 2-propylheptyl groups are preferable. It is referred to
• the liquid cleaning composition of the present invention contains (a-1) a sulfosuccinic acid alkyl ester or salt thereof (hereinafter referred to as (a (hereinafter referred to as component (a-2)) and (a-2) a sulfosuccinic acid alkyl ester or salt thereof whose alkyl group has 9 or more carbon atoms and 18 or less (hereinafter referred to as component (a-2)).
• component (a-2) a sulfosuccinic acid alkyl ester or salt thereof whose alkyl group has 9 or more carbon atoms and 18 or less
• component (a-2) a sulfosuccinic acid alkyl ester or salt thereof whose alkyl group has 9 or more carbon atoms and 18 or less
• component (a) is preferably a branched alkyl sulfosuccinic acid ester or a salt thereof having a branched alkyl group having 8 or more and 12 or less carbon atoms (hereinafter referred to as component (a1)).
• the branched alkyl group of component (a1) is preferably a branched alkyl group having 9 to 12 carbon atoms, more preferably a branched alkyl group having 9 or 10 carbon atoms, and has a main chain of 6 or 7 carbon atoms and one or more side chains.
• a branched alkyl group having a chain and a total number of carbon atoms in side chains of 3 is more preferable.
• the branched alkyl group of component (a1) is preferably a branched alkyl group selected from 2-propylheptyl group and 2-ethylhexyl group, more preferably 2-propylheptyl group.
• component (a1) a branched sulfosuccinic acid ester represented by the following general formula (a1) can be mentioned.
• R 1a and R 2a are each independently a branched alkyl group having 8 or more and 12 or more carbon atoms.
• a 1 and A 2 are each independently an alkylene group having 2 or more and 4 or less carbon atoms, and x and y are the average number of added moles and are each independently 0 or more and 6 or less.
• M 1 is a hydrogen atom or a cation.
• a branched alkyl sulfosuccinic acid ester represented by the following general formula (a1-a) can be mentioned.
• R 1a and R 2a are each independently a branched alkyl group having 8 or more and 12 or more carbon atoms.
• M 1 is a hydrogen atom or a cation.
• the hydrocarbon chain having the largest number of carbon atoms counted from the carbon atom bonded to the oxygen atom is the main chain
• the hydrocarbon chain branched from the main chain is The bonded hydrocarbon chains.
• the main chains are determined in the following order. 1.
• the side chain branching from the longest hydrocarbon chain with a larger number of carbon atoms is considered the main chain. 2.
• the main chain is the one with the largest number of carbon atoms in the side chain closest to the oxygen atom.
• the main chain is the one with the largest number of carbon atoms in the side chain closest to the oxygen atom.
• the total number of carbon atoms constituting the side chains may be the same or different, and is preferably 3 from the viewpoint of detergency and formulation stability.
• the total number of carbon atoms constituting side chains is the total number of carbon atoms in all side chains other than the main chain in one branched alkyl group, and if there are multiple side chains, the total number of carbon atoms in all side chains other than the main chain is the total number of carbon atoms in one branched alkyl group. It is the total number of carbon atoms in the side chain.
• the number of side chains of R 1a and R 2a may be the same or different, and from the viewpoint of detergency and formulation stability, is 1 or more, preferably 3 or less, and more preferably 2 or less.
• the number of side chains is the number of side chains branching from the main chain, and even if the side chain has a side chain further branching from the main chain, the number of side chains does not change.
• the side chain may further have a side chain branching from the side chain.
• the number of branched carbon atoms in R 1a and R 2a may be the same or different, and from the viewpoint of detergency and formulation stability, is 1 or more, preferably 3 or less, and even more preferably 2 or less.
• the number of branched carbon atoms is the total number of tertiary carbon atoms and quaternary carbon atoms in the chain branched hydrocarbon group.
• R 1a and R 2a are such that the total number of carbon atoms in the chain branched hydrocarbon groups of R 1a and R 2a is, each independently, 8 or more and 12 or less, further 9 or more and 12 or less, and further 9 or 10. , the number of carbon atoms in the main chain is 6 or 7, the number of carbon atoms in the side chains is 1 or more and 3 or less, and the number of side chains is 1, respectively. .
• the specific branched alkyl groups of R 1a and R 2a may be the same or different, and a branched alkyl group selected from 2-propylheptyl group and 2-ethylhexyl group is preferable, and 2-propylheptyl group is more preferable. .
• a 1 and A 2 are each independently an alkylene group having 2 or more carbon atoms and 4 or less carbon atoms, preferably 3 or less carbon atoms.
• x and y are the average number of moles added, and from the viewpoint of detergency and formulation stability, each is independently 0 or more and 6 or less, preferably 4 or less, more preferably 2 or less, and more preferably 0.
• x+y is preferably 0 or more, preferably 12 or less, more preferably 6 or less, still more preferably 3 or less, and even more preferably 0, from the viewpoint of detergency and formulation stability.
• M1 is a hydrogen ion, an inorganic cation such as a sodium ion, an ammonium ion, a potassium ion, a magnesium ion, a monoethanol ammonium ion, a diethanol ammonium ion, a triethanol ammonium ion, a morpholinium ion. and preferably inorganic cations selected from sodium ions, ammonium ions, potassium ions, and magnesium ions.
• an inorganic cation such as a sodium ion, an ammonium ion, a potassium ion, a magnesium ion, a monoethanol ammonium ion, a diethanol ammonium ion, a triethanol ammonium ion, a morpholinium ion.
• inorganic cations selected from sodium ions, ammonium ions, potassium ions, and magnesium ions.
• the method for preparing a compound in which R 1a and R 2a are the same in general formula (a1) is not particularly limited, but for example, the method described in U.S. Patent No. 2,028,091 can be referred to. Furthermore, as a method for preparing an asymmetric compound in which R 1a and R 2a are different, for example, it can be produced with reference to JP-A-58-24555.
• a raw material for component (a1) an alcohol having a predetermined number of carbon atoms to which alkylene oxide is added can also be used.
• Suitable alcohols used in the production of component (a1) of the present invention include: (1) Primary alcohols represented by 3,5,5-trimethylhexan-1-ol, 2-propylheptan-1-ol, etc. (2) Secondary alcohols typified by 5-nonanol, 2,6-dimethyl-4-heptanol, etc.
• the liquid detergent composition of the present invention contains (a1-1) a sulfosuccinic acid branched alkyl ester having a branched chain alkyl group having 8 carbon atoms or a salt thereof (hereinafter referred to as (a1)) as the component (a1).
• -1) component a sulfosuccinic acid branched alkyl ester having a branched alkyl group having 9 to 12 carbon atoms or a salt thereof
• (a1-2) component May contain.
• the embodiments described for the component (a1) can be applied as appropriate.
• Component (b) of the present invention is sulfobetaine.
• sulfobetaine N-alkyl-N,N-dimethyl-N-sulfopropylammonium sulfobetaine in which the number of carbon atoms in the alkyl group is preferably 10 or more, preferably 18 or less, and more preferably 14 or less; is preferably 10 or more, preferably 18 or less, more preferably 14 or less N-alkyl-N,N-dimethyl-N-(2-hydroxysulfopropyl)ammonium sulfobetaine, the number of carbon atoms in the alkanoyl group is preferably 10 or more , preferably 18 or less, more preferably 14 or less N-alkanoylaminopropyl-N,N-dimethyl-N-sulfopropylammonium sulfobetaine, the number of carbon atoms in the alkanoyl group is preferably
• the liquid cleaning composition of the present invention may optionally contain the following component (c).
• the anionic surfactant is an alkylbenzene sulfonate, an alkyl or alkenyl ether sulfate, an alkyl or alkenyl sulfate, an alkanesulfonate, a saturated or unsaturated fatty acid salt, an alkyl or alkenyl ether carboxylic acid.
• Examples include one or more selected from salts, ⁇ -sulfofatty acid salts, N-acylamino acids, and phosphoric acid mono- or diesters (hereinafter referred to as component (c-1)).
• the alkyl or alkenyl ether sulfate salts include polyoxyethylene alkyl or alkenyl ether sulfate salts.
• the alkyl group or alkenyl group of component (c-1) has, for example, 8 to 22 carbon atoms.
• the average number of added moles of oxyethylene groups in component (c-1) is, for example, 0 or more and 10 or less.
• Counter ions for the anionic group of component (c-1) include alkali metal ions such as sodium ions and potassium ions; alkaline earth metal ions such as calcium ions and magnesium ions; ammonium ions; alkanols having 2 or 3 carbon atoms; Examples include alkanolamines having 1 to 3 groups (eg, monoethanolamine, diethanolamine, triethanolamine, triisopropanolamine, etc.). These surfactants can be used alone or in combination of two or more.
• Component (c-1) is preferably an alkyl or alkenyl ether sulfate salt from the viewpoint of detergency and formulation stability.
• the alkyl or alkenyl ether sulfate salt is preferably a polyoxyalkylene alkyl or alkenyl ether sulfate salt.
• the polyoxyalkylene alkyl or alkenyl ether sulfate salt has an alkyl or alkenyl group having 8 or more carbon atoms, preferably 10 or more, and 18 or less, preferably 14 or less.
• the number of carbon atoms in the oxyalkylene group is preferably 2 or 3, more preferably 2, and the average number of added moles of the oxyalkylene group is 0.5 or more. It is preferably 1.0 or more and 4.0 or less, preferably 3.0 or less.
• Component (c) is preferably an internal olefin sulfonate (hereinafter referred to as component (c-2)) from the viewpoint of detergency and formulation stability.
• the number of carbon atoms in the internal olefin sulfonate in component (c-2) is preferably 8 or more, more preferably 12 or more, still more preferably 16 or more, and preferably 24 or more, from the viewpoint of detergency and formulation stability. Below, it is more preferably 22 or less, still more preferably 20 or less, even more preferably 18 or less, even more preferably 16.
• the number of carbon atoms in the internal olefin sulfonate in component (c-2) represents the number of carbon atoms in the internal olefin to which the sulfonate is covalently bonded.
• the internal olefin sulfonate of component (c-2) is used as a raw material, preferably having carbon atoms of 8 or more, more preferably 12 or more, even more preferably 16 or more, and preferably 24 or less, more preferably 22 or less, A sulfone obtained by sulfonating, neutralizing and hydrolyzing an internal olefin (olefin having a double bond inside the olefin chain), which is more preferably 20 or less, even more preferably 18 or less, even more preferably 16. It is an acid salt.
• Such internal olefins include those containing a trace amount of so-called alpha olefins (hereinafter also referred to as ⁇ -olefins) in which the double bond is present at the 1st position of the carbon chain. Furthermore, when internal olefins are sulfonated, ⁇ -sultones are produced quantitatively, and some of the ⁇ -sultones are converted into ⁇ -sultones and olefin sulfonic acids, which are further converted into hydroxyl in the neutralization/hydrolysis process. Converted to alkanesulfonates and olefinsulfonates (eg, J. Am. Oil Chem. Soc. 69, 39 (1992)).
• the hydroxy group of the resulting hydroxyalkanesulfonate is located inside the alkane chain, and the double bond of the olefin sulfonate is located inside the olefin chain.
• the obtained products are mainly mixtures of these, and some of them include hydroxyalkanesulfonates having a hydroxyl group at the end of the carbon chain, or olefins having a double bond at the end of the carbon chain. May contain trace amounts of sulfonates.
• each of these products and mixtures thereof are collectively referred to as internal olefin sulfonate (component (c-2)).
• hydroxyalkanesulfonate is referred to as a hydroxy form of internal olefin sulfonate (hereinafter also referred to as HAS form), and olefin sulfonate is referred to as olefin form of internal olefin sulfonate (hereinafter also referred to as IOS form).
• HAS form hydroxy form of internal olefin sulfonate
• IOS form internal olefin sulfonate
• the mass ratio of the HAS form and the IOS form of the compound in component (c-2) can be measured using a high performance liquid chromatography mass spectrometer (hereinafter abbreviated as HPLC-MS). Specifically, the mass ratio can be determined from the HPLC-MS peak area of component (c-2).
• Salts of internal olefin sulfonates include alkali metal salts, alkaline earth metal (1/2 atom) salts, ammonium salts, and organic ammonium salts.
• alkali metal salts include sodium salts and potassium salts.
• organic ammonium salts include alkanol ammonium salts containing alkanolamines and having 2 or more and 6 or less carbon atoms.
• the sulfonic acid group of the internal olefin sulfonate as component (c-2) exists inside the carbon chain, that is, the olefin chain or the alkane chain, and A small amount of sulfonic acid group may be present at the end of the carbon chain.
• the content of the internal olefin sulfonate in which the sulfonic acid group is present at the 5th position or higher, preferably at the 5th or higher position and lower than the 9th position is preferably 5% by mass from the viewpoint of formulation stability.
• the above is more preferably 10% by mass or more, still more preferably 15% by mass or more, even more preferably 20% by mass or more, and preferably 60% by mass or less, more preferably 55% by mass or less, even more preferably 45% by mass or less. % by mass or less.
• (c-2) The content of internal olefin sulfonate [hereinafter sometimes referred to as (IO-1S)] in which the sulfonic acid group is present at the 2nd to 4th position and the sulfonic acid group is at the 5th position.
• the above is the mass ratio of (IO-1S)/(IO-2S) to the content of internal olefin sulfonate [hereinafter sometimes referred to as (IO-2S)] preferably present at the 5th to 9th positions.
• ) is preferably 0.5 or more, more preferably 0.8 or more, even more preferably 1.0 or more, even more preferably 1.5 or more, even more preferably 2 or more, from the viewpoint of formulation stability.
• each compound having a different sulfonic acid group position in component (c-2) can be measured by HPLC-MS.
• the content of each compound having a sulfonic acid group at different positions is expressed as a mass ratio based on the HPLC-MS peak area of the compound having a sulfonic acid group at each position in all HAS forms of component (c-2). shall be sought.
• the content of the olefin sulfonate having a sulfonic acid group at the 1-position in the component (c-2) is preferably 10% by mass or less, More preferably 7% by mass or less, still more preferably 5% by mass or less, even more preferably 3% by mass or less, and from the viewpoint of reducing production costs and improving productivity, preferably 0.01% by mass or more.
• the position of the sulfonic acid group in these compounds is in the olefin or alkane chain.
• the above-mentioned internal olefin sulfonate can be a mixture of a hydroxy form and an olefin form.
• (c-2) The mass ratio between the content of the olefin form of the internal olefin sulfonate and the content of the hydroxy form of the internal olefin sulfonate in the component (olefin form/hydroxy form) is 0/100 or more, and It can be 5/95 or more, and 50/50 or less, further 40/60 or less, further 30/70 or less, and further 25/75 or less.
• the liquid cleaning composition of the present invention may optionally contain the following component (d).
• Component Surfactant other than component (a), component (b), and component (c)
• component includes (d1) nonionic surfactant (hereinafter referred to as component (d1)); (d2) One or more selected from cationic surfactants (hereinafter referred to as component (d2)).
• nonionic surfactant of component (d1) alkyl monoglyceryl ether, polyoxyalkylene monoalkyl or alkenyl ether, alkyl (poly) glycoside (glycoside type nonionic surfactant), sorbitan type nonionic surfactant
• examples include amidated products of alkanolamines such as aliphatic alkanolamides, fatty acid monoglycerides, sucrose fatty acid esters, monoethanolamine, diethanolamine, and methylmonoethanolamine with fatty acids such as lauric acid and myristic acid.
• the alkyl group or alkenyl group of the nonionic surfactant has, for example, 6 or more and 18 or less carbon atoms.
• the average number of moles of oxyalkylene groups, such as oxyethylene groups, added to the nonionic surfactant is, for example, 3 or more and 25 or less.
• (d1) components include (d1-1) alkyl (poly) glycoside (hereinafter referred to as (d1-1) component) and (d1-2) polyoxyalkylene monoalkyl ether (hereinafter referred to as (d1-1) component).
• (d1-1) component alkyl (poly) glycoside
• (d1-2) polyoxyalkylene monoalkyl ether hereinafter referred to as (d1-1) component.
• One or more types selected from d1-2) components are preferred.
• the alkyl group of component (d1-1) is preferably a primary alkyl group, more preferably a linear primary alkyl group.
• the number of carbon atoms in the alkyl group is preferably 8 or more, more preferably 10 or more, and preferably 18 or less, more preferably 16 or less, and still more preferably 14 or less.
• the component (d1-1) preferably has a linear primary alkyl group having 8 to 14 carbon atoms, more preferably a linear primary alkyl group having 10 or 12 carbon atoms.
• the average degree of polymerization of the glycoside of component (d1-1) is preferably 1.0 or more, more preferably 1.3 or more, and preferably 3.0 or less, more preferably 2.5. Below, it is more preferably 2.0 or less, even more preferably 1.7 or less.
• the alkyl group of component (d1-2) is preferably a primary alkyl group, more preferably a linear or branched primary alkyl group, and even more preferably a linear primary alkyl group.
• the number of carbon atoms in the alkyl group is preferably 8 or more, more preferably 12 or more, and preferably 18 or less, more preferably 14 or less, and even more preferably 12.
• the oxyalkylene group of component (d1-2) is preferably one or more selected from oxyethylene groups and oxypropylene groups, and more preferably oxyethylene groups.
• the average number of added moles of oxyalkylene groups in component (d1-2) is preferably 3 or more, more preferably 6 or more, still more preferably 8 or more, and preferably 25 or less, from the viewpoint of detergency. It is preferably 18 or less, more preferably 10 or less.
• the cationic surfactant as the component (d2) includes alkyltrimethylammonium salts in which the alkyl group has 8 to 22 carbon atoms, dialkyldimethylammonium salts in which the alkyl group has 8 to 22 carbon atoms, and alkyl dimethylammonium salts in which the alkyl group has 8 to 22 carbon atoms.
• alkyldimethylbenzylammonium salts and benzethonium salts having a number of 8 or more and 22 or less.
• the salt include halogen salts and alkyl sulfates having 1 to 3 carbon atoms.
• Component (e) of the present invention is an enzyme.
• component (e) one or more enzymes selected from lipase, amylase, and protease are preferred, and lipase is more preferred, from the viewpoint of cleaning properties against complex stains such as fats, oils, carbohydrates, and proteins.
• Preferred lipases include triacylglycerol lipase of EC3.1.1.3, cholesterol esterase of EC3.1.1.13, monoacylglycerol lipase of EC3.1.23, and lipoprotein lipase of EC3.1.1.34.
• the origin of lipase is not limited, but examples include lipase derived from animals, plants, and microorganisms. Lipases derived from microorganisms include those of the genus Rizopus, Aspergillus, Mucor, Pseudomonas, Geotrichum, Penicillium, Candida, etc. One example is the origin.
• the lipases are Lipase A “Amano” 6, Lipase AY “Amano” 30SD, Lipase GS “Amano” 250G, Lipase R “Amano”, Lipase DF “Amano” 15, Lipase MER “Amano” (Amano Enzyme Co., Ltd.) ), lipase (manufactured by Nagase Sangyo Co., Ltd.), lipase MY, lipase OF, lipase PL, lipase PLC, lipase QLM, lipase QLC, phospholipase D (manufactured by Meito Sangyo Co., Ltd.), lipoprotein lipase (Oriental Yeast Co., Ltd.), Lipase (manufactured by Toyo Jozo Co., Ltd.), Lipex, Lipolase, Lipase SP-225 (manufactured by Novozymes), Lipa
• proteases examples include proteases that can act in neutral or alkaline aqueous solutions.
• Specific examples of preferred proteases include alkaline proteases described in WO 99/018218, preferably those in which 70% or more of the amino acid sequence shown in SEQ ID NO: 1 or 2 is conserved;
• alkaline proteases described in JP-A No. 5-25492 preferred examples include alkaline protease K-16 and alkaline protease K-14.
• proteases produced by Bacillus subtilisins sold under the trade names Sabinase, Cannase, Evalase, Alcalase, Polarzyme, and Esperase (manufactured by Novozymes), FN2, FN3, and FN4, Prafect, and Prafect Prime.
• proteases supplied under trade names or mutant types thereof manufactured by DuPont.
• enzymes in which 80% or more of the amino acid sequence shown by SEQ ID NO: 1 or 2 described in International Publication No. 99/018218 is conserved, Sabinase, Evalase, Alcalase, Progress, Plafect, and Plafect. More preferably, one or more types selected from Ffect Prime.
• amylase examples include Bacillus subtilis Marburg, Bacillus subtilis natto, Bacillus amyloliquefaciens, Bacillus licheniformis, Bacillus cereus, and Bacillus macerans ( Bacillusmacerans), Pseudomonas stutzeri, Klebusiella aerogenes, actinomycetes such as Streptomyces griseus, Aspergillus oryzae, Aspergillus niger, etc. Those obtained from many organisms such as molds, seeds of grasses and legumes, and digestive glands of animals such as humans and pigs can be used.
• the amylase used in the present invention can be used to transform host cells, etc., transformed with the above-mentioned microorganisms or their mutants, or recombinant vectors having DNA sequences encoding these enzymes or their mutants, to an assimilable carbon source, a nitrogen source, etc.
• the enzyme can be obtained by inoculating the enzyme into a medium containing essential nutrients and culturing according to a conventional method, and following a general method for collecting and purifying enzymes.
• the enzyme solution obtained in this way can be used as it is, but it can also be purified, crystallized, and made into a powder or liquid preparation by known methods.
• the amylase used in the present invention is preferably ⁇ -amylase.
• amylases that can be used include Rapidase (manufactured by Gistbrokers), Termamil, Duramil and Steinzyme, Amplify (manufactured by Novozymes), and the trade names Plaster ST and Plaster OxAm (manufactured by Genencor International).
• the liquid cleaning composition of the present invention preferably contains component (a) in the liquid cleaning composition in an amount of preferably 1% by mass or more, more preferably 2% by mass or more, and even more preferably contains 5% by mass or more, and preferably 60% by mass or less, more preferably 40% by mass or less, even more preferably 20% by mass or less, even more preferably 15% by mass or less, even more preferably 10% by mass or less.
• the specification regarding the mass of component (a) shall be based on the value converted to sodium salt.
• the content of component (a-1) and component (a-2) is preferably 1 or more, more preferably 2 or more, and preferably 10 or less, more preferably 8 or less, More preferably it is 6 or less, even more preferably 4 or less.
• the content of component (a1-1) and the component (a1-2) is preferably 1 or more, more preferably 2 or more, and preferably 10 or less, more preferably 8 or less, More preferably it is 6 or less, even more preferably 4 or less.
• the liquid detergent composition of the present invention contains component (b) in the liquid detergent composition preferably at least 0.1% by mass, more preferably at least 5% by mass, from the viewpoint of detergency and enzyme activity.
• component (b) in the liquid detergent composition preferably at least 0.1% by mass, more preferably at least 5% by mass, from the viewpoint of detergency and enzyme activity.
• the mass ratio (b)/(a) between the content of component (a) and the content of component (b) is preferably 0 from the viewpoint of detergency and enzyme activity. .01 or more, more preferably 0.5 or more, still more preferably 1 or more, even more preferably 2 or more, and preferably 100 or less, more preferably 50 or less, still more preferably 10 or less, even more preferably 5 or less , and even more preferably 3 or less.
• the component (c) is preferably 50% by mass or less in the liquid cleaning composition from the viewpoint of detergency and formulation stability.
• the content is preferably 40% by mass or less, more preferably 30% by mass or less, even more preferably 20% by mass or less, even more preferably 10% by mass or less, even more preferably 5% by mass or less.
• the liquid cleaning composition of the present invention does not need to contain component (c).
• the specification regarding the mass of component (c) shall be based on a value converted to sodium salt.
• the mass ratio of the content of component (a) to the content of component (c-1) is (c-1)/(a ) is preferably 0 or more, more preferably 0.5 or more, and preferably 5 or less, more preferably 3 or less, still more preferably 2 or less, from the viewpoint of enzyme activity and detergency independent of water hardness. Even more preferably it is 1.5 or less, even more preferably 1 or less.
• the mass ratio of the content of component (a) to the content of component (c-2) is (c-2)/(a ) is preferably 0 or more, more preferably 0.33 or more, even more preferably 0.5 or more, and preferably 3 or less, more preferably 2 It is more preferably 1.5 or less, even more preferably less than 1.
• the component (d) is preferably 5% by mass or more in the liquid detergent composition from the viewpoint of detergency and formulation stability.
• the content is more preferably 30% by mass or less, even more preferably 25% by mass or less, even more preferably 20% by mass or less, even more preferably 15% by mass or less, even more preferably 10% by mass or less.
• the mass of the component (d2) shall be determined using a value converted to chlor salt.
• the mass ratio (d)/(a) of the content of component (a) to the content of component (d) is determined by the combination stability and detergency independent of water hardness. From this viewpoint, it is preferably 0 or more, more preferably 0.5 or more, and preferably 3 or less, more preferably 2 or less, still more preferably 1.5 or less, even more preferably 1 or less.
• the content of the surfactant is preferably 17% by mass or more, more preferably 20% by mass or more, still more preferably 22% by mass or more, and even more preferably is 25% by mass or more, and preferably 70% by mass or less, more preferably 60% by mass or less, even more preferably 54% by mass or less, even more preferably 40% by mass or less, even more preferably 30% by mass or less. .
• the total content of components (a), (b), (c), and (d) is preferably 17% by mass or more, more preferably 17% by mass or more, from the viewpoint of detergency.
• the content is more preferably 40% by mass or less, even more preferably 30% by mass or less.
• the total content of component (a), component (b), component (c), and component (d) is the content of surfactant contained in the liquid cleaning composition of the present invention.
• component (e) is preferably 0.01% by mass or more, more preferably 0.05% by mass, as an enzyme protein, from the viewpoint of detergency and cost. % by mass or more, more preferably 0.1% by mass or more, and preferably 0.5% by mass or less, more preferably 0.4% by mass or less, still more preferably 0.3% by mass or less, even more preferably 0. Contains .2% by mass or less.
• the regulation regarding the mass of component (e) shall be calculated as the amount of enzyme protein.
• component (e) the method described in Examples can be adopted as the method for quantifying the enzyme protein.
• the mass ratio (e)/(a) between the content of component (a) and the content of component (e) is preferably 0 from the viewpoint of enzyme activity and detergency. .001 or more, more preferably 0.005 or more, even more preferably 0.01 or more, even more preferably 0.015 or more, and preferably 0.2 or less, more preferably 0.1 or less, and even more preferably 0. It is .06 or less, more preferably 0.05 or less, even more preferably 0.04 or less.
• the liquid cleaning composition of the present invention may further contain a water-soluble organic solvent as component (f) from the viewpoint of uniformity and formulation stability.
• Components include (f-1) monohydric alcohol having 1 to 4 carbon atoms, (f-2) polyhydric alcohol having 2 to 4 carbon atoms, (f-3) carbon number of alkylene glycol unit. (f-4) monoalkyl (methyl, ethyl, propyl or butyl) of mono, di, tri or tetraalkylene glycols having 2 to 4 carbon atoms in the alkylene glycol unit; Mention may be made of monophenyl or monobenzyl ether. One or more types of these can be used.
• Component (f) is preferably a water-soluble organic solvent having 2 or more carbon atoms, preferably 3 or more carbon atoms, and 10 or less carbon atoms, preferably 8 or less carbon atoms.
• the water-soluble organic solvent refers to a solvent having an octanol/water partition coefficient (LogPow) of 3.5 or less.
• (f-1) is ethanol, isopropyl alcohol, t-butanol, 2-aminoethanol
• (f-2) is 1,3-propanediol, ethylene glycol, propylene glycol, glycerin, isoprene glycol
• (f-3) is diethylene glycol, dipropylene glycol
• (f-4) is propylene glycol monomethyl ether, propylene glycol monoethyl ether, diethylene glycol monobutyl ether (also referred to as butyl diglycol, etc.), dipropylene glycol butyl ether
• Examples include phenoxyethanol, phenoxytriethylene glycol, and phenoxyisopropanol. One or more types of these can be used.
• component (f) one or more selected from ethanol, propylene glycol, dipropylene glycol, diethylene glycol monobutyl ether, phenoxyethanol, and phenoxyisopropanol, from the viewpoint of composition uniformity.
• Water-soluble organic solvents are preferred, and one or more water-soluble organic solvents selected from ethanol and diethylene glycol monobutyl ether are more preferred.
• the component (f) is preferably 1% by mass or more in the liquid cleaning composition from the viewpoint of composition uniformity and cost. , more preferably 5% by mass or more, still more preferably 10% by mass or more, and preferably 30% by mass or less, more preferably 20% by mass or less, still more preferably 15% by mass or less.
• the liquid detergent composition of the present invention may further contain an inorganic salt as component (g) from the viewpoint of detergency.
• component (g) one or more selected from inorganic alkali metal salts, inorganic alkaline earth metal salts, and salts of Group 8 to Group 12 elements of the 4th period can be used.
• Component (g) is preferably one or more selected from chlorides, sulfates, carbonates, and sulfites.
• Ingredients are selected from lithium, sodium, and potassium as alkali metals, magnesium and calcium as alkaline earth metals, and iron, copper, and zinc as elements in Groups 8 to 12 of the 4th period.
• One or more salts can be used.
• Component (g) is more preferably one or more selected from sodium chloride, calcium chloride, magnesium chloride, and potassium chloride.
• the liquid cleaning composition of the present invention contains component (g), preferably 0.001% of the component (g) is contained in the liquid cleaning composition from the viewpoint of cleaning performance and composition uniformity. % by mass or more, more preferably 0.004% by mass or more, still more preferably 0.008% by mass or more, and preferably 0.2% by mass or less, more preferably 0.15% by mass or less, still more preferably 0. Contains 1% by mass or less.
• the liquid cleaning composition of the present invention contains a hydrotrope, an anti-gelling agent such as polyalkylene glycol, a thickener such as polyacrylic acid, a fragrance, a dye, a pigment, a bactericide, a preservative, a pH adjuster, etc. It can contain ingredients.
• the liquid cleaning composition of the present invention contains water. That is, the remainder other than the components (a) to (e) and other optional components is water.
• the liquid cleaning composition of the present invention preferably contains water in an amount of 20% by mass or more, more preferably 30% by mass or more, still more preferably 40% by mass or more, and preferably 60% by mass. The content is more preferably 50% by mass or less. It is preferable to use ion-exchanged water, sterilized ion-exchanged water, or the like as the water.
• the pH of the liquid detergent composition of the present invention at 25°C is preferably 6.0 or higher, more preferably 6.5 or higher, even more preferably 7.0 or higher, and preferably 10 It is more preferably 8.0 or less, still more preferably 7.5 or less.
• the viscosity of the liquid cleaning composition of the present invention at 20° C. is preferably 2000 mPa ⁇ s or less, more preferably 1000 mPa ⁇ s or less.
• the lower limit of this viscosity is preferably 10 mPa ⁇ s or more, more preferably 30 mPa ⁇ s or more, and still more preferably 50 mPa ⁇ s or more.
• the liquid cleaning composition of the present invention can be used for (1) food, such as on the surface of food materials such as vegetables, (2) hard articles, and (3) textile products, such as cloth, thread, etc. It can be used for textile materials and products manufactured using these materials.
• the liquid cleaning composition of the present invention can be suitably used for hard articles.
• hard articles include hard articles having hard surfaces such as bathrooms, toilets, kitchens, floors, doorknobs, tableware, hard articles around the kitchen, food processing equipment, desks, chairs, walls, and the like. These hard articles may be used at home or in public facilities or factories, such as swimming pools, bathhouses, cafeterias, hospitals, etc.
• the liquid cleaning composition of the present invention can be particularly suitably used for tableware and/or hard articles around the kitchen.
• Hard articles around the kitchen are articles used around the kitchen, specifically: (1) Storage areas for food, tableware, and cooking utensils such as refrigerators and cupboards; (2) food preparation areas such as drains, cooking tables, range hoods, sinks, gas ranges, and microwave ovens; and (3) floors and walls around the storage areas and cooking areas. In the present invention, these are referred to as "hard articles around the kitchen" for convenience.
• tableware specifically, (i) So-called tableware such as plates and bowls; (ii) Storage containers such as Tupperware and bottles; (iii) Cooking utensils such as knives, cutting boards, pots, frying pans, and fish grills; (iv) Parts and appliances that come into contact with food, such as cooking appliances such as food processors and mixers. In the present invention, these are referred to as "tableware" for convenience.
• Materials for the tableware and/or hard articles around the kitchen that are the object of the present invention include plastic (including silicone resin, etc.), metal, ceramic, wood, and combinations thereof.
• the liquid cleaning composition of the present invention is used after being diluted with water.
• the hardness of the water used in the liquid cleaning composition of the present invention is German hardness, preferably 0° DH or higher, more preferably 4° DH or higher, still more preferably 8° DH or higher, and more. More preferably, it is 10° DH or more, and preferably 20° DH or less, more preferably 16° DH or less, and still more preferably 11° DH or less.
• the calcium and magnesium concentrations for this German hardness are determined by chelate titration using ethylenediaminetetraacetic acid disodium salt.
• a specific method for measuring the German hardness of water in this specification is shown below. ⁇ How to measure the German hardness of water> ⁇ reagent ⁇ ⁇ 0.01 mol/l EDTA/2Na solution: 0.01 mol/l aqueous solution of disodium ethylenediaminetetraacetate (titration solution, 0.01 M EDTA-2Na, manufactured by SIGMA-ALDRICH) ⁇ Universal BT indicator (product name: Universal BT manufactured by Dojindo Laboratories Co., Ltd.) ⁇ Ammonia buffer solution for hardness measurement (a solution in which 67.5 g of ammonium chloride was dissolved in 570 ml of 28 w/v% ammonia water and the total volume was made up to 1000 ml with ion-exchanged water) [Measurement of hardness] (1) Collect 20
• the present invention provides a method for cleaning a target surface, in which a cleaning liquid (hereinafter referred to as the cleaning liquid of the present invention) obtained by diluting the liquid cleaning composition of the present invention with water 10 times or more and 10,000 times is brought into contact with the target surface.
• a cleaning liquid hereinafter referred to as the cleaning liquid of the present invention
• the hardness of the water used to dilute the liquid detergent composition of the present invention is the same as the range described for the liquid detergent composition of the present invention, and the method for measuring the hardness of water is also the same.
• the surfaces targeted by the cleaning method of the present invention include (1) foods, such as surfaces of food materials such as vegetables, (2) hard articles, and (3) textile products, such as textile materials such as cloth and thread.
• the target surface of products manufactured using these materials can be targeted.
• the target surface targeted by the cleaning method of the present invention is preferably the hard surface of a hard article, and more preferably the hard surface of a hard article around tableware and/or the kitchen.
• the hard articles and the hard articles around tableware and/or the kitchen are the same as the embodiments described for the liquid cleaning composition of the present invention.
• the liquid cleaning composition of the present invention is diluted with water at a rate of 10 times or more, preferably 30 times or more, more preferably 50 times or more, and still more preferably 100 times or more, and from the viewpoint of cleaning performance and environmental load reduction related to environmental release of washing water, 10,000 times or less, preferably 5,000 times or less, more preferably 1,000 times or less, and even more preferably 200 times or less. .
• the content of surfactant in the liquid cleaning composition of the present invention or the total content of component (a), component (b), component (c), and component (d) is 10% by mass or more and 50% by mass.
• the dilution ratio of the liquid cleaning composition of the present invention with water is 10 times or more, preferably 15 times or more, more preferably 20 times or more, and even more preferably is 25 times or more, more preferably 50 times or more, and 5000 times or less, preferably 2500 times or less, more preferably 2000 times or less, even more preferably 1500 times or less.
• the content of surfactant in the liquid cleaning composition of the present invention or the total content of component (a), component (b), component (c), and component (d) exceeds 50% by mass
• the dilution ratio of the liquid cleaning composition of the present invention with water is 50 times or more, preferably 55 times or more, more preferably 60 times or more, and still more preferably 70 times or more, and , 10,000 times or less, preferably 8,000 times or less, more preferably 5,500 times or less, even more preferably 5,000 times or less.
• the surfactant content is preferably 0.01% by mass or more, more preferably 0.05% by mass or more, still more preferably 0.1% by mass or more, from the viewpoint of cleaning performance. It is more preferably 0.2% by mass or more, preferably 1.0% by mass or less, more preferably 0.8% by mass or less, even more preferably 0.6% by mass or less.
• the total content of components (a), (b), (c), and (d) is preferably 0.01% by mass or more, more preferably 0.01% by mass or more from the viewpoint of cleaning performance. is 0.05% by mass or more, more preferably 0.1% by mass or more, even more preferably 0.2% by mass or more, and preferably 1.0% by mass or less, more preferably 0.8% by mass or less, More preferably, it is 0.6% by mass or less.
• the mass ratio of the content of component (a-1) to the content of component (a-2) (a-1)/(a-2), the content of component (a1-1) The mass ratio between the content of component (a1-2) and the content of component (a1-2) (a1-1)/(a1-2), the mass ratio of the content of component (a) and the content of component (b) (b)/( a)
• the mass ratio (e)/(a) of the content of component (e) and (e) is the same as the range described for the liquid cleaning composition of the present invention.
• a cleaning liquid prepared by diluting the liquid cleaning composition of the present invention with water is brought into contact with the target surface in the form of foam or liquid.
• Methods for bringing the cleaning liquid of the present invention into contact with the target surface include coating, spraying, and dipping, with dipping being preferred.
• the cleaning liquid of the present invention can be applied to the target surface by directly applying the cleaning liquid of the present invention to the target surface, or by attaching the cleaning liquid of the present invention to a flexible material and then retaining the cleaning liquid.
• the cleaning liquid can be applied to the surface of the target by rubbing it several times with your hands to form a foam.
• Examples of methods for spraying the cleaning liquid of the present invention onto the target surface include filling a container equipped with a sprayer and spraying the cleaning liquid in the form of droplets or bubbles.
• Containers equipped with a sprayer include manual spray devices that do not use propellants, such as trigger-type spray containers and pump-type spray containers, and aerosols that use propellants.
• the container equipped with the sprayer is preferably a trigger-type sprayer that can spray the contents in the form of droplets or foam, and a trigger-type sprayer or foamer equipped with a mechanism for spraying the contents in the form of droplets or foam.
• a trigger-type spray equipped with a foam-forming mechanism is more preferred.
• the cleaning solution of the present invention After the cleaning solution of the present invention is applied or sprayed on the target surface, it may be left to stand or it may be scrubbed by applying external force (physical force) using a flexible material such as a sponge or fingers. It's okay.
• the time for which the cleaning solution of the present invention is left to stand after being applied or sprayed onto the target surface is preferably 60 seconds or more, more preferably 3 minutes or more, and still more preferably 5 minutes or more.
• the time is preferably 60 minutes or less, more preferably 30 minutes or less, and still more preferably 10 minutes or less.
• the immersion time is preferably 60 seconds or more, more preferably 3 minutes or more, still more preferably 5 minutes or more, and preferably 60 minutes or less, from the viewpoint of cleaning performance. , more preferably 30 minutes or less, still more preferably 10 minutes or less.
• the present invention discloses the following aspects.
• a method for cleaning a target surface comprising: contacting the target surface with a cleaning liquid prepared by diluting a liquid cleaning composition containing the following components (a), (b), and (e), and water.
• e Component: Enzyme
• the content of component (a) is preferably 1% by mass or more, more preferably 2% by mass or more, even more preferably 5% by mass or more, and preferably 60% by mass or less, and more.
• ⁇ 3> The method for cleaning a target surface according to ⁇ 1>, wherein the content of component (a) in the liquid cleaning composition is 5% by mass or more and 12% by mass or less.
• Component (a) is (a-1) a sulfosuccinic acid alkyl ester or salt thereof having an alkyl group of 5 to 8 carbon atoms (hereinafter referred to as component (a-1)), and (a-2) an alkyl group
• component (a-1) a sulfosuccinic acid alkyl ester or salt thereof having an alkyl group of 5 to 8 carbon atoms
• component (a-2) an alkyl group
• the target surface according to any one of ⁇ 1> to ⁇ 3>, which contains two types selected from sulfosuccinic acid alkyl esters having 9 to 18 carbon atoms or salts thereof (hereinafter referred to as component (a-2)). cleaning method.
• the mass ratio (a-1)/(a-2) between the content of component (a-1) and the content of component (a-2) is preferably 1 or more, more preferably The method for cleaning a target surface according to ⁇ 4>, wherein the number is preferably 2 or more, and preferably 10 or less, more preferably 8 or less, still more preferably 6 or less, and even more preferably 4 or less.
• the mass ratio (a-1)/(a-2) of the content of component (a-1) and the content of component (a-2) is 2 or more and 4 or less.
• component (a1) is a sulfosuccinic acid branched alkyl ester or a salt thereof (hereinafter referred to as component (a1)) having a branched alkyl group having 8 to 12 carbon atoms. How to clean the target surfaces described.
• the branched alkyl group of component (a1) is a branched alkyl group having 9 to 12 carbon atoms, preferably a branched alkyl group having 9 or 10 carbon atoms, and more preferably a main chain having 6 or 7 carbon atoms.
• the method for cleaning a target surface according to ⁇ 7>, which is a branched alkyl group having one or more side chains and the total number of carbon atoms in the side chains is 3.
• branched alkyl group of the component (a1) is a branched alkyl group selected from a 2-propylheptyl group and a 2-ethylhexyl group, preferably a 2-propylheptyl group.
• Component (a1) is (a1-1) a sulfosuccinic acid branched alkyl ester having a branched chain alkyl group having 8 carbon atoms or a salt thereof (hereinafter referred to as component (a1-1)), and (a1-2) 9 carbon atoms.
• component (a1-1) a sulfosuccinic acid branched alkyl ester having a branched chain alkyl group having 8 carbon atoms or a salt thereof
• component (a1-2) 9 carbon atoms.
• the mass ratio (a1-1)/(a1-2) of the content of component (a1-1) to the content of component (a1-2) is preferably 1 or more, more preferably The method for cleaning a target surface according to ⁇ 10>, which is preferably 2 or more, and preferably 10 or less, more preferably 8 or less, still more preferably 6 or less, even more preferably 4 or less.
• the mass ratio (a1-1)/(a1-2) of the content of the component (a1-1) and the content of the component (a1-2) is 2 or more and 4 or less.
• Component (b) is N-alkyl-N,N-dimethyl-N-sulfopropylammonium sulfobetaine, in which the alkyl group has 10 to 14 carbon atoms, N-alkyl-, in which the alkyl group has 10 to 14 carbon atoms.
• N,N-dimethyl-N-(2-hydroxysulfopropyl)ammonium sulfobetaine N-alkanoylaminopropyl-N,N-dimethyl-N-sulfopropylammonium sulfobetaine in which the alkanoyl group has 10 to 14 carbon atoms; and one or more types selected from N-alkanoylaminopropyl-N,N-dimethyl-N-(2-hydroxysulfopropyl)ammoniumsulfobetaine in which the alkanoyl group has 10 to 14 carbon atoms, ⁇ 1> to ⁇ 12>.
• the content of component (b) is preferably 0.1% by mass or more, more preferably 5% by mass or more, even more preferably 10% by mass or more, and preferably 60% by mass or less. , more preferably 40% by mass or less, still more preferably 30% by mass or less, even more preferably 25% by mass or less, the method for cleaning a target surface according to any one of ⁇ 1> to ⁇ 13>.
• ⁇ 15> The method for cleaning a target surface according to any one of ⁇ 1> to ⁇ 13>, wherein the content of component (b) in the liquid cleaning composition is 10% by mass or more and 25% by mass or less.
• the mass ratio (b)/(a) of the content of component (a) to the content of component (b) is preferably 0.01 or more, more preferably 0.5 or more. , more preferably 1 or more, even more preferably 2 or more, and preferably 100 or less, more preferably 50 or less, even more preferably 10 or less, even more preferably 5 or less, even more preferably 3 or less.
• the mass ratio (b)/(a) of the content of component (a) to the content of component (b) is 2 or more and 3 or less, ⁇ 1> to ⁇ 15>.
• ⁇ 18> The method for cleaning a target surface according to any one of ⁇ 1> to ⁇ 17>, wherein the component (e) is one or more enzymes selected from lipase, amylase, and protease, preferably lipase.
• the component (e) is one or more enzymes selected from lipase, amylase, and protease, preferably lipase.
• the content of component (e) as enzyme protein is preferably 0.01% by mass or more, more preferably 0.05% by mass or more, still more preferably 0.1% by mass or more, and ⁇ 1> to ⁇ 18, which is preferably 0.5% by mass or less, more preferably 0.4% by mass or less, still more preferably 0.3% by mass or less, even more preferably 0.2% by mass or less.
• ⁇ 20> The object according to any one of ⁇ 1> to ⁇ 18>, wherein the content of component (e) in the liquid cleaning composition is 0.1% by mass or more and 0.2% by mass or less as an enzyme protein. How to clean surfaces.
• the mass ratio (e)/(a) of the content of component (a) to the content of component (e) is preferably 0.0002 or more, more preferably 0.001 or more. , more preferably 0.01 or more, even more preferably 0.015 or more, and preferably 0.2 or less, more preferably 0.1 or less, still more preferably 0.06 or less, even more preferably 0.05
• the mass ratio (e)/(a) of the content of component (a) to the content of component (e) is 0.015 or more and 0.04 or less, ⁇ 1
• the content of component (c) is preferably 50% by mass or less, more preferably 40% by mass or less, still more preferably 30% by mass or less, even more preferably 20% by mass or less, and more.
• the method for cleaning a target surface according to ⁇ 23> further preferably at most 10% by mass, even more preferably at most 5% by mass.
• Component (c) is an alkylbenzene sulfonate, an alkyl or alkenyl ether sulfate, an alkyl or alkenyl sulfate, an alkanesulfonate, a saturated or unsaturated fatty acid salt, an alkyl or alkenyl ether carboxylate, an ⁇ -sulfo fatty acid
• the method for cleaning a target surface according to ⁇ 23> or ⁇ 24>, wherein the cleaning method is one or more selected from salts, N-acyl amino acids, and phosphoric acid mono- or diesters (hereinafter referred to as component (c-1)).
• (c-1) component is an alkyl or alkenyl ether sulfate salt, preferably a polyoxyalkylene alkyl or alkenyl ether sulfate salt, more preferably has a carbon number of 8 or more, preferably 10 or more, and 18 or less, It preferably has 14 or less alkyl or alkenyl groups, the number of carbon atoms in the oxyalkylene group is preferably 2 or 3, more preferably 2, and the average number of added moles of the oxyalkylene group is 0.5 or more. , more preferably 1.0 or more, and 4.0 or less, preferably 3.0 or less, is a polyoxyalkylene alkyl or alkenyl ether sulfate salt, the method for cleaning a target surface according to ⁇ 25>.
• ⁇ 27> (c-1) component has an alkyl group having 10 or more carbon atoms and 14 or less carbon atoms, the carbon number of the oxyalkylene group is 2, and the average number of added moles of the oxyalkylene group is 1.0 or more and 3.0 or less;
• the method for cleaning a target surface according to ⁇ 25> which is a certain polyoxyalkylene alkyl ether sulfate salt.
• the mass ratio (c-1)/(a) of the content of component (a) to the content of component (c-1) is preferably 0 or more, more preferably 0. Any one of ⁇ 25> to ⁇ 27>, which is 5 or more, and preferably 5 or less, more preferably 3 or less, even more preferably 2 or less, even more preferably 1.5 or less, and even more preferably 1 or less.
• the mass ratio (c-1)/(a) of the content of component (a) and the content of component (c-1) is 0.5 or more and 1 or less, ⁇
• Component (c) is an internal olefin sulfonate (hereinafter referred to as component (c-2)), preferably has carbon atoms of 8 or more, more preferably 12 or more, even more preferably 16 or more, and preferably is an internal olefin sulfonate of 24 or less, more preferably 22 or less, even more preferably 20 or less, even more preferably 18 or less, even more preferably 16. Cleaning method.
• the mass ratio (c-2)/(a) of the content of component (a) to the content of component (c-2) is preferably 0 or more, more preferably 0. of the target surface according to ⁇ 30>, which is 33 or more, more preferably 0.5 or more, and preferably 3 or less, more preferably 2 or less, still more preferably 1.5 or less, even more preferably less than 1. Cleaning method.
• the mass ratio (c-2)/(a) of the content of component (a) to the content of component (c-2) is 0.5 or more and less than 1, ⁇ 30>.
• liquid cleaning composition further optionally contains the following component (d).
• component (d) Component: Surfactant other than component (a), component (b), and component (c)
• (d) component is one or more selected from (d1) nonionic surfactant (hereinafter referred to as (d1) component) and (d2) cationic surfactant (hereinafter referred to as (d2) component), The method for cleaning a target surface according to ⁇ 33>.
• Component is alkyl monoglyceryl ether, polyoxyalkylene monoalkyl or alkenyl ether, alkyl (poly) glycoside (glycoside type nonionic surfactant), sorbitan type nonionic surfactant, aliphatic alkanolamide, fatty acid monoglyceride , sucrose fatty acid ester, and amidated products of alkanolamine and fatty acid, preferably polyoxyalkylene monoalkyl or alkenyl ether, more preferably an alkyl group or alkenyl group having 6 or more carbon atoms and 18 carbon atoms.
• the method for cleaning a target surface according to ⁇ 34> which is a polyoxyalkylene monoalkyl or alkenyl ether which is as follows and has an average number of added moles of oxyalkylene groups of 3 or more and 25 or less.
• (d1) component is (d1-1) alkyl (poly)glycoside (hereinafter referred to as (d1-1) component) and (d1-2) polyoxyalkylene monoalkyl ether (hereinafter referred to as (d1-2) component)
• (d1-1) component alkyl (poly)glycoside
• (d1-2) component polyoxyalkylene monoalkyl ether
• the component (d1-1) is an alkyl (poly)glycoside having a linear primary alkyl group having 10 or 12 carbon atoms, and the average degree of polymerization of the glycoside is 1.3 or more and 1.7 or less, ⁇ 36>.
• the component (d1-2) is a polyoxyethylene monoalkyl ether in which the alkyl group has a linear primary alkyl group having 12 or more carbon atoms and 14 or less carbon atoms, and the average number of added moles of oxyethylene groups is 8 or more and 10 or less.
• the content of component (d) is preferably 5% by mass or more, more preferably 10% by mass or more, even more preferably 15% by mass or more, even more preferably 20% by mass or more, and more.
• the mass ratio (d)/(a) of the content of component (a) to the content of component (d) is preferably 0 or more, more preferably 0.5 or more, and , preferably 3 or less, more preferably 2 or less, still more preferably 1.5 or less, even more preferably 1 or less, the method for cleaning a target surface according to any one of ⁇ 33> to ⁇ 39>.
• the mass ratio (d)/(a) of the content of component (a) to the content of component (d) is 0.5 or more and 1 or less, ⁇ 33> to ⁇ 39>.
• the total content of components (a), (b), (c), and (d) is preferably 17% by mass or more, more preferably 20% by mass or more, and ⁇ 33> to ⁇ 41>, preferably 22% by mass or more, even more preferably 25% by mass or more, and preferably 70% by mass or less, more preferably 60% by mass or less, still more preferably 54% by mass or less.
• the total content of component (a), component (b), component (c), and component (d) is 25% by mass or more and 54% by mass or less, ⁇ 33> to ⁇ 41>.
• Component (f) is one or more water-soluble organic solvents selected from ethanol, propylene glycol, dipropylene glycol, diethylene glycol monobutyl ether, phenoxyethanol, and phenoxyisopropanol, preferably selected from ethanol, propylene glycol, and phenoxyethanol.
• the method for cleaning a target surface according to ⁇ 44> which is one or more water-soluble organic solvents.
• the content of component (f) is preferably 1% by mass or more, more preferably 5% by mass or more, even more preferably 10% by mass or more, and preferably 30% by mass or less, and more.
• ⁇ 49> The method for cleaning a target surface according to ⁇ 48>, wherein the component (g) is one or more selected from sodium chloride, calcium chloride, magnesium chloride, and potassium chloride.
• the content of component (g) is preferably 0.001% by mass or more, more preferably 0.004% by mass or more, even more preferably 0.008% by mass or more, and preferably The method for cleaning a target surface according to ⁇ 48> or ⁇ 49>, wherein the amount is 0.2% by mass or less, more preferably 0.15% by mass or less, even more preferably 0.1% by mass or less.
• ⁇ 51> The method for cleaning a target surface according to ⁇ 48> or ⁇ 49>, wherein the content of component (g) in the liquid cleaning composition is 0.008% by mass or more and 0.1% by mass or less.
• the content of water is preferably 20% by mass or more, more preferably 30% by mass or more, even more preferably 40% by mass or more, and preferably 60% by mass or less, more preferably 50% by mass or more. % by mass or less, the method for cleaning a target surface according to any one of ⁇ 1> to ⁇ 51>.
• ⁇ 53> The method for cleaning a target surface according to any one of ⁇ 1> to ⁇ 51>, wherein the liquid cleaning composition has a water content of 40% by mass or more and 50% by mass or less.
• ⁇ 54> The method for cleaning a target surface according to any one of ⁇ 1> to ⁇ 53>, wherein the target surface is a hard surface of a hard article.
• ⁇ 55> The method for cleaning a target surface according to ⁇ 54>, wherein the hard article is a tableware and/or a hard article around the kitchen.
• the hardness of the water in which the liquid cleaning composition is diluted with water is German hardness, preferably 0° DH or more, more preferably 4° DH or more, still more preferably 8° DH or more, even more preferably 10° DH.
• ⁇ 57> The method for cleaning a target surface according to any one of ⁇ 1> to ⁇ 55>, wherein the hardness of the water in which the liquid cleaning composition is diluted with water is 10° DH or more and 11° DH or less on the German hardness scale. .
• ⁇ 58> The method for cleaning a target surface according to any one of ⁇ 1> to ⁇ 57>, wherein the method of bringing the cleaning liquid into contact with the target surface is coating, spraying, or dipping, preferably dipping.
• a liquid cleaning composition containing the following components (a), (b), (e), and water.
• Example (1) Preparation of liquid detergent composition Using the following ingredients, liquid detergent compositions shown in Tables 1 to 5 were prepared, and the following items were evaluated.
• the liquid cleaning compositions in Tables 1 to 5 were prepared by conventional methods. That is, components (a) to (f) are added to an appropriate amount of water, dissolved at room temperature (25°C), and then sodium hydroxide or/and hydrochloric acid is added to adjust the pH (at 25°C) to 7.0. Adjusted to. Note that the mass % of the ingredients in Tables 1 to 5 are all values based on the effective content.
• Component (e) indicates the content (% by mass) as an enzyme protein.
• the enzyme protein (e) was quantified using Protein Assay Kit II manufactured by Bio-Rad (Cat. No. 500-0002) according to the standard assay method using bovine serum albumin attached to the kit as the standard protein.
• ⁇ D26SS Di(2- Sodium ethylhexyl) sulfosuccinate, a compound of general formula (a1-a) in which R 1a and R 2a are 2-ethylhexyl groups and M 1 is a sodium ion ⁇ component (b)> ⁇ Sulfobetaine: lauryl hydroxysulfobetaine, Amhitol 20HD, manufactured by Kao Corporation ⁇ (c) component> ⁇ ES: Sodium polyoxyethylene lauryl sulfate, (c-1) component, Emar 270, manufactured by Kao Corporation ⁇ IOS: Potassium salt of internal olefin sulfonate having 16 carbon atoms obtained in Production Example 1 below, (c- 2) Ingredients
• Example of production of raw material for component (c-2) Example of production of internal olefin having 16 carbon atoms
• 7000 g (28.9 mol) of 1-hexadecanol product name: Calcol 6098, manufactured by Kao Corporation
• 700 g (STREM Chemicals, Inc.) of ⁇ -alumina STREM Chemicals, Inc.
• STREM Chemicals, Inc. ⁇ -alumina
• the obtained crude internal olefin was transferred to a distillation flask and distilled at 148-158° C./0.5 mmHg to obtain a 16-carbon internal olefin with olefin purity of 100%.
• the double bond distribution of the obtained internal olefin is shown.
• component (c-2) is a potassium internal olefin sulfonate product.
• ⁇ (d) component> ⁇ AE Polyoxyethylene lauryl ether, (d1) component, Emulgen 109P, manufactured by Kao Corporation ⁇ (e) component> ⁇ Lipase: Lipex evity 100L, manufactured by Novozymes (effective content 5%) ⁇ Amylase: Amplify Prime 100L, manufactured by Novozymes (effective content 5%) ⁇ Protease: Progless Uno, manufactured by Novozymes (effective content 10%) ⁇ (f) component> ⁇ EtOH: Ethanol (99.5%), manufactured by Fujifilm Wako Pure Chemical Industries, Ltd. ⁇ BDG: Diethylene glycol monobutyl ether, manufactured by Fujifilm Wako Pure Chemical Industries, Ltd.

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