WO2022255392A1 - 樹脂フィルム、合わせガラス、及びスクリーン - Google Patents

樹脂フィルム、合わせガラス、及びスクリーン Download PDF

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Publication number
WO2022255392A1
WO2022255392A1 PCT/JP2022/022236 JP2022022236W WO2022255392A1 WO 2022255392 A1 WO2022255392 A1 WO 2022255392A1 JP 2022022236 W JP2022022236 W JP 2022022236W WO 2022255392 A1 WO2022255392 A1 WO 2022255392A1
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WIPO (PCT)
Prior art keywords
resin
resin film
less
light
light diffusion
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2022/022236
Other languages
English (en)
French (fr)
Japanese (ja)
Inventor
祐輔 太田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sekisui Chemical Co Ltd
Original Assignee
Sekisui Chemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sekisui Chemical Co Ltd filed Critical Sekisui Chemical Co Ltd
Priority to JP2022539315A priority Critical patent/JPWO2022255392A1/ja
Priority to EP22816138.6A priority patent/EP4349793A4/en
Priority to US18/565,266 priority patent/US20240208185A1/en
Priority to KR1020237040840A priority patent/KR20240017349A/ko
Priority to CN202280038391.9A priority patent/CN117425634A/zh
Publication of WO2022255392A1 publication Critical patent/WO2022255392A1/ja
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2605/00—Vehicles
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2329/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Derivatives of such polymer
    • C08J2329/14—Homopolymers or copolymers of acetals or ketals obtained by polymerisation of unsaturated acetals or ketals or by after-treatment of polymers of unsaturated alcohols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/08—Metals
    • C08K2003/0806—Silver
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/08—Metals
    • C08K2003/0881—Titanium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives

Definitions

  • the present invention relates to a resin film, laminated glass, and screen that can be suitably used for image display screens, for example.
  • Laminated glass is safe because it does not scatter glass fragments even if it is damaged by an external impact. Widely used.
  • Laminated glass is generally widely known as one in which an interlayer film for laminated glass composed of a thermoplastic resin or the like is interposed between a pair of glasses to integrate them.
  • the laminated glass used for transparent screens cannot sufficiently improve the color reproducibility when displaying images even if light diffusing fine particles are added to the resin film that constitutes the intermediate film as described above. There's a problem.
  • an object of the present invention is to provide a resin film that can realize image display with high color reproducibility even when used as an image display screen, a laminated glass including the resin film, and a screen.
  • the gist of the present invention is as follows.
  • a resin film comprising a light diffusion layer containing light diffusion particles and a thermoplastic resin, In the chromaticity coordinates (CIE1931) of the transmitted light when the laminated glass obtained by bonding two sheets of clear glass with a thickness of 2.5 mm through the resin film is irradiated with simulated sunlight by a solar simulator.
  • a resin film having an x value of 0.25 or more and 0.4 or less and a y value of 0.25 or more and 0.4 or less.
  • [12] comprising three or more resin layers, each layer comprising a thermoplastic resin;
  • the three or more resin layers include the light diffusion layer and second and third resin layers,
  • [13] The above [ 12].
  • [14] The resin film according to [12] or [13] above, wherein the thermoplastic resin contained in each of the second and third resin layers is a polyvinyl acetal resin.
  • thermoplastic resin contained in each of the second and third resin layers is selected from the group consisting of polyvinyl acetal resin, ethylene-vinyl acetate copolymer resin, ionomer resin, polyurethane resin, and thermoplastic elastomer.
  • the thermoplastic resin contained in the light diffusion layer is at least one selected from the group consisting of polyvinyl acetal resins, ethylene-vinyl acetate copolymer resins, ionomer resins, polyurethane resins, and thermoplastic elastomers.
  • any one of the above [1] to [16], wherein the haze value of the laminated glass obtained by bonding two sheets of clear glass having a thickness of 2.5 mm through the resin film is 6% or less.
  • Any one of the above [1] to [17], wherein the transmittance of the laminated glass obtained by bonding two sheets of clear glass having a thickness of 2.5 mm through the resin film is 70% or more.
  • a laminated glass obtained by bonding two sheets of clear glass with a thickness of 2.5 mm through the resin film has a luminance of 50 cd/m 2 when simulated sunlight is irradiated by a solar simulator.
  • the light diffusing particles are core-shell particles.
  • the light diffusing particles have at least one of metal particles and metal oxide particles as a core and a material containing at least one selected from the group consisting of semimetals and metal oxides as a core-
  • the core is a core-shell particle containing silver element, titanium element, or both silver element and titanium element.
  • the content of the light diffusion particles in 100% by mass of the resin film is 0.0001% by mass or more and 0.01% by mass or less, according to any one of the above [1] to [25].
  • resin film [27] Any one of the above [1] to [26], wherein the content of the light diffusion particles in the light diffusion layer is 0.00005% by mass or more and 2% by mass or less in 100% by mass of the light diffusion layer.
  • the resin film described in . Any one of the above [1] to [27], wherein the content of the light diffusion particles in the light diffusion layer is 0.0005% by mass or more and 0.1% by mass or less in 100% by mass of the light diffusion layer.
  • [33] The x value in the chromaticity coordinates (CIE1931) of transmitted light when irradiated with simulated sunlight by a solar simulator is 0.25 or more and 0.4 or less, and the y value is 0.25 or more and 0.4 or less. is the screen. [34] The screen according to [33] above, which has a haze value of 6% or less. [35] The screen of [33] or [34] above, which has a transmittance of 70% or more. [36] The screen according to any one of [33] to [35] above, which has a luminance of 50 cd/m 2 or more when irradiated with simulated sunlight from a solar simulator.
  • the screen according to any one of [33] to [38] above which has a resin film provided with a light diffusion layer containing light diffusion particles and a thermoplastic resin.
  • An image display system comprising the laminated glass described in [32] above or the screen described in any one of [33] to [39] above, and a light source device.
  • FIG. 1 is a schematic diagram showing an image display system according to an embodiment of the present invention
  • FIG. 4 is a schematic diagram showing a method of measuring chromaticity, luminance, and maximum intensity A, B, and C
  • FIG. 4 is a schematic diagram showing a method of measuring chromaticity, luminance, and maximum intensity A, B, and C
  • the resin film of the present invention comprises a light diffusing layer containing light diffusing particles and a thermoplastic resin.
  • the resin film of the present invention is preferably used for image display screens. Since the resin film of the present invention includes a light diffusion layer containing light diffusion particles, the light irradiated to the resin film is diffused by the light diffusion layer. can be displayed on a screen with the film.
  • the resin film is preferably an intermediate film for laminated glass, and more preferably used for an image display screen made of laminated glass.
  • the resin film of the present invention is a laminated glass made by bonding two sheets of clear glass with a thickness of 2.5 mm (hereinafter also referred to as "reference glass") through the resin film.
  • x value is 0.25 or more and 0.4 or less
  • y value is 0.25 or more and 0.4 or less in the chromaticity coordinates (CIE1931) of transmitted light when irradiated with .
  • CIE1931 chromaticity coordinates
  • the pseudo-sun irradiation was performed by a solar simulator.
  • the reference glass is a clear glass having a thickness of 2.5 mm conforming to JIS R 3211 (1998), and specifically having a visible light transmittance of 90.4%.
  • the simulated sunlight produced by the solar simulator is white light.
  • the white light cannot be reproduced. Therefore, if a resin film is used for a screen for screen display, image display with high color reproducibility cannot be achieved.
  • the x value is preferably 0.28 or more, more preferably 0.3 or more, and preferably 0.39 or less, more preferably 0.38 or less, and still more preferably is 0.35 or less.
  • the y value is preferably 0.28 or more, more preferably 0.3 or more, still more preferably 0.32 or more, and preferably 0 from the viewpoint of improving color reproducibility. 0.39 or less, more preferably 0.38 or less.
  • the x value and the y value are preferably within the above ranges when simulated sunlight is irradiated from one surface of the laminated glass and the chromaticity is measured on the other surface. The same applies to the measurement of the maximum intensity ratio and luminance, which will be described later. It is preferable to measure the maximum intensity ratio and luminance by irradiating simulated sunlight from the surface opposite to the measurement side.
  • Examples of methods for adjusting the above x value and y value within the above ranges include using a combination of light diffusing particles, which will be described later, and controlling the particle size distribution of the light diffusing particles.
  • the x value and the y value can be adjusted within the above ranges by reducing the number of particles of 10 nm or less.
  • the term “composite” means using light diffusing particles in which two or more compositions are combined, rather than containing two or more kinds of light diffusing particles.
  • the resin film of the present invention is a laminated glass prepared by bonding two sheets of reference glass via a resin film.
  • the ratio of intensity A to maximum intensity B at 530 to 560 nm is preferably 1.0 or less.
  • a wavelength of 430 to 460 nm is a wavelength at which blue light appears, and a wavelength of 530 to 560 nm is a wavelength at which green light appears. Therefore, by setting the maximum intensity A/maximum intensity B to 1.0 or less, it is possible to suppress excessive diffusion of blue light by the light diffusion particles as compared with green light. Therefore, the x value and the y value are easily adjusted within the predetermined range, and the color reproducibility is enhanced.
  • maximum intensity A/maximum intensity B is more preferably 0.9 or less, and even more preferably 0.8 or less.
  • the maximum intensity A/maximum intensity B is preferably 0.1 or more, and more preferably 0.3 or more. Preferably, 0.5 or more is even more preferable.
  • the resin film of the present invention is a laminated glass prepared by bonding two sheets of reference glass via a resin film.
  • the ratio of the intensity A to the maximum intensity C at 560 to 600 nm is preferably 1.2 or less.
  • a wavelength of 430 to 460 nm is a wavelength at which blue light appears, and a wavelength of 560 to 600 nm is a wavelength at which red light appears. Therefore, by setting the maximum intensity A/maximum intensity C to 1.2 or less, it is possible to suppress excessive diffusion of blue light by the light diffusion particles as compared with red light. Therefore, the x value and the y value are easily adjusted within the predetermined range, and the color reproducibility is improved.
  • maximum intensity A/maximum intensity C is more preferably 1.1 or less, and even more preferably 1.05 or less.
  • the maximum intensity A/maximum intensity C is preferably 0.2 or more, and more preferably 0.4 or more. Preferably, 0.6 or more is even more preferable.
  • the maximum intensities A, B, and C are the maximum intensity values in the wavelength range of 430 to 460 nm, the wavelength range of 530 to 560 nm, and the wavelength range of 560 to 600 nm, respectively.
  • the maximum intensity ratio described above can be adjusted within the predetermined range described above by appropriately selecting the type, particle size, particle size distribution, etc. of the light diffusion particles contained in the resin film.
  • the use of a combination of light diffusing particles, the control of the particle size distribution of the light diffusing particles, and the like can be mentioned.
  • the resin film of the present invention preferably has a transmittance of 70% or more for a laminated glass prepared by bonding two sheets of reference glass via a resin film.
  • the transmittance means visible light transmittance, and can be obtained by measuring according to JIS R3212 (2015).
  • the transmittance is 70% or more, a certain degree of transparency can be ensured, and it can be suitably used for various window glasses, such as automobile windshields.
  • the transmittance is more preferably 75% or higher, and even more preferably 80% or higher.
  • the higher the transmittance the better, but practically it is 99% or less, and from the viewpoint of appropriately diffusing light in the resin film, it is 97% or less. is preferred.
  • the resin film of the present invention preferably has a haze value of 15% or less for a laminated glass produced by bonding two sheets of reference glass via a resin film.
  • the haze value is more preferably 10% or less, even more preferably 6% or less, and even more preferably 4% or less, from the viewpoint of increasing transparency.
  • the haze value is, for example, 0.5% or more, preferably 1% or more, and more preferably 2% or more, from the viewpoint of appropriately displaying an image by diffusing a certain amount of light with the light diffusion particles.
  • the haze value can be measured according to JIS K6714.
  • the resin film of the present invention has a luminance of 50 cd/m 2 or more when simulated sunlight is irradiated by a solar simulator to a laminated glass produced by bonding two sheets of reference glass via a resin film. is preferably When it is at least the above lower limit, when the resin film of the present invention is used for a screen for screen display, images can be clearly displayed.
  • the luminance is more preferably 100 cd/m 2 or higher, and even more preferably 150 cd/m 2 or higher. Also, the luminance is preferably 10,000 cd/m 2 or less.
  • the luminance is more preferably 8,000 cd/m 2 or less, and even more preferably 5,000 cd/m 2 or less.
  • the above luminance measurement method is evaluated under the same conditions as the chromaticity measurement except that the output of the light source used in the examples is set to 30%.
  • Light diffusing particles used in the resin film of the present invention include silicon oxide such as silica, zirconium oxide, titanium oxide, aluminum oxide such as alumina, magnesium oxide, semimetal or metal oxide particles such as cerium oxide, aluminum, Metal particles such as silver, platinum, gold, titanium, nickel, tin, indium, tin-cobalt alloys, diamond particles, and the like. By using these particles, while ensuring the transparency of the resin film, it becomes easy to improve the light diffusibility, color reproducibility, and the like. Among them, metal particles, metal oxide particles, and diamond particles are preferable from the viewpoint of transparency, light diffusibility, color reproducibility, and the like.
  • the metal element in the metal or metal oxide particles it is preferable to use elemental silver or elemental titanium. Silver particles, titanium oxide particles, titanium particles and diamond particles are more preferred, and silver particles and titanium oxide particles are particularly preferred.
  • the light diffusing particles may be core-shell particles.
  • the light diffusing particles may be core-shell particles in which any of the aforementioned semimetal or metal oxide particles, metal particles, diamond particles, etc. are used as the core and coated with different materials. More specifically, metal particles (core-shell particles) having the metal particle as a core and the above semimetal or metal oxide, or a composite of a semimetal or metal oxide and a polymer as a shell. may Further, metal particles (core-shell particles) having the above metal oxide particles as the core and the above semimetal or metal oxide, or a composite of the semimetal or metal oxide and the polymer as the shell, etc. good. In this case, instead of metal oxide particles, particles containing metal and metal oxide may be used as cores.
  • the light diffusing particles may be core-shell particles whose shell is silica, alumina or a mixture thereof, or core-shell particles whose shell is a composite of silica, alumina or a mixture thereof and a polymer.
  • the light diffusing particles may include core-shell particles having the mixture as a shell and core-shell particles having the composite as a shell.
  • metal particles having a metal particle as a core are preferred.
  • Metal oxide particles having a metal oxide particle as a core (core-shell particles) are also preferred.
  • the light diffusing particles may be core-shell particles whose core is a particle containing a silver element such as silver, or core-shell particles whose core is a particle containing a titanium element such as titanium oxide. It may be a particle, or a core-shell particle having a core of a particle containing both silver element and titanium element.
  • silver particles preferably silver nanoparticles described later
  • the core-shell particles may be particles having silica as the core and silver or other metal as the shell.
  • the light diffusing particles may be used singly or in combination of two or more.
  • the average particle size of the light diffusing particles is preferably, for example, 1 nm or more and 100 ⁇ m or less. Within the above range, visible light is appropriately diffused by the light diffusing particles, and good color reproducibility can be achieved when an image is displayed. From the viewpoint of improving color reproducibility, the average particle size of the light diffusion particles is preferably 3 nm or more and 50 ⁇ m or less, more preferably 5 nm or more and 20 ⁇ m or less, and even more preferably 10 nm or more and 5 ⁇ m or less. .
  • the average particle size of the light diffusing particles can be measured by a laser diffraction/scattering method.
  • the light diffusing particles are preferably so-called nanoparticles. Therefore, the light diffusion particles are more preferably nanoparticles containing at least one of elemental silver and elemental titanium, more preferably silver nanoparticles, titanium oxide nanoparticles, and nanodiamonds, and particularly preferably silver nanoparticles.
  • the nanoparticles are particles having an average particle size of 1 ⁇ m or less (1000 nm or less), and the average particle size of the nanoparticles is preferably 900 nm or less. Although the lower limit of the average particle size of the nanoparticles is as described above for the light diffusion particles, the average particle size of the nanoparticles may be 50 nm or more, or may be 110 nm or more.
  • the light diffusing particles it is preferable to use two or more kinds of particles having mutually different compositions, preferably at least three kinds of particles having mutually different compositions so that the x value and the y value are within the above ranges.
  • the above-mentioned core-shell particles it is preferable to use at least two, preferably at least three kinds of particles in which the core and shell materials are the same and the mass ratio of the shell to each particle is different from each other.
  • the particle size distribution of the light diffusing particles may be appropriately adjusted so that the x value or y value is within the above range.
  • the content of particles with a small particle size should be small, and the content of particles with a diameter of 10 nm or less should be particularly small.
  • the content of particles with a diameter of 10 nm or less should be particularly small.
  • light on the short wavelength side is more easily dispersed.
  • two or more kinds of light-scattering particles having different average particle diameters may be mixed.
  • the shape of the light diffusing particles is not particularly limited, and may be a flaky shape such as a plate shape or scale shape, a spherical shape or a shape approximating a sphere (substantially spherical), a polyhedral shape, or a shape approximating a polyhedron (e.g. , a partially curved polyhedron, a substantially polyhedron), an irregular shape, and the like.
  • the light diffusing particles may, for example, have an aspect ratio of less than 3, preferably 2 or less. By reducing the aspect ratio of the light diffusing particles, it becomes easier to improve the light diffusibility while reducing the haze value.
  • Spherical or substantially spherical light diffusion particles generally have an aspect ratio of 2 or less, which is close to 1.
  • the aspect ratio it is preferable to obtain the ratio of the major axis and the minor axis of the particle, and in the case of flaky light diffusion particles, it is preferable to measure the major axis/thickness.
  • the aspect ratio may be measured by microscopic observation such as SEM, for example, 50 particles may be measured and the average value thereof may be taken as the aspect ratio.
  • the content of the light diffusion particles in the entire resin film is preferably 0.00001% by mass or more and 1% by mass or less in 100% by mass of the resin film.
  • the content of the light diffusing particles is equal to or higher than the above lower limit, light can be diffused appropriately in the resin film, and images can be displayed appropriately.
  • it is possible to ensure the transparency of the resin film without being blocked by the light diffusion particles more than necessary, and it becomes easy to adjust the haze value and the transmittance within the desired ranges described above. .
  • the content of the light diffusion particles in 100% by mass of the resin film is more preferably 0.00005% by mass or more, still more preferably 0.0001% by mass or more, and even more preferably 0.0008% by mass. and more preferably 0.5% by mass or less, more preferably 0.1% by mass or less, even more preferably 0.09% by mass or less, even more preferably 0.05% by mass or less, and particularly preferably is 0.01% by mass or less.
  • the content of the light diffusion particles in the light diffusion layer is preferably 0.00005% by mass or more and 2% by mass or less in 100% by mass of the light diffusion layer.
  • the content of the light diffusing particles in the light diffusing layer is equal to or higher than the above lower limit, the light can be diffused moderately in the light diffusing layer, and an image can be appropriately displayed.
  • the content of the light diffusion particles in 100% by mass of the light diffusion layer is more preferably 0.0001% by mass or more, still more preferably 0.0005% by mass or more, and even more preferably 0.005% by mass. % or more, more preferably 1% by mass or less, still more preferably 0.5% by mass or less, even more preferably 0.1% by mass or less, even more preferably 0.09% by mass or less, particularly preferably 0 .03% by mass or less.
  • the resin film of the present invention has one or more resin layers each containing a thermoplastic resin, one of which is a light diffusion layer containing light diffusion particles and a thermoplastic resin. That is, the resin film may be a resin film composed of a single light diffusion layer, or may have two or more resin layers, one of which may be a light diffusion layer.
  • FIG. 1 shows a resin film 10 having a single resin layer as the resin layer.
  • the resin film 10 is composed of a light diffusion layer (first resin layer) 11.
  • first resin layer a light diffusion layer
  • both surfaces of the light diffusion layer 11 are glass members 21 and 22 for forming a laminated glass 25. It should be glued.
  • FIG. 2 shows a resin film 16 having two resin layers as resin layers. As shown in FIG. 2, the resin film 16 has a second resin layer 12 in addition to the light diffusion layer 11 described above. The second resin layer 12 is provided on one surface of the first resin layer 11 .
  • the resin film 16 when used for laminated glass, includes a surface of the second resin layer 12 opposite to the light diffusion layer 11 side and a surface of the light diffusion layer 11 opposite to the second resin layer 12 side.
  • the surface of is preferably a bonding surface to be bonded to the glass members 21 and 22 for forming the laminated glass 20 .
  • FIG. 3 shows a resin film 17 having three resin layers as resin layers.
  • the resin film 17 has a third resin layer 13 in addition to the light diffusion layer 11 and the second resin layer 12 .
  • the third resin layer 13 is provided on the surface (the other surface) of the light diffusion layer 11 opposite to the one surface on which the second resin layer 12 is provided. That is, the light diffusion layer 11 is arranged between the second resin layer 12 and the third resin layer 13 .
  • the resin film 17 is formed on the outer surface of the second resin layer 12 and the third resin layer 13 (that is, the surface opposite to the surface on which the light diffusion layer 11 is provided). ) should be the surfaces to be adhered to the glass members 21 and 22 constituting the laminated glass 27 .
  • the resin film may have four or more resin layers, in which case one or more resin layers may be provided outside one or both of the second and third resin layers 12 and 13.
  • the outermost resin layer may serve as an adhesive surface with the glass member.
  • the resin film an aspect having at least three resin layers like the resin film 17 is preferable. According to this aspect, since other resin layers are provided on both sides of the first resin layer (light diffusion layer) 11, the resin other than the light diffusion layer 11 containing the light diffusion particles in the laminated glass The layers are adhered to the glass members 21 and 22, and the adhesion to the glass members 21 and 22 is improved. Further, by adjusting the amount of the plasticizer in each resin layer, the amount of hydroxyl groups in the polyvinyl acetal-based resin, and the like, it becomes easier to impart sound insulation and the like to the resin film.
  • the resin film may have layers other than the resin layers described above, and for example, another layer such as an adhesive layer or a barrier layer may be arranged between the resin layers. Further, another layer such as an adhesive layer may be arranged between each glass member and the resin layer.
  • the resin film is used as an intermediate film for laminated glass, but it is not necessary to be used as an intermediate film for laminated glass.
  • the resin film may be used for so-called outer application. That is, one surface of the resin film may be adhered to the surface of the glass member, while the other surface thereof may not be adhered to the glass member.
  • the light diffusion layer (first resin layer) contains a thermoplastic resin as described above, and light diffusion particles are dispersed in the thermoplastic resin. Since the light diffusion layer contains a thermoplastic resin, it becomes easier to adhere the first resin layer to another resin layer, a glass member, or the like.
  • the thermoplastic resin used for the light diffusion layer may be described as thermoplastic resin (1).
  • thermoplastic resin (1) used for the light diffusion layer is not particularly limited, but examples include polyvinyl acetal resin, ethylene-vinyl acetate copolymer resin, ionomer resin, polyurethane resin, and heat Examples include plastic elastomers. By using these resins, it becomes easy to secure the adhesiveness of the first resin layer to other resin layers, glass members, etc., and it can be suitably used as an interlayer film for laminated glass. Among the above, polyvinyl acetal resin is preferable as the thermoplastic resin (1).
  • thermoplastic resin used as the thermoplastic resin (1) in the first resin layer may be used alone or in combination of two or more. Details of the thermoplastic resin used for the first resin layer will be described later.
  • the first resin layer of the present invention further contains a plasticizer.
  • the plasticizer contained in the first resin layer is sometimes referred to as plasticizer (1).
  • the first resin layer becomes flexible by containing the plasticizer (1).
  • the flexibility of the laminated glass is improved, and the penetration resistance and sound insulation properties are improved. make it easier to improve
  • the contrast of the displayed image can be further enhanced when the resin film is used for an image display screen. This is probably because the inclusion of the plasticizer increases the difference in refractive index between the first resin layer and the light diffusing particles.
  • the first resin layer contains a plasticizer, it is possible to increase the adhesiveness to a glass member constituting laminated glass or the like, or to another resin layer constituting a resin film.
  • the plasticizer (1) is particularly effective when the polyvinyl acetal resin (1) is used as the thermoplastic resin (1). The details of the plasticizer (1) will be described later.
  • the content of the plasticizer (1) with respect to 100 parts by mass of the thermoplastic resin (1) (hereinafter sometimes referred to as content (1)) is, for example, 20 parts by mass or more, It is preferably 30 parts by mass or more, more preferably 40 parts by mass or more.
  • content (1) is at least the above lower limit, the flexibility of the resin film is increased and the handling of the resin film is facilitated.
  • the content (1) is preferably increased from the viewpoint of sound insulation when used as an interlayer film for laminated glass, and from such a viewpoint, the content (1) is 50 parts by mass or more. is even more preferable.
  • the resin film preferably has the second resin layer, and more preferably has the second and third resin layers.
  • the content (1) of the plasticizer (1) is preferably 100 parts by mass or less, more preferably 90 parts by mass or less, even more preferably 85 parts by mass or less, and particularly preferably 80 parts by mass or less.
  • the first resin layer is mainly composed of a thermoplastic resin, or a thermoplastic resin and a plasticizer, and the total amount of the thermoplastic resin and the plasticizer is preferably based on the total amount of the first resin layer. is 70% by mass or more, more preferably 80% by mass or more, and still more preferably 90% by mass or more.
  • each resin layer other than the first resin layer is a layer containing a thermoplastic resin.
  • a thermoplastic resin used as the resin for each resin layer, it becomes easier to bond each resin layer to another resin layer or a glass member.
  • the thermoplastic resin used for each of the second and third resin layers may be referred to as thermoplastic resin (2) and thermoplastic resin (3).
  • thermoplastic resin used for each resin layer other than the first resin layer is not particularly limited, but each is used as thermoplastic resin (1), for example. It can be used by appropriately selecting from those listed as resins that can be used.
  • polyvinyl acetal resin is preferred. By using a polyvinyl acetal resin, it is easy to improve the adhesiveness to a glass member, especially when the glass member is inorganic glass, and it can be suitably used as an interlayer film for laminated glass. In addition, it becomes easy to obtain properties required for an interlayer film for laminated glass, such as penetration resistance and sound insulation.
  • thermoplastic resin used for the resin layers other than the first resin layer may be used singly or in combination of two or more in each resin layer.
  • the thermoplastic resin used for each resin layer other than the first resin layer is preferably the same resin as the thermoplastic resin (1) from the viewpoint of improving adhesion. Therefore, when the resin film has the first and second resin layers and the thermoplastic resin (1) is a polyvinyl acetal resin, the thermoplastic resin (2) is also preferably a polyvinyl acetal resin.
  • the thermoplastic resin (3) is preferably the same type of resin as the thermoplastic resin (1) and the thermoplastic resin (2).
  • thermoplastic resin (1) is a polyvinyl acetal resin
  • thermoplastic resins (2) and (3) are polyvinyl acetal resins. is preferred.
  • the details of the thermoplastic resin used for the resin layers other than the first resin layer will be described later.
  • each resin layer other than the first resin layer preferably contains a plasticizer. That is, the second resin layer in the resin film preferably contains a plasticizer. Also, the third resin layer preferably contains a plasticizer. Therefore, when the resin film has a plurality of resin layers, both the first and second resin layers preferably contain a plasticizer. Further, when the resin film has first, second and third resin layers, it is more preferable that all of the first, second and third resin layers contain a plasticizer.
  • the plasticizer contained in each of the second and third resin layers may be referred to as plasticizer (2) and plasticizer (3).
  • the content of the plasticizer (2) with respect to 100 parts by mass of the thermoplastic resin (2) in the second resin layer may be described as content (2), and the thermoplastic resin (3 )
  • content (3) The content of the plasticizer (3) with respect to 100 parts by mass is sometimes described as content (3).
  • the resin film becomes flexible by containing a plasticizer in each resin layer described above, and as a result, when used as an interlayer film for laminated glass, the flexibility and penetration resistance of the laminated glass are improved. Furthermore, it is also possible to exhibit high adhesiveness to other resin layers of the resin film or glass members such as glass plates. Also, in each of the resin layers other than the first resin layer, it is particularly effective to contain a plasticizer when polyvinyl acetal resin is used as the thermoplastic resin. Plasticizers (for example, plasticizers (2) and (3)) used in resin layers other than the first resin layer may be of the same type as plasticizer (1), or may be of different types.
  • plasticizers for example, plasticizers (2) and (3) used in the resin layers other than the first resin layer may be of the same type or different types. Further, only one plasticizer may be used for each resin layer other than the first resin layer, or two or more plasticizers may be used in combination.
  • the plasticizer content relative to 100 parts by mass of the thermoplastic resin is preferably 10 parts by mass or more.
  • the content of the plasticizer is more preferably 15 parts by mass or more, still more preferably 20 parts by mass or more, and particularly preferably 24 parts by mass or more.
  • the content of the plasticizer in each resin layer other than the first resin layer is preferably 60 parts by mass or less, more preferably 50 parts by mass or less, and even more preferably is 45 parts by mass or less. When each of these contents is equal to or less than the above upper limit, mechanical properties such as flexural rigidity of the resin film are improved.
  • the plasticizer content (1) in the first resin layer is preferably greater than the plasticizer content in each of the resin layers other than the first resin layer. That is, the content (1) of the plasticizer is preferably greater than the content (2), and the content (1) is preferably greater than the content (3). Further, when the resin film has the first to third resin layers, the content (1) is more preferably greater than both the above contents (2) and (3).
  • the content (1) and the content of the plasticizer in each resin layer other than the first resin layer are preferably 10 parts by mass or more, more preferably 15 parts by mass or more, and still more preferably 20 parts by mass or more.
  • the absolute values of the differences are preferably 70 parts by mass or less, more preferably 60 parts by mass or less, and even more preferably 50 parts by mass or less.
  • the main component is a thermoplastic resin, or a thermoplastic resin and a plasticizer, and the total amount of the thermoplastic resin and the plasticizer is based on the total amount of each resin layer. , preferably 70% by mass or more, more preferably 80% by mass or more, and still more preferably 90% by mass or more.
  • Each resin layer other than the first resin layer may or may not contain the light diffusion particles described above, but the resin film It is preferable that the total content of the light diffusion particles is designed to be within the above range. Therefore, even if each resin layer other than the first resin layer contains the above-described light diffusion particles, the content is small, or it is preferable not to contain light diffusion particles. It is more preferable not to. As described above, light diffusion particles are not contained in each resin layer other than the first resin layer, or if they are contained in a small amount, light scattering hardly occurs in each resin layer. Thereby, when the resin film is used for an image display screen, the contrast of the displayed image can be enhanced.
  • the content of the light diffusing particles in each resin layer other than the first resin layer is not particularly limited, but is, for example, less than 0.1% by mass, preferably It is less than 0.0005% by mass, more preferably less than 0.00001% by mass, still more preferably 0% by mass.
  • the thickness of the resin film (that is, the thickness of the entire resin film) is not particularly limited, but is preferably 100 ⁇ m or more and 3.0 mm or less.
  • the thickness of the resin film is more preferably 200 ⁇ m or more, still more preferably 400 ⁇ m or more. Also, it is more preferably 2.0 mm or less, and still more preferably 1.5 mm or less.
  • the thickness of the resin film, the thickness of the light diffusion layer, and the thickness of the resin layers other than the first resin layer mean average thickness unless otherwise specified. It can be measured by the measuring method.
  • the thickness of the light diffusion layer (first resin layer) is preferably 20 ⁇ m or more and 400 ⁇ m or less.
  • the thickness of the light diffusion layer (first resin layer) is more preferably 40 ⁇ m or more, still more preferably 60 ⁇ m or more, and more preferably 250 ⁇ m or less, still more preferably 200 ⁇ m or less.
  • the thickness of the light scattering layer is substantially constant in the resin film.
  • the difference between the maximum thickness and the minimum thickness of the light diffusion layer is preferably 40 ⁇ m or less, and 30 ⁇ m or less. It is more preferably 25 ⁇ m or less, and more preferably 25 ⁇ m or less.
  • the transmittance and haze value become uniform, and when used for a screen, images can be displayed without unevenness.
  • the one direction along the surface direction is the MD (Machine Direction) when the MD (Machine Direction) of the light diffusion layer is known, and is an arbitrary direction when the MD is not known.
  • the thickness of each resin layer other than the first resin layer is not particularly limited, but is preferably 50 ⁇ m or more and 1.3 mm or less.
  • the thickness is 50 ⁇ m or more, the adhesion of the resin film and the penetration resistance of the laminated glass when used as an intermediate film for laminated glass can be improved.
  • the thickness of each resin layer other than the first resin layer is preferably 100 ⁇ m or more, more preferably 150 ⁇ m or more, more preferably 1 mm or less, and still more preferably 650 ⁇ m or less.
  • the thickness of the resin layers other than the first resin layer is preferably larger than the thickness of the first resin layer.
  • the ratio of the thickness of the resin layers other than the first resin layer (for example, the second resin layer or the second and third resin layers) to the thickness of the first resin layer is 1.5. It is preferably 2 or more, more preferably 1.4 or more, still more preferably 1.8 or more, preferably 10 or less, more preferably 8 or less, and even more preferably 5 or less.
  • polyvinyl acetal resin Details of the polyvinyl acetal resin used for each resin layer will be described below. In the following description, the common structure of the polyvinyl acetal resin used for each resin layer is simply referred to as "polyvinyl acetal resin". For individual configurations of polyvinyl acetal resins used for the first, second, and third resin layers, respectively, "polyvinyl acetal resin (1),””polyvinyl acetal resin (2),” and “polyvinyl acetal resin ( 3)”.
  • Polyvinyl acetal resin is obtained by acetalizing polyvinyl alcohol (PVA) with aldehyde. That is, the polyvinyl acetal resin is preferably an acetalized product of polyvinyl alcohol (PVA).
  • Polyvinyl alcohol (PVA) is obtained, for example, by saponifying a polyvinyl ester such as polyvinyl acetate. The degree of saponification of polyvinyl alcohol is generally 70-99.9 mol %.
  • Polyvinyl acetal resin may be used individually by 1 type, and may use 2 or more types together.
  • the average degree of polymerization of the polyvinyl acetal resin is preferably 200 or higher, more preferably 500 or higher, still more preferably 1000 or higher, and even more preferably 1500 or higher. When the average degree of polymerization is equal to or higher than the above lower limit, the penetration resistance of the laminated glass increases. Also, the average degree of polymerization of the polyvinyl acetal resin is preferably 5,000 or less, more preferably 4,000 or less, and still more preferably 3,500 or less. When the average degree of polymerization is equal to or less than the upper limit, molding of the resin film becomes easier. Moreover, when increasing the content of the plasticizer, it is preferable to increase the average degree of polymerization of the polyvinyl acetal resin.
  • the average degree of polymerization of the polyvinyl acetal resin (1) may be lower than the average degree of polymerization of each of the polyvinyl acetal resins (for example, the polyvinyl acetal resins (2) and (3)) in the other resin layers, or may be the same. It may be as low as or higher.
  • the average degree of polymerization of the polyvinyl acetal resin (1) is preferably higher than the average degree of polymerization of the polyvinyl acetal resin for forming the other resin layers.
  • the average degree of polymerization of polyvinyl acetal resin is the same as the average degree of polymerization of PVA, which is the raw material of polyvinyl acetal resin, and the average degree of polymerization of PVA is determined by a method based on JIS K6726 "Polyvinyl alcohol test method". .
  • the aldehyde used for acetalization is not particularly limited, but an aldehyde having 1 to 10 carbon atoms is preferably used, more preferably an aldehyde having 3 to 5 carbon atoms, more preferably an aldehyde having 4 or 5 carbon atoms, Aldehydes having 4 carbon atoms are particularly preferred.
  • the aldehyde having 1 to 10 carbon atoms is not particularly limited, and examples thereof include formaldehyde, acetaldehyde, propionaldehyde, n-butyraldehyde, isobutyraldehyde, n-valeraldehyde, 2-ethylbutyraldehyde, n-hexylaldehyde, n- octylaldehyde, n-nonylaldehyde, n-decylaldehyde, benzaldehyde and the like.
  • acetaldehyde, propionaldehyde, n-butyraldehyde, isobutyraldehyde, n-hexylaldehyde and n-valeraldehyde are preferred, propionaldehyde, n-butyraldehyde, isobutyraldehyde and n-valeraldehyde are more preferred, and n-butyl More preferred are aldehydes or n-valeraldehyde, most preferred is n-butyraldehyde. Only one kind of the aldehyde may be used, or two or more kinds thereof may be used in combination.
  • the number of carbon atoms in the acetal group contained in the polyvinyl acetal resin is not particularly limited, it is preferably 1-10, more preferably 3-5, still more preferably 4 or 5, and particularly preferably 4.
  • the acetal group is particularly preferably a butyral group, and therefore, the polyvinyl acetal resin is preferably a polyvinyl butyral resin. That is, in the present invention, the thermoplastic resin (1) in the first resin layer is preferably a polyvinyl butyral resin, and the thermoplastic resins (1) and (2) in the first and second resin layers are Both are more preferably polyvinyl butyral resins.
  • thermoplastic resins (1), (2) and (3) in the first to third resin layers are preferably polyvinyl butyral resin. That is, when the resin film has a plurality of resin layers, the thermoplastic resin in all the resin layers is preferably polyvinyl butyral resin.
  • the hydroxyl content (hydroxyl group amount) of the polyvinyl acetal resin (1) is preferably 17 mol% or more, more preferably 20 mol% or more, and is, for example, 38 mol% or less, preferably 34 mol% or less. be.
  • the content of hydroxyl groups is equal to or higher than the above lower limit, the adhesive strength of the resin film is further increased.
  • the content is more preferably 30 mol % or less, and still more preferably 27 mol % or less. Further, when the content of hydroxyl groups in the polyvinyl acetal resin (1) is 20 mol % or more, the reaction efficiency is high and the productivity is excellent.
  • Each content of hydroxyl groups in the polyvinyl acetal resin (e.g., polyvinyl acetal resins (2) and (3)) used in the resin layers other than the first resin layer is, for example, 20 mol% or more, preferably 25 mol%. above, more preferably at least 28 mol %.
  • the content of the hydroxyl group is at least the lower limit, it is possible to further increase the bending rigidity while maintaining the sound insulation.
  • each hydroxyl group content of the polyvinyl acetal resin (for example, polyvinyl acetal resins (2) and (3)) used in the resin layers other than the first resin layer is preferably 38 mol% or less, more preferably It is 36 mol % or less, more preferably 34 mol % or less. If the hydroxyl content is less than or equal to the above upper limit, the polyvinyl acetal resin tends to precipitate during synthesis of the polyvinyl acetal resin.
  • the hydroxyl content of the polyvinyl acetal resin (1) is preferably lower than the hydroxyl content of the polyvinyl acetal resin used in the resin layers other than the first resin layer. . Therefore, the hydroxyl content of polyvinyl acetal resin (1) is preferably lower than the hydroxyl content of polyvinyl acetal resin (2). Moreover, the content of hydroxyl groups in the polyvinyl acetal resin (1) is preferably lower than the content of hydroxyl groups in the polyvinyl acetal resin (3).
  • the absolute value of the difference in the content is preferably It is 1 mol % or more. Thereby, sound insulation can be further improved. From this point of view, the absolute value of the difference in hydroxyl group content is more preferably 5 mol % or more. Moreover, the absolute value of the difference in each content of the hydroxyl group is preferably 20 mol % or less.
  • the content of hydroxyl groups in the polyvinyl acetal resin is the molar fraction obtained by dividing the amount of ethylene groups to which hydroxyl groups are bonded by the total amount of ethylene groups in the main chain, expressed as a percentage.
  • the amount of ethylene groups to which the hydroxyl groups are bonded can be measured according to, for example, JIS K6728 "Polyvinyl butyral test method".
  • the degree of acetalization of the polyvinyl acetal resin (1) is preferably 47 mol% or more, more preferably 55 mol% or more, still more preferably 60 mol% or more, and more preferably 85 mol% or less, more preferably is 80 mol % or less, more preferably 75 mol % or less.
  • the degree of acetalization means the degree of butyralization when the acetal group is a butyral group and the polyvinyl acetal resin (1) is a polyvinyl butyral resin.
  • Each degree of acetalization (degree of butyralization in the case of polyvinyl butyral resin) of the polyvinyl acetal resin (e.g., polyvinyl acetal resins (2) and (3)) used in resin layers other than the first resin layer is preferably is 55 mol % or more, more preferably 60 mol % or more, and still more preferably 63 mol % or more. Also, it is preferably 85 mol % or less, more preferably 80 mol % or less, and still more preferably 75 mol % or less.
  • the degree of acetalization is at least the lower limit, the compatibility between the polyvinyl acetal resin and the plasticizer is enhanced.
  • the degree of acetalization is the total amount of ethylene groups in the main chain minus the amount of ethylene groups to which hydroxyl groups are bonded and the amount of ethylene groups to which acetyl groups are bonded. It is a value showing the mole fraction obtained by dividing by the percentage.
  • the degree of acetalization (degree of butyralization) may be calculated from the results measured by a method conforming to JIS K6728 "Polyvinyl butyral test method".
  • the degree of acetylation (acetyl group content) of the polyvinyl acetal resin (1) is preferably 0.01 mol% or more, more preferably 0.1 mol% or more.
  • the degree of acetylation is more preferably 7 mol % or more, particularly preferably 9 mol % or more, from the viewpoint of increasing the compatibility between the polyvinyl acetal resin and the plasticizer and facilitating the blending of a large amount of the plasticizer. be.
  • the degree of acetylation of the polyvinyl acetal resin (1) is preferably 30 mol% or less, more preferably 25 mol% or less, still more preferably 24 mol% or less, and particularly preferably 20 mol% or less. When the degree of acetylation is equal to or less than the upper limit, the moisture resistance of the resin film increases.
  • Each degree of acetylation of the polyvinyl acetal resin (for example, polyvinyl acetal resins (2) and (3)) used in the resin layers other than the first resin layer is preferably 10 mol% or less, more preferably 2 mol%. It is below.
  • the degree of acetylation is equal to or less than the upper limit, the moisture resistance of the resin film increases.
  • the content is preferably 0.01 mol % or more, more preferably 0.1 mol % or more.
  • the degree of acetylation is a value expressed as a percentage of a mole fraction obtained by dividing the amount of ethylene groups to which acetyl groups are bonded by the total amount of ethylene groups in the main chain.
  • the amount of ethylene groups to which the acetyl groups are bonded can be measured according to, for example, JIS K6728 "Polyvinyl butyral test method".
  • the ethylene-vinyl acetate copolymer resin may be a non-crosslinked ethylene-vinyl acetate copolymer resin or a high-temperature crosslinked ethylene-vinyl acetate copolymer resin.
  • ethylene-vinyl acetate copolymer resin ethylene-vinyl acetate modified resins such as ethylene-vinyl acetate copolymer saponified products and ethylene-vinyl acetate hydrolysates can also be used.
  • the ethylene-vinyl acetate copolymer resin preferably has a vinyl acetate content of 10 to 50% by mass, more preferably 20 to 40% by mass, as measured according to JIS K 6730 "Ethylene-vinyl acetate resin test method". .
  • a vinyl acetate content 10 to 50% by mass, more preferably 20 to 40% by mass, as measured according to JIS K 6730 "Ethylene-vinyl acetate resin test method".
  • the ionomer resin is not particularly limited, and various ionomer resins can be used. Specific examples include ethylene ionomers, styrene ionomers, perfluorocarbon ionomers, telechelic ionomers, polyurethane ionomers, and the like. Among these, ethylene-based ionomers are preferable because they improve the mechanical strength, durability, transparency, etc. of the screen, and because they have excellent adhesion to the glass plate when the glass plate is made of inorganic glass.
  • an ethylene/unsaturated carboxylic acid copolymer ionomer is preferably used because of its excellent transparency and toughness.
  • the ethylene/unsaturated carboxylic acid copolymer is a copolymer having at least structural units derived from ethylene and structural units derived from unsaturated carboxylic acid, and may have structural units derived from other monomers.
  • unsaturated carboxylic acids include acrylic acid, methacrylic acid, maleic acid, etc. Acrylic acid and methacrylic acid are preferred.
  • Other monomers include acrylic acid esters, methacrylic acid esters, 1-butene, and the like.
  • the ethylene/unsaturated carboxylic acid copolymer preferably has 75 to 99 mol% of ethylene-derived structural units when the total structural units of the copolymer are 100 mol%, and unsaturated carboxylic acid-derived It preferably has 1 to 25 mol % of structural units.
  • the ionomer of the ethylene/unsaturated carboxylic acid copolymer is an ionomer resin obtained by neutralizing or crosslinking at least part of the carboxyl groups of the ethylene/unsaturated carboxylic acid copolymer with metal ions.
  • the degree of neutralization of carboxyl groups is usually 1-90%, preferably 5-85%.
  • Ion sources for ionomer resins include alkali metals such as lithium, sodium, potassium, rubidium and cesium, and polyvalent metals such as magnesium, calcium and zinc, with sodium and zinc being preferred.
  • the method for producing the ionomer resin is not particularly limited, and it can be produced by a conventionally known production method.
  • an ionomer of an ethylene/unsaturated carboxylic acid copolymer for example, ethylene and an unsaturated carboxylic acid are subjected to radical copolymerization at high temperature and high pressure to form an ethylene/unsaturated carboxylic acid. to produce a copolymer;
  • an ionomer of the ethylene/unsaturated carboxylic acid copolymer can be produced.
  • polyurethane resin examples include polyurethanes obtained by reacting an isocyanate compound with a diol compound, polyurethanes obtained by reacting an isocyanate compound with a diol compound, and a chain extender such as polyamine. Moreover, the polyurethane resin may contain a sulfur atom. In that case, part or all of the diols may be selected from polythiols and sulfur-containing polyols. Polyurethane resin can improve adhesion to organic glass. Therefore, it is preferably used when the glass plate is organic glass.
  • thermoplastic elastomer examples include styrene-based thermoplastic elastomers and aliphatic polyolefins.
  • the styrene-based thermoplastic elastomer is not particularly limited, and known ones can be used.
  • a styrenic thermoplastic elastomer generally has a styrene monomer polymer block as a hard segment and a conjugated diene compound polymer block or a hydrogenated block thereof as a soft segment.
  • styrene-based thermoplastic elastomers include styrene-isoprene diblock copolymers, styrene-butadiene diblock copolymers, styrene-isoprene-styrene triblock copolymers, styrene-butadiene/isoprene-styrene triblock copolymers. polymers, styrene-butadiene-styrene triblock copolymers, and hydrogenated forms thereof.
  • the aliphatic polyolefin may be saturated aliphatic polyolefin or unsaturated aliphatic polyolefin.
  • the aliphatic polyolefin may be a polyolefin containing a chain olefin as a monomer, or a polyolefin containing a cyclic olefin as a monomer. From the viewpoint of effectively improving the storage stability and sound insulation of the resin film, the aliphatic polyolefin is preferably saturated aliphatic polyolefin.
  • Materials for the aliphatic polyolefin include ethylene, propylene, 1-butene, trans-2-butene, cis-2-butene, 1-pentene, trans-2-pentene, cis-2-pentene, 1-hexene, trans -2-hexene, cis-2-hexene, trans-3-hexene, cis-3-hexene, 1-heptene, trans-2-heptene, cis-2-heptene, trans-3-heptene, cis-3-heptene , 1-octene, trans-2-octene, cis-2-octene, trans-3-octene, cis-3-octene, trans-4-octene, cis-4-octene, 1-nonene, trans-2-nonene , cis-2-nonene, trans-3-nonene, cis-3-nonene, trans-4-
  • plasticizer for example, plasticizers (1) to (3)
  • plasticizers used in each resin layer include organic ester plasticizers such as monobasic organic acid esters and polybasic organic acid esters, organic phosphate plasticizers, and organic phosphite plasticizers. and phosphorus-based plasticizers.
  • organic ester plasticizers are preferred.
  • the plasticizer is a liquid plasticizer.
  • the liquid plasticizer is a plasticizer that becomes liquid at normal temperature (23° C.) and normal pressure (1 atm).
  • Monobasic organic acid esters include esters of glycols with monobasic organic acids.
  • Glycols include polyalkylene glycols in which each alkylene unit has 2 to 4 carbon atoms, preferably 2 or 3 carbon atoms, and the number of repeating alkylene units is 2 to 10, preferably 2 to 4.
  • the glycol may also be a monoalkylene glycol having 2 to 4 carbon atoms, preferably 2 or 3 carbon atoms, and having 1 repeating unit.
  • Specific examples of glycols include ethylene glycol, diethylene glycol, triethylene glycol, tetraethylene glycol, propylene glycol, dipropylene glycol, tripropylene glycol, tetrapropylene glycol, and butylene glycol.
  • Examples of monobasic organic acids include organic acids having 3 to 10 carbon atoms, and specific examples include butyric acid, isobutyric acid, caproic acid, 2-ethylbutyric acid, 2-ethylpentanoic acid, heptyl acid, and n-octyl. acid, 2-ethylhexylic acid, n-nonylic acid and decylic acid.
  • Preferred monobasic organic acid esters include compounds represented by the following formula (1).
  • R1 and R2 each represent an organic group having 2 to 10 carbon atoms
  • R3 represents an ethylene group, isopropylene group or n-propylene group
  • p represents an integer of 3 to 10.
  • Each of R1 and R2 in the above formula (1) preferably has 5 to 10 carbon atoms, more preferably 6 to 10 carbon atoms.
  • the organic groups of R1 and R2 are preferably hydrocarbon groups, more preferably alkyl groups.
  • glycol esters include ethylene glycol di-2-ethyl butyrate, 1,2-propylene glycol di-2-ethyl butyrate, 1,3-propylene glycol di-2-ethyl butyrate, 1, 4-butylene glycol di-2-ethylbutyrate, 1,2-butylene glycol di-2-ethylbutyrate, diethylene glycol di-2-ethylbutyrate, diethylene glycol dicapriate, diethylene glycol di-2-ethylhexanoate, Dipropylene glycol di-2-ethylbutyrate, triethylene glycol di-2-ethylhexanoate, triethylene glycol dicaprylate, triethylene glycol di-2-ethylpentanoate, triethylene glycol di-n-heptanoate , triethylene glycol di-2-ethylbutyrate, triethylene glycol di-2-ethylpropanoate, tetraethylene glycol di-n-h
  • polybasic organic acid esters examples include ester compounds of dibasic organic acids having 4 to 12 carbon atoms such as adipic acid, sebacic acid and azelaic acid and alcohols having 4 to 10 carbon atoms. .
  • the alcohol having 4 to 10 carbon atoms may be linear, branched, or cyclic.
  • oil-modified alkyd sebacic acid may be used.
  • Mixed adipates include adipates prepared from two or more alcohols selected from alkyl alcohols having 4 to 9 carbon atoms and cyclic alcohols having 4 to 9 carbon atoms.
  • Organic phosphorus plasticizers include phosphoric acid esters such as tributoxyethyl phosphate, isodecylphenyl phosphate and triisopropyl phosphate.
  • a plasticizer may be used individually by 1 type, and may use 2 or more types together.
  • di-(2-butoxyethyl) adipate DBEA
  • triethylene glycol di-2-ethylhexanoate 3GO
  • triethylene glycol di-2-ethylbutyrate 3GH
  • triethylene glycol di-2-ethylpropanoate 3GO
  • triethylene glycol di-2-ethylhexanoate 3GO
  • triethylene glycol di-2-ethylbutyrate 3GH
  • triethylene glycol di-2-ethylbutyrate (3GH) triethylene glycol di-2-ethylbutyrate
  • Triethylene glycol di-2-ethylhexanoate is particularly preferred.
  • the resin film of the present invention preferably contains at least one additive selected from the group consisting of ultraviolet absorbers, antioxidants and light stabilizers.
  • the resin film of the present invention is improved in durability, and image display is improved even after being used for a long period of time under a light irradiation environment such as sunlight.
  • the resin film more preferably contains at least an ultraviolet absorber and an antioxidant, and more preferably contains all of the ultraviolet absorber, antioxidant and light stabilizer.
  • the above-mentioned additive may be contained in at least the light diffusion layer, but in addition to the light diffusion layer, other resin layers (for example, the second resin layer, or the second and third resin layers) It is also preferable to contain.
  • the light diffusion layer more preferably contains an ultraviolet absorber and an antioxidant among the above, and more preferably contains all of the ultraviolet absorber, the antioxidant, and the light stabilizer.
  • other resin layers for example, the second resin layer, or the second and third resin layers
  • UV absorbers include compounds having a malonate skeleton, compounds having an anilide oxalate skeleton, compounds having a benzotriazole skeleton, compounds having a benzophenone skeleton, compounds having a triazine skeleton, compounds having a benzoate skeleton, and hindered amines.
  • a compound or the like having a skeleton can be used.
  • compounds having a benzotriazole skeleton (benzotriazole compounds) are preferred.
  • the ultraviolet absorber absorbs ultraviolet rays contained in sunlight or the like, prevents deterioration of the resin film due to irradiation of sunlight or the like, and improves durability.
  • Preferred specific examples of benzotriazole compounds include compounds represented by the following general formula (2).
  • R 1 represents a hydrogen atom, an alkyl group having 1 to 8 carbon atoms, or an alkoxycarbonylalkyl group having 4 to 20 carbon atoms
  • R 2 represents a hydrogen atom or a represents an alkyl group of ⁇ 8
  • X is a halogen atom or a hydrogen atom
  • Y 1 and Y 2 are each independently a hydroxyl group or a hydrogen atom, and at least one of Y 1 and Y 2 is a hydroxyl group.
  • the alkyl groups of R 1 and R 2 may have a linear structure or a branched structure.
  • the alkoxycarbonylalkyl group may have a linear structure or a branched structure.
  • R 1 and R 2 include hydrogen atom, methyl group, ethyl group, n-propyl group, iso-propyl group, n-butyl group, tert-butyl group, pentyl group, hexyl group and octyl group.
  • R 1 includes a methoxycarbonylpropyl group, an octyloxycarbonylpropyl group, and the like.
  • R 1 is preferably a hydrogen atom or an alkyl group, particularly a hydrogen atom, a methyl group, a tert-butyl group, a pentyl group or an octyl group.
  • R 1 and R 2 may be the same or different.
  • the halogen atom of X includes a fluorine atom, a chlorine atom, a bromine atom and an iodine atom, preferably a chlorine atom.
  • Either one of Y 1 and Y 2 may be a hydroxyl group, or both of them may be a hydroxyl group.
  • Y2 is at least a hydroxyl group.
  • specific examples of the compound represented by formula (1) include 2-(3-t-butyl-5-methyl-2-hydroxyphenyl)-5-chlorobenzotriazole, 2-(3,5-di- t-Butyl-2-hydroxyphenyl)-5-chlorobenzotriazole, Octyl 3-[3-tert-butyl-5-(5-chloro-2H-benzotriazol-2-yl)-4-hydroxyphenyl]propionate , 3-(5-chloro-2H-benzotriazol-2-yl)-5-(1,1-dimethylethyl)-4-hydroxyphenylpropionate methyl, 2-(3,5-di-tert-amyl- 2-hydroxyphenyl)benzotriazole, 2-(2,4-dihydroxyphenyl)-2H-benzotriazole and the like.
  • Ultraviolet absorbers may be used singly or in combination of two or more.
  • the content of the ultraviolet absorber in each resin layer is 0.01 parts by mass or more and 2 parts by mass or less with respect to 100 parts by mass of the thermoplastic resin. is preferred.
  • the content of the ultraviolet absorber is more preferably 0.05 parts by mass or more and 1.5 parts by mass or less, and 0.1 parts by mass or more and 1.1 parts by mass or less with respect to 100 parts by mass of the thermoplastic resin. is more preferred.
  • Antioxidant include phenol compounds, phosphoric compounds, sulfur compounds, and the like.
  • the antioxidant prevents the resin film from being oxidatively deteriorated and improves the durability.
  • phenolic compounds are preferable from the viewpoint of improving durability.
  • phenolic compounds examples include 2,6-di-t-butyl-p-cresol (BHT), butylated hydroxyanisole (BHA), 2,6-di-t-butyl-4-ethylphenol, stearyl- ⁇ -(3,5-di-t-butyl-4-hydroxyphenyl)propionate, 2,2′-methylenebis-(4-methyl-6-butylphenol), 2,2′-methylenebis-(4-ethyl-6 -t-butylphenol), 4,4′-butylidene-bis-(3-methyl-6-t-butylphenol), 1,1,3-tris-(2-methyl-hydroxy-5-t-butylphenyl)butane , tetrakis[methylene-3-(3′,5′-butyl-4-hydroxyphenyl)propionate]methane, 1,3,3-tris-(2-methyl-4-hydroxy-5-t-butylphenol)butane, 1,3,5-trimethyl
  • Examples of the phosphoric acid compound include trisnonylphenyl phosphite, tridecyl phosphite, 2-ethyl-2-butylpropylene-4,6-tri-tert-butylphenol phosphite, 9,10-dihydro-9-oxa- 10-phosphaphenanthrene, tetra(tridecyl)isopropylidenediphenol diphosphite, tris[2-tert-butyl-4-(3-tert-hydroxy-5-methylphenylthio)-5-methylphenyl]phosph fight and the like.
  • Examples of the above sulfur compounds include dialkylthiodipropionates such as dilauryl thiodipropionate, dimyristyl thiodipropionate, and distearyl thiodipropionate, and pentaerythritol tetra( ⁇ -dodecylmercaptopropionate), etc. ⁇ -alkylmercaptopropionate esters of polyols and the like are included. Antioxidants may be used singly or in combination of two or more.
  • the content of the antioxidant in each resin layer is 0.01 parts by mass or more and 2 parts by mass or less with respect to 100 parts by mass of the thermoplastic resin. is preferred. By making it 0.01 mass part or more, it is possible to appropriately prevent oxidation deterioration of the resin film and improve durability. Moreover, by making it 2 mass parts or less, it becomes easy to exhibit the effect commensurate with content.
  • the content of the ultraviolet absorber is more preferably 0.04 parts by mass or more and 1.5 parts by mass or less, and 0.06 parts by mass or more and 1.1 parts by mass or less with respect to 100 parts by mass of the thermoplastic resin. is more preferred.
  • the light stabilizer is preferably a hindered amine light stabilizer.
  • the light stabilizer prevents deterioration of the resin film due to irradiation with ultraviolet rays contained in sunlight.
  • the hindered amine light stabilizer include hindered amine light stabilizers in which an alkyl group, an alkoxy group, or a hydrogen atom is bonded to the nitrogen atom of the piperidine structure. From the viewpoint of further suppressing deterioration, a hindered amine light stabilizer in which an alkyl group or an alkoxy group is bonded to the nitrogen atom of the piperidine structure is preferred.
  • the hindered amine light stabilizer is preferably a hindered amine light stabilizer in which an alkyl group is bonded to the nitrogen atom of the piperidine structure, and is a hindered amine light stabilizer in which an alkoxy group is bonded to the nitrogen atom of the piperidine structure. is also preferred. Only one kind of light stabilizer may be used, or two or more kinds thereof may be used in combination.
  • Examples of the hindered amine light stabilizer having an alkyl group bonded to the nitrogen atom of the piperidine structure include “Tinuvin 765" and “Tinuvin 622SF” manufactured by BASF, and “ADEKA STAB LA-52" manufactured by ADEKA. Further, as the hindered amine light stabilizer having an alkoxy group bonded to the nitrogen atom of the piperidine structure, BASF's “TinuvinXT-850FF" and “TinuvinXT-855FF", and ADEKA's "ADEKA STAB LA-81", etc. mentioned. Examples of the hindered amine light stabilizer in which a hydrogen atom is bonded to the nitrogen atom of the piperidine structure include “Tinuvin770DF” manufactured by BASF and "Hostavin N24" manufactured by Clariant.
  • the content of the light stabilizer in each resin layer is 0.001 parts by mass or more and 0.5 parts by mass or less with respect to 100 parts by mass of the thermoplastic resin. is preferably When the content is 0.001 parts by mass or more, deterioration of the resin film due to ultraviolet rays or the like can be appropriately prevented, and durability can be enhanced. Moreover, by making it 0.5 mass part or less, it becomes easy to exhibit the effect commensurate with content.
  • the content of the light stabilizer is preferably 0.005 parts by mass or more and 0.4 parts by mass or less relative to 100 parts by mass of the thermoplastic resin, and 0.01 parts by mass or more and 0.2 parts by mass or less. more preferred.
  • Each resin layer constituting the resin film may optionally contain, in addition to the above additives, an infrared absorbing agent, a fluorescent brightening agent, a crystal nucleating agent, a metal carboxylate, a heat shielding material, and the like. good.
  • the resin film is obtained by obtaining a resin composition for forming each layer, and molding each layer (first resin layer, second resin layer, third resin layer, etc.) constituting the resin film from the resin composition. , can be manufactured by laminating and integrating each layer as necessary. Moreover, in the case of a plurality of layers, it may be manufactured by laminating and integrating each layer while molding each layer constituting the resin film by co-extrusion or the like.
  • the resin composition for forming each layer is a thermoplastic resin by a known method, and components constituting the resin composition such as light diffusing particles, plasticizers, and other additives, which are blended as necessary, are mixed with a kneading device. It is preferable to obtain by mixing such as. For example, when forming each layer constituting the resin film using an extruder such as a co-extruder, it is preferable to mix the components constituting the resin composition in the extruder.
  • the present invention further provides a laminated glass.
  • the laminated glass of the present invention includes a pair of glass members and a resin film arranged between the pair of glass members.
  • the resin film is preferably used as an intermediate film for laminated glass, and the pair of glass members may be bonded via the resin film. Since the structure of the resin film in the laminated glass is as described above, the description thereof will be omitted.
  • Laminated glass is typically used as a screen as described below.
  • each glass member is laminated on both surfaces of the resin film 10 respectively.
  • glass members 21 and 22 are preferably laminated on both surfaces of the first resin layer 11 .
  • FIG. 2 in the resin film 16 having the first resin layer 11 and the second resin layer 12 , one glass member 21 is placed on the surface of the second resin layer 12 so that the first resin layer 11 It is preferable that the other glass member 22 is laminated on the surface.
  • FIG. 3 in the resin film 17 having the first to third resin layers 11, 12, 13, one glass member 21 is laminated on the surface of the second resin layer 12, and the third resin layer
  • the other glass member 22 is preferably laminated on the surface of 13 .
  • a glass plate may be used as the glass member used in the laminated glass.
  • the glass plate may be inorganic glass or organic glass, but inorganic glass is preferred.
  • inorganic glass include, but are not limited to, clear glass, clear float glass, float plate glass, tempered glass, colored glass, polished plate glass, figured glass, wired plate glass, lined plate glass, ultraviolet absorbing plate glass, infrared reflecting plate glass, and infrared absorbing plate glass. Plate glass, green glass, etc. are mentioned.
  • the organic glass what is generally called resin glass is used, and it is not particularly limited, but examples thereof include organic glass composed of a polycarbonate plate, a polymethylmethacrylate plate, a polyester plate, or the like.
  • the two glass members may be made of the same material, or may be made of different materials.
  • one may be inorganic glass and the other may be organic glass, but it is preferable that both of the two glass members are inorganic glass or organic glass.
  • the thickness of each glass member is not particularly limited, but is preferably 0.5 mm or more and 5 mm or less, more preferably 0.7 mm or more and 3 mm or less.
  • the manufacturing method of laminated glass is not particularly limited.
  • a resin film is sandwiched between two glass members and passed through a pressing roll, or put in a rubber bag and vacuum-sucked to remain between the two glass members and the resin film. Deaerate the air. After that, pre-bonding is performed at about 70 to 110° C. to obtain a laminate.
  • the laminate is put into an autoclave or pressed to crimp at a pressure of about 120-150° C. and 1-1.5 MPa.
  • a laminated glass can be obtained.
  • a plurality of resin layers may be laminated and integrated to form a resin film while manufacturing the laminated glass.
  • the resin film is used for screens.
  • the screen is an image display screen. Specifically, one surface of the laminated glass is irradiated with light from a light source device that constitutes a projector or the like, and the irradiated light is diffused by the resin film and displayed as an image on the screen. Good.
  • the screen is preferably the laminated glass described above, but need not be the laminated glass as long as it has the resin film described above.
  • the screen may be, for example, a so-called external screen in which a resin film is adhered to one surface of a glass member and the resin film is not adhered to another glass member. Screens other than laminated glass may also use the same glass member as the glass member described above.
  • the image display screen may be of the rear projection type or the front projection type, but is preferably of the rear projection type. By using it as a rear projection type, it becomes easier to realize a high-contrast image display.
  • the rear projection type image display screen is a screen in which one surface of the laminated glass is irradiated with light from a light source device and an image is observed from the other surface of the laminated glass. Further, in the front projection type image display screen, one surface of the laminated glass is irradiated with light from the light source device, and from one surface of the laminated glass (that is, the surface irradiated with the light from the light source device), This is the screen for image observation.
  • the screen of the present invention has an x value of 0.25 or more and 0.4 or less and a y value of 0.25 or more and 0.25 or more in the chromaticity coordinates (CIE1931) of transmitted light when irradiated with simulated sunlight from a solar simulator. It is preferable that it is 4 or less. Since the screen has the above x value and y value, when it is used as a screen for screen display, image display with high color reproducibility can be realized.
  • the preferred x and y values of the screen are the same as the x and y values described above for the laminated glass produced by adhering the two sheets of reference glass via a resin film.
  • the screen of the present invention has a preferred value of maximum intensity A/maximum intensity B and a preferred value of maximum intensity A/maximum intensity C of transmitted light when irradiated with simulated sunlight from a solar simulator, and the luminance
  • the preferred value is also the same as the value described for the laminated glass produced by adhering the two reference glasses via the resin film.
  • the x-value, y-value, luminance, and maximum intensity of the screen may be measured by irradiating simulated sunlight from one side of the screen and measuring the other side. The details of the methods for measuring chromaticity, maximum intensity, and luminance are as described in Examples.
  • the preferred values for the transmittance and haze value of the screen of the present invention are also the same as the values described for the laminated glass produced by bonding the above two sheets of reference glass via a resin film. omitted.
  • the transmittance of the screen can be obtained by measuring according to JIS R3212 (2015), and the haze value can be measured according to JIS K6714.
  • the present invention also provides an image display system using the laminated glass as an image display screen as described above.
  • An image display system includes the above-described laminated glass and a light source device that irradiates light on one surface of the laminated glass, and displays an image on the laminated glass by the light from the light source device.
  • the image display system may be of either the rear projection type or the front projection type, but the rear projection type is preferred. An embodiment of the rear projection type image display system will be described in detail below with reference to FIG.
  • An image display system 30 includes laminated glass 31 and a light source device 32 .
  • the laminated glass 31 may have any structure of the laminated glasses described above.
  • the light source device 32 irradiates light onto one surface (back surface 31B) of the laminated glass 31, and an image is displayed from the other surface (front surface 31F) of the laminated glass 31 by the irradiated light.
  • An observer OB in front of the laminated glass 31 visually recognizes the image displayed on the front surface 31 ⁇ /b>F side.
  • the image displayed from the front surface 31F may be a video image such as a moving image, or may be a still image, a message or a logo made up of characters, icons, trademarks, etc., and is not particularly limited.
  • the light source device 32 can use a light source conventionally used in a rear projection type image display system, and uses, for example, a projector capable of projecting various images such as video.
  • a projector capable of projecting various images such as video.
  • the projector it is preferable to use a video display system using a digital mirror device known as a so-called DLP (registered trademark) projector.
  • DLP registered trademark
  • the light applied to the laminated glass 31 is light corresponding to an image that is left-right reversed with respect to the display image.
  • the method of irradiating the light corresponding to the horizontally inverted image is not particularly limited, and the image signal may be horizontally inverted by adjusting the image signal, or a reversing mirror or the like may be used.
  • the light emitted from the light source device 32 may be directly applied to the laminated glass 31, or may be applied to the laminated glass 31 via an optical member such as a reflecting mirror or a reversing mirror. Further, in the image display system 30, a screen other than laminated glass may be used instead of laminated glass.
  • the resin film, laminated glass, and screen of the present invention can be used in various fields, such as various window glasses. More specifically, it can be used as window glass for vehicles such as automobiles, railroad vehicles, aircraft, and ships, or as window glass for construction.
  • the resin film, laminated glass, or screen can be used for various types of window glass to display various images such as images, messages, and logos on the window glass. Also, it may be used as a display for various electrical appliances such as household electrical appliances. Among these, it is preferably used for window glass, and more preferably used for automobile window glass.
  • window glass for automobiles as described above, it can be used for any of windshields, side glasses, and rear glasses because of its high transmittance.
  • a light source device when it is used for architectural window glass, a light source device is installed inside a building, the inner surface of the window glass is irradiated with light from the light source device, and various types of light are applied to the outer surface of the window glass. An image should be displayed.
  • the light source device when it is used as a window glass for a vehicle, it is preferable to install the light source device inside the vehicle and display various images on the outer surface of the window glass.
  • an image may be displayed on the inner surface of the window glass by irradiating the outer surface of the window glass for buildings or vehicles with light from the light source device.
  • a light source device may be installed on the hood, trunk, or the like of an automobile to irradiate the windshield, side glass, rear glass, or the like with light from the outside, and an image may be displayed on the inner surfaces of these glasses.
  • the thickness of the light diffusion layer was measured at intervals of 5 cm along the MD using an Olympus microscope "DSX500", and the maximum and minimum values were taken as the maximum and minimum thicknesses of the light diffusion layer, respectively.
  • Average particle size of light diffusion particles The average particle size of the light diffusing particles was measured by a laser diffraction/scattering method using “LA-960” manufactured by Horiba, Ltd.
  • the output end 50 of a solar simulator (“HAL-320W” manufactured by Asahi Spectrosco Co., Ltd.) is positioned perpendicular to one surface 51A of the laminated glass 51 by 30 cm (distance L1 ), and the laminated glass was irradiated with simulated sunlight.
  • a luminance meter 52 ("SR-3AR" manufactured by Topcon Technohouse Co., Ltd.) placed at a position where the distance L2 from the measurement position on the other surface 51B of the laminated glass 51 is 35 cm, and the luminance on the other surface 51B of the laminated glass 51 Chromaticity (x value, y value) and luminance were measured. Furthermore, the luminance meter 52 measured the intensity at each wavelength. Maximum intensities A, B, and C were defined as the maximum intensities in each range for the measurement results.
  • the measurement position is a position that coincides with the center of the luminous flux of the irradiated pseudo-sunlight, and as shown in FIG. It was measured by the luminance meter 52 from the position of 45°.
  • the output of the solar simulator was the maximum output of the solar simulator when chromaticity and maximum intensity A, B, and C were measured, and 30% of the maximum output when measuring luminance.
  • the laminated glass obtained by a method according to JIS R3205 2005 is irradiated with ultraviolet rays (quartz glass mercury lamp, 750 W) at 2000 from one surface. time irradiated.
  • the laminated glass was irradiated with simulated sunlight using a solar simulator, and L*a*b* was measured at that time to obtain ⁇ E.
  • ⁇ E is the distance between two points in the L*a*b* color space measured before and after ultraviolet irradiation.
  • the L*a*b* values were measured using a solar simulator and a luminance meter in the same manner as the x-value and y-value measurements.
  • PVB1 polyvinyl butyral resin, average degree of polymerization 1700, amount of hydroxyl groups 30.5 mol%, degree of acetylation 1 mol%, degree of acetalization 68.5 mol%
  • PVB2 polyvinyl butyral resin, average degree of polymerization 3000, amount of hydroxyl groups 24 mol%, degree of acetylation 12 mol%, degree of acetalization 64 mol%
  • Plasticizer 3GO: triethylene glycol-di-2-ethylhexanoate, (light diffusion particles)
  • Silver nanoparticles average particle size 200 nm, particle size distribution 45 to 350 nm, particles having a core-shell structure with silver particles as the core and a composite of silica, alumina and polyvinylpyrrolidone as the shell, manufactured by Lux Labs, Inc.
  • Nanodiamond “DINNOVARE” manufactured by Daicel Titanium oxide particles: particles having a core-shell structure with titanium oxide particles as the core (“Titanium oxide nanospheres” manufactured by Lux Labs, Inc.) (Ultraviolet absorber) Tinuvin 326: A compound represented by the formula (2), wherein X is a chlorine atom, R 1 is a methyl group, R 2 is a tert-butyl group, Y 1 is a hydrogen atom, and Y 2 is a hydroxyl group.
  • Tinuvin 326 manufactured by BASF (antioxidant)
  • BHT 2,6-di-t-butyl-p-cresol
  • Irganox 1010 pentaerythritol tetrakis [3-(3,5-di-tert-butyl-4-hydroxyphenyl) propionate], product name "Irganox 1010”
  • Tinuvin765 Hindered amine light stabilizer, product name "Tinuvin765", manufactured by BASF
  • Example 1 (Production of resin film)
  • 100 parts by mass of PVB1 as a polyvinyl acetal resin, 40 parts by mass of 3GO as a plasticizer, and silver nanoparticles as light diffusion particles are kneaded to obtain a resin for the first resin layer.
  • a composition was obtained.
  • the silver nanoparticles were added so that the content with respect to the total amount of the resin film was 0.0015% by mass.
  • 100 parts by mass of PVB1 as a polyvinyl acetal resin and 40 parts by mass of 3GO as a plasticizer were kneaded to obtain resin compositions for the second and third resin layers.
  • the obtained resin compositions for the first to third layers are co-extruded to form a second resin layer with a thickness of 325 ⁇ m, a first resin layer with a thickness of 110 ⁇ m, and a third resin layer with a thickness of 325 ⁇ m.
  • a resin film (intermediate film) having a three-layer structure consisting of three resin layers was obtained. The size of the resin film was 30 cm x 30 cm.
  • Example 2 Comparative Examples 1 and 2
  • Example 1 except that the type of polyvinyl acetal resin used in each resin composition, the amount of plasticizer, the type and amount of light diffusion particles, and the thickness of each resin layer were changed as shown in Table 1. conducted in the same way.
  • Examples 3 and 4 Except that the UV absorber, antioxidant, and light stabilizer shown in Table 1, or the UV absorber, and antioxidant shown in Table 1 were added to each resin composition in the amounts shown in Table 1, It was carried out in the same manner as in Example 2.
  • Example 5 (Production of resin film)
  • 100 parts by mass of PVB1 as a polyvinyl acetal resin, 40 parts by mass of 3GO as a plasticizer, titanium oxide particles as light diffusion particles, 0.2 parts by mass of an ultraviolet inhibitor, and an antioxidant 0.2 parts by mass were kneaded to obtain a resin composition for the first resin layer.
  • the titanium oxide particles were added so that the content with respect to the total amount of the first resin layer was 0.0015% by mass.
  • a resin film having a single-layer structure consisting only of the first resin layer having a thickness of 760 ⁇ m was obtained.
  • the size of the resin film was 30 cm x 30 cm.
  • Example 6 The same procedure as in Example 4 was carried out, except that titanium oxide particles were used as light diffusing particles instead of silver nanoparticles.
  • Example 7-9 The same procedure as in Example 5 was carried out, except that the content of the titanium oxide particles relative to the total amount of the first resin layer was changed as shown in Table 2.
  • Example 6 was carried out in the same manner as in Example 6, except that the content of the titanium oxide particles relative to the total amount of the first resin layer was changed as shown in Table 2.
  • Parts/phr in Tables 1 and 2 is the content (parts by mass) per 100 parts by mass of the polyvinyl acetal resin in each resin layer.
  • Parts/wt% in Tables 1 and 2 is the content (% by mass) of the light diffusion particles in the light diffusion layer.
  • specific light diffusing particles are used to adjust the x-value and y-value of transmitted light when irradiated with simulated sunlight to fall within a predetermined range. Good color reproducibility was achieved when used for display screens. Further, in Examples 3 to 10, by blending an ultraviolet absorber and an antioxidant, or an ultraviolet absorber, an antioxidant, and a light stabilizer in the resin film, ⁇ E was reduced, and good image display could be realized over a long period of time. On the other hand, although the resin films of each comparative example contain light diffusing particles, they are not adjusted so that the x value and y value of transmitted light when irradiated with simulated sunlight fall within a predetermined range. Color reproducibility could not be improved when used for a screen for screen display.

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US18/565,266 US20240208185A1 (en) 2021-06-01 2022-05-31 Resin film, laminated glass, and screen
KR1020237040840A KR20240017349A (ko) 2021-06-01 2022-05-31 수지 필름, 접합 유리, 및 스크린
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