WO2022208643A1 - クリーニング用ラベル、及びクリーニング用タグの製造方法 - Google Patents

クリーニング用ラベル、及びクリーニング用タグの製造方法 Download PDF

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Publication number
WO2022208643A1
WO2022208643A1 PCT/JP2021/013466 JP2021013466W WO2022208643A1 WO 2022208643 A1 WO2022208643 A1 WO 2022208643A1 JP 2021013466 W JP2021013466 W JP 2021013466W WO 2022208643 A1 WO2022208643 A1 WO 2022208643A1
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Prior art keywords
adhesive layer
cleaning
base material
label
sensitive
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PCT/JP2021/013466
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English (en)
French (fr)
Japanese (ja)
Inventor
翔平 朝稲
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Lintec Corp
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Lintec Corp
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Priority to PCT/JP2021/013466 priority Critical patent/WO2022208643A1/ja
Priority to JP2021541094A priority patent/JP7642547B2/ja
Publication of WO2022208643A1 publication Critical patent/WO2022208643A1/ja
Anticipated expiration legal-status Critical
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    • G—PHYSICS
    • G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
    • G09F3/00—Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
    • G09F3/08—Fastening or securing by means not forming part of the material of the label itself
    • G09F3/10—Fastening or securing by means not forming part of the material of the label itself by an adhesive layer

Definitions

  • the present invention relates to a cleaning label and a method for manufacturing a cleaning tag using the cleaning label.
  • tags are used to display information on clothing and the like.
  • cleaning tags are attached to collected clothing for the purpose of identifying and sorting the collected clothing.
  • clothing, etc. is attached with quality labeling tags that include information such as washing labels, washing symbols, sizes, handling precautions including washing or dry cleaning methods, material types, and fiber composition.
  • the above cleaning tags are attached using metal pins or staples.
  • the above-mentioned quality labeling tag is normally sewn directly onto clothing or the like.
  • Patent Document 1 discloses that the hot-melt adhesive layer is present over the entire area with respect to the area of the label. , a label in which the pressure-sensitive adhesive layer is partially present on the surface of the hot-melt adhesive layer at a position other than the end portion of the label.
  • Patent Document 2 a printed layer, a thermal adhesive layer made of a hot melt adhesive provided on the back surface of the printed layer, and a temporary adhesive layer made of a detachable adhesive provided on the back surface of the thermal adhesive layer.
  • the tag for attaching to cloth wherein the temporary adhesive layer is temporarily attached to the release sheet, the tag for attaching to cloth is disclosed in which the temporary adhesive layer is provided on a part of the back surface of the thermal adhesive layer. ing.
  • an adhesive layer (adhesive layer of Patent Document 1, temporary adhesive layer of Patent Document 2) that can be pressure-sensitively adhered to an adherend such as clothing to temporarily attach the cleaning tag.
  • the heat-sensitive adhesive layer (the hot-melt adhesive layer of Patent Document 1, the heat-sensitive adhesive layer of Patent Document 2) tends to hinder the heat-sensitive adhesion. Therefore, in Patent Documents 1 and 2, a pressure-sensitive adhesive layer is provided partially on the heat-sensitive adhesive layer in order to strengthen the heat-sensitive adhesive force and improve the dry-cleaning resistance.
  • the present invention has been made to solve the above problems, and has a sticking aptitude that can be temporarily fixed by pressure-sensitive bonding to an adherend, and is attached to the adherend after being temporarily fixed.
  • Another object of the present invention is to provide a method for producing a cleaning tag having excellent resistance to dry cleaning, using the cleaning label.
  • the present inventors have found that an adhesive layer having pressure-sensitive adhesiveness and heat-sensitive adhesiveness can be employed, and that the adhesive layer can be used as a solvent for dry cleaning.
  • the inventors have found that good dry-cleaning resistance is exhibited by setting the gel fraction to chloroethylene to a specific value or more, and have completed the present invention. That is, the present invention has the following aspects.
  • a first substrate an adhesive layer laminated on the first surface side of the first substrate and having pressure-sensitive adhesiveness and heat-sensitive adhesiveness; with The adhesive layer contains an acrylic acid ester polymer,
  • the adhesive layer has a gel fraction of 60% or more with respect to perchlorethylene, A cleaning label that is dry-cleaned together with the adherend after being attached to the adherend.
  • T between the adhesive layer and the cotton cloth measured at a peel speed of 300 mm / min according to JIS K 6854-3 (ISO 11339) after pressure-sensitive adhesion to the cotton cloth and before heat-sensitive adhesion.
  • the mold peeling adhesive strength (A) is 0.5 to 10 N / 25 mm
  • the adhesive layer after pressure-sensitive adhesion to the cotton cloth and after heat-sensitive adhesion was measured at a peeling speed of 300 mm / min according to JIS K 6854-3 (ISO 11339) T-type peeling between the cotton cloth
  • the adhesive layer after pressure-sensitive adhesion and heat-sensitive adhesion to cotton cloth is peeled according to JIS K 6854-3 (ISO 11339) after a dry cleaning test at 30 ° C. according to JIS L 0860 A1 method.
  • the acrylic ester polymer has a weight average molecular weight (Mw) of 400,000 to 2,000,000;
  • a second adhesive layer opposite to the first surface side on which the first base material is laminated obtaining a laminate comprising the first base material, the adhesive layer, and the second base material in this order by pressure-sensitively bonding a second base material to the face side; heat-treating the laminate to thermally bond the first base material and the second base material via the adhesive layer;
  • a method of manufacturing a cleaning tag comprising: (10) The method for producing a cleaning tag according to (9) above, wherein the second base material has a wireless tag. (11) The method for producing a cleaning tag according to (9) or (10), wherein the second base material is a film, cloth, or nonwoven fabric.
  • the first base material or the second base material is printed,
  • the information to be printed is selected from the group consisting of owner information of an object to be dry-cleaned with a cleaning tag attached, cleaning shop information, an object control code, and an object control number.
  • any one or more selected dry cleaning information or Any one or more selected from the group consisting of washing indications, washing symbols, sizes, handling precautions including washing or dry cleaning methods, material types, fiber compositions, and names of those who display them
  • a cleaning label that has adhesive aptitude for pressure-sensitive adhesion to an adherend and is temporarily fixed, can be heat-sensitively adhered to the adherend after being temporarily fixed, and has excellent dry-cleaning resistance. can provide. Moreover, according to the present invention, it is possible to provide a method for manufacturing a cleaning tag excellent in resistance to dry cleaning, using the cleaning label.
  • FIG. 1 is a cross-sectional view of a cleaning label according to one embodiment of the present invention
  • FIG. 1A to 1C are schematic diagrams for explaining the manufacturing method and structure of a cleaning tag according to an embodiment of the present invention
  • 1A to 1C are schematic diagrams for explaining the manufacturing method and structure of a cleaning tag according to an embodiment of the present invention
  • 1 is a schematic diagram illustrating the configuration of a cleaning tag according to one embodiment of the present invention
  • FIG. 1 is a schematic diagram illustrating the configuration of a cleaning tag according to one embodiment of the present invention
  • FIG. 1A to 1C are schematic diagrams for explaining the manufacturing method and structure of a cleaning tag according to an embodiment of the present invention
  • 1 is a schematic diagram illustrating the configuration of a cleaning tag according to one embodiment of the present invention
  • FIG. 1A to 1C are schematic diagrams for explaining the manufacturing method and structure of a cleaning tag according to an embodiment of the present invention
  • 1 is a schematic diagram illustrating the configuration of a cleaning tag according to one embodiment of the
  • a cleaning label according to an embodiment comprises a first substrate, and an adhesive layer having pressure-sensitive adhesiveness and heat-sensitive adhesiveness, which is laminated on the first surface side of the first substrate, and the adhesive The layer contains an acrylic acid ester polymer, the adhesive layer has a gel fraction of 60% or more with respect to perchlorethylene, and is dry-cleaned together with the adherend after being applied to the adherend. is.
  • the cleaning label according to one embodiment of the present invention is also simply referred to as "label”.
  • pressure-sensitive adhesiveness refers to the property of being able to adhere to an adherend by applying pressure to the adhesive layer. Pressure-sensitive adhesion and adhesion are used in the same sense. "Heat-sensitive adhesiveness” refers to the property of being able to adhere to an adherend by heating the adhesive layer to melt it and harden it again.
  • FIG. 1 is a cross-sectional view of the cleaning label 1 of the embodiment.
  • the label 1 according to the present embodiment includes a first substrate 10 and an adhesive having pressure-sensitive adhesiveness and heat-sensitive adhesiveness, which is laminated on the first surface side of the first substrate 10. a layer 20; Note that the release liner 40 is peeled off when the label is used, and is not an essential component of the label of the present invention.
  • first base material 10 of the label 1 examples include film, cloth, nonwoven fabric, and the like. Cloth or nonwoven fabric is preferable, and it is said that the label 1 has good integrity when attached to clothing or the like, which is suitable as an adherend. Cloth is preferable from the point of view.
  • Cloths and non-woven fabrics include those containing cellulose fibers such as hemp, wool, cotton, pulp, and rayon, and fibers such as nylon, polyester, polyurethane, and vinylon.
  • the type of weave of the cloth is not particularly limited, and examples include satin such as polyester satin, and taffeta such as polyester taffeta and cotton taffeta.
  • films include resin films, and synthetic resin films are preferred.
  • resin films include polyester films such as polyethylene terephthalate, polybutylene terephthalate, and polyethylene naphthalate; polyolefin films such as polyethylene and polypropylene; polyamide films such as nylon; polyurethane films; .
  • the first base material may be a film having microvoids.
  • the film having microvoids is preferably at least one selected from the group consisting of a foamed resin film, a synthetic paper having microvoids, and a resin film having microvoids.
  • a foamed resin film is a porous resin film, and examples thereof include those obtained by extruding and foaming a resin, and those obtained by molding a resin composition in which gas is dispersed.
  • foamed resin films include foamed polyester films, foamed polyethylene terephthalate films, foamed polypropylene films, foamed polyethylene films, and foamed polystyrene films.
  • a resin film with micropores is a porous resin film that is manufactured using synthetic resin as the main raw material.
  • the resin in the resin film having microvoids the same resins as those for the foamed resin film can be exemplified.
  • Synthetic paper with micropores is a film that is porous and has properties similar to paper manufactured using synthetic resin as the main raw material.
  • Synthetic resins that are the main raw material of synthetic paper include polypropylene, polyester, polystyrene, and the like, and polyethylene terephthalate can be exemplified as polyester.
  • the main raw material refers to a raw material that accounts for 50% by mass or more of the total raw material of the synthetic paper.
  • Micropores of synthetic paper include, for example, micropores generated in the stretching process. For example, when a filler-containing synthetic resin is stretched, fine cavities are formed around the filler, giving it a white paper-like texture.
  • synthetic paper having microvoids include Yupo (registered trademark) (containing polypropylene, Yupo Corporation), Crisper (registered trademark) (containing polyester, Toyobo Co., Ltd.), and N-coat (registered trademark) (containing polypropylene). , Nakamoto Pax Co., Ltd.), etc., and those having properties equivalent to these are included in the synthetic paper having microvoids.
  • the first substrate may be transparent or opaque, but is preferably opaque because it facilitates identification of information printed on the label.
  • a film having microvoids is also suitable as a substrate for labels because it is opaque.
  • the first base material 10 may consist of a single layer or may consist of multiple layers. In the case of multiple layers, each layer may be the same or different.
  • the thickness of the first base material 10 can be appropriately set, and is preferably 15 to 300 ⁇ m, more preferably 30 to 200 ⁇ m, and even more preferably 40 to 100 ⁇ m. When the thickness of the first base material is within the above range, good dry cleaning resistance can be obtained.
  • the "thickness" can be obtained by using a constant pressure thickness measuring instrument in accordance with JIS K7130 as a value represented by the average of thicknesses measured at five randomly selected locations.
  • the thickness of the first base means the thickness of the entire first base.
  • the thickness of all It means the total thickness of the layers.
  • the first base material does not break in a dry cleaning test at 30°C according to JIS L 0860 A1 method.
  • the conditions described in Examples can be adopted as the conditions for the dry cleaning test at 30°C according to JIS L 0860 A1 method.
  • a test piece obtained by appropriately cutting the single-layer first substrate into a size corresponding to the label can be used as a sample to be subjected to the dry cleaning test.
  • the adhesive layer 20 in the label 1 according to the embodiment has pressure-sensitive adhesiveness and heat-sensitive adhesiveness. It is a layer that allows a label to be attached to the Since the label has pressure-sensitive adhesiveness, it is provided with sticking aptitude for temporarily fixing the label to an adherend prior to subsequent heat-sensitive adhesion using a press or the like. By enabling the temporary fixing, it becomes easy to adhere the label to the object to which the label is to be thermally adhered accurately at the intended position.
  • An adhesive layer having both pressure-sensitive adhesiveness and heat-sensitive adhesiveness exhibits, for example, a higher heat-sensitive adhesiveness when heated than the pressure-sensitive adhesiveness exhibited at room temperature (23° C.). be done.
  • the heating temperature of the adhesive layer can be appropriately determined according to the composition of the adhesive layer, and heat-sensitive adhesiveness can be exhibited by heating at a temperature equal to or higher than the melting point of the adhesive layer.
  • the adhesive layer is heated to a temperature equal to or higher than its melting point, and after at least a portion of the adhesive layer is melted or softened, the label is thermally adhered to the adherend by cooling.
  • Adoption of heat-sensitive adhesion for example, provides strong adhesion to clothing or a second base material, which will be described later, and makes it possible to manufacture a tag having excellent dry-cleaning resistance.
  • the melting point of the adhesive layer is preferably 130° C. or lower, more preferably 50° C. or higher and 120° C. or lower, and even more preferably 70° C. or higher and 110° C. or lower.
  • the melting point of the adhesive layer is equal to or less than the above upper limit, the heat-sensitive adhesive strength is appropriately exhibited at a practical heating temperature, and the dry-cleaning resistance is improved.
  • the pressure-sensitive adhesive layer and the heat-sensitive adhesive layer are laminated as separate layers.
  • conventional heat sensitive adhesive layers have not been pressure sensitive adhesive.
  • the adhesive layer 20 having both properties of pressure-sensitive adhesiveness and heat-sensitive adhesiveness can be directly attached to the adherend, so both properties can be efficiently applied to the adherend. can work.
  • pressure-sensitive adhesiveness and heat-sensitive adhesiveness can be imparted by a single layer, which is advantageous in terms of label production efficiency.
  • the adhesive layer has a gel fraction of 60% or more, preferably 70% or more, more preferably 80% or more, and even more preferably 90% or more with respect to perchlorethylene.
  • the upper limit of the gel fraction may be 100% or less, 99% or less, 98% or less, or 95% or less. Examples of the numerical range of the gel fraction include 60% to 100%, 70% to 99%, 80% to 98%, and 90% to 95%. may be:
  • Perchlorethylene is used as a solvent for dry cleaning.
  • the gel fraction of the adhesive layer with respect to perchlorethylene is within the above range, a label having excellent dry cleaning resistance can be obtained.
  • dry-cleaning resistance means that the label after pressure-sensitive adhesion to the adherend and heat-sensitive adhesion is subjected to dry-cleaning (for example, a dry-cleaning test using perchlorethylene described later). It means the property that peeling from the adherend due to does not occur or hardly occurs.
  • the gel fraction of the adhesive layer reflects the network structure of the polymer component, for example, due to cross-linking of the polymer component contained in the adhesive layer.
  • the solubility in perchlorethylene can be significantly reduced, and the dry cleaning resistance can be improved.
  • An adhesive layer according to an embodiment contains a polymer component, and the polymer component includes an acrylic acid ester polymer. That is, the adhesive layer contains an acrylate polymer.
  • the content ratio of the polymer component to the total weight of the adhesive layer may be 50 to 100% by weight, 60 to 100% by weight, or 70 to 100% by weight.
  • the acrylic acid ester polymer according to the embodiment will be described below.
  • the adhesive layer can be formed using an adhesive composition containing components constituting the adhesive layer.
  • the adhesive composition contains an acrylate polymer.
  • acrylic acid ester polymers include acrylic polymers having at least structural units derived from (meth)acrylic acid esters, for example, at least alkyl (meth)acrylates Examples thereof include acrylic polymers having structural units derived from esters.
  • the structural units of the acrylic polymer may be of one type or two or more types, and when there are two or more types, the combination and ratio thereof can be arbitrarily selected.
  • (meth)acrylic acid is a concept that includes both “acrylic acid” and “methacrylic acid”. The same is true for (meth)acrylic acid and similar terms.
  • Examples of the (meth)acrylic acid alkyl ester include those in which the alkyl group constituting the alkyl ester has 1 to 20 carbon atoms, and the alkyl group is linear or branched. is preferred.
  • (Meth)acrylic acid alkyl esters more specifically, methyl (meth)acrylate, ethyl (meth)acrylate, n-propyl (meth)acrylate, isopropyl (meth)acrylate, (meth)acrylic acid n-butyl, isobutyl (meth)acrylate, sec-butyl (meth)acrylate, tert-butyl (meth)acrylate, pentyl (meth)acrylate, hexyl (meth)acrylate, heptyl (meth)acrylate, 2-ethylhexyl (meth) acrylate, isooctyl (meth) acrylate, n-octyl (meth) acrylate
  • the acrylic polymer preferably has a structural unit derived from a (meth)acrylic acid alkyl ester having 4 or more carbon atoms in the alkyl group.
  • the number of carbon atoms in the alkyl group is preferably 4 to 12, more preferably 4 to 8, from the viewpoint of further improving the adhesive strength of the adhesive layer.
  • the (meth)acrylic acid alkyl ester in which the alkyl group has 4 or more carbon atoms is preferably an acrylic acid alkyl ester.
  • the acrylic polymer further has a structural unit derived from a functional group-containing monomer in addition to the structural unit derived from the (meth)acrylic acid alkyl ester.
  • the functional group-containing monomer for example, the functional group reacts with a cross-linking agent to be described later, thereby forming a starting point for cross-linking.
  • Examples of the functional group in the functional group-containing monomer include hydroxyl group, carboxyl group, amino group, epoxy group and the like. That is, examples of functional group-containing monomers include hydroxyl group-containing monomers, carboxy group-containing monomers, amino group-containing monomers, and epoxy group-containing monomers.
  • hydroxyl group-containing monomer examples include hydroxymethyl (meth)acrylate, 2-hydroxyethyl (meth)acrylate, 2-hydroxypropyl (meth)acrylate, 3-hydroxypropyl (meth)acrylate, (meth) Hydroxyalkyl (meth)acrylates such as 2-hydroxybutyl acrylate, 3-hydroxybutyl (meth)acrylate, and 4-hydroxybutyl (meth)acrylate; Saturated alcohol (unsaturated alcohol having no (meth)acryloyl skeleton) and the like can be mentioned.
  • Examples of the carboxy group-containing monomer include ethylenically unsaturated monocarboxylic acids (monocarboxylic acids having an ethylenically unsaturated bond) such as (meth)acrylic acid and crotonic acid; fumaric acid, itaconic acid, maleic acid, citracone; ethylenically unsaturated dicarboxylic acids (dicarboxylic acids having an ethylenically unsaturated bond) such as acids; anhydrides of the ethylenically unsaturated dicarboxylic acids; (meth)acrylic acid carboxyalkyl esters such as 2-carboxyethyl methacrylate; be done.
  • monocarboxylic acids having an ethylenically unsaturated bond such as (meth)acrylic acid and crotonic acid
  • fumaric acid, itaconic acid maleic acid, citracone
  • ethylenically unsaturated dicarboxylic acids such as
  • the functional group-containing monomer is preferably a carboxy group-containing monomer.
  • the functional group-containing monomers constituting the acrylic polymer may be of one type or two or more types, and when two or more types are used, the combination and ratio thereof can be arbitrarily selected.
  • the content of structural units derived from functional group-containing monomers is preferably 1 to 35% by mass, more preferably 2 to 32% by mass, based on the total amount of structural units, 3 to 30% by mass is particularly preferred.
  • the acrylic polymer may further have structural units derived from other monomers in addition to structural units derived from (meth)acrylic acid alkyl esters and structural units derived from functional group-containing monomers.
  • the other monomer is not particularly limited as long as it is copolymerizable with (meth)acrylic acid alkyl ester or the like. Examples of the other monomers include styrene, ⁇ -methylstyrene, vinyltoluene, vinyl formate, vinyl acetate, acrylonitrile and acrylamide.
  • the other monomers constituting the acrylic polymer may be of one type or two or more types, and when there are two or more types, the combination and ratio thereof can be arbitrarily selected.
  • the value of the weight average molecular weight (Mw) of the acrylic polymer is preferably 400,000 to 2,000,000, more preferably 400,000 to 1,500,000, and 400,000 to More preferably 1,000,000.
  • Mw of the acrylic acid ester polymer is within the above range, the gel fraction of the acrylic polymer can be easily improved, and the dry cleaning resistance can be easily improved.
  • the value of the molecular weight distribution [weight average molecular weight (Mw)/number average molecular weight (Mn)] of the acrylic polymer is preferably 2 to 6, more preferably 2 to 5, and 2 to 4. is more preferred.
  • Mw/Mn molecular weight distribution
  • polystyrene conversion values measured by gel permeation chromatography can be adopted.
  • the measurement conditions the conditions described in Examples can be adopted.
  • the glass transition temperature (Tg) of the acrylic polymer is preferably ⁇ 40° C. or less, more preferably ⁇ 60° C. or more and ⁇ 40° C. or less, and further preferably ⁇ 60° C. or more and ⁇ 55° C. or less. preferable.
  • Tg of the acrylic polymer is equal to or less than the upper limit, the adhesive strength to the adherend is improved.
  • the glass transition temperature (Tg) of the acrylic polymer can be lowered to increase the pressure sensitive adhesion of the adhesive layer.
  • the values described in Kobunshi Data Handbook, Adhesive Handbook, or Polymer Handbook can be used.
  • the Tg of the homopolymer of n-butyl acrylate is ⁇ 55° C.
  • the Tg of the homopolymer of 2-hydroxyethyl acrylate is ⁇ 15° C.
  • the Tg of the homopolymer of 2-ethylhexyl acrylate is ⁇ 70° C.
  • the Tg of the homopolymer of 2-ethylhexyl acrylate is ⁇ 70° C.
  • the Tg of the homopolymer of 2-ethylhexyl is -10°C.
  • the content of structural units derived from n-butyl acrylate and/or 2-ethylhexyl acrylate is preferably 50% by mass or more, preferably 50 to 95% by mass, based on 100% by mass of the acrylic polymer. is more preferable, and 55 to 65% by mass is even more preferable.
  • the content of structural units derived from n-butyl acrylate and 2-ethylhexyl acrylate in the polymer component (A) is at least the above lower limit, the pressure-sensitive adhesiveness of the adhesive layer can be effectively enhanced.
  • the content ratio of the acrylic polymer to the total mass of the adhesive layer may be 50 to 100% by mass, 60 to 100% by mass, or 70 to 100% by mass.
  • the adhesive composition preferably contains a cross-linking agent in addition to the acrylic polymer.
  • the cross-linking agent can cross-link the polymer component contained in the adhesive layer.
  • the acrylic polymer contained in the adhesive layer is preferably crosslinked via a crosslinking agent.
  • cross-linking agents examples include tolylene diisocyanate, hexamethylene diisocyanate, xylylene diisocyanate, isocyanate-based cross-linking agents (cross-linking agents having isocyanate groups) such as adducts of these diisocyanates; epoxy-based cross-linking agents such as ethylene glycol glycidyl ether ( aziridinyl cross-linking agents such as hexa[1-(2-methyl)-aziridinyl]triphosphatriazine (cross-linking agents having an aziridinyl group); metal chelate cross-linking agents such as aluminum chelate (metal cross-linking agents having a chelate structure); isocyanurate-based cross-linking agents (cross-linking agents having an isocyanuric acid skeleton); Aldehyde compounds, metal alkoxides, metal salts and the like can also be used.
  • epoxy-based cross-linking agents such as ethylene glyco
  • aluminum chelate compounds include diisopropoxyaluminum monooleyl acetoacetate, monoisopropoxyaluminum bisoleyl acetoacetate, monoisopropoxyaluminum monooleate monoethylacetoacetate, diisopropoxyaluminum monolaurylacetoacetate, diisopropoxy Aluminum monostearylacetoacetate, diisopropoxyaluminum monoisostearylacetoacetate, monoisopropoxyaluminum mono-N-lauroyl- ⁇ -alanate monolaurylacetoacetate, aluminum trisacetylacetonate, monoacetylacetonate aluminum bis(isobutylacetate) acetate) chelate, monoacetylacetonate aluminum bis(2-ethylhexylacetoacetate) chelate, monoacetylacetonate aluminum bis(dodecylacetoacetate) chelate, monoacetylacetonate aluminum bis(oleylace
  • the cross-linking agent contained in the adhesive composition may be of one type or two or more types, and when two or more types are used, the combination and ratio thereof can be arbitrarily selected.
  • the content of the cross-linking agent in the adhesive composition is preferably 0.1 parts by mass or more and 10 parts by mass or less, and 0.5 parts by mass or more and 5 parts by mass with respect to 100 parts by mass of the polymer component content. It is more preferably 0.8 parts by mass or more and 3 parts by mass or less.
  • cross-linking agent cross-links the acrylic polymer contained in the adhesive layer, for example, to strengthen the adhesive layer and improve the dry cleaning resistance.
  • the cross-linking agent according to this embodiment may not form a cross-linked structure with the tackifying resin described later.
  • the adhesive composition may further contain a tackifying resin in addition to the acrylic polymer.
  • tackifying resin is used to improve the pressure-sensitive adhesive performance of the adhesive layer when added to the adhesive layer. Tackifying resins are also called tackifiers.
  • the tackifying resin may be a polymer.
  • the weight average molecular weight of the tackifying resin may be, for example, 5000 or less, 100-5000, 200-3000, or 300-1000.
  • a polystyrene conversion value measured by a gel permeation chromatography (GPC) method can be adopted as the weight average molecular weight.
  • the content of the tackifying resin is preferably 4 parts by mass or less, more preferably 3 parts by mass or less, relative to 100 parts by mass of the polymer component (A). , more preferably 1 part by mass or less, and it is particularly preferable that the adhesive layer contains substantially no tackifier resin.
  • the adhesive layer according to the embodiment may have a tackifying resin content ratio of 4% by mass or less, or 3% by mass or less, relative to the total mass of the adhesive layer. , 1% by mass or less, and it is particularly preferred that the adhesive layer contains substantially no tackifying resin.
  • the dry cleaning resistance of the label can be improved by setting the content of the tackifier resin to the above upper limit or less.
  • the tackifying resin is not particularly limited, and petroleum resin-based tackifying resins: rosin-based tackifying resins such as rosin and rosin derivatives; terpenes such as terpene resins, hydrogenated terpene resins, terpene phenol resins, and aromatic modified terpene resins system tackifying resin; In addition, liquid resins, resin emulsions, alkylphenol resins, phenolic resins, vinyl acetate-based resins, styrene-based resins, and the like, which can be used as tackifying resins, can be mentioned.
  • petroleum resin-based tackifying resins such as rosin and rosin derivatives
  • terpenes such as terpene resins, hydrogenated terpene resins, terpene phenol resins, and aromatic modified terpene resins system tackifying resin
  • the tackifier resin may be at least one kind of tackifier resin selected from the group consisting of petroleum resin-based tackifier resins, styrene-based tackifier resins, terpene-based tackifier resins, and rosin-based tackifier resins.
  • Petroleum resins are resins derived from petroleum components, fractions such as C5 fractions and C9 fractions obtained by decomposing naphtha, polymers thereof (e.g., C5 - C9 petroleum resins etc.) can be exemplified.
  • Petroleum resin-based tackifying resins can have structural units derived from, for example, indene, styrene, vinyltoluene, isoprene, piperylene, cyclopentadiene, dicyclopentadiene, and the like.
  • Petroleum resin-based tackifying resins include hydrogenated petroleum resins, aliphatic petroleum resins, aromatic petroleum resins, dicyclopentadiene petroleum resins, and the like.
  • rosin is a generic term for rosin resins and rosin derivatives.
  • Such rosins include unmodified rosins such as tall rosin, gum rosin, and wood rosin containing resin acids such as abietic acid, neoabietic acid, parastric acid, pimaric acid, isopimaric acid, and dehydroabietic acid as main components, disproportionated rosins, Including polymerized rosin, hydrogenated rosin, rosin esters, rosin-containing diols, or other chemically modified rosins.
  • acid-modified means to impart a carboxyl group to rosin.
  • acid-modified rosin examples include (meth)acrylic acid, (anhydrous) maleic acid, fumaric acid, itaconic acid, (anhydride) Examples include those obtained by reacting ⁇ , ⁇ -unsaturated carboxylic acid such as citraconic acid with rosin.
  • Rosin esters can be exemplified by esterification of at least one of rosin and rosin derivatives with alcohols.
  • alcohols that can be used for esterification include ethylene glycol, propylene glycol, neopentyl glycol, trimethylene glycol, glycerin, pentaerythritol, and dipentaerythritol.
  • Terpene resins include those obtained by polymerizing terpene monomers.
  • Hydrogenated terpene resins include those obtained by hydrogenating terpene resins.
  • Terpene phenol resins include those obtained by copolymerizing terpene monomers and phenol, and aromatic terpene resins include those obtained by modifying terpene resins with aromatic monomers.
  • tackifying resins may be used alone or in combination of two or more.
  • the adhesive composition may further contain a plasticizer in addition to the acrylic polymer.
  • a plasticizer any of known and commonly used plasticizers can be used. and other plasticizers.
  • the content of the plasticizer is preferably 4 parts by mass or less, more preferably 3 parts by mass or less, relative to 100 parts by mass of the polymer component (A). It is more preferably 1 part by mass or less, and it is particularly preferable that the adhesive layer contains substantially no plasticizer.
  • the adhesive layer according to the embodiment may have a plasticizer content of 4% by mass or less, or 3% by mass or less, relative to the total mass of the adhesive layer. It may be 1% by mass or less, and it is particularly preferred that the adhesive layer contains substantially no plasticizer.
  • the dry cleaning resistance of the label can be improved by setting the content of the plasticizer to the above upper limit or less.
  • the adhesive layer preferably contains a small amount of compounds with a molecular weight of 5,000 or less, such as the tackifying resins and plasticizers described above.
  • the content of the compound having a molecular weight of 5000 or less may be 4% by mass or less, 3% by mass or less, or 1% by mass with respect to the total mass of the adhesive layer. % or less, and it is particularly preferred that the adhesive layer does not substantially contain compounds having a molecular weight of 5,000 or less.
  • a compound having a molecular weight of 5000 or less is considered to be easily eluted in a dry cleaning solvent. Therefore, the dry cleaning resistance of the label can be improved by setting the content of the compound having a molecular weight of 5000 or less to the above upper limit or less.
  • the T-peel adhesion strength between the adhesive layer and the cotton cloth after pressure-sensitive bonding to the cotton cloth and before heat-sensitive bonding can be used as an index of the pressure-sensitive adhesiveness of the adhesive layer.
  • the adhesive layer after pressure-sensitive adhesion to the cotton cloth and before heat-sensitive adhesion was measured at a peel speed of 300 mm / min according to JIS K 6854-3 (ISO 11339), T-type peel adhesion between the cotton cloth
  • the strength (A) is preferably 0.5 to 10N/25mm, more preferably 1 to 8N/25mm, even more preferably 2 to 6N/25mm.
  • the conditions for pressure-sensitive adhesion to cotton cloth are as follows. Under the conditions of 23° C. and 50% RH, the adhesive layer and the cotton cloth are superimposed and pressure-sensitively adhered by reciprocating a rubber roller with a mass of 2000 g once, and then allowed to stand under the same conditions for 24 hours.
  • the adhesive strength (A) here is assumed to be the adhesive strength of the adhesive layer (of the label that is not thermally adhered) before the label is thermally adhered.
  • the adhesive strength of the adhesive layer is at least the above lower limit value, it is suitable for temporary fixing to a sticking object, and when it is at most the above upper limit value, it is preferable because re-peeling becomes easy.
  • the cotton cloth is Kanakin No. 3 cloth [cotton cloth specified in JIS L0803 (ISO105-F02)], width 25 mm, for example, plain weave, warp 20 tex, weft 16 tex, warp 141 per 5 cm, weft 135, basis weight. 100 g/m 2 can be used.
  • the T-peel adhesion strength between the cotton cloth and the adhesive layer after pressure-sensitive bonding to the cotton cloth and heat-sensitive bonding can be used.
  • the adhesive layer after pressure-sensitive adhesion to the cotton cloth and heat-sensitive adhesion was measured at a peel speed of 300 mm / min according to JIS K 6854-3 (ISO 11339), T-type peel adhesion between the cotton cloth
  • the strength (B) is preferably 3 N/25 mm or more, more preferably 3 to 20 N/25 mm, even more preferably 5 to 20 N/25 mm, and 7 to 20 N/25 mm. Especially preferred.
  • the conditions for thermal adhesion to cotton cloth are as follows.
  • the pressure-sensitive adhesive label and the cotton cloth are subjected to heat-sensitive adhesion by heating at a load of 1 kg/cm 2 and a temperature of 140° C. for 5 seconds, and then allowed to stand at 23° C. and a humidity of 50% RH for 24 hours.
  • the adhesive strength (B) is assumed to be the adhesive strength of the adhesive layer that is heat-sensitively adhered after the label is pressure-sensitively adhered.
  • An adhesive layer having the adhesive strength (B) within the above range has good heat-sensitive adhesion to an application target.
  • the numerical values exemplified above can be freely combined.
  • the value of the adhesive strength (B) of the adhesive layer is preferably greater than the value of the adhesive strength (A).
  • the adhesive layer after pressure-sensitive adhesion to cotton cloth and before heat-sensitive adhesion is measured at a peel rate of 300 mm / min according to JIS K 6854-3 (ISO 11339).
  • the T-type peel adhesive strength (A) between is 0.5 to 10 N / 25 mm
  • the adhesive layer after pressure-sensitive adhesion to the cotton cloth and after heat-sensitive adhesion was measured at a peeling speed of 300 mm / min according to JIS K 6854-3 (ISO 11339) T-type peeling between the cotton cloth
  • a label having an adhesive strength (B) greater than the value of the T-type peel adhesive strength (A) and 3 N/25 mm or more can be exemplified.
  • the T-peel adhesion strength between the adhesive layer and the cotton cloth after the pressure-sensitive adhesion to the cotton cloth, the heat-sensitive adhesion, and the dry-cleaning test. can be adopted.
  • the adhesive layer After pressure-sensitive adhesion and heat-sensitive adhesion to cotton cloth, the adhesive layer has a peeling speed of 300 mm /
  • the T-peel adhesive strength (C) with the cotton cloth, measured in minutes, is preferably 1 N/25 mm or more, more preferably 1 to 20 N/25 mm, and 3 to 15 N/25 mm. is more preferable, and 5 to 10 N/25 mm is particularly preferable.
  • the adhesive strength (C) here is assumed to be the adhesive strength of an adhesive layer that has been subjected to pressure-sensitive bonding, heat-sensitive bonding, and dry cleaning.
  • An adhesive layer having an adhesive strength (C) within the above range is difficult to be peeled off by dry cleaning and is excellent in dry cleaning resistance.
  • the adhesive layer may consist of one layer (single layer) or may consist of two or more layers. The combination of these multiple layers is not particularly limited.
  • the thickness of the adhesive layer is not particularly limited, it is preferably 5 to 50 ⁇ m, more preferably 7 to 40 ⁇ m, even more preferably 10 to 30 ⁇ m. When the thickness of the adhesive layer is within the above upper limit range, good pressure-sensitive adhesiveness and heat-sensitive adhesiveness are exhibited.
  • the thickness of the adhesive layer means the thickness of the entire adhesive layer.
  • the thickness of the adhesive layer consisting of multiple layers is the total thickness of all layers constituting the adhesive layer.
  • the release liner 40 is provided on the side of the adhesive layer 20 opposite to the side on which the first substrate 10 is provided.
  • the release liner 40 is not particularly limited, and in general, a known release liner having one side of a sheet subjected to release treatment can be appropriately selected and used.
  • Examples of the liner that can be used for the release liner 40 include paper such as glassine paper, fine paper, and kraft paper, laminated paper obtained by laminating these papers with a thermoplastic resin such as polyethylene, polyethylene terephthalate, polybutylene terephthalate, and polyethylene.
  • a thermoplastic resin such as polyethylene, polyethylene terephthalate, polybutylene terephthalate, and polyethylene.
  • polyester films such as naphthalate
  • polyolefin films such as polyethylene and polypropylene.
  • release agents for release treatment include silicones, long-chain alkyl-based resins, fluorine-based resins, and the like.
  • the thickness of the release liner 40 is not particularly limited, it is preferably 10 to 150 ⁇ m, more preferably 20 to 130 ⁇ m.
  • the total thickness of each layer of the label 1 of the embodiment, excluding the release liner 40, is preferably 20-350 ⁇ m, more preferably 30-200 ⁇ m, and particularly preferably 50-150 ⁇ m.
  • a method for producing a label according to an embodiment includes providing an adhesive layer having pressure-sensitive adhesiveness and heat-sensitive adhesiveness on the first surface side of a first base material, and the adhesive layer is made of an acrylic acid ester polymer.
  • the adhesive layer can be formed using an adhesive composition containing components that constitute the adhesive layer, and examples thereof include those exemplified above.
  • the adhesive layer can be formed from an adhesive composition containing an acrylic ester polymer having a weight average molecular weight (Mw) of 400,000 to 2,000,000.
  • Mw weight average molecular weight
  • Preferable Mw of the acrylic acid ester polymer includes the numerical values exemplified in the description of the Mw of the acrylic acid ester polymer.
  • the adhesive layer can be formed from an adhesive composition containing an acrylic ester polymer having a molecular weight distribution (Mw/Mn) of 2-6.
  • Mw/Mn molecular weight distribution
  • Preferable Mw/Mn of the acrylic acid ester polymer includes the numerical values exemplified in the description of the Mw/Mn of the acrylic acid ester polymer.
  • the content ratio of the components that do not vaporize at room temperature in the adhesive composition is usually the same as the content ratio of the components in the adhesive layer.
  • the term "ordinary temperature” means a temperature at which no particular cooling or heating is applied, that is, a normal temperature.
  • the method for manufacturing the label 1 of this embodiment includes providing the adhesive layer 20 on the first surface side of the first substrate 10 .
  • An adhesive composition is prepared that contains components that constitute the adhesive layer 20 and, if desired, a solvent.
  • the adhesive composition is applied to the release-treated surface of the release liner 40 by a coating machine such as a roll coater, knife coater, roll knife coater, air knife coater, die coater, bar coater, gravure coater, curtain coater, and dried. to obtain a laminate in which the release liner 40 and the adhesive layer 20 are laminated.
  • the exposed surface of the adhesive layer 20 of the laminate is pressed against the first base material 10 to manufacture the label 1 in which the first base material 10 and the adhesive layer 20 are laminated.
  • a cross-linked structure can be formed by the cross-linking agent by allowing the adhesive layer to stand at room temperature for about 7 days, for example.
  • the label of the embodiment can be used by attaching an object that can be dry cleaned as an adherend.
  • Objects to be dry cleaned include clothes such as shirts, skirts, pants, hats, mufflers, and socks, bedding such as pillows and sheets, covers, curtains, throws, shoes, and bags.
  • clothes such as shirts, skirts, pants, hats, mufflers, and socks
  • bedding such as pillows and sheets, covers, curtains, throws, shoes, and bags.
  • Cloth refers to all materials woven from natural fibers or chemical fibers.
  • dry cleaning refers to all cleaning methods that use solvents other than water.
  • the solvent is not particularly limited as long as it can be used for dry cleaning, and examples thereof include petroleum solvents such as perchlorethylene and gasoline, and perchlorethylene is preferred.
  • the adhesive layer is brought into contact with an adherend that can be dry-cleaned to pressure-bond the label, and the pressure-sensitively bonded label is heated to bond the label to the adherend. and heat-adhering the label to the adherend.
  • a method including a step of dry cleaning an adherend and a label heat-sensitively adhered to the adherend can be exemplified.
  • the heating temperature for the heat-sensitive adhesion can be appropriately determined according to the composition of the adhesive layer, and includes heating at a temperature equal to or higher than the melting point of the adhesive layer. It may be 130-200°C, and may be 140-170°C.
  • thermocompression bonding bonding by applying heat and pressure
  • an iron a press machine, or the like
  • pressure on the label about 0.5 to 10 kg/cm 2 can be exemplified.
  • the first base material is printed,
  • the information to be printed is selected from the group consisting of owner information of an object to be dry-cleaned with a cleaning label attached, cleaning shop information, control code of the object, and control number of the object. Any one or more selected dry cleaning information, or Any one or more selected from the group consisting of washing indications, washing symbols, sizes, handling precautions including washing or dry cleaning methods, material types, fiber compositions, and names of those who display them Object information is preferred.
  • Pieces of information are preferably printed on the first base material, which is the surface of the cleaning label visible to the user (for example, the outermost surface).
  • a known printing device can be used for printing. Printing may be applied before or after the label of the embodiment is attached to an adherend.
  • the label having the above dry cleaning information can be used as a cleaning label that is used after being dry cleaned together with the article after being attached to the article to be dry cleaned.
  • the label having the above object information can be used as a quality display label that is used after being dry-cleaned together with the article after being attached to the article to be dry-cleaned.
  • the cleaning label and quality display label are included in the cleaning label of the embodiment.
  • a second surface of the adhesive layer of the cleaning label of the embodiment which is opposite to the first surface on which the first base material is laminated, is coated with a second surface of the adhesive layer.
  • pressure sensitive bonding of two substrates to obtain a laminate comprising the first substrate, the adhesive layer and the second substrate in this order; heat-treating the laminate to thermally bond the first base material and the second base material via the adhesive layer.
  • tag the cleaning tag according to one embodiment of the present invention will also be simply referred to as "tag”.
  • Examples of the first base material and the adhesive layer include those exemplified in the above embodiments.
  • the second base material examples include those exemplified as the first base material.
  • the second substrate is preferably a film, cloth or non-woven fabric.
  • the first base material and the second base material may be a combination of the same materials, or may be a combination of different materials.
  • a combination in which the first base material is cloth and the second base material is cloth, or a combination in which the first base material is cloth and the second base material is a film can be exemplified.
  • the total thickness of each layer of the tag of the embodiment is preferably 25-2000 ⁇ m, more preferably 50-1000 ⁇ m, even more preferably 100-500 ⁇ m.
  • FIG. 2 is a schematic diagram illustrating the manufacturing method and configuration of the cleaning tag 2 of the embodiment.
  • the release liner 40 is peeled off the label 1 to expose the adhesive layer 20 .
  • the adhesive layer 20 and the second base material 12 are overlapped and pressure-bonded (pressure-sensitive bonding) to obtain a laminate including the first base material 10, the adhesive layer 20, and the second base material 12 in this order.
  • the laminate is heat-treated to thermally bond the first base material 10 and the second base material 12 with the adhesive layer 20 interposed therebetween, thereby obtaining the cleaning tag 2 .
  • the conditions for the above heat treatment include those exemplified as the heat-sensitive adhesive method in the above ⁇ How to use the label>>.
  • the second base material is a concept that includes the material that constitutes the surface of the object to be dry cleaned.
  • at least a part of the label attached to the adherend and the object is the cleaning tag manufactured in the above ⁇ method of using the label>>.
  • the second base material in the first embodiment has a wireless tag.
  • detailed descriptions of matters overlapping with the cleaning tag manufacturing method of the first embodiment will be omitted.
  • FIG. 3 is a schematic diagram for explaining the manufacturing method and configuration of the cleaning tag 3 of the embodiment.
  • a wireless tag 30 is provided on the second base material 12 .
  • the release liner 40 is peeled off the label 1 to expose the adhesive layer 20 .
  • the side of the second base material 12 on which the wireless tag 30 is provided and the exposed surface of the adhesive layer 20 are superimposed and pressure-bonded (pressure-sensitive bonding) to bond the first base material 10, the adhesive layer 20, and the wireless tag 30 together. and the second base material 12 in this order.
  • the laminate is heat-treated to thermally bond the first base material 10 and the second base material 12 having the wireless tag via the adhesive layer 20 to obtain the cleaning tag 3 .
  • the position of the wireless tag 30 on the second base material 12 may be reversed and adhered.
  • the adhesive layer 20, the second base material 12, and the wireless tag 30 in this order, they are heat-sensitively bonded in the same manner as described above to obtain the cleaning tag 4. can be done.
  • Wireless tags include those that can exchange information without contact through short-range wireless communication.
  • wireless tags include IC tags such as RFID (Radio Frequency Identifier) tags and NFC (Near Field Communication) tags, EM (Electronic Magnetic) tags used for EAS (Electronic Article Surveillance), etc. tags are included.
  • An example of an RFID tag is one that includes an IC chip that stores information and an antenna that receives radio waves.
  • the information stored in the IC includes information on objects that have cleaning tags attached and that can be dry cleaned. For example, it is an identification code or the like for identifying an object.
  • the antenna may be a pattern formed on the second substrate by a metal wire or a metal film.
  • the antenna can be formed of a metal foil, a deposited film, a thin film formed by sputtering, or the like.
  • the antenna may be formed by printing using a conductive paste or conductive ink in which metal particles are dispersed in a binder or solvent.
  • the second base material having the wireless tag As for the second base material having the wireless tag, the one provided with the wireless tag 30 arranged in advance on the second base material 12 can be used.
  • a protective resin layer 32 for protecting the wireless tag 30 may be laminated between the wireless tag 30 and the adhesive layer 20 .
  • the adhesive layer may corrode the antenna of the wireless tag because it contains an acrylic acid ester polymer. Therefore, by providing the protective resin layer 32 between the wireless tag 30 and the adhesive layer 20, the antenna can be protected.
  • the protective resin layer 32 a layer formed of urethane-based or acrylic-based varnish or the like can be used.
  • the cleaning tag 5 can be obtained by heat-sensitive adhesion in the same manner as described above.
  • the tag manufacturing method of the present embodiment uses a different cleaning label in the cleaning tag manufacturing method of the second embodiment.
  • detailed descriptions of matters that overlap with the cleaning tag manufacturing method of the second embodiment will be omitted.
  • FIG. 6 is a schematic diagram illustrating the manufacturing method and configuration of the cleaning tag 6 of the embodiment.
  • the side of the second base material 12 on which the wireless tag 30 is provided and the exposed surface of the adhesive layer 20 of the first label 1 are superimposed and pressure-bonded (pressure-sensitive bonding).
  • the side where the wireless tag 30 is not provided and the adhesive layer 20 of the second label 1 ′ are overlapped with the exposed surface and pressed (pressure-sensitive adhesive) to bond the first base material 10 and the adhesive layer 20
  • a laminate having the wireless tag 30, the second base material 12, the adhesive layer 20' and the first base material 10' in this order is obtained.
  • the laminate is heat-treated to thermally bond the first base material 10, the second base material 12 having the wireless tag, and the first base material 10' via the adhesive layers 20, 20'.
  • a cleaning tag 6 is obtained.
  • the label 1, the second base material 12 having the wireless tag 30, and the label 1' are heat-sensitively adhered collectively, but they may be heat-sensitively adhered separately.
  • the label 1 and the second base material 12 having the wireless tag 30 are thermally adhered to manufacture the cleaning tag 3 of the above embodiment.
  • the tag 3 and the label 1' are thermally adhered to obtain the cleaning tag 6.
  • the second base material 12 is preferably a resin film. Resin films tend to be thinner and have higher dimensional stability than cloth and non-woven fabric, and are easy to form the antenna pattern of the wireless tag. Therefore, the cleaning labels 1 and 1' are laminated so as to cover the second substrate to hide the antenna, and the design of the cleaning tag 6 can be improved.
  • a protective resin layer 32 may be laminated between the wireless tag 30 and the adhesive layer 20 in the same manner as in the case of the tag 5 described above.
  • Cleaning tags of embodiments can be used attached to objects that can be dry cleaned.
  • the attachment method include a method of directly sewing to the object.
  • an adhesive layer may be further provided on the side of the first base material or the second base material opposite to the side having the adhesive layer and attached to the article to be dry cleaned.
  • the adhesive layer the same one as exemplified as the adhesive layer 20 can be used.
  • the following configuration can be exemplified as a preferred usage of the cleaning tag of the embodiment.
  • the first base material or the second base material is printed,
  • the information to be printed is selected from the group consisting of owner information of an object to be dry-cleaned with a cleaning tag attached, cleaning shop information, control code of the object, and control number of the object. Any one or more of the dry cleaning information provided, or Any one or more selected from the group consisting of washing indications, washing symbols, sizes, handling precautions including washing or dry cleaning methods, material types, fiber compositions, and names of those who display them Object information is preferred.
  • these pieces of information are printed on the first base material or the second base material, which is the surface of the cleaning tag that is visible to the user (for example, the outermost surface).
  • the tag having the above dry cleaning information can be used as a cleaning tag that is attached to an article to be dry cleaned and then dry cleaned together with the article.
  • the tag having the above object information can be used as a quality display tag that is attached to an article to be dry-cleaned and then dry-cleaned together with the article.
  • a cleaning tag and a quality display tag are included in the cleaning tag of the embodiment.
  • Comparative Example 3 A label of Comparative Example 3 was obtained in the same manner as in Comparative Example 2, except that the acrylic acid ester copolymer had a weight average molecular weight of 350,000 and a molecular weight distribution of 7.
  • Example 1 In Comparative Example 2, the same operation as in Comparative Example 2 was performed except that the weight average molecular weight of the acrylic acid ester copolymer was changed to 400,000, the molecular weight distribution was changed to 4, and the amount of the cross-linking agent added was changed to 1 part by mass. , to obtain the label of Example 1.
  • Example 2 In Comparative Example 2, the same operation as in Comparative Example 2 was performed except that the weight average molecular weight of the acrylic acid ester copolymer was changed to 400,000, the molecular weight distribution was changed to 4, and the amount of the cross-linking agent added was changed to 3 parts by mass. , to obtain the label of Example 2.
  • Example 3 A label of Example 3 was obtained in the same manner as in Comparative Example 2, except that the weight average molecular weight of the acrylic acid ester copolymer was changed to 600,000 and the molecular weight distribution was changed to 4.
  • test piece of the adhesive layer was wrapped in Tetoron mesh (#200; manufactured by NBC Meshtec, opening: 72 ⁇ m, wire diameter: 55 ⁇ m), and immersed in perchlorethylene as a solvent for 3 days.
  • the gel content was measured by extracting the non-gel portion of the test piece, and measuring the gel fraction with the initial mass.
  • Gel fraction (%) mass of gel portion / initial mass x 100
  • GPC device HLC-8220 (manufactured by Tosoh Corporation) Column: TSK guard column HXL-H, TSK gel GMHXL, TSK gel G2000HXL (manufactured by Tosoh Corporation) Column temperature: 40°C Solvent: Tetrahydrofuran Flow rate: 1 ml/min Molecular weight standard substance: Polystyrene Detector: Differential refractive index detector Then, using the results obtained by the above method, the molecular weight distribution (weight average molecular weight Mw/number average molecular weight Mn) was calculated. .
  • test piece was prepared by cutting each of the first substrates used in the above examples and comparative examples into a width of 20 mm and a length of 30 mm.
  • ⁇ Test solution Add 5 g of anionic surfactant (di-2-ethylhexyl sodium sulfosuccinate), 5 g of nonionic surfactant (polyoxyethylene alkyl ether), and 1 mL of water to 1 L of perchlorethylene and mix well.
  • a test solution was prepared by dissolving and preparing a homogeneous and transparent solution.
  • Test 100 mL of the test solution prepared above and 20 stainless steel balls were placed in a test bottle, and the test solution was adjusted to 30°C ⁇ 2°C.
  • test piece was placed in this, it was sealed, attached to a washing tester, and operated at 30° C. ⁇ 2° C. for 30 minutes. After removing the test piece from the test bottle and rinsing it lightly with 100 mL of perchlorethylene, excess liquid was removed and dried in a dryer at 60° C. for 2 hours.
  • test piece after pressure-sensitive adhesion Under conditions of 23°C and 50% RH, a test piece (width 25 mm, length 50 mm) was cut out from each label obtained in the above examples and comparative examples, and the release liner was peeled off. Then, the adhesive layer and Kanakin No. 3 cloth [cotton cloth specified in JIS L0803 (ISO105-F02), thickness 172 ⁇ m, width 25 mm, length 50 mm] as the second base material are overlapped, and a rubber roller with a mass of 2000 g is used. After performing pressure-sensitive adhesion by reciprocating once, the test piece was left to stand under the same conditions for 24 hours to obtain a test piece after pressure-sensitive adhesion.
  • test piece after heat-sensitive bonding (width 25 mm, length 50 mm) is subjected to a load of 1 kg/ cm 2 and a temperature of 140° C. for 5 seconds for heat-sensitive adhesion, and then allowed to stand for 24 hours under conditions of 23° C. and humidity of 50% RH to obtain a test piece after heat-sensitive adhesion.
  • Test piece after dry cleaning test The test piece after the pressure-sensitive bonding and heat-sensitive bonding was subjected to a dry cleaning test at 30 ° C. according to JIS L 0860 A1 method to obtain a test piece after the dry cleaning test. .
  • the test liquid and test contents are the same as above.
  • the T-type peel strength is measured at a peel rate of 300 mm/min according to JIS K 6854-3: 1999 (ISO 11339) under conditions of 23°C and 50% RH. The T-type peel adhesion strength between the two was determined.
  • T-type peel strength (A): T-type peeling strength of the test piece after pressure-sensitive bonding and before heat-sensitive bonding T-type peeling strength (B): T-type peeling adhesion strength of the test piece after pressure-sensitive adhesion and heat-sensitive adhesion T-type peeling adhesion strength (C): The T-peel adhesion strength of the test piece after pressure-sensitive bonding, after heat-sensitive bonding, and after dry-cleaning test
  • Table 1 shows the above evaluation results.
  • the label of Comparative Example 1 did not have an adhesive layer capable of pressure-sensitive adhesion, and had a T-peel adhesive strength (A) value of 0 N/25 mm. That is, the label of Comparative Example 1 lacked aptitude for pressure-sensitive adhesion of the label to the target position before heat-sensitive adhesion.
  • the labels of Comparative Examples 2 to 3 and Examples 1 to 3 are provided with an adhesive layer capable of pressure-sensitive adhesion, and have good values of T-type peel strength (A) after pressure-sensitive adhesion. Aptitude was good.
  • all the labels of Comparative Examples 1 to 3 and Examples 1 to 3 are equipped with an adhesive layer that can be thermally adhered, and have good values of T-type peel adhesive strength (B) after thermal adhesion. Thermal adhesion to the adherend was possible.
  • the labels of Examples 1 to 3 in which the perchlorethylene gel fraction of the adhesive layer is 60% or more, have good values of T-peel adhesion strength (C) after dry cleaning and are resistant to drying. It was excellent in cleanability.

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