WO2022126739A1 - 一种耐低温型高模量沥青混合料专用添加剂及其制备方法 - Google Patents

一种耐低温型高模量沥青混合料专用添加剂及其制备方法 Download PDF

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WO2022126739A1
WO2022126739A1 PCT/CN2020/140501 CN2020140501W WO2022126739A1 WO 2022126739 A1 WO2022126739 A1 WO 2022126739A1 CN 2020140501 W CN2020140501 W CN 2020140501W WO 2022126739 A1 WO2022126739 A1 WO 2022126739A1
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parts
temperature resistant
asphalt mixture
low
resistant high
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PCT/CN2020/140501
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French (fr)
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关永胜
金光来
刘海婷
江臣
曾庆伟
冯雯雯
臧国帅
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江苏中路工程技术研究院有限公司
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L95/00—Compositions of bituminous materials, e.g. asphalt, tar, pitch
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/08—Stabilised against heat, light or radiation or oxydation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Definitions

  • the invention relates to the technical field of road engineering construction, in particular to a special additive for low temperature resistant high modulus asphalt mixture and a preparation method thereof.
  • High-modulus asphalt concrete has been used in France for more than 30 years.
  • High-modulus asphalt concrete can reduce the strain modulus of asphalt concrete, greatly improve the high-temperature deformation resistance of asphalt concrete pavement, delay the generation of rutting, and reduce rutting. depth, prolong the service life of the road surface, and prolong the maintenance period.
  • CN200710178915.1 discloses an anti-rutting additive for asphalt mixture and its preparation method and use method. It is a mixture of polyethylene resin and polypropylene resin. It is difficult for the modifier to melt in the asphalt mixture, so it is easy to reduce the durability of the pavement.
  • CN200910129486 discloses a novel anti-rutting agent, which adopts the technical scheme of combining rock asphalt, polyethylene and diatomite. The process is simple, but the granulation process is prone to problems such as difficulty in feeding.
  • Patent CN201110141313 uses low-density polyethylene, softener, high-density polyethylene and polycarbonate to make various high-modulus modifiers, but the modifier cannot reduce the mixing and molding temperature, and is difficult to be used in low temperature environments in winter, and The low temperature performance of the mixture is insufficient.
  • the high-modulus modifier prepared in the above report only improves the high-temperature performance of the asphalt mixture, but will damage the low-temperature performance of the asphalt mixture.
  • the first object of the present invention is to provide a special additive for low-temperature resistant high-modulus asphalt mixtures, which has good compatibility with asphalt and mixtures, and not only significantly improves the high-modulus asphalt
  • the mixture has anti-cracking performance at low temperature, and has excellent anti-rutting performance and anti-water damage performance. At the same time, the mixing temperature of the mixture is low, and the construction workability is good.
  • the special additive for low-temperature resistant high-modulus asphalt mixture includes the following components: 100 parts of main agent, 30-50 parts of waste plastic mixture, 10-20 parts of styrene-butadiene rubber, 100-150 parts of rock asphalt particles and 1-3 parts of compatibilizer; the main agent is a ternary nanocomposite material consisting of 10-15 parts of polyurethane prepolymer, 5-10 parts of polyethylene wax and 3-7 parts of filler .
  • the polyurethane prepolymer is a polyether type one-component polyurethane prepolymer.
  • the NCO in the polyurethane molecule and the OH in the asphalt molecule undergo a chain extension reaction, the asphalt molecular chain becomes longer, and the flexibility becomes better, which can significantly improve the low-temperature crack resistance of the high-modulus asphalt mixture.
  • the melting point of polyethylene paraffin is lower than 100°C.
  • Polyethylene wax with low melting point can reduce the mixing and compaction temperature of asphalt mixture and improve the compactability of high modulus asphalt mixture.
  • the filler is one or a mixture of any two selected from diatomite, montmorillonite, rectorite, and nano-SiO 2 , passing through a 300-mesh sieve.
  • the sizes of diatomite, montmorillonite, and rectorite are all nanoscale.
  • the above fillers can form a very stable intercalation/exfoliation structure with asphalt/polyurethane and other polymer additives.
  • the lamellae of diatomite, montmorillonite, and rectorite are uniformly dispersed in the asphalt matrix to prevent air from being trapped in the asphalt matrix. Diffusion in the PU, delaying the thermal degradation of polyurethane, inhibiting the mutual conversion between asphalt components and the volatilization of light components, reducing the content of oxidation products, and effectively restricting the movement of asphalt molecular chains, which can effectively improve high performance.
  • the mechanical properties, heat resistance, and oxygen aging properties of modulus asphalt mixtures can improve the durability of high-modulus asphalt mixtures.
  • the waste plastic mixture includes the following components: 20-30 parts of waste plastics, 5-8 parts of diluent and 3-5 parts of 8-hydroxyquinoline aluminum complex.
  • the addition of 8-hydroxyquinoline aluminum complex can modify waste plastics. On the one hand, it improves the toughness of waste plastics and the compatibility with asphalt, thereby improving the low-temperature crack resistance of asphalt mixtures.
  • Diatomite, montmorillonite, rectorite or nano-SiO 2 form a synergistic effect and inhibit the movement of molecular chains with their large steric hindrance, thereby improving the mechanical properties and heat resistance of high-modulus asphalt mixtures.
  • waste plastic is one or a mixture of any two of polyethylene, polypropylene and EVA resin.
  • the diluent is any one of benzothiopyran-3-one, dihydrobenzothiopyran or 2-hydroxy-4H-1-benzothiopyran-4-one, and can also be a mixture of several .
  • the use of the above diluent can reduce the viscosity of waste plastics, and at the same time, through the addition of benzothiopyran, a three-dimensional interpenetrating network is formed, and the low-temperature cracking performance of the asphalt mixture is improved.
  • the rock asphalt particles are preferably high ash content rock asphalt particles, the ash content is about 75%, and the softening point is above 300°C.
  • High-ash rock asphalt particles have various organic chains that can promote the cross-linking polymerization of active groups in petroleum asphalt, which can improve the arrangement and network structure of petroleum asphalt molecules, enhance asphalt cohesion, and significantly improve high-modulus asphalt mixtures. anti-rutting performance.
  • nitrogen elements in high-ash rock asphalt particles exist in the form of functional groups, which have strong wettability and high resistance to free oxidation radicals, enhance the adhesion between asphalt and aggregates, and improve the water content of high-modulus asphalt mixtures. stable performance.
  • the compatibilizer in the present invention is preferably maleic anhydride.
  • the second object of the present invention is to provide a method for preparing a special additive for low temperature resistant high modulus asphalt mixture, which has the same technical effect.
  • the invention provides a method for preparing a special additive for low-temperature resistant high-modulus asphalt mixture, characterized in that it includes the following operation steps:
  • the polyurethane prepolymer, polyethylene wax and filler are placed in a reaction kettle at 100-120°C and mixed evenly to form a melt to obtain the main agent;
  • the special additive for low temperature resistant high modulus asphalt mixture accounts for 1% to 1.2% of the mass of the asphalt mixture.
  • the present invention has the following beneficial effects:
  • the special additive for low-temperature resistant high-modulus asphalt mixture prepared by the invention can simultaneously improve the high-temperature stability and low-temperature crack resistance of asphalt, enhance the high-temperature rutting resistance, low-temperature crack resistance and water stability of asphalt pavement, and effectively prolong the asphalt pavement. service life of the pavement.
  • the polyether type one-component polyurethane prepolymer was purchased from Zibo Huatian Rubber and Plastic Technology Co., Ltd.
  • Example 1 A special additive for low-temperature resistant high-modulus asphalt mixture, calculated in parts by weight, including the following components: 100 parts of main agent, 30-50 parts of waste plastic mixture, 10-20 parts of styrene-butadiene rubber, 100-150 parts of rock asphalt particles, 1-3 parts of compatibilizer; the main agent is a ternary nano-composite material consisting of 10-15 parts of polyurethane prepolymer, 5-10 parts of polyethylene wax and 3-7 parts of filler.
  • the polyurethane prepolymer, polyethylene wax and filler are placed in a reaction kettle at 100-120°C and mixed evenly to form a melt to obtain the main agent;
  • Example 2 A special additive for low-temperature resistant high-modulus asphalt mixture, calculated in parts by weight, including the following components: 100 parts of main agent, 50 parts of waste plastic mixture, 20 parts of styrene-butadiene rubber, and 150 parts of rock asphalt particles parts, 3 parts of maleic anhydride; the main agent is a ternary nanocomposite material composed of 15 parts of polyurethane prepolymer, 10 parts of polyethylene wax and 7 parts of nanodiatomite.
  • the polyurethane prepolymer, polyethylene wax, and nanodiatomite are placed in a reaction kettle at 100-120° C. and mixed uniformly to form a melt to obtain the main agent;
  • Example 3 A special additive for low temperature resistant high modulus asphalt mixture, calculated in parts by weight, including the following components: 100 parts of main agent, 50 parts of waste plastic mixture, 10 to 20 parts of comb-type styrene-butadiene rubber, 150 parts of rock asphalt particles and 1 part of maleic anhydride; the main agent is a ternary nanocomposite material consisting of 15 parts of polyurethane prepolymer, 5 to 10 parts of polyethylene wax, and 7 parts of nano-rectorite, wherein the melting point of polyethylene wax is below 100°C.
  • the polyurethane prepolymer, polyethylene wax and filler are placed in a reaction kettle at 100-120°C and mixed evenly to form a melt to obtain the main agent;
  • Example 4 A special additive for low temperature resistant high modulus asphalt mixture, calculated in parts by weight, including the following components: 100 parts of main agent, 50 parts of waste plastic mixture, 20 parts of star-shaped styrene-butadiene rubber, rock asphalt 150 parts of particles, 1 part of maleic anhydride;
  • the main agent is a ternary nanocomposite material consisting of 15 parts of polyurethane prepolymer, 10 parts of polyethylene wax, and 3 parts of nano-montmorillonite, wherein the melting point of polyethylene wax is lower than 100 °C, the rock asphalt particles are high ash content rock asphalt particles, the ash content is about 75%, and the softening point is above 300 °C.
  • the polyurethane prepolymer, polyethylene wax, and nano-montmorillonite are placed in a reaction kettle at 100-120°C and mixed uniformly to form a melt to obtain the main agent;
  • Example 5 A special additive for low temperature resistant high modulus asphalt mixture, calculated in parts by weight, including the following components: 100 parts of main agent, 50 parts of waste plastic mixture, 20 parts of linear styrene-butadiene rubber, rock asphalt 150 parts of particles, 3 parts of maleic anhydride;
  • the main agent is a ternary nanocomposite material consisting of 15 parts of polyether type one-component polyurethane prepolymer, 5 parts of polyethylene wax, and 7 parts of nano-SiO 2 ; among them, polyethylene wax
  • the melting point is lower than 100 °C
  • the rock asphalt particles are high ash rock asphalt particles, the ash content is about 75%, and the softening point is above 300 °C;
  • the waste plastic mixture includes: polyethylene 30 parts, benzothiopyran-3-one 8 parts and 5 parts of 8-hydroxyquinoline aluminum complex.
  • the polyurethane prepolymer, polyethylene wax, and nano-SiO 2 are placed in a reaction kettle at 100 to 120 ° C and mixed evenly to form a melt to obtain the main agent;
  • Example 6 A special additive for low temperature resistant high modulus asphalt mixture, calculated in parts by weight, including the following components: 100 parts of main agent, 50 parts of waste plastic mixture, 20 parts of linear styrene-butadiene rubber, rock asphalt 150 parts of particles, 3 parts of maleic anhydride;
  • the main agent is a ternary nanocomposite material consisting of 15 parts of polyether type one-component polyurethane prepolymer, 5 parts of polyethylene wax, and 3 parts of nanodiatomite; among them, polyethylene
  • the melting point of wax is lower than 100 °C
  • the rock asphalt particles are high ash content rock asphalt particles, the ash content is about 75%, and the softening point is above 300 °C;
  • the waste plastic mixture includes: 30 parts of EVA resin, 2-hydroxy-4H-1- 8 parts of benzothiopyran-4-one and 5 parts of 8-hydroxyquinoline aluminum complex.
  • the polyurethane prepolymer, polyethylene wax, and nanodiatomite are placed in a reaction kettle at 100-120° C. and mixed uniformly to form a melt to obtain the main agent;
  • the asphalt used in this test is: SBS modified asphalt PG76-22, the type of mixture: EME-14, and its mineral mix ratio and gradation are as follows:

Abstract

本发明涉及道路工程建设技术领域，特别涉及一种耐低温型高模量沥青混合料专用添加剂及其制备方法。其技术要点如下：按照重量份数计算，包括如下组分：主剂100份、废旧塑料混合物30～50份、丁苯橡胶10～20份、岩沥青颗粒100～150份、增容剂1～3份；主剂由聚氨酯预聚体10～15份、聚乙烯蜡5～10份、填料3～7份组成的三元纳米复合材料。该高模量沥青混合料专用添加剂与沥青以及混合料的相容好，不但显著提高了高模量沥青混合料的抗低温开裂性能，而且具有优异的抗车辙性能和抗水侵害性能，同时混合料拌合温度较低，施工和易性好。

Description

一种耐低温型高模量沥青混合料专用添加剂及其制备方法 技术领域
本发明涉及道路工程建设技术领域，特别涉及一种耐低温型高模量沥青混合料专用添加剂及其制备方法。
背景技术
高模量沥青混凝土(HMAC)在法国使用已经超过30年的时间，高模量沥青混凝土能够降低沥青混凝土应变模量，大幅度提高沥青混凝土路面的抗高温变形能力，延缓车辙的产生、减低车辙深度，延长路面使用寿命，延长维修周期。
目前关于高模量改性剂报道很多，其中法国产品PR PLASTS与德国产品Domix能提高沥青路面的抗车辙性能，但是价格贵、掺量较高，且混合料防水效果较差。国内有一些抗车辙剂产品，价格较为便宜，但是性能不稳定，尤其是动态模量方面和低温性能方面国内与国外差距较为明显。CN200710178915.1公开了一种沥青混合料抗车辙添加剂及其制备方法和使用方法，是聚乙烯树脂与聚丙烯树脂混合物，熔融指数低，不易分散，低温性能差，老化严重，在正常拌合温度下，该改性剂很难在沥青混合料中熔融，因此容易降低路面的耐久性。CN200910129486公开了一种新型抗车辙剂，采用了岩沥青、聚乙烯、硅藻土相结合的技术方案，工艺简单，但是造粒过程容易出现吃料困难等问题。专利CN201110141313采用低密度聚乙烯、软化剂、高密度聚乙烯和聚碳酸醋制各高模量改性剂，但是该改性剂不能降低拌合和成型温度，很难用于冬季低温环境，且混合料低温性能不足。上述报道制备的高模量改性剂，仅仅对沥青混合料高温性能有提升，但是会损伤沥青混合料的低温性能。
有鉴于上述现有的高模量改性剂中存在的缺陷，本发明人基于从事此类产品设计制造多年，有着丰富的实务经验及专业知识，熟练和充分地运用化学机理，在实践中不断研究和创新，创设了一种耐低温型高模量沥青混合料专用添加剂及其制备方法，该高模量沥青混合料专用添加剂与沥青以及混合料的相容好，不但显著提高了高模量沥青混合料的抗低温开裂性能，而且具有优异的抗车辙性能和抗水侵害性能，同时混合料拌合温度较低，施工和易性好。通过不断研究、设计，并经过反复试验和改进后，终于创设出确具实用价值的本发明。
发明内容
本发明的第一个目的是提供一种耐低温型高模量沥青混合料专用添加剂，该高模量沥青混合料专用添加剂与沥青以及混合料的相容好，不但显著提高了高模量沥青混合料的抗低温开裂性能，而且具有优异的抗车辙性能和抗水侵害性能，同时混合料拌合温度较低，施工和易性好。
本发明的上述技术目的是通过以下技术方案得以实现的：
本发明提供的一种耐低温型高模量沥青混合料专用添加剂，按照重量份数计算，包括如下组分：主剂100份、废旧塑料混合物30～50份、丁苯橡胶10～20份、岩沥青颗粒100～150份、增容剂1～3份；所述主剂由聚氨酯预聚体10～15份、聚乙烯蜡5～10份、填料3～7份组成的三元纳米复合材料。
进一步的，聚氨酯预聚体为聚醚型单组份聚氨酯预聚体。聚氨酯分子中的NCO与沥青分子中的OH发生扩链反应，沥青分子链变长，柔韧性变好，可以显著提升高模量沥青混合料的低温抗裂性能。
进一步的，聚乙烯石蜡熔点低于100℃。低熔点的聚乙烯石蜡能够降低沥青混合料的拌和及压实温度，提高高模量沥青混合料的易压实性。
进一步的，填料为硅藻土、蒙脱土、累托石、纳米SiO 2中的一种或任意两 种的混合物，过300目筛。
进一步的，硅藻土、蒙脱土、累托石尺寸均为纳米级。上述填料能够与沥青/聚氨酯及其他聚合物添加剂形成非常稳定的插层型/剥离型结构，硅藻土、蒙脱土、累托石的片层均匀的分散在沥青基体中阻止空气在沥青基体中的扩散，延缓聚氨酯的热降解，抑制沥青各组分之间的相互转化及轻质组分的挥发，降低氧化产物的含量，同时还可以有效地限制沥青分子链的运动，可以有效提高高模量沥青混合料的力学性能及耐热性、氧老化性能，提升高模量沥青混合料的耐久性。
进一步的，按照重量份数计算，废旧塑料混合物包括如下组分：废旧塑料20～30份，稀释剂5～8份和8-羟基喹啉铝配合物3～5份。8-羟基喹啉铝配合物的加入，能够对废旧塑料进行改性，一方面提高废旧塑料的韧性以及与沥青的相容性，进而提高沥青混合料的低温抗裂性能，另一个方面与纳米硅藻土、蒙脱石、累托石或纳米SiO 2形成协同作用，并以其大的空间位阻抑制分子链的运动，从而提高高模量沥青混合料的力学性能及耐热性。
进一步的，废旧塑料为聚乙烯、聚丙烯、EVA树脂中的一种或任意两种的混合物。
进一步的，稀释剂是苯并噻喃-3-酮、二氢苯并噻喃或2-羟基-4H-1-苯并噻喃-4-酮中的任意一种也可以是几种的混合物。采用上述稀释剂，能够降低废旧塑料的粘度，同时通过苯并噻喃的加入，形成三维的互穿网络，提高沥青混合料的低温开裂性能。
进一步的，岩沥青颗粒优选为高灰分岩沥青颗粒，灰分含量为75％左右，软化点为300℃以上。高灰分岩沥青颗粒具有多种能促进石油沥青中的活性基团交联聚合的有机链，能改善石油沥青分子的排列方式和网状结构，增强了沥青 内聚力，显著提升高模量沥青混合料的抗车辙性能。同时，高灰分岩沥青颗粒中氮元素以官能团形式存在，具有很强的浸润性和对自由氧化基的高抵抗性，增强沥青与集料的粘附性，提升高模量沥青混合料的水稳性能。
进一步的，本发明中的增容剂优选为马来酸酐。
本发明的第二个目的是提供一种耐低温型高模量沥青混合料专用添加剂的制备方法，具有同样的技术效果。
本发明的上述技术效果是由以下技术方案实现的：
本发明提供的一种耐低温型高模量沥青混合料专用添加剂的制备方法，其特征在于，包括如下操作步骤：
S1.将聚氨酯预聚体、聚乙烯蜡、填料置于100～120℃的反应釜中混合均匀，形成熔融体，得到主剂；
S2.将主剂、废旧塑料混合物、丁苯橡胶、岩沥青颗粒、增容剂混合后制备出耐低温型高模量沥青混合料专用添加剂。
作为上述技术方案的优选，耐低温型高模量沥青混合料专用添加剂占沥青混合料质量的1％～1.2％。
综上所述，本发明具有以下有益效果：
本发明制备的耐低温型高模量沥青混合料专用添加剂可同时提高沥青的高温稳定性、低温抗裂性能，增强沥青路面的高温抗车辙性能、低温抗裂性能以及水稳定性能，有效延长沥青路面的使用寿命。
具体实施方式
为更进一步阐述本发明为达成预定发明目的所采取的技术手段及功效，对依据本发明提出的耐低温型高模量沥青混合料专用添加剂及其制备方法，其具体实施方式、特征及其功效，详细说明如后。
其中，聚醚型单组份聚氨酯预聚体采购于淄博华天橡塑科技有限公司。
实施例1：一种耐低温型高模量沥青混合料专用添加剂，按照重量份数计算，包括如下组分：主剂100份、废旧塑料混合物30～50份、丁苯橡胶10～20份、岩沥青颗粒100～150份、增容剂1～3份；主剂由聚氨酯预聚体10～15份、聚乙烯蜡5～10份、填料3～7份组成的三元纳米复合材料。
其制备方法如下：
S1.将聚氨酯预聚体、聚乙烯蜡、填料置于100～120℃的反应釜中混合均匀，形成熔融体，得到主剂；
S2.将主剂、废旧塑料混合物、丁苯橡胶、岩沥青颗粒、增容剂混合后制备出耐低温型高模量沥青混合料专用添加剂。
实施例2：一种耐低温型高模量沥青混合料专用添加剂，按照重量份数计算，包括如下组分：主剂100份、废旧塑料混合物50份、丁苯橡胶20份、岩沥青颗粒150份、马来酸酐3份；主剂是由聚氨酯预聚体15份、聚乙烯蜡10份、纳米硅藻土7份组成的三元纳米复合材料。
其制备方法如下：
S1.将聚氨酯预聚体、聚乙烯蜡、纳米硅藻土置于100～120℃的反应釜中混合均匀，形成熔融体，得到主剂；
S2.将主剂、废旧塑料混合物、丁苯橡胶、岩沥青颗粒、马来酸酐混合后制备出耐低温型高模量沥青混合料专用添加剂。
实施例3：一种耐低温型高模量沥青混合料专用添加剂，按照重量份数计算，包括如下组分：主剂100份、废旧塑料混合物50份、梳型丁苯橡胶10～20份、岩沥青颗粒150份、马来酸酐1份；主剂由聚氨酯预聚体15份、聚乙烯蜡5～10份、纳米累托石7份组成的三元纳米复合材料，其中聚乙烯蜡的熔点低于100℃。
其制备方法如下：
S1.将聚氨酯预聚体、聚乙烯蜡、填料置于100～120℃的反应釜中混合均匀，形成熔融体，得到主剂；
S2.将主剂、废旧塑料混合物、梳型丁苯橡胶、岩沥青颗粒、增容剂混合后制备出耐低温型高模量沥青混合料专用添加剂。
实施例4：一种耐低温型高模量沥青混合料专用添加剂，按照重量份数计算，包括如下组分：主剂100份、废旧塑料混合物50份、星型丁苯橡胶20份、岩沥青颗粒150份、马来酸酐1份；主剂由聚氨酯预聚体15份、聚乙烯蜡10份、纳米蒙脱石3份组成的三元纳米复合材料，其中，聚乙烯蜡的熔点低于100℃，岩沥青颗粒为高灰分岩沥青颗粒，灰分含量为75％左右，软化点为300℃以上。
其制备方法如下：
S1.将聚氨酯预聚体、聚乙烯蜡、纳米蒙脱石置于100～120℃的反应釜中混合均匀，形成熔融体，得到主剂；
S2.将主剂、废旧塑料混合物、星型丁苯橡胶、岩沥青颗粒、增容剂混合后制备出耐低温型高模量沥青混合料专用添加剂。
实施例5：一种耐低温型高模量沥青混合料专用添加剂，按照重量份数计算，包括如下组分：主剂100份、废旧塑料混合物50份、线型丁苯橡胶20份、岩沥青颗粒150份、马来酸酐3份；主剂由聚醚型单组份聚氨酯预聚体15份、聚乙烯蜡5份、纳米SiO 2 7份组成的三元纳米复合材料；其中，聚乙烯蜡的熔点低于100℃，岩沥青颗粒为高灰分岩沥青颗粒，灰分含量为75％左右，软化点为300℃以上；废旧塑料混合物包括：聚乙烯30份，苯并噻喃-3-酮8份和8-羟基喹啉铝配合物5份。
其制备方法如下：
S1.将聚氨酯预聚体、聚乙烯蜡、纳米SiO 2置于100～120℃的反应釜中混合均匀，形成熔融体，得到主剂；
S2.将主剂、废旧塑料混合物、线型丁苯橡胶、岩沥青颗粒、增容剂混合后制备出耐低温型高模量沥青混合料专用添加剂。
实施例6：一种耐低温型高模量沥青混合料专用添加剂，按照重量份数计算，包括如下组分：主剂100份、废旧塑料混合物50份、线型丁苯橡胶20份、岩沥青颗粒150份、马来酸酐3份；主剂由聚醚型单组份聚氨酯预聚体15份、聚乙烯蜡5份、纳米硅藻土3份组成的三元纳米复合材料；其中，聚乙烯蜡的熔点低于100℃，岩沥青颗粒为高灰分岩沥青颗粒，灰分含量为75％左右，软化点为300℃以上；废旧塑料混合物包括：EVA树脂30份，2-羟基-4H-1-苯并噻喃-4-酮8份和8-羟基喹啉铝配合物5份。
其制备方法如下：
S1.将聚氨酯预聚体、聚乙烯蜡、纳米硅藻土置于100～120℃的反应釜中混合均匀，形成熔融体，得到主剂；
S2.将主剂、废旧塑料混合物、线型丁苯橡胶、岩沥青颗粒、增容剂混合后制备出耐低温型高模量沥青混合料专用添加剂。
性能测试
将实施例1～6中获得的耐低温型高模量沥青混合料专用添加剂添加入沥青混合料中，其中，耐低温型高模量沥青混合料专用添加剂占沥青混合料质量的1％～1.2％，测试沥青混合料的高温稳定性、低温抗裂性能和水稳定性能。测试结果如下表：
本测试中采用的沥青是：SBS改性沥青PG76-22，混合料类型：EME-14，其矿料配合比以及级配如下：
表1.矿料配合比及设计油石比
Figure PCTCN2020140501-appb-000001
表2.合成级配通过率明细表(中国标准筛孔)
Figure PCTCN2020140501-appb-000002
表3.测试结果
Figure PCTCN2020140501-appb-000003
以上所述，仅是本发明的较佳实施例而已，并非对本发明作任何形式上的限制，虽然本发明已以较佳实施例揭露如上，然而并非用以限定本发明，任何熟悉本专业的技术人员，在不脱离本发明技术方案范围内，当可利用上述揭示的技术内容做出些许更动或修饰为等同变化的等效实施例，但凡是未脱离本发明技术方案的内容，依据本发明的技术实质对以上实施例所作的任何简单修改、等同变化与修饰，均仍属于本发明技术方案的范围内。

Claims (10)

  1. 一种耐低温型高模量沥青混合料专用添加剂，其特征在于，按照重量份数计算，包括如下组分：主剂100份、废旧塑料混合物30～50份、丁苯橡胶10～20份、岩沥青颗粒100～150份、增容剂1～3份；所述主剂由聚氨酯预聚体10～15份、聚乙烯蜡5～10份、填料3～7份组成的三元纳米复合材料。
  2. 根据权利要求1所述的一种耐低温型高模量沥青混合料专用添加剂，其特征在于，所述聚氨酯预聚体为聚醚型单组份聚氨酯预聚体。
  3. 根据权利要求1所述的一种耐低温型高模量沥青混合料专用添加剂，其特征在于，所述聚乙烯石蜡熔点不大于100℃。
  4. 根据权利要求1所述的一种耐低温型高模量沥青混合料专用添加剂，其特征在于，所述填料为硅藻土、蒙脱土、累托石、纳米SiO 2中的一种或任意两种的混合物，过300目筛。
  5. 根据权利要求1所述的一种耐低温型高模量沥青混合料专用添加剂，其特征在于，所述硅藻土、蒙脱土、累托石尺寸均为纳米级。
  6. 根据权利要求1所述的一种耐低温型高模量沥青混合料专用添加剂，其特征在于，按照重量份数计算，所述废旧塑料混合物包括如下组分：废旧塑料20～30份，稀释剂5～8份和8-羟基喹啉铝配合物3～5份。
  7. 根据权利要求6所述的一种耐低温型高模量沥青混合料专用添加剂，其特征在于，所述废旧塑料为聚乙烯、聚丙烯、EVA树脂中的一种或任意两种的混合物。
  8. 根据权利要求6所述的一种耐低温型高模量沥青混合料专用添加剂，其特征在于，所述稀释剂是苯并噻喃-3-酮、二氢苯并噻喃或2-羟基-4H-1-苯并噻喃-4-酮中的任意一种。
  9. 根据权利要求1所述的一种耐低温型高模量沥青混合料，其特征在于， 所述岩沥青颗粒为高灰分岩沥青颗粒，灰分含量为75％，软化点大于300℃。
  10. 根据权利要求1～9任意一项所述的一种耐低温型高模量沥青混合料专用添加剂的制备方法，其特征在于，包括如下操作步骤：
    S1.将聚氨酯预聚体、聚乙烯蜡、填料置于100～120℃的反应釜中混合均匀，形成熔融体，得到主剂；
    S2.将主剂、废旧塑料混合物、丁苯橡胶、岩沥青颗粒、增容剂混合后制备出耐低温型高模量沥青混合料专用添加剂。
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