WO2022120920A1 - 一种热固性树脂组合物及包含其的预浸料、层压板和高频电路基板 - Google Patents
一种热固性树脂组合物及包含其的预浸料、层压板和高频电路基板 Download PDFInfo
- Publication number
- WO2022120920A1 WO2022120920A1 PCT/CN2020/137246 CN2020137246W WO2022120920A1 WO 2022120920 A1 WO2022120920 A1 WO 2022120920A1 CN 2020137246 W CN2020137246 W CN 2020137246W WO 2022120920 A1 WO2022120920 A1 WO 2022120920A1
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- WO
- WIPO (PCT)
- Prior art keywords
- maleic anhydride
- resin composition
- parts
- weight
- thermosetting resin
- Prior art date
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- 239000011342 resin composition Substances 0.000 title claims abstract description 41
- 229920001187 thermosetting polymer Polymers 0.000 title claims abstract description 33
- 239000000758 substrate Substances 0.000 title claims abstract description 18
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims abstract description 39
- -1 maleimide compound Chemical class 0.000 claims abstract description 28
- 239000003822 epoxy resin Substances 0.000 claims abstract description 27
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 27
- 229920005989 resin Polymers 0.000 claims abstract description 27
- 239000011347 resin Substances 0.000 claims abstract description 27
- 150000002148 esters Chemical class 0.000 claims abstract description 21
- 239000005062 Polybutadiene Substances 0.000 claims abstract description 20
- 229920002857 polybutadiene Polymers 0.000 claims abstract description 20
- 239000003292 glue Substances 0.000 claims abstract description 10
- 239000007787 solid Substances 0.000 claims abstract description 10
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 18
- 229920001577 copolymer Polymers 0.000 claims description 15
- 239000000945 filler Substances 0.000 claims description 15
- 239000000243 solution Substances 0.000 claims description 11
- PEEHTFAAVSWFBL-UHFFFAOYSA-N Maleimide Chemical compound O=C1NC(=O)C=C1 PEEHTFAAVSWFBL-UHFFFAOYSA-N 0.000 claims description 10
- 150000001875 compounds Chemical class 0.000 claims description 10
- 239000003063 flame retardant Substances 0.000 claims description 9
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 8
- 239000000463 material Substances 0.000 claims description 8
- 239000002245 particle Substances 0.000 claims description 8
- 229910052698 phosphorus Inorganic materials 0.000 claims description 8
- 239000011574 phosphorus Substances 0.000 claims description 8
- 239000002904 solvent Substances 0.000 claims description 8
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 claims description 6
- 239000011888 foil Substances 0.000 claims description 6
- 229910052751 metal Inorganic materials 0.000 claims description 6
- 239000002184 metal Substances 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 claims description 6
- 239000012779 reinforcing material Substances 0.000 claims description 6
- 239000000377 silicon dioxide Substances 0.000 claims description 6
- DLYUQMMRRRQYAE-UHFFFAOYSA-N tetraphosphorus decaoxide Chemical compound O1P(O2)(=O)OP3(=O)OP1(=O)OP2(=O)O3 DLYUQMMRRRQYAE-UHFFFAOYSA-N 0.000 claims description 6
- 125000001624 naphthyl group Chemical group 0.000 claims description 5
- DXZMANYCMVCPIM-UHFFFAOYSA-L zinc;diethylphosphinate Chemical compound [Zn+2].CCP([O-])(=O)CC.CCP([O-])(=O)CC DXZMANYCMVCPIM-UHFFFAOYSA-L 0.000 claims description 5
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 4
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 4
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims description 4
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 4
- 150000004767 nitrides Chemical class 0.000 claims description 4
- 229910052755 nonmetal Inorganic materials 0.000 claims description 4
- 239000004843 novolac epoxy resin Substances 0.000 claims description 4
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 4
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 4
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 claims description 3
- 150000008065 acid anhydrides Chemical class 0.000 claims description 3
- 235000010290 biphenyl Nutrition 0.000 claims description 3
- 239000004305 biphenyl Substances 0.000 claims description 3
- 239000005350 fused silica glass Substances 0.000 claims description 3
- 102220043159 rs587780996 Human genes 0.000 claims description 3
- 235000012239 silicon dioxide Nutrition 0.000 claims description 3
- YYRHIWOOLJRQOA-UHFFFAOYSA-N (2,6-dimethylphenyl)-[3-(2,6-dimethylphenyl)phosphanylphenyl]phosphane Chemical compound CC1=CC=CC(C)=C1PC1=CC=CC(PC=2C(=CC=CC=2C)C)=C1 YYRHIWOOLJRQOA-UHFFFAOYSA-N 0.000 claims description 2
- XQUPVDVFXZDTLT-UHFFFAOYSA-N 1-[4-[[4-(2,5-dioxopyrrol-1-yl)phenyl]methyl]phenyl]pyrrole-2,5-dione Chemical compound O=C1C=CC(=O)N1C(C=C1)=CC=C1CC1=CC=C(N2C(C=CC2=O)=O)C=C1 XQUPVDVFXZDTLT-UHFFFAOYSA-N 0.000 claims description 2
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 claims description 2
- NOQJZCJOXLFFCH-UHFFFAOYSA-N 3-(2,3-dimethylphenyl)pyrrole-2,5-dione Chemical compound CC1=CC=CC(C=2C(NC(=O)C=2)=O)=C1C NOQJZCJOXLFFCH-UHFFFAOYSA-N 0.000 claims description 2
- PPQRFOFHENJYMN-UHFFFAOYSA-N 3-(2,6-dimethylphenyl)pyrrole-2,5-dione Chemical compound CC1=CC=CC(C)=C1C1=CC(=O)NC1=O PPQRFOFHENJYMN-UHFFFAOYSA-N 0.000 claims description 2
- MOSSLXZUUKTULI-UHFFFAOYSA-N 3-[3-(2,5-dioxopyrrol-3-yl)-4-methylphenyl]pyrrole-2,5-dione Chemical compound CC1=CC=C(C=2C(NC(=O)C=2)=O)C=C1C1=CC(=O)NC1=O MOSSLXZUUKTULI-UHFFFAOYSA-N 0.000 claims description 2
- 229910052582 BN Inorganic materials 0.000 claims description 2
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 claims description 2
- YUWBVKYVJWNVLE-UHFFFAOYSA-N [N].[P] Chemical compound [N].[P] YUWBVKYVJWNVLE-UHFFFAOYSA-N 0.000 claims description 2
- 125000002777 acetyl group Chemical group [H]C([H])([H])C(*)=O 0.000 claims description 2
- 125000001931 aliphatic group Chemical group 0.000 claims description 2
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 2
- JRPBQTZRNDNNOP-UHFFFAOYSA-N barium titanate Chemical compound [Ba+2].[Ba+2].[O-][Ti]([O-])([O-])[O-] JRPBQTZRNDNNOP-UHFFFAOYSA-N 0.000 claims description 2
- 229910002113 barium titanate Inorganic materials 0.000 claims description 2
- 239000004841 bisphenol A epoxy resin Substances 0.000 claims description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 2
- 239000000378 calcium silicate Substances 0.000 claims description 2
- 229910052918 calcium silicate Inorganic materials 0.000 claims description 2
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 claims description 2
- PMHQVHHXPFUNSP-UHFFFAOYSA-M copper(1+);methylsulfanylmethane;bromide Chemical compound Br[Cu].CSC PMHQVHHXPFUNSP-UHFFFAOYSA-M 0.000 claims description 2
- 229910002026 crystalline silica Inorganic materials 0.000 claims description 2
- 150000004677 hydrates Chemical class 0.000 claims description 2
- 150000004706 metal oxides Chemical class 0.000 claims description 2
- 239000010445 mica Substances 0.000 claims description 2
- 229910052618 mica group Inorganic materials 0.000 claims description 2
- 229920001568 phenolic resin Polymers 0.000 claims description 2
- 239000005011 phenolic resin Substances 0.000 claims description 2
- NAKOELLGRBLZOF-UHFFFAOYSA-N phenoxybenzene;pyrrole-2,5-dione Chemical compound O=C1NC(=O)C=C1.O=C1NC(=O)C=C1.C=1C=CC=CC=1OC1=CC=CC=C1 NAKOELLGRBLZOF-UHFFFAOYSA-N 0.000 claims description 2
- 239000000049 pigment Substances 0.000 claims description 2
- 150000003839 salts Chemical class 0.000 claims description 2
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims description 2
- 229910010271 silicon carbide Inorganic materials 0.000 claims description 2
- VEALVRVVWBQVSL-UHFFFAOYSA-N strontium titanate Chemical compound [Sr+2].[O-][Ti]([O-])=O VEALVRVVWBQVSL-UHFFFAOYSA-N 0.000 claims description 2
- 239000000126 substance Substances 0.000 claims description 2
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- 229910052623 talc Inorganic materials 0.000 claims description 2
- 239000012745 toughening agent Substances 0.000 claims description 2
- RERMPCBBVZEPBS-UHFFFAOYSA-N tris(2,6-dimethylphenyl)phosphane Chemical group CC1=CC=CC(C)=C1P(C=1C(=CC=CC=1C)C)C1=C(C)C=CC=C1C RERMPCBBVZEPBS-UHFFFAOYSA-N 0.000 claims description 2
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 claims description 2
- QWVGKYWNOKOFNN-UHFFFAOYSA-N o-cresol Chemical compound CC1=CC=CC=C1O QWVGKYWNOKOFNN-UHFFFAOYSA-N 0.000 claims 2
- IPJGAEWUPXWFPL-UHFFFAOYSA-N 1-[3-(2,5-dioxopyrrol-1-yl)phenyl]pyrrole-2,5-dione Chemical compound O=C1C=CC(=O)N1C1=CC=CC(N2C(C=CC2=O)=O)=C1 IPJGAEWUPXWFPL-UHFFFAOYSA-N 0.000 claims 1
- IYMZEPRSPLASMS-UHFFFAOYSA-N 3-phenylpyrrole-2,5-dione Chemical compound O=C1NC(=O)C(C=2C=CC=CC=2)=C1 IYMZEPRSPLASMS-UHFFFAOYSA-N 0.000 claims 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims 1
- 230000001568 sexual effect Effects 0.000 claims 1
- 239000003607 modifier Substances 0.000 abstract description 3
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 16
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 12
- 230000000052 comparative effect Effects 0.000 description 11
- 239000004744 fabric Substances 0.000 description 10
- 229910052802 copper Inorganic materials 0.000 description 9
- 239000010949 copper Substances 0.000 description 9
- 238000002360 preparation method Methods 0.000 description 9
- 238000000034 method Methods 0.000 description 8
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 6
- 239000004593 Epoxy Substances 0.000 description 5
- 239000006087 Silane Coupling Agent Substances 0.000 description 5
- PYSRRFNXTXNWCD-UHFFFAOYSA-N 3-(2-phenylethenyl)furan-2,5-dione Chemical compound O=C1OC(=O)C(C=CC=2C=CC=CC=2)=C1 PYSRRFNXTXNWCD-UHFFFAOYSA-N 0.000 description 4
- 229920000147 Styrene maleic anhydride Polymers 0.000 description 4
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 4
- 239000011521 glass Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 150000003923 2,5-pyrrolediones Chemical class 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
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- 238000000926 separation method Methods 0.000 description 3
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- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 description 2
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- 239000004215 Carbon black (E152) Substances 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/14—Layered products comprising a layer of metal next to a fibrous or filamentary layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/20—Layered products comprising a layer of metal comprising aluminium or copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/02—Layered products essentially comprising sheet glass, or glass, slag, or like fibres in the form of fibres or filaments
- B32B17/04—Layered products essentially comprising sheet glass, or glass, slag, or like fibres in the form of fibres or filaments bonded with or embedded in a plastic substance
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/067—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of fibres or filaments
-
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Definitions
- the invention belongs to the technical field of thermosetting resin compositions, and relates to a thermosetting resin composition and prepregs, laminates and high-frequency circuit substrates comprising the same.
- the application frequency continues to increase, in addition to higher requirements for the heat resistance of laminate materials, the dielectric constant and dielectric loss values are required to be lower and lower, so Reducing Dk/Df has become a hot spot for substrate manufacturers.
- the insulating resin layer containing no glass fiber tends to have a large thermal expansion coefficient, so the difference in thermal expansion coefficient with that of copper filled and stacked via holes greatly affects the reliability of connection. Therefore, a material with a small thermal expansion coefficient is required for the insulating resin layer.
- Resin prepregs are often used as substrate materials in printed circuit boards.
- the substrate materials need to have low dielectric constant and dielectric loss tangent to be suitable for high-frequency operating signals. Considering the requirements of circuit board processing and use, the substrate material needs to have good heat resistance.
- resin prepregs have been prepared using maleimide-containing compounds.
- Styrene-maleic anhydride (SMA) is used as a curing agent to achieve good dielectric properties, and at the same time, when used with a maleimide compound, it can promote the curing of the maleimide compound.
- SMA will reduce the peel strength of resin prepreg and metal foil, and at the same time lead to the disadvantages of increased substrate water absorption, increased brittleness, and increased coefficient of thermal expansion (CTE).
- the object of the present invention is to provide a thermosetting resin composition and a prepreg, a laminate and a high frequency circuit substrate containing the same.
- the laminate and circuit substrate obtained from the thermosetting resin composition provided by the present invention have excellent dielectric properties, lower water absorption, better heat resistance, good processability, and have high Tg, low CTE and other properties.
- thermosetting resin composition which, in parts by weight of solid components, comprises the following components:
- maleic anhydride modified material contains polybutadiene, hydrogenated polybutadiene, polybutadiene-styrene copolymer, or hydrogenated polybutadiene-styrene copolymer segment.
- a maleic anhydride-modified compound containing a segment of polybutadiene, hydrogenated polybutadiene, polybutadiene-styrene copolymer, or hydrogenated polybutadiene-styrene copolymer is used to compound active Ester, epoxy resin and maleimide compound, so that the provided thermosetting resin composition can effectively reduce CTE, and has excellent dielectric properties, lower water absorption rate, and better heat resistance.
- the epoxy resin (A) is selected from dicyclopentadiene epoxy resin, phosphorus-containing epoxy resin, MDI modified epoxy resin, biphenyl epoxy resin, bisphenol A epoxy resin, Any one or a combination of at least two of phenol-type novolac epoxy resin, o-cresol-type epoxy resin or epoxidized polybutadiene.
- the content of the epoxy resin is 1 part by weight, 3 parts by weight, 5 parts by weight, 8 parts by weight, 10 parts by weight, 13 parts by weight, 15 parts by weight, 18 parts by weight, 20 parts by weight parts by weight, 23 parts by weight, 25 parts by weight, 28 parts by weight, 30 parts by weight, 33 parts by weight, 35 parts by weight, 38 parts by weight, or 40 parts by weight.
- the maleic anhydride modified product is preferably maleic anhydride modified polybutadiene-styrene copolymer and/or maleic anhydride modified polybutadiene.
- the number average molecular weight of the maleic anhydride modified product is independently 1,000-10,000, such as 1,000, 2,000, 3,000, 5,000, 8,000, 10,000, etc., preferably 1,000-8,000, more preferably 1,000-7,500. If the molecular weight is too small, it is easy to cause the flow glue to be too large, and the compatibility with other resins is poor. If the molecular weight is too large, the fluidity is affected.
- the number of maleic anhydride contained in each molecule of the maleic anhydride modified product is independently 1 to 30, such as 1, 2, 3, 5, 8, 10, 12, 15, 18, 20, 22 , 25, 28, or 30, etc., preferably 1-20, more preferably 1-15.
- the content of vinyl groups at positions 1 and 2 contained in each molecule of the maleic anhydride modification is independently 0 to 70%, such as 3%, 5%, 8%, 10%, 15%, 20% , 25%, 30%, 35%, 40%, 45%, 50%, 55%, 60%, 65% or 70%, etc., preferably 15-60%, more preferably 15-50%. Too low vinyl content at 1,2 position has a negative impact on CTE, and too high vinyl content at position 1,2 leads to incomplete reaction and affects the stability of the product for multiple laminations.
- the maleimide compound is a compound, monomer, mixture, oligomer, polymer or prepolymer having one or more maleimide functional groups in the molecule.
- the maleimide compound used in the present invention is not particularly limited, and can be any one or more suitable for prepreg, copper foil-attached prepreg, resin film, copper foil-attached resin film, product Maleimide compounds made from laminates or printed circuit boards.
- Specific examples include, but are not limited to, 4,4'-diphenylmethanebismaleimide, phenylmethanemaleimide oligomer or polyphenylmethanemaleimide, m-phenylene bismaleimide Imide, bisphenol A diphenyl ether bismaleimide, 3,3'-dimethyl-5,5'-diethyl-4,4'-diphenylmethane bismaleimide Amine, 4-methyl-1,3-phenylene bismaleimide, 1,6-bismaleimide-(2,2,4-trimethyl)hexane, 2,3- Dimethylbenzenemaleimide, 2,6-dimethylbenzenemaleimide, N-phenylmaleimide, containing C1-C10 (such as C1, C2, C3, C4, C5, C6, C7, C8, C9 or C10) maleimide compounds with aliphatic chain structure and any one or a combination of at least two of the prepolymers of the above compounds.
- the prepolymer can be, for example, a prepolymer of a diallyl compound and a maleimide compound, a prepolymer of a diamine and a maleimide compound, a trifunctional or higher amine and a maleimide Prepolymers of amine compounds or prepolymers of acidic phenolic compounds and maleimide compounds, etc.
- the active ester structural formula is selected from one or more of the following formulas:
- X is phenyl or naphthyl, j is 0 or 1, k is 0 or 1, and n represents a repeating unit ranging from 0.25 to 1.25;
- n, and q are independently an integer from 1 to 6 (eg, 1, 2, 3, 4, 5, or 6).
- X is phenyl or naphthyl
- Y is a group represented by the following formula:
- n is an integer from 2 to 15 (eg, 3, 4, 5, 6, 7, 8, 9, 10, 12, 15, etc.), and Ac represents an acetyl group.
- the use of phosphorus-containing active ester can achieve the effect of halogen-free flame retardant.
- the molar ratio of the maleic anhydride modified product to the active ester is 1:0.02-1:50, such as 1:0.02, 1:0.05, 1:0.1, 1:0.5, 1:1, 1:3 , 1:5, 1:8, 1:10, 1:15, 1:20, 1:25, 1:30, 1:35, 1:40, 1:45 or 1:50, etc., preferably 1:0.05 -1:20.
- maleic anhydride modified product BMI and active ester act synergistically to improve the dielectric properties of the composition. Due to the large difference in polarity between active ester and BMI, the compatibility between the two is poor, and maleic anhydride has poor compatibility.
- the modified compound has a hydrocarbon segment with a lower polar group and a maleic anhydride with a higher polar group, which can improve the compatibility of the active ester and BMI, and the interaction of the three can achieve excellent electrical properties under a certain ratio. Balance of properties such as performance, CTE and heat resistance.
- thermosetting resin composition a maleic anhydride modified product and an epoxy resin are formed into a prepolymer, or a maleic anhydride modified product and a maleimide compound are formed into a prepolymer, or a maleic anhydride modified product is formed into a prepolymer.
- Anhydride modification, epoxy resin and maleimide compound form a prepolymer.
- the prepared plate can have a more uniform secondary appearance and better heat resistance.
- halogen-free flame retardants can also be added according to flame retardant requirements;
- the halogen-free flame retardant is selected from tris(2,6-dimethylphenyl)phosphine, 10-(2,5-dihydroxyphenyl)-9,10-dihydro-9-oxa -10-Phosphinophenanthrene-10-oxide, 2,6-bis(2,6-dimethylphenyl)phosphinobenzene, 10-phenyl-9,10-dihydro-9-oxa-10- Any one or a combination of at least two of phosphine-10-oxide, phenoxyphosphazene compound, zinc borate, nitrogen-phosphorus intumescent flame retardant, phosphoric anhydride or phosphorus-containing phenolic resin.
- thermosetting resin composition further includes fillers.
- the filler is added in an amount of 5-150 parts by weight, for example 5 parts by weight, 8 parts by weight, 10 parts by weight, 15 parts by weight, 20 parts by weight, 30 parts by weight, 50 parts by weight, 80 parts by weight, 100 parts by weight, 120 parts by weight, 140 parts by weight, 150 parts by weight, etc., more preferably 50-120 parts by weight parts by weight, more preferably 70-100 parts by weight.
- the filler is selected from any one or a combination of at least two of non-metal oxides, metal nitrides, non-metal nitrides, inorganic hydrates, inorganic salts or inorganic phosphorus, more preferably fused silica, Crystalline silica, spherical silica, angular silica, hollow silica, aluminum hydroxide, alumina, talc, aluminum nitride, boron nitride, silicon carbide, barium sulfate, barium titanate, Any one or a combination of at least two of strontium titanate, calcium carbonate, calcium silicate or mica.
- the median particle size of the filler D50 2-5 ⁇ m (eg 2 ⁇ m, 2.3 ⁇ m, 2.5 ⁇ m, 2.8 ⁇ m, 3 ⁇ m, 3.5 ⁇ m, 3.8 ⁇ m, 4 ⁇ m, 4.3 ⁇ m, 4.5 ⁇ m, 4.8 ⁇ m or 5 ⁇ m)
- the maximum particle size D100 5-8 ⁇ m (eg 5 ⁇ m, 5.5 ⁇ m, 5.8 ⁇ m, 6 ⁇ m, 6.3 ⁇ m, 6.5 ⁇ m, 6.8 ⁇ m, 7 ⁇ m, 7.5 ⁇ m, 7.8 ⁇ m or 8 ⁇ m)
- the particle size adopts Malvern 2000 laser particle size analysis instrument test.
- fillers with a specific particle size range are preferred, which can further improve the heat resistance of the composition and the prepared laminates. Moreover, the fillers in the above particle size range are used in the resin system of the present invention, even if the amount of filler added Higher (for example, 150 parts), there will be no separation from the resin.
- thermosetting resin composition a curing accelerator, a toughening agent, a pigment, etc. may be added to the thermosetting resin composition.
- the present invention provides a resin glue solution obtained by dissolving or dispersing the thermosetting resin composition according to the first aspect in a solvent.
- the conventional preparation method of the resin glue solution of the present invention is as follows: firstly put the solid matter, then add the liquid solvent, stir until the solid matter is completely dissolved, then add the liquid resin and the accelerator, and continue to stir evenly.
- the solvent in the present invention is not particularly limited, and alcohols such as methanol, ethanol, butanol, ethyl cellosolve, butyl cellosolve, ethylene glycol methyl ether, carbitol, butyl carbitol, etc. can be selected. , acetone, methyl ethyl ketone, methyl ethyl ketone, cyclohexanone and other ketones, toluene, xylene and other aromatic hydrocarbons, ethyl acetate, ethoxyethyl acetate and other esters, N,N-diol Nitrogen-containing solvents such as methylformamide and N,N-dimethylacetamide.
- alcohols such as methanol, ethanol, butanol, ethyl cellosolve, butyl cellosolve, ethylene glycol methyl ether, carbitol, butyl carbitol, etc.
- acetone
- the above solvents may be used alone or in combination of two or more. Ketones such as acetone, butanone, methyl ethyl ketone, and cyclohexanone are preferred.
- the addition amount of the solvent can be selected by those skilled in the art according to their own experience, so that the resin glue can reach a suitable viscosity for use.
- the present invention provides a prepreg, the prepreg comprising a reinforcing material and the thermosetting resin composition according to the first aspect adhered thereon after being impregnated and dried.
- the reinforcing material can be organic fiber cloth, inorganic fiber woven cloth or non-woven fabric; wherein, the organic fiber is aramid non-woven fabric; the inorganic fiber woven cloth is E-glass fiber cloth, D-glass cloth, S-glass cloth, T-glass cloth, NE-glass cloth or quartz cloth.
- the thickness of the reinforcing material is 0.01-0.2mm, such as 0.02mm, 0.05mm, 0.08mm, 0.1mm, 0.12mm, 0.15mm, 0.18mm, and the like.
- the reinforcing material preferably undergoes fiber opening treatment and silane coupling agent surface treatment; the silane coupling agent is any one of epoxy silane coupling agent, amino silane coupling agent or vinyl silane coupling agent or a mixture of at least two.
- the preparation method of the prepreg is as follows: impregnating the above-mentioned thermosetting resin composition with a reinforcing material, and then baking at 100-250° C. for 1-15 minutes to obtain the prepreg.
- the present invention provides a high-frequency circuit substrate, the high-frequency circuit substrate comprising at least one sheet of the prepreg as described in the third aspect and one or both sides of the laminated prepreg metal foil.
- the metal foil is copper foil, nickel foil, aluminum foil, SUS foil, or the like.
- the present invention provides a printed circuit board containing at least one of the above-mentioned prepreg or the above-mentioned high-frequency circuit substrate.
- the present invention has the following beneficial effects:
- epoxy resin, maleimide compound, maleic anhydride modified product and active ester are used to form a thermosetting resin composition, so as to ensure that the resin composition has a higher Tg, excellent resistance to humidity and heat At the same time, the dielectric properties of the resin composition are effectively improved; and the prepreg and printed circuit laminates have excellent properties and excellent machinability.
- the prepreg and laminate made of the resin composition have excellent dielectric properties, high heat resistance, low CTE and can achieve flame retardancy up to UL94V-0 level.
- A-1 Biphenyl type novolac epoxy resin NC-3000H (trade name of Nippon Kayaku, EEW: 288g/eq);
- A-2 Dicyclopentadiene epoxy resin DNE260A75 (trade name in Changchun, Taiwan, EEW: 265g/eq);
- Ricon 131A20 maleic anhydride modified polybutadiene, purchased from Cray Valley
- B-2Ricon 184A6 maleic anhydride modified polybutadiene-styrene copolymer, available from Cray Valley
- C-2 D937 low dielectric maleimide (Sichuan Dongcai Technology);
- E1 contains phosphoric anhydride XQR-7119 (olin trade name))
- thermosetting resin composition is prepared according to the components shown in Table 1. If prepolymerization is required, the prepolymerization method described above is used to prepare a glue solution. And make laminate samples according to the following laminate production methods:
- thermosetting resin composition was prepared according to the components shown in Table 2, and the laminate samples were prepared according to the manufacturing method of the laminate described in the Examples.
- Dielectric constant (Dk) and dielectric loss factor (Df) According to the resonance method using strip line, according to the method of IPC-TM-650 2.5.5.5, measure the dielectric loss and dielectric loss factor at 1GHz ;
- Laminates were measured according to method 2.4.24 of IPC-TM-650.
- T300 (with copper): refer to IPC-TM-650 2.4.24.1, and test with copper foil at a temperature of 300°C.
- Plate uniformity Slice the plate in the vertical direction, and observe the filler of the plate, the compatibility and separation of the resin under a scanning electron microscope.
- the copper clad laminate finally obtained by using the resin composition provided by the present invention has excellent dielectric properties, ultra-high T g , high heat resistance, low CTE and can achieve flame retardancy reaching UL94V-0 level. .
- Example 1 Comparing Example 1 with Example 9, Example 10, and Example 11, it can be concluded that better uniformity of the board can be achieved by an appropriate prepolymerization method, so that the comprehensive performance of the board is better.
- Example 1 From the comparison of Example 1 and Comparative Example 1, it can be concluded that using maleic anhydride-modified polybutadiene-styrene copolymer or maleic anhydride-modified polybutadiene, compared to using common acid anhydride curing agent, can achieve better performance. Low CTE, higher Tg, and better heat resistance, etc., make the overall performance of the sheet better.
- Examples 3-6 show that each component, in the case of a certain range of dosage, the replacement combination of specific types of epoxy and maleimide can obtain PS, CTE, electrical properties, dispersibility and other comprehensive properties. copper clad laminate.
- Example 7 illustrates that the electrical properties of the system can be tuned by introducing functional fillers.
- Example 8 shows that the system can achieve higher filler filling, the filler addition amount increases, the CTE of the sheet decreases significantly, and other properties remain relatively good, and this solution can be applied to application scenarios with high CTE requirements.
- Example 5 and Example 6 show that the amount of maleic anhydride modified compound and maleimide compound should be within a certain range.
- the uniformity, heat resistance, CTE and Tg have negative effects.
- the amount of maleimide compound needs to be controlled within a certain range, otherwise it will also have a negative effect on heat resistance and plate uniformity.
- Example 1 shows that the use of active ester and maleic anhydride-containing modifier can improve the PS, heat resistance and electrical properties of the system, and at the same time, the appearance of the P sheet can be reduced to the next level.
- the appearance has been significantly improved, and the resin filler separation has a greater impact.
- the resin composition of the present invention not only requires the matching of epoxy resin, maleic anhydride modified maleimide and active ester, but also needs to satisfy the matching ratio of each component in order to obtain a copper clad laminate with excellent performance .
- a specific prepolymerization reaction method is also adopted, which greatly improves the uniformity and heat resistance of the board, and improves the comprehensiveness of the board.
- the present invention is to illustrate the thermosetting resin composition of the present invention and the prepreg, laminate and high-frequency circuit substrate comprising the same by the above-mentioned embodiments, but the present invention is not limited to the above-mentioned embodiments, that is, it does not mean that The present invention must rely on the above-described embodiments to be implemented.
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Abstract
一种热固性树脂组合物及包含其的树脂胶液、预浸料、高频电路基板和印刷电路板,所述热固性树脂组合物以固体组分重量份计,包括如下组分:(A)环氧树脂:1-40重量份;(B)马来酸酐改性物:1-40重量份;(C)马来酰亚胺化合物:30-80重量份;(D)活性酯:1-40重量份,其中所述马来酸酐改性物中含聚丁二烯或氢化聚丁二烯链段。所述热固性树脂组合物在保证树脂组合物具有较高Tg,优良耐湿热性的同时,有效提升了树脂组合物的介电性能。
Description
本发明属于热固性树脂组合物技术领域,涉及一种热固性树脂组合物及包含其的预浸料、层压板和高频电路基板。
随着电子产品信息处理的高速化和多功能化,应用频率不断提高,除了对层压板材料的耐热性有更高的要求外,要求介电常数和介电损耗值越来越低,因此降低Dk/Df已成为基板业者的追逐热点。
由于多层印刷布线板的薄型化,不含玻璃纤维的绝缘树脂层显示出热膨胀率大的倾向,所以与填充化、堆叠化了通孔的铜的热膨胀率之差对连接的可靠性产生大大影响,所以绝缘树脂层中要求热膨胀率小的材料。
树脂预浸料常在印刷线路板中作为基板材料,基板材料需要有较低的介电常数和介质损耗角正切,以适用于高频操作信号。考虑到线路板加工及使用的要求,基板材料需要有良好的耐热性。为此,已经使用含马来酰亚胺化合物制备树脂预浸料。其中使用苯乙烯-马来酸酐(SMA)作为固化剂,以实现良好的介电性能,同时在与马来酰亚胺化合物使用时可以促进马来酰亚胺化合物的固化。然而,SMA会降低树脂预浸料与金属箔的剥离强度,同时导致基板吸水率升高、脆性变大、热膨胀率(CTE)升高的缺点。
因此,在本领域中,期望开发一种能够在降低热膨胀率的同时保证树脂组合物具有较高Tg、优良耐湿热性、很好的韧性以及良好的介电性能的基板材料。
发明内容
针对现有技术的不足,本发明的目的在于提供一种热固性树脂组合物及包 含其的预浸料、层压板和高频电路基板。由本发明提供的热固性树脂组合物得到的层压板以及电路基板具有优异的介电性能、较低吸水率、更好的耐热性和良好的工艺加工性,具有高Tg、低CTE等性能。
为达此目的,本发明采用以下技术方案:
一方面,本发明提供一种热固性树脂组合物,所述组合物以固体组分重量份计,包括如下组分:
(A)环氧树脂:1-40重量份;
(B)马来酸酐改性物:1-40重量份;
(C)马来酰亚胺化合物:30-80重量份;
(D)活性酯:1-40重量份;
其中所述马来酸酐改性物中含聚丁二烯、氢化聚丁二烯、聚丁二烯-苯乙烯共聚物、或氢化聚丁二烯-苯乙烯共聚物链段。
在本发明中,利用含聚丁二烯、氢化聚丁二烯、聚丁二烯-苯乙烯共聚物、或氢化聚丁二烯-苯乙烯共聚物链段的马来酸酐改性物配合活性酯以及环氧树脂、马来酰亚胺化合物,使得提供的热固性树脂组合物可以有效地降低CTE,具有优异的介电性能、较低吸水率、更好的耐热性。
在本发明中,所述环氧树脂(A)选自双环戊二烯环氧树脂、含磷环氧树脂、MDI改性环氧树脂、联苯环氧树脂、双酚A型环氧树脂、苯酚型酚醛环氧树脂、邻甲酚醛型环氧树脂或环氧化聚丁二烯中的任意一种或至少两种的组合。
优选地,所述热固性树脂组合物中,环氧树脂的含量为1重量份、3重量份、5重量份、8重量份、10重量份、13重量份、15重量份、18重量份、20重量份、23重量份、25重量份、28重量份、30重量份、33重量份、35重量份、38重量份或40重量份。
在本发明中,所述的马来酸酐改性物优选马来酸酐改性的聚丁二烯-苯乙烯共聚物和/或马来酸酐改性的聚丁二烯。
优选地,所述马来酸酐改性物的数均分子量独立地为1000~10000,例如1000、2000、3000、5000、8000、10000等,优选1000~8000,进一步优选为1000~7500。分子量太小容易导致流胶过大,与其它树脂相容性差,分子量太大影响流动性。
优选地,所述马来酸酐改性物的每个分子所含马来酸酐数目独立地为1~30,例如1、2、3、5、8、10、12、15、18、20、22、25、28或30等,优选1~20,进一步优选为1~15。
优选地,所述马来酸酐改性物中每个分子所含1,2位乙烯基含量独立地为0~70%,例如3%、5%、8%、10%、15%、20%、25%、30%、35%、40%、45%、50%、55%、60%、65%或70%等,优选15~60%,进一步优选为15~50%。太低的1,2位乙烯基含量对CTE有负面影响,过高的1,2位乙烯基含量导致反应不完全,影响产品多次压合稳定性。
在本发明中,所述马来酰亚胺化合物为分子中具有1个以上马来酰亚胺官能团的化合物、单体、混合物、低聚物、聚合物或预聚物。若未特别指明,本发明采用的马来酰亚胺化合物并不特别限制,且可为任一种或多种适用于半固化片、附铜箔的半固化片、树脂膜、附铜箔的树脂膜、积层板或印刷电路板制作的马来酰亚胺化合物。具体实例包括但不限于4,4'-二苯甲烷双马来酰亚胺、苯甲烷马来酰亚胺寡聚物或称聚苯甲烷马来酰亚胺、间-伸苯基双马来酰亚胺、双酚A二苯基醚双马来酰亚胺、3,3'-二甲基-5,5'-二乙基-4,4'-二苯基甲烷双马来酰亚胺、4-甲基-1,3-伸苯基双马来酰亚胺、1,6-双马来酰亚胺-(2,2,4-三甲基)己烷、2,3-二甲基苯马来酰亚胺、2,6-二甲基苯马来酰亚胺、N-苯基马来酰亚胺、含 C1-C10(例如C1、C2、C3、C4、C5、C6、C7、C8、C9或C10)脂肪链结构的马来酰亚胺类化合物和上述化合物的预聚物中的任意一种或至少两种的组合。其中,预聚物例如可为二烯丙基化合物与马来酰亚胺类化合物的预聚物、二胺与马来酰亚胺类化合物的预聚物、三官能以上胺与马来酰亚胺类化合物的预聚物或酸性酚化合物与马来酰亚胺类化合物的预聚物等。
在本发明中,所述活性酯结构式选自下式的一种或多种:
其中X为苯基或者萘基,j为0或1,k为0或1,n表示重复单元为0.25~1.25;
或,
其中,m、n、q独立地为1-6的整数(例如1、2、3、4、5或6)。X为苯基或者萘基,
Y为下述式所示的基团:
其中K为0或1;
其中n为2-15的整数(例如3、4、5、6、7、8、9、10、12、15等),Ac表示乙酰基。
在本发明中,使用含磷活性酯可以达到无卤阻燃的效果。
优选地,所述马来酸酐改性物与活性酯的摩尔比为1:0.02-1:50,例如1:0.02、1:0.05、1:0.1、1:0.5、1:1、1:3、1:5、1:8、1:10、1:15、1:20、1:25、1:30、1:35、1:40、1:45或1:50等,优选1:0.05-1:20。
在本发明中,马来酸酐改性物、BMI与活性酯协同作用,提升组合物的介电性能,由于活性酯与BMI的极性相差较大导致两者相容性较差,马来酸酐改性物具有极性基团较低的碳氢段和极性较大的基团马来酸酐,可以提升活性酯和BMI的相容性,三者相互作用在一定比例下可以实现优异的电性能,CTE和耐热性等性能的平衡。
优选地,所述热固性树脂组合物中,使马来酸酐改性物与环氧树脂形成预聚物,或者使马来酸酐改性物与马来酰亚胺化合物形成预聚物或者使马来酸酐改性物、环氧树脂与马来酰亚胺化合物形成预聚物。
在本发明中,利用如上所述成分形成预聚物后进行使用,可以使得制备出的板材次表观更均匀,耐热性更优异。
在本发明中,根据阻燃需要,还可以添加无卤阻燃剂;
优选地,所述无卤阻燃剂选自三(2,6-二甲基苯基)膦、10-(2,5-二羟基苯基)-9,10-二氢-9-氧杂-10-膦菲-10-氧化物、2,6-二(2,6-二甲基苯基)膦基苯、10-苯基-9,10-二氢-9-氧杂-10-膦菲-10-氧化物、苯氧基膦腈化合物、硼酸锌、氮磷系膨胀型阻燃剂、含磷酸酐或含磷酚醛树脂中的任意一种或至少两种的组合。
优选地,所述热固性树脂组合物中还包括填料。
优选地,以环氧树脂、马来酸酐改性物、马来酰亚胺化合物和活性酯的总重量为100重量份、所述填料的添加量为5-150重量份,例如5重量份、8重量份、10重量份、15重量份、20重量份、30重量份、50重量份、80重量份、100重量份、120重量份、140重量份、150重量份等,进一步优选50-120重量份,更进一步优选70-100重量份。
优选地,所述填料选自非金属氧化物、金属氮化物、非金属氮化物、无机水合物、无机盐或无机磷中的任意一种或者至少两种的组合,进一步优选熔融二氧化硅、结晶型二氧化硅、球型二氧化硅、角形二氧化硅、空心二氧化硅、氢氧化铝、氧化铝、滑石粉、氮化铝、氮化硼、碳化硅、硫酸钡、钛酸钡、钛酸锶、碳酸钙、硅酸钙或云母中的任意一种或至少两种的组合。
优选地,所述填料的中位粒径D50=2-5μm(例如2μm、2.3μm、2.5μm、2.8μm、3μm、3.5μm、3.8μm、4μm、4.3μm、4.5μm、4.8μm或5μm),最大粒径D100=5-8μm(例如5μm、5.5μm、5.8μm、6μm、6.3μm、6.5μm、6.8μm、7μm、7.5μm、7.8μm或8μm),粒径采用马尔文2000激光粒度分析仪测试。本发明优选特定粒径范围的填料,能够进一步提高组合物及其制备得到的层压板的耐热性能,并且,将上述粒径范围的填料应用于本发明的树脂体系中,即使填料的添加量较高(例如150份),也不会出现与树脂分离的情况。
在本发明中,所述热固性树脂组合物还可以添加固化促进剂、增韧剂、颜料等。
第二方面,本发明提供了一种树脂胶液,所述树脂胶液是将如第一方面所述的热固性树脂组合物溶解或分散在溶剂中得到。
本发明的树脂胶液常规制备方法为:先将固形物放入,然后加入液态溶剂,搅拌至固形物完全溶解后,再加入液态树脂和促进剂,继续搅拌均匀即可。
作为本发明中的溶剂,没有特别的限定,可以选用甲醇、乙醇、丁醇等醇类,乙基溶纤剂、丁基溶纤剂、乙二醇甲醚、卡必醇、丁基卡必醇等,丙酮、丁酮、甲基乙基甲酮、环己酮等酮类,甲苯、二甲苯等芳香烃类,醋酸乙酯、乙氧基乙基乙酸酯等酯类,N,N-二甲基甲酰胺、N,N-二甲基乙酰胺等含氮类溶剂。以上溶剂可单独使用,也可两种或两种以上混合使用。优选丙酮、丁酮、甲基乙基甲酮、环己酮等酮类。所述溶剂的添加量由本领域技术人员根据自己经验来选择,使得树脂胶液达到适合使用的粘度即可。
第三方面,本发明提供了一种预浸料,所述预浸料包括增强材料及通过浸渍干燥后附着其上的如第一方面所述的热固性树脂组合物。
在本发明中,所述增强材料可以为有机纤维布、无机纤维编织布或无纺布;其中,所述有机纤维为芳纶无纺布;所述无机纤维编织布为E-玻纤布、D-玻纤布、S-玻纤布、T玻纤布、NE-玻纤布或石英布。所述增强材料的厚度为0.01-0.2mm,例如0.02mm、0.05mm、0.08mm、0.1mm、0.12mm、0.15mm、0.18mm等。且所述增强材料最好经过开纤处理及硅烷偶联剂表面处理;所述硅烷偶联剂为环氧硅烷偶联剂、氨基硅烷偶联剂或乙烯基硅烷偶联剂中的任意一种或至少两种的混合物。
优选地,所述预浸料的制备方法为:将增强材料含浸上述的热固性树脂组合物,然后在100-250℃条件下,烘烤1-15min得到所述预浸料。
第四方面,本发明提供了一种高频电路基板,所述高频电路基板含有至少一张如第三方面所述的预浸料以及覆于叠合后的预浸料一侧或两侧的金属箔。
优选地,所述金属箔为铜箔、镍箔、铝箔或SUS箔等。
第五方面,本发明提供了一种印制电路板,所述印制电路板含有至少一张如上所述的预浸料或如上所述的高频电路基板。
相对于现有技术,本发明具有以下有益效果:
(1)在本发明中,使用了环氧树脂、马来酰亚胺化合物、马来酸酐改性物以及活性酯一起组成热固性树脂组合物,在保证树脂组合物具有较高Tg,优良耐湿热性的同时,有效提升了树脂组合物的介电性能;并使预浸料、印制电路用层压板具有优异性能的同时具有优良的机械加工性能。
(2)使用该树脂组合物制成的预浸料、层压板具有优异的介电性能、高耐热性、低CTE并可以实现阻燃达到UL94V-0级。
下面通过具体实施方式来进一步说明本发明的技术方案。本领域技术人员应该明了,所述实施例仅仅是帮助理解本发明,不应视为对本发明的具体限制。
下述实施例和比较例所涉及的材料及牌号信息如下:
(A)环氧树脂
A-1:联苯型酚醛环氧树脂NC-3000H(日本化药商品名,EEW:288g/eq);
[根据细则91更正 19.08.2021]
A-2:双环戊二烯型环氧树脂DNE260A75(中国台湾长春商品名,EEW:265g/eq);
A-2:双环戊二烯型环氧树脂DNE260A75(中国台湾长春商品名,EEW:265g/eq);
(B)酸酐类固化剂
B-1:Ricon 131A20(马来酸酐改性的聚丁二烯,购自Cray Valley)
B-2Ricon 184A6(马来酸酐改性的聚丁二烯-苯乙烯共聚物,购自Cray Valley)
B-3:SMA EF40(苯乙烯/马来酸酐=4,SARTOMER公司制)
(C)马来酰亚胺
C-1:二(3-乙基-5-甲基-4-马来酰亚胺基苯基)甲烷“BMI-70”(日本KI株式会社);
C-2:D937低介电马来酰亚胺(四川东材科技);
(D)活性酯
D-1:含双环戊二烯型二苯酚结构的活性酯化合物HPC-8000-65T(由DIC提供)
D-2:含萘结构的活性酯HPC-8150(由DIC提供)
D-3:含磷活性酯(ICL商品名E15-152T)
(E)阻燃剂
E1含磷酸酐XQR-7119(olin商品名))
(F)促进剂
F-1:2-苯基咪唑(日本四国化成)
(G)填料
G-1:熔融二氧化硅A(D50=2μm最大粒径D100=5μm,纯度99%以上);
G-2:二氧化钛
实施例1-11
预聚体制备方法:
1、预聚体制备方法1
马来酸酐改性的聚丁二烯或马来酸酐改性的聚丁二烯-苯乙烯共聚物+环氧预聚体的制备:按照表1所示,将需要预聚的马来酸酐改性的聚丁二烯或马来酸酐改性的聚丁二烯-苯乙烯共聚物和环氧树脂混合,缓慢加热到90℃,保持90℃使树脂完全熔融,然后加热到130℃,加入以树脂重量计算0.03%的三苯基膦作为催化剂,反应2h,冷却加入MEK(丁酮)配制成75%固含量的树脂溶液。
2、预聚体制备方法2
马来酸酐改性的聚丁二烯或马来酸酐改性的聚丁二烯-苯乙烯共聚物+马来酰亚胺预聚体的制备:按照表1所示,将需要预聚的马来酸酐改性的聚丁二烯或马来酸酐改性的聚丁二烯-苯乙烯共聚物和马来酰亚胺混合,缓慢加热到150℃,保持150℃使树脂完全熔融,然后加热到190℃,反应2h,冷却加入MEK配制成75%固含量的树脂溶液。
3、预聚体制备方法3
马来酸酐改性的聚丁二烯或马来酸酐改性的聚丁二烯-苯乙烯共聚物+环氧+马来酰亚胺预聚体的制备:按照表1所示,将需要预聚的马来酸酐改性的聚丁二烯或马来酸酐改性的聚丁二烯-苯乙烯共聚物和环氧混合,缓慢加热到90℃,保持90℃使树脂完全熔融,然后加热到130℃,反应2h。然后加入马来酰亚胺混合,缓慢加热到150℃,保持150℃使树脂完全熔融,然后加热到170℃,反应1h,冷却加入MEK配制成75%固含量的树脂溶液。
按表1所示组分配制热固性树脂组合物,如需预聚采用以上描述方法进行预聚后,配制成胶液。并按照如下层压板的制作方法制作层压板样品:
[根据细则91更正 19.08.2021]
将配方量的各组分在溶剂中混合均匀,控制胶液固含量为65%,用2116玻纤布浸渍上述胶液,控制合适厚度,然后在145-175℃的烘箱中烘烤2-15min制成预浸料,然后数张预浸料叠在一起,在其上下两面叠上铜箔(以下实施例和 比较例子均采用1OZ的HTE铜,购自中国台湾长春),在固化温度为190-210℃,固化压力为30-60Kg/cm 2,固化时间为90-120min条件下制成覆铜板。
将配方量的各组分在溶剂中混合均匀,控制胶液固含量为65%,用2116玻纤布浸渍上述胶液,控制合适厚度,然后在145-175℃的烘箱中烘烤2-15min制成预浸料,然后数张预浸料叠在一起,在其上下两面叠上铜箔(以下实施例和 比较例子均采用1OZ的HTE铜,购自中国台湾长春),在固化温度为190-210℃,固化压力为30-60Kg/cm 2,固化时间为90-120min条件下制成覆铜板。
比较例1-6
按表2所示组分配制热固性树脂组合物,按照实施例中所述层压板的制作方法制作层压板样品。
表1
表2
性能测试
对实施例1-11和比较例1-5提供的层压板进行性能测试,测试方法如下:(1)玻璃化转变温度(Tg)
使用粘弹性测定装置(DMA:Rheometric公司制造的固体粘弹性测定装置RSAII、矩形拉伸(Rectangular Tension)法;频率1Hz、升温速度5℃/分钟),对积层板,测定弹性模量变化达到最大(tanδ变化率最大)温度,将其作为玻璃化转变温度进行评价。
(2)介电常数(Dk)和介电损耗因子(Df):根据使用条状线的共振法,按照IPC-TM-650 2.5.5.5的方法测定1GHz下的介电损耗、介电损耗因素;
(3)热膨胀系数(CTE)
按照IPC-TM-650 2.4.24方法,对积层板进行测定。
(4)T300(带铜):参照IPC-TM-650 2.4.24.1,采用带铜箔板材在温度300℃下测试。
(5)板材均匀性:将板材垂直方向打切片,在扫描电镜下观看板材的填料,树脂的相容性和分离情况。
(6)难燃烧性;按照UL 94标准方法进行。
对实施例1-11和比较例1-6提供的层压板的测试结果表3:
表3
由实施例和性能测试可知,利用本发明提供的树脂组合物最后得到的覆铜板具有优异的介电性能、超高T
g、高耐热性、低CTE并可以实现阻燃达到UL94V-0级。
实施例1与实施例9,实施例10,实施例11比较可以得出,通过适当的预聚方法,可以实现更好的板材均匀性,使得板材的综合性能更佳。
实施例1与比较例1比较可以得出,采用马来酸酐改性的聚丁二烯-苯乙烯共聚物或马来酸酐改性的聚丁二烯,对比采用普通酸酐固化剂,可以实现更低的CTE,更高的Tg,以及更好的耐热性等,使得板材的综合性能更佳。
实施例3-6表明各组分,在一定范围用量的情况下,特定种类的环氧和马来酰亚胺的替换组合,可以得到PS,CTE,电性能,分散性等综合性能较好的覆铜板。
实施例7说明可以通过引入功能性填料调节体系的电性能。
实施例8表明该体系可以实现较高的填料填充,填料添加量上升,板材的CTE明显下降,同时其它性能保持较好,该方案可以应用于对CTE要求较高的应用场景。
实施例5、实施例6与比较例2、比较例3比较,说明含马来酸酐改性物和马来酰亚胺化合物,用量应该在一定范围,过多的马来酸酐改性物对板材的均匀性,耐热性,CTE、Tg有负面作用,同样马来酰亚胺化合物的用量也需要控制在一定范围内,否则对耐热性和板材均匀性也有负面作用。
实施例1与比较例1和比较例4的比较说明,活性酯与含马来酸酐改性物,搭配使用可以改善体系PS,耐热性,电性能,同时可以使得P片表观已经次表观有明显改善,以及树脂填料分离性影响较大。
实施例1与比较例5比较可以说明添加了马来酸酐改性物可以提高体系的Tg,降低体系的CTE且电性能更加优异。
因此,本发明的树脂组合物不仅要求环氧树脂、马来酸酐改性物马来酰亚胺和活性酯的搭配,还要求满足各组分的配比,才能制得具有优异性能的覆铜板,对于本发明还采用特定的预聚反应方式,极大的提升板材的均匀性和耐热性,提升板材综合性。
申请人声明,本发明通过上述实施例来说明本发明的热固性树脂组合物及包含其的预浸料、层压板和高频电路基板,但本发明并不局限于上述实施例,即不意味着本发明必须依赖上述实施例才能实施。所属技术领域的技术人员应该明了,对本发明的任何改进,对本发明产品各原料的等效替换及辅助成分的添加、具体方式的选择等,均落在本发明的保护范围和公开范围之内。
Claims (10)
- 一种热固性树脂组合物,其特征在于,所述组合物以固体组分重量份计,包括如下组分:(A)环氧树脂:1-40重量份;(B)马来酸酐改性物:1-40重量份;(C)马来酰亚胺化合物:30-80重量份;(D)活性酯:1-40重量份;其中所述马来酸酐改性物中含聚丁二烯、氢化聚丁二烯、聚丁二烯-苯乙烯共聚物、或氢化聚丁二烯-苯乙烯共聚物链段。
- 根据权利要求1所述的热固性树脂组合物,其特征在于,所述环氧树脂选自双环戊二烯环氧树脂、含磷环氧树脂、MDI改性环氧树脂、联苯环氧树脂、双酚A型环氧树脂、苯酚型酚醛环氧树脂、邻甲酚酚醛型环氧树脂或环氧化聚丁二烯中的任意一种或至少两种的组合。
- 根据权利要求1或2所述的热固性树脂组合物,其特征在于,所述的马来酸酐改性物优选马来酸酐改性的聚丁二烯-苯乙烯共聚物和/或马来酸酐改性的聚丁二烯;优选地,所述马来酸酐改性物的数均分子量独立地为1000~10000,优选1000~8000,进一步优选为1000~7500;优选地,所述马来酸酐改性物的每个分子所含马来酸酐数目独立地为1~30,优选1~20,进一步优选为1~15;优选地,所述马来酸酐改性物中每个分子所含1,2位乙烯基质量比为1-70%,优选15~60%,进一步优选为15~50%。
- 根据权利要求1-3中任一项所述的热固性树脂组合物,其特征在于,所述马来酰亚胺化合物为4,4'-二苯甲烷双马来酰亚胺、苯甲烷马来酰亚胺寡聚物 或称聚苯甲烷马来酰亚胺、间-伸苯基双马来酰亚胺、双酚A二苯基醚双马来酰亚胺、3,3'-二甲基-5,5'-二乙基-4,4'-二苯基甲烷双马来酰亚胺、4-甲基-1,3-伸苯基双马来酰亚胺、1,6-双马来酰亚胺-(2,2,4-三甲基)己烷、2,3-二甲基苯马来酰亚胺、2,6-二甲基苯马来酰亚胺、N-苯基马来酰亚胺、含C1-C10脂肪链结构的马来酰亚胺类化合物和上述化合物的预聚物中的任意一种或至少两种的组合。
- 根据权利要求1-5中任一项所述的热固性树脂组合物,其特征在于,所述热固性树脂组合物中,使马来酸酐改性物与环氧树脂形成预聚物,或者使马来酸酐改性物与马来酰亚胺化合物形成预聚物或者使马来酸酐改性物、环氧树脂与马来酰亚胺化合物形成预聚物;优选地,所述热固性树脂组合物中还包括无卤阻燃剂;优选地,所述无卤阻燃剂选自三(2,6-二甲基苯基)膦、10-(2,5-二羟基苯基)-9,10-二氢-9-氧杂-10-膦菲-10-氧化物、2,6-二(2,6-二甲基苯基)膦基苯、10-苯基-9,10-二氢-9-氧杂-10-膦菲-10-氧化物、苯氧基膦腈化合物、硼酸锌、氮磷系膨胀型阻燃剂、含磷酸酐或含磷酚醛树脂中的任意一种或至少两种的组合;优选地,所述热固性树脂组合物中还包括填料;优选地,以环氧树脂、马来酸酐改性物、马来酰亚胺化合物和活性酯的总重量为100重量份,所述填料的添加量为5-150重量份,进一步优选50-120重量份,更进一步优选70-100重量份;优选地,所述填料选自非金属氧化物、金属氮化物、非金属氮化物、无机水合物、无机盐或无机磷中的任意一种或者至少两种的组合,进一步优选熔融二氧化硅、结晶型二氧化硅、球型二氧化硅、角形二氧化硅、空心二氧化硅、氢氧化铝、氧化铝、滑石粉、氮化铝、氮化硼、碳化硅、硫酸钡、钛酸钡、钛酸锶、碳酸钙、硅酸钙或云母中的任意一种或至少两种的组合;优选地,所述填料的中位粒径D50=2-5μm,最大粒径D100=5-8μm;优选地,所述热固性树脂组合物还包括固化促进剂、增韧剂或颜料中的任意一种或至少两种的组合。
- 一种树脂胶液,其特征在于,所述树脂胶液是将如权利要求1-6中任一项所述的热固性树脂组合物溶解或分散在溶剂中得到。
- 一种预浸料,其特征在于,所述预浸料包括增强材料及通过浸渍干燥后附着其上的如权利要求1-6中任一项所述的热固性树脂组合物。
- 一种高频电路基板,其特征在于,所述高频电路基板含有至少一张如权利要求8所述的预浸料以及覆于叠合后的预浸料一侧或两侧的金属箔。
- 一种印制电路板,其特征在于,所述印制电路板含有至少一张如权利要求8所述的预浸料或如权利要求9所述的高频电路基板。
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