JP2018502937A - ノンハロゲン樹脂組成物、及びそれを用いて製造されたプリプレグと積層板 - Google Patents
ノンハロゲン樹脂組成物、及びそれを用いて製造されたプリプレグと積層板 Download PDFInfo
- Publication number
- JP2018502937A JP2018502937A JP2017525534A JP2017525534A JP2018502937A JP 2018502937 A JP2018502937 A JP 2018502937A JP 2017525534 A JP2017525534 A JP 2017525534A JP 2017525534 A JP2017525534 A JP 2017525534A JP 2018502937 A JP2018502937 A JP 2018502937A
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- JP
- Japan
- Prior art keywords
- weight
- parts
- epoxy resin
- resin
- halogen
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229910052736 halogen Inorganic materials 0.000 title claims abstract description 37
- 239000011342 resin composition Substances 0.000 title claims abstract description 23
- 239000003822 epoxy resin Substances 0.000 claims abstract description 51
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 51
- CMLFRMDBDNHMRA-UHFFFAOYSA-N 2h-1,2-benzoxazine Chemical compound C1=CC=C2C=CNOC2=C1 CMLFRMDBDNHMRA-UHFFFAOYSA-N 0.000 claims abstract description 37
- 150000002367 halogens Chemical class 0.000 claims abstract description 33
- 239000003063 flame retardant Substances 0.000 claims abstract description 24
- PYSRRFNXTXNWCD-UHFFFAOYSA-N 3-(2-phenylethenyl)furan-2,5-dione Chemical compound O=C1OC(=O)C(C=CC=2C=CC=CC=2)=C1 PYSRRFNXTXNWCD-UHFFFAOYSA-N 0.000 claims abstract description 16
- 229920000147 Styrene maleic anhydride Polymers 0.000 claims abstract description 16
- 239000000945 filler Substances 0.000 claims abstract description 15
- 229920001955 polyphenylene ether Polymers 0.000 claims abstract description 13
- 229920005989 resin Polymers 0.000 claims description 23
- 239000011347 resin Substances 0.000 claims description 23
- 239000000203 mixture Substances 0.000 claims description 21
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 17
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 14
- 239000000463 material Substances 0.000 claims description 14
- 229910052698 phosphorus Inorganic materials 0.000 claims description 14
- 239000011574 phosphorus Substances 0.000 claims description 14
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 claims description 13
- 239000000126 substance Substances 0.000 claims description 13
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 claims description 11
- -1 phosphorous nitrogen compound Chemical class 0.000 claims description 10
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 9
- 125000001931 aliphatic group Chemical group 0.000 claims description 9
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 9
- IZSHZLKNFQAAKX-UHFFFAOYSA-N 5-cyclopenta-2,4-dien-1-ylcyclopenta-1,3-diene Chemical group C1=CC=CC1C1C=CC=C1 IZSHZLKNFQAAKX-UHFFFAOYSA-N 0.000 claims description 8
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 claims description 8
- 150000005130 benzoxazines Chemical class 0.000 claims description 6
- PXKLMJQFEQBVLD-UHFFFAOYSA-N bisphenol F Chemical compound C1=CC(O)=CC=C1CC1=CC=C(O)C=C1 PXKLMJQFEQBVLD-UHFFFAOYSA-N 0.000 claims description 6
- 239000011256 inorganic filler Substances 0.000 claims description 6
- 239000003365 glass fiber Substances 0.000 claims description 5
- 239000012766 organic filler Substances 0.000 claims description 5
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 4
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 claims description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 4
- 125000000217 alkyl group Chemical group 0.000 claims description 4
- 239000004305 biphenyl Substances 0.000 claims description 4
- 235000010290 biphenyl Nutrition 0.000 claims description 4
- 229910003475 inorganic filler Inorganic materials 0.000 claims description 4
- 229920003986 novolac Polymers 0.000 claims description 4
- 239000004843 novolac epoxy resin Substances 0.000 claims description 4
- QWVGKYWNOKOFNN-UHFFFAOYSA-N o-cresol Chemical compound CC1=CC=CC=C1O QWVGKYWNOKOFNN-UHFFFAOYSA-N 0.000 claims description 4
- 239000005011 phenolic resin Substances 0.000 claims description 4
- 239000000843 powder Substances 0.000 claims description 4
- 239000000377 silicon dioxide Substances 0.000 claims description 4
- 229920000877 Melamine resin Polymers 0.000 claims description 3
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims description 3
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims description 3
- 239000004810 polytetrafluoroethylene Substances 0.000 claims description 3
- BSYJHYLAMMJNRC-UHFFFAOYSA-N 2,4,4-trimethylpentan-2-ol Chemical compound CC(C)(C)CC(C)(C)O BSYJHYLAMMJNRC-UHFFFAOYSA-N 0.000 claims description 2
- LXBGSDVWAMZHDD-UHFFFAOYSA-N 2-methyl-1h-imidazole Chemical group CC1=NC=CN1 LXBGSDVWAMZHDD-UHFFFAOYSA-N 0.000 claims description 2
- ZCUJYXPAKHMBAZ-UHFFFAOYSA-N 2-phenyl-1h-imidazole Chemical group C1=CNC(C=2C=CC=CC=2)=N1 ZCUJYXPAKHMBAZ-UHFFFAOYSA-N 0.000 claims description 2
- LLEASVZEQBICSN-UHFFFAOYSA-N 2-undecyl-1h-imidazole Chemical group CCCCCCCCCCCC1=NC=CN1 LLEASVZEQBICSN-UHFFFAOYSA-N 0.000 claims description 2
- ULKLGIFJWFIQFF-UHFFFAOYSA-N 5K8XI641G3 Chemical group CCC1=NC=C(C)N1 ULKLGIFJWFIQFF-UHFFFAOYSA-N 0.000 claims description 2
- 239000005995 Aluminium silicate Substances 0.000 claims description 2
- 239000004114 Ammonium polyphosphate Substances 0.000 claims description 2
- 229910052582 BN Inorganic materials 0.000 claims description 2
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 claims description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 2
- 239000004695 Polyether sulfone Substances 0.000 claims description 2
- 239000004734 Polyphenylene sulfide Substances 0.000 claims description 2
- 229910052581 Si3N4 Inorganic materials 0.000 claims description 2
- PZBFGYYEXUXCOF-UHFFFAOYSA-N TCEP Chemical compound OC(=O)CCP(CCC(O)=O)CCC(O)=O PZBFGYYEXUXCOF-UHFFFAOYSA-N 0.000 claims description 2
- WOURXYYHORRGQO-UHFFFAOYSA-N Tri(3-chloropropyl) phosphate Chemical compound ClCCCOP(=O)(OCCCCl)OCCCCl WOURXYYHORRGQO-UHFFFAOYSA-N 0.000 claims description 2
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical group [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 2
- 235000012211 aluminium silicate Nutrition 0.000 claims description 2
- 235000019826 ammonium polyphosphate Nutrition 0.000 claims description 2
- 229920001276 ammonium polyphosphate Polymers 0.000 claims description 2
- DWSWCPPGLRSPIT-UHFFFAOYSA-N benzo[c][2,1]benzoxaphosphinin-6-ium 6-oxide Chemical compound C1=CC=C2[P+](=O)OC3=CC=CC=C3C2=C1 DWSWCPPGLRSPIT-UHFFFAOYSA-N 0.000 claims description 2
- 229910001593 boehmite Inorganic materials 0.000 claims description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 2
- PMHQVHHXPFUNSP-UHFFFAOYSA-M copper(1+);methylsulfanylmethane;bromide Chemical compound Br[Cu].CSC PMHQVHHXPFUNSP-UHFFFAOYSA-M 0.000 claims description 2
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 2
- 238000001035 drying Methods 0.000 claims description 2
- FAHBNUUHRFUEAI-UHFFFAOYSA-M hydroxidooxidoaluminium Chemical compound O[Al]=O FAHBNUUHRFUEAI-UHFFFAOYSA-M 0.000 claims description 2
- 238000007654 immersion Methods 0.000 claims description 2
- QPPQHRDVPBTVEV-UHFFFAOYSA-N isopropyl dihydrogen phosphate Chemical compound CC(C)OP(O)(O)=O QPPQHRDVPBTVEV-UHFFFAOYSA-N 0.000 claims description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 2
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims description 2
- 239000000347 magnesium hydroxide Substances 0.000 claims description 2
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims description 2
- 239000000395 magnesium oxide Substances 0.000 claims description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 2
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims description 2
- 239000010445 mica Substances 0.000 claims description 2
- 229910052618 mica group Inorganic materials 0.000 claims description 2
- GKTNLYAAZKKMTQ-UHFFFAOYSA-N n-[bis(dimethylamino)phosphinimyl]-n-methylmethanamine Chemical compound CN(C)P(=N)(N(C)C)N(C)C GKTNLYAAZKKMTQ-UHFFFAOYSA-N 0.000 claims description 2
- 229910017464 nitrogen compound Inorganic materials 0.000 claims description 2
- 239000004745 nonwoven fabric Substances 0.000 claims description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 2
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims description 2
- 239000002245 particle Substances 0.000 claims description 2
- 229920006393 polyether sulfone Polymers 0.000 claims description 2
- 229920000069 polyphenylene sulfide Polymers 0.000 claims description 2
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims description 2
- 229910010271 silicon carbide Inorganic materials 0.000 claims description 2
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 claims description 2
- 239000000454 talc Substances 0.000 claims description 2
- 235000012222 talc Nutrition 0.000 claims description 2
- 229910052623 talc Inorganic materials 0.000 claims description 2
- 239000004408 titanium dioxide Substances 0.000 claims description 2
- WVLBCYQITXONBZ-UHFFFAOYSA-N trimethyl phosphate Chemical compound COP(=O)(OC)OC WVLBCYQITXONBZ-UHFFFAOYSA-N 0.000 claims description 2
- 239000002759 woven fabric Substances 0.000 claims description 2
- 239000011787 zinc oxide Substances 0.000 claims description 2
- 229910001928 zirconium oxide Inorganic materials 0.000 claims description 2
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 claims 2
- 229910019142 PO4 Inorganic materials 0.000 claims 1
- 229920000388 Polyphosphate Polymers 0.000 claims 1
- 150000002460 imidazoles Chemical class 0.000 claims 1
- 125000002883 imidazolyl group Chemical group 0.000 claims 1
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 claims 1
- 239000010452 phosphate Substances 0.000 claims 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims 1
- 239000001205 polyphosphate Substances 0.000 claims 1
- 235000011176 polyphosphates Nutrition 0.000 claims 1
- DXZMANYCMVCPIM-UHFFFAOYSA-L zinc;diethylphosphinate Chemical compound [Zn+2].CCP([O-])(=O)CC.CCP([O-])(=O)CC DXZMANYCMVCPIM-UHFFFAOYSA-L 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 20
- 238000010521 absorption reaction Methods 0.000 description 19
- 230000000052 comparative effect Effects 0.000 description 17
- 239000000758 substrate Substances 0.000 description 17
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 10
- 230000001070 adhesive effect Effects 0.000 description 6
- 229910052802 copper Inorganic materials 0.000 description 6
- 239000010949 copper Substances 0.000 description 6
- 238000011161 development Methods 0.000 description 6
- 239000000853 adhesive Substances 0.000 description 5
- 230000002411 adverse Effects 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 230000009477 glass transition Effects 0.000 description 5
- 239000004593 Epoxy Substances 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 239000011889 copper foil Substances 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 230000005540 biological transmission Effects 0.000 description 3
- 239000007822 coupling agent Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000011159 matrix material Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- XSXWOBXNYNULJG-UHFFFAOYSA-N 2-(2,4,4-trimethylpentan-2-yl)phenol Chemical compound CC(C)(C)CC(C)(C)C1=CC=CC=C1O XSXWOBXNYNULJG-UHFFFAOYSA-N 0.000 description 2
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- WTEOIRVLGSZEPR-UHFFFAOYSA-N boron trifluoride Chemical compound FB(F)F WTEOIRVLGSZEPR-UHFFFAOYSA-N 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 238000000113 differential scanning calorimetry Methods 0.000 description 2
- 239000002270 dispersing agent Substances 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- 229920001568 phenolic resin Polymers 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 230000008054 signal transmission Effects 0.000 description 2
- 238000005476 soldering Methods 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- 238000004017 vitrification Methods 0.000 description 2
- 206010003497 Asphyxia Diseases 0.000 description 1
- 229910015900 BF3 Inorganic materials 0.000 description 1
- 229930185605 Bisphenol Natural products 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- GCKAMTHMSCXVIL-UHFFFAOYSA-N bis(2,3-dimethylphenyl) (3-hydroxyphenyl) phosphate Chemical compound P(=O)(OC1=C(C(=CC=C1)C)C)(OC1=C(C(=CC=C1)C)C)OC1=CC(O)=CC=C1 GCKAMTHMSCXVIL-UHFFFAOYSA-N 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000005350 fused silica glass Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000000383 hazardous chemical Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 230000010365 information processing Effects 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 239000002648 laminated material Substances 0.000 description 1
- ZQKXQUJXLSSJCH-UHFFFAOYSA-N melamine cyanurate Chemical compound NC1=NC(N)=NC(N)=N1.O=C1NC(=O)NC(=O)N1 ZQKXQUJXLSSJCH-UHFFFAOYSA-N 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 229920000137 polyphosphoric acid Polymers 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 238000009774 resonance method Methods 0.000 description 1
- 238000007151 ring opening polymerisation reaction Methods 0.000 description 1
- FZHAPNGMFPVSLP-UHFFFAOYSA-N silanamine Chemical compound [SiH3]N FZHAPNGMFPVSLP-UHFFFAOYSA-N 0.000 description 1
- 150000003384 small molecules Chemical class 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B15/08—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B15/08—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
- B32B15/092—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin comprising epoxy resins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/14—Layered products comprising a layer of metal next to a fibrous or filamentary layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/20—Layered products comprising a layer of metal comprising aluminium or copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/04—Layered products comprising a layer of synthetic resin as impregnant, bonding, or embedding substance
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
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Abstract
Description
ークの脆性を向上させ、動的条件での粘着特性にも悪影響を及ぼしたため、基材同士及び基材と銅箔との接着強度を低下させるからである。
(A)エポキシ樹脂
(A−1)調製例で合成したジシクロペンタジエニルアルキルフェノールエポキシ樹脂
(A−2)ビフェニル型エポキシ樹脂:NC−3000−H(日本化薬社製、商品名)
(A−3)ジシクロペンタジエン型エポキシ樹脂:HP−7200H(大日本インク社製、商品名)
(B)ベンゾオキサジン
(B−1)脂肪族ベンゾオキサジン樹脂:KAH−F5404(韓国Kolon社製、商品名)
(B−2)フッ化ベンゾオキサジン:KAH−F5301(韓国Kolon社製、商品名)
(B−3)ビスフェノールF型ベンゾオキサジン:LZ8280(ハンツマンアドバンストマテリアル社製)
(B−4)ジシクロペンタジエンベンゾオキサジン:LZ8260(ハンツマンアドバンストマテリアル社製)
(C−1)低分子量ポリフェニレンエーテル:MX90(SABIC Innovative Plastics社製 商品名)、数平均分子量1000〜4000
(C−2)高分子量ポリフェニレンエーテル:Sabic640−111(SABIC
Innovative Plastics社製 商品名)数平均分子量15000〜2
0000
(D)スチレン−無水マレイン酸オリゴマー:SMA−EF40(米国Sartomer社製、商品名)
(E)リン含有フェノール樹脂:XZ92741(DOW化学社製、商品名)
(F)硬化促進剤:2E4MZ(四国化成社製、商品名)
(G)フィラー:溶融シリカ。
示差走査熱量法(DSC)により、IPC−TM−650 2.4.25に規定されたDSC方法を用いて測定する。
IPC−TM−650 2.4.8方法における「熱応力後」の実験条件で、金属キャップの剥離強度をテストする。
ストリップライン共振法を用いて、IPC−TM−650 2.5.5.5に準じて1GHzでの誘電率(Dk)と誘電正接(Df)を測定する。
UL−94標準に準じてテストする。
銅張積層板を銅エッチング液に浸漬して、表面銅箔を除去して基板を評価し、基板を圧力鍋に入れて、121℃、2atmで2h処理し、吸水率をテストした後、温度288℃の錫炉に浸漬し、基材に発泡やクラックが発生する際に対応する時間を記録する。基材を錫炉に入れてから5min超えた後にも、発泡やクラックが発生しないと、評価を終了する。
電率、誘電正接及びPCT吸水率を有する。これは、低分子量ポリフェニレンエーテルを添加した実施例4が、該成分を添加していない比較例4より、低い誘電率、誘電正接及びPCT吸水率が得られることを示す。実施例1と比較例5を比較して明らかなように、両方の総合的性質がほぼ同じであるが、高分子量ポリフェニレンエーテルの使用によって、加工性が低下してしまう。
Claims (10)
- 前記エポキシ樹脂はさらに、ビスフェノールA型エポキシ樹脂、ビスフェノールF型エポキシ樹脂、ビフェニル型エポキシ樹脂、アルキルノボラック型エポキシ樹脂、ジシクロペンタジエン型エポキシ樹脂、ビスフェノールA型ノボラックエポキシ樹脂、o−クレゾールノボラックエポキシ樹脂、フェノールノボラック型エポキシ樹脂、三官能エポキシ樹脂、四官能エポキシ樹脂、イソシアネート変性エポキシ樹脂、ナフタレン型エポキシ樹脂又はリン含有エポキシ樹脂から選ばれる任意の1種又は少なくとも2種の混合物である、ことを特徴とする請求項1に記載のノンハロゲン樹脂組成物。
- 前記ベンゾオキサジンはフッ化ベンゾオキサジン樹脂、脂肪族ベンゾオキサジン樹脂又はジシクロペンタジエン型ベンゾオキサジン樹脂から選ばれる任意の1種又は少なくとも2種の混合物であり、
好ましくは、前記ベンゾオキサジンはフッ化ベンゾオキサジン樹脂又は脂肪族ベンゾオキサジン樹脂から選ばれる任意の1種又は少なくとも2種の混合物であり、
好ましくは、前記フッ化ベンゾオキサジン樹脂は下記化学構造式
好ましくは、前記脂肪族ベンゾオキサジン樹脂の化学構造式は、
好ましくは、前記ジシクロペンタジエン型ベンゾオキサジン樹脂の化学構造式は、
- 前記ポリフェニレンエーテルの数平均分子量は1000〜4000であることを特徴とする請求項1に記載のノンハロゲン樹脂組成物。
- 前記ノンハロゲン難燃剤はホスファゼン、ポリリン酸アンモニウム、トリス(2−カルボキシエチル)ホスフィン、トリス(クロロプロピル)ホスフェート、トリメチルホスフェート、ジメチル−メチルホスフェート、レゾルシノールジキシリルホスフェート、リン窒素系化合物、ポリ燐酸メラミン、メラミンシアヌレート、トリヒドロキシエチルイソシアヌレート、9,10−ジヒドロ−9−オキサ−10−ホスファフェナントレン−10−オキシド又はDOPO含有フェノール樹脂から選ばれる任意の1種又は少なくとも2種の混合物であり、
好ましくは、前記硬化促進剤はイミダゾール系促進剤であり、
好ましくは、前記硬化促進剤は2−メチルイミダゾール、ウンデシルイミダゾール、2−エチル−4−メチルイミダゾール、2−フェニルイミダゾール又は1−シアノエチル置換イミダゾールから選ばれる任意の1種又は少なくとも2種の混合物である、ことを特徴とする請求項1に記載のノンハロゲン樹脂組成物。 - 前記フィラーは無機又は有機フィラーであり、
好ましくは、前記フィラーは無機フィラーであり、前記無機フィラーは水酸化アルミニウム、酸化アルミニウム、水酸化マグネシウム、酸化マグネシウム、アルミナ、シリカ、炭酸カルシウム、窒化アルミニウム、窒化ホウ素、炭化ケイ素、二酸化チタン、酸化亜鉛、酸化ジルコニウム、雲母、ベーマイト、か焼タルク、タルカム粉末、窒化ケイ素又はか焼カオリンから選ばれる任意の1種又は少なくとも2種の混合物であり、
好ましくは、前記フィラーは有機フィラーであり、前記有機フィラーはポリテトラフルオロエチレン粉末、ポリフェニレンサルファイド又はポリエーテルスルホン粉末から選ばれる任意の1種又は少なくとも2種の混合物であり、
好ましくは、前記フィラーの粒径は0.01〜50μm、好ましくは1〜15μm、より好ましくは1〜5μmである、ことを特徴とする請求項1に記載のノンハロゲン樹脂組成物。 - 請求項1〜7のいずれか1項に記載のノンハロゲン樹脂組成物を用いて製造されるプリプレグであって、前記プリプレグは基材、及び浸漬乾燥後に前記基材に付着したノンハロゲン樹脂組成物を含み、
好ましくは、前記基材はガラス繊維不織布又はガラス繊維織布である、ことを特徴とするプリプレグ。 - 請求項8に記載のプリプレグを含むことを特徴とする積層板。
- 請求項9に記載の積層板を含むことを特徴とするプリント回路基板。
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2018100320A (ja) * | 2016-12-19 | 2018-06-28 | Dic株式会社 | エポキシ樹脂、硬化性樹脂組成物及びその硬化物 |
JP2019173009A (ja) * | 2018-03-28 | 2019-10-10 | 積水化学工業株式会社 | 硬化体、樹脂材料及び多層プリント配線板 |
CN111072980A (zh) * | 2019-12-30 | 2020-04-28 | 四川东材科技集团股份有限公司 | 一种改性碳氢树脂预聚物、改性碳氢-dcpd环氧复合材料覆铜板及制备方法 |
JP2020109146A (ja) * | 2018-12-29 | 2020-07-16 | 廣東生益科技股▲ふん▼有限公司Shengyi Technology Co.,Ltd. | ハロゲン無し・燐無し・窒素無し難燃性樹脂組成物、それを含むプリプレグ及び金属張積層板 |
JP2020143239A (ja) * | 2019-03-07 | 2020-09-10 | 味の素株式会社 | 樹脂組成物 |
Families Citing this family (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP6546993B2 (ja) * | 2014-11-11 | 2019-07-17 | 廣東生益科技股▲ふん▼有限公司Shengyi Technology Co.,Ltd. | 熱硬化性樹脂組成物、及びそれを用いて製造されたプリプレグと積層板 |
CN106832764A (zh) * | 2015-12-04 | 2017-06-13 | 广东生益科技股份有限公司 | 一种无卤环氧树脂组合物以及含有它的预浸料、层压板和印制电路板 |
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US20200095422A1 (en) * | 2016-12-09 | 2020-03-26 | Jxtg Nippon Oil & Energy Corporation | Curable resin composition, cured product obtained from the same, method for hardening the same, and semiconductor device |
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WO2021212326A1 (zh) * | 2020-04-21 | 2021-10-28 | 穗晔实业股份有限公司 | 热固型树脂组成物 |
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CN117581641A (zh) | 2021-05-07 | 2024-02-20 | 奥特斯奥地利科技与系统技术有限公司 | 具有光敏粘合促进剂的部件承载件及其制造方法 |
CN116333491B (zh) * | 2023-05-26 | 2023-08-04 | 汕头超声覆铜板科技有限公司 | 一种适用于高速通信的无卤树脂组合物及其应用 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
TW201100488A (en) * | 2009-06-30 | 2011-01-01 | Elite Material Co Ltd | Thermosetting resin composition and copper clad laminate |
US20140107256A1 (en) * | 2012-10-16 | 2014-04-17 | Guangdong Shengyi Sci. Tech Co., Ltd. | Thermoset resin composition and its use |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
TW200413467A (en) * | 2003-01-16 | 2004-08-01 | Chang Chun Plastics Co Ltd | Resin composition without containing halogen |
US20110135944A1 (en) | 2008-08-12 | 2011-06-09 | Huntsman International Llc | Thermosetting composition |
KR20110066929A (ko) * | 2008-10-10 | 2011-06-17 | 스미토모 베이클리트 컴퍼니 리미티드 | 반도체 장치 |
CN101684191B (zh) * | 2009-08-27 | 2012-03-07 | 广东生益科技股份有限公司 | 无卤高频树脂组合物及用其制成的预浸料与层压板 |
JP2011074123A (ja) * | 2009-09-29 | 2011-04-14 | Panasonic Electric Works Co Ltd | 樹脂組成物、樹脂ワニス、プリプレグ、金属張積層板、及びプリント配線板 |
EP2770025B1 (en) | 2011-10-18 | 2017-01-18 | Shengyi Technology Co., Ltd | Halogen-free low-dielectric resin composition, and prepreg and copper foil laminate made by using same |
CN103131131B (zh) * | 2011-11-23 | 2015-07-15 | 台光电子材料股份有限公司 | 无卤素树脂组合物及其应用的铜箔基板及印刷电路板 |
US9005761B2 (en) * | 2011-12-22 | 2015-04-14 | Elite Material Co., Ltd. | Halogen-free resin composition and its application for copper clad laminate and printed circuit board |
CN103421273B (zh) * | 2012-05-22 | 2016-02-10 | 中山台光电子材料有限公司 | 无卤素树脂组成物 |
CN102732029B (zh) * | 2012-06-21 | 2014-01-08 | 广东生益科技股份有限公司 | 无卤树脂组合物及粘结片与覆铜箔层压板 |
WO2014036711A1 (zh) | 2012-09-07 | 2014-03-13 | 广东生益科技股份有限公司 | 环氧树脂组合物以及使用其制作的半固化片与覆铜箔层压板 |
CN103265810B (zh) * | 2013-05-29 | 2015-09-23 | 苏州生益科技有限公司 | 一种用于高频高速基板的树脂组合物及使用其制作的半固化片及层压板 |
CN103980708B (zh) * | 2014-05-28 | 2017-01-11 | 苏州生益科技有限公司 | 用于集成电路的无卤阻燃热固性树脂组合物、半固化片及层压板 |
AU2014411037B2 (en) * | 2014-11-11 | 2018-10-25 | Shengyi Technology Co., Ltd. | Thermosetting resin composition and prepreg and laminated board prepared therefrom |
-
2014
- 2014-11-11 CN CN201410633018.5A patent/CN104371273B/zh active Active
- 2014-12-02 JP JP2017525534A patent/JP6381802B2/ja not_active Expired - Fee Related
- 2014-12-02 WO PCT/CN2014/092842 patent/WO2016074291A1/zh active Application Filing
- 2014-12-02 US US15/525,884 patent/US10336875B2/en not_active Expired - Fee Related
- 2014-12-02 EP EP14905928.9A patent/EP3219757B1/en active Active
- 2014-12-02 KR KR1020177015916A patent/KR101897426B1/ko active IP Right Grant
- 2014-12-02 AU AU2014411040A patent/AU2014411040B2/en not_active Ceased
-
2015
- 2015-01-15 TW TW104101384A patent/TWI555791B/zh active
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
TW201100488A (en) * | 2009-06-30 | 2011-01-01 | Elite Material Co Ltd | Thermosetting resin composition and copper clad laminate |
US20140107256A1 (en) * | 2012-10-16 | 2014-04-17 | Guangdong Shengyi Sci. Tech Co., Ltd. | Thermoset resin composition and its use |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2018100320A (ja) * | 2016-12-19 | 2018-06-28 | Dic株式会社 | エポキシ樹脂、硬化性樹脂組成物及びその硬化物 |
JP2019173009A (ja) * | 2018-03-28 | 2019-10-10 | 積水化学工業株式会社 | 硬化体、樹脂材料及び多層プリント配線板 |
JP2020109146A (ja) * | 2018-12-29 | 2020-07-16 | 廣東生益科技股▲ふん▼有限公司Shengyi Technology Co.,Ltd. | ハロゲン無し・燐無し・窒素無し難燃性樹脂組成物、それを含むプリプレグ及び金属張積層板 |
JP2020143239A (ja) * | 2019-03-07 | 2020-09-10 | 味の素株式会社 | 樹脂組成物 |
JP7124770B2 (ja) | 2019-03-07 | 2022-08-24 | 味の素株式会社 | 樹脂組成物 |
JP2022179472A (ja) * | 2019-03-07 | 2022-12-02 | 味の素株式会社 | 樹脂組成物 |
JP7338758B2 (ja) | 2019-03-07 | 2023-09-05 | 味の素株式会社 | 樹脂組成物 |
CN111072980A (zh) * | 2019-12-30 | 2020-04-28 | 四川东材科技集团股份有限公司 | 一种改性碳氢树脂预聚物、改性碳氢-dcpd环氧复合材料覆铜板及制备方法 |
CN111072980B (zh) * | 2019-12-30 | 2021-11-23 | 四川东材科技集团股份有限公司 | 一种改性碳氢树脂预聚物、改性碳氢-dcpd环氧复合材料覆铜板及制备方法 |
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