WO2022118662A1 - ガス供給装置、射出成形機および発泡成形方法 - Google Patents
ガス供給装置、射出成形機および発泡成形方法 Download PDFInfo
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- WO2022118662A1 WO2022118662A1 PCT/JP2021/042339 JP2021042339W WO2022118662A1 WO 2022118662 A1 WO2022118662 A1 WO 2022118662A1 JP 2021042339 W JP2021042339 W JP 2021042339W WO 2022118662 A1 WO2022118662 A1 WO 2022118662A1
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- Prior art keywords
- gas
- pressure
- gas pressure
- adjusting unit
- pressure adjusting
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- 238000001746 injection moulding Methods 0.000 title claims abstract description 39
- 238000000034 method Methods 0.000 title claims description 47
- 238000010097 foam moulding Methods 0.000 title claims description 38
- 238000002347 injection Methods 0.000 claims abstract description 56
- 239000007924 injection Substances 0.000 claims abstract description 56
- 238000010438 heat treatment Methods 0.000 claims abstract description 47
- 238000000465 moulding Methods 0.000 claims abstract description 37
- 239000011347 resin Substances 0.000 claims description 43
- 229920005989 resin Polymers 0.000 claims description 43
- 230000008569 process Effects 0.000 claims description 41
- 238000005303 weighing Methods 0.000 claims description 27
- 230000007246 mechanism Effects 0.000 claims description 10
- 239000006260 foam Substances 0.000 claims description 8
- 230000008859 change Effects 0.000 abstract description 9
- 239000007789 gas Substances 0.000 description 337
- 238000011144 upstream manufacturing Methods 0.000 description 15
- 235000003642 hunger Nutrition 0.000 description 11
- 230000037351 starvation Effects 0.000 description 11
- 230000006835 compression Effects 0.000 description 9
- 238000007906 compression Methods 0.000 description 9
- 239000000047 product Substances 0.000 description 5
- 230000000694 effects Effects 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 3
- 238000005187 foaming Methods 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 239000004088 foaming agent Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 239000003570 air Substances 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 230000003139 buffering effect Effects 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 230000012447 hatching Effects 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
Images
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- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
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Definitions
- the present invention is a gas supply device that supplies gas in an injection molding machine that injects a gas such as carbon dioxide, nitrogen, argon, helium, air, or a hydrocarbon such as methane or butane into an injection material to form a foam molded product.
- a gas such as carbon dioxide, nitrogen, argon, helium, air, or a hydrocarbon such as methane or butane
- An injection molding machine equipped with a gas supply device, and a foam molding method is an injection molding machine that injects a gas such as carbon dioxide, nitrogen, argon, helium, air, or a hydrocarbon such as methane or butane.
- the foam molding method for obtaining a foam molded product using a physical foaming agent is carried out by an injection molding machine equipped with a gas supply device.
- the injection molding machine is composed of a heating cylinder and a screw, for example, as described in Patent Document 1.
- the inside of the heating cylinder is divided into a plurality of sections according to the shape of the screw. That is, the heating cylinder includes a first compression section, a starvation section, and a second compression section from upstream to downstream.
- the heating cylinder is provided with a gas inlet to correspond to the starvation section.
- the gas supply device is connected to this gas inlet.
- the resin is sent from upstream to downstream by a screw in the heating cylinder to be melted and kneaded in the first compression section. Then, the pressure of the resin decreases in the starvation section.
- the gas supplied from the gas supply device is injected into the starvation section via the gas inlet.
- the resin into which the gas is injected is kneaded and compressed in the second compression section, and the gas dissolves in the resin.
- Such resin is sent to the tip of the screw and weighed.
- the screw is driven to inject the resin into the mold.
- the gas dissolved in the resin foams in the mold to obtain an effervescent molded product.
- the present disclosure provides a gas supply device, an injection molding machine, and a foam molding method in which a sufficient amount of gas is efficiently dissolved in a resin in foam molding and backflow of gas is unlikely to occur.
- the injection device of the injection molding machine consists of a heating cylinder provided with a gas injection port and a screw, and the gas supply device is connected to this gas injection port.
- the gas supply device consists of a gas supply source and a gas pressure adjusting unit. When the gas from the gas supply source is injected into the gas inlet, the gas pressure adjusting unit adjusts the gas pressure to supply the gas.
- the gas pressure regulator makes the gas pressure change in the molding cycle so that at least a part of the boosting period for boosting the gas pressure overlaps with the weighing process.
- the gas pressure is changed by the gas pressure adjusting unit of the gas supply device, and the boosting period in which the gas pressure is increased overlaps with the measuring process. Therefore, since the high-pressure gas is supplied to the resin when the resin is sent from the upstream to the downstream in the weighing process, the gas is efficiently dissolved in the resin. At this time, since the resin flows from the upstream to the downstream, the effect that backflow of gas is unlikely to occur can be obtained.
- the injection molding machine 1 As shown in FIG. 1, the injection molding machine 1 according to the present embodiment is roughly composed of a mold clamping device 2, an injection device 3, and a gas supply device 5 provided on the bed B.
- the gas supply device 5 is a characteristic device in the present embodiment, and will be described in detail later.
- the mold clamping device 2 can also be configured as a direct pressure type, and the type of the mold opening / closing mechanism is not limited.
- the mold clamping device 2 according to the present embodiment is a toggle type. That is, the mold clamping device 2 includes a fixing plate 7, a movable plate 8, a mold clamping housing 9, a tie bar-10, 10, ... That connects the mold clamping housing 9 and the fixing plate 7, and a toggle mechanism 11. It is composed of and.
- the molds 13 and 14 are provided on the fixed plate 7 and the movable plate 8. When the toggle mechanism 11 is driven, the molds 13 and 14 are molded.
- the injection device 3 is an injection device for foam molding using a physical foaming agent, that is, a gas, and its appearance is simplified in FIG. 1 and shown in a cross-sectional view in FIG. ing.
- the injection device 3 includes a heating cylinder 18 and a screw 19 contained in the heating cylinder 18.
- the groove depth of the flight changes from the upstream side to the downstream side, and the inside of the heating cylinder 18 is divided into a plurality of sections. That is, in the heating cylinder 18, a supply section 22 in which the resin is supplied and melted from the upstream side, a first compression section 23 in which the melted resin is compressed, and a starvation section 24 in which the groove depth is deep and the resin pressure drops. And it is divided into the second compression section 25.
- the heating cylinder 18 is provided with a hopper 27 upstream, an injection nozzle 29 at the tip thereof, and a gas injection port 30 for injecting gas inside at a position corresponding to the starvation section 24.
- the injection molding machine 1 is provided with a controller 31 as shown in FIG.
- the mold clamping device 2, the injection device 3, and the gas supply device 5 according to the present embodiment, which will be described in detail later, are connected to the controller 31 and controlled by the controller 31.
- the conventional gas supply device 101 includes a gas supply source, that is, a gas cylinder 102, a pressure reducing valve 103 that reduces the high pressure gas supplied from the gas cylinder 102 to a low pressure secondary pressure, and a pressure reducing valve 103. It is composed of a check valve 104 provided as needed in the pipeline to which the secondary pressure is supplied, and an on-off valve 106 similarly provided as needed. The gas subjected to the secondary pressure is injected into the heating cylinder 18 from the gas injection port 30.
- a gas supply source that is, a gas cylinder 102, a pressure reducing valve 103 that reduces the high pressure gas supplied from the gas cylinder 102 to a low pressure secondary pressure, and a pressure reducing valve 103. It is composed of a check valve 104 provided as needed in the pipeline to which the secondary pressure is supplied, and an on-off valve 106 similarly provided as needed.
- the gas subjected to the secondary pressure is injected into the heating cylinder 18 from the gas injection port 30.
- the state when gas is supplied by the conventional gas supply device 101 to carry out the molding cycle of foam molding is shown in the graph of FIG.
- the screw rotation speed 111 rotates at a predetermined rotation speed
- the resin is weighed
- the screw position 112 retracts substantially linearly in the measuring step 110.
- the screw rotation speed 111 becomes 0 and the screw position 112 becomes constant.
- the resin is sent from the upstream, gas is supplied in the starvation section 24, and the resin is sent to the downstream.
- the gas is gradually dissolved in the resin flowing from the upstream and sent to the downstream side. Therefore, a large amount of gas is temporarily consumed, and the gas pressure 114 is temporarily lowered in the measuring step 110.
- the gas supplied from the gas cylinder 102 should be depressurized by the pressure reducing valve 103 and controlled to a secondary pressure of a constant pressure. However, the gas flows through the pipe at a high speed so as to supplement the gas temporarily consumed in a large amount, which causes a pressure loss, which causes the gas pressure 114 to temporarily decrease.
- the amount of gas required by the resin is shown in Graph 115, and a large amount is required in the measuring step 110.
- the pressure temporarily reduced in the measuring step 110 is, for example, 0.2 to 0.3 MPa, and the amount of gas melted in the resin is reduced by that amount. Due to the high gas consumption of large molding machines, the drop in gas pressure can be even greater.
- the gas supply device 5 according to the present embodiment is configured to prevent this phenomenon.
- the gas supply device 5 can take various embodiments, but first, the gas supply device 5A according to the first embodiment shown in FIG. 2 will be described.
- the gas supply device 5A includes gas cylinders 33 and 33 as gas supply sources, and a gas pressure adjusting unit 34 for adjusting the pressure of the gas supplied from the gas supply source.
- the gas pressure adjusting unit 34 is provided with a configuration not found in the conventional gas supply device 101. That is, the high pressure adjusting unit 36 that adjusts the gas pressure to a high pressure and the low pressure adjusting unit 37 that adjusts the gas pressure to a low pressure.
- the high pressure adjusting unit 36 includes a high pressure pressure reducing valve 38 that reduces the supply source pressure, which is the high pressure gas pressure supplied from the gas cylinder 33.
- the pipeline downstream of the high-pressure pressure reducing valve 38 is branched, and the branched portion is the low-pressure adjusting unit 37.
- the low pressure adjusting unit 37 is provided with a low pressure pressure reducing valve 39.
- the gas supplied at the supply source pressure is depressurized by the high pressure pressure reducing valve 38, and further depressurized by the low pressure pressure reducing valve 39.
- the pressure depressurized by the high pressure pressure reducing valve 38 is lower than the source pressure, but higher than the low pressure which is the pressure decompressed by the low pressure pressure reducing valve 39. Therefore, this gas pressure is referred to as high pressure in the present specification.
- a high pressure side check valve 41 and a high pressure side on-off valve 44 are provided in the pipeline downstream of the high pressure pressure reducing valve 38.
- the low-pressure adjusting unit 37 is also provided with a low-pressure side check valve 42 and a low-pressure side on-off valve 45 in the pipeline downstream of the low-pressure pressure reducing valve 39.
- these on-off valves 44 and 45 are operated by the controller 31 (see FIG. 1).
- the downstream pipelines of the high-pressure side on-off valve 44 and the low-pressure side on-off valve 45 merge and are connected to the gas injection port 30.
- a supply source pressure gauge 47 for detecting the gas supply source pressure is provided in the pipe to which the gas cylinders 33 and 33 are connected.
- the high pressure adjusting unit 36 is provided with a high pressure pressure gauge 48 for detecting high pressure gas.
- the low pressure adjusting unit 37 is provided with a low pressure pressure gauge 49 that detects low pressure gas.
- an injection pressure pressure gauge 51 for detecting the pressure of the injected gas is provided in the pipeline connected to the gas injection port 30.
- the high pressure pressure reducing valve 38 and the low pressure pressure reducing valve 39 are set in advance so that the high pressure and low pressure gas pressures adjusted by each are set to desired pressures. be. Therefore, the gas pressure of the gas supplied from the gas injection port 30 into the heating cylinder 18 becomes high pressure when the low pressure side on-off valve 45 is closed and the high pressure side on-off valve 44 is opened, and the low pressure side on-off valve 45 is opened to increase the pressure.
- the side on-off valve 44 is closed, the pressure becomes low.
- the low pressure side on-off valve 45 is not always essential. This is because the low-pressure side check valve 42 is provided, so that the high-pressure gas does not flow back to the low-pressure adjusting unit 37. That is, in the present embodiment, it is sufficient to have either the low pressure side on-off valve 45 or the check valve 42. This is the same in the subsequent embodiments when the high pressure adjusting unit 36 and the low pressure adjusting unit 37 are included.
- the foam molding method carried out by the injection molding machine 1 according to the present embodiment provided with the gas supply device 5A according to the first embodiment of the present embodiment is, in short, a method of actively changing the gas pressure in the molding cycle. Is. Specifically, the gas pressure is boosted in the weighing step and lowered in the other steps. In the weighing process, since the resin flows in the heating cylinder 18 from upstream to downstream, there is no possibility that the gas will flow back in the heating cylinder 18. Since the gas is boosted to a high pressure in this weighing process, a large amount of gas can be efficiently dissolved in the resin. When the weighing process is completed, the flow of the resin in the heating cylinder 18 is stopped, so that the gas may flow back. At this time, the pressure of the gas is reduced to a low pressure, so that backflow can be prevented.
- the foam molding method will be further described with reference to FIGS. 2 and 7.
- FIG. 7 shows changes in various data during the molding cycle.
- the screw rotation speed 62 rotates at a constant rotation speed in the measuring step 61 of the molding cycle, and becomes 0 in the other steps.
- the screw position 63 drops sharply in the injection step 65, then stays substantially constant, gradually increases in the weighing step 61, and becomes constant after the completion of the weighing step 61.
- the gas is injected from the gas inlet 30. That is, the resin is injected in the starvation section 24. A large amount of gas is dissolved in a resin in which the amount of gas dissolved is 0 or a small amount, and only a small amount is dissolved in a resin in which the gas is sufficiently dissolved.
- the new resin in which the gas is not dissolved flows continuously from the upstream in the heating cylinder 18, so that the gas consumption is large.
- the gas consumption is reduced. That is, the amount of gas required changes.
- the graph of reference numeral 67 shows the change in the required amount of gas in the molding cycle.
- the controller 31 opens the low pressure side on-off valve 45 and closes the high pressure side on-off valve 44 to supply the low pressure gas.
- the controller 31 closes the low-pressure side on-off valve 45 and opens the high-pressure side on-off valve 44 at the timing of reference numeral 69 to supply high-pressure gas.
- the gas pressure 68 rapidly changes to a high pressure.
- the gas pressure is increased.
- a large amount of gas can be efficiently injected into the resin.
- the gas dissolution amount and the gas dissolution rate are proportional to the gas pressure. That is, the amount of gas dissolved is controlled by the gas pressure.
- the controller 31 opens the low-pressure side on-off valve 45 and closes the high-pressure side on-off valve 44 after a predetermined predetermined time to switch to the supply of low-pressure gas.
- This timing is indicated by reference numeral 70. That is, the gas pressure is stepped down. The gas pressure drops slowly. After that, the gas pressure stabilizes at low pressure. This prevents backflow of gas. Further, if the pressure drops too much, the gas dissolved in the resin during the pressurization period 71 separates from the resin and begins to foam, but by maintaining the gas pressure at a low pressure, foaming in the heating cylinder 18 can be prevented.
- the period during which the gas pressure becomes high pressure that is, the pressurization period 71 includes the weighing step 61 and is slightly longer than that.
- the present embodiment is not limited to this.
- the gas supply may be stopped instead of switching to the low pressure gas. Because the cycle is short, the pressure drop is substantially small, and the same effect as switching to low pressure can be obtained.
- the low pressure adjusting unit 37 is not always necessary, and the gas supply device 5 may be configured only by the high pressure adjusting unit 36.
- FIG. 3 shows the gas supply device 5B according to the second embodiment.
- the same members and parts as in the first embodiment are designated by the same reference numerals, and the description thereof will be omitted.
- the injection device 3B according to this embodiment is provided with two gas injection ports, that is, first and second gas injection ports 30a and 30b.
- the gas supply device 5B according to the second embodiment is adapted to inject gas into the first and second gas injection ports 30a and 30b.
- the gas supply device 5B is also provided with the high pressure adjusting unit 36 and the low pressure adjusting unit 37, but these are completely divided into two systems from the upstream side. It is separated. That is, gas cylinders 33a and 33b are provided separately corresponding to each, and supply source pressure gauges 47a and 47b are provided, respectively.
- the pipeline from the high pressure adjusting unit 36 and the conduit from the low pressure adjusting unit 37 are connected to the first gas injection port 30a and the second gas injection port 30b, respectively.
- a bypass pipe 52 is provided in the middle of the pipeline from the high pressure adjusting unit 36 and the pipeline from the low pressure adjusting unit 37, and the bypass pipe 52 is provided with a bypass on-off valve 53.
- the first on-off valve 54 is on the downstream side of the bypass pipe 52 in the pipeline from the high pressure adjusting unit 36, and the second on-off valve 54 is on the downstream side of the bypass pipe 52 in the pipeline from the low pressure adjusting unit 37.
- On-off valves 55 are provided respectively.
- the gas supply device 5B according to the second embodiment can be operated by various methods.
- the bypass on-off valve 53 When the bypass on-off valve 53 is always closed during the molding cycle, the high-pressure gas is always only from the first gas injection port 30a, and the low-pressure gas is always only from the second gas injection port 30b in the heating cylinder 18. Will be injected into.
- the controller 31 opens the high-pressure side on-off valve 44 and the first on-off valve 54 to supply high-pressure gas. Further, in another step, the controller 31 closes these on-off valves 44 and 54 and opens the low-pressure side on-off valve 45 and the second on-off valve 55 to supply the low-pressure gas.
- high-pressure gas and low-pressure gas can be supplied to both the first and second gas injection ports 30a and 30b. That is, when the high-pressure side on-off valve 44 is opened and the low-pressure side on-off valve 45 is closed, high-pressure gas is supplied, and when the high-pressure side on-off valve 44 is closed and the low-pressure side on-off valve 45 is opened, low-pressure gas is supplied.
- gas can be injected into both the first and second gas injection ports 30a and 30b at the same time, or gas is injected into only one of them. You can also.
- the gas injection ports 30a and 30b may be removed from the starvation section 24 depending on the configuration and position of the screw 19 and the arrangement of the gas injection ports 30a and 30b.
- the gas inlets 30a and 30b are arranged so as to be separated in the axial direction, and one of the first and second on-off valves 54 and 55 is selected according to the screw position to open the starvation section. The gas can be continued to be supplied to the appropriate positions of 24.
- bypass on-off valve 53 instead of using the bypass on-off valve 53 with the bypass on-off valve 53 always open, the bypass on-off valve 53 may be eliminated to use the bypass pipe 52, or instead of using the bypass on-off valve 53 with the bypass on-off valve 53 always closed, the bypass pipe 52 may be eliminated. Is also good. When the bypass pipe 52 is eliminated, the first and second on-off valves 54 and 55 may be eliminated.
- FIG. 4 shows the gas supply device 5C according to the third embodiment.
- the high pressure adjusting unit 36 includes a syringe 56 driven by a high pressure piston, and is connected to the downstream side of the low pressure adjusting unit 37.
- the syringe 56 can store a sufficient amount of low-pressure gas, and when the piston is driven, it is compressed so that high-pressure gas can be supplied. That is, the syringe 56 has a boosting mechanism for boosting the gas. Therefore, in the weighing step 61, the controller 31 may drive the syringe 56 to boost the gas and supply the high-pressure gas after closing the low-pressure side on-off valve 45.
- the gas pressure control means of the boosting mechanism is not particularly limited, but for example, the pressure may be obtained and controlled from the driving force of the piston and the cross-sectional area of the piston, or a pressure gauge may be attached to the downstream side of the piston to control the pressure. -You may control the piston.
- FIG. 5 shows the gas supply device 5D according to the fourth embodiment.
- the same members and parts as in the first embodiment are designated by the same reference numerals, and the description thereof will be omitted.
- the gas supply device 5D according to the fourth embodiment includes a nitrogen gas generator 80 and a booster pump 81 for compressing the gas as a gas supply source.
- a pressure reducing valve 83 with an automatic pressure adjusting function is provided in the pipeline from this gas supply source.
- the pressure reducing valve 83 can change the set pressure by a command from the controller 31 (see FIG. 1).
- a pressure gauge 84, a check valve 85, and an on-off valve 86 are provided downstream of the pressure reducing valve 83 and are connected to the gas injection port 30. In the weighing process, the gas is supplied at a high pressure in the pressure reducing valve 83 with an automatic pressure adjustment function, and in the other processes, the gas is supplied at a low pressure.
- the gas pressure is set to three or more stages such as high pressure, medium pressure, and low pressure. It can also be supplied.
- FIG. 8 shows changes in each data in the foam molding method in which the pressure of the gas is changed and supplied in three stages. That is, the boosting period includes a boosting period 71a in which the gas pressure 68 is medium pressure and a boosting period 71b in which the gas pressure 68 is high pressure. The gas pressure 68 is switched from low pressure to medium pressure at the timing of reference numeral 69a prior to the weighing step 61.
- the gas pressure is switched from medium pressure to high pressure at the timing of reference numeral 69b. If the high pressure is switched to the low pressure at the timing of reference numeral 70 slightly before the weighing step 61 is completed, the gas pressure 68 gradually changes to the low pressure thereafter. Further, the gas pressure 68 may be increased or decreased smoothly. That is, the pressure may be gradually increased during the weighing step 61. Further, in the first and second embodiments, a modified example is also possible in which a boosting mechanism is provided in the high pressure adjusting unit 36 and the pressure is adjusted in three or more stages during the measuring step 61.
- the injection molding machine 1 according to the present embodiment and the foam molding method according to the present embodiment can be variously modified.
- a small volume buffer may be provided in the vicinity of the gas inlet 30.
- This buffer acts as a cushion and can suppress sudden changes in gas pressure.
- it is desirable that the buffer is provided between the high pressure side check valve 41 and the high pressure side on-off valve 44 of the high pressure adjusting unit 36.
- the low pressure side check valve 42 may be omitted as described above, or the low pressure side check valve 42 may be omitted instead of the check valve.
- the valves 41 and 42 can also be omitted.
- the gas supply device 5A shown in FIG. 2 and the gas supply device 5C shown in FIG. 4 are used as shown in FIG. 3 as an injection device 3B having two gas injection ports. It can also be combined with. In this case, the pipe leaving the gas supply device is branched into two so as to reach each of the two gas inlets. Further, the gas supply device 5B shown in FIG. 3 may be configured not to be provided with the bypass on-off valve 53.
- the pressure of the gas is increased to a high pressure prior to the measuring step 61, but the pressure may be increased at the same time as the start of the measuring step 61 or later than the start of the measuring step 61.
- the boosting period 71 for boosting the gas in the molding cycle may be at least partially overlapped with the measuring step 61.
- the gas is reduced to a low pressure, that is, the pressure is reduced in the steps other than the measuring step 61, the supply of the gas may be stopped. However, if the pressure drops too low, the gas dissolved in the resin separates and begins to foam in the heating cylinder 18 during the pressurization period 71, so that the gas pressure must be maintained to such an extent that foaming does not occur.
- Gas supply source (102) and A gas pressure adjusting unit (34) that adjusts the pressure of gas from the gas supply source (102) and supplies the gas to the gas inlet (30) is provided.
- the gas pressure adjusting unit (34) is a gas supply device (5) in which the gas pressure is changed in the molding cycle, and the boosting period for boosting the gas pressure is at least partially overlapped with the measuring step.
- the gas supply device (5) according to any one of [1] to [5], wherein the gas pressure adjusting unit (34) includes one or a plurality of pressure reducing valves (38, 39).
- the gas pressure adjusting unit (34) includes at least a high pressure adjusting unit (36) for adjusting the gas pressure to a high pressure and a low pressure adjusting unit (37) for adjusting the gas pressure to a low pressure.
- the gas supply device (5) according to the above section.
- the gas supply device (5) according to any one of [1] to [8], wherein the gas pressure adjusting unit (34) includes a boosting mechanism (56) for boosting the gas pressure.
- a mold clamping device (2) that molds the molds (13, 14) and Equipped with an injection device (3) that injects resin,
- the injection device (3) includes a heating cylinder (18) provided with a gas injection port (30) and a heating cylinder (18).
- a screw (19) provided so as to be driveable in the heating cylinder (18), Gas supply source (102) and A gas pressure adjusting unit (34) that adjusts the pressure of gas from the gas supply source (102) and supplies the gas to the gas inlet (30) is provided.
- the gas pressure adjusting unit (34) is adapted to change the gas pressure in the molding cycle, and the pressurizing period for boosting the gas pressure overlaps at least a part with the measuring step.
- Injection molding machine (1) [11] The injection molding machine (1) according to [10], wherein the gas pressure adjusting unit (34) lowers the gas pressure before, at the time of completion, or after a specified time of completion of the measuring process of the molding cycle. [12] The injection molding machine (1) according to [10] or [11], wherein the gas pressure adjusting unit (34) switches the gas pressure to two or more stages in a molding cycle. [13] The injection molding machine (1) according to any one of [10] to [12], wherein the gas supply source (102) is composed of one or a plurality of gas cylinders (33).
- the injection molding machine (1) according to any one of [10] to [13], wherein two or more gas injection ports (30) are provided in the heating cylinder (18).
- the gas pressure adjusting unit (34) includes one or a plurality of pressure reducing valves (38, 39).
- the gas pressure adjusting unit (34) includes at least a high pressure adjusting unit (36) for adjusting the gas pressure to a high pressure and a low pressure adjusting unit (37) for adjusting the gas pressure to a low pressure.
- the gas pressure adjusting unit (34) includes a boosting mechanism (56) for boosting the gas pressure.
- a heating cylinder (18) provided with a gas inlet (30) and A screw (19) provided so as to be driveable in the heating cylinder (18) A foam molding method for obtaining a foam molded product in an injection molding machine (1) equipped with a gas supply source (102). The pressure of the gas from the gas supply source (102) is adjusted by the gas pressure adjusting process so that the gas is supplied from the gas inlet (30) to the heating cylinder (18).
- the foam molding method wherein the gas pressure adjusting process changes the gas pressure in the molding cycle, and the pressurizing period for boosting the gas pressure overlaps at least a part with the measuring step.
- the foam molding method according to [19] or [20], wherein the gas pressure adjusting process switches the gas pressure to two or more stages in a molding cycle.
- the gas pressure is changed by the gas pressure adjusting unit of the gas supply device, and the boosting period in which the gas pressure is increased overlaps with the measuring process. Therefore, since the high-pressure gas is supplied to the resin when the resin is sent from the upstream to the downstream in the weighing process, the gas is efficiently dissolved in the resin. At this time, since the resin flows from the upstream to the downstream, backflow of gas is unlikely to occur.
- the present invention exhibiting this effect is useful for gas supply devices, injection molding machines and foam molding methods.
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Abstract
Description
<射出成形機>
本実施の形態に係る射出成形機1は、図1に示されているように、ベッドBに設けられている型締装置2と射出装置3とガス供給装置5とから概略構成されている。ガス供給装置5は本実施の形態において特徴的な装置であり、後で詳しく説明する。
型締装置2は直圧式から構成することもでき、型開閉する機構についてその種類は限定されない。本実施の形態に係る型締装置2はトグル式からなる。すなわち、型締装置2は、固定盤7と、可動盤8と、型締ハウジング9と、型締ハウジング9と固定盤7とを連結しているタイバ-10、10、…と、トグル機構11とから構成されている。型締装置2は、金型13、14が固定盤7と可動盤8とに設けられている。トグル機構11を駆動すると金型13、14が型締めされるようになっている。
本実施の形態に係る射出装置3は物理発泡剤つまりガスを使用した発泡成形用の射出装置になっており、図1にはその外観が簡略的に、そして図2には断面図で示されている。射出装置3は加熱シリンダ18と、この加熱シリンダ18に入れられているスクリュ19とから構成されている。スクリュ19は、上流側から下流側に向かってフライトの溝深さが変化しており、加熱シリンダ18内が複数の区間に区分されている。すなわち加熱シリンダ18内は、上流側から、樹脂が供給され溶融する供給区間22、溶融した樹脂が圧縮される第1の圧縮区間23、溝深さが深く樹脂の圧力が低下する飢餓区間24、そして第2の圧縮区間25に区分されている。加熱シリンダ18には上流にホッパ27が、そして先端には射出ノズル29が設けられ、飢餓区間24に対応する位置には内部にガスを注入するガス注入口30が設けられている。
本実施の形態に係るガス供給装置5を説明する前に、従来のガス供給装置101について説明する。従来のガス供給装置101は、図6に示されているように、ガス供給源つまりガスボンベ102と、このガスボンベ102から供給される高圧のガスを低圧の2次圧力に減圧する減圧弁103と、2次圧力が供給される管路に必要に応じて設けられる逆止弁104と、同様に必要に応じて設けられる開閉弁106とから構成されている。2次圧力にされたガスがガス注入口30から加熱シリンダ18内に注入されるようになっている。
本発明に係るガス供給装置5は色々な実施の形態を採ることができるが、最初に、図2に示されている、第1の実施の形態に係るガス供給装置5Aを説明する。ガス供給装置5Aは、ガス供給源としてのガスボンベ33、33と、ガス供給源から供給されるガスの圧力を調整するガス圧力調整部34とから構成されている。ガス圧力調整部34には、従来のガス供給装置101にはない構成が設けられている。すなわちガス圧力を高圧に調整する高圧調整部36と、低圧に調整する低圧調整部37である。
本実施の第1の形態に係るガス供給装置5Aを備えた本実施の形態に係る射出成形機1によって実施する発泡成形方法は、端的に言うと成形サイクルにおいて能動的にガス圧力を変化させる方法である。具体的には、計量工程においてガス圧力を昇圧し、他の工程において降圧する。計量工程では樹脂が加熱シリンダ18内を上流から下流に流れるため、ガスが加熱シリンダ18内を逆流するおそれがない。この計量工程でガスを昇圧して高圧にするので、効率よく大量のガスを樹脂に溶解させることができる。計量工程が完了すると加熱シリンダ18内における樹脂の流れが停止するのでガスが逆流する可能性がある。このときにガスを降圧して低圧にするので逆流を防止できる。発泡成形方法について、図2及び図7を参照しながらさらに説明する。
ガス供給装置5は色々な変形が可能である。図3には第2の実施の形態に係るガス供給装置5Bが示されている。第1の実施の形態と同様の部材、部品には同じ符号を付して説明を省略する。この実施の形態に係る射出装置3Bには、2個のガス注入口、つまり第1、2のガス注入口30a、30bが設けられている。第2の実施の形態に係るガス供給装置5Bは、これら第1、2のガス注入口30a、30bにガスを注入するようになっている。
図4には第3の実施の形態に係るガス供給装置5Cが示されている。第1の実施の形態と同様の部材、部品には同じ符号を付して説明を省略する。この第3の実施の形態に係るガス供給装置5Cは、高圧調整部36は高圧ピストンによって駆動されるシリンジ56からなり、低圧調整部37の下流に接続されている。このシリンジ56は十分な量の低圧のガスを貯留することができ、ピストンを駆動するとこれが圧縮されて高圧のガスを供給できるようになっている。つまりシリンジ56は、ガスを昇圧する昇圧機構になっている。そのため、計量工程61においてコントローラ31は、低圧側開閉弁45を閉じた後、シリンジ56を駆動してガスを昇圧して高圧のガスを供給すればよい。
図5には第4の実施の形態に係るガス供給装置5Dが示されている。第1の実施の形態と同様の部材、部品には同じ符号を付して説明を省略する。この第4の実施の形態に係るガス供給装置5Dは、ガス供給源が窒素ガス発生装置80とガスを圧縮するブースターポンプ81とから構成されている。このガス供給源からの管路には、自動圧力調整機能付き減圧弁83が設けられている。この減圧弁83はコントローラ31(図1参照)からの指令によって設定圧力を変更することができる。この減圧弁83の下流には圧力計84、逆止弁85、開閉弁86が設けられガス注入口30に接続されている。計量工程においては自動圧力調整機能付き減圧弁83においてガスを高圧にして供給し、他の工程においては低圧にして供給する。
第3の実施の形態に係るガス供給装置5C、あるいは第4の実施の形態に係るガス供給装置5Dによって運転する場合、ガスの圧力を高圧、中圧、低圧等のように3段階以上にして供給することもできる。図8には、3段階にガスの圧力を変化させて供給する発泡成形方法における各データの変化が示されている。すなわち、昇圧期間は、ガス圧力68が中圧の昇圧期間71aと、ガス圧力68が高圧の昇圧期間71bと、からなる。ガス圧力68は、計量工程61に先立って符号69aのタイミングで低圧から中圧に切り替える。ついで計量工程61が開始された後に符号69bのタイミングでガスの圧力を中圧から高圧に切り替える。計量工程61が完了するより若干前に符号70のタイミングで高圧から低圧に切り替えると、その後ガス圧力68は緩やかに低圧に変化する。さらに、ガス圧力68の昇圧、降圧は滑らかに実施してもよい。すなわち計量工程61中に除々に圧力を上げていっても良い。また、第1、2の実施の形態において昇圧機構を高圧調整部36に設け、計量工程61中に3段階あるいはそれ以上に分けて圧力を調整するなどの変形例も可能である。
本実施の形態に係る射出成形機1、および本実施の形態に係る発泡成形方法は他にも色々な変形が可能である。例えばガス注入口30にはガス供給装置5からの管路が直接接続されているように説明したが、ガス注入口30の近傍に小容積のバッファを設けてもよい。このバッファがクッションになってガス圧力の急激な変化を抑制できる。しかし、本発明で最大の効果を得るためには、バッファは高圧調整部36の高圧側逆止弁41と高圧側開閉弁44との間に設ける方が望ましい。高圧側開閉弁44より下流側、つまりガス注入口30付近にバッファを設けると、圧力を高圧あるいは低圧に切替えた際に、バッファの緩衝作用により圧力の切替に時間を要するためである。一方で、高圧調整部36にバッファを設けると、高圧側開閉弁44を開いて圧力を低圧から高圧に切替えた直後の高圧調整部36の圧力低下を抑制し、加熱シリンダ18内の昇圧を速く行うことができる。
[1]
ガス注入口(30)が設けられている加熱シリンダ(18)と、
前記加熱シリンダ(18)内で駆動可能に設けられているスクリュ(19)と、を備えた射出装置(3)に設けられ、
ガス供給源(102)と、
前記ガス供給源(102)からのガスの圧力を調整して前記ガス注入口(30)に供給するガス圧力調整部(34)と、を備え、
前記ガス圧力調整部(34)は成形サイクルにおいてガス圧力を変化させるようにし、ガス圧力を昇圧する昇圧期間は計量工程と少なくとも一部が重複するようにする、ガス供給装置(5)。
[2]
前記ガス圧力調整部(34)は成形サイクルの計量工程の完了の規定時間前、完了時、あるいは完了から規定時間後にガス圧力を降圧する、[1]に記載のガス供給装置(5)。
[3]
前記ガス圧力調整部(34)は成形サイクルにおいてガス圧力を2段階以上に切り替える、[1]または[2]に記載のガス供給装置(5)。
[4]
前記ガス供給源(102)は1本または複数本のガスボンベ(33)からなる、[1]~[3]のいずれかの項に記載のガス供給装置(5)。
[5]
前記ガス注入口(30)は前記加熱シリンダ(18)に2個以上設けられている、[1]~[4]のいずれかの項に記載のガス供給装置(5)。
[6]
前記ガス圧力調整部(34)は1個または複数個の減圧弁(38、39)を備えている、[1]~[5]のいずれかの項に記載のガス供給装置(5)。
[7]
前記ガス圧力調整部(34)は少なくともガス圧力を高圧に調整する高圧調整部(36)と、低圧に調整する低圧調整部(37)とを備えている、[1]~[6]のいずれかの項に記載のガス供給装置(5)。
[8]
前記高圧調整部(36)は、バッファを備えている、[1]~[7]のいずれかの項に記載のガス供給装置(5)。
[9]
前記ガス圧力調整部(34)は、ガス圧力を昇圧する昇圧機構(56)を備えている、[1]~[8]のいずれかの項に記載のガス供給装置(5)。
[10]
金型(13、14)を型締する型締装置(2)と、
樹脂を射出する射出装置(3)と、を備え、
前記射出装置(3)は、ガス注入口(30)が設けられている加熱シリンダ(18)と、
前記加熱シリンダ(18)内で駆動可能に設けられているスクリュ(19)と、
ガス供給源(102)と、
前記ガス供給源(102)からのガスの圧力を調整して前記ガス注入口(30)に供給するガス圧力調整部(34)と、を備え、
前記ガス圧力調整部(34)は成形サイクルにおいてガス圧力を変化させるようになっており、ガス圧力を昇圧する昇圧期間が計量工程と少なくとも一部が重複するようになっている、
射出成形機(1)。
[11]
前記ガス圧力調整部(34)は成形サイクルの計量工程の完了の規定時間前、完了時、あるいは完了から規定時間後にガス圧力を降圧する、[10]に記載の射出成形機(1)。
[12]
前記ガス圧力調整部(34)は成形サイクルにおいてガス圧力を2段階以上に切り替える、[10]または[11]に記載の射出成形機(1)。
[13]
前記ガス供給源(102)は1本または複数本のガスボンベ(33)からなる、[10]~[12]のいずれかの項に記載の射出成形機(1)。
[14]
前記ガス注入口(30)は前記加熱シリンダ(18)に2個以上設けられている、[10]~[13]のいずれかの項に記載の射出成形機(1)。
[15]
前記ガス圧力調整部(34)は1個または複数個の減圧弁(38、39)を備えている、[10]~[14]のいずれかの項に記載の射出成形機(1)。
[16]
前記ガス圧力調整部(34)は少なくともガス圧力を高圧に調整する高圧調整部(36)と、低圧に調整する低圧調整部(37)とを備えている、[10]~[15]のいずれかの項に記載の射出成形機(1)。
[17]
前記高圧調整部(36)は、バッファを備えている、[10]~[16]のいずれかの項に記載の射出成形機(1)。
[18]
前記ガス圧力調整部(34)は、ガス圧力を昇圧する昇圧機構(56)を備えている、[10]~[17]のいずれかの項に記載の射出成形機(1)。
[19]
ガス注入口(30)が設けられている加熱シリンダ(18)と、
前記加熱シリンダ(18)内で駆動可能に設けられているスクリュ(19)と、
ガス供給源(102)と、を備えた射出成形機(1)において発泡成形品を得る発泡成形方法であって、
前記ガス供給源(102)からのガスはガス圧力調整処理によって圧力を調整して前記ガス注入口(30)から前記加熱シリンダ(18)に供給するようにし、
前記ガス圧力調整処理は成形サイクルにおいてガス圧力を変化させるようになっており、ガス圧力を昇圧する昇圧期間が計量工程と少なくとも一部が重複するようになっている、発泡成形方法。
[20]
前記ガス圧力調整処理は成形サイクルの計量工程の完了の規定時間前、完了時、あるいは完了から規定時間後にガス圧力を降圧する、[19]に記載の発泡成形方法。
[21]
前記ガス圧力調整処理は成形サイクルにおいてガス圧力を2段階以上に切り替える、[19]または[20]に記載の発泡成形方法。
[22]
前記ガス供給源(102)は1本または複数本のガスボンベ(33)からなる、[19]~[21]のいずれかの項に記載の発泡成形方法。
[23]
前記ガス注入口(30)は前記加熱シリンダ(18)に2個以上設けられている、[19]~[22]のいずれかの項に記載の発泡成形方法。
[24]
前記ガス圧力調整処理は1個または複数個の減圧弁(38、39)によりガス圧力を調整する、[19]~[23]のいずれかの項に記載の発泡成形方法。
[25]
前記ガス圧力調整処理は少なくともガス圧力を高圧に調整する高圧調整処理と、低圧に調整する低圧調整処理とを備えている、[19]~[24]のいずれかの項に記載の発泡成形方法。
[26]
前記ガス圧力調整処理は、ガス圧力を昇圧する昇圧処理を備えている、[19]~[25]のいずれかの項に記載の発泡成形方法。
3 射出装置 5 ガス供給装置
18 加熱シリンダ 19 スクリュ
22 供給区間 23 第1の圧縮区間
24 飢餓区間 25 第2の圧縮区間
30 ガス注入口 31 コントロ-ラ
33 ガスボンベ 34 ガス圧力調整部
36 高圧調整部 37 低圧調整部
38 高圧減圧弁 39 低圧減圧弁
41 高圧側逆止弁 42 低圧側逆止弁
44 高圧側開閉弁 45 低圧側開閉弁
47 供給源圧力計 48 高圧圧力計
49 低圧圧力計 51 注入圧圧力計
61 計量工程 62 スクリュ回転数
63 スクリュ位置 65 射出工程
67 ガスの必要量 68 ガス圧力
71 昇圧期間
Claims (26)
- ガス注入口が設けられている加熱シリンダと、
前記加熱シリンダ内で駆動可能に設けられているスクリュと、を備えた射出装置に設けられ、
ガス供給源と、
前記ガス供給源からのガスの圧力を調整して前記ガス注入口に供給するガス圧力調整部と、を備え、
前記ガス圧力調整部は成形サイクルにおいてガス圧力を変化させるようにし、ガス圧力を昇圧する昇圧期間は計量工程と少なくとも一部が重複するようにする、ガス供給装置。 - 前記ガス圧力調整部は成形サイクルの計量工程の完了の規定時間前、完了時、あるいは完了から規定時間後にガス圧力を降圧する、請求項1に記載のガス供給装置。
- 前記ガス圧力調整部は成形サイクルにおいてガス圧力を2段階以上に切り替える、請求項1または2に記載のガス供給装置。
- 前記ガス供給源は1本または複数本のガスボンベからなる、請求項1~3のいずれかの項に記載のガス供給装置。
- 前記ガス注入口は前記加熱シリンダに2個以上設けられている、請求項1~4のいずれかの項に記載のガス供給装置。
- 前記ガス圧力調整部は1個または複数個の減圧弁を備えている、請求項1~5のいずれかの項に記載のガス供給装置。
- 前記ガス圧力調整部は少なくともガス圧力を高圧に調整する高圧調整部と、低圧に調整する低圧調整部とを備えている、請求項1~6のいずれかの項に記載のガス供給装置。
- 前記高圧調整部は、バッファを備えている、請求項7のいずれかの項に記載のガス供給装置。
- 前記ガス圧力調整部は、ガス圧力を昇圧する昇圧機構を備えている、請求項1~8のいずれかの項に記載のガス供給装置。
- 金型を型締する型締装置と、
樹脂を射出する射出装置と、を備え、
前記射出装置は、ガス注入口が設けられている加熱シリンダと、
前記加熱シリンダ内で駆動可能に設けられているスクリュと、
ガス供給源と、
前記ガス供給源からのガスの圧力を調整して前記ガス注入口に供給するガス圧力調整部と、を備え、
前記ガス圧力調整部は成形サイクルにおいてガス圧力を変化させるようになっており、ガス圧力を昇圧する昇圧期間が計量工程と少なくとも一部が重複するようになっている、
射出成形機。 - 前記ガス圧力調整部は成形サイクルの計量工程の完了の規定時間前、完了時、あるいは完了から規定時間後にガス圧力を降圧する、請求項10に記載の射出成形機。
- 前記ガス圧力調整部は成形サイクルにおいてガス圧力を2段階以上に切り替える、請求項10または11に記載の射出成形機。
- 前記ガス供給源は1本または複数本のガスボンベからなる、請求項10~12のいずれかの項に記載の射出成形機。
- 前記ガス注入口は前記加熱シリンダに2個以上設けられている、請求項10~13のいずれかの項に記載の射出成形機。
- 前記ガス圧力調整部は1個または複数個の減圧弁を備えている、請求項10~14のいずれかの項に記載の射出成形機。
- 前記ガス圧力調整部は少なくともガス圧力を高圧に調整する高圧調整部と、低圧に調整する低圧調整部とを備えている、請求項10~15のいずれかの項に記載の射出成形機。
- 前記高圧調整部は、バッファを備えている、請求項16のいずれかの項に記載の射出成形機。
- 前記ガス圧力調整部は、ガス圧力を昇圧する昇圧機構を備えている、請求項10~17のいずれかの項に記載の射出成形機。
- ガス注入口が設けられている加熱シリンダと、
前記加熱シリンダ内で駆動可能に設けられているスクリュと、
ガス供給源と、を備えた射出成形機において発泡成形品を得る発泡成形方法であって、
前記ガス供給源からのガスはガス圧力調整処理によって圧力を調整して前記ガス注入口から前記加熱シリンダに供給するようにし、
前記ガス圧力調整処理は成形サイクルにおいてガス圧力を変化させるようになっており、ガス圧力を昇圧する昇圧期間が計量工程と少なくとも一部が重複するようになっている、発泡成形方法。 - 前記ガス圧力調整処理は成形サイクルの計量工程の完了の規定時間前、完了時、あるいは完了から規定時間後にガス圧力を降圧する、請求項19に記載の発泡成形方法。
- 前記ガス圧力調整処理は成形サイクルにおいてガス圧力を2段階以上に切り替える、請求項19または20に記載の発泡成形方法。
- 前記ガス供給源は1本または複数本のガスボンベからなる、請求項19~21のいずれかの項に記載の発泡成形方法。
- 前記ガス注入口は前記加熱シリンダに2個以上設けられている、請求項19~22のいずれかの項に記載の発泡成形方法。
- 前記ガス圧力調整処理は1個または複数個の減圧弁によりガス圧力を調整する、請求項19~23のいずれかの項に記載の発泡成形方法。
- 前記ガス圧力調整処理は少なくともガス圧力を高圧に調整する高圧調整処理と、低圧に調整する低圧調整処理とを備えている、請求項19~24のいずれかの項に記載の発泡成形方法。
- 前記ガス圧力調整処理は、ガス圧力を昇圧する昇圧処理を備えている、請求項19~25のいずれかの項に記載の発泡成形方法。
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ES2765731T3 (es) | 2014-11-13 | 2020-06-10 | Applied Med Resources | Modelos y métodos de simulación de tejido |
JP6758790B2 (ja) | 2019-01-11 | 2020-09-23 | 株式会社日本製鋼所 | 発泡成形用の射出成形機のスクリュおよび射出成形機 |
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2020
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2021
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Patent Citations (5)
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JP2002067116A (ja) * | 2000-08-24 | 2002-03-05 | Meiki Co Ltd | ガス溶解樹脂の射出成形方法および射出装置 |
JP2003039473A (ja) * | 2001-07-30 | 2003-02-13 | Japan Steel Works Ltd:The | 発泡剤用ガス供給装置、それを用いた熱可塑性樹脂発泡体の成形装置及び熱可塑性樹脂発泡体の成形方法 |
JP2019018522A (ja) * | 2017-07-21 | 2019-02-07 | 株式会社日本製鋼所 | 発泡成形用の射出成形機 |
US20190118432A1 (en) * | 2017-10-23 | 2019-04-25 | Trexel, Inc. | Blowing agent introduction in polymer foam processing |
WO2020184486A1 (ja) * | 2019-03-08 | 2020-09-17 | 三恵技研工業株式会社 | 発泡成形体の製造装置、発泡成形体の製造方法および発泡成形体製造装置用スクリュ |
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US20240017452A1 (en) | 2024-01-18 |
KR20230117727A (ko) | 2023-08-09 |
JP7576442B2 (ja) | 2024-10-31 |
CN116472157A (zh) | 2023-07-21 |
TW202235247A (zh) | 2022-09-16 |
JP2022089258A (ja) | 2022-06-16 |
DE112021006310T5 (de) | 2023-09-21 |
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