WO2022073527A3 - 一种提高耐水性能的矿物棉专用无甲醛定型剂 - Google Patents

一种提高耐水性能的矿物棉专用无甲醛定型剂 Download PDF

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WO2022073527A3
WO2022073527A3 PCT/CN2022/072535 CN2022072535W WO2022073527A3 WO 2022073527 A3 WO2022073527 A3 WO 2022073527A3 CN 2022072535 W CN2022072535 W CN 2022072535W WO 2022073527 A3 WO2022073527 A3 WO 2022073527A3
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parts
monomer
mineral wool
setting agent
water
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PCT/CN2022/072535
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English (en)
French (fr)
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WO2022073527A2 (zh
WO2022073527A9 (zh
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朱玉国
李炳泉
董春生
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江苏艾科赛特新材料有限公司
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Priority to JP2022554462A priority Critical patent/JP7269689B2/ja
Priority to KR1020247003510A priority patent/KR20240028465A/ko
Publication of WO2022073527A2 publication Critical patent/WO2022073527A2/zh
Publication of WO2022073527A3 publication Critical patent/WO2022073527A3/zh
Publication of WO2022073527A9 publication Critical patent/WO2022073527A9/zh

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/14—Esterification
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/04—Acids; Metal salts or ammonium salts thereof
    • C08F220/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02—Macromolecular compounds
    • C04B26/04—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B26/06—Acrylates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/44—Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/20—Esters of polyhydric alcohols or phenols, e.g. 2-hydroxyethyl (meth)acrylate or glycerol mono-(meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/54—Silicon-containing compounds
    • C08K5/541—Silicon-containing compounds containing oxygen
    • C08K5/5435—Silicon-containing compounds containing oxygen containing oxygen in a ring
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    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00017—Aspects relating to the protection of the environment
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
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    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20—Resistance against chemical, physical or biological attack
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    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
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    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20—Resistance against chemical, physical or biological attack
    • C04B2111/27—Water resistance, i.e. waterproof or water-repellent materials
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50—Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

涉及一种提高耐水性能的矿物棉专用无甲醛定型剂，按100％固含量计算，包括以下重量配比的组分：可水溶性树脂预聚物：100份；多元醇：10～70份；催化剂：2～15份。其中，可水溶性树脂预聚物由单体原料通过共聚反应制得，单体原料按物质的量计包括如下组分：烯键式不饱和羧酸单体：90.0～99.0％；烯键式不饱和羟基功能单体：0.5～5.0％；疏水性烯键式不饱和单体：0.5～5.0％。提供的定型剂无游离甲醛释放，达到绿色环保无VOC和无甲醛的标准要求，具有良好的稳定性，可长期稳定储存，方便工业使用，同时所生产的矿棉板硬度优于传统的丙烯酸均聚物产品，具有良好的耐水耐老化性能和施工性能。
PCT/CN2022/072535 2021-12-30 2022-01-18 一种提高耐水性能的矿物棉专用无甲醛定型剂 WO2022073527A2 (zh)

Priority Applications (2)

Application Number Priority Date Filing Date Title
JP2022554462A JP7269689B2 (ja) 2021-12-30 2022-01-18 耐水性を向上させるミネラルウール専用ホルムアルデヒドフリー成形剤
KR1020247003510A KR20240028465A (ko) 2021-12-30 2022-01-18 내수성을 향상시키는 광물면 전용 무포름알데히드 정형화제

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CN202111654376.0A CN114380938B (zh) 2021-12-30 2021-12-30 一种提高耐水性能的矿物棉专用无甲醛定型剂
CN202111654376.0 2021-12-30

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WO2022073527A2 WO2022073527A2 (zh) 2022-04-14
WO2022073527A3 true WO2022073527A3 (zh) 2022-11-10
WO2022073527A9 WO2022073527A9 (zh) 2022-12-08

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JP (1) JP7269689B2 (zh)
KR (1) KR20240028465A (zh)
CN (1) CN114380938B (zh)
WO (1) WO2022073527A2 (zh)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115353296B (zh) * 2022-08-30 2024-03-01 武汉思越新材料有限公司 一种憎水剂组合物及其制备方法

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WO2021176866A1 (ja) * 2020-03-03 2021-09-10 株式会社日本触媒 結合剤及び固着体
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JP2007211161A (ja) * 2006-02-10 2007-08-23 Asahi Fiber Glass Co Ltd 無機繊維断熱吸音材用水性バインダー及び無機繊維断熱吸音材
CN102533168A (zh) * 2011-12-27 2012-07-04 华南理工大学 一种水性零甲醛玻璃棉粘合剂及其制备方法
US20210292609A1 (en) * 2018-07-24 2021-09-23 Sanyo Chemical Industries, Ltd. Moisture resistance improver for water-based adhesive for inorganic materials, and water-based adhesive for inorganic materials
WO2021176866A1 (ja) * 2020-03-03 2021-09-10 株式会社日本触媒 結合剤及び固着体
CN112521871A (zh) * 2020-12-29 2021-03-19 太尔胶粘剂(广东)有限公司 一种保温棉用水性胶粘剂及其制备方法

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Publication number Publication date
JP2023516211A (ja) 2023-04-18
KR20240028465A (ko) 2024-03-05
CN114380938B (zh) 2022-08-16
CN114380938A (zh) 2022-04-22
WO2022073527A2 (zh) 2022-04-14
JP7269689B2 (ja) 2023-05-09
WO2022073527A9 (zh) 2022-12-08

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