WO2021243941A1 - Filé de mélange de graphène anti-boulochage et tissu composite de fibres et procédé de fabrication associé - Google Patents

Filé de mélange de graphène anti-boulochage et tissu composite de fibres et procédé de fabrication associé Download PDF

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Publication number
WO2021243941A1
WO2021243941A1 PCT/CN2020/125327 CN2020125327W WO2021243941A1 WO 2021243941 A1 WO2021243941 A1 WO 2021243941A1 CN 2020125327 W CN2020125327 W CN 2020125327W WO 2021243941 A1 WO2021243941 A1 WO 2021243941A1
Authority
WO
WIPO (PCT)
Prior art keywords
pilling
fiber composite
blended yarn
composite fabric
graphene
Prior art date
Application number
PCT/CN2020/125327
Other languages
English (en)
Chinese (zh)
Inventor
张春涛
Original Assignee
席梦思床褥家具（苏州）有限公司
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 席梦思床褥家具（苏州）有限公司 filed Critical 席梦思床褥家具（苏州）有限公司
Publication of WO2021243941A1 publication Critical patent/WO2021243941A1/fr

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Classifications

    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/40—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads
    • D03D15/43—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads with differing diameters
    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/40—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads
    • D03D15/47—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads multicomponent, e.g. blended yarns or threads
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B15/00—Removing liquids, gases or vapours from textile materials in association with treatment of the materials by liquids, gases or vapours
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B3/00—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating
    • D06B3/10—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fabrics
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
    • D06M16/003—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic with enzymes or microorganisms
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02—Natural fibres, other than mineral fibres
    • D06M2101/04—Vegetal fibres
    • D06M2101/06—Vegetal fibres cellulosic
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/32—Polyesters
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/35—Abrasion, pilling or fibrillation resistance
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2101/00—Inorganic fibres
    • D10B2101/10—Inorganic fibres based on non-oxides other than metals
    • D10B2101/12—Carbon; Pitch
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/04—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]

Definitions

  • the invention relates to the technical field of fabric processing, in particular to an anti-pilling graphene blended yarn fiber composite fabric and a manufacturing method thereof.
  • Fabric is the material used to make clothing. As one of the three elements of clothing, fabrics can not only interpret the style and characteristics of clothing, but also directly influence the color and shape of clothing. In the world of clothing, the fabrics of clothing are varied and changing with each passing day. But generally speaking, high-quality and high-end fabrics have the characteristics of comfortable wearing, sweat-absorbing and breathable, crisp drape, noble vision, and soft touch.
  • Woven fabric also called woven fabric, is a fabric formed by weaving warp yarns and weft yarns perpendicular to each other.
  • Knitted fabric Knitted Fabric uses knitting needles to form loops of yarn or filaments, and then string the loops into each other.
  • Cotton cloth is the general term for all kinds of cotton textiles. Cotton cloth is divided into cotton, rayon and other varieties. It is mostly used to make fashion, casual wear, underwear and shirts. 2. Linen is a fabric made of hemp, flax, ramie, jute, sisal, abaca and other hemp plant fibers. 3.
  • Silk is a general term for all kinds of silk fabrics woven from silk as raw material. 4. Woolen cloth is also called wool, which is a general term for fabrics woven from various types of wool and cashmere. It is usually used to make formal and high-end clothing such as dresses, suits, and overcoats. 5.
  • leather is an animal fur fabric that has been tanned. It is mostly used to make fashion and winter clothes. It can be divided into two categories: one is leather, that is, leather that has been dehaired. The second is fur, that is, treated leather with belt hair.
  • Chemical fiber is the abbreviation for chemical fiber. It is a textile made of fibers using polymer compounds as raw materials. Usually it is divided into two categories: artificial fibers and synthetic fibers. Their common advantages are bright colors, soft texture, crisp drape, smoothness and comfort. 7.
  • Blended spinning is a fabric made by blending natural fibers and chemical fibers in a certain ratio, which can be used to make various garments.
  • Modal is a cellulose regenerated fiber of high wet modulus viscose fiber.
  • the raw material of this fiber is European beech wood, which is first made into wood pulp, and then processed into fibers through a special spinning process.
  • the raw materials of the product are all natural materials, which are harmless to the human body, and can be decomposed naturally, which is harmless to the environment.
  • the existing fabrics are prone to pilling and fluffing after being worn for a long time, and have poor abrasion resistance. For this reason, an anti-pilling graphene blended yarn fiber composite fabric and a manufacturing method thereof are proposed.
  • the purpose of the present invention is to provide an anti-pilling graphene blended yarn fiber composite fabric and a manufacturing method thereof, so as to solve the problem that the existing fabrics are prone to pilling and fluffing after being worn for a long time and have poor abrasion resistance.
  • the present invention provides the following technical solution: anti-pilling graphene blended yarn fiber composite fabric, which is interlaced with warp yarns and weft yarns, and the warp yarns are woven by a blend of rayon and artificial fibers.
  • the weft yarn is woven from polyester.
  • the proportion of the artificial cotton is 3%.
  • the proportion of the polyester is 75%.
  • the rayon fiber is immersed in a rayon fiber solution, graphene is added to the rayon fiber solution, and the proportion of the rayon fiber is 12%.
  • the ratio of the graphene to the rayon fiber solution is 4:6.
  • the diameter of the warp yarn is 25 micrometers, and the diameter of the weft yarn is 28 micrometers.
  • the rayon 3%, the rayon 12% and the polyester 75% are mixed and woven, and the rayon, the rayon and the polyester are treated with anti-pilling polishing surface treatment.
  • the present invention also provides a method for manufacturing the anti-pilling graphene blended yarn fiber composite fabric, which includes the following steps:
  • liquid preparation add 6-9 kilograms of water in the liquid mixing container, slowly add 2-4 kilograms of rayon solution in the clean water, at the same time, continue to add 2-4 kg of graphene solution, rayon solution and graphite in the water
  • the preparation ratio of the alkene solution is 4:6, stirring slowly and continuously to make it completely and fully mixed;
  • Impregnation add the configured impregnation solution to the impregnation equipment, place the anti-pilling graphene blended yarn fiber composite fabric in the impregnation equipment, and impregnate the anti-pilling graphene blended yarn fiber composite fabric, and the immersion time It is 30-50 minutes.
  • the humidity of the immersion environment is 80%-90%, and the wind speed of the air is 1-9m/h;
  • Graphene is a two-dimensional carbon nanomaterial with a hexagonal honeycomb lattice composed of carbon atoms and sp 2 hybrid orbitals. It has high strength, good toughness, and excellent electrical and thermal conductivity and optical properties. Using 3% rayon 12% graphene (graphene added to man-made fiber solution to spin) blended yarn combined with 75% polyester composition, so that the fabric has a good antistatic effect. And like cotton, it is moisture-absorbing, breathable, skin-friendly and comfortable. The textile fabric is treated with anti-pilling treatment during the finishing process, which gives the fabric excellent anti-pilling performance, reduces the tendency of the fabric to fluff, and obviously improves the abrasion resistance of the fabric.
  • the fiber indirect agent is a two-dimensional carbon nanomaterial with a hexagonal honeycomb lattice composed of carbon atoms and sp 2 hybrid orbitals. It has high strength, good toughness, and excellent electrical and thermal conductivity and optical properties. Using 3% rayon 12% graphene (graphene added
  • the present invention provides a technical solution: anti-pilling graphene blended yarn fiber composite fabric, which is formed by interlacing warp yarns and weft yarns.
  • the warp yarns are woven by a blend of rayon and man-made fibers, and the weft yarns are made of polyester. Woven.
  • the proportion of the artificial cotton is 3%.
  • the proportion of the polyester is 75%.
  • the rayon fiber is immersed in a rayon fiber solution, graphene is added to the rayon fiber solution, and the proportion of the rayon fiber is 12%.
  • the ratio of the graphene to the rayon fiber solution is 4:6.
  • the diameter of the warp yarn is 25 microns, and the diameter of the weft yarn is 28 microns.
  • the rayon 3%, rayon 12%, and polyester 75% are mixed and woven, and the rayon, rayon and polyester are treated with anti-pilling and polishing surface treatment.
  • the present invention also provides a method for manufacturing the anti-pilling graphene blended yarn fiber composite fabric, which includes the following steps:
  • liquid preparation add 6 kg of water in the liquid container, slowly add 2 kg of rayon solution in the water, and at the same time, continue to add 2 kg of graphene solution in the water, the preparation ratio of rayon solution to graphene solution is 4:6, stir slowly and continuously to make it completely and fully mixed;
  • Impregnation add the configured impregnation solution to the impregnation equipment, place the anti-pilling graphene blended yarn fiber composite fabric in the impregnation equipment, and impregnate the anti-pilling graphene blended yarn fiber composite fabric, and the immersion time For 30 minutes, during the immersion process, the humidity of the immersion environment is 80%, and the wind speed of the air is 1m/h;
  • the manufacturing method of anti-pilling graphene blended yarn fiber composite fabric includes the following steps:
  • liquid preparation add 9 kg of water in the liquid container, slowly add 4 kg of rayon solution in the water, and at the same time, continue to add 4 kg of graphene solution in the water, the preparation ratio of rayon solution to graphene solution is 4:6, stir slowly and continuously to make it completely and fully mixed;
  • Impregnation add the configured impregnation solution to the impregnation equipment, place the anti-pilling graphene blended yarn fiber composite fabric in the impregnation equipment, and impregnate the anti-pilling graphene blended yarn fiber composite fabric, and the immersion time For 50 minutes, during the immersion process, the humidity of the immersion environment is 90%, and the wind speed of the air is 9m/h;
  • the manufacturing method of anti-pilling graphene blended yarn fiber composite fabric includes the following steps:
  • liquid preparation add 7.5 kg of water in the liquid mixing container, slowly add 3 kg of rayon solution in the water, at the same time, continue to add 3 kg of graphene solution in the water, the preparation ratio of rayon solution to graphene solution is 4:6, stir slowly and continuously to make it completely and fully mixed;
  • Impregnation add the configured impregnation solution to the impregnation equipment, place the anti-pilling graphene blended yarn fiber composite fabric in the impregnation equipment, and impregnate the anti-pilling graphene blended yarn fiber composite fabric, and the immersion time For 40 minutes, during the immersion process, the humidity of the immersion environment is 85%, and the wind speed of the air is 5m/h;

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Biochemistry (AREA)
  • Microbiology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)

Abstract

L'invention concerne un filé de mélange de graphène anti-boulochage et un tissu composite de fibres et un procédé de fabrication associé. Le filé de mélange de graphène anti-boulochage et le tissu composite à base de fibres sont formés par entrelacement de fils de chaîne et de fils de trame; les fils de chaîne sont formés par mélange et tissage de coton artificiel et de fibres artificielles ; les fils de trame sont formés par tissage de polyester ; la proportion du coton artificiel est de 3 %, et la proportion du polyester est de 75 % ; les fibres artificielles sont trempées dans une solution de fibres artificielles ; du graphène est ajouté à la solution de fibres artificielles ; la proportion des fibres artificielles est de 12 % ; 3 % de coton artificiel, 12 % de fibres artificielles et 75 % de polyester sont mélangés et tissés ; et le coton artificiel, les fibres artificielles et le polyester sont soumis à un traitement de broyage anti-boulochage de surface. Les filés de mélange de coton artificiel et de graphène (tissés par ajout de graphène à la solution de fibres artificielles) sont combinés à 75 % de polyester, le tissu présente un effet antistatique, une propriété d'adsorption d'humidité, une respirabilité, un respect de la peau et un confort qui sont très bons ; un tissu textile est soumis à un traitement anti-boulochage ; le tissu est doté d'une excellente résistance au boulochage ; la tendance au peluchage du tissu est réduite ; et la résistance à l'usure du tissu est manifestement améliorée.
PCT/CN2020/125327 2020-06-04 2020-10-30 Filé de mélange de graphène anti-boulochage et tissu composite de fibres et procédé de fabrication associé WO2021243941A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN202010500459.3 2020-06-04
CN202010500459.3A CN111519316A (zh) 2020-06-04 2020-06-04 抗起球石墨烯混纺纱纤维复合面料及其制造方法

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CN114892402A (zh) * 2022-04-22 2022-08-12 杭州聚源针纺有限公司 一种超柔软生态环保面料及其加工工艺
CN115182156A (zh) * 2022-06-22 2022-10-14 南通瑞意嘉纺织科技有限公司 一种含石墨烯纤维的混纺阻燃面料
CN118408852A (zh) * 2024-07-02 2024-07-30 南通博莎服装有限公司 一种成衣检测装置

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CN111519316A (zh) * 2020-06-04 2020-08-11 席梦思床褥家具（苏州）有限公司 抗起球石墨烯混纺纱纤维复合面料及其制造方法
CN115012094A (zh) * 2022-07-12 2022-09-06 席梦思床褥家具（苏州）有限公司 一种天丝石墨烯混纺纱防泼溅面料

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CN114892402A (zh) * 2022-04-22 2022-08-12 杭州聚源针纺有限公司 一种超柔软生态环保面料及其加工工艺
CN114892402B (zh) * 2022-04-22 2024-04-30 杭州聚源针纺有限公司 一种超柔软生态环保面料及其加工工艺
CN115182156A (zh) * 2022-06-22 2022-10-14 南通瑞意嘉纺织科技有限公司 一种含石墨烯纤维的混纺阻燃面料
CN115182156B (zh) * 2022-06-22 2024-04-16 南通瑞意嘉纺织科技有限公司 一种含石墨烯纤维的混纺阻燃面料
CN118408852A (zh) * 2024-07-02 2024-07-30 南通博莎服装有限公司 一种成衣检测装置

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