WO2021243941A1 - Anti-pilling graphene blended yarn and fiber composite fabric and manufacturing method therefor - Google Patents

Anti-pilling graphene blended yarn and fiber composite fabric and manufacturing method therefor Download PDF

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Publication number
WO2021243941A1
WO2021243941A1 PCT/CN2020/125327 CN2020125327W WO2021243941A1 WO 2021243941 A1 WO2021243941 A1 WO 2021243941A1 CN 2020125327 W CN2020125327 W CN 2020125327W WO 2021243941 A1 WO2021243941 A1 WO 2021243941A1
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Prior art keywords
pilling
fiber composite
blended yarn
composite fabric
graphene
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PCT/CN2020/125327
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French (fr)
Chinese (zh)
Inventor
张春涛
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席梦思床褥家具(苏州)有限公司
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Publication of WO2021243941A1 publication Critical patent/WO2021243941A1/en

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    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/40Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads
    • D03D15/43Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads with differing diameters
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/40Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads
    • D03D15/47Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads multicomponent, e.g. blended yarns or threads
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06BTREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B15/00Removing liquids, gases or vapours from textile materials in association with treatment of the materials by liquids, gases or vapours
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06BTREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B3/00Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating
    • D06B3/10Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fabrics
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M16/00Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
    • D06M16/003Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic with enzymes or microorganisms
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02Natural fibres, other than mineral fibres
    • D06M2101/04Vegetal fibres
    • D06M2101/06Vegetal fibres cellulosic
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16Synthetic fibres, other than mineral fibres
    • D06M2101/30Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/32Polyesters
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/35Abrasion, pilling or fibrillation resistance
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2101/00Inorganic fibres
    • D10B2101/10Inorganic fibres based on non-oxides other than metals
    • D10B2101/12Carbon; Pitch
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/04Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]

Definitions

  • the invention relates to the technical field of fabric processing, in particular to an anti-pilling graphene blended yarn fiber composite fabric and a manufacturing method thereof.
  • Fabric is the material used to make clothing. As one of the three elements of clothing, fabrics can not only interpret the style and characteristics of clothing, but also directly influence the color and shape of clothing. In the world of clothing, the fabrics of clothing are varied and changing with each passing day. But generally speaking, high-quality and high-end fabrics have the characteristics of comfortable wearing, sweat-absorbing and breathable, crisp drape, noble vision, and soft touch.
  • Woven fabric also called woven fabric, is a fabric formed by weaving warp yarns and weft yarns perpendicular to each other.
  • Knitted fabric Knitted Fabric uses knitting needles to form loops of yarn or filaments, and then string the loops into each other.
  • Cotton cloth is the general term for all kinds of cotton textiles. Cotton cloth is divided into cotton, rayon and other varieties. It is mostly used to make fashion, casual wear, underwear and shirts. 2. Linen is a fabric made of hemp, flax, ramie, jute, sisal, abaca and other hemp plant fibers. 3.
  • Silk is a general term for all kinds of silk fabrics woven from silk as raw material. 4. Woolen cloth is also called wool, which is a general term for fabrics woven from various types of wool and cashmere. It is usually used to make formal and high-end clothing such as dresses, suits, and overcoats. 5.
  • leather is an animal fur fabric that has been tanned. It is mostly used to make fashion and winter clothes. It can be divided into two categories: one is leather, that is, leather that has been dehaired. The second is fur, that is, treated leather with belt hair.
  • Chemical fiber is the abbreviation for chemical fiber. It is a textile made of fibers using polymer compounds as raw materials. Usually it is divided into two categories: artificial fibers and synthetic fibers. Their common advantages are bright colors, soft texture, crisp drape, smoothness and comfort. 7.
  • Blended spinning is a fabric made by blending natural fibers and chemical fibers in a certain ratio, which can be used to make various garments.
  • Modal is a cellulose regenerated fiber of high wet modulus viscose fiber.
  • the raw material of this fiber is European beech wood, which is first made into wood pulp, and then processed into fibers through a special spinning process.
  • the raw materials of the product are all natural materials, which are harmless to the human body, and can be decomposed naturally, which is harmless to the environment.
  • the existing fabrics are prone to pilling and fluffing after being worn for a long time, and have poor abrasion resistance. For this reason, an anti-pilling graphene blended yarn fiber composite fabric and a manufacturing method thereof are proposed.
  • the purpose of the present invention is to provide an anti-pilling graphene blended yarn fiber composite fabric and a manufacturing method thereof, so as to solve the problem that the existing fabrics are prone to pilling and fluffing after being worn for a long time and have poor abrasion resistance.
  • the present invention provides the following technical solution: anti-pilling graphene blended yarn fiber composite fabric, which is interlaced with warp yarns and weft yarns, and the warp yarns are woven by a blend of rayon and artificial fibers.
  • the weft yarn is woven from polyester.
  • the proportion of the artificial cotton is 3%.
  • the proportion of the polyester is 75%.
  • the rayon fiber is immersed in a rayon fiber solution, graphene is added to the rayon fiber solution, and the proportion of the rayon fiber is 12%.
  • the ratio of the graphene to the rayon fiber solution is 4:6.
  • the diameter of the warp yarn is 25 micrometers, and the diameter of the weft yarn is 28 micrometers.
  • the rayon 3%, the rayon 12% and the polyester 75% are mixed and woven, and the rayon, the rayon and the polyester are treated with anti-pilling polishing surface treatment.
  • the present invention also provides a method for manufacturing the anti-pilling graphene blended yarn fiber composite fabric, which includes the following steps:
  • liquid preparation add 6-9 kilograms of water in the liquid mixing container, slowly add 2-4 kilograms of rayon solution in the clean water, at the same time, continue to add 2-4 kg of graphene solution, rayon solution and graphite in the water
  • the preparation ratio of the alkene solution is 4:6, stirring slowly and continuously to make it completely and fully mixed;
  • Impregnation add the configured impregnation solution to the impregnation equipment, place the anti-pilling graphene blended yarn fiber composite fabric in the impregnation equipment, and impregnate the anti-pilling graphene blended yarn fiber composite fabric, and the immersion time It is 30-50 minutes.
  • the humidity of the immersion environment is 80%-90%, and the wind speed of the air is 1-9m/h;
  • Graphene is a two-dimensional carbon nanomaterial with a hexagonal honeycomb lattice composed of carbon atoms and sp 2 hybrid orbitals. It has high strength, good toughness, and excellent electrical and thermal conductivity and optical properties. Using 3% rayon 12% graphene (graphene added to man-made fiber solution to spin) blended yarn combined with 75% polyester composition, so that the fabric has a good antistatic effect. And like cotton, it is moisture-absorbing, breathable, skin-friendly and comfortable. The textile fabric is treated with anti-pilling treatment during the finishing process, which gives the fabric excellent anti-pilling performance, reduces the tendency of the fabric to fluff, and obviously improves the abrasion resistance of the fabric.
  • the fiber indirect agent is a two-dimensional carbon nanomaterial with a hexagonal honeycomb lattice composed of carbon atoms and sp 2 hybrid orbitals. It has high strength, good toughness, and excellent electrical and thermal conductivity and optical properties. Using 3% rayon 12% graphene (graphene added
  • the present invention provides a technical solution: anti-pilling graphene blended yarn fiber composite fabric, which is formed by interlacing warp yarns and weft yarns.
  • the warp yarns are woven by a blend of rayon and man-made fibers, and the weft yarns are made of polyester. Woven.
  • the proportion of the artificial cotton is 3%.
  • the proportion of the polyester is 75%.
  • the rayon fiber is immersed in a rayon fiber solution, graphene is added to the rayon fiber solution, and the proportion of the rayon fiber is 12%.
  • the ratio of the graphene to the rayon fiber solution is 4:6.
  • the diameter of the warp yarn is 25 microns, and the diameter of the weft yarn is 28 microns.
  • the rayon 3%, rayon 12%, and polyester 75% are mixed and woven, and the rayon, rayon and polyester are treated with anti-pilling and polishing surface treatment.
  • the present invention also provides a method for manufacturing the anti-pilling graphene blended yarn fiber composite fabric, which includes the following steps:
  • liquid preparation add 6 kg of water in the liquid container, slowly add 2 kg of rayon solution in the water, and at the same time, continue to add 2 kg of graphene solution in the water, the preparation ratio of rayon solution to graphene solution is 4:6, stir slowly and continuously to make it completely and fully mixed;
  • Impregnation add the configured impregnation solution to the impregnation equipment, place the anti-pilling graphene blended yarn fiber composite fabric in the impregnation equipment, and impregnate the anti-pilling graphene blended yarn fiber composite fabric, and the immersion time For 30 minutes, during the immersion process, the humidity of the immersion environment is 80%, and the wind speed of the air is 1m/h;
  • the manufacturing method of anti-pilling graphene blended yarn fiber composite fabric includes the following steps:
  • liquid preparation add 9 kg of water in the liquid container, slowly add 4 kg of rayon solution in the water, and at the same time, continue to add 4 kg of graphene solution in the water, the preparation ratio of rayon solution to graphene solution is 4:6, stir slowly and continuously to make it completely and fully mixed;
  • Impregnation add the configured impregnation solution to the impregnation equipment, place the anti-pilling graphene blended yarn fiber composite fabric in the impregnation equipment, and impregnate the anti-pilling graphene blended yarn fiber composite fabric, and the immersion time For 50 minutes, during the immersion process, the humidity of the immersion environment is 90%, and the wind speed of the air is 9m/h;
  • the manufacturing method of anti-pilling graphene blended yarn fiber composite fabric includes the following steps:
  • liquid preparation add 7.5 kg of water in the liquid mixing container, slowly add 3 kg of rayon solution in the water, at the same time, continue to add 3 kg of graphene solution in the water, the preparation ratio of rayon solution to graphene solution is 4:6, stir slowly and continuously to make it completely and fully mixed;
  • Impregnation add the configured impregnation solution to the impregnation equipment, place the anti-pilling graphene blended yarn fiber composite fabric in the impregnation equipment, and impregnate the anti-pilling graphene blended yarn fiber composite fabric, and the immersion time For 40 minutes, during the immersion process, the humidity of the immersion environment is 85%, and the wind speed of the air is 5m/h;

Abstract

An anti-pilling graphene blended yarn and fiber composite fabric and a manufacturing method therefor. The anti-pilling graphene blended yarn and fiber composite fabric is formed by interlacing warp yarns and weft yarns; the warp yarns are formed by blending and weaving artificial cotton and artificial fibers; the weft yarns are formed by weaving polyester; the proportion of the artificial cotton is 3%, and the proportion of the polyester is 75%; the artificial fibers are soaked in an artificial fiber solution; the artificial fiber solution is added with graphene; the proportion of the artificial fibers is 12%; 3% artificial cotton, 12% artificial fibers and 75% polyester are mixed and woven; and the artificial cotton, the artificial fibers and the polyester are subjected to surface anti-pilling grinding treatment. The blended yarns of artificial cotton and graphene (woven by adding graphene to the artificial fiber solution) are combined with 75% polyester, the fabric has a very good anti-static effect, moisture adsorption property, breathability, skin-friendliness and comfort; a textile fabric is subjected to anti-pilling treatment; the fabric is endowed with excellent resistance to pilling; the fluff tendency of the fabric is reduced; and the wear resistance of the fabric is obviously improved.

Description

抗起球石墨烯混纺纱纤维复合面料及其制造方法Anti-pilling graphene blended yarn fiber composite fabric and manufacturing method thereof 技术领域Technical field
本发明涉及面料加工技术领域,具体为抗起球石墨烯混纺纱纤维复合面料及其制造方法。The invention relates to the technical field of fabric processing, in particular to an anti-pilling graphene blended yarn fiber composite fabric and a manufacturing method thereof.
背景技术Background technique
面料就是用来制作服装的材料。作为服装三要素之一,面料不仅可以诠释服装的风格和特性,而且直接左右着服装的色彩、造型的表现效果。在服装大世界里,服装的面料五花八门,日新月异。但是从总体上来讲,优质、高档的面料,大都具有穿著舒适、吸汗透气、悬垂挺括、视觉高贵、触觉柔美等几个方面的特点。(1)梭织面料(Woven Fabric)也称机织物,是把经纱和纬纱相互垂直交织在一起形成的织物。(2)针织面料(Knitted Fabric)用织针将纱线或长丝构成线圈,再把线圈相互串套而成,由于针织物的线圈结构特征,单位长度内储纱量较多,因此大多有很好的弹性。1、棉布是各类棉纺织品的总称。棉布分全棉,人棉等品种。它多用来制作时装、休闲装、内衣和衬衫。2、麻布是以大麻、亚麻、苎麻、黄麻、剑麻、蕉麻等各种麻类植物纤维制成的一种布料。3、丝绸是以蚕丝为原料纺织而成的各种丝织物的统称。4、呢绒又叫毛料,它是对用各类羊毛、羊绒织成的织物的泛称。它通常适用以制作礼服、西装、大衣等正规、高档的服装。5、皮革是经过鞣制而成的动物毛皮面料。它多用以制作时装、冬装。又可以分为两类:一是革皮,即经过去毛处理的皮革。二是裘皮,即处理过的连皮带毛的皮革。6、化纤是化学纤维的简称。它是利用高分子化合物为原料制作而成的纤维的纺织品。通常它分为人工纤维与合成纤维两大门类。它们共同的优点是色彩鲜艳、质地柔软、悬垂挺括、滑爽舒适。7、混纺是将天然纤维与化学纤维按照一定的比例,混合纺织而成的织物,可用来制作各种服装。8、莫代尔(Modal)是一种高湿模量粘胶纤维的纤维素再生纤维,该纤维的原料采用欧洲的榉木, 先将其制成木浆,再通过专门的纺丝工艺加工成纤维。该产品原料全部为天然材料,对人体无害,并能够自然分解,对环境无害。但是现有的织物穿久了之后容易起球起毛,抗磨性差。为此,提出抗起球石墨烯混纺纱纤维复合面料及其制造方法。Fabric is the material used to make clothing. As one of the three elements of clothing, fabrics can not only interpret the style and characteristics of clothing, but also directly influence the color and shape of clothing. In the world of clothing, the fabrics of clothing are varied and changing with each passing day. But generally speaking, high-quality and high-end fabrics have the characteristics of comfortable wearing, sweat-absorbing and breathable, crisp drape, noble vision, and soft touch. (1) Woven fabric (Woven Fabric), also called woven fabric, is a fabric formed by weaving warp yarns and weft yarns perpendicular to each other. (2) Knitted fabric (Knitted Fabric) uses knitting needles to form loops of yarn or filaments, and then string the loops into each other. Due to the characteristics of the loop structure of knitted fabrics, the amount of yarn stored per unit length is large, so most of them have Very flexible. 1. Cotton cloth is the general term for all kinds of cotton textiles. Cotton cloth is divided into cotton, rayon and other varieties. It is mostly used to make fashion, casual wear, underwear and shirts. 2. Linen is a fabric made of hemp, flax, ramie, jute, sisal, abaca and other hemp plant fibers. 3. Silk is a general term for all kinds of silk fabrics woven from silk as raw material. 4. Woolen cloth is also called wool, which is a general term for fabrics woven from various types of wool and cashmere. It is usually used to make formal and high-end clothing such as dresses, suits, and overcoats. 5. Leather is an animal fur fabric that has been tanned. It is mostly used to make fashion and winter clothes. It can be divided into two categories: one is leather, that is, leather that has been dehaired. The second is fur, that is, treated leather with belt hair. 6. Chemical fiber is the abbreviation for chemical fiber. It is a textile made of fibers using polymer compounds as raw materials. Usually it is divided into two categories: artificial fibers and synthetic fibers. Their common advantages are bright colors, soft texture, crisp drape, smoothness and comfort. 7. Blended spinning is a fabric made by blending natural fibers and chemical fibers in a certain ratio, which can be used to make various garments. 8. Modal is a cellulose regenerated fiber of high wet modulus viscose fiber. The raw material of this fiber is European beech wood, which is first made into wood pulp, and then processed into fibers through a special spinning process. The raw materials of the product are all natural materials, which are harmless to the human body, and can be decomposed naturally, which is harmless to the environment. However, the existing fabrics are prone to pilling and fluffing after being worn for a long time, and have poor abrasion resistance. For this reason, an anti-pilling graphene blended yarn fiber composite fabric and a manufacturing method thereof are proposed.
发明内容Summary of the invention
本发明的目的在于提供抗起球石墨烯混纺纱纤维复合面料及其制造方法,以解决上述背景技术中提出的现有的织物穿久了之后容易起球起毛,抗磨性差的问题。The purpose of the present invention is to provide an anti-pilling graphene blended yarn fiber composite fabric and a manufacturing method thereof, so as to solve the problem that the existing fabrics are prone to pilling and fluffing after being worn for a long time and have poor abrasion resistance.
为实现上述目的,本发明提供如下技术方案:抗起球石墨烯混纺纱纤维复合面料,它由经纱和纬纱相互交错编织而成,所述经纱由人棉和人造纤维混纺编织而成,所述纬纱由涤纶编织而成。In order to achieve the above-mentioned object, the present invention provides the following technical solution: anti-pilling graphene blended yarn fiber composite fabric, which is interlaced with warp yarns and weft yarns, and the warp yarns are woven by a blend of rayon and artificial fibers. The weft yarn is woven from polyester.
作为本技术方案的进一步优选的:所述人棉的比例为3%。As a further preferred aspect of this technical solution, the proportion of the artificial cotton is 3%.
作为本技术方案的进一步优选的:所述涤纶的比例为75%。As a further preferred aspect of this technical solution, the proportion of the polyester is 75%.
作为本技术方案的进一步优选的:所述人造纤维浸泡于人造纤维溶液中,所述人造纤维溶液中添加有石墨烯,所述人造纤维的比例为12%。As a further preference of the technical solution, the rayon fiber is immersed in a rayon fiber solution, graphene is added to the rayon fiber solution, and the proportion of the rayon fiber is 12%.
作为本技术方案的进一步优选的:所述石墨烯与人造纤维溶液的比例为4:6。As a further preferred aspect of the technical solution, the ratio of the graphene to the rayon fiber solution is 4:6.
作为本技术方案的进一步优选的:所述经纱的直径为25微米,所述纬纱的直径为28微米。As a further preferred aspect of this technical solution, the diameter of the warp yarn is 25 micrometers, and the diameter of the weft yarn is 28 micrometers.
作为本技术方案的进一步优选的:所述人棉3%、人造纤维12%与涤纶75%混合编织,所述人棉、人造纤维与涤纶经抗起球打磨表面处理。As a further preferred aspect of the technical solution, the rayon 3%, the rayon 12% and the polyester 75% are mixed and woven, and the rayon, the rayon and the polyester are treated with anti-pilling polishing surface treatment.
本发明还提供抗起球石墨烯混纺纱纤维复合面料的制造方法,包括以下步骤:The present invention also provides a method for manufacturing the anti-pilling graphene blended yarn fiber composite fabric, which includes the following steps:
S1、配液,在配液容器中添加6-9千克清水,在清水中缓慢添加2-4千克人造纤维溶液,同时,在清水中继续添加2-4千克石墨烯溶液,人造纤维 溶液与石墨烯溶液的配制比例为4:6,缓慢且不断的进行搅拌,使其完全且充分的混合;S1, liquid preparation, add 6-9 kilograms of water in the liquid mixing container, slowly add 2-4 kilograms of rayon solution in the clean water, at the same time, continue to add 2-4 kg of graphene solution, rayon solution and graphite in the water The preparation ratio of the alkene solution is 4:6, stirring slowly and continuously to make it completely and fully mixed;
S3、浸渍,将配置好的浸渍溶液添加到浸渍设备中,将抗起球石墨烯混纺纱纤维复合面料放置于浸渍设备中,对抗起球石墨烯混纺纱纤维复合面料进行浸渍,浸渍时间为30-50分钟,在浸渍过程中,浸渍的环境湿度为80%-90%,空气的风速为1-9m/h;S3. Impregnation: add the configured impregnation solution to the impregnation equipment, place the anti-pilling graphene blended yarn fiber composite fabric in the impregnation equipment, and impregnate the anti-pilling graphene blended yarn fiber composite fabric, and the immersion time It is 30-50 minutes. During the dipping process, the humidity of the immersion environment is 80%-90%, and the wind speed of the air is 1-9m/h;
S4、脱水,将浸渍好的抗起球石墨烯混纺纱纤维复合面料放入脱水设备中进行脱水处理,脱水时间设定为10-20分钟,脱去抗起球石墨烯混纺纱纤维复合面料中80%的水分;S4. Dehydration, put the impregnated anti-pilling graphene blended yarn fiber composite fabric into the dehydration equipment for dehydration treatment, the dehydration time is set to 10-20 minutes, remove the anti-pilling graphene blended yarn fiber composite 80% moisture in the fabric;
S5、烘干,完成脱水工序后,将抗起球石墨烯混纺纱纤维复合面料取出,放入烘干设备中进行加热烘干,使其形成石墨烯混纺纱纤维复合面料,烘干设备的烘干时间设定为20-30分钟,热风风速设定为1-9m/h,烘焙温度为130℃-150℃;S5. Drying. After the dehydration process is completed, take out the anti-pilling graphene blended yarn fiber composite fabric and put it into the drying equipment for heating and drying to form a graphene blended yarn fiber composite fabric. Drying equipment The drying time is set to 20-30 minutes, the hot air speed is set to 1-9m/h, and the baking temperature is 130°C-150°C;
S6、表面处理,完成上述工序之后,将抗起球石墨烯混纺纱纤维复合面料进行抗起球表面处理,将抗起球石墨烯混纺纱纤维复合面料涂抹生物酶,通过抛光设备对抗起球石墨烯混纺纱纤维复合面料进行抛光处理,使抗起球石墨烯混纺纱纤维复合面料具有更好的抗起球与抗起毛的性能。S6. Surface treatment. After the above process is completed, the anti-pilling graphene blended yarn fiber composite fabric is subjected to anti-pilling surface treatment, and the anti-pilling graphene blended yarn fiber composite fabric is coated with biological enzymes, and the polishing equipment is used to resist The spherical graphene blended yarn fiber composite fabric is polished, so that the anti-pilling graphene blended yarn fiber composite fabric has better anti-pilling and anti-pilling performance.
与现有技术相比,本发明的有益效果是:Compared with the prior art, the beneficial effects of the present invention are:
石墨烯是一种由碳原子以sp 2杂化轨道组成六角型呈蜂巢晶格的二维碳纳米材料,强度高且有很好的韧性、具有极好的导电导热性和光学性质。采用3%人棉12%石墨烯(将石墨烯加入到人造纤维溶液中纺织而成)混纺纱结合75%涤纶的成分,使面料具有很好的抗静电效果。并且和棉一样吸湿透气,亲肤舒适,纺织面料在后整理过程中进行抗起球处理,赋予织物极佳的抗起毛起球性能,减少织物起毛倾向,明显提高织物的抗磨性,极好的纤维间接着剂。 Graphene is a two-dimensional carbon nanomaterial with a hexagonal honeycomb lattice composed of carbon atoms and sp 2 hybrid orbitals. It has high strength, good toughness, and excellent electrical and thermal conductivity and optical properties. Using 3% rayon 12% graphene (graphene added to man-made fiber solution to spin) blended yarn combined with 75% polyester composition, so that the fabric has a good antistatic effect. And like cotton, it is moisture-absorbing, breathable, skin-friendly and comfortable. The textile fabric is treated with anti-pilling treatment during the finishing process, which gives the fabric excellent anti-pilling performance, reduces the tendency of the fabric to fluff, and obviously improves the abrasion resistance of the fabric. The fiber indirect agent.
具体实施方式detailed description
下面将结合本发明的实施例,对本发明实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例仅仅是本发明一部分实施例,而不是全部的实施例。基于本发明中的实施例,本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例,都属于本发明保护的范围。The technical solutions in the embodiments of the present invention will be clearly and completely described below in conjunction with the embodiments of the present invention. Obviously, the described embodiments are only a part of the embodiments of the present invention, rather than all the embodiments. Based on the embodiments of the present invention, all other embodiments obtained by those of ordinary skill in the art without creative work shall fall within the protection scope of the present invention.
实施例1:Example 1:
本发明提供一种技术方案:抗起球石墨烯混纺纱纤维复合面料,它由经纱和纬纱相互交错编织而成,所述经纱由人棉和人造纤维混纺编织而成,所述纬纱由涤纶编织而成。The present invention provides a technical solution: anti-pilling graphene blended yarn fiber composite fabric, which is formed by interlacing warp yarns and weft yarns. The warp yarns are woven by a blend of rayon and man-made fibers, and the weft yarns are made of polyester. Woven.
本实施例中,具体的:所述人棉的比例为3%。In this embodiment, specifically: the proportion of the artificial cotton is 3%.
本实施例中,具体的:所述涤纶的比例为75%。In this embodiment, specifically: the proportion of the polyester is 75%.
本实施例中,具体的:所述人造纤维浸泡于人造纤维溶液中,所述人造纤维溶液中添加有石墨烯,所述人造纤维的比例为12%。In this embodiment, specifically: the rayon fiber is immersed in a rayon fiber solution, graphene is added to the rayon fiber solution, and the proportion of the rayon fiber is 12%.
本实施例中,具体的:所述石墨烯与人造纤维溶液的比例为4:6。In this embodiment, specifically: the ratio of the graphene to the rayon fiber solution is 4:6.
本实施例中,具体的:所述经纱的直径为25微米,所述纬纱的直径为28微米。In this embodiment, specifically: the diameter of the warp yarn is 25 microns, and the diameter of the weft yarn is 28 microns.
本实施例中,具体的:所述人棉3%、人造纤维12%与涤纶75%混合编织,所述人棉、人造纤维与涤纶经抗起球打磨表面处理。In this embodiment, specifically: the rayon 3%, rayon 12%, and polyester 75% are mixed and woven, and the rayon, rayon and polyester are treated with anti-pilling and polishing surface treatment.
本发明还提供抗起球石墨烯混纺纱纤维复合面料的制造方法,包括以下步骤:The present invention also provides a method for manufacturing the anti-pilling graphene blended yarn fiber composite fabric, which includes the following steps:
S1、配液,在配液容器中添加6千克清水,在清水中缓慢添加2千克人造纤维溶液,同时,在清水中继续添加2千克石墨烯溶液,人造纤维溶液与石墨烯溶液的配制比例为4:6,缓慢且不断的进行搅拌,使其完全且充分的混合;S1, liquid preparation, add 6 kg of water in the liquid container, slowly add 2 kg of rayon solution in the water, and at the same time, continue to add 2 kg of graphene solution in the water, the preparation ratio of rayon solution to graphene solution is 4:6, stir slowly and continuously to make it completely and fully mixed;
S3、浸渍,将配置好的浸渍溶液添加到浸渍设备中,将抗起球石墨烯混 纺纱纤维复合面料放置于浸渍设备中,对抗起球石墨烯混纺纱纤维复合面料进行浸渍,浸渍时间为30分钟,在浸渍过程中,浸渍的环境湿度为80%,空气的风速为1m/h;S3. Impregnation: add the configured impregnation solution to the impregnation equipment, place the anti-pilling graphene blended yarn fiber composite fabric in the impregnation equipment, and impregnate the anti-pilling graphene blended yarn fiber composite fabric, and the immersion time For 30 minutes, during the immersion process, the humidity of the immersion environment is 80%, and the wind speed of the air is 1m/h;
S4、脱水,将浸渍好的抗起球石墨烯混纺纱纤维复合面料放入脱水设备中进行脱水处理,脱水时间设定为10分钟,脱去抗起球石墨烯混纺纱纤维复合面料中80%的水分;S4. Dewatering, put the impregnated anti-pilling graphene blended yarn fiber composite fabric into a dehydration device for dehydration treatment, set the dehydration time to 10 minutes, and remove the anti-pilling graphene blended yarn fiber composite fabric 80% moisture;
S5、烘干,完成脱水工序后,将抗起球石墨烯混纺纱纤维复合面料取出,放入烘干设备中进行加热烘干,使其形成石墨烯混纺纱纤维复合面料,烘干设备的烘干时间设定为20分钟,热风风速设定为1m/h,烘焙温度为130℃;S5. Drying. After the dehydration process is completed, take out the anti-pilling graphene blended yarn fiber composite fabric and put it into the drying equipment for heating and drying to form a graphene blended yarn fiber composite fabric. Drying equipment The drying time is set to 20 minutes, the hot air speed is set to 1m/h, and the baking temperature is 130°C;
S6、表面处理,完成上述工序之后,将抗起球石墨烯混纺纱纤维复合面料进行抗起球表面处理,将抗起球石墨烯混纺纱纤维复合面料涂抹生物酶,通过抛光设备对抗起球石墨烯混纺纱纤维复合面料进行抛光处理,使抗起球石墨烯混纺纱纤维复合面料具有更好的抗起球与抗起毛的性能。S6. Surface treatment. After the above process is completed, the anti-pilling graphene blended yarn fiber composite fabric is subjected to anti-pilling surface treatment, and the anti-pilling graphene blended yarn fiber composite fabric is coated with biological enzymes, and the polishing equipment is used to resist The spherical graphene blended yarn fiber composite fabric is polished, so that the anti-pilling graphene blended yarn fiber composite fabric has better anti-pilling and anti-pilling performance.
实施例2:Example 2:
抗起球石墨烯混纺纱纤维复合面料的制造方法,包括以下步骤:The manufacturing method of anti-pilling graphene blended yarn fiber composite fabric includes the following steps:
S1、配液,在配液容器中添加9千克清水,在清水中缓慢添加4千克人造纤维溶液,同时,在清水中继续添加4千克石墨烯溶液,人造纤维溶液与石墨烯溶液的配制比例为4:6,缓慢且不断的进行搅拌,使其完全且充分的混合;S1, liquid preparation, add 9 kg of water in the liquid container, slowly add 4 kg of rayon solution in the water, and at the same time, continue to add 4 kg of graphene solution in the water, the preparation ratio of rayon solution to graphene solution is 4:6, stir slowly and continuously to make it completely and fully mixed;
S3、浸渍,将配置好的浸渍溶液添加到浸渍设备中,将抗起球石墨烯混纺纱纤维复合面料放置于浸渍设备中,对抗起球石墨烯混纺纱纤维复合面料进行浸渍,浸渍时间为50分钟,在浸渍过程中,浸渍的环境湿度为90%,空气的风速为9m/h;S3. Impregnation: add the configured impregnation solution to the impregnation equipment, place the anti-pilling graphene blended yarn fiber composite fabric in the impregnation equipment, and impregnate the anti-pilling graphene blended yarn fiber composite fabric, and the immersion time For 50 minutes, during the immersion process, the humidity of the immersion environment is 90%, and the wind speed of the air is 9m/h;
S4、脱水,将浸渍好的抗起球石墨烯混纺纱纤维复合面料放入脱水设备中进行脱水处理,脱水时间设定为20分钟,脱去抗起球石墨烯混纺纱纤维复 合面料中80%的水分;S4. Dehydration, put the impregnated anti-pilling graphene blended yarn fiber composite fabric into a dehydration device for dehydration, and set the dehydration time to 20 minutes, and remove the anti-pilling graphene blended yarn fiber composite fabric 80% moisture;
S5、烘干,完成脱水工序后,将抗起球石墨烯混纺纱纤维复合面料取出,放入烘干设备中进行加热烘干,使其形成石墨烯混纺纱纤维复合面料,烘干设备的烘干时间设定为30分钟,热风风速设定为9m/h,烘焙温度为150℃;S5. Drying. After the dehydration process is completed, take out the anti-pilling graphene blended yarn fiber composite fabric and put it into the drying equipment for heating and drying to form a graphene blended yarn fiber composite fabric. Drying equipment The drying time is set to 30 minutes, the hot air speed is set to 9m/h, and the baking temperature is 150°C;
S6、表面处理,完成上述工序之后,将抗起球石墨烯混纺纱纤维复合面料进行抗起球表面处理,将抗起球石墨烯混纺纱纤维复合面料涂抹生物酶,通过抛光设备对抗起球石墨烯混纺纱纤维复合面料进行抛光处理,使抗起球石墨烯混纺纱纤维复合面料具有更好的抗起球与抗起毛的性能。S6. Surface treatment. After the above process is completed, the anti-pilling graphene blended yarn fiber composite fabric is subjected to anti-pilling surface treatment, and the anti-pilling graphene blended yarn fiber composite fabric is coated with biological enzymes, and the polishing equipment is used to resist The spherical graphene blended yarn fiber composite fabric is polished, so that the anti-pilling graphene blended yarn fiber composite fabric has better anti-pilling and anti-pilling performance.
实施例3:Example 3:
抗起球石墨烯混纺纱纤维复合面料的制造方法,包括以下步骤:The manufacturing method of anti-pilling graphene blended yarn fiber composite fabric includes the following steps:
S1、配液,在配液容器中添加7.5千克清水,在清水中缓慢添加3千克人造纤维溶液,同时,在清水中继续添加3千克石墨烯溶液,人造纤维溶液与石墨烯溶液的配制比例为4:6,缓慢且不断的进行搅拌,使其完全且充分的混合;S1, liquid preparation, add 7.5 kg of water in the liquid mixing container, slowly add 3 kg of rayon solution in the water, at the same time, continue to add 3 kg of graphene solution in the water, the preparation ratio of rayon solution to graphene solution is 4:6, stir slowly and continuously to make it completely and fully mixed;
S3、浸渍,将配置好的浸渍溶液添加到浸渍设备中,将抗起球石墨烯混纺纱纤维复合面料放置于浸渍设备中,对抗起球石墨烯混纺纱纤维复合面料进行浸渍,浸渍时间为40分钟,在浸渍过程中,浸渍的环境湿度为85%,空气的风速为5m/h;S3. Impregnation: add the configured impregnation solution to the impregnation equipment, place the anti-pilling graphene blended yarn fiber composite fabric in the impregnation equipment, and impregnate the anti-pilling graphene blended yarn fiber composite fabric, and the immersion time For 40 minutes, during the immersion process, the humidity of the immersion environment is 85%, and the wind speed of the air is 5m/h;
S4、脱水,将浸渍好的抗起球石墨烯混纺纱纤维复合面料放入脱水设备中进行脱水处理,脱水时间设定为15分钟,脱去抗起球石墨烯混纺纱纤维复合面料中80%的水分;S4. Dewatering, put the impregnated anti-pilling graphene blended yarn fiber composite fabric into the dehydration equipment for dehydration treatment, set the dehydration time to 15 minutes, and remove the anti-pilling graphene blended yarn fiber composite fabric 80% moisture;
S5、烘干,完成脱水工序后,将抗起球石墨烯混纺纱纤维复合面料取出,放入烘干设备中进行加热烘干,使其形成石墨烯混纺纱纤维复合面料,烘干设备的烘干时间设定为25分钟,热风风速设定为5m/h,烘焙温度为140℃;S5. Drying. After the dehydration process is completed, take out the anti-pilling graphene blended yarn fiber composite fabric and put it into the drying equipment for heating and drying to form a graphene blended yarn fiber composite fabric. Drying equipment The drying time is set to 25 minutes, the hot air speed is set to 5m/h, and the baking temperature is 140°C;
S6、表面处理,完成上述工序之后,将抗起球石墨烯混纺纱纤维复合面 料进行抗起球表面处理,将抗起球石墨烯混纺纱纤维复合面料涂抹生物酶,通过抛光设备对抗起球石墨烯混纺纱纤维复合面料进行抛光处理,使抗起球石墨烯混纺纱纤维复合面料具有更好的抗起球与抗起毛的性能。S6. Surface treatment. After the above process is completed, the anti-pilling graphene blended yarn fiber composite fabric is subjected to anti-pilling surface treatment, and the anti-pilling graphene blended yarn fiber composite fabric is coated with biological enzymes, and the polishing equipment is used to resist The spherical graphene blended yarn fiber composite fabric is polished, so that the anti-pilling graphene blended yarn fiber composite fabric has better anti-pilling and anti-pilling performance.
尽管已经示出和描述了本发明的实施例,对于本领域的普通技术人员而言,可以理解在不脱离本发明的原理和精神的情况下可以对这些实施例进行多种变化、修改、替换和变型,本发明的范围由所附权利要求及其等同物限定。Although the embodiments of the present invention have been shown and described, those of ordinary skill in the art can understand that various changes, modifications, and substitutions can be made to these embodiments without departing from the principle and spirit of the present invention. And variations, the scope of the present invention is defined by the appended claims and their equivalents.

Claims (8)

  1. 抗起球石墨烯混纺纱纤维复合面料,它由经纱和纬纱相互交错编织而成,其特征在于:所述经纱由人棉和人造纤维混纺编织而成,所述纬纱由涤纶编织而成。The anti-pilling graphene blended yarn fiber composite fabric is formed by interlacing warp yarns and weft yarns, and is characterized in that the warp yarns are woven by blending rayon and man-made fibers, and the weft yarns are woven by polyester.
  2. 根据权利要求1所述的抗起球石墨烯混纺纱纤维复合面料,其特征在于:所述人棉的比例为3%。The anti-pilling graphene blended yarn fiber composite fabric according to claim 1, wherein the proportion of the artificial cotton is 3%.
  3. 根据权利要求1所述的抗起球石墨烯混纺纱纤维复合面料,其特征在于:所述涤纶的比例为75%。The anti-pilling graphene blended yarn fiber composite fabric according to claim 1, wherein the proportion of the polyester is 75%.
  4. 根据权利要求1所述的抗起球石墨烯混纺纱纤维复合面料,其特征在于:所述人造纤维浸泡于人造纤维溶液中,所述人造纤维溶液中添加有石墨烯,所述人造纤维的比例为12%。The anti-pilling graphene blended yarn fiber composite fabric according to claim 1, wherein the rayon fiber is soaked in a rayon fiber solution, the rayon fiber solution is added with graphene, and the rayon fiber The ratio is 12%.
  5. 根据权利要求1所述的抗起球石墨烯混纺纱纤维复合面料,其特征在于:所述石墨烯与人造纤维溶液的比例为4:6。The anti-pilling graphene blended yarn fiber composite fabric according to claim 1, wherein the ratio of the graphene to the rayon fiber solution is 4:6.
  6. 根据权利要求1所述的抗起球石墨烯混纺纱纤维复合面料,其特征在于:所述经纱的直径为25微米,所述纬纱的直径为28微米。The anti-pilling graphene blended yarn fiber composite fabric according to claim 1, wherein the diameter of the warp yarn is 25 microns, and the diameter of the weft yarn is 28 microns.
  7. 根据权利要求1所述的抗起球石墨烯混纺纱纤维复合面料,其特征在于:所述人棉3%、人造纤维12%与涤纶75%混合编织,所述人棉、人造纤维与涤纶经抗起球打磨表面处理。The anti-pilling graphene blended yarn fiber composite fabric according to claim 1, wherein the rayon 3%, rayon 12% and polyester 75% are mixed and woven, and the rayon, rayon and polyester are mixed and woven. After anti-pilling polishing surface treatment.
  8. 一种权利要求1-7任意一项所述的抗起球石墨烯混纺纱纤维复合面料的制造方法,其特征在于:包括以下步骤:A method for manufacturing an anti-pilling graphene blended yarn fiber composite fabric according to any one of claims 1-7, characterized in that it comprises the following steps:
    S1、配液,在配液容器中添加6-9千克清水,在清水中缓慢添加2-4千克人造纤维溶液,同时,在清水中继续添加2-4千克石墨烯溶液,人造纤维溶液与石墨烯溶液的配制比例为4:6,缓慢且不断的进行搅拌,使其完全且充分的混合;S1, liquid preparation, add 6-9 kilograms of water in the liquid mixing container, slowly add 2-4 kilograms of rayon solution in the clean water, at the same time, continue to add 2-4 kg of graphene solution, rayon solution and graphite in the water The preparation ratio of the alkene solution is 4:6, stirring slowly and continuously to make it completely and fully mixed;
    S3、浸渍,将配置好的浸渍溶液添加到浸渍设备中,将抗起球石墨烯混纺纱纤维复合面料放置于浸渍设备中,对抗起球石墨烯混纺纱纤维复合面料 进行浸渍,浸渍时间为30-50分钟,在浸渍过程中,浸渍的环境湿度为80%-90%,空气的风速为1-9m/h;S3. Impregnation: add the configured impregnation solution to the impregnation equipment, place the anti-pilling graphene blended yarn fiber composite fabric in the impregnation equipment, and impregnate the anti-pilling graphene blended yarn fiber composite fabric, and the immersion time It is 30-50 minutes. During the dipping process, the humidity of the immersion environment is 80%-90%, and the wind speed of the air is 1-9m/h;
    S4、脱水,将浸渍好的抗起球石墨烯混纺纱纤维复合面料放入脱水设备中进行脱水处理,脱水时间设定为10-20分钟,脱去抗起球石墨烯混纺纱纤维复合面料中80%的水分;S4. Dehydration, put the impregnated anti-pilling graphene blended yarn fiber composite fabric into the dehydration equipment for dehydration treatment, the dehydration time is set to 10-20 minutes, remove the anti-pilling graphene blended yarn fiber composite 80% moisture in the fabric;
    S5、烘干,完成脱水工序后,将抗起球石墨烯混纺纱纤维复合面料取出,放入烘干设备中进行加热烘干,使其形成石墨烯混纺纱纤维复合面料,烘干设备的烘干时间设定为20-30分钟,热风风速设定为1-9m/h,烘焙温度为130℃-150℃;S5. Drying. After the dehydration process is completed, take out the anti-pilling graphene blended yarn fiber composite fabric and put it into the drying equipment for heating and drying to form a graphene blended yarn fiber composite fabric. Drying equipment The drying time is set to 20-30 minutes, the hot air speed is set to 1-9m/h, and the baking temperature is 130°C-150°C;
    S6、表面处理,完成上述工序之后,将抗起球石墨烯混纺纱纤维复合面料进行抗起球表面处理,将抗起球石墨烯混纺纱纤维复合面料涂抹生物酶,通过抛光设备对抗起球石墨烯混纺纱纤维复合面料进行抛光处理,使抗起球石墨烯混纺纱纤维复合面料具有更好的抗起球与抗起毛的性能。S6. Surface treatment. After the above process is completed, the anti-pilling graphene blended yarn fiber composite fabric is subjected to anti-pilling surface treatment, and the anti-pilling graphene blended yarn fiber composite fabric is coated with biological enzymes, and the polishing equipment is used to resist The spherical graphene blended yarn fiber composite fabric is polished, so that the anti-pilling graphene blended yarn fiber composite fabric has better anti-pilling and anti-pilling performance.
PCT/CN2020/125327 2020-06-04 2020-10-30 Anti-pilling graphene blended yarn and fiber composite fabric and manufacturing method therefor WO2021243941A1 (en)

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