CN108315860A - A kind of preparation method of Graphene antibiosis towel - Google Patents

A kind of preparation method of Graphene antibiosis towel Download PDF

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Publication number
CN108315860A
CN108315860A CN201810215914.8A CN201810215914A CN108315860A CN 108315860 A CN108315860 A CN 108315860A CN 201810215914 A CN201810215914 A CN 201810215914A CN 108315860 A CN108315860 A CN 108315860A
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CN
China
Prior art keywords
graphene
towel
preparation
fibre
antibiosis
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810215914.8A
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Chinese (zh)
Inventor
沙嫣
沙晓林
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nantong Johnson Graphene Technology Co Ltd
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Nantong Johnson Graphene Technology Co Ltd
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Priority to CN201810215914.8A priority Critical patent/CN108315860A/en
Publication of CN108315860A publication Critical patent/CN108315860A/en
Pending legal-status Critical Current

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Classifications

    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D27/00Woven pile fabrics
    • D03D27/02Woven pile fabrics wherein the pile is formed by warp or weft
    • D03D27/06Warp pile fabrics
    • D03D27/08Terry fabrics
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00General methods for the manufacture of artificial filaments or the like
    • D01F1/02Addition of substances to the spinning solution or to the melt
    • D01F1/10Other agents for modifying properties
    • D01F1/103Agents inhibiting growth of microorganisms
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/44Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds
    • D01F6/54Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds of polymers of unsaturated nitriles
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/88Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
    • D01F6/90Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyamides
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/88Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
    • D01F6/92Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyesters
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2201/00Cellulose-based fibres, e.g. vegetable fibres
    • D10B2201/01Natural vegetable fibres
    • D10B2201/02Cotton
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2201/00Cellulose-based fibres, e.g. vegetable fibres
    • D10B2201/20Cellulose-derived artificial fibres
    • D10B2201/22Cellulose-derived artificial fibres made from cellulose solutions
    • D10B2201/24Viscose
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2321/00Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D10B2321/02Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polyolefins
    • D10B2321/022Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polyolefins polypropylene
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/02Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/04Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Artificial Filaments (AREA)

Abstract

The present invention provides a kind of preparation methods of Graphene antibiosis towel comprising following steps:Prepare graphene composite fibre;The graphene composite fibre is blended with general fibre, obtain graphene composite blended yarn line;Using the graphene composite blended yarn line as weft yarn, general fibre is woven into the Graphene antibiosis towel as looped pile and warp thread in terry cloth loom.Compared with prior art, the present invention has following advantageous effect:1, there are three ways to generally giving to antibacterial fabric performance:Anti-bacterial fibre mode, surface splash-proofing sputtering metal mode is added in final finishing mode, and mode of the present invention is the second way.Graphene used in the present invention has stronger antibiotic property, therefore the performance that the additive amount in towel can reach antibiotic property less than 30% and comfort is taken into account, and graphene is environmentally protective harmless from minerals.

Description

A kind of preparation method of Graphene antibiosis towel
Technical field
The present invention relates to a kind of preparation methods of Graphene antibiosis towel, belong to anti-biotic material technical field.
Background technology
With the raising of living standard, requirement of the people to articles for daily use is higher and higher, and the requirement to textile is not It is confined to original essential characteristic such as warming, comfortable again.According to the different purposes of textile, it is also desirable that its with health care, The specific functions such as safety, such as antibacterial, anti-mite, anion, far infrared, antiultraviolet, gas defence, fire-retardant, anti-electromagnetic radiation, magnetic Treatment, fragrance, moisture absorbing and sweat releasing, grease-proof and waterproof etc..
Existing towel will use daily as a kind of daily necessities, and towel plays important work in people's health life With.Wash hair, wash one's face, having a bath, foot bath, wiping furniture etc., the use of towel is it may be said that ubiquitous, and towel is due to usually needing Contact warm water, warm and humid environment easily grows bacterium, and the accelerating rhythm of life make people be easy to ignore the plot of towel with Maintenance, this is easy for towel is caused to go mouldy smelly, and the skin and acarid of grease and aging when wiping face on the face are easy to attached It on towel, and the towel most of the time all uses under dampness, this just provides nutrition for the growth of microorganism Condition, bacterium are easy to breed, and generate unpleasant taste, and especially in summer, due to temperature height, this phenomenon is even more serious, such as The mass propagation of fruit pathogenic bacteria, after invading skin, respiratory tract, to influence the health of people.
Based on current existing towel is mainly strong with water imbibition, pliability is high, it is more convenient for drying in this way, comfort level, But antibiotic property and soil pick-up ability are weaker, and in air pollution increasingly severe today, the antibiotic property and soil pick-up energy of towel Power is particularly important.Existing antibacterial towel is mostly one layer of antibiotic layer to be coated in towel body, and antibiotic layer is thicker, makes Water absorbing capacity of the towel in wiping reduces, while the towel antibacterial in use for some time coated with certain thickness antibiotic layer Layer is easy to peel off, and towel loses antibacterial effect.
In addition, towel is usually symmetrically taken on clothes hanger cross member in suspension, take and need guiding through clothes hanger when drying in the air by towel, grasp It is inconvenient to make, take dry in the air when due to lodge asymmetry, towel is easy to slide.Existing towel ring is generally arranged at the list of towel On a corner, entire towel need to be passed through when flow, and towel hanging is easy to fold occur, dry and uneven bacterium is caused to grow It is raw.Existing towel is functionally relatively simple, is not applied for the requirement to towel under various occasions.
To solve the above problems, Chinese patent CN107059203A disclose it is a kind of using plant fibers such as birch-barks as resisting The antibacterial towel of bacterium material, since this kind of material subjective antisepsis performance is poor, therefore, it is necessary to largely add, at least 30% with On, seriously affect the feel and comfort of towel.
Invention content
For the defects in the prior art, the object of the present invention is to provide a kind of preparation methods of Graphene antibiosis towel.
The present invention is achieved by the following technical solutions:
The present invention provides a kind of preparation methods of Graphene antibiosis towel comprising following steps:
Prepare graphene composite fibre;
The graphene composite fibre is blended with general fibre, obtain graphene composite blended yarn line;
Using the graphene composite blended yarn line as weft yarn, general fibre is as looped pile and warp thread, in terry cloth loom It is woven into the Graphene antibiosis towel.
Preferably, the preparation method of the graphene composite fibre is:
After resin slicer and graphene or modified graphene are mixed, extruding pelletization obtains graphene-masterbatch resin;
By the graphene-masterbatch resin through melt spinning, the graphene composite fibre is obtained.
Preferably, the weight percent of graphene is 0.1~10% in the graphene composite fibre.
Preferably, the preparation method of the graphene is oxidation-reduction method, mechanical stripping method, chemical vapor deposition One kind in method, electrochemical stripping method.
Preferably, the thickness of the graphene is 0.4~10nm, and specific surface area is 400~900m2/g。
Preferably, the graphene composite fibre includes that graphene polyamide fibre composite fibre, graphene terylene are compound One or more of fiber, graphene viscose composite fibre, graphene polypropylene fiber.
Preferably, the preparation method of the graphene composite fibre is melt spinning method or wet spinning process.
Preferably, the mass ratio of the graphene composite fibre and general fibre is 3:7~7:3.
Preferably, the general fibre includes cotton fiber, viscose fiber, polypropylene fiber, polyester fiber, polyamide fibre fibre One or more of dimension.
Compared with prior art, the present invention has following advantageous effect:
1, there are three ways to generally giving to antibacterial fabric performance:Final finishing mode, addition anti-bacterial fibre mode, surface are splashed Radioglold category mode, mode of the present invention are the second way.Graphene used in the present invention has stronger antibiotic property, therefore in towel In additive amount can reach antibiotic property and performance that comfort is taken into account less than 30%, and graphene is green from minerals Colour circle is protected harmless.
2, Graphene antibiosis towel of the invention to staphylococcus aureus, Escherichia coli, Candida albicans bacteriostasis rate It is all higher than 99%, and 99% is all higher than to staphylococcus aureus, Escherichia coli bacteriostasis rate after washing 50 times, reaches AAA grades Not.
3, Graphene antibiosis towel and preparation method thereof of the invention, it is big to acarid inhibiting rate that establishing criteria tests the towel In 95%, reach Primary plateaus.
Specific implementation mode
With reference to specific embodiment, the present invention is described in detail.Following embodiment will be helpful to the technology of this field Personnel further understand the present invention, but the invention is not limited in any way.It should be pointed out that the ordinary skill of this field For personnel, without departing from the inventive concept of the premise, various modifications and improvements can be made.These belong to the present invention Protection domain.
Embodiment 1
The present embodiment is related to a kind of preparation method of Graphene antibiosis towel, specifically comprises the following steps:
Graphene composite fibre is prepared, the weight percent for controlling graphene in graphene composite fibre is 0.1%;
By graphene composite fibre and cotton fiber according to 3:7 weight ratio is blended, obtains graphene composite blended yarn line;
Using the graphene composite blended yarn line as weft yarn, cotton fiber is compiled as looped pile and warp thread in terry cloth loom It is made into the Graphene antibiosis towel;
Wherein, the preparation method of graphene composite fibre is:
After slices of caprone and graphene are mixed, extruding pelletization obtains graphene-chinlon master batch;
By the graphene-masterbatch resin through melt spinning, graphene polyamide fibre composite fibre is obtained.
Embodiment 2
The present embodiment is related to a kind of preparation method of Graphene antibiosis towel, specifically comprises the following steps:
Graphene composite fibre is prepared, the weight percent for controlling graphene in graphene composite fibre is 10%;
By graphene composite fibre and viscose fiber according to 7:3 weight ratio is blended, obtains graphene composite blended yarn line;
Using the graphene composite blended yarn line as weft yarn, viscose fiber is as looped pile and warp thread, in terry cloth loom It is woven into the Graphene antibiosis towel;
Wherein, the preparation method of graphene composite fibre is:
After terylene chips and modified graphene are mixed, extruding pelletization obtains graphene-dacron master grain;
By the graphene-masterbatch resin through melt spinning, graphene terylene composite fibre is obtained.
Embodiment 3
The present embodiment is related to a kind of preparation method of Graphene antibiosis towel, specifically comprises the following steps:
Graphene composite fibre is prepared, the weight percent for controlling graphene in graphene composite fibre is 5%;
By graphene composite fibre and polypropylene fiber according to 1:1 weight ratio is blended, obtains graphene composite blended yarn line;
Using the graphene composite blended yarn line as weft yarn, polypropylene fiber is as looped pile and warp thread, in terry cloth loom It is woven into the Graphene antibiosis towel;
Wherein, the preparation method of graphene composite fibre is:
After acrylic fibers slice and graphene are mixed, extruding pelletization obtains graphene-acrylic fibers master batch;
By the graphene-masterbatch resin through melt spinning, graphene acrylic composite fiber is obtained.
Specific embodiments of the present invention are described above.It is to be appreciated that the invention is not limited in above-mentioned Particular implementation, those skilled in the art can make various deformations or amendments within the scope of the claims, this not shadow Ring the substantive content of the present invention.

Claims (10)

1. a kind of preparation method of Graphene antibiosis towel, which is characterized in that include the following steps:
Prepare graphene composite fibre;
The graphene composite fibre is blended with general fibre, obtain graphene composite blended yarn line;
Using the graphene composite blended yarn line as weft yarn, general fibre weaves as looped pile and warp thread in terry cloth loom At the Graphene antibiosis towel.
2. the preparation method of Graphene antibiosis towel as described in claim 1, which is characterized in that the graphene composite fibre Preparation method be:
After resin slicer and graphene or modified graphene are mixed, extruding pelletization obtains graphene-masterbatch resin;
By the graphene-masterbatch resin through melt spinning, the graphene composite fibre is obtained.
3. the preparation method of Graphene antibiosis towel as described in claim 1, which is characterized in that the graphene composite fibre The weight percent of middle graphene is 0.1~10%.
4. the preparation method of Graphene antibiosis towel as claimed in claim 3, which is characterized in that the preparation side of the graphene Method is one kind in oxidation-reduction method, mechanical stripping method, chemical vapour deposition technique, electrochemical stripping method.
5. the preparation method of Graphene antibiosis towel as claimed in claim 3, which is characterized in that the graphene includes oxidation Graphene or graphene;The graphene oxide is selected from coupling agent modified graphene oxide, cationic surfactant is modified oxygen Graphite alkene, brominated alkanes modified graphene, amino-compound modified graphene, gathers amino-compound modified graphene oxide One or more of vinylpyrrolidone modified graphene, polyvinyl alcohol modification graphene.
6. the preparation method of Graphene antibiosis towel as claimed in claim 3, which is characterized in that the thickness of the graphene is 0.4~10nm, specific surface area are 400~900m2/g。
7. the preparation method of the Graphene antibiosis towel as described in any one of claim 1~6, which is characterized in that described Graphene composite fibre includes graphene polyamide fibre composite fibre, graphene terylene composite fibre, graphene viscose composite fibre, stone One or more of black alkene polypropylene fiber.
8. the preparation method of Graphene antibiosis towel as claimed in claim 7, which is characterized in that the graphene composite fibre Preparation method be melt spinning method or wet spinning process.
9. the preparation method of Graphene antibiosis towel as described in claim 1, which is characterized in that the graphene composite fibre Mass ratio with general fibre is 3:7~7:3.
10. the preparation method of the Graphene antibiosis towel as described in claim 1 or 9, which is characterized in that the general fibre packet Include one or more of cotton fiber, viscose fiber, polypropylene fiber, polyester fiber, nylon fibre.
CN201810215914.8A 2018-03-15 2018-03-15 A kind of preparation method of Graphene antibiosis towel Pending CN108315860A (en)

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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108677307A (en) * 2018-08-09 2018-10-19 魏桥纺织股份有限公司 A kind of graphene modified fibre scribbled, fabric and its production technology
CN109629080A (en) * 2019-01-25 2019-04-16 淄博飞狮巾被有限公司 A kind of antibacterial and the Graphene towel and preparation method thereof to promote blood circulation
CN110241503A (en) * 2019-05-27 2019-09-17 常州市武进城南纺织品有限公司 A kind of antistatic corduroy fabric and preparation method thereof
CN110344160A (en) * 2019-07-09 2019-10-18 杭州高烯科技有限公司 A kind of fabric for sportswear of antibiotic antistatic and preparation method thereof
CN110616485A (en) * 2019-09-26 2019-12-27 扬州尚衣汇时装设计有限公司 Blended yarn of bio-based modified polyester fiber and cotton fiber and production method thereof
CN110846782A (en) * 2019-11-28 2020-02-28 上海昌明实业有限公司 Woven rough-blended woolen fabric containing graphene
CN112064171A (en) * 2020-09-11 2020-12-11 涂一淼 Antistatic fabric and preparation method thereof
CN113122954A (en) * 2021-04-28 2021-07-16 江苏江山红化纤有限责任公司 Sports fabric based on graphene polyamide 6 fibers and preparation method thereof
WO2021243941A1 (en) * 2020-06-04 2021-12-09 席梦思床褥家具(苏州)有限公司 Anti-pilling graphene blended yarn and fiber composite fabric and manufacturing method therefor
CN114053034A (en) * 2021-11-19 2022-02-18 青岛大学 Expansion pressurization band-aid/application and preparation method

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Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108677307A (en) * 2018-08-09 2018-10-19 魏桥纺织股份有限公司 A kind of graphene modified fibre scribbled, fabric and its production technology
CN109629080A (en) * 2019-01-25 2019-04-16 淄博飞狮巾被有限公司 A kind of antibacterial and the Graphene towel and preparation method thereof to promote blood circulation
CN110241503A (en) * 2019-05-27 2019-09-17 常州市武进城南纺织品有限公司 A kind of antistatic corduroy fabric and preparation method thereof
CN110344160A (en) * 2019-07-09 2019-10-18 杭州高烯科技有限公司 A kind of fabric for sportswear of antibiotic antistatic and preparation method thereof
CN110616485A (en) * 2019-09-26 2019-12-27 扬州尚衣汇时装设计有限公司 Blended yarn of bio-based modified polyester fiber and cotton fiber and production method thereof
CN110846782A (en) * 2019-11-28 2020-02-28 上海昌明实业有限公司 Woven rough-blended woolen fabric containing graphene
WO2021243941A1 (en) * 2020-06-04 2021-12-09 席梦思床褥家具(苏州)有限公司 Anti-pilling graphene blended yarn and fiber composite fabric and manufacturing method therefor
CN112064171A (en) * 2020-09-11 2020-12-11 涂一淼 Antistatic fabric and preparation method thereof
CN112064171B (en) * 2020-09-11 2021-11-12 苏州市铂逸针织科技有限公司 Antistatic fabric and preparation method thereof
CN113122954A (en) * 2021-04-28 2021-07-16 江苏江山红化纤有限责任公司 Sports fabric based on graphene polyamide 6 fibers and preparation method thereof
CN113122954B (en) * 2021-04-28 2022-12-16 江苏江山红化纤有限责任公司 Sports fabric based on graphene polyamide 6 fibers and preparation method thereof
CN114053034A (en) * 2021-11-19 2022-02-18 青岛大学 Expansion pressurization band-aid/application and preparation method

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Application publication date: 20180724