CN110846782A - Woven rough-blended woolen fabric containing graphene - Google Patents
Woven rough-blended woolen fabric containing graphene Download PDFInfo
- Publication number
- CN110846782A CN110846782A CN201911188666.3A CN201911188666A CN110846782A CN 110846782 A CN110846782 A CN 110846782A CN 201911188666 A CN201911188666 A CN 201911188666A CN 110846782 A CN110846782 A CN 110846782A
- Authority
- CN
- China
- Prior art keywords
- graphene
- fiber
- polyethylene terephthalate
- woolen fabric
- fibers
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D31/00—Materials specially adapted for outerwear
- A41D31/04—Materials specially adapted for outerwear characterised by special function or use
- A41D31/06—Thermally protective, e.g. insulating
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2211/00—Protein-based fibres, e.g. animal fibres
- D10B2211/01—Natural animal fibres, e.g. keratin fibres
- D10B2211/02—Wool
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/04—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Woven Fabrics (AREA)
Abstract
A graphene-containing carded woolen fabric comprising wool fibers and graphene-containing polyethylene terephthalate fibers, wherein the mass ratio of the wool fibers to the graphene-containing polyethylene terephthalate fibers is between 5:95 and 95: 5. According to the invention, the polyethylene glycol terephthalate fiber containing graphene is introduced into the woolen fabric, so that the heat-insulating property of the woolen fabric is improved.
Description
Technical Field
The invention belongs to the field of textile fabrics, and particularly relates to a woven and rough blended woolen fabric containing graphene.
Background
Woolen cloth is also called as wool, is a generic name for fabrics woven by various wools and cashmere, and has the advantages of crease resistance, wear resistance, soft hand feeling, elegance, stiffness and smoothness and elasticity. The woolen cloth has the advantages of plump hand feeling and soft texture, the surface is generally covered by long or short villi, people feel warm, and the woolen cloth is commonly used for making winter clothes. However, in order to obtain a better warm-keeping effect, a woolen fabric with a higher gram weight needs to be used, so that the woolen garment is thicker and heavier. With the continuous improvement of pursuit of portability and fashion sense of wearing, how to provide enough heat preservation performance without increasing the gram weight of the woolen fabric becomes a problem which is urgently concerned in the field of weaving woolen fabrics.
Polyethylene terephthalate (PET) fiber is a synthetic fiber obtained by spinning polyester formed by polycondensation of terephthalic acid and ethylene glycol, has good crease resistance and shape retention, high strength and elastic recovery capability, and is firm and durable, crease-resistant, easy-care and free of hair sticking.
Graphene is a novel two-dimensional nano carbon material, is widely researched due to ultrahigh strength, electric conductivity, thermal conductivity and light transmittance, and has wide application in the fields of new energy, composite materials, aerospace, electronics and electrics, biomedical treatment, national defense equipment and the like.
Although studies have been made to improve certain properties of fabrics by using graphene, no report has been made on the improvement of the heat insulating property of woolen fabrics by introducing graphene-containing polyethylene terephthalate fibers into woolen fabrics.
Disclosure of Invention
According to the invention, the polyethylene glycol terephthalate fiber containing graphene is introduced into the woolen fabric, so that the heat insulation performance of the woolen fabric is improved.
Specifically, the invention provides a graphene-containing woolen fabric, which comprises wool fibers and graphene-containing polyethylene terephthalate fibers, wherein the mass ratio of the wool fibers to the graphene-containing polyethylene terephthalate fibers is 5:95 to 95: 5.
In one or more embodiments, the graphene-containing woolen fabric is a graphene-containing carded woolen fabric.
In one or more embodiments, the graphene-containing polyethylene terephthalate fibers have a length of 22mm to 51 mm.
In one or more embodiments, the graphene is a multilayer graphene.
In one or more embodiments, the sum of the weight of the wool fibers and the graphene-containing polyethylene terephthalate fibers comprises from 10 wt% to 100 wt% of the total weight of the graphene-containing woolen fabric.
In one or more embodiments, the graphene-containing polyethylene terephthalate fiber has a graphene content of 1 wt% to 2 wt% based on the total weight of the graphene-containing polyethylene terephthalate fiber.
In one or more embodiments, the graphene-inclusive polyethylene terephthalate fiber has a single filament denier of between 0.9 dtex and 3 dtex.
In one or more embodiments, the graphene-containing woolen fabric further comprises one or more fibers selected from the group consisting of cotton, silk, mulberry silk, cuprammonium staple fibers, modal fibers, viscose fibers, lyocell fibers, acetate fibers, polyester fibers other than polyethylene terephthalate, polyamide fibers, polyacrylonitrile fibers, polypropylene fibers, polyvinyl alcohol fibers, polyvinyl chloride fibers, and polyamide-based fibers.
The invention also provides an article made from the graphene-containing woolen fabric of any one of claims 1-7.
The invention also provides application of the polyethylene terephthalate fiber containing graphene in improving the heat preservation performance of the woolen fabric.
In one or more embodiments of the application, the graphene-containing polyethylene terephthalate fibers have a length of 22mm to 51 mm.
In one or more embodiments of the application, the graphene is multilayer graphene.
In one or more embodiments of the application, the graphene-containing polyethylene terephthalate fiber has a graphene content of 1 wt% to 2 wt%, based on the total weight of the graphene-containing polyethylene terephthalate fiber.
In one or more embodiments of the application, the graphene-containing polyethylene terephthalate fibers have a single filament denier of between 0.9 dtex and 3 dtex.
In one or more embodiments of the application, the woolen fabric is a woolen fabric.
In one or more embodiments of the application, the mass ratio of wool fibers to the graphene-containing polyethylene terephthalate fibers in the woolen fabric is between 5:95 and 95: 5.
In one or more embodiments of the application, the sum of the weight of the wool fibers and the graphene-containing polyethylene terephthalate fibers is from 10 wt% to 100 wt% of the total weight of the woolen fabric.
In one or more embodiments of the application, the woolen fabric further comprises one or more fibers selected from cotton, silk, mulberry silk, cuprammonium staple fiber, modal fiber, viscose fiber, polynosic fiber, acetate fiber, polyester fiber other than polyethylene terephthalate, polyamide fiber, polyacrylonitrile fiber, polypropylene fiber, polyvinyl alcohol fiber, polyvinyl chloride fiber, and polyamide fiber.
Detailed Description
To make the features and effects of the present invention comprehensible to those skilled in the art, general description and definitions are made below with reference to terms and expressions mentioned in the specification and claims. Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs.
The theory or mechanism described and disclosed herein, whether correct or incorrect, should not limit the scope of the present invention in any way, i.e., the present disclosure may be practiced without limitation to any particular theory or mechanism.
All features defined herein as numerical ranges or percentage ranges, such as values, amounts, levels and concentrations, are for brevity and convenience only. Accordingly, the description of numerical ranges or percentage ranges should be considered to cover and specifically disclose all possible subranges and individual numerical values (including integers and fractions) within the range. Herein, unless otherwise specified, percentages refer to mass percentages and ratios to mass ratios.
In this context, for the sake of brevity, not all possible combinations of features in the various embodiments or examples are described. Therefore, the respective features in the respective embodiments or examples may be arbitrarily combined as long as there is no contradiction between the combinations of the features, and all the possible combinations should be considered as the scope of the present specification.
The starting materials and materials mentioned herein can be those conventional in the art, and the preparation methods of the materials can be those conventional in the art, and can be reasonably determined by the skilled person based on the disclosure and the prior art, unless otherwise specified.
The inventor of the invention makes extensive and intensive research, introduces the polyethylene glycol terephthalate fiber containing the graphene into the woolen fabric for the first time, obtains the woolen fabric containing the graphene, and greatly improves the heat insulation performance of the fabric while keeping the gram weight of the fabric unchanged. The thermal insulation performance of the woolen fabric containing graphene is far superior to that of the existing woolen fabric.
The woolen fabric is woven and blended woolen fabric. Herein, "fabric" should be understood in a broad sense, i.e., having the same meaning as "cloth" or "fabric". Herein, "woolen" has the meaning well known in the art and refers to fabrics containing wool and/or cashmere fibres. As used herein, "woven" is intended to mean a fabric formed by interlacing two or more sets of yarns perpendicular to each other at a 90 degree angle. As used herein, "blended" refers to a fabric woven from a blend of multiple different fibers. The woolen fabric of the invention is preferably a woolen fabric, in particular a woven and coarse blended woolen fabric. As used herein, "raw" also known as "woolen" has its art-recognized meaning and typically woolen of less than 28 yarns is converted to woolen.
The wool fibers suitable for use in the present invention may be any of various wool fibers commonly used in the art, and the single fiber fineness thereof is preferably from 17 μm to 33 μm, more preferably from 18 μm to 24 μm; the fiber length is preferably 18mm-76mm, more preferably 28mm-65mm, and can be selected according to actual requirements and factors such as monofilament fineness and length of other fibers in the woolen fabric.
Wool fibers suitable for use in the present invention may be, for example but not limited to: goat wool, sheep wool, angora wool, alpah wool, australian wool, new zealand wool, yerba mate wool, argentina wool, american wool, uk wool. It will be appreciated by those skilled in the art that the wool fibres may also contain up to 30% by weight of the total wool fibre of other animal hair, such as one or more of rabbit hair, camel hair, yak hair, alpaca hair, without affecting the properties of the wool fibres.
The graphene suitable for the present invention is not particularly limited, and for example, includes, but is not limited to, single-layer graphene (1LG), double-layer graphene (2LG), multi-layer graphene (MLG), and the like. In a preferred embodiment, the graphene used in the present invention is a multilayer graphene. Herein, multi-layer graphene has the conventional meaning in the art, and generally refers to a two-dimensional material consisting of a stack of 3 or up to 10 layers of graphene. The method for producing graphene suitable for the present invention is not particularly limited, and for example, graphene may be produced by a mechanical exfoliation method, a chemical vapor deposition method, an oxidation-reduction method, a thermal cracking method, an intercalation exfoliation method, a liquid phase exfoliation method, an arc discharge method, a chemical synthesis method, or the like.
When graphene and polymer are blended, the conditions of uneven mixing, agglomeration and the like are easy to occur, and the problems of difficult spinning, poor physical and mechanical properties of the spun fiber and the like are caused. The present invention preferably controls the content of graphene in the fiber. For graphene-containing polyethylene terephthalate fibers, the graphene content is preferably 1% to 2%, for example 1% to 1.5%, of the total weight of the graphene-containing polyethylene terephthalate fibers.
In the present invention, the polyethylene terephthalate is a polyester having ethylene terephthalate units as a main repeating unit, and the ethylene terephthalate units are preferably at least about 70 mol%, more preferably at least about 85 mol%, even more preferably at least about 90 mol%, for example, approximately 100 mol%, of the total repeating units.
In the present invention, the polyethylene terephthalate fiber is not limited to a fiber composed of one kind of polyethylene terephthalate, and may be a fiber containing two or more kinds of polyethylene terephthalate having different polymerization degrees, copolymer compositions, or the like, or a fiber in which at least one main component (70% or more, preferably 85% or more, and more preferably 90% or more of the total mass of the fiber) is polyethylene terephthalate and further contains other components, or the like.
In the present invention, the polyethylene terephthalate fiber may further contain a delustering agent such as titanium dioxide, a stabilizer such as phosphoric acid, an ultraviolet absorber such as a hydroxybenzophenone derivative, a crystal nucleating agent such as talc, an antioxidant such as a hindered phenol derivative, a flame retardant, an antistatic agent, a delustering agent, a pigment, a fluorescent whitening agent, an infrared absorber, a defoaming agent, and the like. The amount of modifier in the polyethylene terephthalate fiber is a level conventional in the art and generally does not exceed 10% by weight of the total weight of the polyethylene terephthalate fiber, preferably does not exceed 5% by weight of the total weight of the polyethylene terephthalate fiber.
The graphene-containing polyethylene terephthalate fibers suitable for use in the present invention are preferably staple fibers. In a preferred embodiment, the graphene-containing polyethylene terephthalate fibers used in the present invention are graphene-containing polyethylene terephthalate staple fibers having a fiber length of between 22mm and 51mm, preferably between 30mm and 51mm, more preferably between 38mm and 51 mm.
The graphene-containing polyethylene terephthalate fiber suitable for use in the present invention preferably has a single filament fineness of between 0.9 dtex and 3 dtex, preferably between 0.9 dtex and 2.5 dtex, more preferably between 0.9 dtex and 2 dtex, for example around 1.5 dtex.
The graphene-containing polyethylene terephthalate fibers suitable for use in the present invention can be prepared by methods known in the art, or can be obtained from commercially available sources.
The graphene-containing woolen fabric (hereinafter referred to as the woolen fabric of the invention) comprises 5-95 parts by weight of wool fibers and 5-95 parts by weight of graphene-containing polyethylene terephthalate fibers, or consists of 5-95 parts by weight of wool fibers and 5-95 parts by weight of graphene-containing polyethylene terephthalate fibers.
In the woolen fabric of the present invention, the mass ratio of the wool fibers to the graphene-containing polyethylene terephthalate fibers may be between 5:95 and 95:5, more preferably between 60:40 and 80:20, and may be, for example, about 70: 30.
In the woolen fabric of the present invention, the sum of the weight of the wool fibers and the weight of the graphene-containing polyethylene terephthalate fibers is generally 10 wt% to 100 wt%, preferably 30 wt% to 100 wt%, more preferably 70 wt% to 100 wt%, and still more preferably 90 wt% to 100 wt% of the total weight of the woolen fabric.
In a preferred embodiment, the woolen fabric of the present invention contains wool fibers and graphene-containing polyethylene terephthalate fibers in a mass ratio of between 60:40 and 80:20, the sum of the weight of the wool fibers and the graphene-containing polyethylene terephthalate fibers making up 90 wt% to 100 wt% of the total weight of the woolen fabric.
In certain embodiments, the woolen fabric of the present invention is comprised of wool fibers and graphene-containing polyethylene terephthalate fibers, preferably at a mass ratio of wool fibers to graphene-containing polyethylene terephthalate fibers of between 5:95 and 95:5, more preferably between 60:40 and 80:20, and may be, for example, around 70: 30.
In certain embodiments, the woolen fabrics of the present invention also contain other fibers in addition to wool fibers and graphene-containing polyethylene terephthalate fibers, the total weight of the other fibers generally not exceeding 90 wt% of the total weight of the woolen fabrics of the present invention. The total weight of the other fibers preferably does not exceed 30 wt%, more preferably does not exceed 70 wt%, more preferably does not exceed 10 wt% of the total weight of the woolen fabric. The other fiber is not particularly limited and may be various fibers suitable for textiles, for example, including, but not limited to, cotton (cotton), silk, mulberry silk (silk), cupra staple fiber (cupra), Modal fiber (Modal), viscose fiber (viscose rayon), polynosic rayon, acetate fiber (acetate), polyester fiber other than polyethylene terephthalate, polyamide fiber, polyacrylonitrile fiber, polypropylene fiber, polyvinyl alcohol fiber, polyvinyl chloride fiber, polyamide-based fiber, and the like.
The weight of the woolen fabric is preferably 240-600 g/sq m, more preferably 240-550 g/sq m, 300-500 g/sq m, 350-500 g/sq m, 300-450 g/sq m, such as 300 g/sq m, 440 g/sq m, etc.
The invention also includes articles made from the graphene-containing woolen fabric according to any embodiment of the invention. The product can be any product containing wool fabric in raw materials, and can be various textiles including clothing textiles, industrial textiles and decorative textiles. In particular, the article may be, but is not limited to, a garment (e.g., a suit, overcoat, coat, pants, coat, etc.), a clothing accessory (e.g., a cape, scarf, headband, etc.), a bedding article (e.g., a blanket, etc.).
The invention also discloses application of the polyethylene terephthalate fiber containing graphene in improving the heat insulation performance of the woolen fabric. In the application of the present invention, the graphene-containing polyethylene terephthalate fiber and woolen cloth fabric may be the graphene-containing polyethylene terephthalate fiber and woolen cloth fabric as described in any one of the above embodiments.
The invention is further illustrated by the following specific examples. The following examples use instrumentation conventional in the art. The experimental procedures, in which specific conditions are not noted in the following examples, are generally carried out under conventional conditions or conditions recommended by the manufacturers. In the following examples, various starting materials were used, and unless otherwise specified, conventional commercially available products were used. Unless otherwise specified, the percentages in the examples are percentages by mass, and the ratios are mass ratios.
The wool used in the examples was sheep wool having a fiber length of 28mm to 30mm and a single-filament fineness of 20 μm to 22 μm.
Example 1: wool/graphene-containing polyethylene terephthalate short fiber woolen fabric
70 parts by weight of wool and 30 parts by weight of polyethylene terephthalate short fiber containing graphene are prepared into woven rough woolen fabric according to a conventional preparation method. The fiber length of the polyethylene terephthalate short fiber containing graphene is 38mm, the filament number is 1.5 dtex, the graphene content is 1 wt%, the graphene is multilayer graphene, and the gram weight of the woven rough woolen fabric is 440 g/square meter.
Comparative example 1: wool/polyethylene terephthalate short fiber woolen fabric
70 parts by weight of wool and 30 parts by weight of polyethylene terephthalate short fibers (not containing graphene) are made into woven rough woolen fabric according to a conventional manufacturing method. The length of the polyethylene terephthalate short fiber is 38mm, the filament number is 1.5 dtex, and the gram weight of the prepared woven rough woolen fabric is 440 g/square meter.
Comparative example 2: pure wool woolen fabric
The wool is made into the woven rough woolen fabric according to a conventional manufacturing method, and the gram weight of the made woven rough woolen fabric is 440 g/square meter.
Test example:
the heat insulation performance of the woolen fabrics of example 1, comparative example 1 and comparative example 2 is measured by GB/T11048-1989 (textile heat insulation performance test method). The test results are shown in table 1.
Table 1: heat insulation performance test result of woolen fabric
In general, a woolen fabric made of pure wool has a decreased thermal insulation property as compared with a woolen fabric made of pure wool by blending polyethylene terephthalate fibers with wool. From the test results in table 1, it is clear that the heat retention of the crude woolen fabric of comparative example 1 obtained by blending the polyethylene terephthalate short fibers containing no graphene with wool is slightly lower than that of the pure wool fabric of comparative example 2.
However, the thermal insulation performance of the rough woolen fabric obtained by blending the graphene-containing polyethylene terephthalate short fibers and wool in example 1 is greatly improved, and the thermal insulation rate is improved by 15% compared with that of the pure wool fabric in comparative example 2. The woolen cloth suede material added with 30% of polyethylene glycol terephthalate short fibers containing graphene has better heat preservation performance than pure wool fabric, and the technical effect is unexpected. In addition, the heat retention of the rough woolen fabric obtained by blending the graphene-containing polyethylene terephthalate short fibers and the wool in example 1 was improved by 20% compared with the fabric obtained by blending the graphene-free polyethylene terephthalate short fibers and the wool in the same proportion. The thermal insulation performance of the graphene-containing woolen fabric is obviously superior to that of the existing woolen fabric.
Example 2: wool/graphene-containing polyethylene terephthalate short fiber woolen fabric
70 parts by weight of wool and 30 parts by weight of polyethylene terephthalate short fiber containing graphene are prepared into woven rough woolen fabric according to a conventional preparation method. The fiber length of the polyethylene terephthalate short fiber containing graphene is 38mm, the filament number is 0.9 dtex, the graphene content is 1 wt%, the graphene is multilayer graphene, and the gram weight of the woven rough woolen fabric is 360 g/square meter.
Example 3: wool/graphene-containing polyethylene terephthalate short fiber woolen fabric
80 parts by weight of wool and 20 parts by weight of polyethylene terephthalate short fiber containing graphene are prepared into woven rough woolen fabric according to a conventional preparation method. The fiber length of the polyethylene terephthalate short fiber containing graphene is 38mm, the filament number is 2.0 dtex, the graphene content is 2 wt%, the graphene is multilayer graphene, and the gram weight of the woven rough woolen fabric prepared is 400 g/square meter.
Example 4: wool/graphene-containing polyethylene terephthalate short fiber woolen fabric
60 parts by weight of wool and 40 parts by weight of polyethylene terephthalate short fiber containing graphene are prepared into woven rough woolen fabric according to a conventional preparation method. The fiber length of the polyethylene terephthalate short fiber containing graphene is 51mm, the filament number is 1.5 dtex, the graphene content is 1 wt%, the graphene is multilayer graphene, and the gram weight of the woven rough woolen fabric is 480 g/square meter.
GB/T11048-9 textile thermal insulation test method the thermal insulation properties of the woolen fabrics of examples 2 to 4 were measured. The result shows that the prepared woven crude woolen fabric has the heat preservation rate of over 29 percent and the heat transfer coefficient of 33W/cm2Below DEG C, the Crohn value is above 0.20.
Claims (10)
1. The graphene-containing woolen fabric is characterized by comprising wool fibers and graphene-containing polyethylene terephthalate fibers, wherein the mass ratio of the wool fibers to the graphene-containing polyethylene terephthalate fibers is 5:95 to 95: 5.
2. The graphene-containing woolen fabric according to claim 1, wherein the graphene-containing polyethylene terephthalate fibers have a length of 22mm to 51 mm.
3. The graphene-containing woolen fabric of claim 1 wherein the graphene is multilayer graphene.
4. The graphene-containing woolen fabric according to claim 1, wherein the sum of the weight of the wool fibers and the weight of the graphene-containing polyethylene terephthalate fibers is 10 wt% to 100 wt% of the total weight of the graphene-containing woolen fabric.
5. The graphene-containing woolen fabric according to claim 1, wherein the graphene-containing polyethylene terephthalate fiber has a graphene content of 1 wt% to 2 wt% based on the total weight of the graphene-containing polyethylene terephthalate fiber.
6. The graphene-containing woolen fabric of claim 1, wherein the graphene-containing polyethylene terephthalate fibers have a single filament denier of between 0.9 dtex and 3 dtex.
7. The graphene-containing woolen fabric according to claim 1, wherein the graphene-containing woolen fabric further comprises one or more fibers selected from cotton, silk, mulberry silk, cuprammonium short fiber, modal fiber, viscose fiber, polynosic fiber, acetate fiber, polyester fiber other than polyethylene terephthalate, polyamide fiber, polyacrylonitrile fiber, polypropylene fiber, polyvinyl alcohol fiber, polyvinyl chloride fiber, and polyamide fiber.
8. An article made from the graphene-containing woolen fabric of any one of claims 1-7.
9. The application of the polyethylene terephthalate fiber containing graphene in improving the heat preservation performance of woolen fabric.
10. The application of claim 9, wherein the application has one or more of the following features:
(1) the length of the polyethylene terephthalate fiber containing graphene is 22-51 mm;
(2) the graphene is multilayer graphene;
(3) the graphene content of the graphene-containing polyethylene terephthalate fiber is 1 wt% -2 wt%; and
(4) the graphene-containing polyethylene terephthalate fiber has a single filament fineness of between 0.9 dtex and 3 dtex.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201911188666.3A CN110846782B (en) | 2019-11-28 | 2019-11-28 | Woven rough-blended woolen fabric containing graphene |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201911188666.3A CN110846782B (en) | 2019-11-28 | 2019-11-28 | Woven rough-blended woolen fabric containing graphene |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN110846782A true CN110846782A (en) | 2020-02-28 |
| CN110846782B CN110846782B (en) | 2022-01-28 |
Family
ID=69605996
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201911188666.3A Active CN110846782B (en) | 2019-11-28 | 2019-11-28 | Woven rough-blended woolen fabric containing graphene |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN110846782B (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111850729A (en) * | 2020-07-28 | 2020-10-30 | 吴炅 | Thin warm type aerogel textile fiber fabric and preparation method thereof |
| CN113005585A (en) * | 2021-03-08 | 2021-06-22 | 苏州大学 | Covered yarn spinning device and preparation method of flame-retardant and anti-electric arc covered yarn |
| CN113005602A (en) * | 2021-02-28 | 2021-06-22 | 佛山奥轩科技有限公司 | Multifunctional graphene fabric |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1834314A (en) * | 2006-03-06 | 2006-09-20 | 上海昌明实业有限公司 | Blend fabric and shuttled fabric from the same and mfg. thereof |
| CN108315860A (en) * | 2018-03-15 | 2018-07-24 | 南通强生石墨烯科技有限公司 | A kind of preparation method of Graphene antibiosis towel |
| CN108950812A (en) * | 2018-08-28 | 2018-12-07 | 江苏倪家巷集团精毛纺织有限公司 | The spinning technique of graphene fiber fabric |
| CN109629080A (en) * | 2019-01-25 | 2019-04-16 | 淄博飞狮巾被有限公司 | A kind of antibacterial and the Graphene towel and preparation method thereof to promote blood circulation |
| CN109770450A (en) * | 2017-11-10 | 2019-05-21 | 江苏云蝠服饰股份有限公司 | A kind of woollen sweater and its method for weaving |
| CN110067067A (en) * | 2019-05-07 | 2019-07-30 | 浙江富润纺织有限公司 | A kind of hair washs graphene stretch nylon and its production method |
-
2019
- 2019-11-28 CN CN201911188666.3A patent/CN110846782B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1834314A (en) * | 2006-03-06 | 2006-09-20 | 上海昌明实业有限公司 | Blend fabric and shuttled fabric from the same and mfg. thereof |
| CN109770450A (en) * | 2017-11-10 | 2019-05-21 | 江苏云蝠服饰股份有限公司 | A kind of woollen sweater and its method for weaving |
| CN108315860A (en) * | 2018-03-15 | 2018-07-24 | 南通强生石墨烯科技有限公司 | A kind of preparation method of Graphene antibiosis towel |
| CN108950812A (en) * | 2018-08-28 | 2018-12-07 | 江苏倪家巷集团精毛纺织有限公司 | The spinning technique of graphene fiber fabric |
| CN109629080A (en) * | 2019-01-25 | 2019-04-16 | 淄博飞狮巾被有限公司 | A kind of antibacterial and the Graphene towel and preparation method thereof to promote blood circulation |
| CN110067067A (en) * | 2019-05-07 | 2019-07-30 | 浙江富润纺织有限公司 | A kind of hair washs graphene stretch nylon and its production method |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111850729A (en) * | 2020-07-28 | 2020-10-30 | 吴炅 | Thin warm type aerogel textile fiber fabric and preparation method thereof |
| CN113005602A (en) * | 2021-02-28 | 2021-06-22 | 佛山奥轩科技有限公司 | Multifunctional graphene fabric |
| CN113005585A (en) * | 2021-03-08 | 2021-06-22 | 苏州大学 | Covered yarn spinning device and preparation method of flame-retardant and anti-electric arc covered yarn |
Also Published As
| Publication number | Publication date |
|---|---|
| CN110846782B (en) | 2022-01-28 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN110846782B (en) | Woven rough-blended woolen fabric containing graphene | |
| EP2222909B1 (en) | Yarns, high wear resistance fabrics and objects made therefrom | |
| JP6068470B2 (en) | Core-sheath composite fiber | |
| CN103284368A (en) | Blended flame-retardant fabric and flame-retardant protecting clothes | |
| CN104726997A (en) | Making method for bio-fiber/bamboo charcoal fiber/viscose fiber blended fabric | |
| CN107385544A (en) | A kind of flame-resistant terylene protective garment fabric | |
| CN108166119A (en) | The fire-retardant blend of comfort arc protection | |
| CN110004554B (en) | High-softness flame-retardant fabric | |
| EP3351662A1 (en) | Fiber for cool contact sensation and fiber product in which same is used | |
| CN103290593B (en) | Wear-resistant, flame-retardant and comfortable fabric with chopped fiber composites and application of wear-resistant, flame-retardant and comfortable fabric | |
| CN105568492A (en) | Toweling composite fabric with water resistance, moisture permeability and breathability | |
| EP1655394B1 (en) | Spun yarn | |
| KR100668213B1 (en) | Nylon 66 Natural Stretch Yarn, the process of producing thereof and the process of producing excellent stretching fabrics using thereby | |
| CN110468463A (en) | A kind of high-end knitting fabric and its processing method | |
| CN105839267A (en) | Flame-retardant polysulfonamide blended fabric | |
| JP3189049U (en) | Temperature drop fabric | |
| KR20140135156A (en) | Polyamide fabric enhancing body warming | |
| CN103361870B (en) | The BLENDED FABRIC of Ju Fang oxadiazole and anti-flaming viscose | |
| CN203354178U (en) | Household blanket with high heat protection value | |
| JP5785720B2 (en) | Knitted fabric and textile products using the same | |
| KR101807000B1 (en) | High Gravity Polyester Composite Yarn and Fabric | |
| CN109049899B (en) | Composite functional fabric | |
| CN106868669B (en) | A kind of polytetrafluoroethylene fibre/woolen spinning yarn and preparation method thereof | |
| CN105568489A (en) | Purely natural linen textile fabric | |
| CN114302985A (en) | Acrylic fiber, spun yarn and knitted fabric comprising same |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |