CN109629080A - A kind of antibacterial and the Graphene towel and preparation method thereof to promote blood circulation - Google Patents

A kind of antibacterial and the Graphene towel and preparation method thereof to promote blood circulation Download PDF

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Publication number
CN109629080A
CN109629080A CN201910074499.3A CN201910074499A CN109629080A CN 109629080 A CN109629080 A CN 109629080A CN 201910074499 A CN201910074499 A CN 201910074499A CN 109629080 A CN109629080 A CN 109629080A
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graphene
towel
fiber
ultra
blood circulation
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赵刚
高长胜
吕凤兰
孙尧
冯红光
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Zibo Feishi Texitiles Co Ltd
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Zibo Feishi Texitiles Co Ltd
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Publication of CN109629080A publication Critical patent/CN109629080A/en
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    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/40Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads
    • D03D15/47Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads multicomponent, e.g. blended yarns or threads
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00Formation of filaments, threads, or the like
    • D01D5/28Formation of filaments, threads, or the like while mixing different spinning solutions or melts during the spinning operation; Spinnerette packs therefor
    • D01D5/30Conjugate filaments; Spinnerette packs therefor
    • D01D5/34Core-skin structure; Spinnerette packs therefor
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00General methods for the manufacture of artificial filaments or the like
    • D01F1/02Addition of substances to the spinning solution or to the melt
    • D01F1/10Other agents for modifying properties
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/02Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from cellulose, cellulose derivatives, or proteins
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/04Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
    • D01F8/14Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyester as constituent
    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02GCRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/02Yarns or threads characterised by the material or by the materials from which they are made
    • D02G3/04Blended or other yarns or threads containing components made from different materials
    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02GCRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/44Yarns or threads characterised by the purpose for which they are designed
    • D02G3/449Yarns or threads with antibacterial properties
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D27/00Woven pile fabrics
    • D03D27/02Woven pile fabrics wherein the pile is formed by warp or weft
    • D03D27/06Warp pile fabrics
    • D03D27/08Terry fabrics
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2101/00Inorganic fibres
    • D10B2101/10Inorganic fibres based on non-oxides other than metals
    • D10B2101/12Carbon; Pitch
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2201/00Cellulose-based fibres, e.g. vegetable fibres
    • D10B2201/01Natural vegetable fibres
    • D10B2201/02Cotton
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2201/00Cellulose-based fibres, e.g. vegetable fibres
    • D10B2201/20Cellulose-derived artificial fibres
    • D10B2201/22Cellulose-derived artificial fibres made from cellulose solutions
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2211/00Protein-based fibres, e.g. animal fibres
    • D10B2211/01Natural animal fibres, e.g. keratin fibres
    • D10B2211/04Silk
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2211/00Protein-based fibres, e.g. animal fibres
    • D10B2211/20Protein-derived artificial fibres
    • D10B2211/26Globulin, e.g. groundnut protein
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2321/00Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D10B2321/02Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polyolefins
    • D10B2321/022Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polyolefins polypropylene
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/04Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00Physical properties
    • D10B2401/13Physical properties anti-allergenic or anti-bacterial

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Woven Fabrics (AREA)
  • Artificial Filaments (AREA)

Abstract

The present invention relates to household items technical fields, specially a kind of antibacterial and the Graphene towel to promote blood circulation, including (according to mass percent meter): graphene ultra-fine polyester fiber 30-45%, general fibre 10-25%, chitin fiber 5-15%, ultra-fine hollow terylene 25-35%, silica gel 3-4%, nano silver 1-2%.The invention also discloses a kind of antibacterial and the preparation methods of Graphene towel that promote blood circulation, comprising the following steps: S1: prepares cortex material;S2: composite spinning;S3: blended;S4: winder;S5: warping;S6: sizing;S7: weaving;S8: dyeing;S9: it arranges.Have the beneficial effect that antibacterial agent uses the nano-Ag particles using silica gel as carrier, graphene ultra-fine polyester fiber outer layer is distributed in by composite spinning mode, nano silver dosage can not only be reduced, and it reduces to graphene ultra-fine polyester fiber Effect on Mechanical Properties, antibiotic property is strong, elasticity is good, gas permeability is good, can industrial mass production.

Description

A kind of antibacterial and the Graphene towel and preparation method thereof to promote blood circulation
Technical field
The present invention relates to household items technical field, specially a kind of antibacterial and the Graphene towel to promote blood circulation and Preparation method.
Background technique
For common cotton towel using cotton as raw material, the characteristic of pure cotton is that water suction is easy to damp, especially in plum rain season and south, There was dampness in the air, and towel, which is constantly under humid air, is not easy drying, and such towel is easy for generating bacterium and mildew, cause using Person's pruitus, allergy, or even skin disease must be gone up.
Summary of the invention
The purpose of the present invention is to provide a kind of antibacterial and the Graphene towel and preparation method thereof that promotes blood circulation, with Solve the problems mentioned above in the background art.
To achieve the above object, the invention provides the following technical scheme: a kind of antibacterial and the graphene to promote blood circulation Towel, including (according to mass percent meter): graphene ultra-fine polyester fiber 30-45%, general fibre 10-25%, chitin Fiber 5-15%, ultra-fine hollow terylene 25-35%, silica gel 3-4%, nano silver 1-2%.
Preferably, the graphene ultra-fine polyester fiber is prepared by biomass graphene and terylene using prefabricated master batch technique It forms, wherein biomass graphene is corncob graphene, and mass fraction 1.0%, far infrared incidence is 0.88.
Preferably, the general fibre is fine using ptt fiber, polypropylene fiber, Modal fibre, Niu Daier fiber, fibroin One or more of dimension, cotton fiber, zein fiber, chitin fiber, bamboo charcoal fiber, wood-fibred, soybean fiber are blended It forms.
Preferably, the diameter of the chitin fiber is 1.5D, and color is pure white.
Preferably, the Kong Rongwei 1.0-1.3cm of the silica gel3/ g, average pore size 10.0-15.0nm, specific surface area are 250.0-290.0m2/ g, water content are lower than 5%.
A kind of preparation method of antibacterial and the Graphene towel to promote blood circulation, comprising the following steps:
S1: preparing cortex material, and silica gel and nano silver investment grinder after evenly mixing, exist with chitin fiber Under the conditions of 120-150 DEG C, cortex material is obtained through double-screw extruding pelletizing;
S2: composite spinning uses core-sheath by cortex material and graphene ultra-fine polyester fiber under inert gas protection Spinning machine produces composite fibre silk, is cooled to room temperature, then by composite fibre silk under the conditions of 80-100 DEG C, is stretched, cut off, Obtain functional fibre silk;
S3: it is blended, functional fibre silk pre-drawing is fed after carding machine with general fibre together, obtains scribbled;
S4: scribbled is twisted, is miscellaneous clearly, on doff bobbin by winder;
S5: warping draws the scribbled of certain radical and length from doff bobbin, forms a width yarn sheet, makes to mix Yarn is tightly wound on warp beam in parallel to each other;
S6: then sizing is squeezed, dries, is wound by the scribbled on warp beam and at a piece of, and by slurries Beam of a loom;
S7: weaving, using ultra-fine hollow terylene as ground warp and weft yarns, scribbled is plush yarn, is weaved, is obtained To towel fabric;
S8: towel fabric is first bleached poststaining by dyeing;
S9: arranging, and stained towel fabric is punched, and sorts out, obtains finished product towel.
Preferably, in step 2, the dosage volume ratio 2:3 of the cortex material and graphene ultra-fine polyester fiber.
Preferably, in step 2, the composite fibre silk draw ratio is 3-4 times.
Preferably, in step 6, the slurries include (according to mass percent meter): converted starch 9%, starching smooth agent 1% and aqueous solvent 90%.
Compared with prior art, the beneficial effects of the present invention are:
1. present invention process is simple, rationally, antibacterial agent uses the nano-Ag particles using silica gel as carrier to formula, by compound Spinning mode is distributed in graphene ultra-fine polyester fiber outer layer, can not only reduce nano silver dosage, but also reduce to graphite Alkene ultra-fine polyester fiber Effect on Mechanical Properties, antibiotic property is strong, elasticity is good, gas permeability is good, can industrial mass production;
2. the present invention is in such a way that graphene ultra-fine polyester fiber incorporates graphene, when sticking towel, graphene hair Far infrared not only promotes face's blood microcirculation out, but also expands face's pore, and cleaning effect is more preferably, and antibacterial anti- Bacterium, it is environmentally protective, it is safe and secure.
Specific embodiment
The following is a clear and complete description of the technical scheme in the embodiments of the invention, it is clear that described embodiment Only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, the common skill in this field Art personnel every other embodiment obtained without making creative work belongs to the model that the present invention protects It encloses.
Embodiment 1
The present invention provides a kind of technical solution: a kind of antibacterial and the Graphene towel to promote blood circulation, including (according to matter Measure percentages): graphene ultra-fine polyester fiber 30%, general fibre 25%, chitin fiber 15%, ultra-fine hollow polyester are fine Tie up 25%, silica gel 4%, nano silver 1%.
A kind of preparation method of antibacterial and the Graphene towel to promote blood circulation, comprising the following steps:
S1: preparing cortex material, and silica gel and nano silver investment grinder after evenly mixing, exist with chitin fiber Under the conditions of 120 DEG C, cortex material is obtained through double-screw extruding pelletizing;
S2: composite spinning uses core-sheath by cortex material and graphene ultra-fine polyester fiber under inert gas protection Spinning machine produces composite fibre silk, is cooled to room temperature, then composite fibre silk is stretched, cut off, obtained under the conditions of 80 DEG C Functional fibre silk;
S3: it is blended, functional fibre silk pre-drawing is fed after carding machine with general fibre together, obtains scribbled;
S4: scribbled is twisted, is miscellaneous clearly, on doff bobbin by winder;
S5: warping draws the scribbled of certain radical and length from doff bobbin, forms a width yarn sheet, makes to mix Yarn is tightly wound on warp beam in parallel to each other;
S6: then sizing is squeezed, dries, is wound by the scribbled on warp beam and at a piece of, and by slurries Beam of a loom;
S7: weaving, using ultra-fine hollow terylene as ground warp and weft yarns, scribbled is plush yarn, is weaved, is obtained To towel fabric;
S8: towel fabric is first bleached poststaining by dyeing;
S9: arranging, and stained towel fabric is punched, and sorts out, obtains finished product towel.
Wherein, graphene ultra-fine polyester fiber is prepared by biomass graphene and terylene using prefabricated master batch technique, Wherein biomass graphene is corncob graphene, and mass fraction 1.0%, far infrared incidence is 0.88;It is common fine Dimension uses ptt fiber;The diameter of chitin fiber is 1.5D, and color is pure white;The Kong Rongwei 1.2cm of silica gel3/ g, average hole Diameter is 10nm, specific surface area 280.0m2/ g, water content 2%;In step 2, cortex material and graphene ultra-fine polyester fiber Dosage volume ratio 2:3;In step 2, composite fibre silk draw ratio is 3 times;In step 6, slurries include (according to quality hundred Divide than meter): converted starch 9%, starching smooth agent 1% and aqueous solvent 90%.
Embodiment 2
The present invention provides a kind of technical solution: a kind of antibacterial and the Graphene towel to promote blood circulation, including (according to matter Measure percentages): graphene ultra-fine polyester fiber 35%, general fibre 20%, chitin fiber 15%, ultra-fine hollow polyester are fine Tie up 25%, silica gel 4%, nano silver 1%.
A kind of preparation method of antibacterial and the Graphene towel to promote blood circulation, comprising the following steps:
S1: preparing cortex material, and silica gel and nano silver investment grinder after evenly mixing, exist with chitin fiber Under the conditions of 130 DEG C, cortex material is obtained through double-screw extruding pelletizing;
S2: composite spinning uses core-sheath by cortex material and graphene ultra-fine polyester fiber under inert gas protection Spinning machine produces composite fibre silk, is cooled to room temperature, then composite fibre silk is stretched, cut off, obtained under the conditions of 85 DEG C Functional fibre silk;
S3: it is blended, functional fibre silk pre-drawing is fed after carding machine with general fibre together, obtains scribbled;
S4: scribbled is twisted, is miscellaneous clearly, on doff bobbin by winder;
S5: warping draws the scribbled of certain radical and length from doff bobbin, forms a width yarn sheet, makes to mix Yarn is tightly wound on warp beam in parallel to each other;
S6: then sizing is squeezed, dries, is wound by the scribbled on warp beam and at a piece of, and by slurries Beam of a loom;
S7: weaving, using ultra-fine hollow terylene as ground warp and weft yarns, scribbled is plush yarn, is weaved, is obtained To towel fabric;
S8: towel fabric is first bleached poststaining by dyeing;
S9: arranging, and stained towel fabric is punched, and sorts out, obtains finished product towel.
Wherein, graphene ultra-fine polyester fiber is prepared by biomass graphene and terylene using prefabricated master batch technique, Wherein biomass graphene is corncob graphene, and mass fraction 1.0%, far infrared incidence is 0.88;It is common fine Dimension is using bamboo charcoal fiber and wood-fibred is blended forms;The diameter of chitin fiber is 1.5D, and color is pure white;The Kong Rong of silica gel For 1.2cm3/ g, average pore size 10.0nm, specific surface area 280.0m2/ g, water content 2%;In step 2, cortex material and The dosage volume ratio 2:3 of graphene ultra-fine polyester fiber;In step 2, composite fibre silk draw ratio is 3 times;In step 6, Slurries include (according to mass percent meter): converted starch 9%, starching smooth agent 1% and aqueous solvent 90%.
Embodiment 3
The present invention provides a kind of technical solution: a kind of antibacterial and the Graphene towel to promote blood circulation, including (according to matter Measure percentages): graphene ultra-fine polyester fiber 40%, general fibre 15%, chitin fiber 10%, ultra-fine hollow polyester are fine Tie up 30%, silica gel 3%, nano silver 2%.
A kind of preparation method of antibacterial and the Graphene towel to promote blood circulation, comprising the following steps:
S1: preparing cortex material, and silica gel and nano silver investment grinder after evenly mixing, exist with chitin fiber Under the conditions of 140 DEG C, cortex material is obtained through double-screw extruding pelletizing;
S2: composite spinning uses core-sheath by cortex material and graphene ultra-fine polyester fiber under inert gas protection Spinning machine produces composite fibre silk, is cooled to room temperature, then composite fibre silk is stretched, cut off, obtained under the conditions of 90 DEG C Functional fibre silk;
S3: it is blended, functional fibre silk pre-drawing is fed after carding machine with general fibre together, obtains scribbled;
S4: scribbled is twisted, is miscellaneous clearly, on doff bobbin by winder;
S5: warping draws the scribbled of certain radical and length from doff bobbin, forms a width yarn sheet, makes to mix Yarn is tightly wound on warp beam in parallel to each other;
S6: then sizing is squeezed, dries, is wound by the scribbled on warp beam and at a piece of, and by slurries Beam of a loom;
S7: weaving, using ultra-fine hollow terylene as ground warp and weft yarns, scribbled is plush yarn, is weaved, is obtained To towel fabric;
S8: towel fabric is first bleached poststaining by dyeing;
S9: arranging, and stained towel fabric is punched, and sorts out, obtains finished product towel.
Wherein, graphene ultra-fine polyester fiber is prepared by biomass graphene and terylene using prefabricated master batch technique, Wherein biomass graphene is corncob graphene, and mass fraction 1.0%, far infrared incidence is 0.88;It is common fine Dimension uses Modal fibre;The diameter of chitin fiber is 1.5D, and color is pure white;The Kong Rongwei 1.0cm of silica gel3/ g is put down Equal aperture is 12.0nm, specific surface area 250.0m2/ g, water content 2%;In step 2, cortex material and graphene is ultra-fine washs The dosage volume ratio 2:3 of synthetic fibre fiber;In step 2, composite fibre silk draw ratio is 4 times;In step 6, slurries include (according to Mass percent meter): converted starch 9%, starching smooth agent 1% and aqueous solvent 90%.
Embodiment 4
The present invention provides a kind of technical solution: a kind of antibacterial and the Graphene towel to promote blood circulation, including (according to matter Measure percentages): graphene ultra-fine polyester fiber 45%, general fibre 10%, chitin fiber 5%, ultra-fine hollow polyester are fine Tie up 35%, silica gel 3%, nano silver 2%.
A kind of preparation method of antibacterial and the Graphene towel to promote blood circulation, comprising the following steps:
S1: preparing cortex material, and silica gel and nano silver investment grinder after evenly mixing, exist with chitin fiber Under the conditions of 150 DEG C, cortex material is obtained through double-screw extruding pelletizing;
S2: composite spinning uses core-sheath by cortex material and graphene ultra-fine polyester fiber under inert gas protection Spinning machine produces composite fibre silk, is cooled to room temperature, then composite fibre silk is stretched, cut off, obtained under the conditions of 100 DEG C To functional fibre silk;
S3: it is blended, functional fibre silk pre-drawing is fed after carding machine with general fibre together, obtains scribbled;
S4: scribbled is twisted, is miscellaneous clearly, on doff bobbin by winder;
S5: warping draws the scribbled of certain radical and length from doff bobbin, forms a width yarn sheet, makes to mix Yarn is tightly wound on warp beam in parallel to each other;
S6: then sizing is squeezed, dries, is wound by the scribbled on warp beam and at a piece of, and by slurries Beam of a loom;
S7: weaving, using ultra-fine hollow terylene as ground warp and weft yarns, scribbled is plush yarn, is weaved, is obtained To towel fabric;
S8: towel fabric is first bleached poststaining by dyeing;
S9: arranging, and stained towel fabric is punched, and sorts out, obtains finished product towel.
Wherein, graphene ultra-fine polyester fiber is prepared by biomass graphene and terylene using prefabricated master batch technique, Wherein biomass graphene is corncob graphene, and mass fraction 1.0%, far infrared incidence is 0.88;It is common fine Dimension uses zein fiber;The diameter of chitin fiber is 1.5D, and color is pure white;The Kong Rongwei 1.3cm of silica gel3/ g, it is average Aperture is 15.0nm, specific surface area 290.0m2/ g, water content 2%;In step 2, cortex material and graphene super fine polyester The dosage volume ratio 2:3 of fiber;In step 2, composite fibre silk draw ratio is 4 times;In step 6, slurries include (according to matter Measure percentages): converted starch 9%, starching smooth agent 1% and aqueous solvent 90%.
Using common cotton knop cloth as reference, four groups of above-mentioned embodiments are lain in a horizontal plane in the environment of same humidity In, after standing 24 hours, the mean concentration (CFU/mL) of Escherichia coli and staphylococcus aureus is counted respectively, such as 1 institute of table Show:
Table 1
Strain bacteriostasis rate calculating formula are as follows: (the strain mean concentration of common cotton knop cloth-embodiment strain concentration is flat Mean value)/common cotton knop cloth strain mean concentration × 100%.
The Graphene towel they four groups of above-mentioned embodiments available antibacterial of the invention and promoted blood circulation, wherein The towel bacteriostasis rate highest that embodiment 2 obtains, is worth of widely use.
The invention has the following advantages that present invention process is simple, rationally, antibacterial agent uses receiving using silica gel as carrier to formula Rice Argent grain, is distributed in graphene ultra-fine polyester fiber outer layer by composite spinning mode, can not only reduce nano silver dosage, And reduce to graphene ultra-fine polyester fiber Effect on Mechanical Properties, antibiotic property is strong, elasticity is good, gas permeability is good, can be industrial big Large-scale production;The present invention is in such a way that graphene ultra-fine polyester fiber incorporates graphene, and when sticking towel, graphene is issued Far infrared not only promotes face's blood microcirculation, but also expands face's pore, cleaning effect more preferably, and bacteriostasis antibiosis, It is environmentally protective, it is safe and secure.
It although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with A variety of variations, modification, replacement can be carried out to these embodiments without departing from the principles and spirit of the present invention by understanding And modification, the scope of the present invention is defined by the appended.

Claims (9)

1. a kind of antibacterial and the Graphene towel to promote blood circulation, which is characterized in that including (according to mass percent meter): stone Black alkene ultra-fine polyester fiber 30-45%, general fibre 10-25%, chitin fiber 5-15%, ultra-fine hollow terylene 25- 35%, silica gel 3-4%, nano silver 1-2%.
2. a kind of antibacterial according to claim 1 and the Graphene towel to promote blood circulation, it is characterised in that: the stone Black alkene ultra-fine polyester fiber is prepared by biomass graphene and terylene using prefabricated master batch technique, wherein biomass graphene For corncob graphene, mass fraction 1.0%, far infrared incidence is 0.88.
3. a kind of antibacterial according to claim 1 and the Graphene towel to promote blood circulation, it is characterised in that: described general Perforating fiber uses ptt fiber, polypropylene fiber, Modal fibre, Niu Daier fiber, fibroin fiber, cotton fiber, zein fiber, first One or more of shell cellulose fiber, bamboo charcoal fiber, wood-fibred, soybean fiber are blended to be formed.
4. a kind of antibacterial according to claim 1 and the Graphene towel to promote blood circulation, it is characterised in that: the first The diameter of shell cellulose fiber is 1.5D, and color is pure white.
5. a kind of antibacterial according to claim 1 and the Graphene towel to promote blood circulation, it is characterised in that: the silicon The Kong Rongwei 1.0-1.3cm of glue3/ g, average pore size 10.0-15.0nm, specific surface area 250.0-290.0m2/ g, water content Lower than 5%.
6. the preparation method of a kind of antibacterial as described in any one in claim 1-5 and the Graphene towel to promote blood circulation, Characterized by comprising the following steps:
S1: preparing cortex material, and silica gel and nano silver investment grinder are carried out after evenly mixing, with chitin fiber in 120- Under the conditions of 150 DEG C, cortex material is obtained through double-screw extruding pelletizing;
S2: composite spinning, by cortex material and graphene ultra-fine polyester fiber under inert gas protection, with core-sheath spinning Mechanism goes out composite fibre silk, is cooled to room temperature, then by composite fibre silk under the conditions of 80-100 DEG C, is stretched, cut off, and obtains Functional fibre silk;
S3: it is blended, functional fibre silk pre-drawing is fed after carding machine with general fibre together, obtains scribbled;
S4: scribbled is twisted, is miscellaneous clearly, on doff bobbin by winder;
S5: warping draws the scribbled of certain radical and length from doff bobbin, forms a width yarn sheet, makes mixed yarn Line is tightly wound on warp beam in parallel to each other;
S6: then sizing squeezes, dries, is wound into beam of a loom by the scribbled on warp beam and at a piece of, and by slurries;
S7: weaving, using ultra-fine hollow terylene as ground warp and weft yarns, scribbled is plush yarn, is weaved, obtains hair Towel fabric;
S8: towel fabric is first bleached poststaining by dyeing;
S9: arranging, and stained towel fabric is punched, and sorts out, obtains finished product towel.
7. the preparation method of a kind of antibacterial according to claim 6 and the Graphene towel to promote blood circulation, feature It is: in step 2, the dosage volume ratio 2:3 of the cortex material and graphene ultra-fine polyester fiber.
8. the preparation method of a kind of antibacterial according to claim 6 and the Graphene towel to promote blood circulation, feature Be: in step 2, the composite fibre silk draw ratio is 3-4 times.
9. the preparation method of a kind of antibacterial according to claim 6 and the Graphene towel to promote blood circulation, feature Be: in step 6, the slurries include (according to mass percent meter): converted starch 9%, starching smooth agent 1% and solvent Water 90%.
CN201910074499.3A 2019-01-25 2019-01-25 A kind of antibacterial and the Graphene towel and preparation method thereof to promote blood circulation Pending CN109629080A (en)

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CN110846782A (en) * 2019-11-28 2020-02-28 上海昌明实业有限公司 Woven rough-blended woolen fabric containing graphene
CN112274044A (en) * 2020-11-04 2021-01-29 淄博飞狮巾被有限公司 Yarn-dyed four-layer combed untwisted color strip multi-arm scarf
CN112281282A (en) * 2020-11-04 2021-01-29 淄博飞狮巾被有限公司 Graphene towel quilt
CN112281274A (en) * 2020-11-04 2021-01-29 淄博飞狮巾被有限公司 Three-layer cotton-linen wrinkled gauze jacquard towel blanket
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Publication number Priority date Publication date Assignee Title
CN110846782A (en) * 2019-11-28 2020-02-28 上海昌明实业有限公司 Woven rough-blended woolen fabric containing graphene
AU2020239781B2 (en) * 2020-04-14 2021-11-25 Guangdong Newdermo Biotech Co.,Ltd Method for preparing porous antibacterial fiber brush
CN112274044A (en) * 2020-11-04 2021-01-29 淄博飞狮巾被有限公司 Yarn-dyed four-layer combed untwisted color strip multi-arm scarf
CN112281282A (en) * 2020-11-04 2021-01-29 淄博飞狮巾被有限公司 Graphene towel quilt
CN112281274A (en) * 2020-11-04 2021-01-29 淄博飞狮巾被有限公司 Three-layer cotton-linen wrinkled gauze jacquard towel blanket
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CN112281282B (en) * 2020-11-04 2021-11-19 淄博飞狮巾被有限公司 Graphene towel quilt
CN112274044B (en) * 2020-11-04 2022-02-15 淄博飞狮巾被有限公司 Yarn-dyed four-layer combed untwisted color strip multi-arm scarf
CN114016195A (en) * 2021-09-24 2022-02-08 山东省产品质量检验研究院 Graphene antibacterial and heat-preservation functional fabric and preparation method thereof
WO2023138707A1 (en) * 2022-01-24 2023-07-27 广东鑫球新材料科技有限公司 Fully degradable composite filament, and manufacturing method therefor and use thereof

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Application publication date: 20190416