KR102495304B1 - Mixed spun yarn comprising antibacterial extract and manufacturing method thereof - Google Patents

Abstract

The present invention relates to blended spun yarn including an antibacterial extract and a method for manufacturing the same. The blended spun yarn of the present invention includes both wool and polyester and has excellent air permeability and durability, and includes an antibacterial composition to maintain antibacterial properties even when a fabric is damaged. The present invention includes: a preparation step; a soaking step; a heating step; a step of soaking in an ethanol extract; a step of manufacturing blended spun yarn; and impregnating in a mixed aqueous solution.

Description

Mixed spun yarn comprising antibacterial extract and manufacturing method thereof}

The present invention relates to a mixed spun yarn containing an antibacterial extract and a manufacturing method thereof.

Wool and polyester are examples of the most commonly used fibers for sportswear. Wool is a natural animal fiber made from sheep's wool, and has low thermal conductivity and high air content between fibers. Polyester fibers have excellent elasticity, hardly generate wrinkles, and have a cool touch.

Wool is more breathable than polyester. Although the weave of polyester can be adjusted to increase breathability, wool has excellent breathability if the same density and same weight are used. On the other hand, polyester has excellent durability and wool is relatively less durable. However, wool is widely used as a material for sports socks because the deodorizing effect of wool is superior to that of polyester. In terms of water absorption, wool has a whopping 5 times water absorption capacity compared to polyester. Wool can absorb up to 35% of its weight in moisture.

As such, wool and polyester have distinct advantages and disadvantages, and there is a limit in that their use is limited depending on the purpose. In order to solve the above problems, clothes have been produced by blending wool and polyester fibers, but clothes manufactured by simple blending with conventional polyester fibers do not effectively alleviate the shrinkage property, and only the hygroscopicity is still It absorbs sweat because it is strong, but it does not release it, so there was a disadvantage that it could not maintain comfort.

Korean Patent Registration No. 10-2262770 has produced a blended yarn using wool and polyester, but there is no mention of water repellency and other performance, so there is a limit to overcoming the limitations of the conventional blended yarn.

Accordingly, the inventors of the present invention completed the invention by developing a blended spun yarn with excellent functionality for use in sportswear, underwear and other clothing by imparting water repellent and other performance and processing natural extracts.

Patent Registration Publication KR10-2262770B1

In order to solve the above problems

One embodiment of the present invention

(1) preparing the wool top and polyester fiber;

(2) adding 10 to 20 parts by weight of purified water to the wool top and soaking for 24 hours;

(3) heating the finished wool top at 70 to 110° C. for 2 to 4 hours;

(4) treating the pretreated wool top with an extract of one or more natural substances selected from the group consisting of rosemary, lavender, pine nut, chamomile, hibiscus, eucalyptus, peppermint, jasmine, propolis, and combinations thereof;

(5) preparing a mixed spun yarn by spinning 45 to 55% by weight of the product of step (4) and 45 to 55% by weight of the polyester fiber using a phyllofil technique; and

(6) A method for producing mixed spun yarn, comprising the step of impregnating the mixed spun yarn of step (5) in a mixed aqueous solution containing a water repellent agent and a penetrating agent.

In order to solve the above problems

Another embodiment of the present invention

It is a mixed spun yarn manufactured by the above manufacturing method.

One embodiment of the present invention for achieving the above object

(1) preparing the wool top and polyester fiber;

(2) adding 10 to 20 parts by weight of purified water to the wool top and soaking for 24 hours;

(3) heating the finished wool top at 70 to 110° C. for 2 to 4 hours;

(4) treating the pretreated wool top with an extract of one or more natural substances selected from the group consisting of lavender, pine tree, chamomile, hibiscus, eucalyptus, peppermint, jasmine, propolis, and combinations thereof;

(5) preparing a mixed spun yarn by spinning 45 to 55% by weight of the product of step (4) and 45 to 55% by weight of the polyester fiber using a phyllofil technique; and

(6) It provides a method for producing mixed spun yarn, including the step of impregnating the mixed spun yarn of step (5) in a mixed aqueous solution containing a water repellent agent and a penetrating agent.

Hereinafter, the present invention will be described in detail below.

Step (1) is a step of preparing a wool saw and polyester fibers. This step is a step of preparing a fiber material for producing a blended spun yarn. The step of preparing the wool saw and the polyester fiber may be to prepare the wool saw and the polyester fiber having an average diameter of 1 to 4 denier made of wool yarn having an average diameter of 20 to 22 μm.

At this time, if the diameter of the wool yarn constituting the wool top is less than 20 μm, the strength of the wool yarn constituting the wool top may be reduced, and if it exceeds 22 μm, the shrinkage of the wool top is strong, so that the mixture prepared according to the embodiment of the present invention The washing stability of the spun yarn may decrease.

The polyester fiber may be a polyethylene terephthalate (Poly Ethylene Terephthalate, PET) fiber.

If the thickness of the polyester fiber is less than 1 denier, the strength of the polyester fiber may be reduced, and if it exceeds 4 denier, the thickness of the polyester fiber is thicker than that of wool, making it difficult to spin uniformly with wool. There may be difficulties in the manufacture of blended yarns.

Preferably, the polyester fiber in the fiber preparation step may be a COOLMAX (E.I. DuPont) fiber having a thickness of 1 to 4 denier.

Preferably, the fiber preparation step may be to prepare a wool saw having a yarn diameter of 21 μm and a Coolmax fiber having a thickness of 2 denier.

If the Coolmax fiber is prepared as polyester fiber in the fiber preparation step, the mixed spun yarn manufactured according to the embodiment of the present invention can absorb and release sweat more smoothly together with the wool, so that the mixed spun yarn manufactured according to the embodiment of the present invention It is possible to maximize the sweat perspiration and quick-drying properties of clothes made of spun yarn.

The step (2) is a step of soaking for 24 hours by adding 10 to 20 parts by weight of purified water to the wool saw, and the step (3) is to heat the wool saw after the soaking process at 70 to 110 ° C. for 2 to 4 hours As a step, it is a step to prepare the wool top for easy post-processing. After step (3), a step of immersing the wool top in a nonionic surfactant may be further included to remove foreign substances from the wool. Non-limiting examples of the nonionic surfactant may be polysorbate 60, PEG-60, octyldodeceth-16, and ceteareth-6olivate.

Step (4) is a step of treating the pretreated wool top with an extract of one or more natural substances selected from the group consisting of rosemary, lavender, pine nut, chamomile, hibiscus, eucalyptus, peppermint, jasmine, propolis, and combinations thereof. This is a step in which the pre-treated and washed wool top is treated with natural extracts to impart antibacterial properties.

Looking in detail at the material of the extract

Rosemary ( Rosmarinus officinalis ) of the present invention is a perennial plant with needle-like leaves and belongs to the same family as mint. It is a herb native to the Mediterranean coast and has green leaves and a unique scent. The name rosemary comes from the Latin word 'rosmarinus', meaning 'dew of the sea'. Flowers bloom in winter and spring, and colors include white, pink, purple, and blue.

Lavender ( lavendula ) of the present invention is a plant belonging to the Lavandula genus, and is native to the Mediterranean coast. The height is 30 ~ 60cm, and it grows up to 90cm if well cultivated in the garden. There are white hairs all over, and the stem is a dull square, clumped together, and branched a lot at the bottom. Leaves are turned or opposite, lancet-shaped, 4 cm long and 4-6 mm wide. There is no petiole, and the leaves have fine hairs.

The pine tree ( Pinus koraiensis ) of the present invention is an evergreen evergreen even in winter, and the height of the tree grows to more than 30m and the diameter of the chest also grows to more than 1m. The bark peels off in a dark brown color, and it is common for the stem to split in a Y shape at a height of 5 to 8 m. Leaves are needle-shaped, 5 in total, 7-12 cm long. There are fine teeth on the edge.

The chamomile of the present invention refers to German chamomile ( Matricaria chamomilla ), chamomile ( Chamaemelum nobile ) and the like belonging to the Asteraceae family. It grows well in sunny places and is resistant to cold. The flower blooms during the day and closes at night, and usually blooms for about a week. Seeding is very easy and you can get the seeds yourself because they sprout well. It blooms well in sunny, well-drained sandy soil.

Hibiscus of the present invention is one of the genus of angiosperms belonging to Malvaceae. Leaves are egg-shaped to lanceolate, sometimes serrated at the periphery. The flowers are large, trumpet-shaped, with five or more petals, and range in color from white to pink, red, orange, peach, yellow, and purple, and are 4 to 18 centimeters wide.

Eucalyptus ( Eucalyptus globulus , or Tasmanian bluegum ) of the present invention is an evergreen tree of the Myrtle family, which is one of the most widely cultivated trees in Australia. It usually grows to a height of 30-55 m (98-180 ft). The leaves are 30cm long, lanceolate, leathery, covered with white powder, and have a scent. Cream-colored flowers bloom from March to November, and the fruit is hemispherical. The flower has many stamens, which extend out of the flower, and there is a well-developed stipule at the bottom of the calyx tube.

Peppermint ( Mentha piperita ) of the present invention is a hybrid between watermint and spearmint belonging to the genus Mint. Peppermint is one of the representative herb plants and is a perennial plant with a rhizome. It grows up to 30 ~ 90 cm, and the cross section of the stem is square and smooth. The fibrous fleshy stem roots spread widely. The leaves are 4 to 9 cm long and 1.5 to 4 cm wide, oval, dark green in color. The leaf edges are serrated. The surface of the leaves and stems have sparse fine hairs. Flowers are purple with 6 to 8 mm long flowers in clusters from mid-summer to late summer.

Jasmine (Jasminum ) of the present invention is a genus of Oleaceae. The main component of the fragrance is methyl jasmonate. Jasmine flowers contain several fragrant components, but among them, cis-jasmone, the only fragrant component that represents the nature of jasmine fragrance, has not yet been established for industrial production, and the only method is to extract and refine it from natural flowers. For this reason, spices with cis-jasmone as the main ingredient are very expensive.

Propolis of the present invention is one of the by-products of beekeeping produced by bees, and is a mixture of resins collected by bees from plants such as tree buds or sap. Unlike honey or royal jelly, which are other substances that can be collected from bees, the amount that can be collected is very small, and it is a valuable product that cannot be artificially increased or synthesized. It has been used all over the world as a folk medicine or tonic since ancient times. . Bactericidal, antioxidant, anti-inflammatory and anti-tumor effects are known.

After step (4), a step of passing a bathtub composed of a washing tank and an antistatic tank may be further included. After the step (4), while unwinding the pretreated wool top, the residual extract is washed in the washing tank and washed in the antistatic tank where the antistatic agent is stored. The antistatic tank may contain an aqueous solution in which 5 to 15 parts by weight of an antistatic agent is added to 100 parts by weight of water for treating the wool top that has passed through the washing tank to prevent damage to wool due to static electricity between wool and polyester fibers. . At this time, if necessary, it is possible to wash the wool top that has passed through the antistatic tank once again.

Step (5) is a step of producing mixed spun yarn by spinning 45 to 55% by weight of the resultant product of step (4) and 45 to 55% by weight of the polyester fiber using a psyrofil technique.

In the spinning step, if the spinning amount of wool is less than 45% by weight, the wool content of the produced blended spun yarn is small, and heat retention and aesthetics may be deteriorated. Not only the sweat perspiration and quick-drying properties of the prepared blended yarn may be deteriorated, but also the washing stability of the prepared blended yarn may be deteriorated due to strong shrinkage due to an increase in the content of wool in the blended yarn.

In the spinning step, if the spinning amount of the polyester fiber is less than 45% by weight, the polyester content in the blended yarn is lower than that of wool, and the sweat absorption and quick-drying properties of the blended yarn may be lowered, and if it exceeds 55% by weight, the polyester fiber In comparison, the amount of wool is small, and the heat retention of the produced mixed spun yarn may be lowered.

Preferably, in the spinning step, 50% by weight of the dried wool and 50% by weight of the polyester fiber prepared in the fiber preparation step may be spun using a phyllofil technique to prepare a mixed spun yarn having a count of 55 to 65.

Step (6) is a step of impregnating the mixed spun yarn of step (5) in a mixed aqueous solution containing a water repellent and a penetrating agent. The water repellent imparts water repellency to the mixed spun yarn, and the penetrating agent helps the water repellent to uniformly penetrate the mixed spun yarn. The water repellent is OLEOPHOBOL as a fluoroalkyl-based water repellent for natural fibers, the penetrant may be isopropyl alcohol, the mixed aqueous solution contains the water repellent at a concentration of 20 to 40 g/L, It may be included at a concentration of 50 g/L. The impregnation may be carried out for a sufficient time until an appropriate pick-up rate of the water repellent agent, for example, 70% is achieved inside the mixed spun yarn.

In order to achieve the above object, in another embodiment of the present invention, the present invention provides a blended spun yarn manufactured by the above manufacturing method.

In order to achieve the above object, in another embodiment of the present invention, the present invention provides an antibacterial fabric including the blended yarn and sportswear and/or underwear including the blended yarn.

Meanwhile, the blended spun yarn of the present invention can be used in a wide variety of fabrics and textile products. At this time, the fibers of the present invention may be blended with at least one additional fiber.

The one type of additional fiber includes, for example, natural fibers, synthetic fibers, inorganic fibers, combinations and blends thereof. The fiber may be of any denier; may be multi- or mono-filament; may be false twisted or twisted; multi-denier filaments may be incorporated into single-twist yarns through twisting and/or melting; For example, it may be a multicomponent fiber exhibiting any type of cross section, including sheath/core configuration, parallel configuration, pie wedge configuration, segmented ribbon configuration, segmented crisscross configuration, tip trilobal configuration, and conjugate configuration.

Natural fibers suitable for use in the present invention may include, for example, silk, cotton, wool, flax, fur, hair, cellulose, ephedra, hemp, linen, wood pulp, and combinations thereof.

Synthetic fibers suitable for use in the present invention include, for example, polyolefins such as polyethylene, polypropylene and polybutylene; halogenated polymers such as polyvinyl chloride; Poly-p-phenyleneteraphthalamide (eg Kevlar® fibers available from DuPont), poly-m-phenyleneteraphthalamide (eg Nomex® fibers available from DuPont) polyaramids such as; melamine and melamine derivatives (eg, Basofil® fibers available from Basofil Fibers, LLC); polyesters such as polyethylene terephthalate and polyester/polyether; polyamides such as nylon 6 and nylon 6,6; polyurethanes such as Tecophilic® aliphatic thermoplastic polyurethanes available from Noveon; acetates; rayon acrylics; and combinations thereof.

Inorganic fibers suitable for use in the present invention may include, for example, glass fibers, boron fibers and rock wool.

In one embodiment of the present invention, the fabric comprises 100% by weight of the fibers or multicomponent fibers of the present invention; or < 75% by weight; or ≤ 50% by weight; or ≤ 40% by weight; or ≤ 30% by weight; or ≤ 20% by weight; or ≤ 10% by weight; or ≤ 5% by weight. In some aspects of these embodiments, the at least one additional fiber can include cotton, wool, polyester, acrylic, nylon, silk, and combinations and blends thereof.

In some embodiments of the present invention, a textile product comprising the fabric of the present invention is provided. In some aspects of some of these embodiments, the textile product is a garment, upholstery, upholstery, carpet, padding, lining, wallpaper, roofing product, house wrap, insulation, bedding, wipes ( wiping cloth, towels, gloves, rugs, floor mats, drapery, napery, bar runners, textile bags, awnings, vehicle upholstery, boat upholstery, tents , agricultural upholstery, geotextiles, automotive headliners, filters, envelopes, tags, labels, diapers, feminine hygiene products (e.g. sanitary napkins, tampons), laundry aids (e.g. textile dryer-sheets), professional wound care products for wound care and professional medical care products for pharmaceutical use (eg sterile wraps, caps, gowns, masks, draping). .

Examples of textile products using the mixed spun yarn of the present invention include absorbent articles such as diapers, napkins, and incontinence pads; medical hygiene products such as gowns and scrubs; Indoor interior materials such as wallpaper, Japanese-style shoji paper, and flooring; life-related materials such as cloth for covers and covers for garbage containers; toilet-related products such as disposable toilet articles and toilet seat covers; pet articles such as pet sheets, pet diapers, and pet towels; general medical supplies; bedding material; filter material; It can be used in various ways in textile products that require various hydrophilicity and water permeability, such as nursing care products.

The mixed spun yarn of the present invention includes both wool and polyester, so it has excellent air permeability and durability, and can maintain antibacterial properties even when the fabric is damaged by including an antibacterial composition.

On the other hand, the effects obtainable in the present invention are not limited to the effects mentioned above, and other effects not mentioned will be clearly understood by those skilled in the art from the description below. You will be able to.

Hereinafter, embodiments of the present invention will be described in more detail. Embodiments of the present invention may be modified in various forms, and the scope of the present invention should not be construed as being limited to the following examples. This embodiment is provided to more completely explain the present invention to those skilled in the art.

Example 1. Manufacturing method of mixed spun yarn containing wool and polyester

Wool saws with an average yarn diameter of 21 μm and polyester fibers with a thickness of 2 denier were prepared. The prepared wool top was left at room temperature for 24 hours by adding purified water 15 times the weight of the wool top. After that, the left wool top was heated at 90 ° C. for 3 hours.

The wool top after the above process was immersed in hot water of 80 ° C. or higher containing a nonionic surfactant and maintained for 30 minutes.

On the other hand, after mixing rosemary, lavender, pine nut, and chamomile in a weight ratio of 1: 1: 2: 2, reflux extraction was performed for 4 hours using ethanol having a mass concentration of 75% at 90 ° C, and then concentrated under reduced pressure to prepare an extract. .

The natural product-derived extract was immersed in the washed wool top at 20 to 25 ° C. for 6 to 12 hours to deposit the natural product-derived extract on the hemp and wool top.

The precipitated wool saw was unwinded to pass through a bath consisting of a washing tank and an antistatic tank at a rate of 10 m per minute to clean the wool saw, and then to obtain wool by winding.

The obtained wool was hot air dried at 90° C. for 120 minutes. 50% by weight of the obtained wool and 50% by weight of polyester fiber were spun using a psyrofil technique to prepare a mixed spun yarn.

The prepared mixed spun yarn was impregnated in a mixed aqueous solution containing a water repellent (OLEOPHOBOL) and isopropyl alcohol. A mixed aqueous solution was prepared to include a water repellent at a concentration of 30 g/L and isopropyl alcohol at a concentration of 40 g/L.

The impregnated blended spun yarn was padded at a pick-up rate of 70%, dried at 100°C, and cured at 140°C for 2 minutes to complete.

Example 2. Washing durability test

In order to check whether the water-repellent layer of the fabric made of the mixed spun yarn of Example 1 is not damaged even after washing several times, ISO 6330 was applied and washed 5 times, and then the KSK-0590: 2008 spray method was used to determine the water repellency. was measured. As a result of the measurement, it was confirmed that the water repellency of the fabric made of the mixed spun yarn of Example 1 was maintained at Grade 4.

In addition, it was confirmed that all of the test conditions specified in KSK 0430 for discoloration and discoloration of fabric during washing, AATCC 61 for water washing, and AATCC 132 for dry cleaning were satisfied.

Example 3. Antibacterial effect confirmation test

The fabric of Example 1 is primarily water-repellent, making it difficult for bacteria to proliferate, and even if the water-repellent coating layer is damaged and the fabric is contaminated, even if conditions are met for bacteria to proliferate, the fabric used in the fabric itself It is characterized in that it has antibacterial properties and can suppress the growth of mold and bacteria.

In order to confirm this, KSK-0693:2011 was applied to confirm antibacterial properties. Specifically, the fabric of Example 1 sterilized at 121 ° C in a high-temperature and high-pressure sterilizer (autoclave), Comparative Example 1 in which the surface of the fabric of Example 1 was artificially scratched to damage the coating layer, and standard wool treated with simple water repellency For Comparative Example 2 in which the cells were artificially damaged, 1 x 10 ⁷ of Staphylococcus aureus and Escherichia coli to be measured were inoculated and cultured for 20 hours, then standard Compared to wool fabric, the reduction rate of bacteriostasis was measured in % and shown in Table 1 below.

division S. aureus (%) E. coli (%) Example 1 100 (uncultivable) 100 (uncultivable) Comparative Example 1 100 (uncultivable) 100 (uncultivable) Comparative Example 2 57 43

As shown in Table 1, the fabrics of Example 1 and Comparative Example 1 of the present invention not only have excellent antibacterial properties themselves, but also have antibacterial properties even if the coating layer is damaged, effectively inhibiting the growth of bacteria. Confirmed. On the other hand, considering the results of Comparative Example 2, since the coating layer penetrates between the damaged coating layers and sufficient bacterial growth is possible, the fabric manufactured by weaving the antibacterial fiber of the present invention into fabric has high durability during long-term use or daily use. seems to be

The above detailed description is illustrative of the present invention. In addition, the foregoing is intended to illustrate and describe preferred embodiments of the present invention, and the present invention can be used in various other combinations, modifications, and environments. That is, changes or modifications are possible within the scope of the concept of the invention disclosed in this specification, within the scope equivalent to the written disclosure and / or within the scope of skill or knowledge in the art. The written embodiment describes the best state for implementing the technical idea of the present invention, and various changes required in the specific application field and use of the present invention are also possible. Therefore, the above detailed description of the invention is not intended to limit the invention to the disclosed embodiments. Also, the appended claims should be construed to cover other embodiments as well.

Claims (9)

(1) preparing the wool top and polyester fiber;
(2) adding 10 to 20 parts by weight of purified water to the wool top and soaking for 24 hours;
(3) heating the finished wool top at 90° C. for 3 hours;
(4) immersing the heated wool top in an ethanol extract of a natural product at a temperature of 20 to 25° C. for 6 to 12 hours;
(5) preparing a mixed spun yarn by spinning 45 to 55% by weight of the product of step (4) and 45 to 55% by weight of the polyester fiber using a phyllofil technique; and
(6) impregnating the mixed spun yarn of step (5) with a mixed aqueous solution containing a water repellent and a penetrating agent;
The ethanol extract of the natural product was prepared by mixing rosemary, lavender, pine nut, and chamomile at a weight ratio of 1: 1: 2: 2, followed by reflux extraction at 90 ° C. for 4 hours using ethanol having a mass concentration of 75%, and then concentrated under reduced pressure. become,
The mixed aqueous solution contains a water repellent at a concentration of 30 g/L and a penetrant at a concentration of 40 g/L,
The method for producing a blended spun yarn in which the penetrant is isopropyl alcohol. The method of claim 1, wherein the step of preparing the wool saw and the polyester fiber,
A method for producing a blended spun yarn comprising preparing a polyester fiber having an average diameter of 1 to 4 denier and the wool top made of wool yarn having an average diameter of 20 to 22 μm. The method according to claim 1, further comprising the step of immersing the wool top in a nonionic surfactant after step (3). The method for producing mixed spun yarn according to claim 1, further comprising passing a bath consisting of a washing tank and an antistatic tank after step (4). delete A blended spun yarn produced by the manufacturing method of any one of claims 1 to 4. Antibacterial fabric comprising the blended spun yarn of claim 6. Sportswear comprising the blended yarn of claim 6. Underwear comprising the blended yarn of claim 6.