CN106063659A - A kind of production technology of copper ion antibacterial and deodouring fiber raschel blanket - Google Patents
A kind of production technology of copper ion antibacterial and deodouring fiber raschel blanket Download PDFInfo
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- CN106063659A CN106063659A CN201610392091.7A CN201610392091A CN106063659A CN 106063659 A CN106063659 A CN 106063659A CN 201610392091 A CN201610392091 A CN 201610392091A CN 106063659 A CN106063659 A CN 106063659A
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- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47G—HOUSEHOLD OR TABLE EQUIPMENT
- A47G9/00—Bed-covers; Counterpanes; Travelling rugs; Sleeping rugs; Sleeping bags; Pillows
- A47G9/02—Bed linen; Blankets; Counterpanes
- A47G9/0207—Blankets; Duvets
- A47G9/0223—Blankets
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- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04B—KNITTING
- D04B21/00—Warp knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
- D04B21/02—Pile fabrics or articles having similar surface features
- D04B21/04—Pile fabrics or articles having similar surface features characterised by thread material
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B3/00—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating
- D06B3/10—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fabrics
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- D06C—FINISHING, DRESSING, TENTERING OR STRETCHING TEXTILE FABRICS
- D06C11/00—Teasing, napping or otherwise roughening or raising pile of textile fabrics
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- D06C—FINISHING, DRESSING, TENTERING OR STRETCHING TEXTILE FABRICS
- D06C13/00—Shearing, clipping or cropping surfaces of textile fabrics; Pile cutting; Trimming seamed edges
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- D06C—FINISHING, DRESSING, TENTERING OR STRETCHING TEXTILE FABRICS
- D06C15/00—Calendering, pressing, ironing, glossing or glazing textile fabrics
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- D06C7/02—Setting
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- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/51—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof
- D06M11/55—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof with sulfur trioxide; with sulfuric acid or thiosulfuric acid or their salts
- D06M11/56—Sulfates or thiosulfates other than of elements of Groups 3 or 13 of the Periodic System
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- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/73—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof
- D06M11/76—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon oxides or carbonates
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- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
- D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
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- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
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- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
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- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
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- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
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- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/16—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dispersed, e.g. acetate, dyestuffs
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- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/82—Textiles which contain different kinds of fibres
- D06P3/8204—Textiles which contain different kinds of fibres fibres of different chemical nature
- D06P3/8295—Textiles which contain different kinds of fibres fibres of different chemical nature mixtures of fibres containing nitrile and ester groups
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- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/02—After-treatment
- D06P5/04—After-treatment with organic compounds
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- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
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- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/18—Synthetic fibres consisting of macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/26—Polymers or copolymers of unsaturated carboxylic acids or derivatives thereof
- D06M2101/28—Acrylonitrile; Methacrylonitrile
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- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/32—Polyesters
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- D10B2101/00—Inorganic fibres
- D10B2101/20—Metallic fibres
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- D10B2201/00—Cellulose-based fibres, e.g. vegetable fibres
- D10B2201/20—Cellulose-derived artificial fibres
- D10B2201/22—Cellulose-derived artificial fibres made from cellulose solutions
- D10B2201/24—Viscose
Abstract
The present invention relates to the production technology of a kind of copper ion antibacterial and deodouring fiber raschel blanket, comprise the following steps: 1) yarn selection 2) braiding 3) kiering 4) printing and dyeing 5) reduction cleaning 6) Final finishing.The copper ion fiber that the present invention uses, by producing with acrylic fiber graft copolymerization, therefore copper content is high, functional persistently, and can excrete through metabolism with the copper of contact skin.Therefore, can eliminate or weaken the harm that microorganism brings in every respect, make living environment more clean, more comfortable, safer, will not only have preferable economic benefit, and there is social benefit widely.
Description
Technical field
The present invention relates to functional Rachael blanket production technical field, especially relate to a kind of elimination or weaken microorganism respectively
The harm that aspect brings, makes living environment more clean, more comfortable, safer copper ion antibacterial and deodouring fiber raschel
The production technology of woollen blanket.
Background technology
Making a general survey of the development trend of domestic and international textile, functional high-tech textile has become as the main flow of market development.People
Textile is not required nothing more than attractive in appearance, and focus on comfortableness and functional.Therefore, functional textile becomes textile industry future
One of developing trend, will collectively form with fine count fiber textile, non-woven fabrics, composite, ep-type material etc. and spin future
The big tendency of fabric.
Blanket series products is great to China's export market significance, as a example by 2010, and 80% outlet of China's blanket class yield
Overseas market.From the point of view of woollen blanket raw materials for production, synthetic fibers blanket accounting is maximum, and close to 90%, its raw material with acrylon is then
Main.Woollen blanket type is still based on warp knit Rachael blanket.
Along with the lifting of living standard, consumer proposes more polyfunctional requirement to woollen blanket: as at thermal insulation
While, also there is antibacterial, antistatic, be prone to maintenance, the most certain health-care effect.Fluffy along with differentiation fiber
The exhibition of breaking out, functional fiber application on the textile also gets more and more.
Home textile articles for use on bed, particularly bedding class, blanket class are longer with direct skin contact and retention time, simultaneously
Cleaning frequency is low, use and storage condition is prone to breed bacteria;And pass through Final finishing or add antibacterial microgranule in the fibre
Realize its functional functional textile, there may be function persistency or the risk of healthy and safe aspect.Therefore,
By the copper ion fiber produced with acrylic fiber graft copolymerization, copper content may be up to 5%, when in copper ion fiber, band is being just
When the trace copper contacted with ions of electric charge is to electronegative microbial cell film, the permeates cell membranes by gravitation, causes microorganism
Death, thus there is strongly lasting antibacterial bacteriostatic, elimination odor function.Additionally, copper ions fabric connects with skin
Physical action can be produced time tactile, stimulate the growth of collagen protein in skin.The use of copper ion fiber is the most comparatively safe
Absorbed to internal copper ion through human body skin by perspiration, can be got rid of by the eubolism of human body external.
By platinum fiber is applied to underwear fabric, it is achieved have the functional fabric of antithrombotic, antibacterial functions,
Involved platinum fiber is based on cellulose fibre, new type functional fiber containing ultramicron (paint little a beautiful gem,
The exploitation application of the knitting fabric of platinum fiber).Utilize silver-plated long filament and polyester filament be interleaved making have antibiotic property,
The blanket class (Huang Lei, the exploitation of silver tapetum fibrosum based article fabric and research) of antistatic behaviour.But silver ion is applied at fiber
Aspect, although be widely used, but expensive;On the other hand silver ion can not be at human body intracellular metabolic.
The preparation method of a kind of refining jute fiber antiseptic printed woolen blanket (application number:
CN201410513515.1), it is provided that tossa and cotton fiber blending are obtained the printed woolen blanket with anti-microbial property;
Medical stone fibre Rachael blanket (application number: CN201110338080.8) utilizes Maifanitum blending health yarn to make product,
There is health care and antibacterial action, but equally exist the disengaging problem of functional particles;Chitin fiber is spun into plush yarn and makes and draw
She Er woollen blanket (application number: CN201320322304.0), has excellent anti-microbial property;There is excellent anti-microbial property;
Utilize coffee carbon fiber (application number: CN201510103169.4) that antibacterial dust is carried out dust adsorption, or pass through coffee
Carbon modified dacron develops antimicrobial form weft knitting mattress fabric, and fabric has superior physical and mechanical properties, anti-microbial property and leads
Wet performance (Xu Qiao, the exploitation of antimicrobial form weft knitting mattress fabric and performance study) realizes anti-microbial property, etc..Utilize nanometer
Complex antimicrobials makes an addition in dry acrylic fiber fiber, develops nano-antibacterial dry acrylic fiber fiber and antibacterial Rachael blanket.
Woollen blanket is outside adding anti-bacterial anti-foul function, and physical and mechanical properties is also not affected by affecting (Zhu's equality, nano-antibacterial dry method nitrile
Synthetic fibre fiber and the development of antibacterial Rachael blanket), but the safety about nanoparticle is the most not yet come to a conclusion, microgranule by
The lowest it is therefore possible to enter human body by skin in size, health is threatened.
Summary of the invention
It is an object of the invention to provide the production technology of a kind of copper ion antibacterial and deodouring fiber raschel blanket, environmental protection, product
Gentlier, more warming, ventilative, there is the most wide market prospect.
To achieve these goals, the present invention is by the following technical solutions:
The production technology of a kind of copper ion antibacterial and deodouring fiber raschel blanket, comprises the following steps:
1) yarn selects: using copper ion fiber-viscose rayon as plush yarn, using polyester drawn yarns as wire gauze;
2) braiding: use double rib warp loom that plush yarn and wire gauze are woven, obtain copper ion fiber raschel blanket;
3) kiering: by step 2) in woollen blanket be placed in kiering liquid and carry out kiering;
4) printing and dyeing: by the regulation of dyeing liquor pH value to after 5.8-6.8 to step 3) in woollen blanket print and dye;
5) reduction cleaning: the copper ion fiber raschel blanket after uniformly dyeing is carried out reduction cleaning with reduction cleaning liquid, with in acetic acid and water
Cylinder is gone out after washing;
6) Final finishing: the copper ion antibacterial and deodouring fiber raschel blanket after reduction cleaning is carried out successively drying and shaping, front hot light,
Front bristle, front scald cut, hair is scalded at back side fluffing, back side bristle, the back side, the back side grab cut, multiple sizing, front boiling hot are cut, carry on the back
Face scald cut, cutting i.e. obtains copper ion Rachael blanket finished product after sewing up, finally will put in storage after packaging after product inspection.
In the technical program, in the present invention, front hot light uses secondary hot light, makes front fluffy, the easy plucking of reverse side;Front
The bristle degree of depth should be grasped, it is impossible to touch base fabric, it is ensured that Muscovitum cool fiber plush yarn is combed into list when bristle, back side bristle
Fiber condition, and comb suitable;The back side is grabbed and is used machine on inverse hair when cutting, it should be ensured that had one's hair trimmed by fine hair;Cutting notes when sewing up should be by
The limit of woollen blanket both sides cuts over-and-over whip suture again.
The copper ion fiber that the present invention uses, by producing with acrylic fiber graft copolymerization, therefore copper content is high, function
Property lasting, and can excrete through metabolism with the copper of contact skin.Therefore, can eliminate or weaken microorganism in every respect
The harm brought, makes living environment more clean, more comfortable, safer, will not only have preferable economic benefit, and
And there is social benefit widely.
Copper ion fiber is the modified fibre of research and development on acrylic based fiber, except having the substantially special of acrylic fiber
Beyond point and antibacterial functions, because of grafting organic brass chain and high hydrophilic group on its side chain, the fibre property is made to have had necessarily
Change.Both compare, and the fracture strength of copper ion fiber is relatively low, and its initial modulus is the most significant lower, and therefore feel is the most more
Add softness.In addition fibre uniformity is good, free from foreign meter, therefore it should be noted that light comb is beaten, slowly to reduce fibre damage.Copper from
The regain of subbundle is far longer than common acrylic fiber, close to cotton fiber, illustrates that moisture pick-up properties is better than common acrylon fine
Dimension.Its mass specific resistance is big, easily produces electrostatic, in spinning process, needs to take pre-humidifying to process in preceding working procedure.
For improving electrostatic phenomenon, by copper ion fiber and viscose fiber blending, reduce manufacturing cost.
As preferably, the specification of doughnut is 150D/140F-180D/150F, and the specification of polyester drawn yarns is 150D/144F.
As preferably, in step (2), the technological parameter of braiding is: on the double rib warp loom that model is E2291A, front
Rear needle-bar spaces for 12-14mm, and with 1, No. 6 sley bars, front and back, needle-bar weaves 4 pin inlaid thread tissues, 2, No. 5 combs respectively respectively
Comb is respectively in needle-bar braiding pillar stitch of front and back, and 3, No. 4 sley bars weave lint respectively at forward and backward needle-bar, and braiding speed is
360-440r/min。
As preferably, step 4) printing and dyeing time, dyeing liquor pH acetic acid regulates, dye bath ratio 1:15-17, dyeing temperature
For 140-155 DEG C, dyeing time is 45-55min, and the concrete formula of dyeing liquor is: Lonsperse EE series disperse dyes
0.95-1.3g/L, anthocyanidin 2.2-2.8g/L, auxiliary agent 3-4g/L, high temperature dispersant 2.3-3.6g/L and high temperature levelling agent 0.5-1g/L,
Described auxiliary agent is that the sodium carbonate of 1:1:2, sodium hydrosulfite form with nano titanium oxide by mass ratio.
As preferably, step 5) in, reduction cleaning liquid include the detergent of 3.5-4g/L, the surfactant of 1.5-2.5g/L,
22-25g/L sodium alginate and the tea saponin of 10-15g/L, bath raio 1:20, temperature 50-55 DEG C, scavenging period 60-75min.
As preferably, controlling bath raio 1:30 during kiering, kiering temperature is 90-100 DEG C, kiering time 40-60min, kiering
The formula of liquid is: sodium silicate 0.3-0.5g/L, sodium carbonate 1-3g/L, Matrii Sulfas Exsiccatus 2-5g/L, penetrating agent JFC 0.5-1g/L, poly-second
Glycol octyl phenyl ether 4-5g/L, glyceryl triacetate 0.2-0.8g/L, Folium Menthae extract 2.5-5g/L, propolis extract 5-10g/L.
In the technical program, the present invention is optimized design to the formula of kiering liquid, wherein sodium carbonate can demineralized water, simultaneously can
Improve kiering effect;Impurity in sodium silicate adsorbable kiering liquid and impurity analyte;Matrii Sulfas Exsiccatus can effectively prevent in kiering liquid
The impurity adsorbed by sodium silicate and impurity analyte are redeposited on woollen blanket, also can improve woollen blanket in follow-up dyeing process simultaneously
Dye uniformity and dyefastness;Triton X-100 is nonionic surfactant, has good scourability;
Sodium silicate is easily generated silicon dirt, causes fabric feeling coarse, easily abrades fiber, and glyceryl triacetate has excellent chelating dispersion
Performance, can eliminate silicon dirt, be effectively improved feel and the capillary effect of woollen blanket, and glyceryl triacetate also has excellent surface activity simultaneously;
Penetrating agent JFC has well moistening osmosis and cooperative effect, by penetrating agent JFC, Triton X-100 with
Synergism between glyceryl triacetate, can be greatly improved moistening, the emulsifying of kiering liquid, clean effect;The present invention is by right
Kiering liquid and the optimization of boiling parameter, it is ensured that the most fully remove the various dirt of carpeted surface, the most guaranteed woollen blanket
Strength and outward appearance are unaffected.
Folium Menthae extract has bactericidal action, has good insect protected effect, is possible to prevent growing of acarid.
Propolis be the secretions such as worker honeybees foraging activity longevity glue source propolis with its secretions such as mandibular gland, wax gland be mixed to form one
Kind with the adhesivity material of soft fragrance, be Apis for repair lair and interior environment disinfection with protection resist pest and disease damage and
A kind of particular matter of pathogenic microorganism invasion lair, is natural antibiotics, and it has strong broad-spectrum antiseptic, antioxidant activity.
As preferably, the preparation method of Folium Menthae extract is: takes 35-65 DEG C of oven drying of Herba Menthae herb, is dried to constant weight
Pulverize, the amount needed for weighing accordingly, and press the material ratio of 1:10-30, add distilled water reflux, extract, 1-5 time, filter;Merge filter
Liquid, concentrating under reduced pressure, and use 90% ethanol concentrating rear 3 times of quality to stand overnight, obtain precipitate;After 2-3 water extract-alcohol precipitation,
Precipitation absolute ethanol washing, and use Vacuum Freezing & Drying Technology to obtain Folium Menthae extract.
As preferably, propolis extract uses following steps to prepare: after propolis raw material freezing being smashed, use supercritical titanium dioxide
Carbon extracts, and extraction tower pressure is 20-25MPa, and extraction temperature is 65-75 DEG C, extraction time 1-2h, and entrainer is that extraction tower enters
The ethanol solution that volumetric concentration is 95% of the 20-25% of material weight, knockout tower pressure 10-15MPa, separation temperature 55-65 DEG C,
Propolis extract is obtained from knockout tower discharging.
As preferably, step 6) in, drying and shaping uses JZR type tentering heat setting machine to carry out, and setting speed is
22-24m/min, design temperature is 180-190 DEG C;Front hot light uses SME473H type list roller secondary natural lustre finishing machine to carry out, hot light
Temperature is 180-190 DEG C, cloth speed 15-17m/min, twice of suitable hair, twice of inverse hair;Front bristle uses the double rod of MB211E type
Brushing machine is carried out, speed 4-5m/min;Front is scalded and is cut employing MB322H type high-speed and high-efficiency and scald shearing machine and carry out, and temperature is 180-190
DEG C, speed is 10-14m/min;Back side fluffing uses MB311E type raising machine to carry out, and fluffing 4 times in the back side, speed is
18-20m/min, plays gross weight 40%, and front retains 60%;Back side bristle uses the double rod brushing machine of MB211E type to carry out, single roller
Bristle, along hairbrush, speed 4-5m/min;Back side hot light uses SME473H type list roller secondary natural lustre finishing machine to carry out, hot light temperature
180-190 DEG C, 10-12m/min of hot light speed regulation, second time 12-14m/min;The back side is grabbed and is cut employing MB322E type height
Effect is scalded shearing machine and is carried out, and speed is 10-11m/min, cropping height 4-5mm;Multiple sizing uses JZR type tentering heat setting machine to carry out,
Setting temperature 160-180 DEG C, speed is 20-21m/min;Front is scalded and is cut employing MB322E type high-speed and high-efficiency and scald shearing machine and carry out,
Temperature is 180-190 DEG C, speed 10-14m/min;The back side is scalded and is cut employing MB322E type high-speed and high-efficiency and scald shearing machine and carry out, temperature
For 180-190 DEG C, speed 10-14m/min, inverse hair scalds cuts twice.
The invention has the beneficial effects as follows the copper ion fiber that the present invention uses, by producing with acrylic fiber graft copolymerization,
Therefore copper content is high, functional persistently, and can excrete through metabolism with the copper of contact skin.Therefore, can eliminate or
Weaken the harm that microorganism brings in every respect, make living environment more clean, more comfortable, safer, will not only have
Preferably economic benefit, and there is social benefit widely.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention will be further explained:
In the present invention, if not refering in particular to, all devices and raw material are all commercially available or the industry is conventional, and wherein, synthesis is clean
Lotion is purchased from seapeak Chemical Co., Ltd. of Shangyu city;Surfactant is purchased from Guangzhou Yi Cheng Chemical Co., Ltd.;In following embodiment
Method, if no special instructions, be this area conventional method.
Copper ion fiber-viscose rayon is purchased from Shanghai Zhengjia Dairy Wire Science Co., Ltd, for Kapp dragon copper ion anti-bacterial fibre.
The specification of copper ion fiber-viscose rayon is 150D/140F-180D/150F, and the specification of polyester drawn yarns is
150D/144F。
Embodiment 1
The production technology of a kind of copper ion antibacterial and deodouring fiber raschel blanket, comprises the following steps:
1) yarn selects: using copper ion fiber-viscose rayon as plush yarn, using polyester drawn yarns as wire gauze;
2) braiding: use double rib warp loom that plush yarn and wire gauze are woven, obtain copper ion antibacterial and deodouring fiber raschel blanket;
The technological parameter of braiding is: on the double rib warp loom that model is E2291A, and front and back needle-bar spaces for 12mm, respectively with 1,
Front and back, needle-bar weaves 4 pin inlaid thread tissues respectively for No. 6 sley bars, 2, No. 5 sley bars respectively in needle-bar braiding pillar stitch of front and back, 3,
No. 4 sley bars weave lint respectively at forward and backward needle-bar, and braiding speed is 360r/min;
3) kiering: by step 2) in woollen blanket be placed in kiering liquid and carry out kiering;Controlling bath raio 1:30 during kiering, kiering temperature is
90 DEG C, kiering time 40min, the formula of kiering liquid is: sodium silicate 0.3g/L, sodium carbonate 1g/L, Matrii Sulfas Exsiccatus 2g/L, infiltration
Agent JFC 0.5g/L, Triton X-100 4g/L, glyceryl triacetate 0.2g/L, Folium Menthae extract 2.5g/L, propolis
Extract 5g/L;Wherein, the preparation method of Folium Menthae extract is: takes 35 DEG C of oven dryings of Herba Menthae herb, is dried to constant weight powder
Broken, needed for weighing accordingly amount, and press the material ratio of 1:10, add distilled water reflux, extract, 1 time, filter;Merging filtrate, subtract
Pressure concentrates, and uses 90% ethanol concentrating rear 3 times of quality to stand overnight, and obtains precipitate;After 2 water extract-alcohol precipitations, precipitation is used
Absolute ethanol washing, and use Vacuum Freezing & Drying Technology to obtain Folium Menthae extract;Propolis extract uses following steps to prepare:
After propolis raw material freezing being smashed, with supercritical carbon dioxide extraction, extraction tower pressure is 20MPa, and extraction temperature is 65 DEG C,
Extraction time 1h, entrainer is the ethanol solution that volumetric concentration is 95% of the 20% of extraction tower feed weight, knockout tower pressure
10MPa, separation temperature 55 DEG C, obtain propolis extract from knockout tower discharging;
4) printing and dyeing: by the regulation of dyeing liquor pH value to after 5.8 to step 3) in woollen blanket print and dye;During printing and dyeing, dyeing liquor pH uses
Acetic acid regulates, dye bath ratio 1:15, and dyeing temperature is 140 DEG C, and dyeing time is 45min, and the concrete formula of dyeing liquor is:
Lonsperse EE series disperse dyes 0.95g/L, anthocyanidin 2.2g/L, auxiliary agent 3g/L, high temperature dispersant 2.3g/L are even with high temperature
Stain 0.5g/L, described auxiliary agent is that the sodium carbonate of 1:1:2, sodium hydrosulfite form with nano titanium oxide by mass ratio;
5) reduction cleaning: with reduction cleaning liquid, the copper ion antibacterial and deodouring fiber raschel blanket after uniformly dyeing is carried out reduction cleaning, use vinegar
Acid goes out cylinder after neutralizing washing;Reduction cleaning liquid includes the detergent of 3.5g/L, the surfactant of 1.5g/L, 22g/L alginic acid
Sodium and the tea saponin of 10g/L, bath raio 1:20, temperature 50 C, scavenging period 60min;
6) Final finishing: the copper ion antibacterial and deodouring fiber raschel blanket after reduction cleaning is carried out successively drying and shaping, front hot light,
Front bristle, front scald cut, hair is scalded at back side fluffing, back side bristle, the back side, the back side grab cut, multiple sizing, front boiling hot are cut, carry on the back
Face scald cut, cutting i.e. obtains copper ion antibacterial and deodouring fiber raschel blanket finished product after sewing up, finally will enter after packaging after product inspection
Storehouse;Drying and shaping uses JZR type tentering heat setting machine to carry out, and setting speed is 22m/min, and design temperature is 180 DEG C;Just
Face hot light uses SME473H type list roller secondary natural lustre finishing machine to carry out, and hot light temperature is 180 DEG C, cloth speed 15m/min, twice of suitable hair,
Twice of inverse hair;Front bristle uses the double rod brushing machine of MB211E type to carry out, speed 4m/min;Front is scalded and is cut employing MB322H
Type high-speed and high-efficiency scalds shearing machine to be carried out, and temperature is 180 DEG C, and speed is 10m/min;Back side fluffing uses MB311E type raising machine
Carrying out, fluffing 4 times in the back side, speed is 18m/min, plays gross weight 40%, and front retains 60%;Back side bristle uses MB211E
The double rod brushing machine of type is carried out, and single roller bristle, along hairbrush, speed 4m/min;Back side hot light uses SME473H type list roller secondary
Natural lustre finishing machine is carried out, hot light temperature 180 DEG C, 10m/min of hot light speed regulation, second time 12m/min;The back side is grabbed and is cut employing
MB322E type efficiently scalds shearing machine to be carried out, and speed is 10m/min, cropping height 4mm;Multiple sizing uses JZR type tentering heat fixed
Type machine is carried out, setting temperature 160 DEG C, and speed is 20m/min;Front is scalded and is cut employing MB322E type high-speed and high-efficiency and scald shearing machine and enter
OK, temperature is 180 DEG C, speed 10m/min;The back side is scalded and is cut employing MB322E type high-speed and high-efficiency and scald shearing machine and carry out, and temperature is
180 DEG C, speed 10m/min, inverse hair scalds cuts twice.
Embodiment 2
The production technology of a kind of copper ion antibacterial and deodouring fiber raschel blanket, comprises the following steps:
1) yarn selects: using copper ion fiber-viscose rayon as plush yarn, using polyester drawn yarns as wire gauze;
2) braiding: use double rib warp loom that plush yarn and wire gauze are woven, obtain copper ion antibacterial and deodouring fiber raschel blanket;
The technological parameter of braiding is: on the double rib warp loom that model is E2291A, and front and back needle-bar spaces for 13mm, respectively with 1,
Front and back, needle-bar weaves 4 pin inlaid thread tissues respectively for No. 6 sley bars, 2, No. 5 sley bars respectively in needle-bar braiding pillar stitch of front and back, 3,
No. 4 sley bars weave lint respectively at forward and backward needle-bar, and braiding speed is 380r/min;
3) kiering: by step 2) in woollen blanket be placed in kiering liquid and carry out kiering;Controlling bath raio 1:30 during kiering, kiering temperature is
95 DEG C, kiering time 50min, the formula of kiering liquid is: sodium silicate 0.4g/L, sodium carbonate 2g/L, Matrii Sulfas Exsiccatus 3g/L, infiltration
Agent JFC 0.7g/L, Triton X-100 4.2g/L, glyceryl triacetate 0.6g/L, Folium Menthae extract 3.9g/L, honeybee
Glue extract 7.6g/L;Wherein, the preparation method of Folium Menthae extract is: takes 45 DEG C of oven dryings of Herba Menthae herb, is dried to constant weight
Rear pulverizing, the amount needed for weighing accordingly, and press the material ratio of 1:20, add distilled water reflux, extract, 3 times, filter;Merging filtrate,
Concentrating under reduced pressure, and use 90% ethanol concentrating rear 3 times of quality to stand overnight, obtain precipitate;After 3 water extract-alcohol precipitations, precipitation
With absolute ethanol washing, and Vacuum Freezing & Drying Technology is used to obtain Folium Menthae extract;Propolis extract uses following steps to prepare:
After propolis raw material freezing being smashed, with supercritical carbon dioxide extraction, extraction tower pressure is 22MPa, and extraction temperature is 65-75
DEG C, extraction time 1.5h, entrainer is the ethanol solution that volumetric concentration is 95% of the 23% of extraction tower feed weight, knockout tower
Pressure 12MPa, separation temperature 60 DEG C, obtain propolis extract from knockout tower discharging;
4) printing and dyeing: by the regulation of dyeing liquor pH value to after 6.2 to step 3) in woollen blanket print and dye;During printing and dyeing, dyeing liquor pH uses
Acetic acid regulates, and dye bath ratio 1:15-17, dyeing temperature is 145 DEG C, and dyeing time is 50min, the concrete formula of dyeing liquor
For: Lonsperse EE series disperse dyes 1g/L, anthocyanidin 2.5g/L, auxiliary agent 3.5g/L, high temperature dispersant 2.8g/L are with high
Temperature levelling agent 0.7g/L, described auxiliary agent is that the sodium carbonate of 1:1:2, sodium hydrosulfite form with nano titanium oxide by mass ratio;
5) reduction cleaning: with reduction cleaning liquid, the copper ion antibacterial and deodouring fiber raschel blanket after uniformly dyeing is carried out reduction cleaning, use vinegar
Acid goes out cylinder after neutralizing washing;Reduction cleaning liquid includes the detergent of 3.7g/L, the surfactant of 1.8g/L, 23g/L alginic acid
Sodium and the tea saponin of 12g/L, bath raio 1:20, temperature 53 DEG C, scavenging period 67min;
6) Final finishing: the copper ion antibacterial and deodouring fiber raschel blanket after reduction cleaning is carried out successively drying and shaping, front hot light,
Front bristle, front scald cut, hair is scalded at back side fluffing, back side bristle, the back side, the back side grab cut, multiple sizing, front boiling hot are cut, carry on the back
Face scald cut, cutting i.e. obtains copper ion antibacterial and deodouring fiber raschel blanket finished product after sewing up, finally will enter after packaging after product inspection
Storehouse;Drying and shaping uses JZR type tentering heat setting machine to carry out, and setting speed is 23m/min, and design temperature is 185 DEG C;Just
Face hot light uses SME473H type list roller secondary natural lustre finishing machine to carry out, and hot light temperature is 185 DEG C, cloth speed 16m/min, twice of suitable hair,
Twice of inverse hair;Front bristle uses the double rod brushing machine of MB211E type to carry out, speed 5m/min;Front is scalded and is cut employing MB322H
Type high-speed and high-efficiency scalds shearing machine to be carried out, and temperature is 185 DEG C, and speed is 13m/min;Back side fluffing uses MB311E type raising machine
Carrying out, fluffing 4 times in the back side, speed is 19m/min, plays gross weight 40%, and front retains 60%;Back side bristle uses MB211E
The double rod brushing machine of type is carried out, and single roller bristle, along hairbrush, speed 5m/min;Back side hot light uses SME473H type list roller secondary
Natural lustre finishing machine is carried out, hot light temperature 185 DEG C, 11m/min of hot light speed regulation, second time 13m/min;The back side is grabbed and is cut employing
MB322E type efficiently scalds shearing machine to be carried out, and speed is 11m/min, cropping height 5mm;Multiple sizing uses JZR type tentering heat fixed
Type machine is carried out, setting temperature 173 DEG C, and speed is 21m/min;Front is scalded and is cut employing MB322E type high-speed and high-efficiency and scald shearing machine and enter
OK, temperature is 185 DEG C, speed 12m/min;The back side is scalded and is cut employing MB322E type high-speed and high-efficiency and scald shearing machine and carry out, and temperature is
185 DEG C, speed 13m/min, inverse hair scalds cuts twice.
Embodiment 3
The production technology of a kind of copper ion antibacterial and deodouring fiber raschel blanket, comprises the following steps:
1) yarn selects: using copper ion fiber-viscose rayon as plush yarn, using polyester drawn yarns as wire gauze;
2) braiding: use double rib warp loom that plush yarn and wire gauze are woven, obtain copper ion antibacterial and deodouring fiber raschel blanket;
The technological parameter of braiding is: on the double rib warp loom that model is E2291A, and front and back needle-bar spaces for 14mm, respectively with 1,
Front and back, needle-bar weaves 4 pin inlaid thread tissues respectively for No. 6 sley bars, 2, No. 5 sley bars respectively in needle-bar braiding pillar stitch of front and back, 3,
No. 4 sley bars weave lint respectively at forward and backward needle-bar, and braiding speed is 440r/min;
3) kiering: by step 2) in woollen blanket be placed in kiering liquid and carry out kiering;Controlling bath raio 1:30 during kiering, kiering temperature is
100 DEG C, kiering time 60min, the formula of kiering liquid is: sodium silicate 0.5g/L, sodium carbonate 3g/L, Matrii Sulfas Exsiccatus 5g/L, infiltration
Agent JFC 1g/L, Triton X-100 5g/L, glyceryl triacetate 0.8g/L, Folium Menthae extract 5g/L, propolis extracts
Thing 10g/L;Wherein, the preparation method of Folium Menthae extract is: takes 65 DEG C of oven dryings of Herba Menthae herb, is dried to constant weight pulverizing,
Amount needed for weighing accordingly, and press the material ratio of 1:30, add distilled water reflux, extract, 5 times, filter;Merging filtrate, reduce pressure dense
Contracting, and use 90% ethanol concentrating rear 3 times of quality to stand overnight, obtain precipitate;After 3 water extract-alcohol precipitations, precipitation is with anhydrous
Washing with alcohol, and use Vacuum Freezing & Drying Technology to obtain Folium Menthae extract;Propolis extract uses following steps to prepare: by honeybee
After collagen material freezing smashes, with supercritical carbon dioxide extraction, extraction tower pressure is 25MPa, and extraction temperature is 75 DEG C, extraction
Time 2h, entrainer is the ethanol solution that volumetric concentration is 95% of the 25% of extraction tower feed weight, knockout tower pressure 15MPa,
Separation temperature 65 DEG C, obtains propolis extract from knockout tower discharging;
4) printing and dyeing: by the regulation of dyeing liquor pH value to after 6.8 to step 3) in woollen blanket print and dye;During printing and dyeing, dyeing liquor pH uses
Acetic acid regulates, dye bath ratio 1:17, and dyeing temperature is 155 DEG C, and dyeing time is 55min, and the concrete formula of dyeing liquor is:
Lonsperse EE series disperse dyes 1.3g/L, anthocyanidin 2.8g/L, auxiliary agent 4g/L, high temperature dispersant 3.6g/L are even with high temperature
Stain 1g/L, described auxiliary agent is that the sodium carbonate of 1:1:2, sodium hydrosulfite form with nano titanium oxide by mass ratio;
5) reduction cleaning: with reduction cleaning liquid, the copper ion antibacterial and deodouring fiber raschel blanket after uniformly dyeing is carried out reduction cleaning, use vinegar
Acid goes out cylinder after neutralizing washing;Reduction cleaning liquid includes the detergent of 4g/L, the surfactant of 2.5g/L, 25g/L sodium alginate
With the tea saponin of 15g/L, bath raio 1:20, temperature 55 DEG C, scavenging period 75min;
6) Final finishing: the copper ion antibacterial and deodouring fiber raschel blanket after reduction cleaning is carried out successively drying and shaping, front hot light,
Front bristle, front scald cut, hair is scalded at back side fluffing, back side bristle, the back side, the back side grab cut, multiple sizing, front boiling hot are cut, carry on the back
Face scald cut, cutting i.e. obtains copper ion antibacterial and deodouring fiber raschel blanket finished product after sewing up, finally will enter after packaging after product inspection
Storehouse;Drying and shaping uses JZR type tentering heat setting machine to carry out, and setting speed is 24m/min, and design temperature is 190 DEG C;Just
Face hot light uses SME473H type list roller secondary natural lustre finishing machine to carry out, and hot light temperature is 190 DEG C, cloth speed 17m/min, twice of suitable hair,
Twice of inverse hair;Front bristle uses the double rod brushing machine of MB211E type to carry out, speed 5m/min;Front is scalded and is cut employing MB322H
Type high-speed and high-efficiency scalds shearing machine to be carried out, and temperature is 190 DEG C, and speed is 14m/min;Back side fluffing uses MB311E type raising machine
Carrying out, fluffing 4 times in the back side, speed is 20m/min, plays gross weight 40%, and front retains 60%;Back side bristle uses MB211E
The double rod brushing machine of type is carried out, and single roller bristle, along hairbrush, speed 5m/min;Back side hot light uses SME473H type list roller secondary
Natural lustre finishing machine is carried out, hot light temperature 190 DEG C, 12m/min of hot light speed regulation, second time 14m/min;The back side is grabbed and is cut employing
MB322E type efficiently scalds shearing machine to be carried out, and speed is 11m/min, cropping height 5mm;Multiple sizing uses JZR type tentering heat fixed
Type machine is carried out, setting temperature 180 DEG C, and speed is 21m/min;Front is scalded and is cut employing MB322E type high-speed and high-efficiency and scald shearing machine and enter
OK, temperature is 190 DEG C, speed 14m/min;The back side is scalded and is cut employing MB322E type high-speed and high-efficiency and scald shearing machine and carry out, and temperature is
190 DEG C, speed 14m/min, inverse hair scalds cuts twice.
Copper ion fiber raschel blanket should reach following technical specification:
Color fastness to water/(level): >=3;Colour fastness to rubbing/(level): >=3;Colour fastness to perspiration/(level): >=3;Bacteriostasis rate is (golden yellow
Color staphylococcus)/(%): >=70;Bacteriostasis rate (escherichia coli)/(%): >=70;Bacteriostasis rate (Candida albicans)/(%):
≥60。
Embodiment described above is the one preferably scheme of the present invention, and the present invention not makees any pro forma limit
System, also has other variant and remodeling on the premise of without departing from the technical scheme described in claim.
Claims (9)
1. the production technology of a copper ion antibacterial and deodouring fiber raschel blanket, it is characterised in that comprise the following steps:
1) yarn selects: using copper ion fiber-viscose rayon as plush yarn, using polyester drawn yarns as wire gauze;
2) braiding: use double rib warp loom that plush yarn and wire gauze are woven, obtain copper ion fiber raschel blanket;
3) kiering: by step 2) in woollen blanket be placed in kiering liquid and carry out kiering;
4) printing and dyeing: by the regulation of dyeing liquor pH value to after 5.8-6.8 to step 3) in woollen blanket print and dye;
5) reduction cleaning: the copper ion fiber raschel blanket after uniformly dyeing is carried out reduction cleaning with reduction cleaning liquid, with in acetic acid and water
Cylinder is gone out after washing;
6) Final finishing: the copper ion antibacterial and deodouring fiber raschel blanket after reduction cleaning is carried out successively drying and shaping, front hot light,
Front bristle, front scald cut, hair is scalded at back side fluffing, back side bristle, the back side, the back side grab cut, multiple sizing, front boiling hot are cut, carry on the back
Face scald cut, cutting i.e. obtains copper ion Rachael blanket finished product after sewing up, finally will put in storage after packaging after product inspection.
The production technology of a kind of copper ion antibacterial and deodouring fiber raschel blanket the most according to claim 1, it is characterised in that copper
The specification of ion antibacterial deodorization fiber is 150D/140F-180D/150F, and the specification of polyester drawn yarns is 150D/144F.
The production technology of a kind of copper ion antibacterial and deodouring fiber raschel blanket the most according to claim 1, it is characterised in that step
Suddenly the technological parameter of braiding is in (2): on the double rib warp loom that model is E2291A, and front and back needle-bar spaces for 12-14mm,
With 1, No. 6 sley bars, front and back, needle-bar weaves 4 pin inlaid thread tissues respectively respectively, and 2, No. 5 sley bars are compiled in front and back's needle-bar braiding respectively
Chain tissue, 3, No. 4 sley bars weave lint respectively at forward and backward needle-bar, and braiding speed is 360-440r/min.
The production technology of a kind of copper ion antibacterial and deodouring fiber raschel blanket the most according to claim 1, it is characterised in that step
Rapid 4), during printing and dyeing, dyeing liquor pH acetic acid regulates, and dye bath ratio 1:15-17, dyeing temperature is 140-155 DEG C, during dyeing
Between be 45-55min, the concrete formula of dyeing liquor is: Lonsperse EE series disperse dyes 0.95-1.3g/L, anthocyanidin
2.2-2.8g/L, auxiliary agent 3-4g/L, high temperature dispersant 2.3-3.6g/L and high temperature levelling agent 0.5-1g/L, described auxiliary agent by mass ratio is
The sodium carbonate of 1:1:2, sodium hydrosulfite form with nano titanium oxide.
The production technology of a kind of copper ion antibacterial and deodouring fiber raschel blanket the most according to claim 1, it is characterised in that step
Rapid 5), in, reduction cleaning liquid includes the detergent of 3.5-4g/L, the surfactant of 1.5-2.5g/L, 22-25g/L sodium alginate
With the tea saponin of 10-15g/L, bath raio 1:20, temperature 50-55 DEG C, scavenging period 60-75min.
The production technology of a kind of copper ion antibacterial and deodouring fiber raschel blanket the most according to claim 1, it is characterised in that boil
Controlling bath raio 1:30 when practicing, kiering temperature is 90-100 DEG C, kiering time 40-60min, and the formula of kiering liquid is: sodium silicate
0.3-0.5g/L, sodium carbonate 1-3g/L, Matrii Sulfas Exsiccatus 2-5g/L, penetrating agent JFC 0.5-1g/L, Triton X-100 4-5g/L,
Glyceryl triacetate 0.2-0.8g/L, Folium Menthae extract 2.5-5g/L, propolis extract 5-10g/L.
The production technology of a kind of copper ion antibacterial and deodouring fiber raschel blanket the most according to claim 6, it is characterised in that thin
The preparation method of lotus extract is: take 35-65 DEG C of oven drying of Herba Menthae herb, is dried to constant weight pulverizing, needed for weighing accordingly
Amount, and press the material ratio of 1:10-30, add distilled water reflux, extract, 1-5 time, filter;Merging filtrate, concentrating under reduced pressure, and use
90% ethanol concentrating rear 3 times of quality stands overnight, and obtains precipitate;After 2-3 water extract-alcohol precipitation, precipitation absolute ethanol washing,
And use Vacuum Freezing & Drying Technology to obtain Folium Menthae extract.
The production technology of a kind of copper ion antibacterial and deodouring fiber raschel blanket the most according to claim 6, it is characterised in that honeybee
Glue extract uses following steps to prepare: after propolis raw material freezing being smashed, with supercritical carbon dioxide extraction, extraction tower pressure
For 20-25MPa, extraction temperature is 65-75 DEG C, extraction time 1-2h, and entrainer is the body of the 20-25% of extraction tower feed weight
Volume concentrations is the ethanol solution of 95%, knockout tower pressure 10-15MPa, and separation temperature 55-65 DEG C obtains honeybee from knockout tower discharging
Glue extract.
The production technology of a kind of copper ion antibacterial and deodouring fiber raschel blanket the most according to claim 1, it is characterised in that step
Rapid 6), in, drying and shaping uses JZR type tentering heat setting machine to carry out, and setting speed is 22-24m/min, and design temperature is 180-190
℃;Front hot light uses SME473H type list roller secondary natural lustre finishing machine to carry out, and hot light temperature is 180-190 DEG C, cloth speed 15-17m/min,
Twice of suitable hair, twice of inverse hair;Front bristle uses the double rod brushing machine of MB211E type to carry out, speed 4-5m/min;Front is scalded and is cut
Using MB322H type high-speed and high-efficiency to scald shearing machine to carry out, temperature is 180-190 DEG C, and speed is 10-14m/min;Back side fluffing is adopted
Carrying out with MB311E type raising machine, fluffing 4 times in the back side, speed is 18-20m/min, plays gross weight 40%, and front retains 60%;
Back side bristle uses the double rod brushing machine of MB211E type to carry out, and single roller bristle, along hairbrush, speed 4-5m/min;Back side hot light is adopted
Carry out with SME473H type list roller secondary natural lustre finishing machine, hot light temperature 180-190 DEG C, 10-12m/min of hot light speed regulation, the
Two times 12-14m/min;The back side is grabbed and is cut employing MB322E type and efficiently scald shearing machine and carry out, and speed is 10-11m/min, cropping height
4-5mm;Multiple sizing uses JZR type tentering heat setting machine to carry out, and setting temperature 160-180 DEG C, speed is 20-21m/min;
Front is scalded and is cut employing MB322E type high-speed and high-efficiency and scald shearing machine and carry out, and temperature is 180-190 DEG C, speed 10-14m/min;The back side
Scalding and cut employing MB322E type high-speed and high-efficiency and scald shearing machine and carry out, temperature is 180-190 DEG C, speed 10-14m/min, and inverse hair scalds to be cut
Twice.
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CN107938102A (en) * | 2017-09-29 | 2018-04-20 | 江苏格玛斯特种织物有限公司 | Antibacterial fabric and preparation method thereof |
CN108035147A (en) * | 2017-12-24 | 2018-05-15 | 青岛大学 | Pure cotton fabric is crease-resistant and the method for antibiotic property for a kind of raising |
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CN108951213A (en) * | 2018-07-12 | 2018-12-07 | 江苏金太阳纺织科技股份有限公司 | A kind of colour combination spins the dyeing and finishing processing method of appearance fabric |
CN111218742A (en) * | 2019-02-01 | 2020-06-02 | 浙江春江轻纺集团有限责任公司 | Antibacterial copper fiber blended yarn and production process thereof |
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