WO2021103805A1 - 具有优异漆膜附着力的热成形部件及其制造方法 - Google Patents
具有优异漆膜附着力的热成形部件及其制造方法 Download PDFInfo
- Publication number
- WO2021103805A1 WO2021103805A1 PCT/CN2020/118368 CN2020118368W WO2021103805A1 WO 2021103805 A1 WO2021103805 A1 WO 2021103805A1 CN 2020118368 W CN2020118368 W CN 2020118368W WO 2021103805 A1 WO2021103805 A1 WO 2021103805A1
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- WO
- WIPO (PCT)
- Prior art keywords
- paint film
- film adhesion
- thermoformed part
- layer
- excellent paint
- Prior art date
Links
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 32
- 239000011248 coating agent Substances 0.000 title abstract description 16
- 238000000576 coating method Methods 0.000 title abstract description 16
- 238000010438 heat treatment Methods 0.000 claims abstract description 80
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 49
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 46
- 239000000758 substrate Substances 0.000 claims abstract description 25
- 238000001816 cooling Methods 0.000 claims abstract description 18
- 238000012546 transfer Methods 0.000 claims abstract description 10
- 238000005520 cutting process Methods 0.000 claims abstract description 4
- 239000003973 paint Substances 0.000 claims description 62
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 43
- 229910052742 iron Inorganic materials 0.000 claims description 26
- 239000012535 impurity Substances 0.000 claims description 25
- 230000003746 surface roughness Effects 0.000 claims description 25
- 238000009792 diffusion process Methods 0.000 claims description 24
- 239000000463 material Substances 0.000 claims description 24
- 239000000203 mixture Substances 0.000 claims description 24
- 239000000126 substance Substances 0.000 claims description 23
- 238000007747 plating Methods 0.000 claims description 22
- 238000000034 method Methods 0.000 claims description 21
- 229910052725 zinc Inorganic materials 0.000 claims description 12
- 229910000734 martensite Inorganic materials 0.000 claims description 11
- 238000009499 grossing Methods 0.000 claims description 10
- 230000008569 process Effects 0.000 claims description 10
- 229910045601 alloy Inorganic materials 0.000 claims description 9
- 239000000956 alloy Substances 0.000 claims description 9
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 8
- 229910015372 FeAl Inorganic materials 0.000 claims description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 6
- 229910052729 chemical element Inorganic materials 0.000 claims description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 4
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 4
- 229910052814 silicon oxide Inorganic materials 0.000 claims description 4
- 229910052804 chromium Inorganic materials 0.000 claims description 3
- 229910052748 manganese Inorganic materials 0.000 claims description 3
- 229910052758 niobium Inorganic materials 0.000 claims description 3
- 229910052757 nitrogen Inorganic materials 0.000 claims description 3
- 229910052698 phosphorus Inorganic materials 0.000 claims description 3
- 230000005855 radiation Effects 0.000 claims description 3
- 229910052710 silicon Inorganic materials 0.000 claims description 3
- 229910052717 sulfur Inorganic materials 0.000 claims description 3
- 229910052720 vanadium Inorganic materials 0.000 claims description 3
- 238000003825 pressing Methods 0.000 claims description 2
- 238000010791 quenching Methods 0.000 claims description 2
- 230000000171 quenching effect Effects 0.000 claims description 2
- 239000010410 layer Substances 0.000 description 36
- 229910000831 Steel Inorganic materials 0.000 description 15
- 239000010959 steel Substances 0.000 description 15
- 229910000838 Al alloy Inorganic materials 0.000 description 12
- 230000000052 comparative effect Effects 0.000 description 12
- 239000011701 zinc Substances 0.000 description 9
- 230000002787 reinforcement Effects 0.000 description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 230000007797 corrosion Effects 0.000 description 4
- 238000005260 corrosion Methods 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 230000009286 beneficial effect Effects 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 239000011247 coating layer Substances 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000001962 electrophoresis Methods 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- 238000003466 welding Methods 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 238000005275 alloying Methods 0.000 description 1
- CSDREXVUYHZDNP-UHFFFAOYSA-N alumanylidynesilicon Chemical compound [Al].[Si] CSDREXVUYHZDNP-UHFFFAOYSA-N 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000013072 incoming material Substances 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000010301 surface-oxidation reaction Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000003856 thermoforming Methods 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0278—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips involving a particular surface treatment
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/18—Hardening; Quenching with or without subsequent tempering
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/62—Quenching devices
- C21D1/673—Quenching devices for die quenching
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D6/00—Heat treatment of ferrous alloys
- C21D6/002—Heat treatment of ferrous alloys containing Cr
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D6/00—Heat treatment of ferrous alloys
- C21D6/005—Heat treatment of ferrous alloys containing Mn
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D6/00—Heat treatment of ferrous alloys
- C21D6/008—Heat treatment of ferrous alloys containing Si
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D7/00—Modifying the physical properties of iron or steel by deformation
- C21D7/13—Modifying the physical properties of iron or steel by deformation by hot working
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0205—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips of ferrous alloys
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0221—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
- C21D8/0242—Flattening; Dressing; Flexing
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/0068—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for particular articles not mentioned below
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/0081—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for slabs; for billets
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/46—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for sheet metals
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
- C22C21/02—Alloys based on aluminium with silicon as the next major constituent
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
- C22C21/10—Alloys based on aluminium with zinc as the next major constituent
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/06—Ferrous alloys, e.g. steel alloys containing aluminium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/24—Ferrous alloys, e.g. steel alloys containing chromium with vanadium
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/26—Ferrous alloys, e.g. steel alloys containing chromium with niobium or tantalum
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/28—Ferrous alloys, e.g. steel alloys containing chromium with titanium or zirconium
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/32—Ferrous alloys, e.g. steel alloys containing chromium with boron
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/38—Ferrous alloys, e.g. steel alloys containing chromium with more than 1.5% by weight of manganese
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/04—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the coating material
- C23C2/12—Aluminium or alloys based thereon
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/26—After-treatment
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/34—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the shape of the material to be treated
- C23C2/36—Elongated material
- C23C2/40—Plates; Strips
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/34—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the shape of the material to be treated
- C23C2/36—Elongated material
- C23C2/40—Plates; Strips
- C23C2/405—Plates of specific length
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C30/00—Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process
- C23C30/005—Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process on hard metal substrates
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21D—WORKING OR PROCESSING OF SHEET METAL OR METAL TUBES, RODS OR PROFILES WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21D22/00—Shaping without cutting, by stamping, spinning, or deep-drawing
- B21D22/02—Stamping using rigid devices or tools
- B21D22/022—Stamping using rigid devices or tools by heating the blank or stamping associated with heat treatment
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/74—Methods of treatment in inert gas, controlled atmosphere, vacuum or pulverulent material
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/008—Martensite
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2251/00—Treating composite or clad material
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2261/00—Machining or cutting being involved
Definitions
- the invention relates to a material and a manufacturing method thereof, in particular to a thermoformed material and a manufacturing method thereof.
- thermoformed parts In recent years, the application of thermoformed parts in the automotive industry has become very important, especially in terms of automotive safety structural parts, which have irreplaceable advantages in some high-strength, complex-shaped parts.
- the materials used for hot forming parts are divided into coated and uncoated materials.
- the main purpose of the coating is to prevent oxidation of the steel sheet surface during the hot stamping process.
- the formed parts can be directly painted and welded.
- materials without coating must be surface shot peened after hot forming to remove the oxide layer generated on the surface, otherwise the subsequent part painting and welding will be affected.
- the material of the hot-dip aluminum coating layer cannot be normally phosphated after hot forming, and the adhesion of the paint film after electrophoresis is completely guaranteed by the surface morphology of the coating.
- Existing materials have the problem that the paint film adhesion cannot satisfy the use during the use process.
- the publication number is CN104651590A
- the publication date is May 27, 2015
- the Chinese patent document titled "Method for manufacturing stamping products and stamping products manufactured therefrom” discloses a hot forming of aluminum or aluminum alloy coating Material and manufacturing method. This method specifically controls the thickness of the coating layer and the five-layer structure to ensure the welding performance of the hot formed parts.
- the publication number is CN108588612A
- the publication date is September 28, 2018,
- the Chinese patent document entitled "Hot stamping forming components, pre-coated steel sheets for hot stamping forming and hot stamping forming process” discloses a hot stamping Forming components.
- the thickness of the coating is reduced, and the protective effect of the coating is also reduced. Therefore, the fluctuation of the thermoforming process can easily affect the surface properties of the component, thereby affecting the subsequent Use performance.
- the publication number is CN101583486
- the publication date is November 18, 2009
- the name is "coated steel strip, its preparation method, its use method, the stamping blank prepared therefrom, the stamping product prepared therefrom
- the Chinese Patent Document "Products Containing Such Stamped Products” discloses a hot stamped product and method for coating steel strips.
- it includes heating, transfer and cooling, but does not involve the hot stamping process, which will cause unstable quality of stamped products, such as shrinkage, cracking, etc., and do not control the furnace atmosphere during the heating process.
- Resulting in changes in the atmosphere in the furnace during the heating process especially the large changes in oxygen content, which makes the appearance and color of the product easy to change.
- thermoformed part with excellent paint film adhesion.
- the thermoformed part has better paintability, good paint film adhesion and better corrosion resistance, and is very suitable for use.
- auto parts such as: front and rear doors, left and right anti-collision bars/beams, front and rear bumpers, A-pillar reinforcement plates, B-pillar reinforcement plates, floor mid-channels, etc.
- thermoformed part with excellent paint film adhesion which includes a substrate layer and an aluminum-plated layer plated on at least one surface of the substrate layer.
- the average surface of the thermoformed part The roughness Ra is 1.0 ⁇ 3.0 ⁇ m, the peak height and the height of the valley Rt are 8 ⁇ 30 ⁇ m, and the roughness peak count Rpc ⁇ 50.
- the aluminized layer includes an aluminum phase and an aluminum-silicon phase.
- the aluminum in the aluminized layer diffuses to the substrate layer, and at the same time the iron in the substrate layer diffuses to form Al 8 Fe 2 Si phase, the formation of a new phase leads to a significant increase in surface roughness.
- Fe 2 Al 5 phase is formed, and the surface roughness is basically maintained.
- all FeAl alloys are formed in the aluminum coating, and the surface is rough. Instead, the degree has dropped slightly.
- the surface of the hot formed part after heat treatment is mainly composed of Fe 2 Al 5 and FeAl alloy.
- the silicon oxide, aluminum oxide and iron oxide produced by the surface oxidation cannot chemically react with the phosphating solution, that is, it cannot be formed.
- Normal phosphate film therefore, the paint film adhesion of thermoformed parts is completely guaranteed by the uneven structure of the surface, that is, the roughness of the thermoformed part has an important influence on the paint film adhesion.
- the aluminized layer includes: a diffusion layer adjacent to the substrate layer and an alloy layer on the surface of the aluminized layer, wherein the thickness of the diffusion layer is equal to The ratio of the total thickness of the aluminized layer is 0.08-0.5.
- the thickness of the diffusion layer is ⁇ 16 ⁇ m; the total thickness of the aluminized layer is ⁇ 60 ⁇ m.
- the thickness of the diffusion layer is 5-16 ⁇ m; the total thickness of the aluminized layer is 20-60 ⁇ m.
- the average roughness Ra of the surface of the thermoformed part is 1.5-2.5 ⁇ m.
- the peak height and the height Rt of the peak and valley on the surface of the thermoformed part are 10-25 ⁇ m.
- the surface roughness peak count Rpc of the thermoformed part is 50-250, such as 80-180.
- the surface of the thermoformed part with excellent paint film adhesion according to the present invention contains Fe 2 Al 5 and FeAl alloy. Furthermore, the surface of the thermoformed part with excellent paint film adhesion according to the present invention also contains silicon oxide, aluminum oxide and iron oxide. Furthermore, the surface of the thermoformed part with excellent paint film adhesion of the present invention is mainly composed of Fe 2 Al 5 and FeAl alloy, and also contains silicon oxide, aluminum oxide and iron oxide. Moreover, the Fe 2 Al 5 content on the surface of the thermoformed part with excellent paint film adhesion according to the present invention is higher than 40 wt %.
- the weight percentage of the chemical composition of the aluminum-plated layer is: Si: 4-14%, Fe: 0-4%, Mg: 0-10 %, Zn: 0-20%, the balance is Al and other unavoidable impurities. Further, in the thermoformed part with excellent paint film adhesion of the present invention, the weight percentage of the chemical composition of the aluminum-plated layer is: Si: 4-14%, Fe: 2-4%, Mg: 0-10 %, Zn: 0-20%, the balance is Al and other unavoidable impurities.
- the weight average value of the aluminized layer is 20-120 g/m 2 per single side.
- the weight average value of the aluminized layer is 30-100 g/m 2 per single side.
- the mass percentage of the chemical composition of the substrate layer is:
- the mass percentage of each chemical element in the substrate layer also satisfies at least one of the following items:
- the mass percentage of each chemical element of the substrate layer also satisfies at least one of the following items:
- the Al content is 0.03-0.09%, and the Ti content is 0.01-0.2%, preferably 0.01-0.1%.
- the Cr content is 0.1-0.8%.
- the content of Nb when it is contained, the content of Nb is 0.001-0.1%; when it is contained, the content of V is 0.001-0.01%.
- the mass percentage of the chemical composition of the base material layer is: C: 0.02-0.8%, Si: 0.05-0.5%, Mn: 0.1-3 %, P ⁇ 0.1%, S ⁇ 0.05%, Al: 0.04-0.09%, Ti: 0.02-0.2%, B: 0.0005-0.09%, Cr: 0.15-0.8%, Nb: 0% or 0.001-0.1%, V is 0% or 0.002-0.008%, and the balance is Fe and other unavoidable impurities.
- the yield strength is 400-1400 MPa
- the tensile strength is 500-2100 MPa
- the elongation is ⁇ 4%.
- the volume percentage of martensite in the microstructure of the substrate of the thermoformed part with excellent paint film adhesion according to the present invention is ⁇ 70%, preferably 85 ⁇ %, more preferably ⁇ 95%.
- another object of the present invention is to provide the above-mentioned method for manufacturing a thermoformed part with excellent paint film adhesion, by which a thermoformed part with excellent paint film adhesion can be obtained.
- the present invention proposes the above-mentioned method for manufacturing a thermoformed part with excellent paint film adhesion, which includes the steps:
- Transfer and hot stamping The hot blank is quickly transferred to the mold for cooling stamping forming to form the hot formed part.
- step (4) the temperature of the heating furnace is too low or the residence time of the billet in the heating furnace is too short, which will lead to insufficient diffusion of iron and aluminum, resulting in excessive surface roughness. Low, affecting the roughness of the final thermoformed part.
- the temperature of the heating furnace is too high or the residence time of the billet in the heating furnace is too long, it will cause excessive diffusion of iron and aluminum and complete formation of FeAl alloy, which will also reduce the roughness of the final hot formed part, and the diffusion process
- the holes formed by the migration of middle elements will affect the surface conductivity, and the electrophoresis process will cause shrinkage holes, which will affect the paintability.
- the mass percentage of the chemical composition of the aluminum plating solution is: Si: 5 to 11%, Fe: 2 to 4%, Zn: 0 to 15%, Mg: 0-8%, the balance is Al and other unavoidable impurities.
- the mass percentage of the chemical composition of the aluminum plating solution is: Si: 8 to 11%, Fe: 2 to 4%, Zn: 0 to 11%, Mg: 0-8%, the balance is Al and other unavoidable impurities.
- the mass percentage of the chemical composition of the aluminum plating solution is: Si: 5-11%, Fe: 2-4%, and the balance is Al And other unavoidable impurities.
- the mass percentage of the chemical composition of the aluminum plating solution is: Si: 5-11%, Fe: 2-4%, optionally Zn : 2-15%, optional Mg: 0.5-8%, the balance is Al and other unavoidable impurities.
- the heating rate does not exceed 10°C/s in the range of 400-600°C to make the coating Pre-alloying of zinc and aluminum to avoid coating damage or cracks.
- step (5) the blank is transferred to the mold within 20 seconds.
- the pressure-holding quenching is continued for 4-20 seconds, and the pressure-holding pressure applied to the surface of the blank is ⁇ 8MPa.
- the holding pressure is 10-20 MPa.
- step (5) the material of the mold satisfies: the thermal diffusion coefficient at 700° C. is greater than 3.8 mm 2 /s.
- the clamping speed of the mold during stamping is 30-150mm/s, so that the thermoformed part can ensure good forming performance and reduce stamping defects such as The occurrence of cracking and necking.
- step (5) the blank is cooled to 50-200°C at a cooling rate of 30-150°C/s, so that the internal structure of the thermoformed part is transformed into The required organizational structure, while ensuring that the thermoformed parts still maintain a good size and shape during the cooling process.
- the present invention also includes thermoformed parts manufactured by the above-mentioned method.
- thermoformed part with excellent paint film adhesion and its method according to the present invention have the following advantages and beneficial effects:
- thermoformed parts with excellent paint film adhesion of the present invention have better paintability, good paint film adhesion and better corrosion resistance, and are very suitable for automotive parts, such as: front and rear doors Left and right anti-collision bars/beams, front and rear bumpers, A-pillar reinforcement plate, B-pillar reinforcement plate, floor middle channel, etc.
- the manufacturing method of the present invention also has the above-mentioned advantages and beneficial effects.
- thermoformed component with excellent paint film adhesion and its manufacturing method according to the present invention in conjunction with specific examples, but the explanation and description do not improperly limit the technical solution of the present invention.
- thermoformed parts with excellent paint film adhesion of Examples 1-10 and Comparative Example 1 were prepared by the following steps:
- the substrate is immersed in an aluminum plating solution to obtain a plate with an aluminum plating layer on the surface.
- Transfer and hot stamping The hot blank is quickly (for example, within 20s) transferred to the mold for cooling stamping forming to form a hot formed part.
- the hot stamping process after the mold is closed, the pressure is maintained and quenched for 4-20s.
- the pressure on the surface of the blank is ⁇ 8MPa, and the material of the mold meets: the thermal diffusion coefficient at 700°C is greater than 3.8mm 2 /s ,
- the clamping speed of the mold during pressing is 30-150mm/s, and the blank is cooled to 50-200°C at a cooling rate of 30-150°C/s.
- the 1.2mm aluminum alloy coated steel plate is leveled by a leveling roller to obtain the plate before heat treatment and hot stamping with the surface roughness shown in Table 2.
- the laser blanks into a blank of a certain size and shape, and the chemical composition quality of the aluminum plating solution
- the percentage content is Si: 8.5%, Fe: 2.6%, Zn: 15%, Mg: 4%, the rest is aluminum and unavoidable impurities.
- the billet enters the heating furnace, the heating furnace temperature is 950°C, the residence time is 3.5min, 400 ⁇ In the range of 600°C, the heating rate is 2°C/s, the transfer time is 4s, the holding time is 5s, the holding pressure is 10MPa, the clamping speed is 50mm/s, the cooling speed is 50°C/s, cooling to 200°C, the mold is at 700
- the thermal diffusivity at °C is 4mm 2 /s.
- the billet enters the heating furnace, the heating furnace temperature is 940°C, the residence time is 5min, 400 ⁇ 600 In the range of °C, the heating rate is 5°C/s, the transfer time is 6s, the holding time is 15s, the holding pressure is 20MPa, the mold clamping speed is 150mm/s, the cooling speed is 150°C/s, cooling to 50°C, the mold is at 700°C
- the thermal diffusion coefficient at that time is 5mm 2 /s.
- the 1.0mm aluminum alloy coated steel plate is leveled with a leveling roller to obtain the plate before heat treatment and hot stamping with the surface roughness shown in Table 2.
- the laser blanks into a blank of a certain size and shape, and the chemical composition quality of the aluminum plating solution
- the percentage content is Si: 9.0%, Fe: 2.7%, and the rest is aluminum and unavoidable impurities.
- the billet enters the heating furnace.
- the heating rate of 400-600°C is 5°C/s
- the heating furnace temperature is 930°C
- the residence time is 7min. It is transferred to the mold within 8s, and the thermal diffusivity of the mold at about 700°C is 7mm 2 /s.
- the clamping speed is 70mm/s
- the holding time is 6s
- the holding pressure is 12MPa
- the cooling speed is 100°C/s
- it is cooled to 100°C.
- the ratio of martensite in the microstructure of the resulting thermoformed part base material is higher than 96%.
- the 2.8mm aluminum alloy coated steel plate is leveled with a leveling roller to obtain the surface roughness of the plate before heat treatment and hot stamping as shown in Table 2.
- the laser blanks into a blank of a certain size and shape, and the chemical composition quality of the aluminum plating solution The percentage content is Si: 8.8%, Fe: 2.7%, the rest is aluminum and unavoidable impurities.
- the billet enters the heating furnace, the heating furnace temperature is 920°C, the residence time is 7min, and the heating rate of 400-600°C is 10°C/s.
- thermoformed part base material Transfer to the mold within 8s, clamping speed 70mm/s, holding time 6s, holding pressure 15MPa, cooling speed 60°C/s, cooling to 60°C, the thermal diffusion coefficient of the mould at 700°C is 6mm 2 /s.
- the ratio of martensite in the microstructure of the resulting thermoformed part base material is higher than 98%.
- the 1.1mm aluminum alloy coated steel plate is leveled with a leveling roller to obtain the plate before heat treatment and hot stamping with the surface roughness shown in Table 2.
- the laser blanks into a blank of a certain size and shape, and the chemical composition quality of the aluminum plating solution
- the percentage content is Si: 10%, Fe: 3.5%, Zn: 2%, Mg: 1%, the rest is aluminum and unavoidable impurities.
- the billet enters the heating furnace, the heating furnace temperature is 935°C, the residence time is 4.5min, 400 ⁇
- the heating rate is 4°C/s in the range of 600°C, and it is transferred to the mold within 7s.
- the upper and lower mold clamping speed is 80mm/s
- the holding time is 5s
- the holding pressure is 15MPa
- the thermal diffusion coefficient of the mold at 700°C is 4mm 2 /s, cooling to 100°C.
- the ratio of martensite in the microstructure of the resulting thermoformed part base material is higher than 95%.
- the 1.5mm aluminum alloy coated steel plate is leveled with a leveling roller to obtain the plate before heat treatment and hot stamping with the surface roughness shown in Table 2.
- the laser blanks into a blank of a certain size and shape, and the chemical composition quality of the aluminum plating solution
- the percentage content is Si: 10%, Fe: 3.5%, Mg: 0.5%
- the rest is aluminum and unavoidable impurities.
- the billet enters the heating furnace, the temperature of the heating furnace is 935°C, the residence time is 5min, and the heating is in the range of 400 ⁇ 600°C
- the rate is 6°C/s, and it is transferred to the mold within 7s.
- the upper and lower mold clamping speed is 80mm/s, the holding time is 5s, and the holding pressure is 15MPa.
- the thermal diffusion coefficient of the mold at 700°C is 4mm 2 /s, and it is cooled to 120 °C.
- the ratio of martensite in the microstructure of the resulting thermoformed part base material is higher than
- the 1.8mm aluminum alloy coated steel plate is leveled with a leveling roller to obtain the plate before heat treatment and hot stamping with the surface roughness shown in Table 2.
- the laser blanks into a blank of a certain size and shape, and the chemical composition quality of the aluminum plating solution The percentage content is Si: 10%, Fe: 3.5%, the rest is aluminum and unavoidable impurities.
- the billet enters the heating furnace, the heating furnace temperature is 945°C, the residence time is 2.5min, and the heating rate is 7°C in the range of 400 ⁇ 600°C /s, transfer to the mold within 7s, the upper and lower mold clamping speed is 80mm/s, the holding time is 5s, the holding pressure is 15MPa, the thermal diffusion coefficient of the mold at 700°C is 6.8mm 2 /s, and it is cooled to 140°C.
- the ratio of martensite in the microstructure of the resulting thermoformed part base material is higher than 95%.
- the 2.0mm aluminum alloy coated steel plate is leveled with a leveling roller to obtain the plate before heat treatment and hot stamping with the surface roughness shown in Table 2.
- the laser blanks into a blank of a certain size and shape, and the chemical composition quality of the aluminum plating solution
- the percentage content is Si: 10%, Fe: 3.5%, the rest is aluminum and unavoidable impurities.
- the billet enters the heating furnace.
- the heating furnace temperature is 940°C
- the residence time is 3min
- the heating rate is 3°C/ in the range of 400 ⁇ 600°C.
- the oxygen content of the atmosphere in the furnace is 22%, and it is transmitted to the mold within 7s, the upper and lower mold clamping speed is 80mm/s, the holding time is 5s, the holding pressure is 15MPa, and the thermal diffusion coefficient of the mold at 700°C is 7mm 2 /s , Cool to 110°C.
- the ratio of martensite in the microstructure of the resulting thermoformed part base material is higher than 95%.
- the 2.4mm aluminum alloy coated steel plate is leveled by a leveling roller, and the surface roughness of the plate before heat treatment and hot stamping is obtained as shown in Table 2.
- the laser blanks into a blank of a certain size and shape, and the chemical composition quality of the aluminum plating solution The percentage content is Si: 10%, Fe: 3.5%, the rest is aluminum and unavoidable impurities.
- the billet enters the heating furnace.
- the temperature of the heating furnace is 935°C
- the residence time is 5min
- the heating rate is 8°C/ in the range of 400 ⁇ 600°C.
- the oxygen content of the atmosphere in the furnace is 22%, and it is transmitted to the mold within 7s, the upper and lower mold clamping speed is 80mm/s, the holding time is 5s, the holding pressure is 15MPa, and the thermal diffusion coefficient of the mold at 700°C is 4mm 2 /s , Cool to 100°C.
- the ratio of martensite in the microstructure of the resulting thermoformed part base material is higher than 95%.
- the 2.8mm aluminum alloy coated steel plate is leveled with a leveling roller to obtain the surface roughness of the plate before heat treatment and hot stamping as shown in Table 2.
- the laser blanks into a blank of a certain size and shape, and the chemical composition quality of the aluminum plating solution The percentage content is Si: 10%, Fe: 3.5%, the rest is aluminum and unavoidable impurities.
- the billet enters the heating furnace.
- the temperature of the heating furnace is 950°C
- the residence time is 2.5min
- the heating rate is 4°C in the range of 400 ⁇ 600°C.
- the oxygen content of the atmosphere in the furnace is 20%, and it is transmitted to the mold within 15s, the upper and lower mold clamping speed is 80mm/s, the holding time is 5s, the holding pressure is 15MPa, and the thermal diffusion coefficient of the mold at 700°C is 5mm 2 / s, cool to 80°C.
- the ratio of martensite in the microstructure of the resulting thermoformed part base material is higher than 95%.
- the 1.5mm aluminum alloy coated steel plate is leveled with a leveling roller to obtain the plate before heat treatment and hot stamping with the surface roughness shown in Table 2.
- the laser blanks into a blank of a certain size and shape, and the chemical composition quality of the aluminum plating solution The percentage content is Si: 10%, Fe: 3.5%, the rest is aluminum and unavoidable impurities.
- the billet enters the heating furnace.
- the heating furnace temperature is 935°C
- the residence time is 5min
- the heating rate is 6°C/ in the range of 400 ⁇ 600°C.
- thermoformed part base material The ratio of martensite in the microstructure of the resulting thermoformed part base material is higher than 95%.
- Table 1 lists the mass percentage ratios of the chemical elements in the base material layer of the thermoformed parts with excellent paint film adhesion of Examples 1-10 and the base material layer of Comparative Example 1.
- the evaluation method of paintability refers to the GMW16170 standard.
- the corrosion resistance test method refers to GMW14872.
- the finished surface roughness Ra of the comparative thermoformed part after hot stamping in Comparative Example 1 is less than 1.8 ⁇ m, Rt is less than 12 ⁇ m, Rpc is less than 90, and the heat of Comparative Example 1
- the paintability of the formed part is poor, the paint film adhesion does not meet the requirements, and its performance is far inferior to the thermoformed parts of the various embodiments of this case.
- the higher the surface roughness of the material before heat treatment and hot stamping used in the hot forming part the higher the roughness of the product after heat treatment and hot stamping, and the better the adhesion to the paint film.
- thermoformed parts with excellent paint film adhesion of the present invention have better paintability, good paint film adhesion and better corrosion resistance, and are very suitable for use in automobiles.
- Components such as: front and rear doors, left and right anti-collision bars/beams, front and rear bumpers, A-pillar reinforcement plates, B-pillar reinforcement plates, and floor channels, etc.
- the manufacturing method of the present invention also has the above-mentioned advantages and beneficial effects.
Abstract
Description
实施例 | C | Si | Mn | P | S | Al | Ti | B | Cr | Nb | V |
1 | 0.02 | 0.05 | 0.12 | 0.059 | 0.038 | 0.09 | 0.090 | 0.0005 | 0.15 | - | - |
2 | 0.06 | 0.23 | 1.19 | 0.015 | 0.001 | 0.04 | 0.030 | 0.040 | 0.27 | - | - |
3 | 0.49 | 0.50 | 2.51 | 0.024 | 0.04 | 0.08 | 0.027 | 0.0052 | 0.51 | 0.002 | 0.002 |
4 | 0.39 | 0.36 | 3.00 | 0.044 | 0.03 | 0.07 | 0.05 | 0.0062 | 0.71 | 0.003 | 0.005 |
5 | 0.78 | 0.48 | 0.50 | 0.081 | 0.02 | 0.05 | 0.48 | 0.0071 | 0.20 | 0.1 | - |
6 | 0.15 | 0.10 | 2.90 | 0.059 | 0.038 | 0.09 | 0.090 | 0.0031 | 0.15 | - | - |
7 | 0.25 | 0.23 | 1.19 | 0.015 | 0.001 | 0.04 | 0.030 | 0.0040 | 0.27 | - | - |
8 | 0.49 | 0.50 | 2.51 | 0.024 | 0.04 | 0.08 | 0.027 | 0.0052 | 0.51 | 0.005 | 0.008 |
9 | 0.39 | 0.36 | 3.00 | 0.044 | 0.03 | 0.07 | 0.05 | 0.0062 | 0.71 | - | - |
10 | 0.50 | 0.9 | 0.50 | 0.081 | 0.02 | 0.05 | 0.20 | 0.09 | 0.20 | - | - |
对比例1 | 0.25 | 0.23 | 1.19 | 0.015 | 0.001 | 0.04 | 0.030 | 0.0040 | 0.27 | - | - |
Claims (20)
- 一种具有优异漆膜附着力的热成形部件,其包括基材层以及镀覆在基材层的至少一个表面上的镀铝层;其特征在于,所述热成形部件表面的平均粗糙度Ra为1.0~3.0μm,峰高与峰谷的高度Rt为8~30μm,粗糙度峰计数Rpc≥50。
- 如权利要求1所述的具有优异漆膜附着力的热成形部件,其特征在于,所述镀铝层包括:与基材层邻接的扩散层和位于镀铝层表面的合金层,其中扩散层的厚度与镀铝层总厚度的比值为0.08-0.5。
- 如权利要求1或2所述的具有优异漆膜附着力的热成形部件,其特征在于,所述扩散层的厚度≤16μm;所述镀铝层总厚度≤60μm。
- 如权利要求1所述的具有优异漆膜附着力的热成形部件,其特征在于,所述的镀铝层的化学成分重量百分比为:Si:4~14%,Fe:0~4%,Mg:0~10%,Zn:0~20%,余量为Al及其他不可避免的杂质;优选地,所述镀铝层的化学成分重量百分比为:Si:4~14%,Fe:2~4%,Mg:0~10%,Zn:0~20%,余量为Al及其他不可避免的杂质。
- 如权利要求1所述的具有优异漆膜附着力的热成形部件,其特征在于,所述镀铝层的重量平均值为20~120g/m 2每单面。
- 如权利要求5所述的具有优异漆膜附着力的热成形部件,其特征在于,所述镀铝层的重量平均值为30~100g/m 2每单面。
- 如权利要求1所述的具有优异漆膜附着力的热成形部件,其特征在于,所述基材层的化学成分质量百分比为:C:0.01~0.8%,Si:0.05~1.0%,Mn:0.1~5%,P≤0.3%,S≤0.1%,Al≤0.3%,Ti≤0.5%,B:0.0005~0.1%,Cr:0.01~3%,Nb≤0.5%,V≤0.5%,余量为Fe及其他不可避免的杂质。
- 如权利要求7所述的具有优异漆膜附着力的热成形部件,其特征在于,所述基材层的各化学元素质量百分比还满足下列各项的至少其中之一:C:0.05~0.6%,Si:0.07~0.8%,Mn:0.3~4%,P≤0.2%,S≤0.08%,Al≤0.2%,Ti≤0.4%,B:0.0005~0.08%,Cr:0.01~2%,Nb≤0.3%,V≤0.3%。
- 如权利要求7或8所述的具有优异漆膜附着力的热成形部件,其特征在于,所述基材层的各化学元素质量百分比还满足下列各项的至少其中之一:C:0.15~0.5%,Si:0.1~0.5%,Mn:0.5~3%,P≤0.1%,S≤0.05%,Al≤0.1%,Ti≤0.2%,Cr:0.01~1%。
- 如权利要求1所述的具有优异漆膜附着力的热成形部件,其特征在于,其屈服强度为400~1400MPa,抗拉强度为500~2100MPa,延伸率≥4%。
- 如权利要求1所述的具有优异漆膜附着力的热成形部件,其特征在于,所述的具有优异漆膜附着力的热成形部件的表面含有Fe 2Al 5和FeAl合金;或主要由Fe 2Al 5和FeAl合金组成,同时还含有硅的氧化物、铝的氧化物和铁的氧化物。
- 如权利要求9所述的具有优异漆膜附着力的热成形部件,其特征在于,所述的具有优异漆膜附着力的热成形部件的基材层的显微组织中马氏体的体积百分比≥95%。
- 如权利要求1-12中任意一项所述的具有优异漆膜附着力的热成形部件的制造方法,其特征在于,包括步骤:(1)将基材浸入铝镀液,得到表面具有镀铝层的板材;(2)平整:采用粗糙度Ra为0.5~3.0μm的平整辊对板材进行平整,控制平整率≤2.0%,所述板材表面热辐射系数为0.1~0.8,板材表面粗糙度Ra为0.3~2.0μm,板材表面粗糙度峰计数Rpc为30~150;(3)落料:将板材冲裁或切割成部件所需形状的坯料;(4)热处理:将坯料放入加热炉中加热并保温,加热炉温度为880~960℃,加热炉内的气氛采用空气或氮气,坯料在加热炉中的停留时间为2.5~10min;(5)传输和热冲压:将热的坯料快速传输到模具中进行冷却冲压成形,以形成所述热成形部件。
- 如权利要求13所述的制造方法,其特征在于,在所述步骤(1)中,铝镀液的化学成分质量百分含量为:Si:5~11%,Fe:2~4%,Zn:0~15%,Mg:0~8%,余量为Al及其他不可避免的杂质;优选为:Si:8~11%,Fe:2~4%,Zn:0~11%,Mg:0~8%,余量为Al及其他不可避免的杂质。
- 如权利要求13所述的制造方法,其特征在于,在所述步骤(4)中,在坯料加热的升温过程中,在升温至400~600℃的范围内加热速率不超过10℃/s。
- 如权利要求13所述的制造方法,其特征在于,在所述步骤(5)中,坯料在20s以内被传输到模具中。
- 如权利要求13所述的制造方法,其特征在于,在所述步骤(5)的热冲压过程中,所述模具合模后持续保压淬火4~20s,对坯料表面施加的保压压强≥8MPa。
- 如权利要求13所述的制造方法,其特征在于,在所述步骤(5)中,所述模具的材质满足:在700℃时的热扩散系数大于3.8m 2/s。
- 如权利要求13所述的制造方法,其特征在于,在所述步骤(5)中,冲压时模具的合模速度为30~150mm/s。
- 如权利要求13所述的制造方法,其特征在于,在所述步骤(5)中,将坯料以30~150℃/s的冷却速度冷却至50~200℃。
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BR112022009756A BR112022009756A2 (pt) | 2019-11-29 | 2020-09-28 | Componente termoformado com excelente adesão de revestimento e método de fabricação para o mesmo |
JP2022530312A JP7326612B2 (ja) | 2019-11-29 | 2020-09-28 | 優れた塗装フィルム付着力を有する熱成形部品及びその製造方法 |
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WO2024028641A1 (en) * | 2022-08-04 | 2024-02-08 | Arcelormittal | Steel sheet having excellent corrosion properties after press hardening and method for manufacturing the same |
WO2024028642A1 (en) * | 2022-08-04 | 2024-02-08 | Arcelormittal | Steel sheet having excellent powdering properties after press-hardening and method for manufacturing the same |
CN115945571A (zh) * | 2023-01-18 | 2023-04-11 | 上海新顿长菁科技有限公司 | 6xxx系铝合金的热成形工艺及其制得的零件和应用 |
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