WO2021070314A1 - 冷凍サイクル装置 - Google Patents

冷凍サイクル装置 Download PDF

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Publication number
WO2021070314A1
WO2021070314A1 PCT/JP2019/039966 JP2019039966W WO2021070314A1 WO 2021070314 A1 WO2021070314 A1 WO 2021070314A1 JP 2019039966 W JP2019039966 W JP 2019039966W WO 2021070314 A1 WO2021070314 A1 WO 2021070314A1
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WO
WIPO (PCT)
Prior art keywords
port
refrigerant
mixed refrigerant
refrigeration cycle
azeotropic mixed
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2019/039966
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English (en)
French (fr)
Japanese (ja)
Inventor
智隆 石川
洋貴 佐藤
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Electric Corp
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Mitsubishi Electric Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
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Priority to PCT/JP2019/039966 priority Critical patent/WO2021070314A1/ja
Priority to JP2021551031A priority patent/JP7278399B2/ja
Publication of WO2021070314A1 publication Critical patent/WO2021070314A1/ja
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B1/00—Compression machines, plants or systems with non-reversible cycle
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B39/00—Evaporators; Condensers
    • F25B39/04—Condensers
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B41/00—Fluid-circulation arrangements
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B6/00—Compression machines, plants or systems, with several condenser circuits
    • F25B6/02—Compression machines, plants or systems, with several condenser circuits arranged in parallel
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28—HEAT EXCHANGE IN GENERAL
    • F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D1/00—Heat-exchange apparatus having stationary conduit assemblies for one heat-exchange medium only, the media being in contact with different sides of the conduit wall, in which the other heat-exchange medium is a large body of fluid, e.g. domestic or motor car radiators
    • F28D1/02—Heat-exchange apparatus having stationary conduit assemblies for one heat-exchange medium only, the media being in contact with different sides of the conduit wall, in which the other heat-exchange medium is a large body of fluid, e.g. domestic or motor car radiators with heat-exchange conduits immersed in the body of fluid
    • F28D1/04—Heat-exchange apparatus having stationary conduit assemblies for one heat-exchange medium only, the media being in contact with different sides of the conduit wall, in which the other heat-exchange medium is a large body of fluid, e.g. domestic or motor car radiators with heat-exchange conduits immersed in the body of fluid with tubular conduits
    • F28D1/047—Heat-exchange apparatus having stationary conduit assemblies for one heat-exchange medium only, the media being in contact with different sides of the conduit wall, in which the other heat-exchange medium is a large body of fluid, e.g. domestic or motor car radiators with heat-exchange conduits immersed in the body of fluid with tubular conduits the conduits being bent, e.g. in a serpentine or zig-zag

Definitions

  • the present invention relates to a refrigeration cycle device in which a non-azeotropic mixed refrigerant circulates.
  • Patent Document 1 discloses an air conditioner in which a non-azeotropic mixed refrigerant circulates.
  • the non-azeotropic mixed refrigerant flowing out of the outdoor heat exchanger functioning as a condenser flows into the receiver. Since the liquid refrigerant flows out from the receiver, the vicinity of the outlet of the outdoor heat exchanger can be easily maintained in a saturated liquid state. As a result, changes in the composition of the non-azeotropic mixed refrigerant can be appropriately detected.
  • the outdoor heat exchanger has a plurality of flow paths through which the non-azeotropic mixed refrigerant passes.
  • the gas-liquid two-phase non-cobo-boiling mixed refrigerant flows out from a certain flow path of multiple flow paths, the gas-liquid two-phase non-co-boiling mixed refrigerant and the liquid flowing out from another flow path are non-co-boiling It is necessary that the mixed refrigerant is mixed to eliminate the gas-liquid two-phase state at the receiver.
  • the degree of supercooling of the liquid is increased to the extent that the gas-liquid two-phase state is eliminated in the receiver, the bias of the degree of supercooling among the non-azeotropic mixed refrigerants flowing through the plurality of flow paths increases. , The heat exchange efficiency of the outdoor heat exchanger may decrease. As a result, the performance of the air conditioner can be reduced.
  • the present invention has been made to solve the above-mentioned problems, and an object thereof is to suppress deterioration of the performance of the refrigeration cycle apparatus.
  • the non-azeotropic mixed refrigerant circulates.
  • the refrigeration cycle device includes a compressor, a first heat exchanger, a refrigerant container, an expansion valve, a second heat exchanger, and a blower.
  • the first heat exchanger has a first port, a second port, a third port, and a fourth port.
  • the blower forms an air flow that passes in the order of the second port to the first port and passes in the order of the fourth port to the third port.
  • the non-co-boiling mixed refrigerant circulates in the order of the compressor, the first port, the second port, the refrigerant container, the expansion valve, and the second heat exchanger, and the compressor, the third port, the fourth port, the refrigerant container, and the like. It circulates in the order of the expansion valve and the second heat exchanger.
  • the temperature gradient of the non-azeotropic mixed refrigerant which is the relationship between the dryness of the non-azeotropic mixed refrigerant and the temperature of the non-azeotropic mixed refrigerant, represents the dryness. It is represented as an upwardly convex monotonic increase curve in a coordinate plane having a horizontal axis and a vertical axis representing temperature.
  • the non-co-boiling which is the relationship between the dryness of the non-co-boiling mixed refrigerant and the temperature of the non-co-boiling mixed refrigerant.
  • FIG. 2 It is a functional block diagram which shows the structure of the refrigeration cycle apparatus which concerns on embodiment. It is an external perspective view of the condenser of FIG.
  • FIG. 2 is a plan view of the condenser of FIG. 2 from the X-axis direction. It is a figure which shows the specific flow of the air flow of FIG. A straight line representing the relationship between the position in the flow path of the condenser and the temperature of R407 when R407C, which is an azeotropic mixed refrigerant, is used as the refrigerant that circulates in the refrigeration cycle device, and the relationship between the position and the temperature of air. It is a figure which also shows the straight line which represents. It is a graph which shows the temperature gradient of R463A at the pressure in the condensation process.
  • R463A When R463A is used as the refrigerant circulating in the refrigeration cycle device, a curve showing the relationship between the position in the flow path of the condenser and the temperature of R463A and a straight line showing the relationship between the position and the temperature of air are combined. It is a figure which shows.
  • FIG. 1 is a functional block diagram showing the configuration of the refrigeration cycle device 100 according to the embodiment.
  • the refrigeration cycle device 100 includes a compressor 1, a condenser 2 (first heat exchanger), a receiver 11 (refrigerant container), an expansion valve 3, and an evaporator 4 (second heat exchanger).
  • a heat exchanger a fan 5 (blower), a fan 6, and a control device 10.
  • the refrigerant circulates in the order of the compressor 1, the condenser 2, the receiver 11, the expansion valve 3, and the evaporator 4.
  • the refrigeration cycle device 100 is filled with an amount of refrigerant such that a liquid refrigerant (liquid refrigerant) is stored in the receiver 11. Examples of the refrigerating cycle device 100 include a refrigerator, an air conditioner, or a showcase.
  • the condenser 2 has a port P1 (first port), a port P2 (second port), a port P3 (third port), and a port P4 (fourth port).
  • the flow path FP1 (first flow path) connecting the ports P1 and P2 is formed so as to meander
  • the flow path FP2 (second flow path) connecting the ports P3 and P4 is formed.
  • the volume of the flow path FP1 (the size of the region through which the refrigerant can pass) is larger than the volume of the flow path FP2.
  • the fan 5 passes in the order of ports P2 to P1 and forms an airflow Wd1 that passes in the order of ports P4 to P3.
  • the refrigerant passing through the condenser 2 and the air flow Wd1 form a countercurrent.
  • the airflow Wd1 intersects each of the flow paths FP1 and FP2 twice or more.
  • the airflow Wd1 is formed from the ports P2 to P1 along the respective flow paths FP1 and FP2, and is formed from the ports P4 to P3.
  • the fan 6 forms an air flow that passes through the evaporator 4.
  • the refrigerant from the port P2 and the refrigerant from the port P4 flow into the receiver 11.
  • the liquid refrigerant flows out from the receiver 11 to the expansion valve 3.
  • the control device 10 controls the drive frequency of the compressor 1 to control the amount of refrigerant discharged by the compressor 1 per unit time.
  • the control device 10 controls the drive frequency so that the evaporation temperature is in the range of ⁇ 40 ° C. to 0 ° C., for example.
  • the control device 10 controls the opening degree of the expansion valve 3 so that the degree of superheat of the refrigerant flowing out from the port P2 is within a desired range (for example, 5K to 10K).
  • the control device 10 controls the amount of air blown per unit time of each of the fans 5 and 6.
  • the control device 10 includes a processing circuit.
  • the processing circuit may be dedicated hardware or a CPU (Central Processing Unit) that executes a program stored in the memory.
  • the processing circuit is dedicated hardware, the processing circuit is, for example, a single circuit, a composite circuit, a programmed processor, a parallel programmed processor, an ASIC (Application Specific Integrated Circuit), an FPGA (Field Programmable Gate). Array), or a combination of these.
  • the processing circuit is a CPU
  • the function of the control device 10 is realized by software, firmware, or a combination of software and firmware.
  • Software or firmware is written as a program and stored in memory. The processing circuit reads and executes the program stored in the memory.
  • the memory includes a non-volatile or volatile semiconductor memory (for example, RAM (Random Access Memory), ROM (Read Only Memory), flash memory, EPROM (Erasable Programmable Read Only Memory), or EEPROM (Electrically Erasable Programmable Read Only Memory). ), And magnetic discs, flexible discs, optical discs, compact discs, mini discs, or DVDs (Digital Versatile Disc).
  • the CPU is also called a central processing unit, a processing unit, an arithmetic unit, a microprocessor, a microcomputer, a processor, or a DSP (Digital Signal Processor).
  • FIG. 2 is an external perspective view of the condenser 2 of FIG.
  • the condenser 2 includes a plurality of fins 21 and a plurality of heat transfer tubes 22 through which the refrigerant passes.
  • the plurality of fins 21 are juxtaposed at regular intervals.
  • a ventilation path through which the airflow Wd1 passes is formed between the two fins.
  • the plurality of heat transfer tubes 22 penetrate the plurality of fins 21 in the normal direction of the plurality of fins 21.
  • the flow paths FP1 and FP2 of FIG. 1 are formed from a plurality of heat transfer tubes 22.
  • the refrigerant in the condenser 2 The distribution is biased to the flow path FP1 having a large volume among the flow paths FP1 and FP2.
  • the header 20 described in FIG. 3 is not shown in FIG. 2 in order to make it easier to see the arrangement of the plurality of heat transfer tubes 22.
  • FIG. 3 is a plan view of the condenser 2 of FIG. 2 from the X-axis direction.
  • the header 20 extends along the gravity direction Gd (minus direction of the Z axis).
  • the refrigerant from the compressor 1 passes through the header 20 in the direction opposite to the gravity direction Gd.
  • a plurality of ports arranged along the gravity direction Gd are connected to the header 20.
  • the plurality of ports include ports P1 to P4 of FIG.
  • the position of port P3 is higher than the position of port P1.
  • the header 20 is a vertical header.
  • the refrigerant passing through the header 20 receives gravity in the direction of gravity.
  • the amount of refrigerant flowing into port P3 per unit time tends to be larger than the amount of refrigerant flowing into port P1 per unit time.
  • the refrigerant distribution in the condenser 2 tends to be biased toward the FP1 rather than the flow path FP2.
  • FIG. 4 is a diagram showing a specific flow of the air flow Wd1 of FIG.
  • the airflow Wd1 passes through the condenser 2 in the X-axis direction and then changes its traveling direction toward the fan 5 arranged at a position higher than the position of the condenser 2.
  • the fan 5 is a top flow type fan.
  • the wind speed distribution is biased, and the higher the position in the condenser 2, the higher the wind speed.
  • the lower the position of the flow path formed in the condenser 2 the smaller the heat exchange efficiency in the flow path.
  • the heat exchange efficiency of the flow path FP1 is smaller than the heat exchange efficiency of the flow path FP2.
  • the cooling in the flow path FP1 becomes insufficient, and the refrigerant in a gas-liquid two-phase state tends to flow out from the flow path FP1.
  • FIG. 5 shows a curve R11 showing the relationship between the position in the flow path FP1 and the temperature of R407 when the azeotropic mixed refrigerant R407C is used as the refrigerant circulating in the refrigeration cycle device 100, and the curve R11 showing the relationship between the position and the air. It is also a figure which also shows the curve A11 which shows the relationship with temperature. As shown in FIG. 5, the temperature of R407C and the temperature of air decrease linearly as the position in the flow path FP1 approaches from port P1 to P2. When the state of R407C at the port P2 is a gas-liquid two-phase state, the heat exchange efficiency of the condenser 2 is lowered and the performance of the refrigeration cycle device 100 is lowered.
  • a temperature gradient (relationship between the dryness of the refrigerant and the temperature of the refrigerant) is set in the pressure of the refrigerant in the condenser 2.
  • a refrigerant represented as an upwardly convex monotonous increase curve is used in the refrigeration cycle device 100.
  • the refrigerant include R463A, which is a non-azeotropic mixed refrigerant.
  • R463A contains R32, R125, R134a, R1234yf, and carbon dioxide (CO2).
  • the number of types of the refrigerant contained in R463A is 5.
  • the composition ratio (mass ratio) of R32 is 36 wt%.
  • the composition ratio of R125 is 30 wt%.
  • the composition ratio of R134a is 14 wt%.
  • the composition ratio of R1234yf is 14 wt%.
  • the composition ratio of carbon dioxide is 6 wt%.
  • the refrigerant having the lowest boiling point is carbon dioxide.
  • the composition ratio of carbon dioxide in R463A is smaller than 20 wt% (0.2), which is the value obtained by dividing 100 wt% (1) by the number of types of refrigerant contained in R463A.
  • FIG. 6 is a graph showing the temperature gradient of R463A at the pressure in the condensation process.
  • the pressure is 2.305 MPa.
  • the temperature gradient of R463A is drawn on a coordinate plane having a horizontal axis representing the dryness of R463A and a vertical axis representing the temperature of R463A.
  • the temperature gradient of R463A is represented as an upwardly convex monotonically increasing curve in the coordinate plane.
  • the slope of the temperature gradient of R463A is steep in the range where the dryness is relatively low, and gentle in the range where the dryness is relatively high.
  • FIG. 7 shows a curve R1 showing the relationship between the position in the flow path FP1 and the temperature of R463A when R463A is used as the refrigerant circulating in the refrigeration cycle device 100, and the relationship between the position and the temperature of air. It is a figure which also shows the curve A1.
  • the ports P1 and P2 in the flow path FP1 are the start point and the end point of the condensation process, respectively, as the position in the flow path FP1 approaches P1 from the port P2, the R463A flowing through the flow path FP1 The degree of dryness increases. Since the curve R1 shows the relationship between the dryness of R463A and the temperature in the condensation process, it is expressed as an upwardly convex monotonically increasing curve similar to the curve shown in FIG.
  • the slope of the curve R1 near the port P1 is smaller and gentler than the slope of the curve A1 near the port P1.
  • the temperature difference between the air and R463A increases.
  • the temperature of R463A sharply decreases near the port P2 in the process of approaching the port P1 to the P2 in the flow path FP1. Therefore, R463A can be sufficiently cooled by air near the port P2. As a result, it is possible to suppress the state of R463A flowing out from the condenser 2 from becoming a gas-liquid two-phase state, so that it is possible to suppress a decrease in the heat exchange efficiency of the condenser 2.
  • the absolute value of the temperature difference is preferably a reference value (for example, 10K) or less. The reference value can be appropriately calculated by an actual machine experiment or a simulation.
  • the non-azeotropic mixed refrigerant expressed as a monotonically increasing curve in which the temperature gradient is convex upward is not limited to R463A.
  • the features common to the non-co-boiling mixed refrigerants are that they contain at least three types of refrigerants having different boiling points from each other, and that the mass of the refrigerant having the lowest boiling point among the refrigerants contained in the non-co-boiling mixed refrigerant is the non-co-boiling. It can be mentioned that the value divided by the mass of the mixed refrigerant is smaller than the value obtained by dividing 1 by the number of types of the refrigerant contained in the non-coboiling mixed refrigerant.
  • the non-azeotropic mixed refrigerant contains carbon dioxide.
  • the boiling point of carbon dioxide (-78.5 ° C.) is often extremely lower than the boiling point of other refrigerants contained in the non-azeotropic mixed refrigerant. Since the non-co-boiling mixed refrigerant, which is expressed as a monotonically increasing curve in which the temperature gradient is convex upward, contains carbon dioxide, the slope of the temperature gradient becomes steep in a range where the dryness is relatively low, and the dryness is relatively high. The characteristic that the slope of the temperature gradient becomes gentle in the range becomes remarkable.
  • the absolute value of the temperature difference between the boiling point (-51.7 ° C.) of R32 (50 wt%) and the boiling point (-48.1 ° C.) of R125 (50 wt%) contained in R410A, which is a pseudo azeotropic mixed refrigerant, is 3. It is .6K. That is, it is treated that the boiling point of R32 and the boiling point of R125 are equal. Therefore, in the present specification, "the boiling points are different" means that the absolute value of the temperature difference between the boiling points of the two refrigerants is larger than 3.6K.

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  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Compression-Type Refrigeration Machines With Reversible Cycles (AREA)
PCT/JP2019/039966 2019-10-10 2019-10-10 冷凍サイクル装置 Ceased WO2021070314A1 (ja)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP4671641A1 (en) * 2024-06-21 2025-12-31 Vertiv Corporation LIQUID VALVE CONDENSER COLLECTOR

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH1019416A (ja) * 1996-07-03 1998-01-23 Toshiba Corp 熱交換器
WO2013160954A1 (ja) * 2012-04-26 2013-10-31 三菱電機株式会社 熱交換器及びこの熱交換器を備えた冷凍サイクル装置
WO2018155513A1 (ja) * 2017-02-27 2018-08-30 三菱重工サーマルシステムズ株式会社 組成異常検知装置及び組成異常検知方法
WO2019021364A1 (ja) * 2017-07-25 2019-01-31 三菱電機株式会社 冷凍装置及び冷凍装置の運転方法
WO2019073596A1 (ja) * 2017-10-13 2019-04-18 三菱電機株式会社 冷凍サイクル装置および組成調節装置
JP2019512031A (ja) * 2016-02-29 2019-05-09 ザ ケマーズ カンパニー エフシー リミテッド ライアビリティ カンパニー ジフルオロメタン、ペンタフルオロエタン、テトラフルオロエタン、テトラフルオロプロペン、及び二酸化炭素を含む冷媒混合物、並びにその使用
WO2019150852A1 (ja) * 2018-01-31 2019-08-08 ダイキン工業株式会社 熱交換器又は熱交換器を有する冷凍装置

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH1019416A (ja) * 1996-07-03 1998-01-23 Toshiba Corp 熱交換器
WO2013160954A1 (ja) * 2012-04-26 2013-10-31 三菱電機株式会社 熱交換器及びこの熱交換器を備えた冷凍サイクル装置
JP2019512031A (ja) * 2016-02-29 2019-05-09 ザ ケマーズ カンパニー エフシー リミテッド ライアビリティ カンパニー ジフルオロメタン、ペンタフルオロエタン、テトラフルオロエタン、テトラフルオロプロペン、及び二酸化炭素を含む冷媒混合物、並びにその使用
WO2018155513A1 (ja) * 2017-02-27 2018-08-30 三菱重工サーマルシステムズ株式会社 組成異常検知装置及び組成異常検知方法
WO2019021364A1 (ja) * 2017-07-25 2019-01-31 三菱電機株式会社 冷凍装置及び冷凍装置の運転方法
WO2019073596A1 (ja) * 2017-10-13 2019-04-18 三菱電機株式会社 冷凍サイクル装置および組成調節装置
WO2019150852A1 (ja) * 2018-01-31 2019-08-08 ダイキン工業株式会社 熱交換器又は熱交換器を有する冷凍装置

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP4671641A1 (en) * 2024-06-21 2025-12-31 Vertiv Corporation LIQUID VALVE CONDENSER COLLECTOR

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