WO2021033571A1 - カバー部材及びこれを備える部材供給アセンブリ - Google Patents

カバー部材及びこれを備える部材供給アセンブリ Download PDF

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Publication number
WO2021033571A1
WO2021033571A1 PCT/JP2020/030270 JP2020030270W WO2021033571A1 WO 2021033571 A1 WO2021033571 A1 WO 2021033571A1 JP 2020030270 W JP2020030270 W JP 2020030270W WO 2021033571 A1 WO2021033571 A1 WO 2021033571A1
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Prior art keywords
cover member
base material
film
protective film
material layer
Prior art date
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PCT/JP2020/030270
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English (en)
French (fr)
Inventor
陽輔 菅谷
裕貴 木上
Original Assignee
日東電工株式会社
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Publication date
Application filed by 日東電工株式会社 filed Critical 日東電工株式会社
Priority to DE112020003876.9T priority Critical patent/DE112020003876T5/de
Priority to CN202080005478.7A priority patent/CN112789226A/zh
Priority to US17/632,676 priority patent/US20220348393A1/en
Priority to CN202211031070.4A priority patent/CN115367303A/zh
Priority to JP2020568575A priority patent/JP6845974B1/ja
Priority to KR1020207037732A priority patent/KR102335705B1/ko
Publication of WO2021033571A1 publication Critical patent/WO2021033571A1/ja

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    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2266/00Composition of foam
    • B32B2266/02Organic
    • B32B2266/0214Materials belonging to B32B27/00
    • B32B2266/0264Polyester
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2266/00Composition of foam
    • B32B2266/02Organic
    • B32B2266/0214Materials belonging to B32B27/00
    • B32B2266/0278Polyurethane
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2266/00Composition of foam
    • B32B2266/08Closed cell foam
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/724Permeability to gases, adsorption
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2435/00Closures, end caps, stoppers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2435/00Closures, end caps, stoppers
    • B32B2435/02Closures, end caps, stoppers for containers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D2585/00Containers, packaging elements or packages specially adapted for particular articles or materials
    • B65D2585/68Containers, packaging elements or packages specially adapted for particular articles or materials for machines, engines, or vehicles in assembled or dismantled form
    • B65D2585/86Containers, packaging elements or packages specially adapted for particular articles or materials for machines, engines, or vehicles in assembled or dismantled form for electrical components
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65HHANDLING THIN OR FILAMENTARY MATERIAL, e.g. SHEETS, WEBS, CABLES
    • B65H18/00Winding webs
    • B65H18/28Wound package of webs
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65HHANDLING THIN OR FILAMENTARY MATERIAL, e.g. SHEETS, WEBS, CABLES
    • B65H2701/00Handled material; Storage means
    • B65H2701/10Handled articles or webs
    • B65H2701/18Form of handled article or web
    • B65H2701/184Wound packages
    • B65H2701/1842Wound packages of webs
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65HHANDLING THIN OR FILAMENTARY MATERIAL, e.g. SHEETS, WEBS, CABLES
    • B65H2701/00Handled material; Storage means
    • B65H2701/10Handled articles or webs
    • B65H2701/19Specific article or web
    • B65H2701/1944Wrapping or packing material
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00Additional features of adhesives in the form of films or foils
    • C09J2301/10Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet
    • C09J2301/12Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers
    • C09J2301/124Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers the adhesive layer being present on both sides of the carrier, e.g. double-sided adhesive tape
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2423/00Presence of polyolefin
    • C09J2423/04Presence of homo or copolymers of ethene
    • C09J2423/046Presence of homo or copolymers of ethene in the substrate
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2433/00Presence of (meth)acrylic polymer
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2467/00Presence of polyester
    • C09J2467/006Presence of polyester in the substrate

Definitions

  • the present invention relates to a cover member arranged on the surface of an object having a surface having an opening to prevent the passage of foreign matter in the opening, and a member supply assembly for supplying the member.
  • Patent Document 1 describes a waterproof breathable membrane, a first double-sided adhesive tape bonded to the peripheral edge of the surface of the waterproof breathable membrane, and a first surface bonded to the peripheral edge of the surface of the waterproof breathable membrane opposite to the surface.
  • a waterproof ventilation member comprising a two-sided adhesive tape and the base material of the first double-sided adhesive tape being a foam.
  • the cover member is usually supplied in a state of being arranged on a member supply sheet such as a liner sheet.
  • the cover member supplied in this state is placed on the surface of the object after being peeled from the sheet.
  • the most distant layers are, for example, protective films and tab films.
  • the cover member from the sheet is low, the force for lifting the cover member is concentrated and the protective film may be damaged. Breakage is particularly likely to occur in cover members with a protective film that is highly breathable in the thickness direction.
  • An object of the present invention is to provide a cover member having excellent peelability from a sheet for supplying a member.
  • the present invention A cover member that is arranged on the surface of an object having a surface having an opening to prevent foreign matter from passing through the opening.
  • a protective film having a shape that covers the opening when the cover member is arranged on the surface,
  • a first base material layer bonded to one main surface of the protective film is provided.
  • the first base material layer has a laminated structure including two or more base material films, and is located between the protective film and the surface when the cover member is arranged on the surface.
  • the two or more base films are cover members including a non-foaming film and a foaming film. I will provide a.
  • the present invention A sheet for supplying members and a cover member arranged on the sheet are provided.
  • the cover member is the cover member of the present invention.
  • a first base material layer having a laminated structure of two or more base material films including a non-foamed film and a foamed film is bonded to a protective film.
  • the first substrate layer is located between the protective film and the surface when placed on the surface of the object.
  • the cover member supplied by the member supply sheet such as the liner sheet is usually arranged so that the side in contact with the sheet is in contact with the surface of the object. Therefore, the first base material layer is located on the sheet side when supplied by the sheet.
  • the cover member of the present invention is relatively rigid, and is relatively flexible with a non-foamed film capable of efficiently transmitting the above force to the cover member as a force for peeling the member while preventing excessive deformation.
  • the first base material layer is provided with a foamed film that allows appropriate deformation of the first base material layer located on the sheet side.
  • the cover member of the present invention has a structure suitable for improving the peelability from the sheet for supplying the member.
  • FIG. 1A is a cross-sectional view schematically showing an example of the cover member of the present invention.
  • FIG. 1B is a plan view of the cover member of FIG. 1A as viewed from the side of the protective film.
  • FIG. 2 is a cross-sectional view schematically showing another example of the cover member of the present invention.
  • FIG. 3 is a cross-sectional view schematically showing another example of the cover member of the present invention.
  • FIG. 4 is a cross-sectional view schematically showing still another example of the cover member of the present invention.
  • FIG. 5 is a cross-sectional view schematically showing another example of the cover member of the present invention.
  • FIG. 6A is a cross-sectional view schematically showing another example of the cover member of the present invention.
  • FIG. 1B is a plan view of the cover member of FIG. 1A as viewed from the side of the protective film.
  • FIG. 2 is a cross-sectional view schematically showing another example of the cover member of the present invention.
  • FIG. 6B is a plan view of the cover member of FIG. 6A as viewed from the side of the second base material layer.
  • FIG. 7 is a cross-sectional view schematically showing another example of the cover member of the present invention.
  • FIG. 8A is a cross-sectional view schematically showing another example of the cover member of the present invention.
  • FIG. 8B is a plan view of the cover member of FIG. 8A as viewed from the tab film side.
  • FIG. 9 is a schematic view showing an example of arrangement of the cover member of the present invention on an object.
  • FIG. 10 is a schematic view showing another example of arrangement of the cover member of the present invention on an object.
  • FIG. 11 is a plan view schematically showing an example of the member supply assembly of the present invention.
  • FIG. 12 is a cross-sectional view schematically showing an example of the arrangement of the cover member of the present invention with respect to the sheet for supplying the member.
  • FIG. 13 is a cross-sectional view schematically showing another example of the arrangement of the cover member of the present invention with respect to the sheet for supplying the member.
  • FIGS. 1A and 1B An example of the cover member of the present invention is shown in FIGS. 1A and 1B.
  • FIG. 1B is a plan view of the cover member 1 (1A) of FIG. 1A as viewed from the side of the protective film 2.
  • FIG. 1A shows a cross section AA of FIG. 1B.
  • the cover member 1A is a member arranged on the surface 53 of the object 51 having the surface 53 having the opening 52 to prevent the passage of foreign matter in the opening 52.
  • 1A and 1B show a cover member 1A arranged on the surface 53 of the object 51.
  • the cover member 1A includes a protective film 2 and a first base material layer 3 bonded to one main surface of the protective film 2.
  • the cover member 1A is composed of a laminate including the protective film 2 and the first base material layer 3.
  • the protective film 2 has a shape that covers the opening 52 when the cover member 1A is arranged on the surface 53.
  • the first base material layer 3 is located between the protective film 2 and the surface 53 when the cover member 1A is arranged on the surface 53.
  • the first base material layer 3 has a laminated structure including two base material films 11.
  • the first base material layer 3 includes, as the base film 11, a non-foamed film 11A made of a non-foamed material and a foamed film 11B made of a foamed material.
  • the foamed film 11B is located farther from the protective film 2 than the non-foamed film 11A.
  • the cover member 1A is peeled off, the deformation of the first base material layer 3 by the foamed film 11B becomes more appropriate, and the peelability of the cover member 1A can be improved.
  • the base film 11 located at the position farthest from the protective film 2 in the first base material layer 3 is the foamed film 11B. In this form, the improvement of the peelability based on the above-mentioned appropriate deformation becomes more certain.
  • the laminated structure of the first base material layer 3 is not limited to the above example as long as the non-foaming film 11A and the foamed film 11B are included as the two or more base film 11.
  • the first base material layer 3 may include two or more non-foaming films 11A and / or two or more foamed films 11B.
  • FIG. 2 shows a modified example in which the structure of the first base material layer 3 is different.
  • the cover member 1A of FIG. 2 has the same configuration as the cover member 1A of FIGS. 1A and 1B except that the configuration of the first base material layer 3 is different.
  • the first base material layer 3 of FIG. 2 includes two non-foaming films 11A and 11C and one foamed film 11B as the base film 11.
  • the non-foamed films 11A and 11C and the foamed film 11B are laminated in this order.
  • the foamed film 11B is located farther from the protective film 2 than the non-foamed films 11A and 11C.
  • the base film 11 located at the position farthest from the protective film 2 in the first base material layer 3 is the foamed film 11B.
  • the base film 11 may be bonded to each other by an adhesive or an adhesive, or may be bonded to each other by various welding methods such as ultrasonic welding and heat welding.
  • the pressure-sensitive adhesive that bonds the base film 11 to each other may be in a layered form (adhesive layer). In this form, the flexibility of the pressure-sensitive adhesive layer can contribute to the improvement of peelability.
  • the pressure-sensitive adhesive layer may be a base-less double-sided pressure-sensitive adhesive tape.
  • adhesives are acrylic adhesives, silicone adhesives, urethane adhesives, epoxy adhesives and rubber adhesives.
  • acrylic pressure-sensitive adhesive or a silicone-based pressure-sensitive adhesive having excellent heat resistance, particularly a silicone-based pressure-sensitive adhesive is preferable to select an acrylic pressure-sensitive adhesive or a silicone-based pressure-sensitive adhesive having excellent heat resistance, particularly a silicone-based pressure-sensitive adhesive.
  • the base material and the single-sided adhesive tape or double-sided adhesive tape obtained by applying the adhesive on one or both sides of the base material may be used as the base film 11 and the pressure-sensitive adhesive layer.
  • An example of using the double-sided adhesive tape is shown in FIGS. 3 and 4.
  • the foamed film 11B is the base material of the double-sided adhesive tape 13.
  • the foamed film 11B and the non-foamed film 11A are joined by the pressure-sensitive adhesive layer 12A of the double-sided adhesive tape 13.
  • the cover member 1A of FIG. 3 is arranged on the surface 53 via the adhesive layer 12B of the double-sided adhesive tape 13.
  • the cover member 1A of FIG. 3 has the same configuration as the cover member 1A of FIGS. 1A and 1B except for these points.
  • the foamed film 11B is the base material of the double-sided adhesive tape 13.
  • the foamed film 11B and the non-foamed film 11C are joined by the pressure-sensitive adhesive layer 12A of the double-sided adhesive tape 13.
  • the non-foamed film 11A is the base material of the double-sided adhesive tape 15.
  • the non-foaming film 11C and the non-foaming film 11A are joined by the pressure-sensitive adhesive layer 14B of the double-sided adhesive tape 15.
  • the protective film 2 and the first base material layer 3 are bonded by an adhesive layer 14A of the double-sided adhesive tape 15.
  • the cover member 1A of FIG. 4 is arranged on the surface 53 via the adhesive layer 12B of the double-sided adhesive tape 13.
  • the cover member 1A of FIG. 4 has the same configuration as the cover member 1A of FIG. 2 except for these points.
  • the protective film 2 and the first base material layer 3 may be bonded by an adhesive or an adhesive, or may be bonded by the above-mentioned various welding methods.
  • the protective film 2 and the first base material layer 3 may be bonded by an adhesive layer 17 (see FIG. 5).
  • the flexibility of the pressure-sensitive adhesive layer can contribute to the improvement of peelability.
  • Examples of the pressure-sensitive adhesive and the pressure-sensitive adhesive layer are as described above.
  • the pressure-sensitive adhesive layer for joining the protective film 2 and the first base material layer 3 is a pressure-sensitive adhesive layer of a single-sided adhesive tape or a double-sided pressure-sensitive adhesive tape using the base material film 11 as a base material (for example, the pressure-sensitive adhesive layer 14A in FIG. 4). It may be.
  • the cover member 1A may be arranged on the surface 53 via the adhesive layer 16 included in the cover member 1A (see FIG. 5).
  • Examples of the pressure-sensitive adhesive layer are as described above.
  • the pressure-sensitive adhesive layer 16 may be a pressure-sensitive adhesive layer of a single-sided pressure-sensitive adhesive tape or a double-sided pressure-sensitive adhesive tape using the base film 11 as a base material (for example, the pressure-sensitive adhesive layer 12B in FIGS. 3 and 4).
  • the shape of the cover member 1A is rectangular when viewed perpendicular to the main surface of the protective film 2.
  • the shape of the cover member 1 is not limited to this example.
  • the shape of the cover member 1 may be a polygon including squares and rectangles, a circle, and an ellipse when viewed perpendicular to the main surface of the protective film 2.
  • the corners of the polygon may be rounded (see FIG. 1B).
  • the first base material layer 3 of the cover member 1A has an outer circumference that coincides with the outer circumference of the protective film 2 when viewed perpendicularly to the main surface of the protective film 2. Further, the first base material layer 3 of the cover member 1A has a shape (frame shape) corresponding to the peripheral edge portion of the protective film 2 when viewed perpendicularly to the main surface of the protective film 2. The surface of the protective film 2 on the side of the first base material layer 3 is exposed in a region where the first base material layer 3 is not in contact. When the protective film 2 has air permeability in the thickness direction, the region can be used as the air permeability region of the cover member 1A. However, the shape of the first base material layer 3 is not limited to the above example.
  • the area of the ventilation region in the cover member 1 is, for example, 40 mm 2 or less.
  • the cover member 1 having an area of the ventilation region within the range is suitable for arrangement on an object having an opening having a small diameter, for example.
  • the lower limit of the area of the ventilation region is, for example, 0.008 mm 2 or more.
  • the area of the ventilation region may be a larger range depending on the type of the object on which the cover member 1 is arranged.
  • the thickness of the first base material layer 3 may be, for example, 50 to 1000 ⁇ m, 70 to 800 ⁇ m, and further 130 to 600 ⁇ m.
  • the foamed film 11B has closed cells. Therefore, the foamed film 11B can maintain its flexibility by suppressing the impregnation of the pressure-sensitive adhesive into the film even when the pressure-sensitive adhesive layer is provided on the surface, for example.
  • Examples of materials constituting the foamed film 11B are polyolefins such as polyethylene (PE) and polypropylene (PP), silicone resins, acrylic resins, and polyurethanes.
  • the material constituting the foamed film 11B is not limited to the above example.
  • the foamed film 11B does not have to have adhesiveness.
  • the non-foamed films 11A and 11C do not have closed cells.
  • the non-foamed films 11A and 11C may have air permeability in the thickness direction.
  • Examples of the non-foamed films 11A and 11C are metal films, resin films, non-woven fabrics, woven fabrics and papers.
  • the non-foamed films 11A and 11C are preferably resin films.
  • Examples of resins that can form the non-foamed films 11A and 11C are polyolefins such as PE and PP, polyesters such as polyethylene terephthalate (PET), silicone resins, polycarbonates, polyimides, polyamideimides, polyphenylene sulfides, and polyetheretherketones (PEEK). ), Polyvinyl chloride, and fluororesin.
  • Examples of fluororesins include polytetrafluoroethylene (PTFE), tetrafluoroethylene-perfluoroalkyl vinyl ether copolymer (PFA), tetrafluoroethylene-hexafluoropropylene copolymer (FEP), and tetrafluoroethylene-ethylene copolymer. It is coalescence (ETFE).
  • the resin is not limited to the above example.
  • Examples of metals that can form the non-foamed films 11A and 11C are stainless steel and aluminum. However, the metal is not limited to the above example.
  • the non-foamed films 11A and 11C do not have to have adhesiveness.
  • the foamed film 11B and the non-foamed films 11A and 11C may have the same shape when viewed perpendicular to the first base material layer 3. Further, in the first base material layer 3, the outer circumferences of the base material films 11 may coincide with each other.
  • the thickness of the base film 11 is, for example, 10 to 250 ⁇ m.
  • the base film 11, particularly the non-foamed films 11A and 11C, may have higher strength than the protective film 2. In this case, damage to the protective film 2 at the time of peeling can be suppressed.
  • the strength can be evaluated as, for example, tensile breaking strength or cohesive breaking strength.
  • the protective film 2 may be non-breathable in the thickness direction or may have breathability in the thickness direction.
  • the arrangement of the cover member 1 can ensure air permeability through the opening of the object while preventing the passage of foreign matter. By ensuring ventilation, for example, it is possible to adjust the pressure through the opening and mitigate the fluctuation of the pressure.
  • the air permeability (air permeability in the thickness direction) of the protective film 2 having air permeability in the thickness direction is measured by the air permeability specified in Japanese Industrial Standards (former Japanese Industrial Standards; hereinafter referred to as "JIS") L1096. Displayed by the air permeability (hereinafter referred to as "Garley air permeability”) obtained in accordance with the B method (Garley type method), for example, it is less than 10,000 seconds / 100 mL.
  • Garley air permeability is 5000 seconds / 100 mL or less, 1000 seconds / 100 mL or less, 500 seconds / 100 mL or less, 100 seconds / 100 mL or less, 50 seconds / 100 mL or less, 10 seconds / 100 mL or less, and further 5 seconds / 100 mL or less. You may.
  • the lower limit of Garley air permeability is, for example, 0.2 seconds / 100 mL or more.
  • the air permeability of the protective film 2 that is non-breathable in the thickness direction is, for example, 10,000 seconds / 100 mL or more, expressed by the Garley air permeability.
  • Examples of materials constituting the protective film 2 are metals, resins, and composite materials thereof.
  • the examples of the resin and metal that can form the protective film 2 are the same as the examples of the resin and metal that can form the base film 11.
  • the resin constituting the protective film 2 may be PTFE.
  • the resin and the metal are not limited to the above examples.
  • the protective film 2 having air permeability in the thickness direction may include a stretched porous film.
  • the stretched porous membrane may be a fluororesin stretched porous membrane, particularly a PTFE stretched porous membrane.
  • the PTFE-stretched porous membrane is usually formed by stretching a paste extruded or cast membrane containing PTFE particles.
  • the PTFE stretched porous membrane is composed of fine fibrils of PTFE, and may have nodes in which PTFE is in an aggregated state as compared with fibrils. According to the PTFE stretched porous membrane, it is possible to achieve both the performance of preventing the invasion of foreign substances and the air permeability at a high level.
  • a known stretched porous film can be used as the protective film 2.
  • the protective film 2 having air permeability in the thickness direction may include a perforated film in which a plurality of through holes connecting both main surfaces are formed.
  • the perforated membrane may be a membrane having a non-porous substrate structure, for example, a non-porous membrane in which a plurality of through holes are provided.
  • the perforated membrane may not have a ventilation path in the thickness direction other than the plurality of through holes.
  • the through hole may extend in the thickness direction of the perforation membrane, or may be a straight hole extending linearly in the thickness direction.
  • the shape of the through-hole opening may be circular or elliptical when viewed perpendicular to the main surface of the perforated membrane.
  • the perforated membrane can be formed, for example, by laser processing the raw film, or by drilling by ion beam irradiation and subsequent chemical etching.
  • the protective film 2 having breathability in the thickness direction may include a non-woven fabric, a woven fabric, a mesh, and a net.
  • the protective film 2 may have a single-layer structure or a multilayer structure composed of two or more different layers.
  • An example of the protective film 2 having a multi-layer structure has a laminated structure of a PTFE-stretched porous film and a non-woven fabric.
  • the protective film 2 is not limited to the above example.
  • the shape of the protective film 2 of the cover member 1A is rectangular when viewed perpendicular to the main surface of the protective film 2.
  • the shape of the protective film 2 is not limited to the above example, and may be, for example, a polygon including a square and a rectangle, a circle, and an ellipse when viewed perpendicular to the main surface of the protective film 2.
  • the corners of the polygon may be rounded.
  • the thickness of the protective film 2 is, for example, 1 to 100 ⁇ m.
  • the cohesive force of the protective film 2 may be 2.0 N / 20 mm or less.
  • the cohesive force of the protective film 2 having high air permeability in the thickness direction tends to be low. Therefore, the conventional cover member provided with the protective film 2 having high air permeability in the thickness direction tends to damage the protective film 2 at the time of peeling.
  • the present invention is particularly advantageous when the cover member 1 includes a protective film 2 having high air permeability in the thickness direction.
  • the cohesive force of the protective film 2 may be 1.8 N / 20 mm or less, and further may be 1.5 N / 20 mm or less.
  • the protective film 2 having high air permeability in the thickness direction has an air permeability of 100 seconds / 100 mL or less, which is indicated by, for example, Garley air permeability.
  • the cohesive force of the protective film 2 can be measured by the method shown below with reference to the method for measuring the 180 ° peeling adhesive force defined in JIS Z0237: 2009.
  • the protective film 2 to be measured is cut out into a rectangle (length 100 mm ⁇ width 20 mm).
  • two double-sided adhesive tapes manufactured by Nitto Denko, No. 5610) having the same shape as the protective film 2 are prepared. Each double-sided adhesive tape is attached to one surface and the other surface of the protective film 2 with their outer circumferences aligned with each other.
  • two rectangular PET films (thickness 25 ⁇ m) having a length of 150 mm and a width of 20 mm are prepared. Each PET film is attached to one side and the other side of the protective film 2 by the double-sided adhesive tape.
  • both ends in the width direction of each PET film coincide with both ends in the width direction of the protective film 2, and both ends in the longitudinal direction of each PET film are perpendicular to the main surface of the PET film. As you can see, it is carried out so as not to overlap with the protective film 2 and the double-sided adhesive tape. However, as the length (longitudinal direction) of the free end portion of each PET film, a length (for example, 25 mm) at which the chuck of the tensile tester can stably grasp the PET film is secured.
  • the crimping roller with a load of 19.6 N is reciprocated once so that the crimping force is applied in the thickness direction of the laminated body of the PET film / double-sided adhesive tape / protective film 2 / double-sided adhesive tape / PET film. Then, leave it for at least 30 minutes before starting the tensile test to prepare a test piece.
  • a tensile tester for example, a desktop precision universal tester Autograph AGS-X manufactured by Shimadzu Corporation
  • the free end of one PET film at one end in the longitudinal direction of the test piece is fixed to the upper chuck of the tensile tester.
  • the free end of the other PET film at the other end in the longitudinal direction of the test piece is attached to the lower chuck.
  • the area of the protective film 2 is, for example, 175 mm 2 or less.
  • the cover member 1 in which the area of the protective film 2 is within the range is suitable for arrangement on an object having an opening having a small diameter, for example.
  • the lower limit of the area of the protective film 2 is, for example, 0.20 mm 2 or more.
  • the area of the protective film 2 may be a larger value depending on the type of the object on which the cover member 1 is arranged.
  • the area of the cover member 1 is, for example, 175 mm 2 or less.
  • the cover member 1 having an area within the range is suitable for placement on an object having an opening having a small diameter, for example.
  • the lower limit of the area of the cover member 1 is, for example, 0.20 mm 2 or more.
  • the area of the cover member 1 may be a larger value depending on the type of the object to be arranged. The smaller the area of the cover member 1, the more difficult it is to peel it off from the member supply sheet. Therefore, when the area of the cover member 1 is within the above range, the effect of the present invention becomes particularly remarkable.
  • the cover member 1 may include any layer and / or member other than those described above as long as the effects of the present invention can be obtained.
  • FIG. 6B is a plan view of the cover member 1 (1B) of FIG. 6A as viewed from the side of the second base material layer 4.
  • FIG. 6A shows a cross section AA of FIG. 6B.
  • 6A and 6B show the cover member 1B arranged on the surface 53 of the object 51.
  • the cover member 1B has the same configuration as the cover member 1A except that it further includes a second base material layer 4 including one or more base film 18.
  • the second base material layer 4 is joined to the other main surface of the protective film 2 and sandwiches the protective film 2 together with the first base material layer 3. In this form, damage to the protective film 2 at the time of peeling can be more reliably suppressed. Further, when the cover member 1 includes the tab film 5 described later, damage to the protective film 2 when the tab film 5 is peeled off can be suppressed.
  • the second base material layer 4 may include only the non-foaming film 18A composed of the non-foaming material as the base film 18.
  • the composition of the base film 18 and the non-foaming film 18A may be the same as the composition of the base film 11 and the non-foaming film 11A, respectively.
  • the configurations of the substrate films 11 and 18 closest to the protective film 2 in each of the first substrate layer 3 and the second substrate layer 4 may be the same. In this form, damage to the protective film 2 can be suppressed more reliably.
  • the second base material layer 4 may include two or more base material films 18.
  • the two or more base film 18s may have the same shape when viewed perpendicular to the second base material layer 4. Further, the outer circumferences of the two or more base film 18s may coincide with each other in the second base material layer 4. Two or more substrate films 18 are usually bonded to each other.
  • the joining method of the base film 18 may be the same as the joining method of the base film 11.
  • a single-sided adhesive tape or a double-sided adhesive tape obtained by applying an adhesive to one or both sides of the base material may be used as the base film 18 and the pressure-sensitive adhesive layer.
  • An example of using the double-sided adhesive tape is shown in FIG.
  • the second base material layer 4 of FIG. 7 includes two non-foaming films 18A and 18B as the base film 18.
  • the non-foamed film 18A is the base material of the double-sided adhesive tape 20.
  • the non-foaming film 18A and the non-foaming film 18B are joined by an adhesive layer 19A of the double-sided adhesive tape 20.
  • the protective film 2 and the second base material layer 4 are bonded by an adhesive layer 19B of the double-sided adhesive tape 20.
  • the cover member 1B of FIG. 7 has the same configuration as the cover member 1B of FIGS. 6A and 6B except for these points.
  • the protective film 2 and the second base material layer 4 may be bonded by an adhesive or an adhesive, or may be bonded by the above-mentioned various welding methods.
  • the protective film 2 and the second base material layer 4 may be bonded by an adhesive layer.
  • Examples of the pressure-sensitive adhesive and the pressure-sensitive adhesive layer are as described above.
  • the pressure-sensitive adhesive layer for joining the protective film 2 and the second base material layer 4 is a pressure-sensitive adhesive layer of a single-sided pressure-sensitive adhesive tape or a double-sided pressure-sensitive adhesive tape using the base material film 18 as a base material (for example, the pressure-sensitive adhesive layer of FIG. 7). 19B) may be used.
  • the second base material layer 4 of the cover member 1B has an outer circumference that coincides with the outer circumference of the protective film 2 when viewed perpendicularly to the main surface of the protective film 2. Further, the second base material layer 4 of the cover member 1B has a shape (frame shape) corresponding to the peripheral edge portion of the protective film 2 when viewed perpendicularly to the main surface of the protective film 2. The surface of the protective film 2 on the side of the second base material layer 4 is exposed in the region where the second base material layer 4 is not in contact. When the protective film 2 has air permeability in the thickness direction, the region can be used as the air permeability region of the cover member 1. However, the shape of the second base material layer 4 is not limited to the above example.
  • the thickness of the second base material layer 4 is, for example, 10 to 700 ⁇ m, and may be 30 to 300 ⁇ m.
  • FIGS. 8A and 8B An example different from the above of the cover member of the present invention is shown in FIGS. 8A and 8B.
  • FIG. 8B is a plan view of the cover member 1 (1C) of FIG. 8A as viewed from the side of the tab film 5.
  • FIG. 8A shows a cross section AA of FIG. 8B.
  • 8A and 8B show the cover member 1C in a state of being arranged on the surface 53 of the object 51.
  • the cover member 1C has the same configuration as the cover member 1B except that the tab film 5 is further provided.
  • the tab film 5 is arranged on the outermost layer of the cover member 1.
  • the outermost layer is at the position farthest from the surface 53 when the cover member 1 is arranged on the surface 53.
  • the outermost layer of the example of FIGS. 8A and 8B is the base film 18 (18B) included in the second base material layer 4.
  • the tab film 5 has a tab 21 that protrudes outward from the outer periphery of the outermost layer when viewed perpendicularly to the main surface of the outermost layer.
  • the shape of the tab 21 of FIGS. 8A and 8B is rectangular when viewed perpendicular to the main surface of the tab film 5.
  • the shape of the tab 21 is not limited to this example.
  • the outside means the direction away from the center of the cover member 1 when viewed perpendicular to the main surface of the protective film 2.
  • the tab film 5 is usually removed when the cover member 1 is used.
  • the tab film 5 is removed after, for example, the cover member 1 is peeled off from the member supply sheet and placed on the surface 53 of the object 51. By gripping the tab 21, peeling from the sheet and / or removal of the tab film 5 may be performed.
  • the peeling force between the tab film 5 and the outermost layer may be larger than the peeling force between the sheet for supplying the member and the cover member 1.
  • the peeling force means a force required to peel one layer or member from two layers and / or members in a state of being joined to each other.
  • the cover member 1 can be peeled off from the member supply sheet, for example, by lifting or gripping the layer of the cover member 1 at the position farthest from the sheet.
  • the layer is, for example, a protective film 2 or a tab film 5.
  • the mode of peeling the cover member 1 is not limited to the above example.
  • the object 51 on which the cover member 1 is arranged is, for example, a housing of an electronic device.
  • the cover member 1 can be arranged on the outer surface and / or the inner surface of the housing of the electronic device.
  • the opening may be a vent and / or a sound passage provided in the housing of the electronic device.
  • electronic devices are wearable devices such as smart watches and wristbands; various cameras including action cameras and security cameras; information and communication devices such as mobile phones, smartphones and tablets; virtual reality (VR) devices; augmented reality (AR) ) Equipment; and sensor equipment.
  • VR virtual reality
  • AR augmented reality
  • electronic devices are not limited to this example.
  • the foreign matter that is prevented from passing by the arrangement of the cover member 1 is, for example, particles such as dust and liquid water such as water droplets.
  • the cover member 1 is arranged on the inner surface 54 of the housing 51 of the electronic device which is the object.
  • the housing 51 is provided with an opening 52, and the cover member 1 is arranged on the inner surface 54 so that the protective film 2 covers the opening 52.
  • the first base material layer 3 is located between the protective film 2 and the inner surface 54 in a state where the cover member 1 is arranged on the inner surface 54.
  • the second base material layer 4 faces the space inside the housing 51.
  • the first base material layer 3 surrounds the opening 52 when viewed perpendicular to the inner surface 54.
  • the protective film 2 prevents the passage of foreign matter through the opening 52.
  • the cover member 1 can function as a member that prevents the passage of foreign matter while ensuring the transmission of sound through the opening 52. Further, when the protective film 2 has air permeability in the thickness direction, ventilation through the protective film 2 is ensured. At this time, the cover member 1 can function as a member that prevents the passage of foreign matter while ensuring ventilation through the opening 52.
  • the second base material layer 4 is in contact with the semiconductor element 55. Except for this point, it is the same as the example of FIG.
  • the semiconductor element 55 is arranged inside the housing 51.
  • the semiconductor element 55 may be provided with an opening for ventilation and / or sound transmission.
  • the second base material layer 4 may surround the opening when viewed perpendicularly to the surface of the semiconductor element 55 having the opening.
  • Examples of the semiconductor element 55 are various sensor elements that detect atmospheric pressure, humidity, gas, airflow, acceleration, and the like, and acoustic conversion elements such as speakers and microphones.
  • the cover member 1 can function as a member that prevents foreign matter from passing from the outside of the housing 51 to the semiconductor element 55 while ensuring ventilation and / or sound transmission through the openings 52 and the openings of the semiconductor element 55.
  • the mode in which the cover member 1 is used is not limited to the above example.
  • the cover member 1 can be formed by, for example, shaping and laminating the protective film 2, the base films 11 and 18, and the tab film 5.
  • the cover member 1 can be supplied by a sheet for supplying members.
  • FIG. 11 shows an example of the member supply assembly which is the supply mode of the cover member 1 by the sheet.
  • the member supply assembly 41 of FIG. 11 includes a sheet 31 for supplying members and one or more cover members 1 arranged on the sheet 31. In each cover member 1, the first base material layer 3 faces the sheet 31. According to the member supply assembly 41, for example, the cover member 1 can be efficiently supplied to the process of arranging the cover member 1 on the surface of the object.
  • FIG. 12 and 13 show an example of the arrangement of the cover member 1 on the seat 31.
  • the cover member 1A of FIG. 1A is arranged on the seat 31.
  • the cover member 1C of FIG. 8A is arranged on the seat 31.
  • An adhesive layer 16 (see FIG. 5) can be used for arranging the cover member 1 on the sheet 31.
  • the cover member 1 may be arranged on the sheet 31 via an adhesive layer provided on the arrangement surface of the cover member 1 on the sheet 31.
  • the pressure-sensitive adhesive layer on the arrangement surface is preferably weakly adhesive.
  • Examples of materials constituting the sheet 31 are paper, metal, resin, and composite materials thereof.
  • the metal is, for example, stainless steel and aluminum.
  • the resin is, for example, polyester such as PET and polyolefin such as PE and PP.
  • the material constituting the sheet 31 is not limited to the above example.
  • the thickness of the sheet 31 is, for example, 1 to 250 ⁇ m.
  • the member supply assembly 41 of FIG. 11 includes a rectangular seat 31 when viewed perpendicular to the main surface of the seat 31.
  • the shape of the sheet 31 is not limited to this example.
  • the shape of the sheet 31 may be a polygon other than a rectangle (for example, a square), a circle, an ellipse, or a band when viewed perpendicular to the main surface of the sheet 31.
  • the corners of the polygon may be rounded.
  • a plurality of cover members 1 are regularly arranged and arranged on the sheet 31. More specifically, the plurality of cover members 1 are arranged at the intersections of virtual grids on the arrangement surface.
  • the form of arrangement of the cover member 1 in the member supply assembly 41 is not limited to the above example.
  • the member supply assembly 41 of FIG. 11 is rectangular when viewed perpendicular to the main surface of the assembly 41.
  • the shape of the member supply assembly 41 is not limited to the above example.
  • the shape of the member supply assembly 41 may be a polygon other than a rectangle (for example, a square), a circle, an ellipse, or a band when viewed perpendicular to the main surface of the assembly 41.
  • the corners of the polygon may be rounded.
  • the shape of the member supply assembly 41 may be the same as the shape of the sheet 31.
  • the strip-shaped member supply assembly 41 typically includes a strip-shaped sheet 31.
  • the strip-shaped member supply assembly 41 may be a wound body (may be wound to form a wound body).
  • the strip-shaped member supply assembly 41 may be wound around a winding core to form a winding body.
  • the member supply assembly 41 can be manufactured by arranging the cover member 1 on the seat 31.
  • the protective film is not damaged such as cracks and the cover member can be peeled off without bending the sheet for supplying the member ( ⁇ ).
  • the cover member It is inferior ( ⁇ ) when it is necessary to bend the sheet for supplying members (bending with the arrangement surface of the cover member as the outer surface) for peeling, and even though the sheet for supplying members is bent, it cracks during peeling.
  • the protective film is damaged, such as is not possible (x).
  • the peeled cover member was attached to the surface of the polycarbonate plate via the first base material layer.
  • the tab was gripped with tweezers to peel the tab film from the second base material layer.
  • the case where the protective film was damaged such as a crack was regarded as damaged (x), and the case where it did not occur was regarded as no damage ( ⁇ ).
  • peeling force between the first base material layer and the sheet for supplying members The peeling force between the first base material layer and the sheet for supplying members is determined by the method for measuring the 180 ° peeling adhesive force specified in JIS Z0237: 2009, separately from the production of the cover members of Examples and Comparative Examples. Based on this, the evaluation was made as follows.
  • a sheet for supplying members used for each cover member and a double-sided adhesive tape in contact with the sheet in each cover member were prepared.
  • the sheet and the double-sided adhesive tape were bonded together in an atmosphere of a temperature of 23 ° C. and a humidity of 65% RH, and left in the atmosphere for 24 hours to stabilize the bonding between the two.
  • a crimping roller having a mass of 2 kg was reciprocated once.
  • a laminated body of the sheet and the double-sided adhesive tape was cut out into a rectangle (length 120 mm ⁇ width 30 mm) to obtain a test piece.
  • a 180 ° peeling test was conducted to peel off the double-sided adhesive tape from the sheet, and the 180 ° peeling adhesive strength (180 ° peeling adhesive strength) Unit: N / 30 mm) was measured.
  • the tensile tester a desktop precision universal tester Autograph AGS-X (manufactured by Shimadzu Corporation) was used. The obtained 180 ° peeling adhesive force was used as the peeling force between the first base material layer and the sheet.
  • [Cover member including the first base material layer] (Example 1) ⁇ Preparation of protective film> 100 parts by weight of PTFE fine powder (manufactured by Daikin Industries, Ltd., Polyflon PTFE F-104) and 20 parts by weight of n-dodecane (manufactured by Japan Energy) as a molding aid were uniformly mixed. The obtained mixture was compressed using a cylinder and then ram extrusion molded to form a sheet-like mixture. Next, the sheet-like mixture was rolled through a pair of metal rolls to a thickness of 0.2 mm, and the molding aid was further removed by heating at 150 ° C. to form a PTFE sheet molded product.
  • PTFE fine powder manufactured by Daikin Industries, Ltd., Polyflon PTFE F-104
  • n-dodecane manufactured by Japan Energy
  • the formed sheet molded product was stretched in the longitudinal direction at a stretching temperature of 260 ° C. and a stretching ratio of 1.5 times.
  • the film was stretched in the width direction at a stretching temperature of 150 ° C. and a stretching ratio of 6.5 times, and further fired at 360 ° C. for 10 minutes to obtain a protective film A which is a PTFE-stretched porous film.
  • the cohesive force of the protective film A was 2.0 N / 20 mm.
  • the cohesive force of the protective film A was evaluated by the above method.
  • a non-woven fabric (thickness 270 ⁇ m, basis weight 70 g / m 2 ) was bonded to one main surface of the protective film A to obtain a protective film B.
  • This non-woven fabric was made of a composite fiber having a core-sheath structure with PET as a core and polyethylene as a sheath.
  • the protective film A and the non-woven fabric were joined by thermal lamination (temperature 200 ° C., pressure 0.2 MPa).
  • Double-sided adhesive tape A (Nitto Denko, No. 57120B, thickness 100 ⁇ m), PET film A (Toray, Lumirror # 25S10, thickness 25 ⁇ m, non-foaming) and double-sided adhesive tape B (Nitto Denko, No. 5603, A laminated body having a thickness of 30 ⁇ m) (each layer is arranged in this order) was prepared.
  • the base material of the double-sided adhesive tape A was a PE foam film (thickness 60 ⁇ m).
  • the base material of the double-sided adhesive tape B was a PET non-foamed film (thickness 12.5 ⁇ m).
  • the laminated body was punched into a frame shape having an outer shape of 11 mm ⁇ 10 mm and an inner shape of 6.8 mm ⁇ 3.8 mm to obtain a first base material layer A.
  • the first base material layer A includes a two-layer non-foaming film and a one-layer foamed film as the base film.
  • the adhesives of the double-sided adhesive tapes A and B were acrylic.
  • PET sheet manufactured by nippers, PET75x1-JOL, thickness 75 ⁇ m
  • the sheet was a rectangle having a length of 160 mm and a width of 60 mm.
  • the protective film B and the first base material layer A were joined by the double-sided adhesive tape B of the first base material layer A.
  • the bonding was carried out so that the double-sided adhesive tape B and the PTFE stretched porous film were in contact with each other.
  • the entire surface was punched into a rectangle having an outer diameter of 9 mm ⁇ 6 mm to obtain a cover member of Example 1.
  • the punching process was carried out so that the center of the inner shape of the first base material layer A, which had a frame shape, coincided with the center of the entire surface after the process.
  • the cover member was placed on the member supply sheet via the double-sided adhesive tape A. In this state, among the base films included in the first base material layer A, the foamed film which is the base material of the double-sided adhesive tape A is located at the position closest to the protective film B and the sheet for supplying the member. It was.
  • Example 2 As the non-woven fabric to be bonded to the protective film A, except that a non-woven fabric (thickness 105 ⁇ m, grain 30 g / m 2 ) made of a composite fiber having a core-sheath structure with PET as a core and a low melting point copolymer polyester as a sheath was used.
  • a cover member was obtained in the same manner as in Example 1.
  • the protective film provided on the cover member of the second embodiment is referred to as the protective film C.
  • the cover member was placed on the member supply sheet via the double-sided adhesive tape A of the first base material layer A.
  • a cover member was obtained in the same manner as in Example 1 except that the first base material layer B was used instead of the first base material layer A.
  • Double-sided adhesive tape C (Nitto Denko, No. 5610, thickness 100 ⁇ m) was used for the first base material layer B.
  • the base material of the double-sided adhesive tape C was a PET non-foamed film (thickness 50 ⁇ m).
  • the first base material layer B provided a single layer of non-foamed film as a base film.
  • the adhesive of the double-sided adhesive tape C was an acrylic type.
  • the cover member was placed on the member supply sheet via the double-sided adhesive tape C of the first base material layer B.
  • Example 2 A cover member was obtained in the same manner as in Example 2 except that the first base material layer C was used instead of the first base material layer A. Double-sided adhesive tape A was used for the first base material layer C. The first base material layer C provided a one-layer foamed film as a base film. The cover member was placed on the member supply sheet via the double-sided adhesive tape A of the first base material layer C.
  • Comparative Example 3 A cover member was obtained in the same manner as in Example 2 except that the first base material layer B was used instead of the first base material layer A.
  • the cover member of Comparative Example 3 was arranged on the sheet for supplying the member via the double-sided adhesive tape C of the first base material layer B.
  • Table 1 shows the structure of the first base material layer.
  • Table 2 shows the configurations and evaluation results of Examples 1 and 2 and Comparative Examples 1 to 3.
  • “Foam” and “non-foam” in Table 1 indicate that the base material of the double-sided adhesive tape is a foam film and a non-foam film, respectively.
  • the cover member of the example in which the first base material layer includes the non-foamed film and the foamed film was superior in peelability as compared with the cover member of the comparative example.
  • the first base material layer A was bonded to one surface of the protective film A with the double-sided adhesive tape B of the first base material layer A.
  • the second base material layer A was bonded to the other surface of the protective film A with the double-sided adhesive tape C of the second base material layer A.
  • the joining of the second base material layer A was carried out so that the inner shapes of the first base material layer A and the second base material layer, which are frame-shaped, match each other when viewed perpendicular to the main surface of the protective film A. ..
  • the entire surface was punched into a rectangle having an outer diameter of 9 mm ⁇ 6 mm to obtain a cover member.
  • the punching process was carried out so that the center of the inner shape of the first base material layer A and the second base material layer A became the center of the whole after the processing.
  • the cover member was placed on the member supply sheet via the double-sided adhesive tape A of the first base material layer A.
  • the foamed film which is the base material of the double-sided adhesive tape A is located at the position closest to the protective film A and the sheet for supplying the member. It was.
  • Example 4 A cover member was obtained in the same manner as in Example 3 except that the second base material layer B was used instead of the second base material layer A.
  • the second base material layer B a laminate of double-sided adhesive tape B and PET film B was used.
  • the second base material layer B was bonded to the protective film A by the double-sided adhesive tape B of the second base material layer B.
  • the cover member was placed on the member supply sheet via the double-sided adhesive tape A of the first base material layer A. In this state, among the base films included in the first base material layer A, the foamed film which is the base material of the double-sided adhesive tape A is located at the position closest to the protective film A and the sheet for supplying the member. It was.
  • Example 5 A cover member was obtained in the same manner as in Example 4 except that the first base material layer D was used instead of the first base material layer A.
  • a double-sided adhesive tape D manufactured by Nitto Denko, No. 57115B, thickness 150 ⁇ m
  • the base material of the double-sided adhesive tape D was a polyethylene foam film (thickness 80 ⁇ m).
  • the first base material layer D includes a two-layer non-foaming film and a one-layer foamed film as the base film.
  • the adhesive of the double-sided adhesive tape D was an acrylic type.
  • the first base material layer D was bonded to the protective film A by the double-sided adhesive tape B of the first base material layer D.
  • the cover member was placed on the member supply sheet via the double-sided adhesive tape D of the first base material layer D.
  • the foamed film which is the base material of the double-sided adhesive tape D is located at the position closest to the protective film A and the sheet for supplying the member. It was.
  • Example 6 A cover member was obtained in the same manner as in Example 4 except that the first base material layer E was used instead of the first base material layer A.
  • a double-sided adhesive tape E manufactured by Nitto Denko, No. 57120B, thickness 200 ⁇ m
  • the base material of the double-sided adhesive tape E was a polyethylene foam film (thickness 100 ⁇ m).
  • the first base material layer E includes a two-layer non-foaming film and a one-layer foamed film as the base film.
  • the adhesive of the double-sided adhesive tape E was an acrylic type.
  • the first base material layer E was bonded to the protective film A by the double-sided adhesive tape B of the first base material layer E.
  • the cover member was placed on the member supply sheet via the double-sided adhesive tape E of the first base material layer E.
  • the foamed film which is the base material of the double-sided adhesive tape E is located at the position closest to the protective film A and the sheet for supplying the member. It was.
  • Example 7 A cover member was obtained in the same manner as in Example 4 except that the first base material layer F was used instead of the first base material layer A.
  • a laminate of double-sided adhesive tape A and double-sided adhesive tape B was prepared for the first base material layer F.
  • the first base material layer F includes one layer of non-foaming film and one layer of foamed film as the base film.
  • the first base material layer F was bonded to the protective film A by the double-sided adhesive tape B of the first base material layer F.
  • the cover member was placed on the member supply sheet via the double-sided adhesive tape A of the first base material layer F. In this state, among the base films included in the first base material layer F, the foamed film which is the base material of the double-sided adhesive tape A is located at the position closest to the protective film A and the sheet for supplying members. It was.
  • Example 4 A cover member was obtained in the same manner as in Example 3 except that the first base material layer B was used instead of the first base material layer A. The cover member was placed on the member supply sheet via the double-sided adhesive tape C of the first base material layer B.
  • Example 5 A cover member was obtained in the same manner as in Example 3 except that the first base material layer C was used instead of the first base material layer A. The cover member was placed on the member supply sheet via the double-sided adhesive tape A of the first base material layer B.
  • the configurations of the first base material layer and the second base material layer are shown in Tables 3 and 4, respectively.
  • Table 5 shows the configurations and evaluation results of Examples 3 to 7 and Comparative Examples 4 and 5.
  • “Foam” and “non-foam” in Table 3 indicate that the base material of the double-sided adhesive tape is a foam film and a non-foam film, respectively.
  • the cover member of the example in which the first base material layer includes the non-foamed film and the foamed film was superior in peelability as compared with the cover member of the comparative example.
  • the protective film was damaged when the tab film was peeled off. It is presumed that this is because the first base material layer is excessively flexible, so that the protective film is deformed greatly when the tab film is peeled off, and the protective film is coagulated and fractured. Since the protective film of the cover member of Comparative Example 4 was damaged when it was peeled from the film for supplying the member, it was not possible to evaluate whether or not the protective film was damaged when the tab film was peeled off.
  • the cover member of the present invention can be used for the same purposes as a conventional cover member provided with a protective film.

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Abstract

本発明のカバー部材は、開口を有する面を持つ対象物の当該面に配置されて、上記開口における異物の通過を防ぐ部材であって、当該カバー部材が上記面に配置されたときに上記開口を覆う形状を有する保護膜と、保護膜の一方の主面に接合された第1基材層とを備える。第1基材層は、2以上の基材フィルムを含む積層構造を有すると共に、カバー部材が上記面に配置されたときに保護膜と上記面との間に位置する。前記2以上の基材フィルムは、非発泡フィルムと発泡フィルムとを備える。本発明のカバー部材は、部材供給用のシートからの剥離性の改善に適している。

Description

カバー部材及びこれを備える部材供給アセンブリ
 本発明は、開口を有する面を持つ対象物の当該面に配置されて上記開口における異物の通過を防ぐカバー部材と、当該部材を供給するための部材供給アセンブリとに関する。
 開口を有する面を持つ対象物の当該面に配置されて、上記開口における異物の通過を防ぐカバー部材が知られている。特許文献1には、防水通気膜と、防水通気膜の表面の周縁部に接合された第1両面粘着テープと、防水通気膜の上記表面とは反対側の表面の周縁部に接合された第2両面粘着テープと、を備え、第1両面粘着テープの基材が発泡体である防水通気部材が開示されている。
国際公開第2015/064028号
 カバー部材は、通常、ライナーシート等の部材供給用のシートに配置された状態で供給される。当該状態で供給されたカバー部材は、シートから剥離した後に、対象物の面に配置される。このとき、カバー部材におけるシートから最も離れた層を吸着や把持により持ち上げることでカバー部材をシートから剥離させ、そのまま対象物の面にカバー部材を配置すると効率的である。最も離れた層は、例えば、保護膜やタブフィルムである。しかし、シートからのカバー部材の剥離性が低いと、カバー部材を持ち上げる力が集中して保護膜が破損することがある。破損は、厚さ方向に高い通気性を有する保護膜を備えたカバー部材において特に生じやすい。
 本発明は、部材供給用のシートからの剥離性に優れるカバー部材の提供を目的とする。
 本発明は、
 開口を有する面を持つ対象物の当該面に配置されて、前記開口における異物の通過を防ぐカバー部材であって、
 前記カバー部材が前記面に配置されたときに前記開口を覆う形状を有する保護膜と、
 前記保護膜の一方の主面に接合された第1基材層と、を備え、
 前記第1基材層は、2以上の基材フィルムを含む積層構造を有すると共に、前記カバー部材が前記面に配置されたときに前記保護膜と前記面との間に位置し、
 前記2以上の基材フィルムは、非発泡フィルムと発泡フィルムとを備えるカバー部材、
 を提供する。
 別の側面から、本発明は、
 部材供給用のシートと、前記シート上に配置されたカバー部材と、を備え、
 前記カバー部材は、上記本発明のカバー部材であり、
 前記カバー部材の前記第1基材層が前記シートに面している、部材供給アセンブリ、
 を提供する。
 本発明のカバー部材では、非発泡フィルム及び発泡フィルムを含む2以上の基材フィルムの積層構造を有する第1基材層が、保護膜に接合されている。第1基材層は、対象物の面に配置されたときに保護膜と当該面との間に位置する。ここで、ライナーシート等の部材供給用のシートにより供給されたカバー部材は、通常、シートに接していた側が対象物の面に接するように配置される。このため、シートによる供給時には、第1基材層がシート側に位置している。シートからの剥離時には、カバー部材を折り曲げようとする力が働く。この力によりカバー部材が過度に変形すると、剥離が難しくなり、保護膜が破損しやすくなる。しかし、部材がある程度折り曲がらなければ、剥離はスムーズに進行しない。本発明のカバー部材は、相対的に剛直であって、過度の変形を防ぎながら部材を剥離する力として上記力を効率的にカバー部材に伝達できる非発泡フィルムと、相対的に柔軟であって、シート側に位置する第1基材層の適度な変形を許容する発泡フィルムと、を第1基材層に備えている。本発明のカバー部材は、部材供給用のシートからの剥離性の改善に適した構造を有する。
図1Aは、本発明のカバー部材の一例を模式的に示す断面図である。 図1Bは、図1Aのカバー部材を保護膜の側から見た平面図である。 図2は、本発明のカバー部材の別の一例を模式的に示す断面図である。 図3は、本発明のカバー部材のまた別の一例を模式的に示す断面図である。 図4は、本発明のカバー部材の更にまた別の一例を模式的に示す断面図である。 図5は、本発明のカバー部材の上記とは別の一例を模式的に示す断面図である。 図6Aは、本発明のカバー部材の上記とは別の一例を模式的に示す断面図である。 図6Bは、図6Aのカバー部材を第2基材層の側から見た平面図である。 図7は、本発明のカバー部材の上記とは別の一例を模式的に示す断面図である。 図8Aは、本発明のカバー部材の上記とは別の一例を模式的に示す断面図である。 図8Bは、図8Aのカバー部材をタブフィルムの側から見た平面図である。 図9は、本発明のカバー部材の対象物への配置の一例を示す模式図である。 図10は、本発明のカバー部材の対象物への配置の別の一例を示す模式図である。 図11は、本発明の部材供給アセンブリの一例を模式的に示す平面図である。 図12は、部材供給用のシートに対する本発明のカバー部材の配置の一例を模式的に示す断面図である。 図13は、部材供給用のシートに対する本発明のカバー部材の配置の別の一例を模式的に示す断面図である。
 以下、本発明の実施形態について、図面を参照しながら説明する。本発明は、以下の実施形態に限定されない。
 [カバー部材]
 本発明のカバー部材の一例を図1A及び図1Bに示す。図1Bは、図1Aのカバー部材1(1A)を保護膜2の側から見た平面図である。図1Aには、図1Bの断面A-Aが示されている。カバー部材1Aは、開口52を有する面53を持つ対象物51の面53に配置されて、開口52における異物の通過を防ぐ部材である。図1A及び図1Bには、対象物51の面53に配置された状態にあるカバー部材1Aが示されている。
 カバー部材1Aは、保護膜2と、保護膜2の一方の主面に接合された第1基材層3とを備える。カバー部材1Aは、保護膜2及び第1基材層3を含む積層体から構成される。保護膜2は、カバー部材1Aが面53に配置されたときに開口52を覆う形状を有する。第1基材層3は、カバー部材1Aが面53に配置されたときに、保護膜2と面53との間に位置している。
 第1基材層3は、2つの基材フィルム11を含む積層構造を有する。第1基材層3は、基材フィルム11として、非発泡体により構成される非発泡フィルム11Aと、発泡体により構成される発泡フィルム11Bとを備える。発泡フィルム11Bは、非発泡フィルム11Aよりも保護膜2から離れた位置にある。この形態では、カバー部材1Aの剥離時に、発泡フィルム11Bによる第1基材層3の変形がより適度となり、カバー部材1Aの剥離性を向上できる。また、第1基材層3において保護膜2から最も離れた位置にある基材フィルム11は、発泡フィルム11Bである。この形態では、上記適度な変形に基づく剥離性の向上がより確実となる。
 ただし、第1基材層3の積層構造は、2以上の基材フィルム11として非発泡フィルム11A及び発泡フィルム11Bを含む限り、上記例に限定されない。第1基材層3は、2以上の非発泡フィルム11A及び/又は2以上の発泡フィルム11Bを備えていてもよい。第1基材層3の構成が異なる変形例を図2に示す。
 図2のカバー部材1Aは、第1基材層3の構成が異なる以外は、図1A及び図1Bのカバー部材1Aと同様の構成を有する。図2の第1基材層3は、2つの非発泡フィルム11A,11Cと、1つの発泡フィルム11Bとを基材フィルム11として備える。非発泡フィルム11A,11C及び発泡フィルム11Bは、この順に積層されている。発泡フィルム11Bは、非発泡フィルム11A,11Cよりも保護膜2から離れた位置にある。第1基材層3において保護膜2から最も離れた位置にある基材フィルム11は、発泡フィルム11Bである。
 第1基材層3における2以上の基材フィルム11は、通常、互いに接合されている。基材フィルム11は、粘着剤又は接着剤によって互いに接合されていてもよいし、超音波溶着や熱溶着等の各種の溶着法によって互いに接合されていてもよい。基材フィルム11を互いに接合する粘着剤は層状(粘着剤層)であってもよい。この形態では、粘着剤層の柔軟性が剥離性の向上に寄与しうる。粘着剤層は、基材レスの両面粘着テープであってもよい。
 粘着剤の例は、アクリル系粘着剤、シリコーン系粘着剤、ウレタン系粘着剤、エポキシ系粘着剤及びゴム系粘着剤である。高温下でのカバー部材1Aの使用を考慮する必要がある場合には、耐熱性に優れるアクリル系粘着剤又はシリコーン系粘着剤、特にシリコーン系粘着剤、を選択することが好ましい。
 基材と、当該基材の片面又は両面に粘着剤が塗布されてなる片面粘着テープ又は両面粘着テープを、基材フィルム11及び粘着剤層として使用してもよい。両面粘着テープを使用した例を図3及び図4に示す。
 図3の第1基材層3では、発泡フィルム11Bは両面粘着テープ13の基材である。発泡フィルム11Bと非発泡フィルム11Aとは、両面粘着テープ13の粘着剤層12Aによって接合されている。また、図3のカバー部材1Aは、両面粘着テープ13の粘着剤層12Bを介して面53に配置されている。図3のカバー部材1Aは、これらの点以外は、図1A及び図1Bのカバー部材1Aと同様の構成を有する。
 図4の第1基材層3では、発泡フィルム11Bは両面粘着テープ13の基材である。発泡フィルム11Bと非発泡フィルム11Cとは、両面粘着テープ13の粘着剤層12Aによって接合されている。非発泡フィルム11Aは両面粘着テープ15の基材である。非発泡フィルム11Cと非発泡フィルム11Aとは、両面粘着テープ15の粘着剤層14Bによって接合されている。また、保護膜2と第1基材層3とは、両面粘着テープ15の粘着剤層14Aによって接合されている。図4のカバー部材1Aは、両面粘着テープ13の粘着剤層12Bを介して面53に配置されている。図4のカバー部材1Aは、これらの点以外は、図2のカバー部材1Aと同様の構成を有する。
 保護膜2と第1基材層3とは、粘着剤又は接着剤によって接合されていてもよいし、上記各種の溶着法によって接合されていてもよい。保護膜2と第1基材層3とは粘着剤層17によって接合されていてもよい(図5参照)。この形態では、粘着剤層の柔軟性が剥離性の向上に寄与しうる。粘着剤及び粘着剤層の例は、上述のとおりである。保護膜2と第1基材層3とを接合する粘着剤層は、基材フィルム11を基材とする片面粘着テープ又は両面粘着テープの粘着剤層(例えば、図4の粘着剤層14A)であってもよい。
 カバー部材1Aは、カバー部材1Aが備える粘着剤層16を介して面53に配置されてもよい(図5参照)。粘着剤層の例は、上述のとおりである。また、粘着剤層16は、基材フィルム11を基材とする片面粘着テープ又は両面粘着テープの粘着剤層(例えば、図3,4の粘着剤層12B)であってもよい。
 カバー部材1Aの形状は、保護膜2の主面に垂直に見て、長方形である。ただし、カバー部材1の形状は、この例に限定されない。カバー部材1の形状は、保護膜2の主面に垂直に見て、正方形及び長方形を含む多角形、円、並びに楕円であってもよい。多角形の角は、丸められていてもよい(図1B参照)。
 カバー部材1Aの第1基材層3は、保護膜2の主面に垂直に見て、保護膜2の外周に一致する外周を有している。また、カバー部材1Aの第1基材層3は、保護膜2の主面に垂直に見て、保護膜2の周縁部に対応する形状(額縁状)を有している。保護膜2の第1基材層3側の面は、第1基材層3が接していない領域において露出している。保護膜2が厚さ方向の通気性を有する場合には、当該領域をカバー部材1Aの通気領域とすることができる。ただし、第1基材層3の形状は、上記例に限定されない。
 カバー部材1における通気領域の面積は、例えば、40mm2以下である。通気領域の面積が当該範囲にあるカバー部材1は、例えば、小径の開口を有する対象物への配置に適している。通気領域の面積の下限は、例えば、0.008mm2以上である。ただし、通気領域の面積は、カバー部材1が配置される対象物の種類によっては、より大きな範囲であってもよい。
 第1基材層3の厚さは、例えば、50~1000μmであり、70~800μm、更には130~600μmであってもよい。
 発泡フィルム11Bは、独立気泡を有する。このため、発泡フィルム11Bは、例えば粘着剤層が表面に設けられた場合においても、フィルム内部への粘着剤の含浸が抑制されることで柔軟性を維持できる。
 発泡フィルム11Bを構成する材料の例は、ポリエチレン(PE)及びポリプロピレン(PP)等のポリオレフィン、シリコーン樹脂、アクリル樹脂、並びにポリウレタンである。ただし、発泡フィルム11Bを構成する材料は、上記例に限定されない。
 発泡フィルム11Bは、接着性を有さなくてもよい。
 非発泡フィルム11A,11Cは、独立気泡を有さない。非発泡フィルム11A,11Cは、厚さ方向の通気性を有していてもよい。非発泡フィルム11A,11Cの例は、金属フィルム、樹脂フィルム、不織布、織布及び紙である。非発泡フィルム11A,11Cは、樹脂フィルムが好ましい。
 非発泡フィルム11A,11Cを構成しうる樹脂の例は、PE及びPP等のポリオレフィン、ポリエチレンテレフタレート(PET)等のポリエステル、シリコーン樹脂、ポリカーボネート、ポリイミド、ポリアミドイミド、ポリフェニレンサルファイド、ポリエーテルエーテルケトン(PEEK)、ポリ塩化ビニル、並びにフッ素樹脂である。フッ素樹脂の例は、ポリテトラフルオロエチレン(PTFE)、テトラフルオロエチレン-パーフルオロアルキルビニルエーテル共重合体(PFA)、テトラフルオロエチレン-ヘキサフルオロプロピレン共重合体(FEP)、テトラフルオロエチレン-エチレン共重合体(ETFE)である。ただし、樹脂は上記例に限定されない。
 非発泡フィルム11A,11Cを構成しうる金属の例は、ステンレス及びアルミニウムである。ただし、金属は上記例に限定されない。
 非発泡フィルム11A,11Cは、接着性を有さなくてもよい。
 発泡フィルム11B及び非発泡フィルム11A,11Cは、第1基材層3に垂直に見て、同じ形状を有していてもよい。また、第1基材層3において各基材フィルム11の外周は、互いに一致していてもよい。
 基材フィルム11の厚さは、例えば、10~250μmである。
 基材フィルム11、特に非発泡フィルム11A,11C、は、保護膜2に比べて高い強度を有していてもよい。この場合、剥離時における保護膜2の破損を抑制できる。強度は、例えば、引張破断強度又は凝集破壊強度として評価できる。
 保護膜2は、厚さ方向に非通気性であっても、厚さ方向の通気性を有していてもよい。保護膜2が厚さ方向の通気性を有する場合、カバー部材1の配置により、対象物の開口における異物の通過を防ぎながら当該開口を介した通気を確保できる。通気の確保により、例えば、開口を介した圧力の調整や圧力の変動の緩和が可能となる。
 厚さ方向の通気性を有する保護膜2の通気度(厚さ方向の通気度)は、日本産業規格(旧日本工業規格;以下、「JIS」と記載する)L1096に定められた通気性測定B法(ガーレー形法)に準拠して求めた空気透過度(以下、「ガーレー通気度」と記載)により表示して、例えば1万秒/100mL未満である。ガーレー通気度は、5000秒/100mL以下、1000秒/100mL以下、500秒/100mL以下、100秒/100mL以下、50秒/100mL以下、10秒/100mL以下、更には5秒/100mL以下であってもよい。ガーレー通気度の下限は、例えば、0.2秒/100mL以上である。
 厚さ方向に非通気性である保護膜2の通気度は、ガーレー通気度により表示して、例えば1万秒/100mL以上である。
 保護膜2を構成する材料の例は、金属、樹脂及びこれらの複合材料である。
 保護膜2を構成しうる樹脂及び金属の例は、基材フィルム11を構成しうる樹脂及び金属の例と同じである。保護膜2を構成する樹脂は、PTFEであってもよい。ただし、樹脂及び金属は、上記例に限定されない。
 厚さ方向の通気性を有する保護膜2は、延伸多孔質膜を含んでいてもよい。延伸多孔質膜は、フッ素樹脂の延伸多孔質膜、特にPTFE延伸多孔質膜、であってもよい。PTFE延伸多孔質膜は、通常、PTFE粒子を含むペースト押出物又はキャスト膜を延伸して形成される。PTFE延伸多孔質膜は、PTFEの微細なフィブリルにより構成され、フィブリルに比べてPTFEが凝集した状態にあるノードを有することもある。PTFE延伸多孔質膜によれば、異物の侵入を防ぐ性能及び通気性を高いレベルで両立させることが可能である。保護膜2には、公知の延伸多孔質膜を使用できる。
 厚さ方向の通気性を有する保護膜2は、双方の主面を接続する複数の貫通孔が形成された穿孔膜を含んでいてもよい。穿孔膜は、非多孔質の基質構造を有する原膜、例えば無孔膜、に複数の貫通孔が設けられた膜であってもよい。穿孔膜は、上記複数の貫通孔以外に、厚さ方向の通気経路を有していなくてもよい。貫通孔は、穿孔膜の厚さ方向に延びていてもよく、厚さ方向に直線状に延びるストレート孔であってもよい。貫通孔の開口の形状は、穿孔膜の主面に垂直に見て、円又は楕円であってもよい。穿孔膜は、例えば、原膜に対するレーザー加工、又は、イオンビーム照射及びこれに続く化学エッチングによる孔開け加工により形成できる。
 厚さ方向の通気性を有する保護膜2は、不織布、織布、メッシュ、ネットを含んでいてもよい。
 保護膜2は、単層構造を有していても、2以上の異なる層からなる多層構造を有していてもよい。多層構造を有する保護膜2の例は、PTFE延伸多孔質膜と不織布との積層構造を有する。
 保護膜2は、上記例に限定されない。
 カバー部材1Aの保護膜2の形状は、保護膜2の主面に垂直に見て、長方形である。ただし、保護膜2の形状は上記例に限定されず、例えば、保護膜2の主面に垂直に見て、正方形及び長方形を含む多角形、円、並びに楕円であってもよい。多角形の角は、丸められていてもよい。
 保護膜2の厚さは、例えば、1~100μmである。
 保護膜2の凝集力は、2.0N/20mm以下であってもよい。厚さ方向の高い通気性を有する保護膜2の凝集力は低い傾向にある。このため、厚さ方向の高い通気性を有する保護膜2を備える従来のカバー部材は、剥離時に保護膜2を破損しやすい。一方、カバー部材1では、厚さ方向の高い通気性を有する保護膜2を備える場合においても、保護膜2の破損を抑制できる。言い換えると、厚さ方向の高い通気性を有する保護膜2をカバー部材1が備える場合に、本発明は特に有利である。保護膜2の凝集力は、1.8N/20mm以下、更には1.5N/20mm以下であってもよい。厚さ方向の高い通気性を有する保護膜2は、例えば、ガーレー通気度により表示して、100秒/100mL以下の通気度を有する。
 保護膜2の凝集力は、JIS Z0237:2009に定められた180°引きはがし粘着力の測定方法を参考にして、以下に示す方法により測定できる。
 <試験片の準備>
 最初に、測定対象である保護膜2を長方形(長さ100mm×幅20mm)に切り出す。次に、保護膜2と同一の形状を有する両面粘着テープ(日東電工製、No.5610)を2枚準備する。各両面粘着テープは、それぞれ、保護膜2の一方の面及び他方の面に外周を一致させて貼り合わせる。次に、長さ150mm×幅20mmの長方形のPETフィルム(厚さ25μm)を2枚準備する。各PETフィルムは、それぞれ、保護膜2の一方の面及び他方の面に上記両面粘着テープにより貼り合わせる。PETフィルムの貼り合わせは、各PETフィルムの幅方向の両端部が保護膜2の幅方向の両端部と一致し、かつ各PETフィルムの長手方向の両端部が、PETフィルムの主面に垂直に見て、保護膜2及び両面粘着テープと重複しないように実施する。ただし、各PETフィルムの自由端部の長さ(長手方向)として、引張試験機のチャックがPETフィルムを安定してつかめる長さ(例えば25mm)を確保する。次に、PETフィルム/両面粘着テープ/保護膜2/両面粘着テープ/PETフィルムの積層体の厚さ方向に圧着力が加わるように、荷重19.6Nの圧着ローラを1往復させる。その後、引張試験を開始するまでに少なくとも30分放置して、試験片とする。
 <引張試験による保護膜2の凝集力の測定>
 次に、引張試験機(例えば、島津製作所製、卓上型精密万能試験機オートグラフAGS-X)を準備する。試験片の長手方向の一方の端部における一方のPETフィルムの自由端部を引張試験機の上部チャックに固定する。試験片の長手方向の他方の端部における他方のPETフィルムの自由端部を下部チャックに取り付ける。次に、測定温度25±5℃、測定湿度60±5%RH及び引張速度300mm/分の条件で、他方のPETフィルムの下端部を下向きに引っ張る引張試験を実施して、保護膜2に凝集破壊を発生させる。保護膜2の凝集破壊によるPETフィルムの変位が始まった後、初期の25mmの変位の際に測定されたチャック間の応力は無視し、その後の50mmの変位の際に連続的に記録された応力の測定値の平均値を、保護膜2の凝集力(単位:N/25mm)とする。
 保護膜2の面積は、例えば、175mm2以下である。保護膜2の面積が当該範囲にあるカバー部材1は、例えば、小径の開口を有する対象物への配置に適している。保護膜2の面積の下限は、例えば、0.20mm2以上である。ただし、保護膜2の面積は、カバー部材1が配置される対象物の種類によっては、より大きな値であってもよい。
 カバー部材1の面積は、例えば、175mm2以下である。面積が当該範囲にあるカバー部材1は、例えば、小径の開口を有する対象物への配置に適している。カバー部材1の面積の下限は、例えば、0.20mm2以上である。ただし、カバー部材1の面積は、配置される対象物の種類によっては、より大きな値であってもよい。なお、カバー部材1の面積が小さいほど、部材供給用のシートからの剥離は困難である。このため、カバー部材1の面積が上記範囲にある場合に、本発明の効果は特に顕著となる。
 カバー部材1は、本発明の効果が得られる限り、上述した以外の任意の層及び/又は部材を備えていてもよい。
 本発明のカバー部材の上記とは別の一例を図6A及び図6Bに示す。図6Bは、図6Aのカバー部材1(1B)を第2基材層4の側から見た平面図である。図6Aには、図6Bの断面A-Aが示されている。図6A及び図6Bには、対象物51の面53に配置された状態にあるカバー部材1Bが示されている。カバー部材1Bは、1又は2以上の基材フィルム18を備える第2基材層4を更に備える以外は、カバー部材1Aと同様の構成を有する。
 第2基材層4は、保護膜2の他方の主面に接合されて、第1基材層3と共に保護膜2を挟持している。この形態では、剥離時における保護膜2の破損をより確実に抑制できる。また、後述のタブフィルム5をカバー部材1が備える場合に、タブフィルム5の剥離時における保護膜2の破損を抑制できる。
 第2基材層4は、基材フィルム18として、非発泡体により構成される非発泡フィルム18Aのみを備えていてもよい。基材フィルム18及び非発泡フィルム18Aの構成は、それぞれ、基材フィルム11及び非発泡フィルム11Aの構成と同様でありうる。
 第1基材層3及び第2基材層4の各々において保護膜2に最も近い位置にある基材フィルム11,18の構成は、同一であってもよい。この形態では、上記保護膜2の破損をより確実に抑制できる。
 第2基材層4は、2以上の基材フィルム18を備えていてもよい。2以上の基材フィルム18は、第2基材層4に垂直に見て、同じ形状を有していてもよい。また、2以上の各基材フィルム18の外周は、第2基材層4において互いに一致していてもよい。2以上の基材フィルム18は、通常、互いに接合されている。基材フィルム18の接合法は、基材フィルム11の接合法と同じであってもよい。
 基材と、当該基材の片面又は両面に粘着剤が塗布されてなる片面粘着テープ又は両面粘着テープを、基材フィルム18及び粘着剤層として使用してもよい。両面粘着テープを使用した例を図7に示す。
 図7の第2基材層4は、2つの非発泡フィルム18A,18Bを基材フィルム18として備える。非発泡フィルム18Aは、両面粘着テープ20の基材である。非発泡フィルム18Aと非発泡フィルム18Bとは、両面粘着テープ20の粘着剤層19Aによって接合されている。また、保護膜2と第2基材層4とは、両面粘着テープ20の粘着剤層19Bによって接合されている。図7のカバー部材1Bは、これらの点以外は、図6A及び図6Bのカバー部材1Bと同様の構成を有する。
 保護膜2と第2基材層4とは、粘着剤又は接着剤によって接合されていてもよいし、上記各種の溶着法によって接合されていてもよい。保護膜2と第2基材層4とは粘着剤層によって接合されていてもよい。粘着剤及び粘着剤層の例は、上述のとおりである。また、保護膜2と第2基材層4とを接合する粘着剤層は、基材フィルム18を基材とする片面粘着テープ又は両面粘着テープの粘着剤層(例えば、図7の粘着剤層19B)であってもよい。
 カバー部材1Bの第2基材層4は、保護膜2の主面に垂直に見て、保護膜2の外周に一致する外周を有している。また、カバー部材1Bの第2基材層4は、保護膜2の主面に垂直に見て、保護膜2の周縁部に対応する形状(額縁状)を有している。保護膜2の第2基材層4側の面は、第2基材層4が接していない領域において露出している。保護膜2が厚さ方向の通気性を有する場合には、当該領域をカバー部材1の通気領域とすることができる。ただし、第2基材層4の形状は、上記例に限定されない。
 第2基材層4の厚さは、例えば、10~700μmであり、30~300μmであってもよい。
 本発明のカバー部材の上記とは別の一例を図8A及び図8Bに示す。図8Bは、図8Aのカバー部材1(1C)をタブフィルム5の側から見た平面図である。図8Aには、図8Bの断面A-Aが示されている。図8A及び図8Bには、対象物51の面53に配置された状態にあるカバー部材1Cが示されている。カバー部材1Cは、タブフィルム5を更に備える以外は、カバー部材1Bと同様の構成を有する。
 タブフィルム5は、カバー部材1の最外層の上に配置されている。最外層は、カバー部材1が面53に配置されたときに、面53から最も離れた位置にある。図8A及び図8Bの例の最外層は、第2基材層4が備える基材フィルム18(18B)である。タブフィルム5は、最外層の主面に垂直に見て、最外層の外周よりも外方に突出したタブ21を有する。図8A及び図8Bのタブ21の形状は、タブフィルム5の主面に垂直に見て、長方形である。タブ21の形状は、この例に限定されない。なお、本明細書において外方とは、保護膜2の主面に垂直に見て、カバー部材1の中心から離れる方向を意味する。
 タブフィルム5は、通常、カバー部材1の使用時に除去される。タブフィルム5は、例えば、カバー部材1を部材供給用のシートから剥離して対象物51の面53に配置した後に除去される。タブ21を把持することで、シートからの剥離及び/又はタブフィルム5の除去を実施してもよい。
 タブフィルム5と最外層との剥離力は、部材供給用のシートとカバー部材1との剥離力に比べて大きくてもよい。なお、剥離力とは、互いに接合した状態にある2つの層及び/又は部材から一方の層又は部材を剥離するのに要する力を意味する。
 部材供給用のシートからのカバー部材1の剥離は、例えば、カバー部材1におけるシートから最も離れた位置にある層を吸着や把持により持ち上げて実施できる。当該層は、例えば、保護膜2又はタブフィルム5である。ただし、カバー部材1の剥離の態様は、上記例に限定されない。
 カバー部材1が配置される対象物51は、例えば、電子機器の筐体である。カバー部材1は、電子機器の筐体の外面及び/又は内面に配置できる。このとき、開口は、電子機器の筐体に設けられた通気口及び/又は通音口であってもよい。電子機器の例は、スマートウォッチ及びリストバンド等のウェアラブルデバイス;アクションカメラ及び防犯カメラを含む各種のカメラ;携帯電話、スマートフォン及びタブレット等の情報通信機器;仮想現実(VR)機器;拡張現実(AR)機器;並びにセンサー機器である。ただし、電子機器は、この例に限定されない。
 カバー部材1の配置により通過が防がれる異物は、例えば、塵埃等の粒子、水滴等の液体の水である。
 カバー部材1を使用する態様の例を図9及び図10に示す。
 図9の例では、対象物である電子機器の筐体51の内面54にカバー部材1が配置されている。筐体51には開口52が設けられており、カバー部材1は、開口52を保護膜2が覆うように、内面54に配置されている。第1基材層3は、カバー部材1が内面54に配置された状態で、保護膜2と内面54との間に位置する。第2基材層4は、筐体51の内部の空間に面している。第1基材層3は、内面54に垂直に見て、開口52を囲んでいる。保護膜2により、開口52を介した異物の通過が防がれる。カバー部材1は、開口52を介した音の透過を確保しながら異物の通過を防ぐ部材として機能しうる。また、保護膜2が厚さ方向の通気性を有する場合には、保護膜2を介した通気が確保される。このとき、カバー部材1は、開口52を介した通気を確保しながら異物の通過を防ぐ部材として機能しうる。
 図10の例では、第2基材層4が半導体素子55に接している。この点以外は、図9の例と同様である。半導体素子55は、筐体51の内部に配置されている。半導体素子55には、通気及び/又は通音用の開口が設けられていてもよい。このとき、当該開口を有する半導体素子55の面に垂直に見て、当該開口を第2基材層4が囲んでいてもよい。半導体素子55の例は、気圧、湿度、ガス、エアフロー又は加速度等を検出する各種のセンサー素子、並びにスピーカー及びマイクロフォン等の音響変換素子である。カバー部材1は、開口52及び半導体素子55の開口を介した通気及び/又は音の透過を確保しながら筐体51の外部から半導体素子55への異物の通過を防ぐ部材として機能しうる。
 カバー部材1を使用する態様は、上記例に限定されない。
 カバー部材1は、例えば、保護膜2、基材フィルム11,18及びタブフィルム5の形状加工及び積層により形成できる。
 [部材供給アセンブリ]
 カバー部材1は、部材供給用のシートにより供給可能である。当該シートによるカバー部材1の供給態様である部材供給アセンブリの一例を図11に示す。図11の部材供給アセンブリ41は、部材供給用のシート31と、シート31上に配置された1又は2以上のカバー部材1とを備える。各カバー部材1では、第1基材層3がシート31に面している。部材供給アセンブリ41によれば、例えば、対象物の面に配置する工程に対してカバー部材1を効率的に供給できる。
 シート31上へのカバー部材1の配置の例を図12及び図13に示す。図12の例では、図1Aのカバー部材1Aがシート31上に配置されている。図13の例では、図8Aのカバー部材1Cがシート31上に配置されている。シート31へのカバー部材1の配置には、粘着剤層16(図5参照)が利用できる。また、カバー部材1は、シート31におけるカバー部材1の配置面に設けられた粘着剤層を介して、シート31上に配置されていてもよい。配置面の粘着剤層は、弱粘着性であることが好ましい。
 シート31を構成する材料の例は、紙、金属、樹脂及びこれらの複合材料である。金属は、例えば、ステンレス及びアルミニウムである。樹脂は、例えば、PET等のポリエステル、PE及びPP等のポリオレフィンである。ただし、シート31を構成する材料は、上記例に限定されない。
 シート31の厚さは、例えば、1~250μmである。
 図11の部材供給アセンブリ41は、シート31の主面に垂直に見て、長方形のシート31を備えている。ただし、シート31の形状は、この例に限定されない。シート31の形状は、シート31の主面に垂直に見て、長方形以外の多角形(例えば正方形)、円、楕円又は帯状であってもよい。多角形の角は、丸められていてもよい。
 図11の部材供給アセンブリ41では、複数のカバー部材1は、シート31上に規則的に整列して配置されている。より具体的には、複数のカバー部材1は、配置面上の仮想の格子の交点に配置されている。ただし、部材供給アセンブリ41におけるカバー部材1の配置の形態は、上記例に限定されない。
 図11の部材供給アセンブリ41は、当該アセンブリ41の主面に垂直に見て、長方形である。ただし、部材供給アセンブリ41の形状は、上記例に限定されない。部材供給アセンブリ41の形状は、当該アセンブリ41の主面に垂直に見て、長方形以外の多角形(例えば正方形)、円、楕円又は帯状であってもよい。多角形の角は、丸められていてもよい。部材供給アセンブリ41の形状は、シート31の形状と同じであってもよい。帯状の部材供給アセンブリ41は、通常、帯状のシート31を備える。帯状の部材供給アセンブリ41は、巻回体としてもよい(巻回されて巻回体を構成してもよい)。帯状の部材供給アセンブリ41は、巻芯に巻回されて巻回体を構成してもよい。
 部材供給アセンブリ41は、シート31上にカバー部材1を配置して製造できる。
 以下、実施例により、本発明を更に詳細に説明する。ただし、本発明は、実施例に示す態様に限定されない。
 最初に、カバー部材の評価方法を示す。
 [部材供給用のシートからのカバー部材の剥離性]
 実施例及び比較例の各カバー部材について、部材供給用のシートからの剥離性を以下のように評価した。作製したカバー部材を温度23℃、湿度65%RHの雰囲気に24時間放置して、カバー部材を構成する各層の間の接合及びカバー部材と部材供給用のシートとの間の接合を安定させた。次に、カバー部材の側面(実施例1,2及び比較例1~3)又はタブフィルムのタブ(実施例3~7、比較例4,5)をピンセットで把持して持ち上げることにより、部材供給用のシートからカバー部材を剥離した。亀裂等の破損が保護膜に生じず、かつ部材供給用のシートを折り曲げることなくカバー部材を剥離できた場合を優(◎)、亀裂等の破損は保護膜に生じなかったが、カバー部材の剥離には部材供給用のシートの折り曲げ(カバー部材の配置面を外面とする折り曲げ)が必要であった場合を劣(△)、部材供給用のシートを折り曲げたにもかかわらず、剥離時に亀裂等の破損が保護膜に生じた場合を不可(×)とした。
 [タブフィルムの剥離時における保護膜の破損の有無]
 第1基材層、第2基材層及びタブフィルムを備える実施例3~7及び比較例4,5の各カバー部材について、以下のように、タブフィルムの剥離時における保護膜の破損の有無を評価した。作製したカバー部材を温度23℃、湿度65%RHの雰囲気に24時間放置して、カバー部材を構成する各層の間の接合及びカバー部材と部材供給用のシートとの間の接合を安定させた。次に、タブフィルムのタブをピンセットで把持して持ち上げることにより、部材供給用のシートからカバー部材を剥離した。次に、剥離したカバー部材を、第1基材層を介してポリカーボネート板の表面に貼り付けた。次に、ピンセットでタブを把持して、タブフィルムを第2基材層から剥離した。このとき、保護膜に亀裂等の破損が生じた場合を破損有り(×)、生じなかった場合を破損無し(〇)とした。
 [第1基材層と部材供給用のシートとの剥離力]
 第1基材層と部材供給用のシートとの剥離力は、実施例及び比較例の各カバー部材の作製とは別に、JIS Z0237:2009に定められた180°引きはがし粘着力の測定方法に準拠して、以下のように評価した。
 最初に、各カバー部材に使用した部材供給用のシートと、各カバー部材において当該シートに接する両面粘着テープとを準備した。次に、シートと両面粘着テープとを温度23℃、湿度65%RHの雰囲気下にて貼り合わせ、当該雰囲気に24時間放置して、両者の間の接合を安定させた。貼り合わせる際には、質量2kgの圧着ローラを一往復させた。次に、シート及び両面粘着テープの積層体を長方形(長さ120mm×幅30mm)に切り出して試験片を得た。次に、測定温度23℃、測定湿度65%RH及び引張速度300mm/分の測定条件にて、両面粘着テープをシートから引き剥がす180°引きはがし試験を実施して、180°引きはがし粘着力(単位:N/30mm)を測定した。引張試験機には、卓上型精密万能試験機オートグラフAGS-X(島津製作所製)を用いた。得られた180°引きはがし粘着力を、第1基材層とシートとの剥離力とした。
 [第1基材層を備えるカバー部材]
 (実施例1)
 <保護膜の準備>
 PTFEファインパウダー(ダイキン工業製、ポリフロンPTFE F-104)100重量部と、成形助剤としてn-ドデカン(ジャパンエナジー製)20重量部とを均一に混合した。得られた混合物をシリンダーを用いて圧縮した後、ラム押出成形して、シート状の混合物を形成した。次に、シート状の混合物を一対の金属ロールを通して厚さ0.2mmに圧延し、更に150℃の加熱により成形助剤を除去して、PTFEシート成形体を形成した。次に、形成したシート成形体を、延伸温度260℃、延伸倍率1.5倍で長手方向に延伸した。次に、延伸温度150℃、延伸倍率6.5倍で幅方向に延伸し、更に360℃で10分焼成して、PTFE延伸多孔質膜である保護膜Aを得た。保護膜Aの凝集力は、2.0N/20mmであった。保護膜Aの凝集力は、上述の方法により評価した。
 次に、保護膜Aの一方の主面に不織布(厚さ270μm、目付70g/m2)を接合して、保護膜Bを得た。この不織布は、PETをコアとし、ポリエチレンを鞘とする芯鞘構造を有する複合繊維からなっていた。保護膜A及び不織布は、熱ラミネート(温度200℃、圧力0.2MPa)により接合した。
 <第1基材層の準備>
 両面粘着テープA(日東電工製、No.57120B、厚さ100μm)、PETフィルムA(東レ製、ルミラー#25S10、厚さ25μm、非発泡)及び両面粘着テープB(日東電工製、No.5603、厚さ30μm)の積層体(この順に各層が配置)を準備した。両面粘着テープAの基材は、PEの発泡フィルム(厚さ60μm)であった。両面粘着テープBの基材は、PETの非発泡フィルム(厚さ12.5μm)であった。次に、外形11mm×10mm、内形6.8mm×3.8mmの額縁状に積層体を打ち抜き加工して、第1基材層Aを得た。第1基材層Aは、基材フィルムとして、2層の非発泡フィルムと1層の発泡フィルムとを備えていた。両面粘着テープA,Bの粘着剤は、アクリル系であった。
 <部材供給用のシートの準備>
 部材供給用のシートとして、PETシート(ニッパ製、PET75x1-JOL、厚さ75μm)を準備した。シートは、長さ160mm及び幅60mmの長方形とした。
 <カバー部材の作製>
 保護膜Bと第1基材層Aとを、第1基材層Aの両面粘着テープBにより接合した。接合は、両面粘着テープBとPTFE延伸多孔質膜とが接するように実施した。次に、全体を外径9mm×6mmの長方形に打ち抜き加工して、実施例1のカバー部材を得た。打ち抜き加工は、額縁状である第1基材層Aの内形の中心が当該加工後の全体の中心と一致するように実施した。次に、カバー部材を部材供給用のシートに両面粘着テープAを介して配置した。この状態で、第1基材層Aが備える基材フィルムのうち、両面粘着テープAの基材である発泡フィルムが、保護膜Bから最も離れ、かつ部材供給用のシートに最も近い位置にあった。
 (実施例2)
 保護膜Aに接合する不織布として、PETをコアとし、低融点共重合ポリエステルを鞘とする芯鞘構造を有する複合繊維からなる不織布(厚さ105μm、目付30g/m2)を使用した以外は実施例1と同様にして、カバー部材を得た。実施例2のカバー部材が備える保護膜を保護膜Cとする。カバー部材は、第1基材層Aの両面粘着テープAを介して、部材供給用のシートに配置した。
 (比較例1)
 第1基材層Aの代わりに第1基材層Bを使用した以外は実施例1と同様にして、カバー部材を得た。第1基材層Bには、両面粘着テープC(日東電工製、No.5610、厚さ100μm)を使用した。両面粘着テープCの基材は、PETの非発泡フィルム(厚さ50μm)であった。第1基材層Bは、基材フィルムとして、1層の非発泡フィルムを備えていた。両面粘着テープCの粘着剤は、アクリル系であった。カバー部材は、第1基材層Bの両面粘着テープCを介して、部材供給用のシートに配置した。
 (比較例2)
 第1基材層Aの代わりに第1基材層Cを使用した以外は実施例2と同様にして、カバー部材を得た。第1基材層Cには、両面粘着テープAを使用した。第1基材層Cは、基材フィルムとして、1層の発泡フィルムを備えていた。カバー部材は、第1基材層Cの両面粘着テープAを介して、部材供給用のシートに配置した。
 (比較例3)
 第1基材層Aの代わりに第1基材層Bを使用した以外は実施例2と同様にして、カバー部材を得た。比較例3のカバー部材は、第1基材層Bの両面粘着テープCを介して、部材供給用のシートに配置した。
 第1基材層の構成を表1に示す。実施例1,2及び比較例1~3の構成及び評価結果を表2に示す。表1の「発泡」及び「非発泡」は、それぞれ、両面粘着テープの基材が発泡フィルム及び非発泡フィルムであることを示す。
Figure JPOXMLDOC01-appb-T000001
Figure JPOXMLDOC01-appb-T000002
 表1に示すように、非発泡フィルム及び発泡フィルムを第1基材層が備える実施例のカバー部材は、比較例のカバー部材に比べて剥離性に優れていた。
 [第1基材層、第2基材層及びタブフィルムを備えるカバー部材]
 (実施例3)
 <第2基材層の準備>
 両面粘着テープC及びPETフィルムB(東レ製、ルミラー#50S10、厚さ50μm、非発泡)の積層体を準備した。次に、積層体を、外形11mm×10mm、内形6.8mm×3.8mmの額縁状に打ち抜き加工して、第2基材層Aを得た。
 <カバー部材の作製>
 保護膜Aの一方の面に対して第1基材層Aを、第1基材層Aの両面粘着テープBにより接合した。次に、保護膜Aの他方の面に対して第2基材層Aを、第2基材層Aの両面粘着テープCにより接合した。第2基材層Aの接合は、保護膜Aの主面に垂直に見て、額縁状である第1基材層A及び第2基材層の各々の内形が一致するように実施した。次に、全体を外径9mm×6mmの長方形に打ち抜き加工して、カバー部材を得た。打ち抜き加工は、第1基材層A及び第2基材層Aの内形の中心が当該加工後の全体の中心となるように実施した。次に、カバー部材を部材供給用のシートに第1基材層Aの両面粘着テープAを介して配置した。この状態で、第1基材層Aが備える基材フィルムのうち、両面粘着テープAの基材である発泡フィルムが、保護膜Aから最も離れ、かつ部材供給用のシートに最も近い位置にあった。
 (実施例4)
 第2基材層Aの代わりに第2基材層Bを使用した以外は実施例3と同様にして、カバー部材を得た。第2基材層Bには、両面粘着テープB及びPETフィルムBの積層体を使用した。第2基材層Bは、第2基材層Bの両面粘着テープBにより保護膜Aに接合した。カバー部材は、第1基材層Aの両面粘着テープAを介して、部材供給用のシートに配置した。この状態で、第1基材層Aが備える基材フィルムのうち、両面粘着テープAの基材である発泡フィルムが、保護膜Aから最も離れ、かつ部材供給用のシートに最も近い位置にあった。
 (実施例5)
 第1基材層Aの代わりに第1基材層Dを使用した以外は実施例4と同様にして、カバー部材を得た。第1基材層Dには、両面粘着テープD(日東電工製、No.57115B、厚さ150μm)、PETフィルムA及び両面粘着テープBの積層体(この順に各層が配置)を準備した。両面粘着テープDの基材は、ポリエチレンの発泡フィルム(厚さ80μm)であった。第1基材層Dは、基材フィルムとして、2層の非発泡フィルムと1層の発泡フィルムとを備えていた。両面粘着テープDの粘着剤は、アクリル系であった。第1基材層Dは、第1基材層Dの両面粘着テープBにより保護膜Aに接合した。カバー部材は、第1基材層Dの両面粘着テープDを介して、部材供給用のシートに配置した。この状態で、第1基材層Dが備える基材フィルムのうち、両面粘着テープDの基材である発泡フィルムが、保護膜Aから最も離れ、かつ部材供給用のシートに最も近い位置にあった。
 (実施例6)
 第1基材層Aの代わりに第1基材層Eを使用した以外は実施例4と同様にして、カバー部材を得た。第1基材層Eには、両面粘着テープE(日東電工製、No.57120B、厚さ200μm)、PETフィルムA及び両面粘着テープBの積層体(この順に各層が配置)を準備した。両面粘着テープEの基材は、ポリエチレンの発泡フィルム(厚さ100μm)であった。第1基材層Eは、基材フィルムとして、2層の非発泡フィルムと1層の発泡フィルムとを備えていた。両面粘着テープEの粘着剤は、アクリル系であった。第1基材層Eは、第1基材層Eの両面粘着テープBにより保護膜Aに接合した。カバー部材は、第1基材層Eの両面粘着テープEを介して、部材供給用のシートに配置した。この状態で、第1基材層Eが備える基材フィルムのうち、両面粘着テープEの基材である発泡フィルムが、保護膜Aから最も離れ、かつ部材供給用のシートに最も近い位置にあった。
 (実施例7)
 第1基材層Aの代わりに第1基材層Fを使用した以外は実施例4と同様にして、カバー部材を得た。第1基材層Fには、両面粘着テープA及び両面粘着テープBの積層体を準備した。第1基材層Fは、基材フィルムとして、1層の非発泡フィルムと1層の発泡フィルムとを備えていた。第1基材層Fは、第1基材層Fの両面粘着テープBにより保護膜Aに接合した。カバー部材は、第1基材層Fの両面粘着テープAを介して、部材供給用のシートに配置した。この状態で、第1基材層Fが備える基材フィルムのうち、両面粘着テープAの基材である発泡フィルムが、保護膜Aから最も離れ、かつ部材供給用のシートに最も近い位置にあった。
 (比較例4)
 第1基材層Aの代わりに第1基材層Bを使用した以外は実施例3と同様にして、カバー部材を得た。カバー部材は、第1基材層Bの両面粘着テープCを介して、部材供給用のシートに配置した。
 (比較例5)
 第1基材層Aの代わりに第1基材層Cを使用した以外は実施例3と同様にして、カバー部材を得た。カバー部材は、第1基材層Bの両面粘着テープAを介して、部材供給用のシートに配置した。
 第1基材層及び第2基材層の構成を、それぞれ、表3,4に示す。実施例3~7及び比較例4,5の構成及び評価結果を表5に示す。表3の「発泡」及び「非発泡」は、それぞれ、両面粘着テープの基材が発泡フィルム及び非発泡フィルムであることを示す。
Figure JPOXMLDOC01-appb-T000003
Figure JPOXMLDOC01-appb-T000004
Figure JPOXMLDOC01-appb-T000005
 表5に示すように、非発泡フィルム及び発泡フィルムを第1基材層が備える実施例のカバー部材は、比較例のカバー部材に比べて剥離性に優れていた。また、発泡フィルムのみを第1基材層が備える比較例5のカバー部材では、タブフィルムの剥離時に保護膜の破損が生じた。これは、第1基材層が過度に柔軟であることでタブフィルムを剥離する際の保護膜の変形が大きくなり、凝集破壊したためと推定される。なお、比較例4のカバー部材は、部材供給用のフィルムから剥離する際に保護膜が破損したため、タブフィルムの剥離時における保護膜の破損の有無は評価不能であった。
 本発明のカバー部材は、保護膜を備える従来のカバー部材と同様の用途に使用できる。

Claims (14)

  1.  開口を有する面を持つ対象物の当該面に配置されて、前記開口における異物の通過を防ぐカバー部材であって、
     前記カバー部材が前記面に配置されたときに前記開口を覆う形状を有する保護膜と、
     前記保護膜の一方の主面に接合された第1基材層と、を備え、
     前記第1基材層は、2以上の基材フィルムを含む積層構造を有すると共に、前記カバー部材が前記面に配置されたときに前記保護膜と前記面との間に位置し、
     前記2以上の基材フィルムは、非発泡フィルムと発泡フィルムとを備える、カバー部材。
  2.  前記発泡フィルムは、前記非発泡フィルムよりも前記保護膜から離れた位置にある、請求項1に記載のカバー部材。
  3.  前記第1基材層において、前記保護膜から最も離れた位置にある前記基材フィルムが前記発泡フィルムである、請求項1又は2に記載のカバー部材。
  4.  前記保護膜は、厚さ方向の通気性を有する、請求項1~3のいずれかに記載のカバー部材。
  5.  前記保護膜は、ポリテトラフルオロエチレン延伸多孔質膜を含む、請求項1~3のいずれかに記載のカバー部材。
  6.  前記保護膜の凝集力が2.0N/20mm以下である、請求項1~5のいずれかに記載のカバー部材。
  7.  前記第1基材層は、前記保護膜の主面に垂直に見て、前記保護膜の外周に一致する外周を有する、請求項1~6のいずれかに記載のカバー部材。
  8.  前記カバー部材は、1又は2以上の前記基材フィルムを備える第2基材層を更に備え、
     前記第2基材層は、前記保護膜の他方の主面に接合されて、前記第1基材層と共に前記保護膜を挟持している、請求項1~7のいずれかに記載のカバー部材。
  9.  前記第2基材層は、前記基材フィルムとして非発泡フィルムのみを備える、請求項8に記載のカバー部材。
  10.  前記第1基材層及び前記第2基材層の各々において前記保護膜に最も近い位置にある前記基材フィルムの構成が同一である、請求項8又は9に記載のカバー部材。
  11.  前記第2基材層は、前記保護膜の主面に垂直に見て、前記保護膜の外周に一致する外周を有する、請求項8~10のいずれかに記載のカバー部材。
  12.  前記カバー部材は、前記カバー部材が前記面に配置されたときに前記面から最も離れた位置にある前記カバー部材の最外層の上に配置されたタブフィルムを更に備え、
     前記タブフィルムは、前記最外層の主面に垂直に見て、前記最外層の外周よりも外方に突出した部分を有する請求項1~11のいずれかに記載のカバー部材。
  13.  部材供給用のシートと、前記シート上に配置されたカバー部材と、を備え、
     前記カバー部材は、請求項1~12のいずれかに記載のカバー部材であり、
     前記カバー部材の前記第1基材層が前記シートに面している、部材供給アセンブリ。
  14.  前記部材供給アセンブリは帯状であり、巻回されて巻回体を構成している請求項13に記載の部材供給アセンブリ。
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