Classifications

• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
  • A61K8/00—Cosmetics or similar toiletry preparations
  • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
  • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
  • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
  • A61K8/00—Cosmetics or similar toiletry preparations
  • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
  • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
  • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
  • A61K8/34—Alcohols
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
  • A61K8/00—Cosmetics or similar toiletry preparations
  • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
  • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
  • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
  • A61K8/35—Ketones, e.g. benzophenone
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
  • A61K8/00—Cosmetics or similar toiletry preparations
  • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
  • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
  • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
  • A61K8/37—Esters of carboxylic acids
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
  • A61K8/00—Cosmetics or similar toiletry preparations
  • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
  • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
  • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
  • A61K8/41—Amines
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
  • A61K8/00—Cosmetics or similar toiletry preparations
  • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
  • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
  • A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
  • A61K8/00—Cosmetics or similar toiletry preparations
  • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
  • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
  • A61K8/60—Sugars; Derivatives thereof
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
  • A61K8/00—Cosmetics or similar toiletry preparations
  • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
  • A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
  • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
  • A61Q1/02—Preparations containing skin colorants, e.g. pigments
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
  • A61Q15/00—Anti-perspirants or body deodorants
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
  • A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
  • A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
  • A61Q19/00—Preparations for care of the skin
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
  • A61Q19/00—Preparations for care of the skin
  • A61Q19/10—Washing or bathing preparations
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
  • A61Q5/00—Preparations for care of the hair
  • A61Q5/02—Preparations for cleaning the hair
• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
  • C11D3/16—Organic compounds
  • C11D3/20—Organic compounds containing oxygen
• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
  • C11D3/16—Organic compounds
  • C11D3/26—Organic compounds containing nitrogen
  • C11D3/30—Amines; Substituted amines ; Quaternized amines

Definitions

• the present invention relates to cosmetics and cleaning agents, and more particularly to cosmetics and cleaning agents which are applied to the hair, scalp or skin, and which have an excellent refreshing feeling.
• the present invention has been made in view of the above prior art, and a problem to be solved is to provide a cosmetic and a cleansing agent having an excellent refreshing feeling.
• the cosmetics and cleaning agents according to the present invention are characterized by containing the components (a) and (b).
• A a cooling agent
• the primary amine (b) is represented by the following formula (I).
• (Formula 1) NH 2 —C (R 1 ) 2 —CH 2 —R 2 (I)
• R 1 is a hydrogen atom or a methyl group
• R 2 is a functional group selected from OH, SO 2 H, SO 2 SH, and SO 3 H.
• the secondary amine is preferably represented by the following formula (II).
• R 3 is an alkyl group having 1 to 9 carbon atoms
• R 2 is any one selected from OH, SO 2 H, SO 2 SH, and SO 3 H.
• the compounding amount of the component (a) is 0.2 to 1.2% by mass.
• the pH is 6.5 or less.
• the refreshing agent is menthol, peppermint oil, l-menthyl glyceryl ether, menthyl lactate, camphor, isopulegol, borneol, cineolmentone, spearmint, peppermint, menthyl malonate, glycosyl- One or more TRP M8 activators selected from the group consisting of mono-menthyl-O-acetate, 3-L-menthoxypropane-1,2-diol and 1-menthyl-3-hydroxybutyrate It is preferred that the cosmetics and cleaning agents contain 0.1 to 1.0% by mass of a cationic polysaccharide. It is preferable that the cosmetics and cleaning agents include an anionic surfactant.
• the cosmetics and cleaning agents according to the present invention are characterized by containing the components (a) and (b).
• Cooling agent As the cooling agent, those usually used for cosmetics and cleaning agents can be used.
• Refreshing agents include menthol, peppermint oil, l-menthyl glyceryl ether, menthyl lactate, camphor, isopulegol, borneol, cineolmentone, spearmint, peppermint, menthyl malonate, glycosyl-mono-menthyl-O-acetate, 3-L
• TRP M8 activators selected from the group consisting of -menthoxypropane-1,2-diol and 1-menthyl-3-hydroxybutyrate are preferred.
• menthol, peppermint oil, l-menthyl glyceryl ether and menthyl lactate are more preferable.
• the blending amount of the cooling agent in the present invention is preferably 0.2 to 1.2% by mass based on the total amount of the cosmetic or cleaning agent. If the amount is less than 0.2% by mass, the refreshing feeling may be poor. If the amount is more than 1.2% by mass, the stimulus that causes pain to the skin and eyes becomes too strong, which is not preferable.
• (B) primary amine and / or secondary amine having no amide bond and no alkyl chain having 10 or more carbon atoms in the molecule As the primary amine or secondary amine and / or secondary amine having no amide bond and no alkyl chain having 10 or more carbon atoms in the molecule, those commonly used in cosmetics and cleaning agents can be used.
• the primary amine (b) is represented by the following formula (I). (Formula 3) NH 2 —C (R 1 ) 2 —CH 2 —R 2 (I)
• R 1 is a hydrogen atom or a methyl group
• R 2 is a functional group selected from OH, SO 2 H, SO 2 SH, and SO 3 H.
• the primary amine having no amide bond or an alkyl chain having 10 or more carbon atoms in the molecule include, for example, taurine, hypotaurine, thiotaurine, 2-amino-2-methyl-1-propanol, monoethanolamine and the like. Is mentioned.
• the secondary amine is preferably represented by the following formula (II).
• R 3 is an alkyl group having 1 to 9 carbon atoms
• R 2 is any one selected from OH, SO 2 H, SO 2 SH, and SO 3 H.
• Specific examples of the secondary amine having no amide bond and no alkyl chain having 10 or more carbon atoms in the molecule include N-methyltaurine and diethanolamine.
• taurine or N-methyltaurine is used as the component (b).
• examples of commercially available taurine include aminoethylsulfonic acid (manufactured by Mutual Pharmaceutical Co., Ltd.).
• Commercial products containing N-methyltaurine include MTS-50 (manufactured by Clariant).
• the compounding amount of the primary amine and / or the secondary amine having no amide bond and no alkyl chain having 10 or more carbon atoms in the molecule is 0.1 to 1.2% by mass based on the total amount of the cosmetic or cleaning agent. Is preferred. If the amount is less than 0.1% by mass, the refreshing feeling may be poor. If the amount is more than 1.2% by mass, the feeling of cooling may be inferior or the viscosity of the composition may not be increased, and the stickiness after use may be significantly increased.
• (b) / (a) 0.01 to 20, which is the mixing ratio of the component (b) and the component (a).
• the duration of the refreshing feeling may be short.
• the refreshing feeling may be poor.
• the cationic polysaccharide is contained in an amount of 0.1 to 1.0% by mass based on the total amount of the cosmetics or cleaning agent.
• the cationic polysaccharide include cationized guar gum, cationized cellulose, cationized locust bean gum, cationized cod gum, cationized fenugreek gum, and cationized starch.
• the cosmetic and cleaning agent according to the present invention contain an anionic surfactant.
• anionic surfactant include sodium laurate, potassium laurate, coconut oil fatty acid sodium, coconut oil fatty acid potassium, sodium myristate, potassium myristate, sodium palmitate, potassium palmitate, triethanolamine palmitate, Higher fatty acid salts such as sodium stearate, potassium stearate, sodium behenate and potassium behenate; alkyl ether sulfates such as sodium polyoxyethylene lauryl ether sulfate, ammonium polyoxyethylene lauryl ether sulfate and triethanolamine polyoxyethylene lauryl ether sulfate Salts: alkyl sulfates such as sodium lauryl sulfate and triethanolamine lauryl sulfate; sodium tetradecene sulfonate, tetradecenesul ⁇ -olefin sulfonates such as potassium phosphate; sodium N-lauroy
• the cosmetic and cleaning agent according to the present invention contain an anionic surfactant
• the cationic surfactant By adding a large amount of the cationic surfactant, a complex may be formed with the anionic surfactant, and the stability may be poor.
• cationic surfactant examples include stearyltrimethylammonium chloride, cetyltrimethylammonium chloride, behenyltrimethylammonium chloride, distearyldimethylammonium chloride, dioleyldimethylammonium chloride, didecyldimethylammonium chloride, amidobutylguanidine acetate laurate, Amidobutyl guanidine myristate acetate, amide guanidine butyl palmitate, distearyl dimethyl ammonium sulfate, stearyl ethyl dihydroxyethyl ammonium ethyl sulfate, N-coconut oil fatty acid L-arginine ethyl DL-pyrrolidone carboxylate, dimethylaminoethyl stearate Amide, dimethylaminopropylamide stearate, diethylaminoethyl stearate Amides, diethyl
• the cosmetics and cleaning agents according to the present invention include, in addition to the above-mentioned components, components usually used in cosmetics or cleaning agents, such as amphoteric surfactants, liquid oils, semi-solid oils, solid oils, powders, and film agents. , A humectant, an ultraviolet absorber, a warming agent, a cosmetic ingredient, a fiber, a fragrance, water and the like can be blended within a range that does not impair the effects of the present invention.
• amphoteric surfactant examples include coconut oil fatty acid amidopropyl betaine, octyldimethylaminoacetic acid betaine, lauryldimethylaminoacetic acid betaine, lauric acid amidopropyl betaine, coconut oil fatty acid alkyldimethylaminoacetic acid betaine, myristyldimethylaminoacetic acid betaine, and cetyldimethyl.
• Carbobetaine type amphoteric surfactants such as betaine aminoacetate, betaine coconut fatty acid amidopropyldimethylaminoacetate betaine, betaine laurate amidopropyldimethylaminoacetate betaine, lauryldihydroxyethylaminoacetate betaine, and cetyldihydroxyethylaminoacetate betaine; Sulfobetaine-type amphoteric surfactants such as betaine and lauryl sulfobetaine, 2-alkyl-N-carboxymethyl-N-hydroxyethyl Ampho (di) acetic acid type amphoteric surfactants such as imidazolinium betaine, N-coconut fatty acid acyl-N-carboxymethoxyethyl-N-carboxymethylethylenediamine disodium, sodium laurylaminodiacetate, coconut oil alkylaminodiacetic acid Alkyl iminodicarboxylate type amphoteric surfactants such
• liquid oil component examples include silicone oil, polar oil component, hydrocarbon oil, natural animal and vegetable oil, and semi-synthetic oil.
• silicone oil examples include non-volatile silicone oils such as dimethylpolysiloxane having a polymerization degree of 6 or more, phenyltrimethicone, diphenyldimethicone, diphenylsiloxyphenyltrimethicone, and trimethylpentaphenyltrisiloxane; and dimethylpolysiloxane having a polymerization degree of 2 to 5.
• non-volatile silicone oils such as dimethylpolysiloxane having a polymerization degree of 6 or more, phenyltrimethicone, diphenyldimethicone, diphenylsiloxyphenyltrimethicone, and trimethylpentaphenyltrisiloxane; and dimethylpolysiloxane having a polymerization degree of 2 to 5.
• volatile silicone oils such as decamethylcyclopentasiloxane, octamethylcyclotetrasiloxane, dodecamethylcyclohexasiloxane, methyltrimethicone, dimethylpolysiloxane, decamethyltetrasiloxane, and ethyltrisiloxane.
• polar oils examples include glyceryl tri-2-ethylhexanoate, diisostearyl malate, glyceryl diisostearate, diglyceryl triisostearate, glyceryl tri (capryl / caprin) ate, neopentyl glycol dicaprate, tetra-2-ethyl Pentaerythrityl hexanoate, diethylhexyl sebacate, octyldodecanol, trimethylolpropane tri-2-ethylhexanoate, oxystearyl oxystearate, pentaerythrityl tetra (ethylhexanoate / benzoate), trioctanoin, tetraoctane Pentaerythrityl acid, dipentaerythrityl hexahydroxystearate, castor oil, diisopropyl sebacate, pentaeryth
• hydrocarbon oil examples include hydrogenated polyisobutene, liquid paraffin, squalane, squalene, heavy liquid isoparaffin, polyisobutylene, ⁇ -olefin oligomer and the like.
• Natural animal and vegetable oils and semi-synthetic oils include avocado oil, linseed oil, almond oil, olive oil, kaya oil, liver oil, kyounin oil, wheat germ oil, sesame oil, rice germ oil, rice bran oil, sasanqua oil, safflower oil, cinnamon oil Oil, cinnamon oil, turtle oil, soybean oil, teaseed oil, camellia oil, evening primrose oil, corn oil, rapeseed oil, Japanese kiri oil, germ oil, persic oil, palm oil, red palm oil, palm kernel oil, castor oil , Sunflower oil, grape oil, jojoba oil, macadamia nut oil, cottonseed oil, coconut oil, tricoconut oil fatty acid glyceride, peanut oil,
• semi-solid oil component examples include petrolatum, tetra (behenic acid / benzoic acid / ethylhexanoic acid) pentaerythrit, dipentaerythrityl hexahydroxystearate, dimer dilinoleate, macadamia nut oil polyglyceryl-6 ester sbehenate, tetra (Hydroxystearic acid / isostearic acid) dipentaerythrityl, bisdiglyceryl polyacyl adipate-2 and the like.
• petrolatum tetra (behenic acid / benzoic acid / ethylhexanoic acid) pentaerythrit, dipentaerythrityl hexahydroxystearate, dimer dilinoleate, macadamia nut oil polyglyceryl-6 ester sbehenate
• tetra Hydroxystearic acid / iso
• solid oils and fats examples include solid oils and fats, waxes, solid hydrocarbons, and higher alcohols.
• solid oils such as cocoa butter and hydrogenated castor oil
• waxes such as mocro, carnauba wax, beeswax, salami beeswax, candelilla wax and jojoba wax: hydrocarbon waxes such as polyethylene wax, paraffin wax, ceresin, and microcrystalline wax; cetyl; Higher alcohols such as alcohol, stearyl alcohol, behenyl alcohol, and butyl alcohol; silicone wax;
• Examples of the powder include a spherical powder, a plate-like powder, and a coloring material.
• spherical powder examples include spherical particles such as polymethyl methacrylate, organopolysiloxane elastomer, polystyrene, polyamide resin (nylon), polyethylene, copolymer of styrene and acrylic acid, benzoguanamine resin, polytetrafluoroethylene, and silicone resin. Resin powder.
• the plate-like powder examples include mica, synthetic mica, talc, sericite, aluminum oxide, magnesium oxide, zirconium oxide, magnesium carbonate, calcium carbonate, calcium sulfate, chromium oxide, chromium hydroxide, aluminum silicate, magnesium silicate, and silicate.
• Inorganic powders such as aluminum magnesium, kaolin, silicon carbide, barium sulfate, bentonite, smectite, and boron nitride; organic powders such as N-acyl lysine; mica titanium coated with fine particle titanium oxide; mica titanium coated with fine particle zinc oxide; barium sulfate Composite powders such as coated mica titanium and the like can be mentioned.
• coloring materials include inorganic white pigments (titanium dioxide, zinc oxide), inorganic red pigments (iron oxide (iron oxide), iron titanate), inorganic brown pigments ( ⁇ -iron oxide), and inorganic yellow pigments Pigments (yellow iron oxide, loess), inorganic black pigments (black iron oxide, carbon, low titanium oxide), inorganic purple pigments (mango violet, cobalt violet), inorganic green pigments (chromium oxide, chromium hydroxide, Cobalt titanate), inorganic blue pigments (ultramarine, navy blue), pearl pigments (titanium oxide coated mica, titanium oxide coated bismuth oxychloride, titanium oxide coated talc, colored titanium oxide coated mica, bismuth oxychloride, fish scale foil), metal Powder pigments (aluminum powder, copper powder), organic pigments (red 202, red 205, red 220, red 228, red 405, orange) Color No.
• inorganic white pigments titanium dioxide, zinc oxide
• Yellow 4 Yellow 202, green 3, blue 1
• natural pigments chlororophyll, carcinoids ( ⁇ -carotene), calsamine, cochineal, chalcone, curcumin, betanin, flavonol, flavone, anthocyanidin, anthraquinone, naphthoquinone ), Functional pigments (boron nitride, photochromic pigments, synthetic fluorophlogopite, iron-containing synthetic fluorophlogopite, fine-particle composite powder (hybrid fine powder)), and the like.
• film-forming agent examples include siliconized pullulan, trimethylsiloxysilicic acid, quaternary salt of dimethylaminomethacrylate, vinylpyrrolidone / methacrylic acid-N, N-dimethyl-ethylantinioethyl salt copolymer, and silicone / polyether polyurethane.
• humectants include dipropylene glycol, polyethylene glycol, propylene glycol, glycerin, diglycerin, decaglycerin, 1,3-butylene glycol, xylitol, sorbitol, maltitol, erythritol, chondroitin sulfate, hyaluronic acid, mucoitin sulfate, Carolinic acid, atelocollagen, cholesteryl-12-hydroxystearate, sodium lactate, bile salts, dl-pyrrolidone carboxylate, short-chain soluble collagen, diglycerin (EO) PO adduct, lycopodium extract, Achillea millefolium extract, Melilot extract and the like.
• EO diglycerin
• the ultraviolet absorber examples include benzoic acid-based ultraviolet absorbers (for example, paraaminobenzoic acid (hereinafter abbreviated as PABA), PABA monoglycerin ester, N, N-dipropoxy PABA ethyl ester, N, N-diethoxy PABA ethyl ester , N, N-dimethyl PABA ethyl ester, N, N-dimethyl PABA butyl ester, N, N-dimethyl PABA ethyl ester, etc.); anthranilic acid type ultraviolet absorbers (eg, homomenthyl-N-acetylanthranilate, etc.); Salicylic acid-based ultraviolet absorbers (eg, amyl salicylate, menthyl salicylate, homomenthyl salicylate, octyl salicylate, phenyl salicylate, benzyl salicylate, p-isopropanol phenyl salicylate, etc.);
• warming sensate examples include pepper tincture, capsaicin, capsinoid, vanillyl butyl ether and the like.
• incorporable components include, for example, preservatives (eg, ethyl paraben, butyl paraben); whitening agents (eg, placental extract, saxifrage extract, arbutin); blood circulation promoters (nicotinic acid, benzyl nicotinate, nicotine) Acid tocopherol, nicotinic acid ⁇ -butoxyester, minoxidil or an analog thereof, vitamin Es, ⁇ -oryzanol, alkoxycarbonylpyridine N-oxide, carpronium chloride, and acetylcholine or a derivative thereof; various extracts (eg, ginger, Ubak, spinach, spinach, birch, loquat, carrot, aloe, mallow, iris, grape, loofah, lily, saffron, senkyu, ginger, hypericum, ononis, garlic, capsicum, chimpanzee, cypress, button, seaweed, etc.), activation Agent (for example
• the cosmetic and cleaning agent of the present invention preferably have a pH of 6.5 or less. If the pH exceeds 6.5, the refreshing feeling may be poor. In addition, by setting the pH to 6.5 or less and using the cleaning agent, the cleaning agent can have not only a refreshing feeling but also excellent foaming and foam quality.
• the cosmetics and cleaning agents of the present invention are preferably cosmetics and cleaning agents applied to hair, scalp or skin.
• Specific examples include, for example, skin care cosmetics such as lotions and body lotions, hair and scalp cosmetics such as hair tonics, deodorant cosmetics, hair cleansing products such as shampoos, and skin cleansing products such as body soaps. No.
• the present invention will be described in more detail below with reference to examples, but the present invention is not limited thereto. Unless otherwise specified, the compounding amount is shown in mass% based on the system in which the component is compounded. Prior to the description of the examples, the evaluation test method used in the present invention will be described.
• Evaluation (1) Appearance After each sample was prepared, it was stored in a transparent glass container at 15 ° C. for 2 weeks, and then the appearance was determined. G: Transparent, no foreign matter floating or settling. B: Not transparent or foreign matter floating / sedimenting.
• Evaluation (2) Refreshing feeling Five professional panels evaluated the strength of the refreshing feeling during shampoo lathering against Test Example 1-1 (reference shampoo) in an actual use evaluation test comparing half heads as follows. did. A: Out of five specialized panels, four or more evaluated that “the refreshing feeling was enhanced”. B: Two or three of the five specialized panels evaluated that “the refreshing feeling was enhanced”. C: Out of the five specialized panels, one or less evaluated that “the refreshing feeling was enhanced”.
• Evaluation (3) Creamyness of foam
• Five professional panels evaluated the creamyness of foam when shampoo was used in an actual use evaluation test of half-head comparison as follows. A: Out of 5 panelists, 4 or more evaluated as “very creamy.” B: Two or three of the five expert panels rated “very creamy.” C: One of the five expert panels rated “very creamy”. D: None of the five expert panels rated "very creamy”.
• the present inventors produced a hair cleansing agent (hair shampoo) shown in Table 1 below by a conventional method and measured it by the above evaluation method. Table 1 shows the results.
• the cosmetics and cleaning agents according to the present invention have (a) a cooling agent and (b) an amide bond and an alkyl chain having 10 or more carbon atoms in the molecule. It was revealed that cosmetics and cleansers having excellent refreshing feeling can be obtained by containing 0.1 to 1.2% by mass of a secondary amine and / or a secondary amine.
• the present inventors produced a hair cleansing agent (hair shampoo) shown in Table 2 below by a conventional method and measured it by the above evaluation method. Table 2 shows the results.
• the pH is preferably 6.5 or less.
• the present inventors produced a hair cleansing agent (hair shampoo) shown in Table 3 below by a conventional method and measured it by the above evaluation method. Table 3 shows the results.
• the hair cleansing compositions containing cationic polysaccharides, cationized guar gum (Test Example 1-5) and cationized cellulose (Test Example 3-1) were excellent in refreshing feeling and creamy foam.
• a hair cosmetic containing a cationic polymer, polyquaternium-7 (Test Example 3-2) or (propyltrimonium chloride acrylamide / dimethylacrylamide) copolymer (Test Example 3-3) has a refreshing feeling and There was room for improvement in the creaminess of the foam.
• Formulation example 1 0.6% by mass of deodorant cosmetic menthol N-methyltaurine sodium 0.1 Ethanol 45 PPG-20 Decyltetradeceth-10 0.05 Fragrance 0.1 Water residue
• Formulation Example 2 Foamed aqueous cosmetic potassium cocoyl glutamate 0.1% by mass Lauryl betaine 0.07 PEG-60 hydrogenated castor oil 1.0 Glycerin 10.0 Dipropylene glycol 8.0 1,3-butylene glycol 4.0 Sorbitol 2.0 PEG400 2.0 Menthol 0.2 Phenoxyethanol 0.5 Taurine 0.2 Fragrance 0.1 Water residue
• Formulation Example 3 Cream POE (20) Sorbitan stearate 2.0% by mass Stearoyl methyl taurine sodium 0.5 POE (5) glyceryl stearate 0.2 Behenyl alcohol 1.8 Stearyl alcohol 1.8 Glyceryl stearate 1.0 Mineral oil 12.0 Cetyl ethylhexanoate 5.0 N-lauroyl glutamate di (phytosteryl / octyldodecyl) 2.0 Dipropylene glycol 5.0 Trehalose 1.0 Dipotassium glycyrrhizinate 0.1 Menthyl lactate 0.2 Acrylic acid / alkyl acrylate (C10-30) copolymer potassium 0.03 Taurine 0.1 Chelating agent qs Preservative appropriate amount Fragrance 0.1 Water residue
• Formulation Example 4 Essence POE (20) Sorbitan stearate 0.5% by mass Stearoyl methyl taurine sodium 0.05 Stearyl alcohol 0.5 Cetostearyl alcohol 0.6 Dimethicone 5.0 Glyceryl diisostearate 1.0 Ethanol 5.0 Butylene glycol 10.0 Glycerin 1.0 Tranexamic acid 1.0 N-methyltaurine sodium 0.3 Xanthan gum 0.05 Mint oil 0.1 l-menthyl glyceryl ether 0.2 Chelating agent qs Preservative appropriate amount Fragrance 0.15 Water residue
• Formulation Example 5 makeup base POE (20) sorbitan palmitate 0.8% by mass Stearoyl methyl taurine sodium 0.1 Behenyl alcohol 0.4 Butyl alcohol 0.2 Cyclomethicone 9.0 Phenyltrimethicone 5.0 Ethanol 2.0 Butylene glycol 5.0 Menthol 0.1 Menthyl lactate 0.1 Talc 2.0 Titanium dioxide 1.0 Citric acid 0.05 N-methyltaurine sodium 0.1 Cellulose gum 0.09 Chelating agent qs Preservative appropriate amount Water residue
• Formulation Example 6 Sunscreen cosmetics POE (20) Sorbitan stearate 1.0% by mass Stearoyl methyl taurine sodium 0.2 Behenyl alcohol 1.0 Cetostearyl alcohol 0.2 Glyceryl stearate 0.5 Cyclomethicone 10.0 Ethylhexyl methoxycinnamate 7.0 t-butylmethoxybenzoylmethane 1.0 Isostearic acid 0.5 Dimethicone copolyol 0.5 Butylene glycol 7.0 Dipropylene glycol 7.0 Menthol 0.2 Tranexamic acid 2.0 N-methyltaurine sodium 0.2 Chelating agent qs Preservative appropriate amount Water residue
• Formulation Example 7 Lotion Glycerin 5% by mass Butylene glycol 5 Taurine 0.2 Polyethylene glycol 1500 2 Phenoxyethanol 0.3 Trisodium edetate 0.02 Citric acid 0.03 N-methyltaurine sodium 0.02 Ethanol 5 POE ⁇ POP-decyltetradecyl ether (24E.O.) (13P.O.) 0.4 PPG-20 Decyltetradeceth-10 0.05 Menthol 0.1 Camphor 0.1 Water residue
• Formulation Example 8 emulsified foundation talc 3% by mass Titanium dioxide 4 Bengara 0.5 Yellow iron oxide 1.5 Black iron oxide 0.1 Bentonite 0.5 Polyoxyethylene sorbitan monostearate 1 N-methyltaurine sodium 0.8 Dipropylene glycol 8 Dicocoylethyl hydroxyethylmonium methosulfate 0.6 Ion exchange water residue Behenic acid 0.5 Stearyl alcohol 0.4 Isohexadecyl alcohol 6 Glycerin monostearate 2 Liquid lanolin 2 Liquid paraffin 6 Paraben 0.1 3-L-menthoxypropane-1,2-diol 0.3 Fragrance 0.05

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