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  • C22C—ALLOYS
  • C22C38/00—Ferrous alloys, e.g. steel alloys
  • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
  • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
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  • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
  • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
  • C22C38/58—Ferrous alloys, e.g. steel alloys containing chromium with nickel with more than 1.5% by weight of manganese
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  • C22C38/60—Ferrous alloys, e.g. steel alloys containing lead, selenium, tellurium, or antimony, or more than 0.04% by weight of sulfur
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  • C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
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  • C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
  • C21D1/56—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering characterised by the quenching agents
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  • C21D6/00—Heat treatment of ferrous alloys
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  • C21D7/00—Modifying the physical properties of iron or steel by deformation
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  • C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
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  • C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
  • C21D8/06—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of rods or wires
  • C21D8/065—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of rods or wires of ferrous alloys
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  • C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
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  • C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
  • C21D9/02—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for springs
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  • C21D9/52—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for wires; for strips ; for rods of unlimited length
  • C21D9/525—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for wires; for strips ; for rods of unlimited length for wire, for rods
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  • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
  • C22B9/00—General processes of refining or remelting of metals; Apparatus for electroslag or arc remelting of metals
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  • C22B9/00—General processes of refining or remelting of metals; Apparatus for electroslag or arc remelting of metals
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  • C22B9/00—General processes of refining or remelting of metals; Apparatus for electroslag or arc remelting of metals
  • C22B9/16—Remelting metals
  • C22B9/22—Remelting metals with heating by wave energy or particle radiation
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  • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
  • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
  • C22C38/52—Ferrous alloys, e.g. steel alloys containing chromium with nickel with cobalt
• • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
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  • F16F—SPRINGS; SHOCK-ABSORBERS; MEANS FOR DAMPING VIBRATION
  • F16F1/00—Springs
• • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
  • F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
  • F16F—SPRINGS; SHOCK-ABSORBERS; MEANS FOR DAMPING VIBRATION
  • F16F1/00—Springs
  • F16F1/02—Springs made of steel or other material having low internal friction; Wound, torsion, leaf, cup, ring or the like springs, the material of the spring not being relevant
  • F16F1/021—Springs made of steel or other material having low internal friction; Wound, torsion, leaf, cup, ring or the like springs, the material of the spring not being relevant characterised by their composition, e.g. comprising materials providing for particular spring properties
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
  • B21C—MANUFACTURE OF METAL SHEETS, WIRE, RODS, TUBES OR PROFILES, OTHERWISE THAN BY ROLLING; AUXILIARY OPERATIONS USED IN CONNECTION WITH METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL
  • B21C1/00—Manufacture of metal sheets, metal wire, metal rods, metal tubes by drawing
  • B21C1/003—Drawing materials of special alloys so far as the composition of the alloy requires or permits special drawing methods or sequences
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  • C21D2211/00—Microstructure comprising significant phases
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  • C21D2211/00—Microstructure comprising significant phases
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  • C21D2211/00—Microstructure comprising significant phases
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  • C21D7/00—Modifying the physical properties of iron or steel by deformation
  • C21D7/02—Modifying the physical properties of iron or steel by deformation by cold working
  • C21D7/04—Modifying the physical properties of iron or steel by deformation by cold working of the surface
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  • C22C38/002—Ferrous alloys, e.g. steel alloys containing In, Mg, or other elements not provided for in one single group C22C38/001 - C22C38/60
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Definitions

• the invention relates to a steel wire, a method for manufacturing the same, and a method for manufacturing a spring or medical wire products.
• the invention relates to a precipitation hardening stainless steel suitable for the manufacturing of a spring or medical wire products.
• Precipitation hardening stainless steels embrace a number of alloys such as 17-7PH, 17-4 PH, 15-5 PH, PH l5-7Mo, PH l4-8Mo and PH l3-8Mo.
• 17-7 PH Steels of the type 17-7 PH are steels that provide high strength and hardness, excellent fatigue properties and good corrosion resistance.
• 17-7 PH steel is designated EN Number: 1.4568, EN Name: X7CrNiAl 17-7, ASTM: 631, UNS: S17700 and JIS: SUS631.
• the chemical composition of 17-7 PH is (in wt. %): C: ⁇ 0.09, Si: ⁇ 1, Mn: ⁇ 1, P: ⁇ 0.04, S: ⁇ 0.03, Cr: 16 - 18, Ni: 6.50 - 7.75, Al: 0.75 - 1.50, balance Fe.
• a drawback of 17-7 PH is that work hardening during cold working is remarkable due to the fact that d-ferrite (delta ferrite) is prone to be generated during casting the steel and the quality of the steel products is deteriorated by the d-ferrite, and that instability of austenite, which is formed in a steel having the chemical composition of 17-7 PH, tends to invite a stress cracking during cold reduction or after cold reduction. Attempts to remedy these drawbacks have been made in the past.
• GB 2073249 A discloses the intentional addition of nitrogen to reduce the d-ferrite for this reason.
• stress cracking in non-patent literature 1.
• This invention is directed to an alternative composition of a precipitation hardenable stainless steel wire.
• the object of the present invention is to provide a steel wire having an improved property profile.
• the present invention aims at providing a precipitation hardening stainless steel wire having improved mechanical properties while the corrosion resistance is similar to the conventional steel wire.
• the steel wire made of 17-7PH steel is used for various applications due to its excellent characteristics, it is superior in fatigue resistance as compared with the 18-8 series stainless steel wire, but corrosion resistance and stability in wire drawing process of 17-7PH steel is inferior.
• the present invention aims to provide a stainless steel wire excellent in strength, a manufacturing method thereof, and a spring or medical wire products.
• a further object is to provide a steel wire, which can be used to obtain a prolonged fatigue life of springs.
• the inventors of the present invention used precipitation hardening type stainless steels in which the M d 3o value which is indicators of the stability of the austenite phase, the amount of Ni + Cr + Mo contents, and the work hardening index CWH are optimized.
• the precipitation hardening type stainless steels were subjected to a manufacturing method comprising wire drawing at room temperature, a manufacturing method comprising cooling to a sub-zero temperature and subsequent wire drawing, or a manufacturing method combining both.
• the metal structure after the final cold working comprising 40 to 90 volume% martensite, 10 to 60 volume% austenite, and 5 volume% or less d-ferrite is useful for solving the technical problem.
• the amount of martensite after final drawing was preferably 71 to 73%, and the tensile strength was preferably 1680 to 1880 MPa. Furthermore, by subjecting the steel wire to a precipitation hardening treatment at 480 °C for 1 hour, a steel wire having a tensile strength of 2270 MPa which is larger than that of the conventional steel and having a high degree of precipitation hardening was obtained. This makes it possible to achieve much higher strength than the conventional 17-7PH steel wire, the spring using the steel wire has high fatigue strength, and the medical product using the steel wire can obtain high flexural rigidity.
• the present invention has been made on the basis of the above-described finding, and the gist is as described below.
• a steel wire suitable for making a spring or medical wire products according to an aspect of the present invention includes, in weight %: C: 0.02 to 0.15;
• Si 0.1 to 0.9; Mn: 0.8 to 1.6; Cr: 16 to 20; Ni: 7.5 to 10.5; Mo: ⁇ 3; W: ⁇ 0.5; Co: ⁇ 1; Al: 0.5 to 2.5; Ti: ⁇ 0.15; V: ⁇ 0.1; Nb: ⁇ 0.1 ; Zr: ⁇ 0.1 ; Ta: ⁇ 0.1; Hf: ⁇ 0.1; Y: ⁇ 0.1;
• N ⁇ 0.05; B: ⁇ 0.01 ; Cu: ⁇ 2.5; S: ⁇ 0.05; P: ⁇ 0.05; Ca: ⁇ 0.01; Mg: ⁇ 0.01; REM: ⁇
• martensite 40 to 90; austenite: 10 to 60; and delta ferrite: ⁇ 5.
• the steel wire may fulfil at least one of the following requirements: C: 0.06 to 0.08; Si: 0.25 to 0.75; Mn: 0.9 to 1.5; Cr: 17.4 to 18.2; Ni: 8.5 to 9.1 ; Mo: ⁇ 2; W: ⁇ 0.1; Al: 1.00 to 1.30; Ti: 0.05 to 0.10; N: 0.004 to 0.017; Cu: ⁇ 0.3, and; S: ⁇ 0.003, optionally the steel wire may have a microstructure including in volume %: the martensite: 50 to 80, and the austenite: 20 to 50, and optionally the steel wire may fulfil at least one of
• the steel wire may fulfil at least one of the following requirements: C: 0.06 to 0.08; Si: 0.25 to 0.75; Mn: 0.9 to 1.5; Cr: 17.4 to
• the steel wire may have a microstructure including in volume %: the martensite: 50 to 80, and the austenite: 20 to 50, and optionally the steel wire may fulfil at least one of
• the steel wire may have a cleanliness fulfilling the following maximum requirements with respect to non-metallic inclusions according to ASTM E45-97, Method A:
• number of non-metallic inclusions having a maximum size within the range of 10 to 15 pm in a 350 mm 2 large inspected area may be ⁇ 10, and optionally the number of non-metallic inclusions having a size larger than 15 pm may be zero in said area.
• the total amount of Cr, Ni, and Mo may be 25 to 27 wt. %.
• the wire may fulfil the following requirements: C: 0.02 to 0.09; Si: 0.1 to 0.9; Mn: 0.8 to 1.6; Cr: 17 to 19; Ni: 8 to 10; Mo: ⁇ 1 ; W: ⁇ 0.5; Co: ⁇ 1; Al: 0.9 to 1.4; Ti: ⁇ 0.15; V: ⁇ 0.1; Nb: ⁇ 0.1; Zr: ⁇ 0.1; Ta: ⁇ 0.1; Hf: ⁇ 0.1; Y: ⁇ 0.1; N: ⁇ 0.02; B: ⁇ 0.01; Cu: ⁇ 2.5; S: ⁇ 0.05; P: ⁇ 0.05; Ca: ⁇ 0.01 ; Mg: ⁇ 0.01; REM: ⁇ 0.2, and Fe and impurities balance.
• a method for manufacturing a steel wire according to any one of (1) to (7) includes: melting a raw material having a composition as described above to obtain an ingot or a billet; optionally, subjecting the ingot or the billet to one or more selected from the group consisting of Electro Slag Remelting method, Vacuum Arc Remelting method, Electron Beam Remelting method, and Plasma Arc Remelting method; hot working the ingot or the billet to obtain a wire rod; optionally, shaving the wire rod; optionally, annealing the shaved wire rod; intermediate drawing the wire rod to obtain an intermediate drawn wire having an intermediate diameter; annealing the intermediate drawn wire; pre-drawing the intermediate drawn wire to obtain a pre-drawn wire having a pre diameter; sub-zero cooling the pre-drawn wire; and final drawing the pre-drawn wire to obtain the steel wire having a final diameter.
• a working rate during the pre-drawing the intermediate drawn wire may be 30 to 60%.
• the surface temperature of the pre-drawn wire just before the final drawing may be -130 to -l96°C, and a working rate during the final drawing the pre-drawn wire may be 10 to 30%.
• a method for manufacturing a steel wire according to any one of (1) to (7) includes: melting a raw material having a composition as described above to obtain an ingot or a billet; optionally, subjecting the ingot or the billet to one or more selected from the group consisting of Electro Slag Remelting method, Vacuum Arc Remelting method, Electron Beam Remelting method, and Plasma Arc Remelting method; hot working the ingot or the billet to obtain a wire rod; optionally, shaving the wire rod; optionally, annealing the shaved wire rod; optionally, one or more times of intermediate drawing the wire rod to obtain an intermediate drawn wire having an intermediate diameter; optionally, one or more times of annealing the intermediate drawn wire; and final drawing the wire rod, the shaved wire rod, or the intermediate drawn wire to obtain the steel wire having a final diameter.
• a working rate during the final drawing may be 70 to 96%.
• a method for manufacturing a spring or medical wire products according to other aspect of the present invention includes: working the steel wire according to any one of (1) to (7) to obtain a shape of the spring or the medical wire products; and precipitation hardening the spring or the medical wire products.
• a method for manufacturing a spring or medical wire products according to other aspect of the present invention includes: manufacturing a steel wire by the method according to any one of (8) to (12), working the steel wire to obtain a shape of the spring or the medical wire products; and precipitation hardening the spring or the medical wire products.
• a steel wire which can be used to obtain a steel wire having an improved property profile.
• a precipitation hardening stainless steel wire having improved mechanical properties while the corrosion resistance is similar to the conventional steel wire.
• FIG. 1 A flowchart showing an example of method for manufacturing steel wire.
• FIG. 2 A flowchart showing the other example of method for manufacturing steel wire.
• FIG. 3 A flowchart showing an example of method for manufacturing steel products using the inventive steel wire.
• FIG. 4 A flowchart showing an example of method for manufacturing spring using the inventive steel wire.
• FIG. 5 A flowchart showing an example of method for manufacturing medical products (for example, surgical needle) using the inventive steel wire.
• FIG. 6 A cross sectional view of steel wire parallel to axis direction.
• Carbon is a strong austenite former and carbon is also effective for improving the strength and the hardness of the steel matrix.
• C should be present in a minimum content of 0.02 %.
• the lower limit may be set to 0.03, 0.04, 0.05 or 0.06 %. However, if the content is too high the steel may be prone to the formation of chromium carbides.
• the upper limit for carbon is therefore 0.15 %.
• the upper limit may be set to 0.10, 0.09, 0.08 or 0.07 %.
• Silicon is used for deoxidation.
• Si is also a strong ferrite former. Si is therefore limited to 0.9% or less.
• the upper limit may be 0.85, 0.8, 0.75 or 0.70 %.
• the lower limit may be 0.15, 0.2 or 0.25 %.
• Manganese is an austenite stabilizing element and contributes to the deoxidation and to the hardenability of the steel. If the content is too low, then the hardenability may be too low. Manganese shall therefore be present in a minimum content of 0.8 %.
• the lower limit may be set to 0.9, 1.0 or 1.1 %.
• the upper limit may be set to 1.5, 1.4 or 1.3 % for avoiding too stable austenite.
• Chromium is to be present in a content of at least 16 % in order to make the steel stainless and to provide a good corrosion resistance.
• high amounts of Cr may lead to the formation of high-temperature ferrite, which reduces the hot- workability.
• the lower limit may be 16.5, 17, 17.1, 17.2, 17.3 or 17.4 %.
• the upper limit Cr is 20 % and the amount of Cr may be limited to 19.5, 19, 18.8, 18.6, 18.5, 18.4, or 18.2 %.
• a preferred range is 17.4 - 18.2 %.
• Nickel is an austenite stabilizer and supress the formation of delta ferrite. Nickel gives the steel a good hardenability and toughness. Nickel is also beneficial for the machinability of the steel. Nickel is essential for the precipitation hardening as it together with Al forms minute intermetallic NiAl- and/or Ni 3 Al- particles during aging. However, excess Ni additions results in too high an amount of retained austenite.
• the lower limit is 7.5 % and may be set to 7.7, 8, 8.2, 8.3, 8.4, 8.4, 8.5 or 8.6 %.
• the upper limit is 10.5 % and may be set to 10.2, 10, 9.8, 9.7, 9.6, 9.5, 9.4, 9.3, 9.2 or 9.1 %.
• the total content of Cr, and Ni is 25 - 27 %.
• the lower amount may be 25.2, 25.3, 25.4 or 25.5 %.
• the upper limit may be 26.9, 26.8, 26.7 or 26.6 %.
• Mo is a strong carbide-forming element and also a strong ferrite former.
• Mo contributes to stabilization of austenite and improvement of corrosion resistance.
• fine clusters containing Mo are precipitated in martensite, leading to high strength and improved heat resistance.
• Mo is excessively added, the formation of strain-induced martensite during the final processing is suppressed, leading to shortage of the amount of strain-induced martensite for precipitation hardening. For this reason, the amount of Mo is limited to 3 % or less. The upper limit may be 2.8, 2.5, 2, 1, 0.8, 0.6, 0.4 or 0.2 %.
• Chromium + Nickel + Molybdenum (preferably, 25 - 27 %)
• the total content of Cr, Ni and Mo may be 25 - 27 %.
• the lower amount may be 25.2, 25.3, 25.4 or 25.5 %.
• the upper limit may be 26.9, 26.8, 26.7 or 26.6 %.
• Al is an essential element for improving the strength.
• addition of Al of 0.5% or more is necessary.
• the upper limit can be 2.4, 2.2, 2.0, 1.8, 1.6, 1.4, 1.35, 1.30, 1.25, 1.20 or 1.15%.
• the lower limit can be set to 0.6, 0.7, 0.8, 0.9, 0.95 or 1.00 %.
• the lower limit of W is 0%.
• the lower limit of W may be 0.001, 0.002, 0.005, or 0.010%.
• W is an element effective not only for improving the creep strength of stainless steel but also for improving corrosion resistance, it may be contained. However, excessive addition of W leads to the formation of intermetallic compounds, which may lead to degradation of corrosion resistance, so the W content should be 0.5% or less.
• the upper limit of W may be 0.1 %.
• the lower limit of Co is 0%.
• the lower limit of Co may be 0.001, 0.002, 0.005, or 0.010%.
• Co may be added in an amount of 0.1% or more as necessary. However, when it is added in an amount exceeding 1%, the strength is lowered and the heat resistance deteriorates, so the upper limit is 1%. It is preferably 0.3% or less.
• the lower limit of B is 0%.
• the lower limit of B may be 0.001, 0.002, 0.005, or 0.010%.
• B is an optional element that can be used in small amounts in order to improve the hot workability of the stainless steel wire.
• B also has the function of improving the strength of grain boundary.
• the upper limit may then be set to 0.007, 0.006, 0.005 or 0.004 %.
• the lower limit of N is 0%.
• N is a strong austenite former and also a strong nitride former such as A1N.
• the upper limit of the nitrogen content is limited to 0.05%.
• the upper limit may be set to 0.02, 0.019, 0.018 and 0.017%.
• a small and controlled amount of nitrogen may be beneficial for obtaining a small austenite grain size in that N combine with Ti and Al to form minute nitrides.
• the lower limit may therefore, optionally, be set to 0.004, 0.005 or 0.006 %.
• the lower limit of Cu is 0%.
• the lower limit of Cu may be 0.001, 0.002, 0.005, or 0.010%.
• Cu is an austenite stabilizing element.
• Cu may contribute to increase the hardness and the corrosion resistance of the steel.
• the e-Cu phase formed during aging not only reinforces the steel by precipitation hardening but also influences on the precipitation kinetics of the intermetallic phases.
• copper is an optional element in the present invention and the upper limit may be 1.0, 0.5, 0.3, 0.2 or 0.1 %.
• Titanium ( ⁇ 0.15 %) Ti is an element having the effect of improving the strength of the alloy by precipitation hardening as same as Al.
• Ti has a larger austenite stabilization function than Al, excessive addition suppresses the formation of strain-induced martensite during cold working and invites insufficient amount of strain-induced martensite required for precipitation hardening, and therefore, Ti is set to 0.15% or less.
• the upper limit may be set to 0.14, 0.13, 0.12, 0.1 1, 0.10, 0.09 or 0.08 %.
• addition of Ti is not necessarily required, and Ti may be 0% (no addition).
• the lower limit of Ti may be 0.001, 0.002, 0.005, 0.001, 0.01, 0.03, or 0.05 %.
• V, Nb, Zr, Ta, Hf and Y are strong carbide and nitride formers.
• the content of each of these elements should therefore be limited to 0.1 % or less, in order to avoid the formation of undesired carbides and nitrides.
• the maximum amount of these elements is preferably 0.05 or even 0.01 %.
• the lower limit of the amount of these elements may be 0, 0.001, 0.002, 0.005, or 0.010%.
• These elements may be added to the steel in the amounts according to the present embodiment for modifying the non-metallic inclusion.
• the amount of Ca and Mg are set to 0.01% or less, respectively, and the amount of REM is set to 0.2% or less.
• the lower limit of the amount of these elements may be 0, 0.001, 0.002, 0.005, or 0.010%.
• S is an impurity.
• the upper limit shall therefore be 0.05 %. However, preferably the upper limit is set to 0.015, 0.010, 0.005, 0.003, 0.002 or even 0.001 %.
• the lower limit of the amount of S may be 0, 0.001, 0.002, or 0.005%.
• Phosphorus ( ⁇ 0.05 %) P is an impurity element, which may have a negative effect on the mechanical properties of the steel. P may therefore be limited to 0.05, 0.04, 0.03 0.02 or 0.01 %. The lower limit of the amount of P may be 0, 0.001, 0.002, 0.005, or 0.010%.
• the remainder (balance) of the chemical composition of the steel wire according to the present embodiment includes impurities, and Fe as balance.
• impurities refer to components which mix into steel wire during the industrial production of the steel wire due to raw materials such as minerals or scraps or a variety of causes in production processes and are allowed to be included as long as the present steel wire is not adversely affected.
• the microstructure of the steel can be adjusted with respect to the intended use.
• the M s -temperature of steels of 18-8 series, EN number: 1.4325, EN name: Xl2CrNil88, ASTM: 302, UNS: S30200, JIS: SUS302 or ASTM: 304, UNS: S30400, and JIS: SUS304, which are representative as metastable austenite stainless steel, is calculated to be less than -273 ° C, in according to the calculation Eq. (1). This means that the metal structure of these metastable austenite stainless steels do not transform to martensite even when immersed in liquid nitrogen (boiling point -196 °C.).
• the M d 30-temperature for the steel wire according to the present embodiment may be -40 °C or more, -20 °C or more, or -12 °C or more.
• the M d 3o-temperature for the steel wire according to the present embodiment may be 10 °C or less, 0 °C or less, or -2 °C or less.
• the steels propensity to cold work hardening can be estimated by using the Cold Work Hardening (CWH) factor as shown in Eq. (3):
• the lower limit of CWH may be 113, 118, or 120.
• the upper limit of CWH may be 133, 130, or 126.
• A-type manufacturing method includes:
• ESR Electro Slag Remelting method
• VAR Vacuum Arc Remelting
• EBR Electron Beam Remelting method
• PAR Plasma Arc Remelting method
• a raw metal is melted to obtain an ingot or a billet.
• a composition of the raw material is substantially equal to the above-described composition of the steel wire according to the present invention.
• the conditions for performing the melting Sl are not limited, and typical conditions can be applied to the melting Sl .
• the remelting S2 such as ESR, VAR, EBR and/or PAR may be included in the method. If the steel wire is intended to be used in applications having very high requirements on the fatigue strength such as compression springs for diesel injection then it is preferred to have a super clean steel. Hence, the ingot or the billet may be subjected to one or more selected from the group consisting of Electro Slag Remelting method (ESR), Vacuum Arc Remelting (VAR) method, Electron Beam Remelting method (EBR), and Plasma Arc Remelting method (PAR), and/or similar method in order to improve the cleanliness of the steel.
• ESR Electro Slag Remelting method
• VAR Vacuum Arc Remelting
• EBR Electron Beam Remelting method
• PAR Plasma Arc Remelting method
• the remelting methods can be combined, and thus, the method may include two or more of the remelting methods.
• the conditions for performing the remelting S2 are not limited, and typical conditions can be
• the ingot or the billet is heated and worked so as to obtain a wire rod.
• An example of the hot working is hot rolling.
• the conditions for performing the hot working S3 are not limited, and typical conditions can be applied to the hot working S3.
• the shaving S4 may include light drawing before the shaving, and the shaving S4 and the annealing S5 may be included in the A-type manufacturing method.
• the shaving S4 remove the surface layer of the wire rod so that the surface defects of the wire rod, which deteriorate the mechanical property of the finally obtained steel wire, are removed. Therefore, the shaving S4 further enhances the mechanical property of the steel wire.
• the shaved wire rod after the shaving S4 is annealed.
• the annealing S5 is performed in order to soften the shaved wire rod, which is hardened by the shaving S4. Therefore, if the shaving S4, and the annealing S5 are not included in the A-type manufacturing method, the annealing is not also included therein. If the shaving S4, and the annealing S5 are included in the A-type manufacturing method, a heating temperature during the annealing S4 may be 980 to 1 l00°C.
• the wire rod is drawn and an intermediate drawn wire having an intermediate diameter is obtained.
• the intermediate drawn wire which is hardened by the intermediate drawing S6, is softened.
• drawing the wire rod is performed in plurality times (for example, two or more) with avoiding wire breakage in order to obtain the ratio of austenite phase and martensite phase (or austenite phase, martensite phase, and delta ferrite phase) required in the final wire drawing process. Therefore, the manufacturing method may further include one or more of intermediate drawing.
• the wire rod can be drawn so as to be the final diameter in one time.
• the reduction ratio during the intermediate drawing S6 is not limited, and can be selected in accordance with the final wire diameter. Therefore, in the case of fine size at finale drawing, intermediate drawing process will take plural times.
• the intermediate diameter which is smaller than the diameter of the wire rod just before the intermediate drawing S6 and larger than the diameter of a pre diameter, is not limited.
• a heating temperature during the annealing S7 may be 980 to H00°C.
• the intermediate drawn wire is drawn to obtain a pre-drawn wire having a pre diameter.
• a working rate i.e. reduction of area
• the working rate may be 40 to 50%.
• the pre-drawn wire includes 10 volume% or less of strain-induced martensite. The larger the working rate of the pre-drawing S8 is, the larger the amount of the strain-induced martensite in the pre-drawn wire is.
• the sub-zero cooling S9 is included in the A-type manufacturing method.
• the presence of martensite in steels is indispensable for obtaining high strength in precipitation hardening, and in order to further increase the amount of martensite, it is necessary for the A-type manufacturing method to cool the steel wire to the sub-zero temperature just before final drawing the pre-drawn wire.
• the sub-zero cooling S9 can be made by means of all conventionally known cryogenic cooling media. However, it is preferred to make use of liquid nitrogen for the cryogenic treatment.
• the pre-drawn wire is further drawn to obtain the steel wire having a final diameter.
• a working rate i.e. reduction of area
• the surface temperature of the pre-drawn wire just before the final drawing S10 may be -130 to -l96°C.
• the upper limit of the surface temperature of the pre-drawn wire just before the final drawing S10 is more preferably -l90°C.
• the pre-drawn wire and final drawn wire may be formed by conventional die, rolled or drawn by rollers.
• the cross-sectional shape of the steel wire after the final working may be not only round cross section but also egg shape, oval shape, modified cross section similar to these, flat shape or any other shape. The drawing tools and the cross-sectional shapes can be applied to the other shape.
• B-type manufacturing method includes:
• ESR Electro Slag Remelting method
• VAR Vacuum Arc Remelting
• EBR Electron Beam Remelting method
• PAR Plasma Arc Remelting method
• the melting sl, the remelting s2, the hot working s3, the shaving s4, and the annealing s5 for the shaved wire rod in the B-type manufacturing method are similar to the melting Sl, the remelting S2, the hot working S3, the shaving S4, and the annealing S5 for the shaved wire rod in the A-type manufacturing method, respectively.
• the intermediate drawing s6 and the subsequent annealing s7 is optional. That is, the intermediate drawing s6 may be omitted and the wire rod may be drawn in one time in the final drawing s8.
• the working rate (i.e. reduction of area) in the final drawing s8 is 70 to 96%.
• the intermediated drawing s6 and the subsequent annealing s7 may be performed one or more times in order to control the working ratio in the final drawing s8.
• the amount of martensite can be adjusted to the desired value.
• the microstructure may include 40 - 90 vol. % martensite, 10 - 60 vol. % austenite and not more than 5 vol. % delta ferrite.
• the amount of delta ferrite should preferable be limited to 3 vol. % for not impairing the hot workability.
• the amount of austenite in the structure may be 20 vol. % or more.
• the amount of martensite may be 50 vol. % or more.
• the amount of austenite in the structure may be 50 vol. % or less.
• the amount of martensite may be 80 vol. % or less.
• the amount of strain-induced martensite included in the steel wire according to the present embodiment is evaluated in accordance with the following Eq. (4), which is disclosed in“Study of the High Strength Stainless Steel wires for Springs”, Koizumi et al., Transactions of Japan Society of Spring Engineers No. 36, p25 to p28, 1983, Japan Society of Spring Engineers.
• VFM (%) as(uic) / cs(M) x 100 (4)
• “VFM” is volume fraction of martensite included in the steel wire
• “O S (UK)” is saturation magnetization of the steel wire
• “O S (M)” is saturation magnetization of a reference sample of which the amount of martensite is 100 vol. %.
• OS(UK) BS(U ) / 4pr (5)
• “p” density of the steel wire
• “BS(UK)” saturation magnetic flux density Bs of the steel wire, which is obtained by applying ⁇ 1000 Oe of magnetizing force to the steel wire with solenoidal coil and DC-magnetizing device (for example, Type 3257 of Yokogawa Electric Corporation) to obtain B-H curve (magnetic flux density - magnetization curve) thereof, evaluating the maximum magneticflux density Bm based on the B-H curve, and assuming Bm as Bs.
• CTS(M) can be estimated in accordance with the following Eq. (6) for the chemical composition of the steel wire as described above.
• VFM obtained with the Eq. (4) includes the amount of a’ martensite having bcc structure and delta ferrite having bcc structure, and excludes the amount of e martensite having hep structure. Although the amount of the e martensite is extremely small and can be ignored, the amount of delta ferrite is omitted from VFM in accordance with the following evaluation method in order to precisely approximate the amount of strain-induced martensite included in the steel wire according to the present embodiment.
• the evaluation of the delta ferrite is performed on the wire rod.
• the metal structure is mainly constructed from the austenite and the delta ferrite.
• the drawing transforms a part of the austenite to the strain-induced martensite, while does not transform the delta ferrite. That is, the amount of the delta ferrite before the drawing and the amount of the delta ferrite after the drawing are substantially equal.
• the VFM before the drawing is substantially equal to the amount of the delta ferrite. Accordingly, difference between VFM before the drawing and VFM after the drawing is assumed as the amount of the strain-induced martensite after the drawing.
• the amount of the delta ferrite of the wire rod i.e. the VFM before the drawing
• the amount of delta ferrite before the drawing can be estimated by annealing the steel wire in order to cause transformation from the strain-induced martensite to the austenite (i.e. reproducing the metal structure of the wire rod in the steel wire) and taking measurement the amount of delta ferrite of the annealed steel wire.
• the amount of austenite is substantially equal to an amount of remainder of the strain-induced martensite and the delta ferrite.
• the steel is intended to be used in applications having very high requirements on the fatigue strength such as compression springs for diesel injection then it is preferred to have a super clean steel.
• the steel may be subjected to Electro Slag Remelting (ESR) method, Vacuum Arc Remelting (VAR) method or both methods and/or similar method in order to improve the cleanliness of the steel.
• ESR Electro Slag Remelting
• VAR Vacuum Arc Remelting
• the number of non-metallic inclusions having a maximum size within the range of 10 to 15 pm in a 350 mm 2 large inspected area may be ⁇ 10, and the number of non-metallic inclusions having a size larger than 15 pm is zero in said area.
• the non-metallic inclusions act as fracture origins during gigacycle fatigue test (such as 10 7 times or more of fatigue life). Accordingly, the non-metallic inclusions is one of the factor decreasing fatigue strength. Therefore, the number of the non-metallic inclusions may be limited as described below.
• the evaluation of the number of non-metallic inclusions A is performed as follows. One or more of sample is sampled from the coil. The inspection should be evenly distributed between the coils. The zone from the surface to the depth of 1 mm shall be inspected. The inclusion size is to be measured as the width, w (see FIG. 6, which is a cross sectional view of steel wire parallel to axis direction B). 350 mm 2 of every ESR-heat shall be inspected. Inclusions having sizes of 10 to 15 pm, as well as inclusions having sizes of larger than 15 pm are counted accordingly to the JK-scale on the area with the highest concentration of inclusions.
• a use of the steel wire of the present invention is not limited, it is preferable for the steel wire to be used for obtaining a spring or medical wire products (for example, a surgical needle).
• An example of a method (See FIG. 3) for manufacturing a spring and medical wire products includes:
• the working S51 is a method for manufacturing a spring, as shown in FIG. 4, the working S51 is
• the method may include after the precipitation hardening S54:
• Working S51 is usually coiling or forming S53, but there is the case to take straightening and cutting S52 process, optionally applied before coiling or forming S53 the steel wire.
• the working Sl 11 includes:
• the method further includes:
• the conditions for performing the working S 111 and precipitation hardening Sl 17 are not limited, and typical conditions can be applied thereto. Since the steel wire according to the present invention has excellent precipitation hardenability, the medical products obtained from the steel wire has excellent mechanical property with typical precipitation hardening condition.
• An alloy was produced in a conventional way by melting, continuous casting and forging to an ESR-ingot, which was remehed.
• the remelted ingot was rolled to a wire rod having a diameter of 8.5 mm.
• the remelted steel had the composition (in wt. %): C: 0.077, Si: 0.39, Mn: 1.19, Cr: 17.61, Ni: 8.81, Al: 1.03, Ti: 0.077, N: 0.011 balance Fe and impurities.
• the amount of Ni + Cr + Mo of this steel is 26.42 and the CWH is 122.3.
• the amount of delta ferrite was less than 2.5 vol. % and the rest of the steel matrix consisted of austenite.
• the wire rod was subjected to conventional shaving and heat treatment before being drawn to a wire having a diameter of 5.4 mm.
• Said wire had a martensite content of less than 10 vol. % before it was cooled in liquid nitrogen and drawn to a diameter of 4.75 mm.
• the martensite content after the drawing was increased to 73 vol. %.
• the as-drawn wire had a tensile strength (R m ) of 1680 MPa, which increased to 2270 MPa after heat treatment at 480 °C for 1 hour.
• the modulus of elasticity was 185 GPa at as drawn condition and increased by 5.4% after precipitation hardening to 195 GPa.
• the inventive alloy was compared to a commercial available steel of the type steel wire 17-7 PH.
• the comparative steel had the following nominal composition (in wt. %): C: 0.09, Si: 0.70, Mn: 1.0, Cr: 16 - 18, Ni: 6.5 -7.8, Al: 0.7 - 1.5, balance Fe and impurities.
• the comparative steel wire was subjected to the same processing as the inventive steel wire until diameter of 5.40 mm.
• the drawing to the final diameter of 4.75 mm was made without cryogenic cooling.
• the as-drawn comparative wire had a tensile strength (R m ) of 1310 - 1550 MPa, which increased to 1580 - 1800 MPa after precipitation hardening by heat treatment at 480 °C for 1 hour.
• the modulus of elasticity was 189 GPa at as drawn condition and increased by 4.8 % after precipitation hardening to 198 GPa.
• a wire rod having a diameter of 6.5 mm was produced in the same way as in Example 1.
• the remelted steel had the composition (in wt. %): C: 0.073, Si: 0.39, Mn: 1.18, Cr: 17.59, Ni: 8.80, Al: 1.05, Ti: 0.079, N: 0.010 balance Fe and impurities.
• the amount of Ni + Cr + Mo of this steel is 26.39 and the CWH is 122.1.
• the amount of delta ferrite was less than 2.5 vol. % and the rest of the steel matrix consisted of austenite.
• the wire rod was subjected to conventional shaving and heat treatment before being drawn to a wire having a diameter of 4.10 mm.
• Said wire had a martensite content of less than 10 vol. % before it was cooled in liquid nitrogen and drawn to a diameter of 3.60 mm.
• the martensite content after the drawing was increased to 71 vol. %.
• the as-drawn wire had a tensile strength (R m ) of 1760 MPa, which increased to 2270 MPa after precipitation hardening by heat treatment at 480 °C for 1 hour.
• the modulus of elasticity was 184 GPa at as drawn condition and increased by 6.5% after precipitation hardening to 196 GPa.
• the inventive steel wire was compared to a commercial available steel wire of the type steel 17-7 PH.
• the comparative steel wire was subjected to the same processing as the inventive steel wire until diameter of 4.10 mm.
• the drawing to the final diameter of 3.60 mm was made without cryogenic cooling.
• the as-drawn wire had a tensile strength (R m ) of 1550 - 1650 MPa, which increased to 1620 - 1920 MPa after the precipitation hardening by heat treatment at 480 °C for 1 hour.
• the increasing of the elastic modulus was only 4.3 - 4.8%.
• Examples 1 and 2 reveal that the inventive steel wires could be processed to become high mechanical properties after cryogenic wire drawing and that the inventive steel wires had a much more pronounced increase in the tensile strength (R m ) after precipitation hardening than the comparative steel wires.
• the inventive steel wire is obtained by manufacturing a wire rod, which has a diameter of 6.5 mm, which is produced in the same way as in Example 1, and which has the same chemical composition as in Example 1 , light drawing and shaving the wire rod so as to decrease the diameter from 6.5 mm to 5.8 mm, bright annealing the wire rod, intermediate drawing the wire rod so as to decrease the diameter from 5.8 mm to 5.4 mm to obtain an intermediated drawn wire, bright annealing the intermediated drawn wire, Ni plating the intermediated drawn wire (in order to increase spring formability), pre-drawing the intermediated drawn wire so as to decrease the diameter from 5.4 mm to 4.0 mm to obtain a pre-drawn wire, sub-zero cooling the pre-drawn wire, and final drawing the pre-drawn wire so as to decrease the diameter from 4.0 mm to 3.5 mm.
• the inventive steel wire was compared to a commercial available steel wire of the type steel 17-7 PH.
• the chemical composition of the commercial available steel wire is same as the 17-7 PH compared with the inventive steel wire in Example 1.
• the commercial steel wire is obtained by manufacturing a wire rod with a diameter of 6.4 mm, bright annealing the wire rod, intermediate drawing the wire rod so as to decrease the diameter from 6.4 mm to 5.4 mm to obtain an intermediated drawn wire, bright annealing the intermediated drawn wire, Ni plating the intermediated drawn wire (in order to increase spring formability), and final drawing the intermediated drawn wire so as to decrease the diameter from 5.4 mm to 3.5 mm.
• the wire rods for the inventive steel wire and the commercial steel wire in“Example 3” are identical to those in above-described“Example 1”, respectively.
• the inventive steel wire has excellent fatigue properties in comparison to the steel wire of 17-7 PH.
• inventive steel wire and commercial available steel wire of the type steel 17-7 PH of the above-described“Example 3” are manufactured and the corrosion resistance of the steel wires were evaluated in accordance with JIS G 0577“Methods of pitting potential measurement for stainless steels”. The results are shown in the table 3.
• the corrosion resistance of the inventive steel wire is similar to the commercial available steel wire.
• the inventive steel wire has improved mechanical properties while the corrosion resistance is similar to the conventional steel wire.
• the method for manufacturing the inventive steel wire may not include sub-zero cooling.
• the inventive examples obtained by the manufacturing method without sub-zero cooling are as follows.
• the inventive steel wire 4-1 is obtained by manufacturing a wire rod which has a diameter of 6.5 mm, is produced in the same way as in Example 1, and has the same chemical composition as in Example 1, first intermediate drawing the wire rod so as to decrease the diameter from 6.5 mm to 4.8 mm to obtain a first intermediated drawn wire, bright annealing the first intermediated drawn wire, second intermediate drawing the first intermediated drawn wire so as to decrease the diameter from 4.8 mm to 2.4 mm to obtain a.
• second intermediated drawn wire bright annealing the second intermediated drawn wire
• third intermediate drawing the second intermediated drawn wire so as to decrease the diameter from 2.4 mm to 1.20 mm to obtain a third intermediated drawn wire
• bright annealing the third intermediated drawn wire and final drawing the third intermediated drawn wire so as to decrease the diameter from 1.20 mm to 0.34 mm.
• the VFM for“Third intermediated drawn wire (cpl.20 mm) after bright annealing” is substantially equal to an amount of delta ferrite
• the VFM for“Steel wire (fq.34 mm) after final drawing” includes the amount of delta ferrite and an amount of strain-induced martensite. Accordingly, the amount of strain-induced martensite in the“Steel wire (fq.34 mm) after final drawing” is assumed as 66.4%.
• the inventive steel wire 4-2 is obtained by manufacturing a wire rod which has a diameter of 6.5 mm, is produced in the same way as in Example 1, and has the same chemical composition as in Example 1, first intermediate drawing the wire rod so as to decrease the diameter from 6.5 mm to 4.8 mm to obtain a first intermediated drawn wire, bright annealing the first intermediated drawn wire, second intermediate drawing the first intermediated drawn wire so as to decrease the diameter from 4.8 mm to 2.6 mm to obtain a second intermediated drawn wire, bright annealing the second intermediated drawn wire, third intermediate drawing the second intermediated drawn wire so as to decrease the diameter from 2.6 mm to 1.4 mm to obtain a third intermediated drawn wire, bright annealing the third intermediated drawn wire, and final drawing the third intermediated drawn wire so as to decrease the diameter from 1.4 mm to 0.34 mm.
• the VFM for“Third intermediated drawn wire (f ⁇ .40 mm) after bright annealing” is substantially equal to an amount of delta ferrite
• the VFM for“Steel wire (fq.34 mm) after final drawing” includes the amount of delta ferrite and an amount of strain-induced martensite. Accordingly, the amount of strain-induced martensite in the“Steel wire (fq.34 mm) after final drawing” is assumed as 74.5%.
• the manufacturing methods in which the total working rate during the drawing at room temperature is 92 to 94% can form 67 to 75% of strain-induced martensite without the sub-zero cooling.
• the amount of the strain-induced martensite in examples 4-1 and 4-2 is similar to a steel wire having a diameter of 3.5 mm and obtained by sub-zero cooling and drawing.
• the tensile strength of the inventive examples 4-1 and 4-2 can be further increased by the precipitation hardening. Accordingly, the method for manufacturing the steel wire which does not include sub-zero cooling can provide the inventive steel wire, which has improved mechanical properties and which is suitable for springs . or medical wire products.
• the steel of the present invention is useful for parts requiring high mechanical properties. It is particular useful for compression springs in diesel injection fuel pumps or medical wire products as surgical suture needles, blood lancets and dental tools.

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