WO2019181737A1 - Procédé de thermoformage pour produit textile - Google Patents

Procédé de thermoformage pour produit textile Download PDF

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Publication number
WO2019181737A1
WO2019181737A1 PCT/JP2019/010604 JP2019010604W WO2019181737A1 WO 2019181737 A1 WO2019181737 A1 WO 2019181737A1 JP 2019010604 W JP2019010604 W JP 2019010604W WO 2019181737 A1 WO2019181737 A1 WO 2019181737A1
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WO
WIPO (PCT)
Prior art keywords
sheath
core
polyethylene
component
fiber
Prior art date
Application number
PCT/JP2019/010604
Other languages
English (en)
Japanese (ja)
Inventor
弘平 池田
真理子 本多
Original Assignee
ユニチカ株式会社
弘平 池田
真理子 本多
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP2018167031A external-priority patent/JP6604583B2/ja
Application filed by ユニチカ株式会社, 弘平 池田, 真理子 本多 filed Critical ユニチカ株式会社
Priority to KR1020207026411A priority Critical patent/KR102389445B1/ko
Priority to AU2019238661A priority patent/AU2019238661B2/en
Priority to US16/981,592 priority patent/US20210054537A1/en
Priority to EP19772558.3A priority patent/EP3770313A4/fr
Priority to CA3093528A priority patent/CA3093528A1/fr
Publication of WO2019181737A1 publication Critical patent/WO2019181737A1/fr

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/06Fibrous reinforcements only
    • B29C70/10Fibrous reinforcements only characterised by the structure of fibrous reinforcements, e.g. hollow fibres
    • B29C70/16Fibrous reinforcements only characterised by the structure of fibrous reinforcements, e.g. hollow fibres using fibres of substantial or continuous length
    • B29C70/20Fibrous reinforcements only characterised by the structure of fibrous reinforcements, e.g. hollow fibres using fibres of substantial or continuous length oriented in a single direction, e.g. roofing or other parallel fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/024Woven fabric
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/08Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer the fibres or filaments of a layer being of different substances, e.g. conjugate fibres, mixture of different fibres
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00Formation of filaments, threads, or the like
    • D01D5/08Melt spinning methods
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00Formation of filaments, threads, or the like
    • D01D5/28Formation of filaments, threads, or the like while mixing different spinning solutions or melts during the spinning operation; Spinnerette packs therefor
    • D01D5/30Conjugate filaments; Spinnerette packs therefor
    • D01D5/34Core-skin structure; Spinnerette packs therefor
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/04Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
    • D01F8/06Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyolefin as constituent
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/04Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
    • D01F8/14Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyester as constituent
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D1/00Woven fabrics designed to make specified articles
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/20Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads
    • D03D15/283Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads synthetic polymer-based, e.g. polyamide or polyester fibres
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/20Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads
    • D03D15/292Conjugate, i.e. bi- or multicomponent, fibres or filaments
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/40Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/40Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads
    • D03D15/41Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads with specific twist
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/40Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads
    • D03D15/44Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads with specific cross-section or surface shape
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/40Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads
    • D03D15/47Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads multicomponent, e.g. blended yarns or threads
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/50Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
    • D03D15/587Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads adhesive; fusible
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06CFINISHING, DRESSING, TENTERING OR STRETCHING TEXTILE FABRICS
    • D06C7/00Heating or cooling textile fabrics
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/12Conjugate fibres, e.g. core/sheath or side-by-side
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2321/00Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D10B2321/02Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polyolefins
    • D10B2321/021Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polyolefins polyethylene
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/04Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2505/00Industrial
    • D10B2505/02Reinforcing materials; Prepregs

Definitions

  • the present invention relates to a method for thermoforming by applying heat and, if necessary, pressure to a fiber product composed of multifilament yarns in which core-sheath composite long fibers are bundled, and in particular, excellent in wear resistance and other types of articles. It is related with the thermoforming method which can obtain the thermoforming body excellent in peeling strength when it is made to stick to.
  • This invention solves the said subject by employ
  • the present invention uses a composite melt spinning method in which polyethylene having a melt flow rate of 10 to 15 g / 10 min under measurement conditions of a temperature of 280 ° C. and a load of 2.16 kg is used as a sheath component, and polyethylene terephthalate is used as a core component.
  • a step of obtaining a multifilament yarn in which core-sheath composite long fibers having a mass ratio of the core component to the sheath component of core component: sheath component 1 to 4: 1 are bundled, using the multifilament yarn
  • the present invention relates to a method for thermoforming a textile product.
  • polyethylene having a melt flow rate of 10 to 15 g / 10 min under measurement conditions of a temperature of 280 ° C. and a load of 2.16 kg is prepared.
  • the polyethylene include linear high density polyethylene, linear low density polyethylene, and branched polyethylene, and the molecular weights thereof are various.
  • the present invention uses the specific polyethylene described above from among these polyethylenes. Specifically, a linear low density polyethylene having a high molecular weight is preferably used. When the melt flow rate is less than 10 g / 10 min, it becomes difficult to perform composite melt spinning with polyethylene terephthalate, which is not preferable.
  • melt flow rate exceeds 15 g / 10 min, the wear resistance of the fused part is lowered and the adhesive force to other kinds of articles is lowered, which is not preferable.
  • the melt flow rate is measured in accordance with the method described in JIS K7210 under the conditions of a temperature of 280 ° C. and a load of 2.16 kg. In the examples of the present invention, the melt flow rate was measured under the above-described conditions using a device called a melt indexer G-01 manufactured by Toyo Seiki Seisakusho.
  • polyethylene terephthalate together with the specific polyethylene mentioned above.
  • a conventionally well-known thing is used as a polyethylene terephthalate.
  • Polyethylene terephthalate does not melt at the temperature at which polyethylene melts, and maintains the original fiber form. Therefore, the melt flow rate is arbitrary because it has nothing to do with the wear resistance and adhesive strength of the fused part.
  • polyethylene as a sheath component and polyethylene terephthalate as a core component to obtain a core-sheath-type long fiber by a composite melt spinning method, it is converged to obtain a multifilament yarn.
  • the mass ratio of the sheath component is lower than this range, it is not preferable because the wear resistance and adhesive strength of the fused part are lowered.
  • the mass ratio of the sheath component is higher than this range, the diameter of the core component maintaining the original fiber form is reduced, and the tensile strength of the thermoformed product is lowered, which is not preferable.
  • the multifilament yarn may be untwisted but is generally twisted.
  • a woven fabric may be obtained by weaving multifilament yarn as warp and weft, or a knitted fabric may be obtained by applying the multifilament yarn to a warp knitting machine or a weft knitting machine.
  • a knotted network or a knotless network may be obtained while twisting a plurality of multifilament yarns.
  • a string may be obtained by assembling a plurality of multifilament yarns.
  • conventionally known fiber products are obtained by various methods.
  • the multifilament yarn is passed through the kite. Specifically, in the case of a woven fabric, a multifilament yarn that is a warp is passed through the knot, and in the case of warp knitting, the multifilament yarn that is a warp is passed through a guide eye of the knot. At this time, the multifilament yarn comes into contact with the edges of the mesh and the guide eye to cause friction, and wear occurs in the multifilament yarn.
  • the multifilament yarn used in the present invention is excellent in abrasion resistance in such a situation.
  • the sheath component of the core-sheath type composite continuous fiber constituting the multifilament yarn has a low melt flow rate, so that the sheath component contacting the edge of the eyelet or guide eye is melted or softened by frictional heat. This is because it is difficult to adhere to the edges of the eyelets and the guide eye, and the sheath component is difficult to be scraped off.
  • magnesium stearate is contained in the sheath component, the sheath component is less likely to adhere to the edges of the eyelets or guide eyes.
  • the content of magnesium stearate in the sheath component may be about 0.01 to 1% by weight.
  • the obtained fiber product is heated and thermoformed.
  • the heating temperature is equal to or higher than the melting point of polyethylene, which is the sheath component of the core-sheath composite long fiber, and specifically 140 ° C. or higher.
  • polyethylene is melted, and the core-component polyethylene terephthalate is fused with the core-sheath composite long fibers in a state in which the original fiber form is maintained, thereby obtaining a thermoformed body.
  • a coarse knitted fabric or net is used as a textile product and the knitted fabric or net is heated to melt polyethylene, a thermoformed body that is firmly fused at the intersection of the knitted fabric or net is obtained. It is done.
  • the intersection of the knitted fabric or the net is, for example, an intersection of warp and weft in the case of a woven fabric, and a knot in the case of a knitted or net.
  • a thermoformed article can be favorably used at a construction site as a mesh sheet that is not easily noticed or a peeling prevention sheet.
  • the laminated body obtained by laminating the obtained fiber products may be heated to perform thermoforming.
  • thermoforming For example, woven fabrics, woven fabrics and mesh fabrics, or knitted fabrics and mesh fabrics may be laminated and thermoformed.
  • the core-sheath type composite long fibers of the upper layer fiber product and the lower layer fiber product are fused and bonded to each other, and a composite material that is difficult to peel off on the laminated surface is obtained.
  • the sheath component of the core-sheath type composite long fiber in the fiber product is fused and bonded to another type of article.
  • Examples of other types of articles include arbitrary articles such as plastic articles, metal articles, and ceramic articles.
  • a casing formed of a polyolefin resin or the like is used as another type of article, the sheath component of the core-sheath composite long fiber and the polyolefin resin are firmly bonded, and the core component has the original fiber state. As a result, a reinforced housing is obtained.
  • thermoforming method for fiber products since core-sheath type composite long fibers having a specific polyethylene as a sheath component are present in the fiber product, the core-sheath type composite long fibers are fused together with this polyethylene. There is an effect that the wear resistance of the fused part is improved.
  • the core-sheath type composite continuous fibers fused with the polyethylene also have an effect of increasing the adhesive force. Therefore, for example, when the fiber product used in the present invention and another type of article are laminated and fused, the fiber product and the other type of article are difficult to peel off.
  • Example 1 [Preparation of multifilament yarn]
  • polyethylene manufactured by Nippon Polyethylene Co., Ltd., product number UJ960
  • polyethylene terephthalate having a melting point of 256 ° C. was prepared as a core component.
  • the above-mentioned polyethylene and polyethylene terephthalate are supplied to a compound melt spinning apparatus equipped with a core-sheath type compound spinneret having a hole diameter of 0.6 mm and 192 holes.
  • As the (mass ratio) composite melt spinning was performed.
  • the obtained filaments having 192 core-sheath composite long fibers converged were subjected to cooling, stretching and relaxation treatments by conventional means to obtain 1670 dtex / 192 filament multifilament yarns.
  • thermoformed product A in which a fusion site having a length of 200 mm was formed. This thermoformed product A is formed by fusing the sheath component of the core-sheath type composite continuous fiber in each plain fabric at the center thereof, and is obtained by firmly bonding the two plain fabrics. It was.
  • thermoforming (2) The obtained multifilament yarn was twisted with a twist number of 60 T / m and introduced into an 8-striking cord making machine to obtain an 8-piece braid. And the sheath component of the core-sheath type
  • Example 2 A multifilament yarn was obtained by the same method as in Example 1 except that polyethylene (manufactured by Prime Polymer Co., Ltd., product number SP4030) having a melting point of 127 ° C. and a melt flow rate of 14.5 g / 10 minutes was used as the sheath component. Using this multifilament yarn, fiber products were prepared and thermoformed (part 1) and (part 2) in the same manner as in Example 1 to obtain thermoformed bodies A and B.
  • polyethylene manufactured by Prime Polymer Co., Ltd., product number SP4030
  • Comparative Example 2 A multifilament yarn was obtained in the same manner as in Example 1 except that polyethylene (manufactured by Nippon Polyethylene Co., Ltd., product number UJ560) having a melting point of 123 ° C. and a melt flow rate of 59.8 g / 10 minutes was used as the sheath component. Using this multifilament yarn, fiber products were prepared and thermoformed (part 1) and (part 2) in the same manner as in Example 1 to obtain thermoformed bodies A and B.
  • polyethylene manufactured by Nippon Polyethylene Co., Ltd., product number UJ560
  • thermoformed body A obtained in Examples 1 and 2 and Comparative Examples 1 and 2 using the autograph AG50kNI manufactured by Shimadzu Corporation, each plain fabric part not bonded at one end of the width of the thermoformed body A was gripped with a chuck, a peel test was performed at a tensile speed of 100 mm / min, and the peel strength was measured. The peel test was conducted on three thermoformed bodies A, and the peel strength was defined as an average value of each value at which the load exhibited a maximum value during the test. As a result, the thermoformed product A according to Example 1 is 17.8 N, the one according to Example 2 is 15.7 N, the one according to Comparative Example 1 is 10.1 N, and the one according to Comparative Example 2 is 13.1 N. there were. From this, it turns out that the thermoformed body A which concerns on Example 1 and 2 is excellent in the adhesive force of two plain fabrics.
  • thermoformed product B according to Examples 1 and 2 did not break, but the thermoformed product B according to Comparative Example 1 was about 15%. It broke in minutes.
  • thermoformed body B which concerns on the comparative example 2 was not fractured
  • the above-mentioned polyethylene composition and polyethylene terephthalate are supplied to a compound melt spinning apparatus equipped with a core-sheath type compound spinneret having a hole diameter of 0.6 mm and a number of holes of 128, and the die temperature is set to 280 ° C.
  • the obtained filaments with 128 core-sheath composite long fibers bundled were subjected to cooling, drawing and relaxation treatments by conventional means to obtain 1830 dtex / 128 filament multifilament yarns.

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Composite Materials (AREA)
  • Woven Fabrics (AREA)
  • Multicomponent Fibers (AREA)

Abstract

Le problème décrit par la présente invention est de fournir un procédé de thermoformage permettant d'obtenir un article thermoformé qui présente une excellente résistance à l'usure au niveau de parties liées par fusion, et une excellente force adhésive entre des tissus et avec d'autres types d'articles. La solution selon l'invention porte sur la préparation d'un polyéthylène téréphtalate et d'un polyéthylène ayant un indice de fluidité, mesuré dans des conditions d'une température de 280 °C et d'une charge de 2,16 kg, de 10 à 15 g/10 min. Par un procédé de filage par fusion de fibres conjuguées utilisant le polyéthylène téréphtalate comme composant central et le polyéthylène comme composant de gaine, un fil multifilament dans lequel des fibres longues conjuguées cœur-gaine ayant un rapport de masse entre le composant central et le composant de gaine de 1 à 4:1 sont collectées est obtenu. Un produit textile est obtenu par tissage, tricotage, tressage ou enroulement utilisant le fil multifilament. Le thermoformage de ce produit textile est effectué en chauffant le produit textile pour faire fondre le polyéthylène et simultanément pour lier par fusion les fibres longues conjuguées cœur-gaine les unes aux autres, le polyéthylène téréphtalate conservant sa forme de fibre initiale.
PCT/JP2019/010604 2018-03-19 2019-03-14 Procédé de thermoformage pour produit textile WO2019181737A1 (fr)

Priority Applications (5)

Application Number Priority Date Filing Date Title
KR1020207026411A KR102389445B1 (ko) 2018-03-19 2019-03-14 섬유 제품의 열성형법
AU2019238661A AU2019238661B2 (en) 2018-03-19 2019-03-14 Method for thermoforming textile product
US16/981,592 US20210054537A1 (en) 2018-03-19 2019-03-14 Method for thermoforming product of filaments
EP19772558.3A EP3770313A4 (fr) 2018-03-19 2019-03-14 Procédé de thermoformage pour produit textile
CA3093528A CA3093528A1 (fr) 2018-03-19 2019-03-14 Procede de thermoformage pour produit textile

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP2018-050348 2018-03-19
JP2018050348 2018-03-19
JP2018-167031 2018-09-06
JP2018167031A JP6604583B2 (ja) 2018-03-19 2018-09-06 繊維製品の熱成形法

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