NO344891B1 - Method for manufacturing fishing net - Google Patents

Method for manufacturing fishing net Download PDF

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Publication number
NO344891B1
NO344891B1 NO20181438A NO20181438A NO344891B1 NO 344891 B1 NO344891 B1 NO 344891B1 NO 20181438 A NO20181438 A NO 20181438A NO 20181438 A NO20181438 A NO 20181438A NO 344891 B1 NO344891 B1 NO 344891B1
Authority
NO
Norway
Prior art keywords
net
intersections
strands
core
sheath
Prior art date
Application number
NO20181438A
Other languages
Norwegian (no)
Other versions
NO20181438A1 (en
Inventor
Hidehito Andoh
Kohei Ikeda
Original Assignee
Unitika Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP2017217236A external-priority patent/JP7022976B2/en
Priority claimed from JP2018000346A external-priority patent/JP6359215B1/en
Priority claimed from JP2018096346A external-priority patent/JP6437686B1/en
Application filed by Unitika Ltd filed Critical Unitika Ltd
Publication of NO20181438A1 publication Critical patent/NO20181438A1/en
Publication of NO344891B1 publication Critical patent/NO344891B1/en

Links

Classifications

    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D10/00Physical treatment of artificial filaments or the like during manufacture, i.e. during a continuous production process before the filaments have been collected
    • D01D10/02Heat treatment
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/04Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04CBRAIDING OR MANUFACTURE OF LACE, INCLUDING BOBBIN-NET OR CARBONISED LACE; BRAIDING MACHINES; BRAID; LACE
    • D04C1/00Braid or lace, e.g. pillow-lace; Processes for the manufacture thereof
    • D04C1/06Braid or lace serving particular purposes
    • D04C1/08Tulle fabrics
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01KANIMAL HUSBANDRY; CARE OF BIRDS, FISHES, INSECTS; FISHING; REARING OR BREEDING ANIMALS, NOT OTHERWISE PROVIDED FOR; NEW BREEDS OF ANIMALS
    • A01K75/00Accessories for fishing nets; Details of fishing nets, e.g. structure
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00Formation of filaments, threads, or the like
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/04Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
    • D01F8/12Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyamide as constituent
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04CBRAIDING OR MANUFACTURE OF LACE, INCLUDING BOBBIN-NET OR CARBONISED LACE; BRAIDING MACHINES; BRAID; LACE
    • D04C1/00Braid or lace, e.g. pillow-lace; Processes for the manufacture thereof
    • D04C1/06Braid or lace serving particular purposes
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06CFINISHING, DRESSING, TENTERING OR STRETCHING TEXTILE FABRICS
    • D06C7/00Heating or cooling textile fabrics
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00Physical properties
    • D10B2401/04Heat-responsive characteristics
    • D10B2401/041Heat-responsive characteristics thermoplastic; thermosetting
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2507/00Sport; Military
    • D10B2507/02Nets

Description

SPECIFICATION
METHOD FOR MANUFACTURING FISHING NET
BACKGROUND OF THE INVENTION
TECHNICAL FIELD
[0001]
The present invention relates to a method for manufacturing a fishing net having high strength, particularly to a method for manufacturing a fishing net composed of a plastic net.
BACKGROUND ART
[0002]
Conventionally, it has been well known that a core-sheath type composite filament comprising a core component formed from polyethylene terephthalate and a sheath component formed from polyester copolymer or polyolefin having a melting point lower than that of polyethylene terephthalate is used as a material for a mesh sheet. It has also been well known that a coarse fabric is woven using a multifilament yarn made of core-sheath type composite filaments as warp and weft, and that an intersection of the warp and the weft is fused by melting the sheath component by heat treatment to form the mesh sheet (see JP 2001-271270 A and JP 2009-299209 A). In this context, the intersection of the warp and the weft is fused for preventing mesh slippage. The fusion of the intersections can be generated at a pressure from both upper side and lower sides, even if it is conducted by non-pressure heat treatment, the warp and the weft outside the intersections are hardly fused in the heat treatment, such that some of the intersections are selectively fused. The mesh sheet is generally covered on an outside surface of a temporary structure such as a scaffold at a construction site and is used for preventing foreign falling objects and the like from jumping out of the temporary structure, so that there is no drawback even if some of portions except for the intersections are not fused.
[0003]
However, a high-rigid plastic sheet in which portions outside the intersections are fused is sometimes necessary for industrial applications other than the mesh sheets. For example, a culturing fishing net, which is a kind of the fishing nets, is easily worn down by continuous contacts with fishes, and fishes may cut off the net by its mouth, so that a plastic type sheet is very suitable for the culturing fishing net. In order to obtain the plastic sheet, it is considered that heat treatment is performed while the sheet is pressed as described in JP 2001-271270 A and JP 2009-299209 A. However, when heat treatment is conducted under pressure for producing the plastic sheet, the sheet becomes very rigid and can only be treated in the form of a flat plate, because it is very difficult to wind it up as a scroll.
Document JP 2016056487 describes a sheath-core composite polyamide monofilament by compositing polyamide and a polyamide resin other than the polyamide, a cross section of the monofilament shows a sheath-core cross section, the sheath part has the polyamide and the core part has the polyamide resin other than the polyamide.
SUMMARY OF THE INVENTION
[0005]
An object of the present invention is to provide a method for manufacturing a fishing net comprising a plastic net, which can be easily handled by winding or folding and has highly rigid intersections, although the plastic net is strong.
BRIEF DESCRIPTION OF THE DRAWINGS
[0020]
FIG. 1 is a schematic plan view illustrating a strand according to an embodiment of the plastic net of the present invention.
FIG. 2 is a schematic plan view illustrating a part of strands and intersections according to an embodiment of the plastic net of the present invention.
FIG. 3 is a photograph showing a plan view of an embodiment of the plastic net of the present invention.
FIG. 4 is a schematic diagram illustrating a state of a test piece in measuring intersection strength of the plastic nets obtained in Examples and Comparative Examples; and
FIG. 5 is a schematic diagram illustrating a state of a test piece in measuring tensile strength of the plastic nets obtained in Examples and Comparative Examples.
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS
[0006]
The present invention provides a method for manufacturing a fishing net comprising a plastic net, wherein strands and intersections are formed by a specific method using a specific core-sheath type composite filament and then heat treating to obtain the plastic net, thus solving the above problem. Thus, the present invention is to provide a method for manufacturing a fishing net, the method comprising:
a step of preparing a multifilament yarn formed by bundling a plurality of core-sheath type composite filaments, wherein a core component is made of polyamide B and a sheath component is made of polyamide A having a melting point lower than the polyamide B, a mass ratio of the core component and the sheath component being core component : sheath component = 1 to 3 : 1, a step of obtaining a net constructed with strands and intersections, using a yarn thread obtained by paralleling a plurality of the multifilament yarns, a step of heat-treating the net to melt the sheath component of the yarn threads constituting the strands and the intersections, followed by solidifying, thus obtaining a plastic net constructed with solidified strands and solidified intersections, in which the core component is existent as an initial fiber form in a matrix formed of the sheath component; and
a step of forming the fishing net using the plastic net.
[0007]
In the present invention, the core-sheath type composite filament having the core component of polyamide A and the sheath component of polyamide A having a melting point lower than the polyamide A is prepared. In the coresheath type composite filament, a mass ratio of the core component to the sheath component is core component : sheath component = 1 to 3 : 1. The polyamide A which is formed into the sheath component would form a matrix of a fiber-reinforced plastic material. Consequently, when the mass ratio of the sheath component is lower than the lower limit of the above range, it hardly forms the matrix. When the mass ratio of the sheath component is higher than the upper limit of the above range, a diameter or a number of the core component decreases and the strength of the fiber-reinforced plastic material deteriorates. A fineness of the core-sheath type composite filament ranges from 4 dtex to 20 dtex. A plurality of core-sheath type composite filaments are bundled to form a multifilament yarn. The number of bundled filaments can be within the range of 30 to 400.
[0008]
Subsequently, a plurality of multifilament yarns are paralleled to obtain a yarn thread. The number of paralleled yarns can be about 5 to about 20. The net constructed with strands and intersections may be obtained by applying the plurality (for example, 2 threads to 10 threads) of yarn threads to a net making machine or a Russell knitting machine. The plurality (for example, 2 lines to 10 lines) of yarn threads may also be applied to a braid net making machine to braid the plurality of yarn threads to form a net constructed with the strands 1 and the intersections 2. In the present specification, the term "intersection" is meant by a portion at which adjacent strands are crossed with each other. FIG.
1 is a schematic diagram illustrating the strand 1 in which four yarn threads 11, 12, 13, and 14 are braided. The strand 1 is formed by repeating a process of crossing the yarn thread 11 with the yarn thread 12, crossing the yarn thread 12 with the yarn threads 11 and 13, crossing the yarn thread 13 with the yarn threads 12 and 14, and crossing the yarn thread 14 with the yarn thread 13. When the yarn threads are braided, each yarn thread may not be twisted or may be twisted. By twisting the yarn thread, the core-sheath type composite filaments constituting the strands 1 and the intersections 2 are intimately contacted so as to improve the rigidity of the fishing net. Accordingly, whether the yarn thread is twisted and how much extent the yarn thread is twisted may be determined in consideration of a balance between rigidity and flexibility of the fishing net. The intersections 2 may be formed in the form of knot by binding the strands 1, 1 formed as a braid, but it can preferably be in the form of knotless by penetrating the yarn threads 11, 12, 13, and 14 constituting the two strands 1, 1 into one another (see FIG.2). The net is mainly used as a fishing net such as a culturing fishing net, so that the knotless net without having roughness formed by knots is preferable due to little damage to fishes.
[0009]
The obtained net is subjected to heat treatment. A temperature of the heat treatment is higher than or equal to a melting point of the polyamide A of the sheath component, for example ranging from 140 ºC to 200 ºC. Only the sheath component of the core-sheath type composite filament constituting the yarn thread is fused by the heat treatment. The heat treatment may be conducted either without pressure or under pressure, but it may preferably be conducted without pressure, for imparting flexibility for easy winding. When the sheath component is cooled after the heat treatment, the fused sheath component is solidified, and the solidified strands 1 and the solidified intersections 2 constitute fiber-reinforced plastic material in a matrix of the polyamide A of the sheath component. In the case where the yarn threads are braided in the present invention, the strands 1 and the intersections 2 are constructed in a braided form and the core-sheath type composite filaments constituting the yarn thread are in close and strong contact with each other, thus the fused sheath component easily forms the matrix even if the heat treatment is conducted without pressure. As a result, the solidified strands 1 and the solidified intersections 2 are formed into the fiber-reinforced plastic material in which the core component maintaining the original fiber form is present in the matrix formed by melting and solidifying the sheath, to obtain the plastic net constructed with the fiber-reinforced plastic material. The resulting plastic net is employed and fabricated into fishing nets, such as a fixed fishing net, a cage fishing net, a culturing fishing net and the like.
[0010]
The plastic net obtained by the process of the present invention is constructed with the strands 1 and the intersections 2. A region surrounded by the strands 1 and the intersections 2 is an opening and can be referred to as a mesh 3. As illustrated in FIG.3, a shape of the mesh 3 may be a square mesh, or can be another form such as a rhomboid mesh. The intersections 2 can preferably be knotless as illustrated in FIG.3, but the intersections 2 may be in the form of a knot. A diameter of the strand 1 ranges from about 2 mm to about 7 mm and an area of the intersection 2 ranges from about 25 mm<2 >to about 80 mm<2>. An area of the mesh 3 ranges from about 2 cm<2 >to about 20 cm<2>.
[0011]
The solidified strands 1 and the solidified intersections 2 are formed by the fiber-reinforced plastic material in which the sheath component constitutes the matrix and the core component exists in the matrix as an initial fibrous form. That is, a fiber-reinforced plastic material in which the polyamide A constitutes a matrix and a plurality of polyamide B filaments are present in the matrix is formed.
[0012]
The fishing net obtained by the method of the present invention is formed from a high strength fiber-reinforced plastic material in which the polyamide A constitutes a matrix and the polyamide B filaments are present in the matrix. Since the polyamide is more flexible than polyethylene telephthalate and the like, the resulting fishing net is easily wound and easily folded, although it is plastic. Accordingly, the fishing net formed from the plastic net of the present invention is highly strong and rigid in use and can be conveyed as a wound scroll before and after use, thus it has technical effects of being easy to handle. In addition, since the polyamide A is compatible with the polyimide B, the intersections show high strength and the resulting fishing net is very difficult to cut off in use.
EXAMPLES
[0013]
Example 1
A core-sheath type composite filaments having a fineness of about 7.3 dtex with core component : sheath component = 3 : 1 (mass ratio) was prepared from a core component made of polyamide 6 having a melting point of 225 ºC and a sheath component made of polyamide copolymer having a melting point of 155 ºC. Then, 192 core-sheath type composite filaments were bundled to obtain the multifilament yarns of 1,400 dtex/192 filaments. Eight multifilament yarns were paralleled to obtain a yarn thread. Three yarn threads were applied to a twisted knotless net making machine while twisted to obtain a knotless net. The knotless net was introduced into a pin tenter type heat treatment apparatus and subjected to a heat treatment in an atmosphere at 175 ºC for 3 minutes while tension was applied in the width direction of the knotless net. Subsequently, the knotless net was left at a room temperature and cooled to obtain a plastic net. In the plastic net, a diameter of the strand was about 4 mm, a knotless area was about 50 mm<2>, a mesh was square, and an area of the mesh was about 10 cm<2>. A culturing fishing net having a tubular parallelepiped shape was obtained using the plastic net.
[0014]
Example 2
A polyamide core-sheath type composite filaments having the fineness of about 7.3 dtex with core component : sheath component = 3 : 1 (mass ratio) was prepared from a core component made of polyamide 6 having a melting point of 225 ºC and a sheath component made of polyamide copolymer having a melting point of 155 ºC. Then, 192 core-sheath type composite filaments were bundled to obtain the multifilament yarns of 1,400 dtex/192 filaments. Eight multifilament yarns were paralleled to obtain a yarn thread. Three yarn threads were applied to a braid net making machine for braiding to obtain a knotless net having strands and intersections as shown in Fig.2. The knotless net was introduced into a pin tenter type heat treatment apparatus and subjected to a heat treatment in an atmosphere at 175 ºC for 3 minutes while tension was applied in the width direction of the knotless net. Subsequently, the knotless net was left at a room temperature and cooled to obtain a plastic net. In the plastic net, a diameter of the strand was about 4 mm, a knotless area was about 50 mm<2>, a mesh was square, and an area of the mesh was about 10 cm<2>. A culturing fishing net having a tubular parallelepiped shape was obtained using the plastic net, as described in Example 1.
[0015]
Comparative Example 1
A core-sheath type composite filament having the fineness of about 8.7 dtex with core component : sheath component = 3 : 1 (mass ratio) were prepared using a core component made of polyethylene terephthalate having a melting point of 260 ºC and a sheath component made of polyester copolymer having a melting point of 160 ºC. Then, 192 core-sheath type composite filaments were bundled to obtain the multifilament yarns of 1,670 dtex/192 filaments. A plastic net was obtained as generally described in Example 1, with the exception that the resulting multifilament yarns were employed and that the atmospheric temperature during the heat treatment was changed to 180 ºC.
[0016]
Comparative Example 2
A core-sheath type composite filament having the fineness of about 8.7 dtex with core component : sheath component = 3 : 1 (mass ratio) were prepared using a core component made of polyethylene terephthalate having a melting point of 260 ºC and a sheath component made of polyester copolymer having a melting point of 160 ºC. Then, 192 core-sheath type composite filaments were bundled to obtain the multifilament yarns of 1,670 dtex/192 filaments. A plastic net was obtained as generally described in Example 2, with the exception that the resulting multifilament yarns were employed and that the atmospheric temperature during the heat treatment was changed to 180 ºC.
[0017]
Although all the plastic nets obtained by the methods according to Examples 1 and 2 and Comparative Examples 1 and 2 were strong, the plastic nets of Comparative Examples 1 and 2 were hardly wound in comparison with the plastic nets obtained in Examples 1 and 2. This is because the strands and the intersections of the latter plastic nets were made of the fiber-reinforced plastic material in which the matrix was polyester copolymer. That is, the polyester copolymer has poor flexibility compared with polyamide, and is highly compatible with polyethylene terephthalate filament so that the fiber-reinforced plastic material constituting the strands and the intersections is rigid.
[0018]
[Measurement of Intersection Strength]
A test piece consisting a total of 9 meshes, of which 3 meshes are in a longitudinal direction and 3 meshes are in a longitudinal direction, as shown in FIG. 4, was taken from the plastic nets obtained in Example 2 and Comparative Example 2. An intersection surrounded by a mark O in FIG.4 was hooked and pulled in an arrow direction and its strength (intersection strength) was measured when the intersection was broken. An autograph manufactured by Shimadzu Corporation was used as a measuring instrument and the measurement was conducted under a condition of a tensile speed of 10 cm/min. As a result, the plastic net of Example 2 had an intersection strength of 2,572 N, and that of Comparative Example 2 had an intersection strength of 2,096 N.
[0019]
[Measurement of Tensile Strength]
From the plastic nets obtained in Example 2 and Comparative Example 2, a central portion of the strands in a weft direction was cut in parallel to a warp direction to obtain a test piece as shown in FIG.5. The upper and lower ends in FIG.5 were grasped by a chuck and pulled in an arrow direction to measure a strength (tensile strength) when the strand in the warp direction was cut. An autograph manufactured by Shimadzu Corporation was used as a measuring instrument, and a measurement was conducted under conditions of a distance between the chucks of 25 cm and the tensile speed of 30 cm/min. As a result, the plastic net of Example 2 had a tensile strength of 1,904 N, and that of Comparative Example 2 had a tensile strength of 1,713 N.

Claims (5)

WHAT IS CLAIMED IS:
1. A method for manufacturing a fishing net, the method comprising: a step of preparing a multifilament yarn formed by bundling a plurality of core-sheath type composite filaments, wherein a core component is made of polyamide B and a sheath component is made of polyamide A having a melting point lower than the polyamide B, a mass ratio of the core component and the sheath component being core component : sheath component = 1 to 3 : 1, a step of obtaining a net constructed with strands and intersections, using a yarn thread obtained by paralleling a plurality of the multifilament yarns, a step of heat-treating the net to melt the sheath component of the yarn threads constituting the strands and the intersections, followed by solidifying, thus obtaining a plastic net constructed with solidified strands and solidified intersections, in which the core component is existent as an initial fiber form in a matrix formed of the sheath component; and
a step of forming the fishing net using the plastic net.
2. The method according to claim 1, wherein a net is obtained by either twisting a plurality of the yarn threads to obtain a net constructed with strands and intersections, or braiding the plurality of the yarn threads to obtain a net constructed with strands and intersections.
3. The method according to claim 1, wherein the plurality of the yarn threads are twisted when braided.
4. The method according to claim 1 or 2, wherein the heat-treating is conducted without pressure.
5. The method according to claim 1, wherein the intersections are knotless.
NO20181438A 2017-11-10 2018-11-08 Method for manufacturing fishing net NO344891B1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP2017217236A JP7022976B2 (en) 2017-11-10 2017-11-10 Plastic-like mesh and its manufacturing method
JP2018000346A JP6359215B1 (en) 2018-01-05 2018-01-05 Production method of fishing net
JP2018096346A JP6437686B1 (en) 2018-05-18 2018-05-18 Production method of fishing net

Publications (2)

Publication Number Publication Date
NO20181438A1 NO20181438A1 (en) 2019-05-13
NO344891B1 true NO344891B1 (en) 2020-06-15

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NO20181438A NO344891B1 (en) 2017-11-10 2018-11-08 Method for manufacturing fishing net

Country Status (1)

Country Link
NO (1) NO344891B1 (en)

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001271270A (en) * 2000-03-23 2001-10-02 Unitica Fibers Ltd Mesh sheet for construction work and method for producing the same
WO2011135082A1 (en) * 2010-04-29 2011-11-03 Dsm Ip Assets B.V. Multifilament yarn construction
JP2016056487A (en) * 2014-09-12 2016-04-21 ユニチカ株式会社 Sheath-core composite polyamide monofilament having excellent flexural fatigue resistance
WO2016162569A1 (en) * 2015-04-10 2016-10-13 Lankhorst Euronete Portugal, S.A. Sealed rope, use thereof and method for production

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001271270A (en) * 2000-03-23 2001-10-02 Unitica Fibers Ltd Mesh sheet for construction work and method for producing the same
WO2011135082A1 (en) * 2010-04-29 2011-11-03 Dsm Ip Assets B.V. Multifilament yarn construction
JP2016056487A (en) * 2014-09-12 2016-04-21 ユニチカ株式会社 Sheath-core composite polyamide monofilament having excellent flexural fatigue resistance
WO2016162569A1 (en) * 2015-04-10 2016-10-13 Lankhorst Euronete Portugal, S.A. Sealed rope, use thereof and method for production

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