WO2019091237A1 - 一种玻璃嵌制品及其制备方法 - Google Patents

一种玻璃嵌制品及其制备方法 Download PDF

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Publication number
WO2019091237A1
WO2019091237A1 PCT/CN2018/107493 CN2018107493W WO2019091237A1 WO 2019091237 A1 WO2019091237 A1 WO 2019091237A1 CN 2018107493 W CN2018107493 W CN 2018107493W WO 2019091237 A1 WO2019091237 A1 WO 2019091237A1
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WO
WIPO (PCT)
Prior art keywords
glass
substrate
cavity
wall
blown
Prior art date
Application number
PCT/CN2018/107493
Other languages
English (en)
French (fr)
Inventor
欧介仁
Original Assignee
广东介仁玻璃有限公司
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 广东介仁玻璃有限公司 filed Critical 广东介仁玻璃有限公司
Priority to JP2020554343A priority Critical patent/JP7043624B2/ja
Priority to US16/771,678 priority patent/US11479058B2/en
Publication of WO2019091237A1 publication Critical patent/WO2019091237A1/zh

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B44—DECORATIVE ARTS
    • B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C5/00—Processes for producing special ornamental bodies
    • B44C5/005—Processes for producing special ornamental bodies comprising inserts
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B9/00—Blowing glass; Production of hollow glass articles
    • C03B9/30—Details of blowing glass; Use of materials for the moulds
    • C03B9/31—Blowing laminated glass articles or glass with enclosures, e.g. wires, bubbles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B44—DECORATIVE ARTS
    • B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C5/00—Processes for producing special ornamental bodies
    • B44C5/06—Natural ornaments; Imitations thereof
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B9/00—Blowing glass; Production of hollow glass articles
    • C03B9/30—Details of blowing glass; Use of materials for the moulds
    • C03B9/32—Giving special shapes to parts of hollow glass articles
    • A—HUMAN NECESSITIES
    • A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47G—HOUSEHOLD OR TABLE EQUIPMENT
    • A47G19/00—Table service
    • A47G19/22—Drinking vessels or saucers used for table service
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2031/00—Other particular articles
    • B29L2031/722—Decorative or ornamental articles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B44—DECORATIVE ARTS
    • B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C3/00—Processes, not specifically provided for elsewhere, for producing ornamental structures
    • B44C3/10—Producing and filling perforations, e.g. tarsia plates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B44—DECORATIVE ARTS
    • B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C5/00—Processes for producing special ornamental bodies
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B44—DECORATIVE ARTS
    • B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C5/00—Processes for producing special ornamental bodies
    • B44C5/04—Ornamental plaques, e.g. decorative panels, decorative veneers
    • B44C5/0407—Ornamental plaques, e.g. decorative panels, decorative veneers containing glass elements

Definitions

  • the invention relates to a glass ornament, in particular to a glass insert and a preparation method thereof.
  • Glass is an amorphous material that cannot be formed by conventional means such as demolding.
  • Today's glass products such as hot paperweights, hollow animals, solid animals, abstract animal forms, and hemp ropes, are based on glass blowing.
  • the current glass blown products have a single shape and material, and the decorative effect is monotonous, and the glass blown inlaid decorative structure cannot be obtained.
  • the technical problem to be solved by the present invention is to provide a glass embedded product to solve the problem that the shape, material, product and decorative effect of the glass product are monotonous, and the glass-blown inlaid decorative structure cannot be obtained.
  • the technical problem to be solved by the present invention is to provide a method for preparing a glass insert to solve the problem that the prior art method cannot prepare a glass blown inlaid decorative structure.
  • a glass insert comprising a substrate, the substrate having a hollow cavity, a sidewall of the cavity being formed with a plurality of hollow holes, the hollow hole penetrating with the hollow cavity; the glass insert further comprising a glass blown decorative structure nested in a substrate; the glass blown decorative structure comprising a glass blown liner sleeved in the substrate cavity and a glass raised decorative portion embedded in the hollow hole of the substrate; The raised decorative portion and the glass blown inner liner are integrally formed into a blow molded body.
  • the glass blown decorative structure decorates the substrate from the inside to the outside; the glass raised decorative portion is formed on the outer side wall of the glass blown inner liner close to the inner wall of the substrate cavity, and protrudes outwardly and An integral convex structure held in the hollow hole of the substrate; the glass blown inner liner is close to the inner wall of the hollow substrate cavity and forms a double inner wall structure of the substrate cavity with the inner wall of the substrate cavity.
  • the inner wall of the material cavity is annular, and the glass blowing inner liner is annular, and forms a double-layer annular wall adjacent to the inner wall of the substrate cavity.
  • the substrate cavity is adapted to be glass blow molded therein; the glass raised decorative portion is adapted to the shape of the hollow hole; the glass raised decorative portion is a figure, a pattern or a pattern.
  • a gap is formed between the glass blowing inner liner and the inner wall of the substrate cavity; and a gap is formed between the glass convex decorative portion and the hole wall of the substrate hollow hole.
  • the spacer includes a removable protective adhesive layer formed on the inner wall surface of the substrate before blowing the glass, and a corresponding interval formed after the protective layer is removed after blowing the glass blown decorative structure; Further infusion in the interval forms an adhesive layer.
  • the removable protective layer is a bone cement layer.
  • a method of preparing a glass insert comprises the steps of:
  • Step 1 providing a substrate to be decorated: a hollow cavity is formed inside the substrate, and a plurality of hollow holes are formed on the sidewall of the cavity, and the hollow hole and the hollow cavity are penetrated;
  • Step 2 forming a removable protective layer on the substrate to be decorated: applying a removable protective glue to the inner wall of the substrate and/or the hollow hole or directly immersing the substrate in the protective glue, thereby
  • the inner wall of the material cavity and/or the inner surface of the hollow hole form a removable protective layer of a predetermined thickness, and the heat resistant temperature of the protective layer is not lower than the glass melting temperature;
  • Step 3 blowing a glass decorative structure in the substrate cavity: the molten glass is blown into the cavity, a glass blowing lining is formed in the cavity, and the molten glass is filled with the hollow hole to form a glass convex embedded in the hollow hole.
  • the decorative portion, the glass convex decorative portion and the glass blown inner liner are a one-piece integrated structure;
  • Step 4 the protective adhesive layer is removed: the protective adhesive layer is removed from the inner wall of the substrate cavity and/or the hollow hole, and the space for removing the protective adhesive layer is correspondingly formed into a space.
  • the step 4 is a method of cleaning to remove the protective adhesive layer, and the substrate having the decorative structure is washed with a cleaning agent or a solvent, and the protective adhesive layer is dissolved in the corresponding cleaning agent or solvent and then removed; the method further includes the step 5. Infiltrating the gap to form an adhesive layer.
  • the removable protective glue is bone cement
  • the protective rubber layer is a bone cement layer
  • the solvent is water.
  • the glass embossed decorative portion is formed by blowing the inner lining of the glass inside the hollow substrate while the liquid glass is outwardly protruded by extruding the hollow hole during blowing, thereby forming various shapes on the surface of the substrate and / or size of the shape.
  • the glass inserts combined with the blown glass and the hollow substrate are more aesthetic, simple in structure, diversified in decorative effects, diversified in products, and can be blown into various glass blows without costing a fixed abrasive.
  • the decorative structure is suitable for any cavity and hollow hole shape of various substrates, and has better adaptability.
  • Figure 1 is a perspective view of a hollow base body in accordance with an embodiment of the present invention.
  • FIG. 2 is a perspective view of a hollowed out substrate having an inner surface covered with a bone cement protective layer in accordance with an embodiment of the present invention.
  • Fig. 3 is a perspective view of the blown glass in the hollow substrate after the embodiment of the present invention is formed.
  • FIG. 4 is a perspective view of a glass insert according to an embodiment of the present invention.
  • the invention relates to a glass embedded product and a preparation method thereof, which are used for blowing glass decoration on various hollow substrates by using a blown glass process, and decorating the substrate from the inside to the outside to form a glass inside the substrate.
  • the inner lining is blown, and the glass convex decorative part is integrally formed with the glass blowing inner lining in the hollow hole outside the substrate, and the decorative effect is excellent, various decorative patterns can be formed, and the process method is simple.
  • the glass insert 100 of the embodiment of the present invention includes a hollow hollow substrate 10 having a hollow cavity 1 and a plurality of hollow holes 11 formed on the sidewall of the cavity 1.
  • the hollow hole 11 penetrates the hollow body 1.
  • the glass inlay 100 further includes a glass blown decorative structure 20 nested within the substrate 10.
  • the glass blown decorative structure 20 includes a glass blown liner 2 sleeved in the substrate cavity 1 and a glass raised decorative portion 21 embedded in the hollow hole 11 of the substrate 1.
  • the glass convex decorative portion 21 is a projection which is integrally protruded outward from the outer wall of the glass blowing inner liner 2 into the hollow hole 11 and is held in the hollow hole 11.
  • the glass convex decorative portion 21 is an integral glass blow forming structure which is formed by one blow molding with the inner liner 2, and has a shape and a size corresponding to the corresponding hollow holes 11, and is flowed into the hollow hole 11 by the liquid glass during the blowing of the molten glass. After cooling, it is naturally formed, so that a stable and fitted mosaic bond is formed with the hollow hole 11, and the inner liner 2 is used to be held together with the substrate 1 without being detached.
  • some or all of the glass convex decorative portions 21 may also protrude from the outer surface of the hollow hole 11 to be a spherical surface, a curved surface, a curved surface or other shapes of the bubble body, and the end surface size may be More than the size of the hollow hole 11, the bubble body is clamped on the outside of the hollow hole 11, so that the inner liner 2 and the substrate 1 can be snapped together at the hollow hole 11, and the glass is blown to the inner liner 2 and the substrate. 10 further tightens to form a firm nested structure.
  • the hollow holes 11 may have one or several, and correspondingly, the outer wall of the inner liner correspondingly forms one or more glass convex decorative portions 21.
  • the outer wall of the inner liner 2 is a side wall that faces and is adjacent to the inner wall 12 of the substrate cavity 1.
  • the glass blown decorative structure 20 is formed by performing liquid glass blow molding and cooling in the hollow cavity 1 of the hollow substrate 10.
  • the hollow substrate 10 of the present invention may be various shapes and shapes of articles to be decorated, and may be made of metal or non-metal, such as a ceramic substrate, a metal substrate or a wood substrate; It is in a variety of shapes, such as various containers such as cups, bowls, bottles, etc., or other items or supplies.
  • the substrate 10 has an internal cavity 1 adapted to be blown into the glass, and the glass blowpipe extends into the interior of the cavity 1 when the glass is blown.
  • the hollow hole 11 can also be inserted into the inlet of the glass blowing tube when the glass is blown, so that the substrate 10 does not need to be separately formed according to the actual situation.
  • One or more hollow holes 11 penetrating therethrough are formed in the side wall of the cavity 1.
  • the side wall of the substrate cavity 1 is annular, and accordingly, the inner wall 12 of the substrate cavity 1 is annular.
  • the glass blown liner 2 is formed by blowing and cooling liquid glass in the cavity 1 of the hollow substrate 10.
  • the shape of the inner liner 2 coincides with and conforms to the inner wall 12 of the hollow substrate cavity 1.
  • the glass convex decorative portion 21 is an integral part of the glass blowing inner liner 2, and is a projection formed by cooling the liquid glass filled with the hollow holes 11 when the liquid glass is blown.
  • a glass raised decorative portion 21 is embedded and held in a hollow hole 11 to protrude from the outer surface of the substrate 10.
  • the glass convex decorative portion 21 may be a single glass bead, bead or other various graphic shapes, or may be various patterns or patterns to form a decorative structure for the substrate 10.
  • the glass blown liner 2 is blown into the cavity 1 of the substrate by the melted glass.
  • the shape of the glass blowing liner 2 is the same as the shape of the inner wall 12 of the hollow substrate cavity 1, and is sleeved in the cavity 1 to form a double inner wall structure of the cavity 1.
  • the glass blown liner 2 overlaps the inner wall 12 of the hollow substrate 10 in parallel to form a double inner wall structure of the cavity 1.
  • the side wall of the inner liner 2 corresponds to a ring shape, and overlaps with the inner wall of the substrate 1 to form a double-layer annular side wall of the cavity 1, and the inner center encloses the cavity 1.
  • the side wall of the inner liner 2 corresponds to one side of the cavity 1 as an inner wall (not labeled), and the side that fits the inner wall of the substrate cavity is an outer wall 22 (see FIG. 4), and the outer wall 22 is adjacent to the inner wall of the substrate cavity, and the outer wall
  • the integral glass convex decorative portion 21 formed on the surface is embedded in the substrate hollow hole 11 and is engaged with each other to stabilize the cooperation between the inner liner 2 and the substrate 1.
  • the glass convex decorative portion 21 protrudes from the hollow hole 11 to form a decorative pattern, a pattern or a pattern on the surface of the substrate, and can form decorative beads of various patterns, and the decorative effect is beautiful, and the structure is simple and firm.
  • the spacer 3 comprises a removable (eg washable) protective layer 4 applied to the inner wall surface of the substrate cavity prior to blowing the liner 2, which is removed after blowing to form the liner 2
  • the interval formed corresponding to the protective layer 4 is formed.
  • the substrate 10 is completely immersed in the washable glue before blowing the glass blown liner, or directly on the inner wall of the substrate 10 (and also in the outer wall and the hollow hole) to be coated with removable protection.
  • the glue thus forms the protective adhesive layer 4, and then the glass is blow molded in the cavity 1, and the glass blown liner 2 is formed inside the protective adhesive layer 4 on the surface of the inner wall 12 of the cavity, as an embodiment.
  • the glass blowing liner 2 is attached to the protective layer 4 of the inner wall 12 of the chamber. Therefore, when the glass decorative structure 20 is blown, a protective adhesive layer 4 is formed between the outer side surface 22 of the formed inner liner 2 and the inner wall 12 of the substrate cavity. After the glass blowing is completed, the entire product is cleaned to remove the washable protective layer 4 on the inner wall of the substrate cavity.
  • the faded protective layer 4 forms a space 3 between the inner wall 12 of the substrate cavity and the glass-blown liner 2.
  • a gap 3 ′ is also formed between the glass convex decorative portion 21 and the hole wall of the substrate hollow hole 11 , and the inner wall surface of the substrate cavity and the hollow hole are coated before the blowing of the inner liner 2
  • the washable protective adhesive layer 4 is formed by correspondingly forming the protective adhesive layer 4 after being blown to form the inner liner 2.
  • the inner and outer surfaces of the substrate 1 and the hollow holes are covered with a removable protective layer, which is dried and then inside the substrate.
  • the removable protective adhesive layer 4 is formed in both the outer wall and the hollow hole.
  • the whole product is cleaned with a corresponding cleaning agent, and the gap between the glass convex decorative portion 21 and the hole wall of the substrate hollow hole 11 is formed after the protective adhesive layer 4 is dissolved and eluted. And the spacing 3 between the inner wall 12 of the substrate cavity and the glass blown liner 2.
  • the removable protective glue refers to a paint or adhesive that can be dissolved in a cleaning agent such as a solvent, and is removed by immersion cleaning.
  • the form of the removable protective layer formed means that the layer of glue can be dissolved and dissolved in a dissolved manner by a corresponding cleaning agent such as a solvent.
  • the washable protective glue may be a washable protective glue (ie, a coating or an adhesive), and the corresponding protective layer is a washable protective layer (ie, dissolved in water).
  • the heat resistant temperature of the protective adhesive layer 4 is not lower than the melting temperature of the glass, so that when the glass is blow molded, the substrate 10 is insulated by the protective adhesive layer 4 and the liquid glass slag is isolated so as not to be burnt or Break the surface layer of the substrate.
  • the water-washable protective rubber is bone cement
  • the corresponding protective rubber layer 4 is a bone cement layer 4.
  • the inner (and outer) wall surface and the hollow hole are coated with bone glue before the inner liner 2 is blown, or the substrate is directly immersed in the bone glue, and after drying, it is inside the substrate (outside The surface layer and the hollow hole form a bone cement layer 4.
  • the cleaning product is soaked with water, and the bone cement layer 4 is dissolved in the water and then removed from the substrate 1, corresponding to the interval 3' between the glass convex decorative portion 21 and the wall of the substrate hollow hole 11. And the spacing 3 between the inner wall 12 of the substrate cavity and the glass blown liner 2.
  • the glue may be injected again into the gap 3, 3' to form an adhesive layer (not shown).
  • a prior art glass glue or a glue suitable for bonding substrates can be selected.
  • the adhesive layer may be configured to cooperate with the expansion coefficients of the glass blown liner 2 and the hollow substrate 10 so that the hollow substrate 10 and the glass blown liner 2 do not detach from each other in the case of thermal expansion and contraction, and Will not be crushed or broken.
  • the shape of the glass blowing liner 2 can be various shapes, which are formed in a unitary structure in the substrate cavity and the glass convex decorative portion 21 of the outer side wall thereof.
  • the distance between the inner liner 2 and the inner wall of the chamber may be only a gap of 3, or a variety of different spacings to accommodate decorative or other functional needs.
  • the glass convex decorative portion 21 has a plurality of shapes or patterns, and the spacing between the walls of the holes may be 3' or may be different from the interval 3'.
  • the shape, size, and height of the glass raised decorative portion 21 may be the same or different.
  • a method of preparing a glass insert 100 according to an embodiment of the invention includes the steps described below.
  • the substrate 10 to be decorated is provided.
  • the inside of the substrate 10 has a hollow cavity 1 and a plurality of hollow holes 11 formed in the side walls of the cavity 1, and the hollow holes 11 penetrate the hollow cavity 1.
  • the internal cavity 1 of the substrate 1 is designed to be internally molded into a molten glass.
  • a washable protective layer 4 is formed on the substrate 10 to be decorated, and dried.
  • a protective glue that can be removed eg, cleaned and removed
  • a removable protective layer 4 is formed in the hollow hole.
  • the substrate 10 is immersed in a washable protective gel to form a protective layer 4 of a predetermined thickness in the inner wall, the outer wall and the hollow of the substrate cavity.
  • the washable protective glue is bone glue, which is an animal type bonding material, which can be dissolved in water and washed with water.
  • the protective rubber layer 4 is a bone cement layer 4 whose heat resistant temperature is not lower than the temperature at which the glass is blown and the temperature of the blown glass.
  • the protective adhesive layer (or the bakelite layer) 4 is used to protect the substrate 10 from being broken or thermally deformed by the molten glass, and can insulate and block the molten glass from contacting the substrate 10.
  • step three the glass decorative structure 20 is blown in the substrate cavity.
  • one end of the glass blow pipe is extended into the substrate cavity 1, the other end is inserted into the molten glass, and the glass is blown into the cavity 1, and the molten glass is blown into the cavity 1 to be cooled to form a glass blow.
  • the lining 2 is formed, and at the same time, the molten glass fills the hollowed-out hole at the cooled glass raised decorative portion 21, and the glass blown lining 2 and its glass raised decorative portion 21 constitute the glass blown decorative structure 20.
  • the glass blowing decorative structure 20 forms a parallel double wall structure of the glass blowing liner 2 on the inner wall 12 of the substrate 1, and forms a glass convex decorative portion 21 in the hollow hole 11 of the surface of the substrate.
  • a glass blowing lining 2 is formed in the cavity 1 to be close to the inner wall 12 of the substrate 1 and adhered to the bone cement layer 4, and at the same time, the liquid glass forming glass embossing portion 21 is embedded in the hollow hole 11 in the hollow hole position, and the glass bulge is formed.
  • the decorative portion 21 is an integral inseparable glass blowing structure integrally formed on the outer wall 21 of the glass blowing liner 2.
  • the glass blowing liner 2 blown in the substrate cavity 1 can be of various shapes or sizes, and may have the same or different shape as the inner wall of the cavity, and may be attached to the inner wall of the cavity or separated from the inner wall.
  • the shape, size and structure of the integral glass convex decorative portion 21 formed by the liquid glass filled hollow holes may be the same or different, and may have different gaps with the hollow holes, and the mosaic is not in phase.
  • step four the protective layer is removed. Specifically, the finished product is immersed and washed to obtain the glass insert 100 of FIG.
  • the substrate 10 with the decorative structure 20 is blown together, and a suitable cleaning agent or solvent is selected.
  • the water is washed, the bone glue layer 4 is dissolved in water and completely washed away, and the removed bone glue layer 4 is in the glass.
  • a gap 3 is formed between the blown inner liner 2 and the inner wall 12 of the substrate 1, and a gap 3' is also formed between the glass convex decorative portion 21 and the hole wall of the hollowed hole, and the spacing 3, 3' is used to adjust the substrate 1
  • the difference from the coefficient of thermal expansion of the glass to accommodate the difference in volume change between the two due to thermal expansion and contraction.
  • the glass blown decorative structure 20 and the substrate are nested with each other, and the structure is stable, and the decorative substrate is from the inside to the outside, the decorative effect is excellent, and the process method is simple.
  • the present invention can use a ceramic, metal or other hollow material as a substrate, and a water-washable adhesive layer acts as a treatment layer inside the substrate, and is then blown inside the treatment layer by liquid glass.
  • the glass is filled with various hollow holes, and after the liquid glass is cooled, a glass blowing lining is formed on the inner wall of the substrate cavity, and the outer hollow of the substrate forms a shape of various sizes and shapes.

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Geometry (AREA)
  • Joining Of Glass To Other Materials (AREA)
  • Details Of Rigid Or Semi-Rigid Containers (AREA)
  • Containers Having Bodies Formed In One Piece (AREA)
  • Surface Treatment Of Glass (AREA)

Abstract

一种玻璃嵌制品（100）及其制备方法，该玻璃嵌制品（100）包括基材（10），基材（10）具有腔体（1），腔体（1）的侧壁上形成有若干镂空孔（11），镂空孔（11）与腔体（1）贯通。玻璃嵌制品（100）还包括嵌套于基材（10）的玻璃吹制装饰结构（20），玻璃吹制装饰结构（20）包括套设于基材（10）的腔体（1）内的玻璃吹制内衬（2）以及嵌入基材（10）的镂空孔（11）内的玻璃凸起装饰部（21）。玻璃凸起装饰部（21）与玻璃吹制内衬（2）是一体吹制成型的整体结构。

Description

一种玻璃嵌制品及其制备方法 技术领域
本发明涉及玻璃装饰品，尤其是指一种玻璃嵌制品及其制备方法。
 背景技术
玻璃是一种非晶体，无法用脱模等常规方式成型。现今市场上的玻璃制品，如热摊镇纸、空心动物、实心动物、抽象动物形态、麻绳工艺，都是以玻璃吹制术为基础的。但当前的玻璃吹制品形状及材质单一，装饰效果单调，无法获得玻璃吹制镶嵌装饰结构。
 技术问题
本发明所要解决的技术问题是：提供一种玻璃嵌制品，以解决玻璃制品形状、材质、产品及其装饰效果单调，无法获得玻璃吹制镶嵌装饰结构的问题。
本发明所要解决的技术问题是：提供一种制备玻璃嵌制品的方法，以解决现有技术的方法无法制备玻璃吹制镶嵌装饰结构的问题。
 技术解决方案
为解决上述技术问题，本发明采用如下技术方案：
一种玻璃嵌制品，包括基材，所述基材具有中空腔体，所述腔体的侧壁上形成有若干镂空孔，所述镂空孔与中空腔体贯通；所述玻璃嵌制品进一步包括嵌套于基材的玻璃吹制装饰结构；所述玻璃吹制装饰结构包括套设于基材腔体内的玻璃吹制内衬以及嵌入基材镂空孔内的玻璃凸起装饰部；所述玻璃凸起装饰部与玻璃吹制内衬是一体吹制成型的整体结构。
所述玻璃吹制装饰结构由内至外地装饰所述基材；所述玻璃凸起装饰部是在玻璃吹制内衬与基材腔体内壁贴近的外侧壁上形成的、向外凸出并卡持在基材镂空孔内的一体凸起结构；所述玻璃吹制内衬贴近镂空基材腔体内壁且与基材腔体内壁形成基材腔体的双层内壁结构。
所述玻璃吹制内衬与基材腔体内壁平行重叠地形成基材腔体的双层内壁结构；所述玻璃吹制内衬与镂空基材腔体内壁的形状及尺寸相互适配；基材腔体内壁为环形，所述玻璃吹制内衬为环形，且与基材腔体内壁形成相互贴近的双层环状壁。
基材腔体适合于其内进行玻璃吹制成形；所述玻璃凸起装饰部与镂空孔形状相适配；所述玻璃凸起装饰部是图形、图案或花纹。
所述玻璃吹制内衬与基材腔体内壁之间形成有间隔；所述玻璃凸起装饰部与基材镂空孔的孔壁之间形成有间隔。
所述间隔包括由吹制玻璃之前形成于基材内壁表面的一种可去除的保护胶层、在吹制形成所述玻璃吹制装饰结构之后褪去该保护胶层后对应形成的间隔；所述间隔内进一步灌注形成粘胶层。
所述可去除的保护胶层为骨胶层。
为解决上述技术问题，本发明进一步采取的技术方案是：
一种制备玻璃嵌制品的方法，包括以下步骤：
步骤一，提供待装饰基材：基材内部具有中空腔体以及腔体的侧壁上形成若干镂空孔，镂空孔与中空腔体贯通；
步骤二，在待装饰基材上形成可去除的保护胶层：在基材的腔体内壁和/或镂空孔内涂覆可去除的保护胶或者直接将基材浸入保护胶中，从而在基材腔体内壁和/或镂空孔内表面形成预定厚度的可去除的保护胶层，所述保护胶层的耐热温度不低于玻璃熔化温度；
步骤三，在基材腔体内吹制玻璃装饰结构：熔化的玻璃在腔体内吹制成型，在腔体内形成玻璃吹制内衬，熔化玻璃填充镂空孔位形成镶嵌于镂空孔内的玻璃凸起装饰部，所述玻璃凸起装饰部与玻璃吹制内衬是由一次吹制成形的一体结构；
步骤四，褪去保护胶层：从基材腔体内壁和/或镂空孔内褪去保护胶层，褪去保护胶层的空间对应形成间隔。
所述步骤四是清洗的方法褪去保护胶层，将吹制有装饰结构的基材用清洗剂或溶剂进行清洗，保护胶层溶解于对应的清洗剂或溶剂后褪去；所述方法进一步包括步骤五，在所述间隔内灌注形成粘胶层。
所述可去除的保护胶为骨胶，所述保护胶层为骨胶层，所述溶剂为水。
 有益效果
本发明的有益效果是：
通过在镂空基材内部吹制玻璃内层，同时由液态玻璃在吹制时挤出镂空孔向外凸出而形成镶嵌结构的玻璃凸起装饰部，从而可在基材表面形成各种形状和/或大小的造型。
这种吹制玻璃与镂空基材结合而成的玻璃嵌制品更具有美感，结构简单，装饰效果多样化，产品多样化，无需花费更多成本制作固定磨具就可吹制成形各种玻璃吹制装饰结构，适合各种基材的任意腔体及镂空孔形状，适应性更强。
下面结合附图对本发明作进一步的详细描述。
 附图说明
图1是本发明实施例的镂空基体的立体图。
图2是本发明实施例的内表面覆盖有骨胶保护层的镂空基体的立体图。
图3是本发明实施例的镂空基体内吹制玻璃成形后的立体图。
图4是本发明实施例的玻璃嵌制品的立体图。
 本发明的最佳实施方式
需要说明的是，在不冲突的情况下，本申请中的各实施例及实施例中的特征可以相互结合，下面结合附图和具体实施例对本发明作进一步详细说明。
本发明实施例提供的一种玻璃嵌制品及其制备方法，是利用吹制玻璃工艺对各种镂空基材进行吹制玻璃装饰，且自内至外地装饰基材，从而在基材内部形成玻璃吹制内衬，在基材外部的镂空孔内与玻璃吹制内衬一体成形地形成玻璃凸起装饰部，其装饰效果极佳，可形成各种装饰图案，工艺方法简单。
请参照图1-4所示，本发明实施例的玻璃嵌制品100包括中空的镂空基材10，镂空基材10具有中空腔体1以及腔体1的侧壁上形成的若干镂空孔11，镂空孔11与中空腔体1贯通。
玻璃嵌制品100进一步包括嵌套于基材10的玻璃吹制装饰结构20。所述玻璃吹制装饰结构20包括套设于基材腔体1内的玻璃吹制内衬2以及镶嵌于基材1的镂空孔11内的玻璃凸起装饰部21。玻璃凸起装饰部21是从玻璃吹制内衬2的外壁一体地向外凸起至镂空孔11内的突起物并卡持在镂空孔11内。玻璃凸起装饰部21是与内衬2一次吹制成型的整体玻璃吹制成形结构，其形状及大小与对应镂空孔11相适应，是在熔融玻璃吹制时由液态玻璃流入镂空孔11冷却后自然形成，因此与镂空孔11之间形成稳固、适配的镶嵌结合，进而使用内衬2与基材1卡持固定在一起而不会脱离。
作为一些实例，根据液滴表面张力原理，部分或全部玻璃凸起装饰部21也可能凸出在镂空孔11外部的端面可以是球面、弧面、曲面或其它形状的泡状体，端面尺寸可以大于镂空孔11的尺寸，其泡状体卡持在镂空孔11的外部，从而可在镂空孔11处将内衬2与基材1卡接在一起，将玻璃吹制内衬2与基材10进一步套紧形成牢固的嵌套结构。
所述镂空孔11可以有一个或若干个，相应地，内衬外壁对应形成一个或多个玻璃凸起装饰部21。内衬2的外壁是朝向并贴近于基材腔体1的内壁12上的侧壁。
玻璃吹制装饰结构20是在镂空基材10的中空腔体1内进行液态玻璃吹制成形并冷却后形成的。
请再次参照图1，本发明的镂空基材10，可以是各种材质各种形状的待装饰物品，可以由金属或非金属制成，例如陶瓷基材、金属基材或木质基材；可以为多种形状，例如各种容器如杯子、碗、瓶等，或者其它物品或用品。基材10具有适合于玻璃吹制成形的内部腔体1，玻璃吹制成型时玻璃吹管伸入腔体1内部。当然，镂空孔11也可作为玻璃吹制成型时伸入玻璃吹管的入口，因此基材10根据实际情况也可不另行形成开口。腔体1的侧壁上形成有贯通的一个或多个镂空孔11。作为一种实施方式，基材腔体1的侧壁为环形，相应地，基材腔体1的内壁12为环形。
进一步参照图3-4，玻璃吹制内衬2是由液态玻璃在镂空基材10的腔体1内进行吹制成形并冷却而成。作为一种实施例，内衬2的形状与镂空基材腔体1的内壁12一致且相互贴合。玻璃凸起装饰部21是玻璃吹制内衬2整体不可分割的一部分，是在液态玻璃吹制时填充镂空孔11的液态玻璃冷却后形成的凸起。一个玻璃凸起装饰部21嵌入且卡持于一个镂空孔11内，可突出于基材10的外表面。与镂空孔11的造型相对应，玻璃凸起装饰部21可以是单个玻璃嵌珠，为珠状或其它各种图形形状，也可以是各种图案或花纹，形成对基材10的装饰结构。
玻璃吹制内衬2由融化的玻璃吹制成形于基材的腔体1内。作为一种实施方式，玻璃吹制内衬2的形状与镂空基材腔体1的内壁12形状一致，套设于腔体1内形成腔体1的双层内壁结构。在一些实施方式中，玻璃吹制内衬2与镂空基材10的内壁12平行重叠形成腔体1的双层内壁结构。本实施例中，内衬2的侧壁对应为环形，与基材1的内壁重叠构成腔体1的双层环形侧壁，内部中心围成腔体1。内衬2的侧壁对应腔体1的一面为内壁（未标号），与基材腔体内壁相贴合的一侧为外壁22（如图4），外壁22贴近基材腔体内壁，外壁表面形成的一体玻璃凸起装饰部21嵌入基材镂空孔11内，相互卡持配合，使内衬2与基材1之间的配合稳固。同时，玻璃凸起装饰部21伸出镂空孔11形成基材表面的装饰图形、图案或花纹，可形成各种图案的装饰珠，装饰效果美观，结构简单牢固。
进一步地，所述玻璃吹制内衬2与镂空基材10的内壁之间存在间隔3，可用以适应及调节热胀冷缩时二者之间的体积变化差。作为一种实施方式，间隔3包括在吹制内衬2之前涂抹于基材腔体内壁表面的一种可去除（如可水洗去除）的保护胶层4、在吹制形成内衬2之后褪去除该保护胶层4后对应形成的间隔。具体是，在吹制玻璃吹制内衬之前将基材10完全浸入可洗除的胶中，或者直接在基材10内壁（同时也可以在其外壁及镂空孔内）涂覆可去除的保护胶从而形成保护胶层4，之后再在腔体1内进行玻璃吹制成形，并在腔体内壁12表面的保护胶层4内侧成形所述玻璃吹制内衬2，作为一种实施例，玻璃吹制内衬2贴合于腔体内壁12的保护胶层4上。因此，当吹制玻璃装饰结构20时，形成的内衬2的外侧面22与基材腔体内壁12之间有一层保护胶层4。玻璃吹制结束后，对制品整体进行清洗，从而去除基材腔体内壁上的可洗除保护胶层4。相应地，褪去的保护胶层4在基材腔体内壁12与玻璃吹制内衬2之间形成了间隔3。
同理，玻璃凸起装饰部21与基材镂空孔11的孔壁之间也形成有间隔3’，在吹制内衬2之前基材腔体内壁表面以及镂空孔内均涂覆有所述可洗除的保护胶层4、在吹制形成内衬2之后清洗去除该保护胶层4后对应形成的间隔。或者，当吹制玻璃前将基材整体浸入所述可去除的保护胶中时，基材1的内外表面及镂空孔内均覆盖有可去除的保护胶层，晾干后在基材的内外壁和镂空孔内均形成所述可去除的保护胶层4。玻璃吹制装饰结构20吹制完成后，用相应的清洗剂清洗整体产品，保护胶层4溶解洗脱后形成玻璃凸起装饰部21与基材镂空孔11的孔壁之间的间隔3’以及基材腔体内壁12与玻璃吹制内衬2之间的间隔3。
可去除的保护胶是指可溶解于清洁剂如溶剂的涂料或粘胶剂，以浸泡清洗的方式褪去。相应地，形成的可去除的保护胶层是指可用相应清洁剂如溶剂以溶解的方式溶解去除胶层。可洗除的保护胶可以是可水洗去除的保护胶（即涂料或粘胶剂），对应形成的保护胶层为可水洗去除的保护胶层（即溶解于水）。保护胶层4的耐热温度不低于玻璃的熔融温度，因此在玻璃吹制成形时，基材10由所述保护胶层4隔热以及隔离液体玻璃熔渣，从而不会被烫坏或破环基材表层。较佳地，可水洗去除的保护胶为骨胶，对应形成的保护胶层4为骨胶层4。
使用时，在吹制内衬2之前在基材内（和外）壁表面以及镂空孔内均涂覆有骨胶，或直接将基材浸入骨胶中，晾干后即在基材的内（外）表面、镂空孔内形成骨胶层4。在吹制形成内衬2之后用水浸泡清洗制品，骨胶层4溶解于水后从基材1上褪去，对应形成玻璃凸起装饰部21与基材镂空孔11的孔壁之间的间隔3’以及基材腔体内壁12与玻璃吹制内衬2之间的间隔3。
进一步地，为使玻璃吹制内衬2与镂空基材10之间稳固配合，可在间隔3、3’内再次注入胶体形成粘胶层（未图示）。可选择现有技术中玻璃胶或适用于粘结基材的粘胶。
粘胶层可以配置为与玻璃吹制内衬2和镂空基材10的膨胀系数相配合，使得镂空基材10与玻璃吹制内衬2发生热胀冷缩的情形时不会相互脱离，也不会挤碎或破碎。
可以理解，所述玻璃吹制内衬2的形状可以为各种形状，其成形于基材腔体内与其外侧壁的玻璃凸起装饰部21为一体结构。内衬2与腔体内壁之间的距离可以仅为间隔3，也可以为各种不同间距，以适应装饰或其它功能需要。同样，玻璃凸起装饰部21的形状或图案有多种，与孔壁之间的间距可以是间隔3’，也可以不同于间隔3’。玻璃凸起装饰部21的形状、大小及高度可以各自相同或不同。
本发明实施例提供的一种制备玻璃嵌制品100的方法，包括以下描述的各步骤。
步骤一，提供待装饰基材10。参照图1，基材10内部具有中空腔体1以及腔体1的侧壁上形成的若干镂空孔11，镂空孔11与中空腔体1贯通。基材1的内部腔体1设计为适用于内部进行熔融玻璃吹制成形。
步骤二，在待装饰基材10上形成可洗除的保护胶层4，并晾干。参照图2，在基材10的腔体内壁12，也可同时在外壁以及镂空孔11内，涂覆可去除（如清洗去除）的保护胶，从而在基材腔体内壁12（或包括外壁及镂空孔内）形成可去除的保护胶层4。或者，将基材10浸入可洗除的保护胶中，从而在基材腔体内壁、外壁及镂空孔内形成一层预定厚度的保护胶层4。本实施例中，所述可洗除的保护胶为骨胶，是一种动物类黏结材料，可溶解于水中而用水洗除。相应地，所述保护胶层4为骨胶层4，其耐热温度不低于玻璃吹制时工作的温度以及吹制玻璃的温度。
保护胶层（或骨胶层）4用于保护基材10不会被溶化玻璃破环或受热变形等，可隔热及阻隔溶化玻璃接触基材10。
步骤三，在基材腔体内吹制玻璃装饰结构20。参照图3，将玻璃吹管一端伸基材腔体1内，另一端插入熔化的玻璃中，并在腔体1内进行玻璃吹制成形，熔化的玻璃吹至腔体1内经冷却后形成玻璃吹制内衬2，同时熔化的玻璃填充镂空孔位处经冷却后玻璃凸起装饰部21，玻璃吹制内衬2及其玻璃凸起装饰部21构成玻璃吹制装饰结构20。
作为一种实例，玻璃吹制装饰结构20在基材1内壁12上形成玻璃吹制内衬2的平行双层壁结构、且在基材表面的镂空孔11内形成玻璃凸起装饰部21，腔体1内形成玻璃吹制内衬2贴近于基材1内壁12且粘附于骨胶层4，同时在镂空孔位的液态玻璃形成玻璃凸起装饰部21嵌入镂空孔11内，玻璃凸起装饰部21是玻璃吹制内衬2的外壁21上一体凸出的整体不可分的玻璃吹制结构。
可以理解，在基材腔体1内吹制的玻璃吹制内衬2可以是各种形状或尺寸，可能与腔体内壁形状相同或不同，可以附着于腔体内壁，也可与内壁分离。液态玻璃填充镂空孔形成的一体玻璃凸起装饰部21形状、尺寸及结构可以相同或不同，与镂空孔之间可以有不同间隙，不相程度的镶嵌。
步骤四，褪去保护胶层。具体是浸泡清洗成品，获得图4的玻璃嵌制品100。将吹制有装饰结构20的基材10一并进行清洗，选择合适的清洗剂或溶剂，本实施例中是进行水洗，骨胶层4溶解于水而完全洗去，褪去的骨胶层4在玻璃吹制内衬2与基材1内壁12之间形成间隔3，且镂空孔位的玻璃凸起装饰部21与孔壁之间也形成间隔3’，间隔3、3’用于调节基材1与玻璃的热膨胀系数的差别，以适应二者因热胀冷缩时体积变化的差异。最终获得的成品100中，玻璃吹制装饰结构20与基材相互嵌套，结构稳固，自内至外装饰基材，装饰效果极佳，工艺方法简单。
本发明可使用陶瓷、金属或其它镂空材料作为基材，在基材内部作用可水洗去除的胶层作为处理层，再在处理层内部利用液态玻璃进行吹制。使玻璃填充各镂空孔位，液态玻璃冷却后，在基材腔体内壁形成玻璃吹制内衬，基材外部镂空处形成大小不一，形态多样的造型。
尽管已经示出和描述了本发明的实施例，对于本领域的普通技术人员而言，可以理解在不脱离本发明的原理和精神的情况下可以对这些实施例进行多种变化、修改、替换和变型，本发明的保护范围由所附权利要求及其等同范围限定。

Claims (10)

  1. 一种玻璃嵌制品，包括基材，所述基材具有中空腔体，所述腔体的侧壁上形成有若干镂空孔，所述镂空孔与中空腔体贯通；其特征在于，所述玻璃嵌制品进一步包括嵌套于基材的玻璃吹制装饰结构；所述玻璃吹制装饰结构包括套设于基材腔体内的玻璃吹制内衬以及嵌入基材镂空孔内的玻璃凸起装饰部；所述玻璃凸起装饰部与玻璃吹制内衬是一体吹制成型的整体结构。
  2. 如权利要求1所述的玻璃嵌制品，其特征在于，所述玻璃吹制装饰结构由内至外地装饰所述基材；所述玻璃凸起装饰部是在玻璃吹制内衬与基材腔体内壁贴近的外侧壁上形成的、向外凸出并卡持在基材镂空孔内的一体凸起结构；所述玻璃吹制内衬贴近镂空基材腔体内壁且与基材腔体内壁形成基材腔体的双层内壁结构。
  3. 如权利要求2所述的玻璃嵌制品，其特征在于，所述玻璃吹制内衬与基材腔体内壁平行重叠地形成基材腔体的双层内壁结构；所述玻璃吹制内衬与镂空基材腔体内壁的形状及尺寸相互适配；基材腔体内壁为环形，所述玻璃吹制内衬为环形，且与基材腔体内壁形成相互贴近的双层环状壁。
  4. 如权利要求1所述的玻璃嵌制品，其特征在于，基材腔体适合于其内进行玻璃吹制成形；所述玻璃凸起装饰部与镂空孔形状相适配；所述玻璃凸起装饰部是图形、图案或花纹。
  5. 如权利要求1~4中任一项所述的玻璃嵌制品，其特征在于：所述玻璃吹制内衬与基材腔体内壁之间形成有间隔；所述玻璃凸起装饰部与基材镂空孔的孔壁之间形成有间隔。
  6. 如权利要求5所述的玻璃嵌制品，其特征在于：所述间隔包括由吹制玻璃之前形成于基材内壁表面的一种可去除的保护胶层、在吹制形成所述玻璃吹制装饰结构之后褪去该保护胶层后对应形成的间隔；所述间隔内进一步灌注形成粘胶层。
  7. 如权利要求6所述的玻璃嵌制品，其特征在于：所述可去除的保护胶层为骨胶层。
  8. 一种制备玻璃嵌制品的方法，其特征在于，所述方法包括以下步骤：
    步骤一，提供待装饰基材：基材内部具有中空腔体以及腔体的侧壁上形成若干镂空孔，镂空孔与中空腔体贯通；
    步骤二，在待装饰基材上形成可去除的保护胶层：在基材的腔体内壁和/或镂空孔内涂覆可去除的保护胶或者直接将基材浸入保护胶中，从而在基材腔体内壁和/或镂空孔内表面形成预定厚度的可去除的保护胶层，所述保护胶层的耐热温度不低于玻璃熔化温度；
    步骤三，在基材腔体内吹制玻璃装饰结构：熔化的玻璃在腔体内吹制成型，在腔体内形成玻璃吹制内衬，熔化玻璃填充镂空孔位形成镶嵌于镂空孔内的玻璃凸起装饰部，所述玻璃凸起装饰部与玻璃吹制内衬是由一次吹制成形的一体结构；
    步骤四，褪去保护胶层：从基材腔体内壁和/或镂空孔内褪去保护胶层，褪去保护胶层的空间对应形成间隔。
  9. 如权利要求8所述的制备玻璃嵌制品的方法，其特征在于：所述步骤四是清洗的方法褪去保护胶层，将吹制有装饰结构的基材用清洗剂或溶剂进行清洗，保护胶层溶解于对应的清洗剂或溶剂后褪去；所述方法进一步包括步骤五，在所述间隔内灌注形成粘胶层。
  10. 如权利要求9所述的制备玻璃嵌制品的方法，其特征在于：所述可去除的保护胶为骨胶，所述保护胶层为骨胶层，所述溶剂为水。
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